Calculos para diagramas T vs X-Y y X vs Y ideales para Metanol (1)-Agua(2) @

Pman (Hg) 175 Patm (Hg) 585 PTOT (Hg) 760

(g/mol) (cal/g°C) (cal/mol°C) VanLaar (cal/mol) A B C (°C)

Compuesto PM Cp Cp A12_21 l Ctes. de Antoine (mm Hg y °C) p.e.
Metanol (1) 32.04 0.605 19.3842 0.9014 8415 8.0724 1574.99 238.8 64.574
Agua (2) 18.015 0.999 17.9970 0.5559 9718 7.96681 1669.21 228 100.197

Ec. Antoine Raoult/Dalton

(°C) (mm Hg) (-) (mm Hg) (-) (cal °C/mol) Relación de Equilibrio
Ti P1 i
0
P2 i
0
X1 P y1 hl Hv K1 K1 K2 K2
64.574 760.0135 182.6218 0.999977 760.00000 0.999994 1252 9667 1.00002 1.000018 0.24029 0.24029
65.000 772.8605 186.1434 0.978081 760.00000 0.994631 1258 9681 1.01692 1.016922 0.24493 0.24493
66.000 803.7296 194.6368 0.928205 760.00000 0.981613 1273 9717 1.05754 1.057539 0.25610 0.25610
67.000 835.6176 203.4562 0.880382 760.00000 0.967978 1288 9752 1.09950 1.099497 0.26771 0.26771
68.000 868.5504 212.6116 0.834511 760.00000 0.953704 1303 9789 1.14283 1.14283 0.27975 0.27975
69.000 902.5545 222.1132 0.790497 760.00000 0.938772 1317 9826 1.18757 1.187572 0.29225 0.29225
70.000 937.6565 231.9712 0.748250 760.00000 0.923159 1332 9865 1.23376 1.233759 0.30523 0.30523
71.000 973.8839 242.1965 0.707684 760.00000 0.906845 1347 9903 1.28143 1.281426 0.31868 0.31868
72.000 1011.264 252.7998 0.668720 760.00000 0.889806 1363 9943 1.33061 1.330611 0.33263 0.33263
73.000 1049.826 263.7921 0.631281 760.00000 0.872019 1378 9984 1.38135 1.381349 0.34709 0.34709
74.000 1089.597 275.1849 0.595295 760.00000 0.853462 1393 10025 1.43368 1.43368 0.36209 0.36209
75.000 1130.606 286.9896 0.560694 760.00000 0.834110 1408 10068 1.48764 1.48764 0.37762 0.37762
76.000 1172.884 299.2179 0.527412 760.00000 0.813938 1423 10111 1.54327 1.543269 0.39371 0.39371
77.000 1216.46 311.8820 0.495389 760.00000 0.792922 1439 10155 1.60061 1.600606 0.41037 0.41037
78.000 1261.365 324.9940 0.464566 760.00000 0.771036 1454 10201 1.65969 1.65969 0.42762 0.42762
79.000 1307.628 338.5664 0.434888 760.00000 0.748253 1469 10247 1.72056 1.720564 0.44548 0.44548
80.000 1355.283 352.6119 0.406303 760.00000 0.724546 1485 10294 1.78327 1.783267 0.46396 0.46396
81.000 1404.359 367.1435 0.378761 760.00000 0.699889 1500 10342 1.84784 1.847841 0.48308 0.48308
82.000 1454.89 382.1744 0.352214 760.00000 0.674254 1516 10392 1.91433 1.914329 0.50286 0.50286
83.000 1506.908 397.7180 0.326618 760.00000 0.647611 1531 10442 1.98277 1.982774 0.52331 0.52331
84.000 1560.446 413.7881 0.301931 760.00000 0.619931 1547 10494 2.05322 2.053219 0.54446 0.54446
85.000 1615.538 430.3985 0.278112 760.00000 0.591185 1563 10547 2.12571 2.125708 0.56631 0.56631
86.000 1672.218 447.5634 0.255122 760.00000 0.561342 1578 10601 2.20029 2.200287 0.58890 0.58890
87.000 1730.52 465.2974 0.232926 760.00000 0.530371 1594 10657 2.27700 2.27700 0.61223 0.61223
88.000 1790.479 483.6151 0.211487 760.00000 0.498241 1610 10713 2.35589 2.355893 0.63634 0.63634
89.000 1852.13 502.5315 0.190774 760.00000 0.464919 1625 10771 2.43701 2.437013 0.66123 0.66123
90.000 1915.51 522.0618 0.170755 760.00000 0.430372 1641 10831 2.52041 2.520408 0.68692 0.68692
91.000 1980.655 542.2215 0.151400 760.00000 0.394567 1657 10891 2.60612 2.606124 0.71345 0.71345
92.000 2047.6 563.0264 0.132680 760.00000 0.357469 1673 10954 2.69421 2.694211 0.74082 0.74082
93.000 2116.385 584.4924 0.114569 760.00000 0.319043 1689 11017 2.78472 2.784717 0.76907 0.76907
94.000 2187.046 606.6358 0.097041 760.00000 0.279253 1704 11082 2.87769 2.877692 0.79820 0.79820
95.000 2259.622 629.4731 0.080071 760.00000 0.238065 1720 11149 2.97319 2.973186 0.82825 0.82825
96.000 2334.15 653.0212 0.063635 760.00000 0.195439 1736 11217 3.07125 3.07125 0.85924 0.85924
97.000 2410.671 677.2971 0.047712 760.00000 0.151340 1752 11287 3.17194 3.171935 0.89118 0.89118
98.000 2489.224 702.3182 0.032280 760.00000 0.105727 1768 11358 3.27529 3.275294 0.92410 0.92410
99.000 2569.848 728.1021 0.017319 760.00000 0.058563 1784 11431 3.38138 3.381379 0.95803 0.95803
100.000 2652.584 754.6666 0.002810 760.00000 0.009808 1800 11506 3.49024 3.490242 0.99298 0.99298
100.197 2669.136 759.9934 0.000003 760.00000 0.000012 1803 11521 3.51202 3.512021 0.99999 0.99999
etanol (1)-Agua(2) @ 760 mm de Hg 760.0 mmHg = 1.0 atm = 1.0132472 bar = 1.033

