KIMIA

PERSIAPAN SIMAK UI KKI (2)

01. Consider the data in the following table. 04.

Despite having lowest molar mass, NH3 does

not have the lowest boiling point among the
equivalent compounds of the same class. This is
resulted from the fact that ...

(A) the molecules are small

(B) there are hydrogen bonds

(C) there are London forces

(D) the molecules are polar Consider the water phase diagram above.
The volume of one mole of water in solid phase at
(E) the molecules are non-polar the triple point is .... (At the triple point, the density
of H2O(l) is 0.9998 g.mL-1 and the density of H2O(s),
is 0.90 g.mL-1 Ar O=16, H=1)
02. The Following experiment is perfomed to determine
the reaction rate 0f 2A + B  A2B, and the obtained (A) 1 mL
table below shows the variation of concetration of (B) 2 mL
reactants A and B. (C) 18 mL
(D) 20 mL
[A] [B] rate 1 ×0.0821 × 273.17
(E) V = 4.579 L
1. 0.050 M 0.050 M 5. M.s-1 760
2. 0.050 M 0.100 M 10. M.s-1
3. 0.025 M 0.050 M 2.5 M.s-1 05. If NaF and BaCl2 of the same volume are mixed,
4. 0.100 M 0.100 M 20. M.s-1 which of the following combinations does not obtain
precipitate? Ksp BaF2 = 1.7 x 10-7
The Overrall rate law of this reaction is …
(A) 0.0040 M BaC12 and 0.020 M NaF
(A) rate = k [A]2[B]2 (B) 0.010 M BaC12 and 0.015 M NaF
(B) rate = k [A]2[B] (C) 0.010 M BaC12 and 0.020 M NaF
(D) 0.015 M BaC12 and 0.010 M NaF
(C) rate = k [A][B]2
(E) 0.020 M BaC12 and 0.0020 M NaF
(D) rate = k [A][B]
(E) rate = k 06. Given ozonolysis reaction below
1
O3 +C12  2OC1 + O2,
2
03. Energy is emitted when the following electronic The enthalphy reaction (kJ/mol)of 1 mol Cl2 is ....
transitions occur in hydrogen, EXCEPT ... . O-O = 142
O=O = 498
(A) from n = 3 to n = 1 C-CI = 242
(B) from n = 5 to n = 4 Cl-O = 203
(C) from orbit which has wavelength 430 nm to one
of 280 nm (A) -129
(D) from an orbit of radius 4.76 Å to one of radius (B) -24
0.529 Å (C) -15
(E) an electron adds to the H+ ion and ends up in the (D) 85
n = 4 shell (E) 227

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07. Which of these elements has the second lowest 11. Given the following standard reduction potentials for
ionization energy? the redox-pairs of chemical species:

(A) Na
(B) K
(C) Rb
(D) Cs
(E) Li
It is possible to state that, in normal electrochemical
08. conditions, by arranging these species in pairs in an
electrochemical cell, ...

(A) lead is reduced when faced to all other elements

(B) lead is an oxidant agent when faced to silver
and copper and a reducing agent versus zinc
(C) lead oxidizes when faced to silver and copper
and is reduced versus zinc
(D) lead oxidizes only when faced to zinc
(E) lead is neither oxidizes nor reduced when faced
to all other elements

Look at the structure of amino acid above,

how many chiral centers does an ileusin have? 12. The following compound which forms a cis-trans
isomer is ... .
(A) 1
(B) 2 (A) (C5H6)2C=CH2
(C) 3 (B) CH3-CH=CH2
(D) 4
(E) none (C) C2H5-CH=CH-CH3
(D) CH3-CH=C(CH3)2
09. Based on the follwing equilibrium reactions:
(E) CH2=CH2

13. Consider the following thermochemical compounds:

The correct order of acidity rates is....

H for:
2MnO2 + CO  Mn2O3 + CO2
IS ….

(A) −313 kJ
(B) −291 kJ
(C) +291 kJ
(D) +313 kJ
(E) −219 kJ
10. HF is a weak acid (Ka = 6.7 × 10-4 ). And NH3 is a
weak base (Kb = 1.8 × 10-5 ). In A 1.0 M solution of 14. A possible molecular formula for a gas with density
NH4F, which of the following condition is possible. 1.43 g/L at STP is ...

(A) F- is a less basic than H2O (A) N2

(B) NH4 + is more basic than H2O (B) O2
(C) Hydrolysis degree of NH4, + is greater than F- (C) F2
(D) pH of solution is basic (D) Cl2
(E) pH of solution is acid (E) CO

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15. Examine the data below for the reaction:
2A + 2B  C + 2D
19. Given solutions, containing 0.20 molal of ethyl
alcohol and 0.l0 molal of magnesium sulphate in
water, both are soluble in water. The freezing point
of the mixture is ....
(freezing point of water = 0°C, Kl water = 1.86 m
Kg-1 K1)

(A) (0.744°C
The following equation which is the correct rate (B) 0.558°C
equation for the reaction is ... . (C) 0.372°C
(D) -0.372°C
(A) rate = k[A]2[B]2 (E) -0.744°C
(B) rate = k[A]2[B]2
(C) rate = k[A][B]2 20. A mixture of 400 mL Cd(NO3)2 solution 2.0 × 10−4
(D) rate = k[A][B] M and 600 mL KIO3 solution 1.5 × 10−3 M forms
(E) rate = k[A]2[B]3 cadmium iodate. Ksp Cd(IO3)2 = 2.3 × 10−8.
BECAUSE
16. The solubility of magnesium ftouride (ionic The quotient reaction of Cd2+ and IO 3 is greater than
compound), MgF2 (Mr = 62.3) is 3.115 x 10-3 in
100 mL pure water. The solubility product of MgF2 is the value of Ksp.
is ....
21 . The compound H2C2O4 participates readily both in
(A) 5 × 10-11 acid-base reaction and in oxidation-reduction.
(B) 1 × 10-11 BECAUSE
(C) 8 × 10-10 In a basic solution, H2C2O4 is ready to form a salt
(D) 5 × 10-10 substance and can be oxidized by KMnO4 forming
(E) 1 × 10-10 Co2.

17. The maximum number of stereoisomers for 22. Nitrogen dioxide, NO2, undergo reactions to form
CH2 = CCICHCCH3 are .... nitrite ion, NO2- , and nitronium ion, NO2 +.
According to the Lewis method, structure nitrite ion
(A) 0 is linear and the structure of nitronium ion is V-
(B) 2 shaped.
(C) 4 BECAUSE
(D) 6 Nitrogen atom in nitrite ion has an electron pair,
(E) 8 whereas in nitronium ion has no electron pair in its
Lewis structure.
18. The following two half reactions are used to make an
electrochemical (galvanic) cell: 23. What is the following metallic atom which does not
have unpaired electron in d orbital?

Using the standard reduction potentials for these

reactions, we can predict that the spontaneous
reaction is
24. Electrolysis 1.00 L solution of 1.00 M Na2SO4 is
conducted by passing 1.0 amps electric current for
1hour and 35 minutes. (1 atm, 25°C, l F = 95000 C)

(1) Gas H2 is produced in cathode

(2) Solution in the cathode area is basic
(3) Gas O2 is produced in anode
(4) Volume of gas collected in anode is 0.733 L

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25. In the following reaction, which reaction will
generate hydrogen gas?

(1) Hidrochloride solution is added by Zinc metal.

(2) Carbon is reacted with steam (water at 1000°C).
(3) Potassium metal is immersed to the water.
(4) Copper is immersed to the concentrated nitric
acid solution.

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