Sec: JR.

IIT _*CO-SC(MODEL-A) Date: 11-06-23

Time: 3 Hrs Max. Marks: 180
11-06-23_JR.IIT_STAR CO-SC(MODEL-A) _JEE ADV_WAT-7_SYLLABUS
PHYSICS: PRESENT WEEK (80%): Relative velocity (Relative velocity 1D,2D,Rate
of approach and rate of separation, condition for collission of two
projectiles, relative motion of one projectile with respect to another
projectile, rain problems, river boat problems, air craft wind problems
etc..)
PREVIOUS WEEK (20%): Non - uniformly accelerated motion in 1D &
related graphs, Motion in 2D,Projectile motion, projectile motion on
inclined planes
CHEMISTRY: PRESENT WEEK (80%): Relative velocity (Relative velocity 1D,2D,Rate
of approach and rate of separation, condition for collission of two
projectiles, relative motion of one projectile with respect to another
projectile, rain problems, river boat problems, air craft wind problems
etc..)
PREVIOUS WEEK (20%): De-Broglie Equation, Heisenberg's
Uncertainty principle, Schrodinger's wave equation; Quantum numbers,
Radial probability curves, Aufbau priciple, Pauli's exclusion Principle;
Hund's rule; Electronic configuration of the elements

MATHEMATICS: PRESENT WEEK (80%): SEQUENCE & SERIES:

Introduction to A.P,. nth term, Sum of n terms of an A.P, Properties of
AP,AM/Insertion of Arithmetic Means, Introduction to G.P,.nth term,
Sum of n terms of an G.P, Properties of GP,GM/Insertion of Geometric
Means, Sum of terms of a finite/infinite A.G.P/Number of common
terms to two different sequences
PREVIOUS WEEK (20%): Equations reducible to quadratic, Quadratic
Inequations/Inequations involving Logarithms, Exponentials, Modulus,
Range of Rational functions
Narayana IIT Academy 11-06-23_JR.STAR CO-SC(MODEL-A)_JEE-ADV_WAT-7_QP
Time: 3HRS IMPORTANT INSTRUCTIONS Max Marks: 180
PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 1 – 10) Questions with Multiple Correct Choice 3 0 10 30
Sec – II(Q.N : 11 – 20) Questions with Integer Answer Type 3 0 10 30
Total 20 60

CHEMISTRY:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 21 – 30) Questions with Multiple Correct Choice 3 0 10 30
Sec – II(Q.N : 31 – 40) Questions with Integer Answer Type 3 0 10 30
Total 20 60

MATHS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 41 – 50) Questions with Multiple Correct Choice 3 0 10 30
Sec – II(Q.N : 51 – 60) Questions with Integer Answer Type 3 0 10 30
Total 20 60

JR.IIT_*CO-SC Page. No. 2

Narayana IIT Academy 11-06-23_JR.STAR CO-SC(MODEL-A)_JEE-ADV_WAT-7_QP
PHYSICS Max Marks:60
SECTION-I
(One or More options Correct Type)
This section contains 10 multiple choice equations. Each question has four choices (A) (B)(C) and (D) out of which
ONE or MORE are correct.
1. A body projected with certain initial velocity, certain angle with the ground, the path of
the projectile is represented by y  Ax  Bx 2 where A, B are positive constants and
projection point is taken as origin the which of the following statements are correct?
Acceleration due to gravity is g
A) Displacement of the projectile in x direction is A/B
A2
B) Time of flight is
gB
A2
C) Maximum height of projectile is
4B
2A2
D) Time of flight is
gB
2. The figure shown the velocity (v) of a particle plotted against time (t)

V0

V0

A) The particle changes its direction of motion at some point

B) The acceleration of the particle remains constant
C) The displacement of the particle is zero
D) The initial and final speeds of the particle are the same

3. The position vector of a particle is time dependent and is given by r  5iˆ  10t ˆj where t

is in seconds and r is in meters. Choose the correct statement(s) :
A) Velocity of particle is of magnitude 10 m/s
B) Velocity of particle is of magnitude 125m / s
C) Direction of motion of particle is parallel to x-axis
D) Direction of motion of particle is perpendicular to x-axis