NOMENCLATURA DE COLOR

(cal /mol) Celdas dato (llenar)

hli Hvi y Constantes de los componentes de la mz
1251.7066 9666.7066 y Titulos generales del proceso de cálculo
1803.2483 11521.248 y Variables calculadas

volatilidad f (x) Referencia

a 1/(y-x) p/graficar
4.16168 56429.858 0.999977 Diagrama T vs x-y (mezcla metanol-agua) @ 760 mm de
4.15196 60.420 0.978081 IDEAL
4.12938 18.724 0.928205 105
4.10711 11.416 0.880382
4.08515 8.390 0.834511 100
4.06349 6.744 0.790497
liquido V
4.04212 5.717 0.748250 95
4.02105 5.021 0.707684
4.00026 4.523 0.668720 90
3.97975 4.154 0.631281
Temperatura, T (°C)

3.95951 3.873 0.595295

85
3.93954 3.657 0.560694
3.91983 3.490 0.527412
3.90039 3.361 0.495389 80
3.88119 3.263 0.464566
3.86225 3.191 0.434888 75
3.84355 3.142 0.406303
3.82510 3.114 0.378761 70
3.80687 3.105 0.352214
3.78889 3.115 0.326618
65
3.77112 3.145 0.301931
3.75359 3.194 0.278112
60
3.73627 3.266 0.255122
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8
3.71917 3.362 0.232926
Fracción molar x, y
3.70228 3.487 0.211487
3.68560 3.648 0.190774
3.66912 3.852 0.170755
3.65285 4.112 0.151400
3.63678 4.449 0.132680
Diagrama x vs y (mezcla Metanol-agua) @ 760 mm de
3.62089 4.891 0.114569
IDEAL
3.60520 5.488 0.097041 1.0
3.58970 6.329 0.080071
3.57439 7.587 0.063635 0.9
3.55925 9.650 0.047712
0.8

