VAN DER WAALS

Componente Yi * ai Yi * ai bi Yi* bi
C1 0.8608 8575.5407 7381.8254 0.6896 0.59361 Temperatura de operación
C2 0.0748 20765.394 1553.2515 1.0423 0.07796
C3 0.0187 34958.482 653.7236 1.4494 0.02710 Presión de operación
n-C4 0.0038 51704.5463 196.4773 1.8647 0.00709
i-C4 0.0022 49590.2748 109.0986 1.8631 0.00410 A
n-C5 0.0012 71098.8265 85.3186 2.3215 0.00279 B
i-C5 0.0015 68084.2414 102.1264 2.2675 0.00340
n-C6 0.0010 92812.9206 92.8129 2.8049 0.00280
n-C7 115840.0388 0.0000 3.2882 0.00000 Valor de Z
n-C8 141300.6032 0.0000 3.8095 0.00000
n-C9 167712.1517 0.0000 4.3254 0.00000
n-C10 197604.7282 0.0000 4.9065 0.00000 a
CO2 0.0340 13614.3328 462.8873 0.6861 0.02333 1
N2 0.0020 5103.6493 10.2073 0.6192 0.00124
H2S 16829.9533 0.0000 0.6908 0.00000
0.0000 0.00000
C3+,C5+,C7+ 0.0000 0.00000
Sumatoria 1.0000 ------- 10647.7289 ------- 0.74342
am bm
 R (PSIA ft3 / lbM °R) 10.732

Temperatura de operación 107.07 0 F 567.07 °R

Presión de operación 1232.59 PSI 1247.29 °PSIA

0.3586
0.1524

0.7835

b c d
1.1524 0.3586 0.05464 -0.00013937
 REDLLICH-KWONG

Componente Yi * ai Yi * ai bi Yi* bi R (PSIA ft3 / lbM °R) 10.732

C1 0.8608 161138.635 138708.1370 0.4783 0.4117 Temperatura de operación
C2 0.0748 493871.5865 36941.5947 0.723 0.0541
C3 0.0187 914850.0825 17107.6965 1.0053 0.0188 Presión de operación
n-C4 0.0038 1450777.678 5512.9552 1.2934 0.0049
i-C4 0.0022 1363299.4707 2999.2588 1.2922 0.0028 D 0.01582
n-C5 0.0012 2096657.9636 2515.9896 1.6102 0.0019 E 0.00008
i-C5 0.0015 1987957.2941 2981.9359 1.5728 0.0024
n-C6 0.0010 2844901.5489 2844.9015 1.9455 0.0019 Valor de Z 0.8093
n-C7 3663763.7851 0.0000 2.2807 0.0000
n-C8 4585615.45 0.0000 2.6423 0.0000
n-C9 5564823.1381 0.0000 3.0001 0.0000 a b
n-C10 6682304.203 0.0000 3.4032 0.0000 1 1
CO2 0.0340 323149.884 10987.0961 0.4759 0.0162
N2 0.0020 78077.1494 156.1543 0.4294 0.0009
H2S 442639.9584 0.0000 0.4791 0.0000
0.0000 0.0000
C3+,C5+,C7+ 0.0000 0.0000
Sumatoria 1.00 ------- 220755.71963406 ------- 0.51563425
am bm
107.07 0 F 567.07 °R

1232.59 PSI 1247.29 °PSIA

c d
0.19535 0.03299 0.00018
 PENG ROBINSON

Componente Yi * aci Yi * aci

C1 0.8608 9294.4124 8000.6302
C2 0.0748 22506.1185 1683.4577
C3 0.0187 37888.9868 708.5241
n-C4 0.0038 56038.8426 212.9476
i-C4 0.0022 53747.3357 118.2441
n-C5 0.0012 77058.9094 92.4707
i-C5 0.0015 73791.6172 110.6874
n-C6 0.0010 100593.2558 100.5933
n-C7 125550.6947 0
n-C8 153145.5711 0
n-C9 181771.1508 0
n-C10 214169.5666 0
CO2 0.0340 14755.5971 501.6903
N2 0.0020 5531.4788 11.0630
H2S 18240.7771 0

