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Cleaner Materials 5 (2022) 100113

Contents lists available at ScienceDirect

Cleaner Materials
journal homepage: www.journals.elsevier.com/cleaner-materials

Recycling of waste HDPE and PP plastic in preparation of plastic brick and


its mechanical properties
Prathik Kulkarni a, *, Vikas Ravekar a, P. Rama Rao b, Sahil Waigokar a, Sanket Hingankar a
a
Department of Civil Engineering, Bajaj Institute of Technology, Wardha, India
b
Research Scholar, Pondicherry Technological University, Puducherry, India

A R T I C L E I N F O A B S T R A C T

Keywords: Brick is a primary building material that is often utilized in the construction of masonry. Conventionally, brick is
Plastic brick made up of dried clay and recently many studies have focused on the use of waste materials as an alternate
Thermoplastic material to a conventional brick. In the present study thermoplastics like High-Density Polyethylene (HDPE) and
Physical recycling
Polypropylene (PP) are used to manufacture the plastic brick using the physical recycling method. Here, waste
HDPE and PP
Plastic brick wall
plastic from Maharashtra Industrial Development Corporation (MIDC) is collected, segregated, cleaned, and
melted to manufacture a 190 × 90 × 90 mm modular sized HDPE and PP brick according to IS 1077:1992. In the
first phase of work, standard tests are performed to study the physical, mechanical and thermal properties of the
plastic brick. In the next phase, a 500 × 110 × 500 mm wall is constructed and the results of the plastic brick wall
are compared with a conventional brick wall. The wall was tested using a universal testing machine (UTM) as per
IS 1905:1987. It was interesting to observe that the HDPE and PP brick gave a compressive strength of 11.19 N/
mm2 and 10.02 N/mm2 which were in good agreement with first-class conventional brick which gave a
compressive strength of 10.5 N/mm2. While it is also worth noting that HDPE brick had the highest compressive
strength. The ultimate load for the plastic brick wall was 197.50 KN with a shear failure at a 45◦ , while the
conventional brick wall experienced a vertical failure at 153.95 KN load. A fire-resistance test on a plastic brick
wall and a conventional brick wall was performed to evaluate if the specifications of Nation Building Code
(2005): Part 4: Table 1 were met. It was observed that the plastic brick wall even after 30 min of heating at 4
corners and centre, showed a better temperature difference as compared to the conventional brick wall. The
study initiates a new line of research in sustainable plastic waste management.

1. Introduction mechanical properties have been investigated. In previous research, the


replacement and addition have been done in the brick with the direct
Brick is a vital building material that is widely utilized throughout composition of different raw materials like rice husk or rice husk ash
the world. It is one of the most demanding masonry units. India, along (Sutas et al., 2012), grapevine twig dust and popular dust(Andiç-Çakır
with China and Spain, is the leading brick manufacturing country, with et al., 2021), slate tailing, fly ash, and OPC(Wang et al., 2021); fly ash
an annual production rate of more than 240 billion bricks (Muheise- and lime(Çiçek and Çinçin, 2015), cigarettes buds(Kadir and Mohajer­
Aralia and Pavia, 2021). India produces about a 3.5 million tons of waste ani, 2015), crushed glass(Chidiac and Federico, 2007; Demir, 2009),
plastic every year which has almost doubled in the last five years. The clay, sawdust, marble(Eliche-Quesada et al., 2012), and sugarcane
production of waste plastic adversely affects our ecosystem and even it is bagasse ash(Faria et al., 2012).
linked with air pollution. Due to this high rate of production, it was In addition to the above-mentioned materials, Plastics are widely
brought to investigate and scrutinize the feasibility of using waste plastic employed in the production of bricks. The use of thermoplastic waste in
as an alternative for manufacturing the brick. As they will be benefiting the production of bricks is the most effective alternative for reducing
the environment as well as maintaining the requirements of materials plastic waste, saving raw materials, and enhancing the properties of
and their standards. As a result, numerous attempts have been made to bricks. Plastics are preferred over other materials due to their light­
incorporate waste into the production of bricks, and their physical and weight, low cost, low density, good stability, and durability, ability to be

* Corresponding author.
E-mail address: prathik.kulkarni@bitwardha.ac.in (P. Kulkarni).

