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Electrolytic Rust Removal Aka Magic
Electrolytic Rust Removal Aka Magic
Table of Contents
step 6: Power it up . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14
step 8: Samples . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16
Related Instructables . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20
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http://www.instructables.com/id/Electrolytic-Rust-Removal-aka-Magic/
intro: Electrolytic Rust Removal aka Magic
This is a relatively simple, safe and cheap way to remove light or heavy rust from any ferrous object. I used this process to restore an old wood plane that I bought for $1
(it looked totally un-usable because of the rust). As opposed to grinding, heavy wire brushing and acid bath processes, this method removes none of the original steel
and is not noisy or caustic.
Several other sites do a better job of explaining the chemistry of this - but basically you set up a conductive solution and insert some sacrificial anodes. You hang your
rusted tool in the solution and attach it to the negative end of the power supply. You attach the positive end to the anode and turn on the power. The current travels
through the solution and in the process flakes off the rust - the flaking/softening occurs because of the reaction at the surface of the good steel that pushes the rust off.
http://www.instructables.com/id/Electrolytic-Rust-Removal-aka-Magic/
Image Notes
1. This was my first try - very hokey. the clamp was holding the wire to the tool.
Alligator clips were a good upgrade.
http://www.instructables.com/id/Electrolytic-Rust-Removal-aka-Magic/
Image Notes
1. saw after about 15 minutes of running in the tank - the rust turns black
2. previsouly cleaned section
3. This section of the blade had some oil on it - which was preventing good
cleaning action. i re cleaned it with acetone and hit it with the power wire brush
before re-starting.
Image Notes
1. If the bubbles dont start to form within a minute or so you probably did
something wrong or there is a bad connection.
http://www.instructables.com/id/Electrolytic-Rust-Removal-aka-Magic/
http://www.instructables.com/id/Electrolytic-Rust-Removal-aka-Magic/
http://www.instructables.com/id/Electrolytic-Rust-Removal-aka-Magic/
Image Notes
1. Original surface
2. no electrolysis but power brushed for the same amount of time as left side.
NOte the rust is very much still there and will come back almost immediatly.
3. cleaned for 1 hour and then wire brushed on grinder wheel for about 5
seconds per linear inch of blade.
http://www.instructables.com/id/Electrolytic-Rust-Removal-aka-Magic/
step 1: Gather supplies
You will need:
This project cost me about $40 because I did not have access to a small battery charger. If you have a charger, then most folks with a decent shop full of crap can do it
for almost nothing.
- Clean 5 gallon spackle bucket or other plastic container to meet your size needs
- 5 sections of 18” long 1/2” steel rebar ($5 at Home Depot –
buy in longer sections as needed) (DO NOT USE STAINLESS STEEL)
- 5 feet 12 awg (or so) insulated copper wire in two colors
- 5 yellow wire nuts
- several red wire nuts
- 5 feet pliable tire wire (non insulated)
- Box of washing soda NOT baking soda
- Anti-oxidant goo (IE Noalox – This is not necessary
but helps I think.
- Small battery charger or home made power supply ($20-$50 at AutoZone etc) - Its best if the charger
has a 6v option and an internal "trouble" switch that stops charging if something shorts out.
- Variety pack of alligator clips from RadioShack (unless charger comes with decent ones…)
- Outside outlet or extension cord
- GFCI protected outlet (this is a must in my opinion - working around power and water is stupid unless
you have GFCI protection
- 5 gal water
- misc clamps/small boards
- drill with 1/4 bit
- wire cutting and twisting pliars (linemans tools are best
- wire brush (better if on a grinder or dremel tool)
- anti rust spray or light oil
http://www.instructables.com/id/Electrolytic-Rust-Removal-aka-Magic/
step 2: Assemble tank and anodes
NOTE: Do not use stainless steel for the electrodes. As pointed out by a commenter on the intro page (thanks!) "The chrome in the stainless will leach out during the
electrolysis and form hexavalent chromium compounds in your electrolyte. These are extremely bad for you." This is true - dont even think about using stainless steel for
this project.
