Tugas Thermodinamika Lanjut

Nama = Nur Aminah Hasanah Faizin

3.9) Data =
7 5
P = 10bar T = 600K 𝐶𝑝 = 2 𝑅 𝐶𝑣 = 2 𝑅

Step12 = Isotermal, P = 3 bar

Step 23 = Isokorik, P = 2 bar
Step 34 = Isobarik
Step 41 = adiabatik

P1 = 10 bar T1 = 600 K R = 83,14 cm3 .bar.mol-1.K-1

𝑅. 𝑇1
V1 =
𝑃1
83,14 ∗ 600
V1 =
10
V1 = 4,988*10-3m3/mol
P4 = 2 bar
𝑅
𝑃4 𝐶𝑝
Step 41 = 𝑇4 = 𝑇1 (𝑃1)
83,14
2 7
𝑇4 = 600. (10)(2)83,14 =

T4 = 378,83 K
ΔU41 = Cv(T1-T4)
5
= (2 (8,314 J. mol − 1. K − 1))(600 K - 378,83 K)

ΔU41 = 4597*103J/mol
ΔH41 = Cp(T1-T4)
7
= (2 (8,314 J. mol − 1. K − 1))(600 K - 378,83 K)

ΔH41 = 6436*103J/mol
Q41 = 0 J/mol
 W41 = ΔU41
W41 = 4597*103J/mol

Step 12 = P2 = 3 bar T2 = 600 K

𝑅. 𝑇2
V2 =
𝑃2
83,14 cm3 . mol − 1 ∗ 600 𝑐𝑚3
V2 = = 16628
3 𝑚𝑜𝑙
𝑚3
V2 = 0,017
𝑚𝑜𝑙
Isotermal = ΔU12 = ΔH12= 0 J/mol
𝑃2
Q12 = -R.T1.ln𝑃1 (3.27)
3
= -83,14*600* ln10
𝐽
Q12 = 6006 ∗ 103 𝑚𝑜𝑙

W12 = -Q12
𝐽
W12 = -6006*103𝑚𝑜𝑙

Step 23 = P3 = 2 bar
V3 = V2
𝑚3
V3 = 0,017𝑚𝑜𝑙

𝑃3. 𝑉3
T3 =
𝑅
2 ∗ 0,0017
T3 =
0,00008314
T3 = 409 K
ΔU23 = Cv(T3-T2)
5
= (2 (8,314 J. mol − 1. K − 1))(409 K – 600 K)

ΔU23 = -627, J/mol

 ΔH23 = Cp(T3-T2)
7
= (2 (8,314 J. mol − 1. K − 1))(409 K - 600 K)

ΔH23 = -5557*103 J/mol

Q23 = ΔU23
Q23 = -3969*103 J/mol
W23 = 0 J/mol
Step 34 = P4 = 2 bar T4 = 378,83 K
𝑅. 𝑇4
V4 =
𝑃4
83,14 cm3 . mol − 1 ∗ 378,83
V4 =
2
cm3
V4 = 15747,9631 𝑚𝑜𝑙
cm3
V4 = 0,016 𝑚𝑜𝑙

ΔU34 = Cv(T4-T3)
5
= (2 (8,314 J. mol − 1. K − 1))(378,83 K – 409 K)

ΔU34 = -3969*103 J/mol

ΔH34 = Cp(T4-T3)
7
= (2 (8,314 J. mol − 1. K − 1))(378,83 K – 409 K)

ΔH34 = -5557 J/mol

Q34 = ΔH34
Q34 = -5557 J/mol
W34 = -R(T4-T3)
= -8,314(378,83 K – 409 K)
W34 = 250,833 J/mol
3.45) Data =
30m3 contains 14m3 of liquid n-butane
T = 25ºC P = 2,43 bar
T = 298,15 K
Molar mass = 58,123 g/mol
ω = 0,2
Tc = 425,1 K
Pc = 37,96 bar
𝑇
𝑇𝑟 =
𝑇𝑐
298,15
𝑇𝑟 =
425,1
Tr = 0,7 K
𝑃
𝑃𝑟 =
𝑃𝑐
2,43
𝑃𝑟 =
37,96
Pr = 0,06
Vvap = 30-14
Vvap = 16 m3

𝑅𝑢𝑚𝑢𝑠 𝐵 0 𝑑𝑎𝑛 𝐵1 𝑑𝑖𝑑𝑎𝑝𝑎𝑡 𝑑𝑎𝑟𝑖 3.65 𝑑𝑎𝑛 3.66

0,422
𝐵 0 = 0,083 −
𝑇𝑟1,6
0,422
𝐵 0 = 0,083 −
0,71,6
𝐵 0 = 0,746
0,172
𝐵1 = 0,139
𝑇𝑟 4,2
0,172
𝐵1 = 0,139 −
0,74,2
𝐵1 = −0,63
 𝑅. 𝑇 𝑇𝑐
𝑉= + (𝐵0 + 𝜔. 𝐵1 ). 𝑅
𝑃 𝑃𝑐

83,14 . 298,15 425,1

𝑉= + (0,746 + 0,2 ∗ (−0,63)). 83,14 .
2,34 37,96
𝑐𝑚3
𝑉 = 11367,75
𝑚𝑜𝑙
𝑉𝑣𝑎𝑝
mvap =
𝑉
𝑚𝑜𝑙𝑎𝑟 𝑚𝑎𝑠𝑠
16 𝑚3
mvap =
11367,75 cm3/mol
58,123 g/mol
16 𝑚3
mvap =
0.01136775 m3/mol
58,123 g/mol
mvap = 81807,57 g
mvap = 81,8075 kg
3,46) Data = Etane
A] V = 0,15 m3 T = 333,15 K = 60ºC P = 14 bar
B] Mass = 40 kg V = 0,15m3 P = 20 bar
a) T = 333,15 K Tc = 305,3 K
𝑇
𝑇𝑟 =
𝑇𝑐
333,15
𝑇𝑟 =
305,3
Tr = 1,09 K
P = 14 bar Pc = 48,72 bar
𝑃
𝑃𝑟 =
𝑃𝑐
14
𝑃𝑟 =
48,72
Pr = 0,3 bar
ω = 0,1 Molar mass = 30,07 g/mol
Interpolasi buat Z0 dan Z1 dari Tr dan Pr
Z0 = 0,918 Z1 = 0,0003
Z = Z0+ω.Z1
Z = 0,918+0,1.0,0003
Z = 0,91803

𝑍. 𝑅. 𝑇
𝑉=
𝑃
0,91803 ∗ 83,14 ∗ 333,15
𝑉=
14
𝑐𝑚3
V = 1816,263 𝑚𝑜𝑙

𝑚3
V = 0,001816263 𝑚𝑜𝑙
 𝑉𝑡𝑜𝑡𝑎𝑙
𝑚𝑒𝑡ℎ𝑎𝑛𝑒 =
𝑉
𝑀𝑜𝑙𝑎𝑟 𝑚𝑎𝑠𝑠

0,15
𝑚𝑒𝑡ℎ𝑎𝑛𝑒 =
0,001816
30,07

methane = 2483,75 g
methane = 2,48375 kg

b) P = 20 bar m = 40 kg