UTS 2010/2011

1. Dik : n = 1 T = 30 atau 303 K

P0 = 1 P1 = 50
Keadaan isotherm
Dit : a.) Q
b.) W
c.)
Jawab :
V0 = n.R.T / P0 V1 = n.R.T/P1
= 1. 8,314. 303 / 1 = 1. 8,314. 303/50
= 2519,142 = 50,382
a.) Q = W
= n.R.T ln V1/V0
= 1. 8,314. 303 ln 50,382/2519,142
= -9854,941 J
b.) W = Q
= 9854,941 J
c.) U = 0
2. Dik : n = 2 mol T = 350 K
P0 = 10 atm P1 = 2 atm
Cv = R Keadaan adiabatic
Dit : a.) Q
b.) W
c.) U
Jawab :
a.) Q = 0
Cv
T2 R P2 T1
b.) ( ) = x
T1 P1 T2
1/2R
T2 R 2 350
(350) = x
10 T2

T2 752
=
350 T22
 T23 = 1968750
T2 = 125,332 K
W = -U
= -n. Cv. dt
= -2. . 8,314. (125,332-350)
= 1867,886 Joule
3. Dik : T = 600K R = 2 kal/molK
1/2 1/2
t = orde 1 (1/2 dari t 400K)
Dit : energi pengaktifan
Jawab :
0,693 0,693
K400K = K600K =
2t1 /2 t1 /2

R(T1.T2) K600K
E = x ln
T2T1 K400K
2.(600.400) 0,693/t^1/2
= x ln
600400 0,693/2t^1/2

= 1663,553 kalori
4. Dik : t1/2 = 30 menit
[P0] = 2mol/L
Dit : V setelah 60 menit
Jawab :
2 0,693
[P1] = 60 K=
2 t1 /2
30

2 0,693
= =
4 3600

= 0,5 mol/L = 1,925.10-4

[P1]
V = k.
t1
0,5
= 1,925.10-4 x
3600

= 2,674 mol/L.detik