ASTM Method D5134-92 (continued)

Naphtha
1. Propane 7. Cyclopentane 19. 2-Methylhexane
2. iso-Butane 8. 2,3-Dimethylbutane 20. 2,3-Dimethylpentane
3. Butane 9. 2-Dimethylpentane 21. 1,1-Dimethylcyclopentane
4. iso-Pentane 10. 3-Dimethylpentane 22. 3-Methylhexane
11. Hexane 23. cis-1,3-Dimethylcyclopentane
5. Pentane
12. 2,2-Dimethylpentane 24. trans-1,3-Dimethylcyclopentane
6. 2,2-Dimethylbutane
13. Methylcyclopentane 25. 3-Ethylpentane
14. 2,4-Dimethylpentane 26. trans-1,3-Dimethylcyclopentane
29 27. 2,2,4-Trimethylpentane
11 15. 2,2,3-Trimethylbutane
5 16. Benzene 28. Heptane
17. 3,3-Dimethylpentane 29. Methylcyclohexane and
18. Cyclohexane cis-1,2- Dimethylcyclopentane
4
38. Toluene and 2,3,3-Trimethylpentane
9 13 18 28 n-C8 42. 2-ethylheptane
55 46. 3-Methylheptane and
n-C9 n-C10 1-cis-2-trans-3-Trimethylcyclopentane
38
3 55. Octane

22 46 n-C11
42

n-C12
NOTE: The 100 m HP-1 column 6
1
is also suitable for this analy
sis. The larger ID (0.25 mm) re
quires a long column to obtain 20 40 60 80 100 120 140 min
the required efficiency for re
Column: HP-1, 100 m x 0.25 mm x 0.5 µm Injection: 0.5 µl Split (250:1)
solving these compounds.
(Agilent part no. 19091Z-530) Oven: 35C (13 min) to 45C (15 min) at
GC System: Agilent 6890 10C/min, to 60C (15 min) at 1C/min,
Carrier: Helium, 23 cm/sec, constant pressure to 220C (5 min) at 1.9C/min

Analysis of petroleum naphtha: ASTM D5134

HP-PONA, 50 m x 0.20 mm x 0.5 µm

(Agilent part no. 19091S-001)
35C (30 min), 2C/min to 200C
0.5 µl split 200:1, helium, 24 cm/sec,
constant pressure

0 10 20 30 40 50 60 70 min

32