0.7
or, y
 1.0

0.9

3.54430 13.615 0.032280 0.8

3.52952 24.246 0.017319
3.51491 142.899 0.002810 0.7

Fracción molar del vapor, y

3.51205 115228.818 0.000003
0.6

0.5

0.4

0.3

0.2

0.1

0.0
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8

Fracción molar del líquido, x

 Kg/cm2

l-agua) @ 760 mm de Hg

liquido Vapor

0.6 0.7 0.8 0.9 1.0

x, y

agua) @ 760 mm de Hg
 0.6 0.7 0.8 0.9 1.0

quido, x
 Calculos para diagramas T vs X-Y y X vs Y no ideales para Etanol (1)-Agua(2)
Pman (Hg) 0 Patm (Hg) 585 PTOT (Hg) 585

(g/mol) (cal/g°C) (cal/mol°C) VanLaar (cal/mol) A B C (°C)

Compuesto PM Cp A12_21 l Ctes. de Antoine (mm Hg y °C) p.e.
Etanol (1) 46.07 0.582 26.8127 1.6383 9216 8.2133 1652.05 231.48 71.863
Agua (2) 18.015 0.999 17.9970 0.5559 9718 7.96681 1669.21 228 93.023

Ec. Antoine Ec. Van Laar Raoult m

(°C) (mm Hg) (-) (-) (-) (mm Hg) (-) (-) (cal °C/mol)
Ti P1 i
0
P2 i
0
X1_supuesta g1 g2 P X1_calculada y1 hl Hv K1
71.863 584.9987 251.3244 1.000009 1.00000 1.74352 585.00000 1.000009 1.000007 1927 11143 1.00000
72.000 588.3198 252.7998 0.977690 1.00010 1.72874 585.00000 0.977690 0.983333 1916 11144 1.00577
73.000 613.0446 263.7921 0.828463 1.00708 1.62468 585.00000 0.828463 0.874330 1847 11156 1.05536
74.000 638.6364 275.1849 0.699394 1.02690 1.52714 585.00000 0.699394 0.784054 1788 11168 1.12105
75.000 665.1189 286.9896 0.586130 1.06312 1.43588 585.00000 0.586130 0.708465 1737 11181 1.20872
76.000 692.5167 299.2179 0.485492 1.12143 1.35085 585.00000 0.485492 0.644508 1693 11194 1.32754
77.000 720.8542 311.8820 0.395332 1.21076 1.27243 585.00000 0.395332 0.589810 1654 11208 1.49194
78.000 750.157 324.9940 0.314685 1.34425 1.20181 585.00000 0.314685 0.542441 1620 11222 1.72376
79.000 780.4505 338.5664 0.244165 1.53718 1.14137 585.00000 0.244165 0.500723 1592 11237 2.05076
80.000 811.761 352.6119 0.185788 1.79624 1.09404 585.00000 0.185788 0.463079 1571 11252 2.49251
81.000 844.115 367.1435 0.140877 2.10573 1.06079 585.00000 0.140877 0.428043 1558 11267 3.03842
82.000 877.5398 382.1744 0.107966 2.43531 1.03917 585.00000 0.107966 0.394414 1554 11281 3.65313
83.000 912.0628 397.7180 0.083939 2.76123 1.02545 585.00000 0.083939 0.361356 1555 11295 4.30498
84.000 947.7121 413.7881 0.065971 3.07222 1.01664 585.00000 0.065971 0.328341 1561 11308 4.97706
85.000 984.5163 430.3985 0.052101 3.36478 1.01086 585.00000 0.052101 0.295033 1569 11321 5.66270
86.000 1022.504 447.5634 0.041071 3.63877 1.00701 585.00000 0.041071 0.261215 1579 11333 6.36009
87.000 1061.706 465.2974 0.032072 3.89527 1.00441 585.00000 0.032072 0.226735 1590 11344 7.06945
88.000 1102.15 483.6151 0.024575 4.13571 1.00266 585.00000 0.024575 0.191479 1603 11354 7.79174
89.000 1143.869 502.5315 0.018217 4.36150 1.00150 585.00000 0.018217 0.155360 1616 11364 8.52817
90.000 1186.892 522.0618 0.012748 4.57396 1.00075 585.00000 0.012748 0.118305 1630 11372 9.27999
91.000 1231.251 542.2215 0.007987 4.77425 1.00030 585.00000 0.007987 0.080254 1644 11380 10.04838
92.000 1276.979 563.0264 0.003798 4.96342 1.00007 585.00000 0.003798 0.041151 1659 11386 10.83449
93.000 1324.107 584.4924 0.000082 5.14236 1.00000 585.00000 0.000082 0.000949 1674 11392 11.63938
93.023 1325.208 584.9940 0.000001 5.14637 1.00000 585.00000 0.000001 0.000011 1674 11392 11.65812
Etanol (1)-Agua(2) @ 585 mm de Hg 585.0 mmHg = 0.8 atm = 0.7799337 bar =