1) Space the rebar evenly around the bucket along the sides (running top to bottom). Mark the locations
2) Drill two small holes about 1/2 inch apart 2” down from rim for each rebar
3) Insert 5” of tire wire through the holes around the rebar and out again . Lube the ends of the bar with anti oxidant compound and twist the wire tight and snip off so 1”
of the wire is remaining.
4) Once all rebar is in place, make 4 sections of copper wire with the ends skinned off to connect each rebar wire.
http://www.instructables.com/id/Electrolytic-Rust-Removal-aka-Magic/
5) Wire nut each rebar to the next with a section of cooper wire (connecting the protruding tire wire (I also used Noalox on these connections). Do not connect the first
and last rebar (ie: X---X---X---X---X---)
6) Add 5 tablespoons of washing soda to the bucket and fill within 2” of the rim with clean water (adding extra soda will not help…)
Image Notes
1. fill the wire nut with anti oxidant goop before you attache the steel wire to the
copper line
http://www.instructables.com/id/Electrolytic-Rust-Removal-aka-Magic/
step 3: Set up hanging clips
Step 2:
1) Find a board (or any non-conductive object) to lay across the top of the bucket.
2) Attach a short lead of copper wire with an alligator clip attached to the water end. (I just stapled the wire to the board)
3) The clip should hang low enough to just enter the water. ( first photo below shows three clips - i was doing three parts at once..)
Image Notes
1. I usually scrape the clips back and forth on the tool (even after wire brushing a
clean spot) to make sure there is a good connection. On this saw i used two clips
just for overkill.
Image Notes
1. This was my first try - very hokey. the clamp was holding the wire to the tool.
Alligator clips were a good upgrade.
http://www.instructables.com/id/Electrolytic-Rust-Removal-aka-Magic/
step 4: Attach charger
Don’t mess this step up – the polarity is important:
1) attach the positive (red +) end of the battery charger to the rebar wire
2) attach the negative (black -) end of the battery charger to the alligator clip over the water
3) I remember this by saying to myself “the rust flows off the tool towards the positive side”
Image Notes
1. Negative end to the tool
2. I actualy set the charger further away for safety - this was just for demonstration pics.
3. positive end to the rebar (anode) side.
2) Attach alligator clip (which is attached to the negative end of the charger) and and hang the tool completely in the water. Its ok if the clip is in the water – it wont hurt it.
Wiggle the clip to make sure you have a good connection.
3) Make sure the tool is attached firmly and is not touching the rebar or any part of the setup that is attached to the positive lead.
4) Areas of the tool that do not have a “line of sight” to the rebar will not be cleaned – if you have a complex part you might need to rotate it or add more rebar
electrodes.
http://www.instructables.com/id/Electrolytic-Rust-Removal-aka-Magic/
Image Notes
1. I usually scrape the clips back and forth on the tool (even after wire brushing a
clean spot) to make sure there is a good connection. On this saw i used two clips
just for overkill.
Image Notes
1. This was my first try - very hokey. the clamp was holding the wire to the tool.
Alligator clips were a good upgrade.
Image Notes
1. Last rebar in line has a tail of coper wire left - it does not connect back to the
first rebar
step 6: Power it up
1) set the battery charger to a low setting (6v – 1.5 amp works great for me)
You should see tiny bubbles start to form all over the tool. As the process progresses, the rust will start to flake off and the water will become muddied with rust and goop
and foam depending on how fast the bubbles are forming.
http://www.instructables.com/id/Electrolytic-Rust-Removal-aka-Magic/
Image Notes
1. If the bubbles dont start to form within a minute or so you probably did something wrong or there is a bad connection.
The tool will turn black and the rust changes form and flakes off.
If you leave it in long enough, you should be able to wipe the rust off with your finders and find a smooth (but pitted) surface. The nice part about this is that even after
only 1/2 hour, the rust is much easier to remove with a wire brush.
NOTE: the tool will not come out of the tank ready to paint. it will still need wire brushing or final polishing with steel wool. the process leaves a gray/black layer of oxidant
that you will probably want to remove prior to final rust-proofing or painting.