C3+,C5+,C7+
Sumatoria 1.0000 ------- 11540.3083
acm
PENG ROBINSON

bi Yi* bi Wi Wi* bi
0.4292 0.3695 0.0104 0.0045
0.6487 0.0485 0.0986 0.0640
0.9021 0.0169 0.1524 0.1375
1.1606 0.0044 0.2010 0.2333
1.1596 0.0026 0.1848 0.2143
1.4449 0.0017 0.2539 0.3669
1.4113 0.0021 0.2223 0.3137
1.7458 0.0017 0.3007 0.5250
2.0465 0.0000 0.3498 0.7159
2.3710 0.0000 0.4018 0.9527
2.6921 0.0000 0.4455 1.1993
3.0538 0.0000 0.4885 1.4918
0.4270 0.0145 0.2250 0.0961
0.3853 0.0008 0.0400 0.0154
0.4299 0.0000 0.1000 0.0430
0.0000 0.0000
0.0000 0.0000
----- 0.4627 ------- 6.3732
bm Wm
R (PSIA ft3 / lbM °R) 10.732
Temperatura de operación 107.07 0 F 567.07 °R

Presión de operación 1232.59 PSI 1247.29 °PSIA

A 0.388642399318
B 0.09482961576

Valor de Z 0.7183

a b c d
1 0.9052 0.1720 0.0270 0.000111
 SOAVE-REDLLICH-KWONG (SRK)

Componente Yi * aci Yi * aci

C1 0.8608 8689.2715 7479.7249
C2 0.0748 21040.7892 1573.8510
C3 0.0187 35422.1091 662.3934
n-C4 0.0038 52390.2634 199.0830
i-C4 0.0022 50247.9521 110.5455
n-C5 0.0012 72041.7549 86.4501
i-C5 0.0015 68987.1897 103.4808
n-C6 0.0010 94043.8262 94.0438
n-C7 117376.3351 0.0000
n-C8 143174.5632 0.0000
n-C9 169936.3875 0.0000
n-C10 200225.4060 0.0000
CO2 0.0340 13794.8891 469.0262
N2 0.0020 5171.3351 10.3427
H2S 17053.1559 0.0000
0.0000
C3+,C5+,C7+ 0.0000
Sumatoria 1.0000 ------- 10788.9415
am
E-REDLLICH-KWONG (SRK)

bi Yi* bi Wi Wi* bi
0.4781 0.4115 0.0104 0.0090
0.7227 0.0541 0.0986 0.0074
1.0049 0.0188 0.1524 0.0028
1.2928 0.0049 0.2010 0.0008
1.2917 0.0028 0.1848 0.0004
1.6095 0.0019 0.2539 0.0003
1.5721 0.0024 0.2223 0.0003
1.9447 0.0019 0.3007 0.0003
2.2797 0.0000 0.3498 0.0000
2.6412 0.0000 0.4018 0.0000
2.9988 0.0000 0.4455 0.0000
3.4017 0.0000 0.4885 0.0000
0.4757 0.0162 0.2250 0.0077
0.4293 0.0009 0.0400 0.0001
0.4789 0.0000 0.1000 0.0000
0.0000 0.0000
0.0000 0.0000
----- 0.5154 ------- 0.0290
bm Wm
 R (PSIA ft3 / lbM °R) 10.732

Temperatura de operación 107.07 0 F 567.07 °R

Presión de operación 1232.59 PSI 1247.29 °PSIA

A 0.36334
B 0.10564

Valor de Z 0.7362

a b c d
1 1 0.246544 0.038382 0.000143
 STANDING-KATZ
Componente Yi Yi * Mi
(lb/lbmol)
C1 0.8608 0.8608 16.0430
C2 0.0748 0.0748 30.0700
C3 0.0187 0.0187 44.0970
n-C4 0.0038 0.0038 58.1240
i-C4 0.0022 0.0022 58.1240
n-C5 0.0012 0.0012 72.1510
i-C5 0.0015 0.0015 72.1510
n-C6 0.0010 0.0010 86.1780
n-C7 100.2050
n-C8 114.2320
n-C9 128.2590
n-C10 142.2860
CO2 0.0340 0.0340 44.0100
N2 0.0020 0.0020 28.0130
H2S 34.0760

