Tugas Thermodinamika Lanjut

Nama = Nur Aminah Hasanah Faizin

3.9) Data =
7 5
P = 10bar T = 600K 𝐶𝑝 = 2 𝑅 𝐶𝑣 = 2 𝑅

Step12 = Isotermal, P = 3 bar

Step 23 = Isokorik, P = 2 bar
Step 34 = Isobarik
Step 41 = adiabatik

P1 = 10 bar T1 = 600 K R = 83,14 cm3 .bar.mol-1.K-1

𝑅. 𝑇1
V1 =
𝑃1
83,14 ∗ 600
V1 =
10
V1 = 4,988*10-3m3/mol
P4 = 2 bar
𝑅
𝑃4 𝐶𝑝
Step 41 = 𝑇4 = 𝑇1 (𝑃1)
83,14
2 7
𝑇4 = 600. (10)(2)83,14 =

T4 = 378,83 K
ΔU41 = Cv(T1-T4)
5
= (2 (8,314 J. mol − 1. K − 1))(600 K - 378,83 K)

ΔU41 = 4597*103J/mol
ΔH41 = Cp(T1-T4)
7
= (2 (8,314 J. mol − 1. K − 1))(600 K - 378,83 K)

ΔH41 = 6436*103J/mol
Q41 = 0 J/mol
 W41 = ΔU41
W41 = 4597*103J/mol

Step 12 = P2 = 3 bar T2 = 600 K

𝑅. 𝑇2
V2 =
𝑃2
83,14 cm3 . mol − 1 ∗ 600 𝑐𝑚3
V2 = = 16628
3 𝑚𝑜𝑙
𝑚3
V2 = 0,017
𝑚𝑜𝑙
Isotermal = ΔU12 = ΔH12= 0 J/mol
𝑃2
Q12 = -R.T1.ln𝑃1 (3.27)
3
= -83,14*600* ln10
𝐽
Q12 = 6006 ∗ 103 𝑚𝑜𝑙

W12 = -Q12
𝐽
W12 = -6006*103𝑚𝑜𝑙

Step 23 = P3 = 2 bar
V3 = V2
𝑚3
V3 = 0,017𝑚𝑜𝑙

𝑃3. 𝑉3
T3 =
𝑅
2 ∗ 0,0017
T3 =
0,00008314
T3 = 409 K
ΔU23 = Cv(T3-T2)
5
= (2 (8,314 J. mol − 1. K − 1))(409 K – 600 K)

ΔU23 = -627, J/mol

 ΔH23 = Cp(T3-T2)
7
= (2 (8,314 J. mol − 1. K − 1))(409 K - 600 K)

ΔH23 = -5557*103 J/mol

Q23 = ΔU23
Q23 = -3969*103 J/mol
W23 = 0 J/mol
Step 34 = P4 = 2 bar T4 = 378,83 K
𝑅. 𝑇4
V4 =
𝑃4
83,14 cm3 . mol − 1 ∗ 378,83
V4 =
2
cm3
V4 = 15747,9631 𝑚𝑜𝑙
cm3
V4 = 0,016 𝑚𝑜𝑙

ΔU34 = Cv(T4-T3)
5
= (2 (8,314 J. mol − 1. K − 1))(378,83 K – 409 K)

ΔU34 = -3969*103 J/mol

ΔH34 = Cp(T4-T3)
7
= (2 (8,314 J. mol − 1. K − 1))(378,83 K – 409 K)

ΔH34 = -5557 J/mol

Q34 = ΔH34
Q34 = -5557 J/mol
W34 = -R(T4-T3)
= -8,314(378,83 K – 409 K)
W34 = 250,833 J/mol
3.45) Data =
30m3 contains 14m3 of liquid n-butane
T = 25ºC P = 2,43 bar
T = 298,15 K
Molar mass = 58,123 g/mol
ω = 0,2
Tc = 425,1 K
Pc = 37,96 bar
𝑇
𝑇𝑟 =
𝑇𝑐
298,15
𝑇𝑟 =
425,1
Tr = 0,7 K
𝑃
𝑃𝑟 =
𝑃𝑐
2,43
𝑃𝑟 =
37,96
Pr = 0,06
Vvap = 30-14
Vvap = 16 m3

𝑅𝑢𝑚𝑢𝑠 𝐵 0 𝑑𝑎𝑛 𝐵1 𝑑𝑖𝑑𝑎𝑝𝑎𝑡 𝑑𝑎𝑟𝑖 3.65 𝑑𝑎𝑛 3.66

0,422
𝐵 0 = 0,083 −
𝑇𝑟1,6
0,422
𝐵 0 = 0,083 −
0,71,6
𝐵 0 = 0,746
0,172
𝐵1 = 0,139
𝑇𝑟 4,2
0,172
𝐵1 = 0,139 −
0,74,2
𝐵1 = −0,63
 𝑅. 𝑇 𝑇𝑐
𝑉= + (𝐵0 + 𝜔. 𝐵1 ). 𝑅
𝑃 𝑃𝑐