JR.IIT_*CO-SC Page. No. 3

Narayana IIT Academy 11-06-23_JR.STAR CO-SC(MODEL-A)_JEE-ADV_WAT-7_QP
4. A projectile is projected with certain initial velocity and certain angle with the horizontal
ground it just grazes the four vertices B, C, D, E of the regular hexagon of side length
10 3 m as shown in fig.  g  10m / sec 2 

C D

B E

A F Horizontal ground

Time of flight of the projectile and the time when it grazes the vertex Dare x and y
respectively
A) x  7 B) y = 1 sec C) x  2 7 D) y = 2 3 sec
5. Two particles A and B are thrown from same level as shown in figure. A with a velocity
of 50 m/s at an angle of  with horizontal while B with a velocity of 20 m/s in vertical
upward direction. The two particles collide in air after 1 s. For this situation mark the
correct statement.
50 m/s

20 m/s


A B
x

A) The value of  is sin1  0.4 

B) The value of x is 45.83 m

C) The particles collide at a height of 15 m from the projection level.
D) This situation is not possible
6. A box is falling freely. Inside the box, a particle is projected with some velocity u with
respect to box at an angle  as shown in figure. For this situation mark the correct
statement.


JR.IIT_*CO-SC Page. No. 4
Narayana IIT Academy 11-06-23_JR.STAR CO-SC(MODEL-A)_JEE-ADV_WAT-7_QP
A) The path of the projectile with respect to box frame of reference is a straight line.
B) The path of the projectile with respect to ground fame of reference is a parabola.
C) If the box is falling with acceleration a   g then path of projectile with respect to box
as well as with ground would be a parabola, although trajectories with respect both
frame of reference would be different.
D) If the box is falling with constant velocity then path of projectile with respect to box
would be same (identical) as that with respect to ground.
7. Two particles are projected simultaneously from two points O and O such that d is the
horizontal distance and h is the vertical distance between them as shown in the figure.
They are projected at the same inclination  to the horizontal with the same speed .
The time after which their separation becomes minimum is

v

O
v
h

O
d

d 2d d d
A) B) C) D)
 cos   cos  2 cos  

8. Two shots are fired from a gun at the same speed but with elevations 1 and  2 . Their
times of flight, respectively, are t1 and t2 .If they have same horizontal range, then

A) t1  t2 B) t1 sin 1  t2 sin  2 C) t1 / t2  tan  2 D) t1 cos 1  t2 cos  2

9. A river is flowing with a speed of 1km/hr. A Swimmer wants to go to point ‘C’ starting
from ‘A’. He swims with a speed of 5 km/hr, at an angle  w.r.t. the river. If AB =
BC=400m. Then:

B C

1 km/hr

)
A

A) The Value of  is 530 B) Time taken by the man is 6 min

C) Time taken by the man is 8 min D) The value of  is 450

JR.IIT_*CO-SC Page. No. 5

Narayana IIT Academy 11-06-23_JR.STAR CO-SC(MODEL-A)_JEE-ADV_WAT-7_QP
10. A man is standing on a road and observes that rain is falling at angle 450 with the
vertical. The man starts running on the road with constant acceleration 0.5 m / s 2 . After a
certain time from the start of the motion, it appears to him that rain is still falling at
angle 450 with the vertical, with speed 2 2 m/s. Motion of the man is in the same vertical
plane in which the rain is falling. Then which of the following statement(s) are true:
A) It is not possible
B) Speed of the rain relative to the ground is 2m/s.
C) Speed of the man when he finds rain to be falling at angle 450 with the vertical,
is 4m/s.
D) The man has travelled a distance 16m on the road by the time he again finds rain
to be falling at angle 450
SECTION-II
(Integer Value Correct Type)
This section contains 10 questions. The answer to each question is a single digit integer, ranging from 0 to 9
(both inclusive).
11. A particle of mass 10-2 kg is moving along the negative x-axis under the influence
K
of a force F  x   where k=10-2 Nm2. At time t=0 it is at x=1.0 m and its velocity is
2x2
v=0 Find its velocity when its reaches x=0.50 m
12. A projectile is projected with a initial velocity of 20 m/sec at an angle of 300 with
horizontal ground the modulus of rate of change of speed of projectile just before strikes
to the ground (Acceleration due to gravity g  10m / sec2 )
13. An aeroplane is flying in geographic meridian vertical plane at an angle of 300 with the
horizontal (north) and wind is blowing from west. A package is dropped from an
aeroplane. The velocity of the wind if package hits a kite flying in the space with a
 

