Practicod 4: Viscosity ~The wolor _Dote : 25 March 021 © Nome: Nevissa Rajkumar sf Student Number: a1q003¢90/ mass of « Polymer: ~The determine the molar mass of polymeus/by deter viscosity od measuring the flow take of a liqui __ @pillang twoewias the viscosity methed , using Flow Chart : a ee = _ : fim woes Find My ,ond=k\ M? Plt My = 1 yd Py 6 - : Oe = — t - ____ Relative Viscosity _ _ Plot tins me ys Oy: eM EM fe MK Tuy Fine! density Pus Me f | | | Viscosity - ny tote : ; [— Measure Flow rate “of polymer (Stock Solutions) T | Measure the flow rote of verter | Scanned with CamScannerResults Table 1: Flow rote of water. Run: | Time ts: ines osauw 1 u 2 2 A 3 " # 12 Ss (2 6 2 _ 3 R 3 u Vw lo. " Average WG Toble 2: Flow rote of Poly mer. - | Payee ist. Polymer'a net | Polyrier get, Run: | Pitemele: “Time ts : o| Time ts: ! | 3a a | 3 2 a6 125 | Average 34 19.45, Concentration of Prva Stock solution 4.00 “hiviv) Scanned with CamScannerCalculations : joke scosity of water at 25°C = 9.343 x10 kg . Dilution 1: Ms a a tte : _ (9.344 x10°%) 2 a | Ne 3 3 Ma = 2.981 x 107 kg mt gt — Na 7 9.34% x10" = 3190 ‘Calculations for dlilutions 2,3 aud A were done following the Same method i 7 | able 3: ‘The viscosity and Yelative viscosities of the. four dl Solutions =. - fe eo. t : : Dilution: [ta [kgm st: | Relative vacosity : | 2.981 x 1077 | 3-190 Ls x10 7% | Lele 1.128 x 107° 1.203 1.024 K (07 Scanned with CamScannerPolymer = 4.00 (wiv) Volume of Stock solution use = 50 ml. “Ms > Som) Me = ag + 0-049 Im! ax lo -3 kg Ph =m = ae oP kg v ee = Calculations for Same method. Table 4 : mass Concentrations For aul 100 x 107 © m akg ©1006 20 Kg dilutions : 3 m 3 mm" 2,3 aud 4 were done following the the solutions ot 25°C. ‘Scanned with CamScannerr dilution |: (To plot the graph) : © Calculations for dilutions 9, 3 aud 4 oe “done fotoaing ¢ the © game, method) . “Table $+ Values “for ™-' [pg ond “Fe Un densities: “for the dilutions - Scanned with CamScannerGraph 1: From the equation :of the graph: Y= mx tC - Yr O-Ola2x + 9.0338 . Extrapolating to zero , 220 Ys o-o012 (0) + 0.0338 Y= 0-0339 Cn} =-0-o3a8.:- Cni=k ( my \* mate o-eSan =, F-Oxilo nm Mika” f\ i, sl \Saay : & sof Vg mol My = 14669 .30 g I mol Groph 2: From the equation of the he Yeme +¢ u Orape: oy Y= 0-0042x + 90-0038 "| Extrapolating to 20 , x20 Y= 00042 (0) + 0-038 Yr 0-023 Cnt = 20-0239 Cua= kK = a aes “5 3 “1 e o-4e 0 °023% = 2.0 x10 7 m3. kg ( ae ) —— \g | mot My = 134-0 glmel. Scanned with CamScannerGraph 1 Scanned with CamScannerScanned with CamScanner___ Salution viscosity is rferied-t0. a5 0 fluids -resistance.to. flow ut te the internal faickion of a moving Fluid ond. largely . sdeperds on the nature. oud temperature of the FluidA fluid with ____ high Mscosty sis motion whereas a fluid: with low. visesity fles feel. Viscometry. is a. very useful technique in choracteviaing : “polymers heceuse of Ue ease in Conducting viscaslty “pmecisuroments: _ Tis Process 1s @nducted in a. vigometen. Readings taken of the Slow tine. Cin Seconds). of ditute Solutions ond. the. solvet to chrawvel - From, the -uppew ark te the lower mark Gre @mpared.’ The! Wesults obtained shons that the time taker ‘Flow Unrou gle: the capillary vawied .Sligutly.. Treve Was ¢ random -oard: Systematic errors in the procedure. Solation. [> wos the most concentrated of the 4 Solutions. amd olution. b vxos the least Concentrated. This means that solution | Look the longest time. Therefore, the more diluted the polyvinyl alcoho) — Solution, the Faster it flowed. From physical observations Solution. was, Yor thide and this Property decreased og, the _ Solution -became wore ‘diluted. . Since this, proctical was done. Virtually ; weiwere hot provided — » with the temperature of , the, water bath, although thes . [ temperature. chould be : approximately . 95°C. T. took...a hypothetical | temperature of 23.°C_ and the theoretical value for the viscas ity lof rater cts this temperature is, 9.343 x 107 Kg IMs. tahice | Used for way -colculations. Temperature would, lave beew Kept. coustaut: because viscosity is temperature. dependant Any; voviations in the temperate would have Skewed the. vesults- was — Scanned with CamScannereo with om increase in. yease in temperature cause. se.oud thé molecules The viscasity of liquids decreas temperature - This is because the ine’ the Kinetic 0% thevmod energy” 9. Increase: —— become. more imobile. Tne attractie: binding veg is reduced ou thevelove tle viscosity is reduced. ze ge a stabi tee liquid the kinetic-energy wil exceed” the binding energy ovel liquid quad it! cour became 0. Vapour. \ byaolecules will escape From the : decreased.” < 1 “epposite is tire whe the temperature 35 “The “viscosities of tHe. golution's were calculdted: Using: the Videosity of Water “avid average time dip boole For : Bre. Solutio, te Flow through the Capillary . Solution Lwos the most Viscous “of oul the solutions anid solution 4, was the.cleast viscous. Te ‘relative Viscosities were ‘calculated © by: dividing © the’ &xpevimentas hvalues oF the: wiseosities: of the: 4 solutions with the viscosity ef water.iThis ratio decreased ee:the “solutions” became. move diluted’ and less: viscous.’ T oto was calculated vaud “it is “The mass Concerttration ‘directly’ Proportional’ te hows clilute the Solution Is. Solution | had the highest Py value ond: Solution + had the lowest. The & values vanged from 2-5 to 20 Hg m3. From the plots , the inolar macs oF the Pelyner was fouud bo be Hacg3s 3 lm Tt was obtaired’ from the graph wf: Paivys' Mest hog = Tye mndlor ‘yndst was found Lo be'smallee') due bo gross error. An: overage: Strand of PYA:hasiay: moleculoy weight oF: ateeub HBO. One MONOmMEN Wait” loots” like: (CHa - CoH) - uiblch has :a. Fovmula . wei gic of 44. So 48000] 4y = 1943...wonomer Units - bse . Scanned with CamScannerConclusion : wonclusion : ee ave Wolecules with long , repetative Grains ond thevefove ere large Wola masses: Typ wrscosity of 0. polymer Solution Som how concentrated the Solution is - Temperature lias 0 be Kept constant to obtain acumte sults, since viscosity is temperature deperdout- The molar moss of Use PYA polymer woo Gund to be W390 gl mol. Referentces : (1d Coursehero . Com. 202). Lob report I- Viseometry — 42128 Lab Report 03-10-16 Bismah Kapadia Experiment ig ViscomeTRY Determination of dilute solution viscosity oF PS using au | Cause Hero - Conline J Available at: < hittps: Il www . courseheve com I file (1q442e3!6 | Lob - Report-1 - Viscometiy | > Cacessed 2 Apu! aoait. Patkins aud J-D. Paula - Physion! Chemisty » Sth edition Orford University . Press (ao0c) Py cag ~ 680° Uke CHems30 Practical manucd Payslcal Chemistry cla Scanned with CamScanner