83,14 . 298,15 425,1

𝑉= + (0,746 + 0,2 ∗ (−0,63)). 83,14 .
2,34 37,96
𝑐𝑚3
𝑉 = 11367,75
𝑚𝑜𝑙
𝑉𝑣𝑎𝑝
mvap =
𝑉
𝑚𝑜𝑙𝑎𝑟 𝑚𝑎𝑠𝑠
16 𝑚3
mvap =
11367,75 cm3/mol
58,123 g/mol
16 𝑚3
mvap =
0.01136775 m3/mol
58,123 g/mol
mvap = 81807,57 g
mvap = 81,8075 kg
3,46) Data = Etane
A] V = 0,15 m3 T = 333,15 K = 60ºC P = 14 bar
B] Mass = 40 kg V = 0,15m3 P = 20 bar
a) T = 333,15 K Tc = 305,3 K
𝑇
𝑇𝑟 =
𝑇𝑐
333,15
𝑇𝑟 =
305,3
Tr = 1,09 K
P = 14 bar Pc = 48,72 bar
𝑃
𝑃𝑟 =
𝑃𝑐
14
𝑃𝑟 =
48,72
Pr = 0,3 bar
ω = 0,1 Molar mass = 30,07 g/mol
Interpolasi buat Z0 dan Z1 dari Tr dan Pr
Z0 = 0,918 Z1 = 0,0003
Z = Z0+ω.Z1
Z = 0,918+0,1.0,0003
Z = 0,91803

𝑍. 𝑅. 𝑇
𝑉=
𝑃
0,91803 ∗ 83,14 ∗ 333,15
𝑉=
14
𝑐𝑚3
V = 1816,263 𝑚𝑜𝑙

𝑚3
V = 0,001816263 𝑚𝑜𝑙
 𝑉𝑡𝑜𝑡𝑎𝑙
𝑚𝑒𝑡ℎ𝑎𝑛𝑒 =
𝑉
𝑀𝑜𝑙𝑎𝑟 𝑚𝑎𝑠𝑠

0,15
𝑚𝑒𝑡ℎ𝑎𝑛𝑒 =
0,001816
30,07

methane = 2483,75 g
methane = 2,48375 kg

b) P = 20 bar m = 40 kg
10,2 Data =
P-x-y diagram T= 90 °C
t-x-y diagram P= 90 kPa
a) Benzene(1)/ethylbenzene(2)
b) 1-Chlorobutane(1)/chlorobenzene(2)

a) Antoine coef. Benzene = 1 ; Ethylbenzene = 2

A1 = 13.7819 B1 = 2726.81 C1 = 217.572
A2 = 13.9726 B2 = 3259.91 C2 = 212.3

Bulp P 140
B
Psat = exp(A - )
T(°C) + C
120
P1 sat = 136.50
P2 sat = 24.26
100
P = P2sat+(P1sat-P2sat)x1
asumsi = x1 = 0.3 P/kPa
P= 57.93 80

x1*P1sat
y1 = 60
P
y1 = 0.71
40
x1 y1 P (kPa)
0 0.00 24.26
0.3 0.71 57.93 20
0 0.5 1
1 1.00 136.50
x1-y1
B1
Tsat = (-C
A1-lnP 135
T1sat = 76.20
T2sat = 131.83
125

T-T2sat
x1 =
T1sat-T2sat 115
x1 = 0.8
T (°C)

x1.T1sat 105
y1 =
T
y1 = 0.6
95

T = T2sat+(T1sat-T2sat)x1
T= 90 °C 85

x1 y1 T (°C) 75
0 0 131.83 0 0.5 1

0.5 0.42 104.02 x1-y1

1 1.00 76.20
b) Antoine coef.
1-Chlorobutane = 1 Chlorobenzene = 2
A1 = 13.7965 A2 = 13.8635
B1 = 2723.73 B2 = 3174.78
C1 = 218.265 C2 = 211.7

B 150
Psat = exp(A - )
T(°C) + C
P1 sat = 142.71
P2 sat = 28.23
125

P = P2sat+(P1sat-P2sat)x1
asumsi = x1 = 0.2
P= 51.13 100
P/kPa
x1*P1sat
y1 =
P 75
y1 = 0.56

x1 y1 P (kPa)
50
0 0.00 28.23
0.2 0.56 51.13
1 1.00 142.71
25
0 0.5 1
B1
Tsat = (-C x-y1
A1-lnP
T1sat = 74.71
T2sat = 127.35
130
T-T2sat
x1 =
T1sat-T2sat
120
x1 = 0.7

x1.T1sat 110
y1 =
T
y1 = 0.6
100
T (°C)

T = T2sat+(T1sat-T2sat)x1
T= 90 °C 90

x1 y1 T (°C) 80
0 0 127.352
0.5 0.42 101.033
70
1 1.00 74.713 0 0.2 0.4 0.6 0.8 1
x1-y1
x1 y1 P (kPa) 140
0 0.00 24.26 130
0.1 0.24 35.49 120
0.2 0.47 46.71 110
0.3 0.71 57.93 100
0.4 0.94 69.16 90
1 1.00 136.50 80
70
60
50
40
30
20
0 0.2 0.4 0.6 0.8 1

x1 y1 T (°C) 135
0 0 131.83 130
0.1 0.08 126.27
125
0.2 0.17 120.71
0.3 0.25 115.14 120

0.4 0.34 109.58 115

0.5 0.42 104.02 110
0.6 0.51 98.45
105
0.7 0.59 92.89
100
0.8 0.68 87.33
0.9 0.76 81.76 95
1 1.00 76.20 90
85
80
75
0 0.2 0.4 0.6 0.8 1
x1 y1 P (kPa) 150
0 0.00 28.23 140
0.1 0.28 39.68 130
0.2 0.56 51.13 120
0.3 0.84 62.58 110
1 1.00 142.71 100
90
80
70
60
50
40
30
20
0 0.2 0.4 0.6 0.8 1

x1 y1 T (°C) 130
0 0 127.352
0.1 0.083015 122.088 120
0.2 0.16603 116.824
0.3 0.249045 111.561 110
0.4 0.33206 106.297
0.5 0.415075 101.033 100
0.6 0.49809 95.769
0.7 0.581105 90.505 90
0.8 0.66412 85.241
1 1.00 74.713 80

70
0 0.2 0.4 0.6 0.8 1