The photo of the saw below shows three stages: The left side was run for an hour and then brushed. The middle spot was steel brushed for the same amount of time but
without the electrolysis (and rust remained) and the right side is the original rust.
http://www.instructables.com/id/Electrolytic-Rust-Removal-aka-Magic/
Image Notes
1. Original surface
2. no electrolysis but power brushed for the same amount of time as left side.
NOte the rust is very much still there and will come back almost immediatly.
3. cleaned for 1 hour and then wire brushed on grinder wheel for about 5
seconds per linear inch of blade.
Image Notes
1. saw after about 15 minutes of running in the tank - the rust turns black
2. previsouly cleaned section
3. This section of the blade had some oil on it - which was preventing good
cleaning action. i re cleaned it with acetone and hit it with the power wire brush
before re-starting.
Image Notes
1. closeup of previous photo L to R - Run in tank and cleaned - no tank
treatment - original rust.
step 8: Samples
Here are a few samples:
The chisel was very rusted – normal rust removal would have required much original steel grinding to remove the deep pits that a wire brush would not have touched.
Check out the stamp that was revealed after cleaning.
The entire project was started because I bought this sweet plane that was totally rusted. I only paid a few bucks, but knew that a used non-rusted one was worth quite a
chunk of change. After the tank proces it took about an hour of going over it with the light wire brush wheel on the dremel to shine it up – but it would have been
impossible without the electrolysis first.
http://www.instructables.com/id/Electrolytic-Rust-Removal-aka-Magic/
http://www.instructables.com/id/Electrolytic-Rust-Removal-aka-Magic/
http://www.instructables.com/id/Electrolytic-Rust-Removal-aka-Magic/
step 9: Final Rust proofing
If you are not going to paint the tool then it will require immediate rust proofing.
– but I think there are some less noxious easier to clean up products out there like Camellia oil
http://www.instructables.com/id/Electrolytic-Rust-Removal-aka-Magic/
step 10: FAQ
How big/small of an object can I do?
- My browsing around on the web found people doing anything from small parts in a 1/2 gallon tub to a trailer body in a swimming pool using a large welder for the power.
- As little as possible to still get the job done. I think you will get better results with low power and two days of processing than high power and getting it done in an hour.
The larger the object (surface area) the more power required to do it in a given amount of time. My charger is 1.5 amp 6 volt and works great for hand tools. the small
stuff takes a few hours. The larger complex plane took a day and a half before i was happy with the amount of removal.
Is this dangerous?
- Only if you don’t have any common sense and don’t use a GFCI protected power source.
- Yes if you do it inside - the bubbles forming are evidently hydrogen which is flammable. Outside it does not cause any problems.
- The low voltage is pretty safe - especially if your charger has an automatic cut off "trouble" switch.
- Some people say that depending on the power and time involved, the steel can become brittle due to a temporary change in structure. This is cured by "baking" the tool
for a few hours at 350 in the oven or letting it sit around for a few months before any hard use. see the links below for more info. I have not found this to be a problem.
These guys deserve the credit for teaching me how to do this and provide way more info on this system:
http://www3.telus.net/public/aschoepp/electrolyticrust.html
http://myweb.tiscali.co.uk/andyspatch/rust.htm#top
http://antique-engines.com/electrol.asp
Related Instructables
http://www.instructables.com/id/Electrolytic-Rust-Removal-aka-Magic/
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Comments
50 comments Add Comment view all 196 comments
My problem is the rust inside the pistons. The brake is hydraulic and I can't take it apart to actually reach the pistons inside...
http://www.instructables.com/id/Electrolytic-Rust-Removal-aka-Magic/
latemtech says: May 28, 2009. 12:08 PM REPLY
i dont know what kind of tool you got at home but i hope this helps. secure the caliper down GOOD! (vise clamp?) Spray it
down with pb blaster, every 10 min for an hour then take a metal brush that has a long brittle, long enough to reach
through it but not longer than that. go scrubbing. elbow grease all the way. or take a small screw driver, flathead, and grind
the flathead until it become a sharp tiny chisel. chip away the rust. most screwdriver are chromoly so they are harder than
steel and certainly harder than rust. or just buy one of those dangerous chemical rust remover.
