DPP - Daily Practice Problems Date Start Tim CHEMISTRY §(cc15 ‘SYLLABUS : Chemical Kinetics Max. Marks : 74 Timo : 60 min. (GENERAL INSTRUCTIONS ‘+ The Daly Practice Prablem Sheet contains 20 Questions divided into 5 sections. ‘Section T has 5 MCQs with ONLY 1 Cortect Option, 3 marks for each corect answer and = foreach incorrect answer ‘Section II has 4 MCQs with ONE or MORE THAN ONE Corect options. For each question, marks wil be awarded In one of the follwing categories: Full marks: +4 If only the bubbles) coresponding to all the correct option(s) Is (are) darkened. Partial marks: +1 For darkening a bubble corresponding to each corect option provided NO INCORRECT option is darkened. Zero marks: If nane ofthe bubbles is darkened, Negative marks: ~2 In al other cases. ‘Section IIE has § Single Dgt Integer Answer Type Questions, 3 marks for each Correct Ansier and O marks in all ther cases End Time Section TV has Comprehension/Matching CurmComprehension Type Questions having 5 MCQs with ONLY ONE correct ‘option, 3 marks for each Correct Answer and 0 marks in all oer cases, ‘Section V has 2 Matching Type Questions, 2 mark forthe correct matching of each row and 0 marks in all other cases. ‘You have to evaluate your Response Grids yoursef wih the help of Solutons,, ‘Section - Straight Objective Type 2 The rate coefficient (k) for a particular reactions is Thssecon conta mile che queso. Eachqussonbasd 13 <104Ms at Cand 310M 5 at SO oes a) erotic ONLY ONE Sexe. ‘Whats the energy oft (Ea) fr section? Tr Reaction atebetvrntwosubsiancedand Biverprowed (Rei gsconstan'= 8.314 Km) L Ragonrichanen montane danidncpecd — (N or ra ilartar ©» @ 2 Ihc ctneentton fA isdoblotandconesnration of 3. Therate constant, theativation egy andthe ares ismade halfof initial concentration, the ratio of the new rate parameter of a chemical reaction at 25°C are 3.0 « 10-4s"!, tote tel TORI mot andGd 10% respectively The value oF @) men (0) nm the rate constant as T —» 0 is 20-1085!) 60x 108s! © Fara] © aren (©) Infinity (@) 36x 10"s BREE + 9800 2 0000 _ 3 0000 ‘Space for Rough Work¢88_-_—$A ——. DPP/ CCB 4. Farthenon stoichiometric reaction 2.4448 -» C+D, the following kinetic data were oblained in three separate experiments alla 298K, c Tran | tial ateof Concentration |Cncentzation] formation oc “) ® uM am | aio aun mm [1310 02M orm [20107 The rate law for the formation of Cs éc oy Canara} aoe a © Sar @ S=nt4 S Teint ofeaton Sree ee Relat at itrentntal ac _, Leatate) ‘concentrations are piven below: Initial ate, [Aly TBipM ——[ClyM Ms! 50102 0010 anes 010 50=103 0010 000s ois Tox102, 0010 010 010 125x102 00s 000s 010 ‘The order with respect to the reactants, A, B and C are respectively (3.2.07 32.1 @ 220 210 ‘Section i- Multiple Correct Answer Type This secon contains mutigle covet answers type question. Each question has 4 choices, (0), (and (cto which ONEOR MORE. ise corect. 6 Hidroysisofan ester is catalysed by "ion. Using equimolar ‘cancentratons of two acids AX and HY, beth being strong ‘cid, the rate constants of the reaction are found to be 3» 1 min-! and $ = 107 min“ respectively at a fixed ‘temperature. tean be concluded that (@) Rate constant may be taken asthe measure of degree of ionization ofthe acid used as catalyst (0) HX isa stronger acid than HY, thei relative strength being 17 (©) Hts weaker acid than HY, ther elatve strength bring 06 (2) none is comet Hydrolysis of sugars catalysed by H*ion, Half ofthe reaction isindependent of inital concentration of sugar at a particular pH. Ata constant concentration of sugar rate imereases 10 times when pH is deveased by one unt, Pick ‘ut the corret statements ofthe fllowing. 4. @©OO 5. OOOO 9% @O0O@ W.O@OO 6 @0OO OO! 12.ODOOQHDOOOO 13.0O0OOOOOOOO (@) Rate {sugar} (b) Rate o[H") (6). Reelaw: rete=4(suga] (q@) Rate law : rate=k (sugar) (H*] 8 Theratelawofgasoms reaction: 4 + i ~» Products awenbyALARUHT lithe volume ofthe eben vessels Suddenly doubled, which ofthe following wil happen? {@) Theratewet. 4 will decrease wo times (0) ‘Theratewrt wl dees fou times (©) Theratewet Bil derease wo times {G) ‘The overall rate will esease 8 times ofthe original vale ‘Thereaction 24+B—»C+D goes o completion and fllows the following rate law a Slal= AAPL] Fo this eation the values ofx andy inthe illowing tubleare Se TAI Go) [BT oT a) HIPC NS a) “ 26 2 wo @ x 3008 x0 es a x0 y @) 626und62s (© 626ana3i25 (@ 13and62s (@ 313ana3i25 ‘Section Il Integer Type ‘Hissin otis questions. Theanserieschotthequstensisa Sinj cgtnoge ang 08 TO. IF one sans with | Cure (Cl) of radiosive sistance {ign i9 hea ser ape oo wes Shut Odie cs Fin thevlue ot 1. Hydrossis of an sly halide (RX) by due eta (81) takes place simultaneously by $,2 and Syl pathways. A plot of ~- Ra 2 vs (OH) isa straight line of the slope cq CoHSCKD +N2(8) {Titian ofan sligut ofreacton mixture with ala ©) Cj:H20)(aq)+41,0-LL, 4. Measurement of pressure ofeaction mixture at Dela) +CsHi20¢ (oq) eee aol Col ®OOO: B- OOOO: C- POO: D- OOOO. Total Questions Attempted Incorrect Net Score [Cut-off Score Qualifying Score ‘Success Gap = Net Score — Qualifying Score Net Score = (Correct x 4) — (Incorrect x 1) ‘Space for Rough Work a5 GP_3368,