(PRINT NAME CLEARLY FIRST LAST) _____________________________________

CH 201 Petrovich Wednesday February 15, 2023

Test 1 – Form B
1. a. Complete the following reaction table in mmol for 50.00 mL of 0.185 M HF reacting with
15.68 grams of iodine, I2(s). (10 pts)

50.00 mL x (0.185 mmol/mL) = 9.250 mmol HF

15.68 g I2 x (1 mol/253.8 g) = 0.061781 mol I2 = 61.781 mmol I2

2HF(aq) + I2(s)  2HI(aq) + F2(g)

initial 9.250 61.781 0 0
∆ -9.250 -4.625 +9.250 +4.625
final 0 57.156 9.250 4.625

b. What is the theoretical yield of F2(g) in grams? (4 pts)

4.625 mmol F2 x (38.00 mg/mmol) = 175.75 mg = 0.1758 g F2

theoretical yield = _____________ grams (3 pts)

c. What concentration of HI(aq) is formed?
M = mmol/mL = 9.250 mmol HI/50.00 mL = 0.185 M

[HI] = ________________ M (3 pts)

2. What is [OH-] in a solution prepared by mixing the following solutions:
600. mL of 1.2 M NaOH = 600 mL x 1.2 M = 720 mmol
710. mL of 2.0 M LiOH = 710 mL x 2.0 M = 1420 mmol
350. mL of 1.5 M KOH = 350 mL x 1.5 M = 525 mmol
200. mL of water = 200 mL x ~0.0 M
1760 mL 2665 mmol

2665 mmol / 1760 mL = 1.51 M (gain sig fig when adding)

[OH-] = ___________M (5 pts)

Page 1 Score = _______________/25

3. For the following reaction at 1 atm and 25.0C: 3CH3OH (g) + H2 (g) C3H8 (g) + 3H2O(l)
a. Using standard heats of formation, calculate the enthalpy change (∆H).
∆Hf kJ/mol Hrxn = Hf(C3H8(g)) + 3Hf(H2O(l)) - 2Hf(CH3OH(g)) -
CH3OH (g) –201.2 Hf(H2(g))
H2 (g) 0
C3H8 (g) -104.7 Hrxn = (-104.7) + 3(-285.83) – 3(-201.2) – (0)
H2O (l) -285.83 Hrxn = -358.59 kJ

∆H = ___________ kJ (5 pts)
b. Calculate the work (w).
ngas = (1 – 4) = -3 mol
w = -ngasRT = -(-3 mol)(8.314 J/molK)(298 K) = 7432.7 J = 7.433 kJ

w = _____________ kJ (5 pts)
c. If 25.0 grams of CH3OH reacts with an excess of hydrogen gas at constant pressure and
298 K, calculate the change in energy (∆E). The mass of CH3OH if 32.05 g/mol.

E = H + w = -358.59 + 7.443 = -351.147 kJ for 3 mol CH3OH

25.0 g CH3OH x (1 mol CH3OH / 32.05 g) x (-351.147 kJ/3 mol CH3OH) = -91.30 kJ

∆E = ______________ kJ (5 pts)

4. For an aqueous solution with a colligative molality of 1.31 m,…

a. Calculate the vapor pressure of the solution at 15C given that the vapor pressure of
pure water at 15C is 12.8 torr, P.

1.31 m  1.31 mol solute & 1 kg water

1000 g water x (1 mol/18.02 g) = 55.49 mol water
Xwater = (55.49)/(55.49 + 1.31) = 0.9769
Psol’n = XwaterP = (0.9769)(12.8 torr) = 12.50 torr

P = _____________ torr (6 pts)

b. Calculate the boiling point of the resulting solution. (kf = 1.86 C/m, kb = 0.563 C/m)
Tb = mckb = (2.43 m)(0.563 C/m) = 1.368 C
Tb = 100.0 + 1.368 = 101.4 C

boiling point = _____________ C (4 pts)

Page 2 Score = _____________ /25

5. Given the following thermodynamic data:

N2 (g) + 3H2 (g)  2NH3 (g) ΔHº = -115 kJ

2 NH3 (g) + 4 H2O (l)  2NO2 (g) + 7 H2 (g) ΔHº = -142.5 kJ
H2O (l)  H2 (g) + ½ O2 (g) ΔHº = -43.7 kJ

Calculated ΔHº for the following reaction: Show the logic of how reactions were added!

N2 (g) + 2 O2 (g)  2 NO2 (g)

N2 (g) + 3H2 (g)  2NH3 (g) -115 kJ

2 NH3 (g) + 4 H2O (l)  2 NO2 (g) + 7 H2 (g) -142.5 kJ
4H2 (g) + 2O2 (g) 4H2O (l) -4 x -43.7 kJ
N2 (g) + 2 O2 (g)  2 NO2 (g) -82.7

ΔHº = ______________ kJ (5 pts)

6. Calculate the colligative molarity of a 500.0 mL solution prepared with 1.3768 g aluminium
bromide, AlBr3(s).
AlBr3 (s)  Al3+ (aq) + 3 Br- (aq) so i = 4
1.3768 g AlBr3 x (1 mol/266.68 g) = 0.00516271mol AlBr3
M = mol/L = (0.00516271 mol)/(0.5000 L) = 0.010325 M AlBr3
Mc = i x M = 4 x 0.010325 = 0.041302

Mc = ____________ M (5 pts)

7. A compound has an empirical formula of C2H4NO2.

a. Calculate the mass % of carbon in this compound to the nearest 0.01%.