C3+,C5+,C7+
Sumatoria 1.0000 1 -------

Temperatura de operación 107.07 0 F 567.07

Presión de operación 1232.59 PSI 1247.29

Corrección por Wichert y Azis

Tsc' 370.7714
Psc' 672.3239
Fsk 5.1851
A 0.0340
B 0
STANDING-KATZ
Yi * Mi Tci Yi * Tci Pci Yi * Pci
(lb/lbmol) (ºR) (ºR) (lpca) (lpca)
13.8098 343.37 295.5729 667.8 574.8422
2.2492 550.09 41.1467 707.8 52.9434
0.8246 666.01 12.4544 616.3 11.5248
0.2209 765.65 2.9095 550.7 2.0927
0.1279 734.98 1.6170 529.1 1.1640
0.0866 845.7 1.0148 488.6 0.5863
0.1082 829.1 1.2437 490.4 0.7356
0.0862 913.7 0.9137 436.9 0.4369
0.0000 972.8 0.0000 396.8 0.0000
0.0000 1024.22 0.0000 360.6 0.0000
0.0000 1070.68 0.0000 332 0.0000
0.0000 1112.1 0.0000 304 0.0000
1.4963 547.9 18.6286 1071 36.4140
0.0560 227.6 0.4552 493 0.9860
0.0000 672.7 0.0000 1306 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
19.0658 ------- 375.9564 ------ 681.7260

°R

°PSIA 1.53

Z=0.84

1.86
 MÉTODO DEL EMR

Componente Yi Yi * EMR
C1 0.8608 0.8608 13.984
C2 0.0748 0.0748 23.913
C3 0.0187 0.0187 34.316
n-C4 0.0038 0.0038 44.243
i-C4 0.0022 0.0022 44.741
n-C5 0.0012 0.0012 55.267
i-C5 0.0015 0.0015 55.302
n-C6 0.0010 0.001 65.617
n-C7 75.875
n-C8 86.193
n-C9 96.529
n-C10 106.859
CO2 0.0340 0.034 15.75
N2 0.0020 0.002 9.407
H2S 19.828

C3+,C5+,C7+
Sumatoria 1.0000 1

X1 15.1104 Pc
X2 0.4956 Tc
X3 0.8925
X4 0.5365

Temperatura de operación 107.07 0 F 567.07

Presión de operación 1232.59 PSI 1247.29

1.33
Z=0.82
1.57
Yi* EMR Grupo I
12.0374 Componente Yi* Yi **
1.7887 C1 0.8606 0.959848315859915
0.6417 CO2 0.0340 0.037921035021191
0.1681 N2 0.0020 0.002230649118894
0.0984 H2S
0.0663 Sumatoria 0.8966 1
0.0830
0.0656
0
0 Grupo II
0 Componente Yi* Yi **
0 C2 0.0748 0.7248
0.5355 C3 0.0187 0.1812
0.0188 n-C4 0.0038 0.0368
0 i-C4 0.0022 0.0213
n-C5 0.0012 0.0116
i-C5 0.0015 0.0145
15.5036 n-C6 0.0010 0.0097
EMRm n-C7
n-C8
n-C9
793.2504 n-C10
425.5805 C3+,C5+,C7+

Sumatoria 0.1032 1

°R

°PSIA MC7+ (lb/lbmol) 114.232

EMR C7+ 86.1437
upo I
EMR Yi** EMR
13.984 13.4225
15.75 0.5973
9.407 0.0210
19.828 0
14.0408
EMRI

upo II
EMR Yi* EMR
23.913 17.3322906976744
34.316 6.21811240310078
44.243 1.62910271317829
44.741 0.953781007751938
55.267 0.642639534883721
55.302 0.803808139534884
65.617 0.635823643410853
75.875
86.193
96.529
106.859

28.2156
EMRII
Componente Yi * Mi Yi * Mi
(lb/lbmol) (lb/lbmol)
C1 0.8608 16.0430 13.8098
C2 0.0748 30.0700 2.2492
C3 0.0187 44.0970 0.8246
n-C4 0.0038 58.1240 0.2209
i-C4 0.0022 58.1240 0.1279
n-C5 0.0012 72.1510 0.0866
i-C5 0.0015 72.1510 0.1082
C6 0.0010 86.1780 0.0862
C7 100.2050 0.0000
C8 114.2320 0.0000
C9 128.2590 0.0000
C10 142.2860 0.0000
CO2 0.0340 44.0100 1.4963
N2 0.0020 28.0130 0.0560
H2S 34.0760 0.0000
0.0000
C3+,C5+,C7+ 0.0000
Sumatoria 1 ------- 19.0658