https://doi.org/10.1016/j.clema.2022.100113
Received 29 April 2022; Received in revised form 23 June 2022; Accepted 29 June 2022
Available online 2 July 2022
2772-3976/© 2022 The Author(s). Published by Elsevier Ltd. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-
nc-nd/4.0/).
P. Kulkarni et al. Cleaner Materials 5 (2022) 100113

easily molded, good impact resistance, and mechanical properties Table 1


(Jahidul Islam and Shahjalal, 2021; Banerjee et al., 2014; Ahmad et al., Physical and mechanical properties of HDPE and PP (Maddah, 2016; Kusuktham
2017) . M.K. Mondal et al.(Mondal et al., 2019) conducted an experi­ and Teeranachaideekul, 2014).
mental study on three batches of blocks composed of polycarbonate (RIC Property HDPE PP
7), polystyrene (RIC 6), and mixed thermoplastics, sand with fly ash, and Melting point (◦ C) 110–140 160–166
OPC. Whereas mixed thermoplastics are 0–10% by weight and sand is Flashpoint (◦ C) greater than 300 greater than 300
60–70% by weight. The test results suggest that the brick containing Density (g/cm3) 0.90–1.00 0.91–0.94
10% waste plastics has a compressive strength of 17 MPa and high Specific gravity 0.90–1.00 0.9–1.00
Tensile Strength (MPa) 19–39 22–34
thermal resistance. Although these bricks are lightweight, the density is
Elongation (%) 180–1000 3–700
significantly lower. Isaac I. Akinwumi et al.(Akinwumi et al., 2019) Water absorption (%) <0.05 0.01
manufactured compressed earth brick with the use of stabilized soil and
shredded waste plastic varying in percentages and by the size of particles
(less than 6.3 mm and more than 9.6 mm). The results showed that obtained using FE analysis were compared with the theoretical values
compressed earth brick (CEB) incorporating shredded waste plastic (1% and it was observed that FE analysis gave much accurate results.
by weight and particle size <6.3 mm) resulted in a 50% rise in erosion Many researchers have partially replaced waste plastic to improve
rate (the lowest among them) and a 244.4% increase in compressive the mechanical and durability properties of brick, but no study is carried
strength compared to brick containing no plastic (0.45 MPa). These out on the complete (100%) replacement of HDPE and PP plastic in the
earth bricks can be used in residential and commercial buildings. preparation of brick. As HDPE and PP do not emit harmful gases when
In the construction industry Polyethylene (PET) and Polypropylene melted, so the melting process was carried out to prepare 19 × 9 × 9 cm
(PP) plastics are frequently employed. PET plastic brick in composition modular brick. The physical, durability, and mechanical properties of
with foundry sand(Aneke and Shabangu, 2021)and recycled glass plastic brick and first-class (designation-10) red clay brick which is
granules(Frank Ikechukwu and Shabangu, 2021) respectively had 2.5 termed conventional brick are examined. Additionally, an experimental
and 3 times higher compressive strength, and the temperature required study and comparison of plastic brick walls with the conventional brick
to manufacture those bricks was approximately 5 times lower than burnt wall are conducted in accordance with its compressive strength and fire
clay brick. The bricks with a higher percentage of PET i.e., 5% gave resistance test. All the tests were performed according to Indian Stan­
many effective results when compared with conventional fire clay dard codes. This research contributes to the use of plastic waste (HDPE
bricks, but beyond 5% replacement of PET in fire clay bricks, a reduction and PP) in the manufacture of bricks, which is the most effective method
in compressive strength was observed (Akinyele et al., 2020a,b). for reducing plastic waste, conserving raw materials, and enhancing the
Many experimental studies have been undertaken on a brick ma­ properties of bricks.
sonry wall and masonry prisms of varied constituent materials, bonds,
dimensions, and height to thickness (h/t) ratio. The physical and me­ 2. Materials and methodology
chanical characteristics of brick masonry units, as well as their masonry
with lime mortar joints, are determined(Drougkas et al., 2016; Bompa 2.1. Materials