if this isnt feasible, get a plastic container, just big enough for the caliper (spagetti sauce container?) pour in sand to fill 1/3
of the way. put in the caliper. shake... however, shaking gonna tire you out. so this is what i did, i took a long screw, put it
thru the cap, bolt it down thru the cap, put a drill on a vice clamp and put the screw on the drill. tie down the trigger. make
sure it on slow speed. dude, i never wrote an instructables but now i think i should. huh.
I'll see if the caliper can be disassembled. Perhaps I'll call a bike shop about it.
I use a similar setup for removing rust from cast iron fry pans and dutch ovens.
All that said, is it really so hard to just use some rubber gloves?
You can also get a serious burn if you are wearing jewelery that gets fried.
Just because you are working with low voltage doesn't mean you don't have to observe proper precautions.
I like to use a hard drive spindle with all the platters still on as the anode
http://www.instructables.com/id/Electrolytic-Rust-Removal-aka-Magic/
jeff-o says: May 27, 2009. 6:45 AM REPLY
I've used salt before and it does work. Of course, I did it outside!
I used dry dishwasher detergent. It's serious tough on work clothes too!
And I wonder if anyone has rigged up a UPS to provide power for the cleaning? I have used a couple of low power wall warts, rigged up. Now I have a small
battery charger.
http://www.instructables.com/id/Electrolytic-Rust-Removal-aka-Magic/
sensoryhouse says: Feb 10, 2009. 9:15 PM REPLY
Here's my first finished piece, forgot to take a before picture.
I just got my battery charger about two weeks ago from my father. I had to chuckle a little when i saw you had posted an "ible with the same charger.
I was unable to find Washing Soda (Sodium Carbonate) in stores in my area as well. I did, however, find that I could purchase it on drugstore.com.
Please let your other (frustrated) readers know. It was $6 for the product and about the same to ship to Seattle.
Jim
http://www.instructables.com/id/Electrolytic-Rust-Removal-aka-Magic/
ToolNut says: Feb 10, 2009. 8:59 AM REPLY
Now that I think more - I think it may have been stainless steel that you should not use. I still wouldn't do chrome until you confirm that it will be safe.
The iron object is put into a caustic bath connected to an electrode or an anode and the process of removing the ions from the iron. (It has been a long time
since I sat in chemistry class).
A friend found a rusted pistol frame in a sand dune. He kept it as a souvenir but the gun dissolved into a pile of rust after a couple of years after surviving
decades in a sand dune. If you find something that could be of historic important, please leave it for the experts to deal with.
Thank you.
;)
Um, but isn't the safety thing here on hydrogen gas meeting oxygen as a gas and not a liquid? You can't reburn H20 but wouldn't you be worried if you were
separating hydrogen from oxygen, and then something sparked? Isn't it not the voltage of the battery you are using but the hydrogen & oxygen you are
separating that you should be worried about? But I don't know much about that stuff. But wouldn't it provide an explosion if hydrogen & oxygen gas is
emitted? I'm pretty sure hydrogen & oxygen burn the best out of everything on earth.
Also I'm pretty sure its the sodium that makes something a salt. Baking powder is also a salt. Its the chloride in Sodium Chloride that is bad not the salt.
Electrolysis/hydrogen power systems require really good filtering due to the gas storage involved, as you are correct that the combined hydrogen/oxygen
mix from filtration leakage can lead to an impressive boom.
An open bucket in the back yard isn't going to build up a significant concentration, after all, hydrogen rises pretty quickly on it's own. So don't do it inside
where it can get trapped and ignited by a fan motor or something.
http://www.instructables.com/id/Electrolytic-Rust-Removal-aka-Magic/
frenzone says: Feb 5, 2009. 9:16 AM REPLY
Excuse me for my ignorance, but what does GFCI stand for? thanks!
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