position vector R = 400 3i  80 J  200k m with respect to the point of dropping is 5x

m/s. Find x. (Here i and j are the unit vectors along north and vertically up respectively
and k be the unit vector due east. Assume the bag is light enough to get carried away by
the wind):
14. P is a point moving with the constant speed 10 m/s such that its velocity vector always
maintains an angle 600 with line OP as shown in figure (O is a fixed point in space). The
initial distance between O an P is 100 m. The time when P reach O is 4x sec. Find x
P
(

m 60o
100

O V=10m/s

JR.IIT_*CO-SC Page. No. 6

Narayana IIT Academy 11-06-23_JR.STAR CO-SC(MODEL-A)_JEE-ADV_WAT-7_QP
15. Two particles P and Q move with constant velocities v1  2ms 1 and v2  4ms 1 along two
mutually perpendicular straight lines towards the intersection point 0. At moment t=0,
the particles were located at distances l1 =12m and l2 =19m from 0, respectively. Find the
time in second when they are nearest.

16. A 2m wide truck is moving with a velocity of 10ms-1 along a straight road of width 2m.
A man starts crossing the road with a uniform speed V across the road when the truck is
4m away from him. The minimum value of V (in m/s) to cross the truck safely is k√5.
Find k.

17. A grass hopper can jump a maximum horizontal distance of 0.3 m. If it spends negligible
x
time on the ground, its horizontal component of velocity is m/s, find x
2

( g  10 m / s 2 )

18. Two particles are projected simultaneously from ground as shown in figure. Find
minimum distance in meter between during their flight.

19. A particle is projected from point P with velocity 53 ms-1 perpendicular to the surface
of a hollow right angled cone as shown in figure. It collides at Q normally. The velocity
with which it collides at Q is 5k ms-1. Find k

Q
300

20. A boat having a speed of 5km/hr in still water crosses a river of width 1km along the
shortest path in fifteen minutes. The velocity of water in km/hr is:

JR.IIT_*CO-SC Page. No. 7

Narayana IIT Academy 11-06-23_JR.STAR CO-SC(MODEL-A)_JEE-ADV_WAT-7_QP
CHEMISTRY Max Marks:60
SECTION-I
(One or More options Correct Type)
This section contains 10 multiple choice equations. Each question has four choices (A) (B)(C) and (D) out of which
ONE or MORE are correct.
21. The ground state energy of hydrogen atom is -13.6 eV. Consider an electronic state 
of Li 2 whose energy, azimuthal quantum number and magnetic quantum number are -
4.896eV, 2 and 0 respectively. Which of the following statement (s) is (are) true from
the state  ?
A) It is a 5d state
B) It has 2 spherical nodes.
C) It has 2 angular nodes.
D) The nuclear charge experienced by the electron in this state is less than 2e, where ‘e’
is the magnitude of electronic charge.
22. Vander waals constants 'a' and 'b' for a gas are 4.0 atm. L2 . mol2 and 0.05 L. mol1
respectively. If 80g of the gas (MW = 16) is placed in a 10L vessel at 300K, then select
the correct statement (s) regarding the gas?
A) pressure correction is 1 atm
B) Free volume of gas is 9.75L
C) Actual volume occupied by molecules is 0.625L
D) Volume correction is 0.025L
23. Which of the following statements regarding Maxwell distribution of speeds of ideal gas
molecules is/are correct?

JR.IIT_*CO-SC Page. No. 8

Narayana IIT Academy 11-06-23_JR.STAR CO-SC(MODEL-A)_JEE-ADV_WAT-7_QP
A) for the same gas at two different temperatures the graph is wide at high temperature
and narrow at low temperature

B) for two gases at same temperature the graph is wide for lighter gas and narrow for
heavier gas.

C) for same amount of SO 2 gas at 600K and O 2 gas at 300K the graph will be identical

D) for the same gas at two different temperatures the fraction of molecules with most
probable speed will be more at high temperature than at low temperature.