and Elghazouli, 2020). Nassif Nazeer Thaickavil et al.(Thaickavil and
Thomas, 2018)proposed a masonry model with two different types of The thermoplastics, which include High-Density Polyethylene
bricks: cement stabilized pressed earth brick (B1) and local burnt clay (HDPE) and Polypropylene (PP), were used in this research for
brick (B2). Cement mortar ratios of different proportions were used to manufacturing the plastic bricks. PP plastics are the most often used
make masonry prisms. They assessed the compressive strength of the thermoplastics as they are lightweight and easily mouldable (Maddah,
masonry prism and recorded the cracking pattern by performing a lab­ 2016), whilst HDPE is commonly recyclable but decomposition time is
oratory test on 192 masonry prism specimens. The model proposed by too long (almost 100 years (Material Safety Data Sheet: High Density
Thaickavil et al.(Thaickavil and Thomas, 2018) accommodates a wide Polyethylene), therefore those plastics were implemented. Furthermore,
range of mortar (0.3–52.6 MPa) and masonry unit strength (3.5–127 according to the Material safety data sheet (Material Safety Data Sheet:
MPa) in his study. Kumavat et al.(Kumavat, 2016) conducted experi­ High Density Polyethylene; Material Safety Data Sheet: Polypropylene
mental research on the mechanical properties and compressive strength (PP) Homopolymer, HDPE and PP have properties such as low toxicity,
of clay brick masonry prisms using mortar composed of fine aggregate non-hazardous, and safe use. The physical, durability, and mechanical
with clay brick waste (in percentage proposition) as a replacement for properties of HDPE and PP are tabulated in Table 1.
sand. In that, the cement mortar of 1:4 and a 20% replacement of clay The reddish-brown local river sand (as fine aggregate) with a particle
brick waste gave higher results in compressive strength. They found that size of less than 4.75 mm was collected from the Bajaj Institute of
due to this replacement compressive strength of the masonry prism was Technology in Wardha. Sand has a specific gravity of 2.65, a bulk den­
found to be more as compared to standard masonry prism. The sity of 1595 kg/m3, and a fineness modulus of 2.88. As a binding ma­
compressive strength of brick and mortar is the primary factor influ­ terial, ordinary Portland cement (OPC) of 43 grade is used. Normal tap
encing the compressive strength of masonry prism, since the strength of water with a pH value of 7.0 is used for making masonry mortar.
masonry increases as the strength of brick and mortar increases (Nau­
man Azhar and Ali Qureshi, 2020; Francis et al., 2017; Singh and 2.2. Methodology
Munjal, 2017). Gumaste et al. (2007) conduct experimental research on
strength, elastic properties, and failure pattern of brick masonry prism A physical (mechanical) recycling method is involved while
and Wallette under axial compression. The masonry prism is constructed manufacturing plastic bricks (Leng et al., 2018). Initially, we collected
with varying mortar ratios and designed following IS 1905:1987 speci­ discarded plastic materials of High-density Polyethylene (HDPE) and
fications. Ajith Thamboo and Dhanasekar (2019)compared the behavior Polypropylene (PP) from Maharashtra Industrial Development Corpo­
of a prism to a cube and found that the prism provides more strength ration (MIDC) Wardha, Maharashtra, India. However, to make these
than a cube. Aside from constructing brick and analyzing its mechanical waste plastics appropriate for brick manufacturing, undesired elements
properties, numerical simulation and computerized modeling of brick are then removed from the HDPE and PP plastics. The collected plastic
masonry are also done using a finite element (FE) program (Srinivas and materials are then individually chopped into 10–20 mm size using a
Sasmal, 2016; Furtmüller and Adam, 2011). The cracking pattern, plastic crusher machine, as shown in Fig. 1(a). Now, this chopped plastic
crushing, failure of the wall, deformation by mesh application, and material is placed in a container as shown in Fig. 1(b) and heated to
maximum principal strain are all shown in the FE analysis. The results 230 ◦ C (Temperature was measured using an infrared thermometer)

