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Slides done by KARTIKA SINGH

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 Remembering
Organic Reagents
can be so
Confusing
 Don’t Worry
We have some

for you
Substrate Alkane, alkene, alkyne & Benzene
❖

❖
Reagents ❖

❖
Na/Liq.NH3
Na/Liq.NH3
Pd-BaSO4 + Pb(CH3COO)2 + Quinoline
(Lindlar’s Catalyst)
Pd-BaSO4 + Pb(CH3COO)2 + Quinoline
(Lindlar’s Catalyst)
Raney Ni, Pt, Pd/H2
Raney Ni, Pt, Pd/H2
NBS (N-Bromo Succinimide)
 NBS (N-Bromo Succinimide)

∝
CO +HCl + AlCl3/CuCl
CO +HCl + AlCl3/CuCl
Substrate Haloalkane & Haloarene
❖
Reagents
❖

❖
Alcoholic KOH/NaOH
Alcoholic KOH/NaOH
Aqueous KOH/NaOH
Aqueous KOH/NaOH
NaNH2/LiNH2
NaNH2/LiNH2
Na/Dry ether
Na/Dry ether
Substrate Alcohol, Phenol & Ether
❖
Reagents
❖

❖
Conc. H2SO4
Conc. H2SO4
PCC/PDC
PCC/PDC
PDC
PCC

PDC
Alkaline KMnO4
Alkaline KMnO4
 Jones Reagent
(CrO3/aq. H2SO4/ acetone)
 Jones Reagent
(CrO3/aq. H2SO4/ acetone)
 Substrate Aldehyde & Ketone
❖

Reagents ❖

❖
Dil. KOH/NaOH
Dil. KOH/NaOH
Conc. KOH/NaOH
Conc. KOH/NaOH
Grignard’s Reagent (RMgX)
Grignard’s Reagent (RMgX)
NH2-NH2/KOH
NH2-NH2/KOH
Zn/Hg + HCl
Zn/Hg + HCl
LiAlH4
LiAlH4
NaBH4
NaBH4
Substrate Carboxylic Acid & Derivatives

Reagents ❖

❖
Soda Lime (NaOH/ CaO)
Soda Lime (NaOH/ CaO)
LiAlH4
LiAlH4
Let’s do some
Examples
 Predict the Reagent

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 Predict the Reagent

Solution
 Predict the Reagent

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 Predict the Reagent

Solution
 Predict the Reagent

Question
 Predict the Reagent

Solution
 Predict the Reagent

Question
 Predict the Reagent

Solution
Let’s do some
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 Predict the Reagent

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 Predict the Reagent

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 Predict the Reagent

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 Predict the Reagent

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92