NOMENCLATURA DE COLOR

(cal /mol) Celdas dato (llenar)

hli Hvi y Constantes de los componentes de la mz
1926.845412 11142.845 y Titulos generales del proceso de cálculo
1674.138489 11392.138 y Variables calculadas

volatilidad f (x) Referencia

K2 a 1/(y-x) p/graficar
0.749039 1.33504 -439155.4865 1.000000
Diagrama T vs X-Y (mezcla etanol-agua) @ 585 mm de H
0.747050 1.34633 177.2017 0.977690
NO IDEAL
0.732612 1.44055 21.8022 0.828463
0.718369 1.56054 11.8120 0.699394
0.704413 1.71592 8.1743 0.586130
0.690935 1.92136 6.2887 0.485492 91
0.678372 2.1992896 5.1420 0.395332 liquido Vap

0.667662 2.58178 4.3907 0.314685

0.660563 3.10456 3.8977 0.244165
0.659436 3.77976 3.6063 0.185788 86
0.665745 4.56394 3.4823 0.140877
Temperatura, T (°C)

0.678882 5.38109 3.4910 0.107966

0.697163 6.17499 3.6047 0.083939
0.719099 6.92124 3.8114 0.065971
81
0.743715 7.61407 4.1164 0.052101
0.770427 8.25528 4.5425 0.041071
0.798887 8.84912 5.1371 0.032072
0.828891 9.40020 5.9915 0.024575
0.860313 9.9128728 7.2917 0.018217 76
0.893080 10.39099 9.4736 0.012748
0.927151 10.83791 13.8376 0.007987
0.962504 11.25656 26.7714 0.003798
0.999132 11.64949 1152.5542 0.000082 71
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8
0.999990 11.65824 97430.1985 0.000001
Fracción molar x, y

Diagrama X vs Y (mezcla etanol-agua) @ 585 mm de Hg

NO IDEAL
1.0
Fracción molar del vapor, y

0.9

0.8

0.7
 NO IDEAL
1.0

Fracción molar del vapor, y

0.9

0.8

0.7

0.6

0.5

0.4

0.3

0.2

0.1

0.0
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8

Fracción molar del líquido, x

 0.7951 Kg/cm2

nol-agua) @ 585 mm de Hg

liquido Vapor

.5 0.6 0.7 0.8 0.9 1.0

molar x, y

nol-agua) @ 585 mm de Hg
0.5 0.6 0.7 0.8 0.9 1.0

r del líquido, x