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P. Kulkarni et al. Cleaner Materials 5 (2022) 100113

Fig. 1. The manufacturing process of Plastic brick. (a) Chopped plastic, (b) Melting, (c) Designed mold, (d) Plastic brick.

Fig. 2. (a) Soundness Test (b) Hardness test.

Fig. 3. (a) Plastic brick wall (b) Painting on plastic brick wall.

which is above the melting point of HDPE and PP individually. Once the properties were conducted on plastic and conventional bricks, Plastic
plastic has been converted into paste form, it is poured into molds of the and conventional brick wall was constructed according to IS 1905: 1987
standard-modular brick size of dimension 190 × 90 × 90 mm in to determine the crack pattern and load-carrying capacity of the plastic
accordance with IS 1077:1992, as shown in Fig. 1(c). Then the molten brick wall (HDPE) (500 × 110 × 500 mm) with a conventional wall
plastic paste is properly compacted in the mold during filling to avoid (500 × 110 × 500 mm) as HDPE brick carries more compressive strength
any pores in the brick. After 24 h, the plastic brick is removed from the than PP brick, fire resistance test of plastic brick wall and a conventional
mold as shown in Fig. 1(d) and tested afterward. brick wall was carried out according to Table 1 in Part 4 of SP 7: Group 1
(2005): National Building Code. The soundness test and hardness test
2.3. Experimental program are as shown in Fig. 2a and 2b. The plastering was a quite challenging
job on a plastic brick wall, so grooves were made on all the surfaces of
In the present study, Physical (Soundness, Efflorescence, Hardness, the plastic brick to have a good bond between cement mortar (1:3 (IS
Impact, and Structure) and mechanical (Compression strength) 1661 (1972)) and brick as shown in Fig. 3a and b.

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P. Kulkarni et al. Cleaner Materials 5 (2022) 100113

Table 2 includes certain physical and durability properties of HDPE, PP, and
Properties of HDPE and PP brick. conventional brick.
Parameters HDPE brick PP brick Conventional brick
3.2. Compressive strength test on plastic brick and conventional brick
Weight (kg) 1.330 1.350 2.920
Dry density (kg/m3) 864.197 877.192 1897.335
Specific gravity 0.866 0.879 1.903 HDPE, PP, and conventional brick specimens were tested under the
Water absorption (%) 0.752 0.370 12 universal testing (AIMIL) machine of capacity 1000 kN. The ultimate
Efflorescence Nil Nil Slight load carried by HDPE brick is 191.35 kN at a displacement of 18.40 mm,
whereas PP brick carries 171.35 kN at a displacement of 15.30 mm. In
3. Results and discussion addition, the conventional brick carries an ultimate load of 178.95 kN at
a displacement of 13.50 mm. The Load vs Displacement graph of brick
3.1. Physical properties of plastic brick specimens is obtained through computerized UTM and illustrated in
Fig. 4(a). The failure pattern of plastic brick was observed, with bricks
Plastic brick appears to be greyish-black in color and free of cracks. forming vertical cracks in the tension zone and splitting the edges.
The edges of plastic bricks are not precisely sharp. The weights of HDPE Similarly, conventional brick is crushed completely. However, HDPE
and PP bricks were found to be 1.33 kg and 1.35 kg, respectively. The brick has better compressive strength than PP brick and is significantly
brick’s density is calculated as a ratio of dry weight to volume (Ornam greater than conventional brick (First class) it was used in the prepa­
et al., 2017). ration of plastic brick walls. HDPE brick and PP brick have 11.19 N/mm2
A water absorption test had carried out on HDPE and PP plastic and 10.02 N/mm2 compressive strength respectively. Similarly con­
bricks according to IS 3495 (Part 2): 2019. We observed that the water ventional brick has 10.50 N/mm2 compressive strength as shown in
absorption capacity of plastic brick is drastically lower than that of Fig. 4(b).
conventional brick. After the water absorption test, an efflorescence test
is performed on both types of plastic bricks, to find the salt contents 3.3. Compressive strength test on plastic brick and conventional brick wall
available in the HDPE and PP plastic in accordance with IS 3495 (Part
3): 2019. We investigated the surfaces of brick for two evaporation cy­ A plastic brick wall is tested on a computerized Universal testing
cles and discovered that there are no perceptible changes on the satu­ machine (UTM) with a capability of 1000 kN, and a load is applied to the
rated surface of the brick. The results are tabulated in Table 2, which wall. The results revealed that loading up to 16 kN caused no
displacement on the specimen. However, the plastic brick wall bears an

Fig. 4. (a) Load vs Displacement graph of brick specimens (b) Compressive strength of brick specimens.

