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Culture Documents
DOI 10.1007/s13201-013-0077-2
ORIGINAL ARTICLE
R. K. Somashekar
Received: 7 October 2012 / Accepted: 2 January 2013 / Published online: 24 January 2013
Ó The Author(s) 2013. This article is published with open access at Springerlink.com
Abstract The present work aims at assessing the water Keywords Sankey tank Mallathahalli lake
quality index (WQI) in the surface water of Sankey tank Water quality index SAR Percent sodium
and Mallathahalli lake situated in Bangalore Urban district
by monitoring three sampling locations within Sankey tank
(viz., A, B and C) and Mallathahalli lake (viz., Inlet, Centre Introduction
and outlet) for a period of 3 months from March to May
2012. The surface water samples were subjected to com- Lakes and tanks are known to be ecological barometers of
prehensive physico-chemical analysis involving major the health of a city as they regulate the micro-climate of
cations (Ca2?, Mg2?, Na?, K?, Fe2?), anions (HCO3-, any urban center (Benjamin et al. 1996), thereby influ-
Cl-, SO42-, NO3-, F-, PO43-) besides general parameters encing the life of the people adjacent to it. The quality of
(pH, EC, TDS, alkalinity, total hardness, DO, BOD, COD, surface water in an inland water bodies have a profound
CO2, SiO2, colour, turbidity). For calculating the WQI, 14 effect on the ground water table and ground water quality
parameters namely, pH, electrical conductivity, total dis- of the nearby aquifers due to existence of direct interaction
solved solids, total hardness, alkalinity, calcium, magne- between surface and ground water. Lakes have a great
sium, sodium, potassium, chloride, sulphate, nitrate, significance environmentally due to reasons such as
fluorides and iron were considered. SAR values indicated (a) sources of water: surface and groundwater recharge and
that both Sankey tank and Mallathahalli lake waters are discharge, for drinking and irrigation, (b) supports liveli-
excellent (S1) for irrigation, while electrical conductivity hoods, lung space of clear and cool air, (c) food and
values classified these lake water, respectively under nutrition, (d) act as flood control and stream flow mainte-
medium salinity (C2) and high (C3) salinity category. nance, (e) recreation—education, boating, swimming,
Correlation between SAR and electrical conductivity walking and jogging on the lake bund, (f) lakes are natural
revealed that Sankey tank water is C2S1 (medium salinity- infrastructure for climate change adaptation and biogeo-
low sodium) type while Mallathahalli lake water is C3S1 logical cycles, (g) pisciculture, (h) wildlife habitat, espe-
(high salinity-low sodium) type. Sankey tank and Malla- cially fishes and birds, (i) rain water harvesting and,
thahalli lake water were, respectively hard and very hard in (j) emergency water supply for firefighting.
nature. Further, it is apparent from WQI values that Sankey The environmental conditions of any lake system
tank water belongs to good water class with WQI values depend upon the nature of that lake and its exposure to
ranging from 50.34 to 63.38. The Mallathahalli lake water various environmental factors. Hence, surface water qual-
with WQI value ranging from 111.69 to 137.09, fall under ity depends not only on natural processes (precipitation
poor water category. inputs, erosion, and weathering of crustal material, etc.) but
also on anthropogenic influences (urban, industrial, and
agricultural activities) (Papatheodorou et al. 2006). Their
P. Ravikumar (&) M. Aneesul Mehmood R. K. Somashekar
fragile ecosystem must maintain the state of environmental
Department of Environmental Science, Bangalore University,
Bangalore 560056, India equilibrium with the existing surroundings particularly
e-mail: prakruthiravi@gmail.com; nisargaravi@gmail.com from a special prospective of human encroachment and
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248 Appl Water Sci (2013) 3:247–261
pollution. However, in recent decades, population growth, (WQI) is one of the most effective tools (Mishra and Patel
agricultural practices and sewage runoff from urban areas 2001; Naik and Purohit 2001; Singh 1992; Tiwari and
have increased nutrient inputs many folds to the level of Mishra 1985) to communicate information on the quality of
their natural occurrence, resulting in accelerated eutrophi- water to the concerned citizens and policy makers as it is
cation (Choudhary et al. 2010; Zan et al. 2010). The lakes an important parameter for the assessment and manage-
and reservoirs, all over India without exception, are in ment of surface/ground waters. Hence, the present work
varying degrees of environmental degradation, might be has been carried out with a focus to evaluate comparatively
due to encroachments, eutrophication (from domestic and the prevailing water quality and potability of two lakes,
industrial effluents) and silt. There has been a quantum Mallathahalli lake (viz., sewage fed lake) and Sankey tank
jump in population during the last century without corre- (viz., rainfed lake) by analyzing physico-chemical param-
sponding expansion of civic facilities resulting in lakes and eters and by estimating WQI.