(2 x 12.01) + (4 x 1.01) + (1 x 14.01) + (2 x 16.00) = 74.07 g/mol

(mass C/total mass) x 100 = {(2 x 12.01)/74.07} x 100 = 32.43 %

mass % carbon = _______________ (5 pts)

b. If the molecular weight of this compound is 296.28 g/mol, what is the chemical formula
for it?
296.28/74.07 = 4.00
4 x C2H4NO2 = C8H16N4O8

Chemical Formula = _______________ (5 pts)

Page 3 score = _____________ /20

8a. Write the atomization reaction of H2S. Include states-of-matter. (3 pts)

H2S (g)  2H (g) + S (g)

8b. Use the heats of formation to determine the average S-H bond energy in H2S. Please
include units with your answer!
ΔHºf kJ/mol
ΔHºf H2S (g) -20.6
ΔHºf S (g) 276.98
ΔHºf S (s) 0
ΔHºf H (g) 217.97
ΔHºf H2 (g) 0
H2S (g)  2H (g) + S (g)
∆Hatom = 2∆Hf (H(g)) + ∆Hf (S(g)) - ∆Hf (H2S (g))
∆Hatom = (2 x 217.97) + (276.98) – (-20.6) = 733.38 kJ
∆Hatom =bonds broke – bonds formed = 2 (S-H)
733.38 kJ = 2 mol S-H bonds
366.69 kJ/mol = S-H bond energy

DS-H = _________________ ______________ (5 pts)

9. What mass of carbon is in a sample of aluminium acetate, Al(C2H3O2)3, that contains 2.35
grams of aluminium?

2.35g Al x (1 mol Al/26.98 g Al) x (6 mol C / 1 mol Al)

x (12.01 g C / 1 mol C) = 6.277 g C

mass carbon = _______________ g (5 pts)

10. A 0.2568 M red dye solution was found to have an absorbance of 0.3820 in a 1.00 cm cell.
What is the concentration of a solution with an absorbance of 0.1925 in the same cell at the
same wavelength?

A = elC
A1/C1 = A2/C2  C2 = C1A2/A1
C2 = (0.2568 M)(0.1925)/(0.3820) = 0.1294 M

[dye] = _______________ M (5 pts)

Page 4 Score = _____________ /18

11a. Write the two processes required to change solid water at 0.00 C to liquid warmer water
at final temperature “Tf”. Include the phase of the water.
_________ at _______C to _______ at _______ C
_________ at _______C to ________at _______ C
(4 pts)
11b. If 2.150 kJ of heat are added to 5.3044 grams of 0.00C solid water (ice), what will the final
temperature of the water be?
For water: 5.3044 g water x (1 mol/18.02 g) = 0.29436 mol
∆Hfusion, 273K 6.01 kJ/mol water
∆Hvaporization, 373K 40.7 kJ/mol
sice 2.00 J/gC
sliquid 4.18 J/gC
ssteam 2.00 J/gC
To melt ice at 0C,
q = nHfusion = (0.29436 mol)(6.01 kJ/mol) = 1.76911 kJ

2.150 kJ – 1.76911 kJ = 0.380089 kJ or 380.89 J left over to heat water from

0C.
q = msT  T = q/ms
T = (380.89 J)/(5.3044 g x 4.18 J/gC) = 17.179 C
T = Tf – Ti  Tf = T + Ti
Tf = 17.179 + 0 = 17.2C

Tfinal = ______________ C ( 8 pts)

Pledge: I have neither given nor received help during this test.
Signature: ______________________________ Name (print): ______________________________

Pg1: : /25 Pg2: : /25 Pg3: /20 Pg4: /18 Pg5: /12 Total = /100

Page 5
 Formula Sheet
Please tear off this page for use during the test.

While taking the test:

 Please answer each of the following questions as directed.
 Show all of your work for credit or possible partial credit.
 Please report answers to the correct number of significant figures.
 Always include units with your responses on the second line of each answer.
 Use the periodic table above for molar mass calculations.

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 You may leave when you have finished the test but please be respectful of your
classmates who are still working by being quiet as you exit.
 Bring your test and your picture ID to the proctor in the front of the room to turn in your
test.
Test 1

Useful Information
1.00 atm = 760 torr = 760 mm Hg
R = 0.0821 (Latm)/(molK) = 8.314 J/(molK)

Useful Information
P = XsolventP
mc = im PV = nRT
Tb = kbmc A = lC
Tf = kfmc w = -ngRT
 = iMRT q = msT = CT = nH