Temperatura de operación 107.07 0 F 567.07

Presión de operación 1232.59 PSI 1247.29

 PITZER
Tci Yi * Tci Pci Yi * Pci Tci/Pci
(ºR) (ºR) (lpca) (lpca)
343.37 295.5729 667.8 574.8422 0.5142
550.09 41.1467 707.8 52.9434 0.7772
666.01 12.4544 616.3 11.5248 1.0807
765.65 2.9095 550.7 2.0927 1.3903
734.98 1.6170 529.1 1.1640 1.3891
845.7 1.0148 488.6 0.5863 1.7309
829.1 1.2437 490.4 0.7356 1.6907
913.7 0.9137 436.9 0.4369 2.0913
972.8 0.0000 396.8 0.0000 2.4516
1023.17 0.0000 361.1 0.0000 2.8335
1070.47 0.0000 330.7 0.0000 3.2370
1111.87 0.0000 304.6 0.0000 3.6503
547.9 18.6286 1071 36.4140 0.5116
227.6 0.4552 493 0.9860 0.4617
672.7 0.0000 1306 0.0000 0.5151
0.0000 0.0000
0.0000 0.0000
------- 375.9564 ------ 681.7260

°R Corrección por Witcher y Azis

Tsc' 376.7830
°PSIA Psc' 684.8255
Fp 0.9362
A 0.0340
B 0

1.51
Z0
Z'
Z
1.82
Yi * Tci/Pci Tci/ √Pci Yi * Tci/ √Pci √(Tci/Pci)

0.4426 13.2874 11.4378 0.7171

0.0581 20.6766 1.5466 0.8816
0.0202 26.8278 0.5017 1.0395
0.0053 32.6267 0.1240 1.1791
0.0031 31.9526 0.0703 1.1786
0.0021 38.2595 0.0459 1.3156
0.0025 37.4396 0.0562 1.3003
0.0021 43.7132 0.0437 1.4461
0.0000 48.8357 0.0000 1.5658
0.0000 53.8436 0.0000 1.6833
0.0000 58.8650 0.0000 1.7992
0.0000 63.7073 0.0000 1.9106
0.0174 16.7420 0.5692 0.7152
0.0009 10.2506 0.0205 0.6795
0.0000 18.6144 0.0000 0.7177
0.0000 0.0000
0.0000 0.0000
0.5543 14.4158
a k

Regla SBV
J 0.5502
Tsc)sc 377.7191
Psc)sc 686.5270

0.85
0.17
0.8549
Yi * √(Tci/Pci) Factor Acéntrico Factor Acéntrico
de Pitzer (w) Yi* wi (wp)
0.6172 0.0104 0.0090
0.0659 0.0986 0.0074
0.0194 0.1524 0.0028
0.0045 0.2010 0.0008
0.0026 0.1848 0.0004
0.0016 0.2539 0.0003
0.0020 0.2223 0.0003
0.0014 0.3007 0.0003
0.0000 0.3498 0.0000
0.0000 0.3900 0.0000
0.0000 0.4439 0.0000
0.0000 0.4869 0.0000
0.0243 0.2250 0.0077
0.0014 0.0400 0.0001
0.0000 0.0950 0.0000
0.0000 0.0000
0.0000 0.0000
0.7404 0.0290
b w
 Dranchuk Abou Kassen
Componente Yi Yi * Mi Yi * Mi Tci Yi * Tci Pci
(lb/lbmol) (lb/lbmol) (ºR) (ºR) (lpca)
C1 0.8608 0.8608 16.0430 13.8098 343.37 295.5729 667.8
C2 0.0748 0.0748 30.0700 2.2492 550.09 41.1467 707.8
C3 0.0187 0.0187 44.0970 0.8246 666.01 12.4544 616.3
n-C4 0.0038 0.0038 58.1240 0.2209 765.65 2.9095 550.7
i-C4 0.0022 0.0022 58.1240 0.1279 734.98 1.6170 529.1
n-C5 0.0012 0.0012 72.1510 0.0866 845.7 1.0148 488.6
i-C5 0.0015 0.0015 72.1510 0.1082 829.1 1.2437 490.4
n-C6 0.0010 0.0010 86.1780 0.0862 913.7 0.9137 436.9
n-C7 100.2050 0.0000 972.8 0.0000 396.8
n-C8 114.2320 0.0000 1024.22 0.0000 360.6
n-C9 128.2590 0.0000 1070.68 0.0000 332
n-C10 142.2860 0.0000 1112.1 0.0000 304
CO2 0.0340 0.0340 44.0100 1.4963 547.9 18.6286 1071
N2 0.0020 0.0020 28.0130 0.0560 227.6 0.4552 493
H2S 34.0760 0.0000 672.7 0.0000 1306
0.0000 0.0000
C3+,C5+,C7+ 0.0000 0.0000
Sumatoria 1 1 ------- 19.0658 ------- 375.9564 ------