24. Consider a 1L container of Neon gas initially at STP and select the correct statement (s)
:

A) If the temperature is increased to 1000 C keeping volume constant, wall collision

frequency increases

B) If the temperature is decreased to 500 C keeping the volume constant, average

kinetic energy per mole decreases

C) If volume is decreased to 0.5 L at constant temperature, wall collision frequency

remains constant.

D) If the number of moles of Neon is doubled keeping the temperature and pressure
constant, average kinetic energy per mole remains same.

25. If critical temperature for a vanderwaal's real gas is 500 K then which of the following
is/are correct:

(R=0.08 L-atm mole-1K-1)

JR.IIT_*CO-SC Page. No. 9

Narayana IIT Academy 11-06-23_JR.STAR CO-SC(MODEL-A)_JEE-ADV_WAT-7_QP
A) Boyle's temperature is 1687.50 K.

B) At Boyle's temperature the behavior of gas is always ideal

C) The vander waal's constant 'b' is 0.16 L.mol-1.

D) The vander waal's constant 'a' is 21.6 atm. L2.mol-2

26. Select the correct statement(s) regarding real gases:

A) A gas is more compressible, if repulsive forces dominate over attractive forces

between molecules

B) At extremely low pressure and high temperature, gases behave ideally

C) At Boyle's temperature, gases behave ideally in low pressure region

D) If gas is kept at T > TC , it can never be liquefied ( TC is critical temperature)

27. Among the following regarding energy order, select the true statement(s)
A) E 2s  H   E 2s  Li   E 2s  Na   E 2s  K 

B) E1s  Li   E1s  Be   E1s  B   E1s  C 

C) E1s  H   E1s  Li   E1s  Na   E1s  K 

D) E 4s  Fe   E 4p  Fe   E 4d  Fe   E 4f  Fe 

28. For a gas it is given that, its critical pressure is 1.8atm and critical temperature is 350K.
Under which of the following conditions, the gas can be liquified?

A) P=2atm and T=310K B) P=1.8atm and T=350K

C) P=1.7atm and T=340K D) P=1.9atm and T= 360K

29. One mole of helium and one mole of neon are taken in a vessel. Which of the following
statement(s) is(are) correct regarding the two gases?(assume temperature is constant)

A) Molecules of helium strike the wall of vessel more frequently.

B) Molecules of neon apply more average force per collision on the wall of vessel.

C) Molecules of helium have greater average molecular speed.

D) Helium exerts higher pressure than neon

JR.IIT_*CO-SC Page. No. 10

Narayana IIT Academy 11-06-23_JR.STAR CO-SC(MODEL-A)_JEE-ADV_WAT-7_QP
30. The concentration of dry air at 1atm and 298K is about 2.5  1019 molecules cm 3 .
Assuming that air contains only nitrogen molecules. Which of the following is/are
correct:
[ Z1 = number of bimolecular collisions by one particle in unit time, Z11  number of
bimolecular collisions by all particles in unit time and unit volume ]

A) The ratio of  Z11 / Z1  =1.25  1019 cm 3

B) On keeping the concentration (number of particles per unit volume) constant and
increasing the absolute temperature two times its initial value, there is no effect on Z11
and Z1 .
C) on keeping the number of particles per unit volume constant and increasing the
absolute temperature 4 times its initial value, Z11 becomes 2 times and Z1 becomes 2
times its initial value.
D) on keeping the number of particles per unit volume constant and increasing the
absolute temperature two times its initial value, Z11 becomes 1/4 times and Z1 becomes
1/2 times its initial value.
SECTION-II
(Integer Value Correct Type)
This section contains 10 questions. The answer to each question is a single digit integer, ranging from 0 to 9
(both inclusive).
31. The uncertainty in the measurement of position of an electron in 2nd excited state of

He is 9/16 A . What will be the minimum uncertainty in the measurement of De -

Broglie wave length of this electron in angstroms ( A )?