Fig. 5. (a) Load vs Displacement graph of brick wall specimens and (b) Cracking pattern on the plastic brick wall.

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Table 3 masonry is affected by the strength of the brick and mortar used in the
Properties of the brick wall. brickwork (Venkatesh, 2010). Furthermore, the compressive strength of
Parameters Plastic brick Conventional brick masonry (8.5 MPa) is less than the masonry unit strength (10.5
wall brick wall MPa) (Ludovikus Sugeng Wijanto, 2007). The same graph pattern was
Dimensions: b × t × h (mm) 500 × 110 × 500 × 110 × 500 even observed in our study, individual bricks carry higher strength than
500 mm mm the brick masonry.
Weight (kg/m) 47.530 104.353
Density (kg/m3) 1728.363 3794.654
Compressive strength (N/mm2) 3.59 2.79
3.4. Fire resistance test on plastic brick and conventional brick wall
Corrected Compressive strength: after 3.48 2.70
applying a correction factor of 0.97 (N/
mm2) The plastic itself is combustible at high temperatures. In the event of
Masonry efficiency (%) 28.95 25.71 a fire, the cement sand mortar with burnt clay bricks may be able to
resist the temperature that the plastic brick could not. So, in order to
determine the fire resistance of plastic brick and conventional brick
ultimate load of 197.5 kN at a displacement of 27.50 mm on the wall, as
walls, we applied continuous heat to the plastered walls’ faces according
shown in Fig. 5(a). However, according to IS 1905:1987, the correction
to Nation Building Code (2005): Part 4: Table 1.
factor for the height to thickness (h/t) ratio is multiplied by the exper­
The face of the walls has been continuously heated by a torch of gas
imental compressive strength value obtained. The height to thickness
wielding at a temperature of around 1000–1200 ◦ C and the temperature
(h/t) ratio is 4.54, and the correction factor for the brickwork specimen
on both sides of the wall was measured using a digital thermometer (TP-
according to interpolation is 0.97 and the corrected or normalized
101). The test result reveals that after 30 min, the structural integrity of
compressive strength of the wall is then calculated. The normalized
plastic brick increased burning as illustrated in Fig. 6(a). The exact rear
masonry efficiency is also calculated as the ratio of normalized or cor­
unexposed area of the plastic brick wall was at a normal temperature of
rected compressive strength to brick strength (Gumaste et al., 2007).
about 32 ◦ C, which the bare hand could touch, while the edge of this
The plastic brick wall fails due to the crushing of bricks and spalling of
brick wall has a temperature of 78 ◦ C. Cracks form on the face of heat-
mortar cover and de-bonding between the bricks. Shear failure was
affected surfaces as shown in Fig. 6(b).
observed in the wall at 45◦ angle as shown in Fig. 5(b).
The conventional brick wall is tested in the same way as the plastic
The conventional brick wall took a deflection from 21.80 kN, and the
brick wall, with a constant rate of temperature and time as shown in
first crack was observed at 98.25 kN loading. The maximum load carried
Fig. 7(a). After 30 min of constant heating, the structural integrity of the
by the wall is 153.95 kN, as shown in Fig. 5(a). The compressive strength
conventional brick is nearly identical, with a tiny cracks pattern and
of a conventional brick wall was calculated, and the correction factor of
some roughness in the texture of that exposed surface as shown in Fig. 7
0.97 was multiplied by the experimental compressive strength according
(b). In this case, heat transfers well to the rear side of the wall having a
to IS 1905:1987. Hence the experimental compressive strength data for
temperature of 113 ◦ C after 30 min. The temperature at the edges of
the plastic brick wall and the conventional brick wall is given in Table. 3.
conventional brick was 173 ◦ C. As a result, we observed that using a
The wall was deflected by an amount of 18.70 mm with vertical cracks
digital thermometer (TP-101), in the case of a plastic brick wall, bricks
along with their height.
burned while heat did not transmit very well through the wall. However,
Previous research has shown that the compressive strength of brick
in a conventional brick wall, heat is transferred more evenly throughout

Fig. 6. Heat on Plastic brick wall. (a) Burning of brick and (b) Crack on the face of a wall.

Fig. 7. Heat on Red clay brick wall. (a) Applied heat and (b) Crack and Roughness on the face of a wall.

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