Temperatura de operación 107.07 0 F 567.07 °R Agrupación de constantes DAK

C1 -0.5252
Presión de operación 1232.59 PSI 1247.29 °PSIA C2 0.1452
C3 -0.0425
Corrección por Wichert y Azis C4 0.0260
Tsc' 370.7714
Psc' 672.3239 1.53 Densidad reducida (ρr) 0.3908
Fsk 5.1851
A 0.0340 Z (Standing y Katz) 0.84
B 0
1.86

Z por DAK 0.8433

Yi * Pci
(lpca)
574.8422
52.9434
11.5248
2.0927
1.1640
0.5863
0.7356
0.4369
0.0000
0.0000
0.0000
0.0000
36.4140
0.9860
0.0000
0.0000
0.0000
681.7260

Valores de las constantes

DAK
A1 0.327
A2 -1.070
A3 -0.534
A4 0.016
A5 -0.052
A6 0.548
A7 -0.736
A8 0.184
A9 0.106
A10 0.613
A11 0.721
 Dranchuk-Pulvis-Robinso
Componente Yi Yi * Mi
(lb/lbmol)
C1 0.8608 0.8608 16.0430
C2 0.0748 0.0748 30.0700
C3 0.0187 0.0187 44.0970
n-C4 0.0038 0.0038 58.1240
i-C4 0.0022 0.0022 58.1240
n-C5 0.0012 0.0012 72.1510
i-C5 0.0015 0.0015 72.1510
n-C6 0.0010 0.0010 86.1780
n-C7 100.2050
n-C8 114.2320
n-C9 128.2590
n-C10 142.2860
CO2 0.0340 0.0340 44.0100
N2 0.0020 0.0020 28.0130
H2S 34.0760

C3+,C5+,C7+
Sumatoria 1.0000 1 -------

Temperatura de operación 107.07 0 F 567.07

Presión de operación 1232.59 PSI 1247.29

Corrección por Wichert y Azis CONSTANTES DPR

Tsc' 370.7714 a1
Psc' 672.3239 a2
Fsk 5.1851 a3
A 0.0340 a4
B 0 a5
a6
a7
a8
 Dranchuk-Pulvis-Robinson
Yi * Mi Tci Yi * Tci Pci Yi * Pci
(lb/lbmol) (ºR) (ºR) (lpca) (lpca)
13.8098 343.37 295.5729 667.8 574.8422
2.2492 550.09 41.1467 707.8 52.9434
0.8246 666.01 12.4544 616.3 11.5248
0.2209 765.65 2.9095 550.7 2.0927
0.1279 734.98 1.6170 529.1 1.1640
0.0866 845.7 1.0148 488.6 0.5863
0.1082 829.1 1.2437 490.4 0.7356
0.0862 913.7 0.9137 436.9 0.4369
0.0000 972.8 0.0000 396.8 0.0000
0.0000 1024.22 0.0000 360.6 0.0000
0.0000 1070.68 0.0000 332 0.0000
0.0000 1112.1 0.0000 304 0.0000
1.4963 547.9 18.6286 1071 36.4140
0.0560 227.6 0.4552 493 0.9860
0.0000 672.7 0.0000 1306 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
19.0658 ------- 375.9564 ------ 681.7260

°R

°PSIA 1.53

CONSTANTES DPR Z (Standing-Katz)

0.31506237
-1.0467099 1.86
-0.57832729
0.53530771
-0.61232032 Densidad reducida (ρr)
-0.10488813
0.68157001 Z (Ajuste DPR)
0.68446549
0.84

0.3899

0.8778