05092023 Class Practice Test-1 Ranker Batch

ORGANIC CHEMISTRY
Time : 45 : 00 Min. (Topic : GOC & CARBOHYDRATE) Max. Marks : 60
(for JEE-Mains & Advanced 2024)
* Each question + 4 (for correct answer) & - 1 (for wrong answer)
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01.M The decreasing order of basic strength is :

(a) 1 > 5 > 3 > 4 > 2 *(b) 4 > 1 > 5 > 3 > 2
(c) 5 > 4 > 1 > 2 > 3 (d) 4 > 5 > 3 > 1 > 2
02.M Choose the order for increasing boiling point of the following compounds.

(i) (ii) (iii)

(a) *(b)

(c) (d)

Comprehension for Q. No 03 & 04 :

03.M The correct order of acidic strength of underhead H is :

(a) III > I > II > IV (b) I > II > IV > III (c) II > I > III > IV *(d) I > II > III > IV
04.M The correct order of bond energy of the marked C – H bond in homolysis is :
(a) a > b > c > d *(b) d > c > b > a (c) c > b > d > a (d) d > c > a > b
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 05.M Which of the following 3° alcohol cannot be prepared from reaction of an ester with
excess of Grignard reagent ?
OH OH
(a) *(b)

OH OH
*(c) (d)

06.M Choose the correct option(s) among the following statement(s).

I
*(a) will react more readily than I for SN2 reaction

I
(b) will react more readily than Cl for SN1 reaction

*(c) CH2 Br will react more readily than Br for S 2 reaction

N

*(d) Cl will react more readily than I for E2 reaction

07.M Rate of Biomolecular ellimination (E2) reaction for the following :

(i) (ii)

(a) same for both conformers (b) i > ii

*(c) ii > i
(d) Can’t say anything about rate of E2 reaction
08.M (A) is Ketooctose of formula CnH2nOn . (A) on reduction with H2 – Ni gives (B). Which
of the following is/are correct :
*(a) (B) contains six chiral carbons.
*(b) Three moles of (B) on reaction with excess Ac2O gives a product (C) whose mo-
lecular weight is 336 greater than that of (B).
*(c) Two moles of (A) on reaction with excess Ac2O gives a product (D) whose molecu-
lar weight is 294 greater than that of (A).
*(d) The number of position isomers of (A) are two each containing 5 chiral carbons.

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 09.M Which of the following is /are correct :
*(a) D-Erythrose on reduction with H2–Ni gives Meso product.
*(b) D-Arabinose on reduction with H2 – Ni gives optically active product.
*(c) D-xylose on reduction with H2–Ni gives Meso product.
*(d) D-Galactose on reduction with H2–Ni gives Meso product.
10.M Which of the following is /are Isomers of D-Glucose :
*(a) D-Allose *(b) L-Altrose *(c) D-Gulose (d) L-Lyxose
11.M The number of chiral carbons in open chain structure of D-Ribulose are equal to the
number of chiral carbons in :
(a) Lactic acid *(b) Tartaric acid (c) Acetadol (d) Mesityl oxide
12.M A decasaccharide (A) {CxHyOz} on hydrolysis gives Ribose and arabinose in 1 : 2 mo-
lar ratio and glucose, fructose, galactose, Lyxose in 1 : 1 : 2 : 3 molar ratio. Which of
the following is /are correct :
*(a) ‘x’ is equal to atomic number of one of the noble gas element.
*(b) ‘y’ is equal to atomic number of first Actinide metal.
(c) ‘z’ is equal to the atomic number of metal just below Fe in long form of periodic
table.
*(d) | x + 2y – 5z | = perfect square .
13.M Which of the following pairs form the same osazone ?
*(a) Glucose and Fructose (b) Glucose and Galactose
(c) Glucose and Arabinose (d) Idose , Sorbose
14.M The order of acidity of position X, Y and Z is :

*(a) X > Y > Z (b) Y > X > Z (c) Z > X > Y (d) X > Z > Y
15.M All carbohydrates
*(a) are optically active
(b) give blue-black complex with iodine solution
(c) are soluble in water as there are too many hydroxyl groups
(d) belonging to D-family are dextro-rotatory

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