[take first Bohr radius = 0.5 A ]    3.14



32. The diffusion coefficient of an ideal gas is proportional to its mean free path and mean
speed. The absolute temperature of an ideal gas is increased 4 times and its pressure is
increased 4 times. As a result, the diffusion coefficient of this gas increases x times. The
value of x is:

33. At 400K, the root mean square speed of a gas X (molecular weight = 40) is equal to the
most probable speed of gas Y and 60 K. If equal mass of gas X and Y are present at
5.5atm, then the partial pressure of gas Y (in ‘atm’) is:

JR.IIT_*CO-SC Page. No. 11

Narayana IIT Academy 11-06-23_JR.STAR CO-SC(MODEL-A)_JEE-ADV_WAT-7_QP
34. The graph of compressibility factor (Z) vs. P for one mole of a real gas is shown in
following diagram. The graph is plotted at constant temperature 273K. If the slope of
 dZ   1  1
graph at very high pressure   is   atm , then calculate volume of one mole of
 dP   2.8 
the real gas molecules (in L/mol)
22.4
Given: N A  6  10 23 and R  Latm K 1mol1
273

35. If the temperature of 1 mole of a gas is increased by 500 C , the change in kinetic energy
of the system is ‘x’ KJ. Find the value of x 10. (Consider the nearest integer).
36. Suppose that helium atoms in a sealed container all start with the same
speed, 2.74  104 cms 1 . The atoms are then allowed to collide with one another until the
Maxwell distribution is established. If the temperature of the gas at equilibrium is ‘X’
Kelvin, then X/2 is? Assume that there is no heat exchange between the gas and its
surroundings.
37. The wave function for an atomic orbital of single electron atom or ion is
1
2  Z 2 
2Z
  , ,        


 1   12  8   2
..e 2
cos . Where    0.529 A
3  3a 0  na 0

Find the value of  n  l  m1  for the given orbital. (Assuming Z-axis is the internuclear
axis & all other parameters have their usual meaning)
38. One litre of a gas at 300atm and 473 K is compressed to a pressure of 600 atm and 344
K. The compressibility factors are found to be 1.250 and 1.357 respectively at the initial
and final states. The final volume of the real gas is ‘x’L. Then 10x value is:
39. The critical pressure and critical temperature of a gas obeying van der waals equation
are 200 atm and 1730 C . The value of the gas constant R is 0.08 LatmK 1mol 1 . The
value of coefficient 'b' is y  103 L. mol 1. Then ' y ' is____

40. The equation of state for a gas is P  V  nb   nRT, where ‘b’ and ‘R’ are constants. If
the pressure and temperature are such that Vm =10b, the compressibility factor of the gas
in this condition is 10/x. Then ‘x’ is:

JR.IIT_*CO-SC Page. No. 12

Narayana IIT Academy 11-06-23_JR.STAR CO-SC(MODEL-A)_JEE-ADV_WAT-7_QP
MATHEMATICS Max Marks:60
SECTION-I
(One or More options Correct Type)
This section contains 10 multiple choice equations. Each question has four choices (A) (B)(C) and (D) out of which
ONE or MORE are correct.
n
1
41. The value of  is
r 1 a  rx  a  (r  1)x

n a  nx  a
A) B)
a  a  nx x

C)
n  a  nx  a  D)
1
x a  a  nx

42. All terms of an A.P. are natural numbers. The sum of its first nine terms lies between
200 and 220. If the second term is 12, then

A) First term = 8 B) Common difference = 4

C) 5th term = 24 D) 3rd term = 20

1 1 1
43. If S     .... upto  , then
3 32 33

A) (0.25)log (S)  4
2
B) (0.008)log (S)  8 5

C) (0.008)log (S)  4 5
D) (0.25)log (S)  8
2

44. Sn  12  22 x  32 x 2  42 x 3  ........   , then S 

A) 12 for x = ½ B) 9/2 for x = 1/3 C) 16 for x = ½ D) 64/9 for x = ¼

45. If the arithmetic mean of two positive numbers a & b (a > b) is twice their geometric
mean, then a : b can be

A) 2  3 : 2  3 B) 7  4 3 :1 C) 1: 7  4 3 D) 2 : 3

46. Let x  111...11,

  y  444...44,
  z  777...77
  , w  999...99
  then choose the correct option(s).
20 digits 20 digits 10 digits 10 digits

49x  9z 2 7 49x  9z 2 2
A)  B) 
14w 9 14w 9
16  x  y 
C) 9y  4w 2  8w D)    10  1
10

