Tugas Thermodinamika Lanjut

Nama = Nur Aminah Hasanah Faizin

3.9) Data =
7 5
P = 10bar T = 600K Cp= R C v= R
2 2
Step12 = Isotermal, P = 3 bar
Step 23 = Isokorik, P = 2 bar
Step 34 = Isobarik
Step 41 = adiabatik

P1 = 10 bar T1 = 600 K R = 83,14 cm3 .bar.mol-1.K-1

R.T 1
V1=
P1
83,14∗600
V1=
10
V1 = 4,988*10-3m3/mol
P4 = 2 bar

( )
R
P4
Step 41 = T 4=T 1 Cp
P1
83,14

( 102 )( )
7
83,14
T 4=600. 2
=¿

T4 = 378,83 K
ΔU41 = Cv(T1-T4)
5
= ( ( 8 ,314 J . mol−1 . K −1))(600 K - 378,83 K)
2
ΔU41 = 4597*103J/mol
ΔH41 = Cp(T1-T4)
7
= ( (8,314 J . mol−1 . K−1))(600 K - 378,83 K)
2
 ΔH41 = 6436*103J/mol
Q41 = 0 J/mol
W41 = ΔU41
W41 = 4597*103J/mol

Step 12 = P2 = 3 bar T2 = 600 K

R.T 2
V2=
P2
3
83,14 cm3 . mol−1∗600 cm
V2= =16628
3 mol
m3
V2 = 0,017
mol
Isotermal = ΔU12 = ΔH12= 0 J/mol
P2
Q12 = -R.T1.ln (3.27)
P1
3
= -83,14*600* ln
10
J
Q12 ¿ 6006∗10 3
mol
W12 = -Q12
J
W12 = -6006*103
mol

Step 23 = P3 = 2 bar
V3 = V2

m3
V3 = 0,017
mol
P 3. V 3
T3=
R
2∗0,0017
T3=
0,00008314
T3 = 409 K
 ΔU23 = Cv(T3-T2)
5
= ( ( 8,314 J .mol−1 . K −1))(409 K – 600 K)
2
ΔU23 = -627, J/mol
ΔH23 = Cp(T3-T2)
7
= ( (8,314 J . mol−1 . K−1))(409 K - 600 K)
2
ΔH23 = -5557*103 J/mol
Q23 = ΔU23
Q23 = -3969*103 J/mol
W23 = 0 J/mol
Step 34 = P4 = 2 bar T4 = 378,83 K
R.T 4
V 4=
P4
83,14 cm3 . mol−1∗378,83
V 4=
2
cm3
V 4=15747,9631
mol
cm3
V4 = 0,016
mol
ΔU34 = Cv(T4-T3)
5
= ( ( 8,314 J .mol−1 . K −1))(378,83 K – 409 K)
2
ΔU34 = -3969*103 J/mol
ΔH34 = Cp(T4-T3)
7
= ( (8,314 J . mol−1 . K−1))(378,83 K – 409 K)
2
ΔH34 = -5557 J/mol
Q34 = ΔH34
Q34 = -5557 J/mol
W34 = -R(T4-T3)
 = -8,314(378,83 K – 409 K)
W34 = 250,833 J/mol
3.45) Data =
30m3 contains 14m3 of liquid n-butane
T = 25ºC P = 2,43 bar
T = 298,15 K
Molar mass = 58,123 g/mol
ω = 0,2
Tc = 425,1 K
Pc = 37,96 bar
T
Tr=
Tc
298,15
Tr=
425,1
Tr = 0,7 K
P
P r=
Pc
2,43
Pr=
37,96
Pr = 0,06
Vvap = 30-14
Vvap = 16 m3

0 1
Rumus B dan B didapat dari 3.65 dan3.66
0,422
B0=0,083− 1,6
Tr
0,422
B0=0,083− 1,6
0,7
0
B =¿ 0,746
0 ,17 2
B1=0,139 4,2
Tr
1 0,172
B =0,139−
0,7 4,2
 1
B =−0,63
R.T Tc
V= + ( B0 +ω . B 1 ) . R
P Pc

83,14 . 298,15 425,1

V= + ( 0,746+ 0,2∗(−0,63) ) . 83,14 .
2,34 37,96

cm3
V =11367,75
mol
Vvap
m vap=
V
molar mass
16 m 3
m vap=
11367,75 cm3 /mol
58,123 g /mol
16 m3
m vap=
0.01136775 m3 / mol
58,123 g/mol
mvap = 81807,57 g
mvap = 81,8075 kg
3,46) Data = Etane
A] V = 0,15 m3 T = 333,15 K = 60ºC P = 14 bar
B] Mass = 40 kg V = 0,15m3 P = 20 bar
a) T = 333,15 K Tc = 305,3 K
T
Tr=
Tc
333,15
Tr=
305,3
Tr = 1,09 K
P = 14 bar Pc = 48,72 bar
P
P r=
Pc
14
Pr=
48,72
Pr = 0,3 bar
ω = 0,1 Molar mass = 30,07 g/mol
Interpolasi buat Z0 dan Z1 dari Tr dan Pr
Z0 = 0,918 Z1 = 0,0003
Z = Z0+ω.Z1
Z = 0,918+0,1.0,0003
Z = 0,91803

Z . R .T
V=
P
0,91803∗83,14∗333,15
V=
14

cm3
V = 1816,263
mol
3
m
V = 0,001816 263
mol
 V total
methane =
V
Molar mass

15
methane =
0,001816
30,07

methane = 2483,75 g
methane = 2,48375 kg

b) P = 20 bar m = 40 kg