5 zw

JR.IIT_*CO-SC Page. No. 13

Narayana IIT Academy 11-06-23_JR.STAR CO-SC(MODEL-A)_JEE-ADV_WAT-7_QP
47. a1 , a 2 , a 3 ….. are distinct terms of an A.P. we call (p, q, r) an increasing triad if a p , a q , a r are

in G.P. where p, q, r  N such that p < q < r. If (5, 9, 16) is an increasing triad, then
which of the following option is/are correct

A) If a1 is a multiple of 4 then every term of the A.P. is an integer

B) (85, 149, 261) is an increasing triad

1 1
C) If the common difference of the A.P. is , then its first term is
4 3

D) Ratio of the (4k + 1)th term and 4kth term can be 4

48. In an arithmetic progression whose first term is  and common difference is ; ,   0 ,

the ratio r of the sum of the first n terms to the sum of n terms succeeding them, does not
depend on n. Then which of the following is/are correct?

A)  :   2 :1

B) If  and  are roots of the equation ax 2  bx  c  0 then 2b 2  9ac

C) The sum of inifinte G.P., 1  r  r 2  .... is 3/2

D) If   1 , then sum of 10 terms of A.P. is 100

49. Let S1 ,S2 ,..... be squares such that for each n  1 , the length of a side of Sn equals the
length of a diagonal of Sn 1 . If the length of a side of S1 is 10 cm, then for which of the
following values of n is the area of Sn less than 1 sq. cm?

A) 7 B) 8 C) 9 D) 10

50. If Sn  12  22  32  42  52  62  ...., then

A) S40  820 B) S2n  S2n  2

C) S51  1326 D) S2n 1  S2n 1

JR.IIT_*CO-SC Page. No. 14

Narayana IIT Academy 11-06-23_JR.STAR CO-SC(MODEL-A)_JEE-ADV_WAT-7_QP
SECTION-II
(Integer Value Correct Type)
This section contains 10 questions. The answer to each question is a single digit integer, ranging from 0 to 9
(both inclusive).
If  x 2  x  2    3     x 2  x  1 x 2  x  2      4   x 2  x  1  0 has atleast one real root,
2 2
51.
then complete set of values of '  ' contains ‘n’ integers where n = …………..
2x 2  7x  3
52. Given y  , then sum of all integral values which lies in the range of y
2x 2  x  1
53. Sum of first three terms of G.P. with non-integer common ratio is 21 and sum of their
S
squares is 189. If S denotes sum of infinite term of this series, then is equal to
4
p
54. Let a1 , a 2 , a 3 ,...., a100 be an non constant arithmetic progression with a1  3 and Sp   a i ,
i 1

Sm
1  p  100 . For any integer n with 1  n  20 , let m = 5n. If does not depend on n, then
Sn
a 2 is ________

b
55. Let a, b, c be positive integers such that is an integer. If a, b, c are in geometric
a
a 2  a  14
progression and the arithmetic mean of a, b, c is b  2 , then the value of is
a 1
56. Let fourth term of an arithmetic progression be 6 and mth term be 18. If A.P. has integral
terms only then the numbers of such A.P.s is ________
57. 150 workers were engaged to finish a piece of work in a certain number of days. Four
workers dropped the second day, four more workers dropped the third day and so on.
Because of this, it took 8 extra days to finish the work. If N is number of days in which
N
the work is completed., then ?
5

58. A player plays n matches (n  1) and the total runs made by him in n matches is
1
(n  1)(2n 1  n  2) . If he makes k.2n  k 1 runs in the k-th match for 1  k  n , then n = ?
4
59. In a circle of radius R a square is inscribed, then a circle is inscribed in the square, a new
square in the circle and so on for n times. If the ratio of the limit of the sum of areas of
all the circles to the limit of the sum of areas of all the squares as n   is k, then find
4k
the value of

1 1
60. If 3  (3  d)  (3  2d)  ...  upto   8 , then the value of d is
4 42

JR.IIT_*CO-SC Page. No. 15

Narayana IIT Academy 11-06-23_JR.STAR CO-SC(MODEL-A)_JEE-ADV_WAT-7_QP

JR.IIT_*CO-SC Page. No. 16