reservoirs, especially the urban ones, becoming sinks for
contaminants. Most urban and rural lakes have vanished
under this pressure with worldwide environmental con- Study area
cerns (Iscen et al. 2008; Prasanna et al. 2010). However, in
those lakes that could endure, drinking water supply is Bangalore district is situated in the heart of the South-
either substantially reduced or is non-potable, flood Deccan plateau in peninsular India to the South-Eastern
absorption capacity impaired, biodiversity threatened and corner of Karnataka State between the latitudinal parallels
there is diminished fish production (Zhang et al. 2009). The of 12°390 N and 13°180 N and longitudinal meridians of
main reasons which resulted in impaired conditions of the 77°220 E and 77°520 E at an average elevation of about
lakes could be categorized into two classes namely, 920 m (3,020 ft) covering an areal extent of land of about
(a) pollutants entering from fixed point sources (viz., 2,174 km2 (Bangalore rural and urban districts). Bangalore
nutrients from wastewater, from municipal and domestic district (Bangalore rural and urban districts) borders with
effluents; organic, inorganic and toxic pollutants from Kolar and Chikkaballapur in the northeast, Tumkur in the
industrial effluents and storm water runoff) (b) pollutants northwest, Mandya and Ramanagaram in the southeast and
entering from non-point sources (viz., nutrients through Mysore and Tamil Nadu in the south. Bangalore urban
fertilizers, toxic pesticides and other chemicals, mainly district is bounded in all the directions by Bangalore rural
from agriculture runoff; organic pollution from human district except in southeast, where the district is bounded
settlements spread over areas along the periphery of the by Dharmapuri district of Tamil Nadu state. Bangalore
lakes and reservoirs). urban district divided into three taluks namely Bangalore
Developmental pressures and increasing human popu- North, Bangalore South and Anekal (Fig. 1). Major part of
lation has made the lakes of the study area vulnerable to the district (viz., Bangalore north and South taluks) is
sewage flow, solid waste dumping, etc., in turn exerting drained by Shimsha and Kanva rivers of Cauvery basin
pressure on the percolation and infiltration processes (Catchment area of 468 km2, which includes Nelamangala
responsible for the groundwater recharge (Ravikumar et al. and Magadi taluks of Bangalore rural also). Anekal taluk is
2011). The municipal effluents from such natural drains drained by South Pennar river of Ponnaiyar basin, which
leading to tanks and lakes deteriorated the quality of these takes its birth from Nandi hills and flows toward south
water bodies. Sedimentation of the pollutants has not only (Catchment area is 2,005 km2 which covers Devanahalli
reduced the surface area of the water which in turn has and Hoskote taluks of Bangalore rural district also). Ban-
increased evaporation rate, but also reduced ground water galore is considered to be climatically a well favoured
levels on account of poor permeability with more and more district. The climate of the district is classed as the sea-
silt, clay deposits, trash and toxic waste accumulation in sonally dry tropical Savanna climate with four seasons. The
them year after year. In spite of the fact that nutrient main features of the climate of Bangalore are agreeable and
enrichment stimulates the growth of plants (algae as well as favourable range of temperatures. The dry season with
higher plants), nutrient enrichment in lakes is considered as clear bright summer weather (December to February), is
one of the major environmental problems in many coun- characterized by high temperatures (March to May), fol-
tries (Oczkowski and Nixon 2008), ultimately leading to lowed by the South-West monsoon season (June to Sep-
deterioration of water quality and degradation of entire tember) and post-monsoon/retreating monsoon season
ecosystems (Yu et al. 2010). Hence, periodic monitoring (October to November). Two rainy seasons come one after
and assessment of water quality helps to develop man- the other but with opposite wind regimes, corresponding to
agement strategies to control surface water pollution the south-west and north-east monsoons. Typical mon-
(Shuchun et al. 2010) in spite of increasing urbanization soonal climate prevails in the district with major contri-
and anthropogenic pressure on them. Water quality index bution of rainfall from southwest monsoon. Contribution
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Appl Water Sci (2013) 3:247–261 249
from south-west monsoon and north-east monsoon A. Sankey tank, a man-made freshwater lake or tank,
respectively account for 54.18 and 26.53 % of the total situated in the western part of Bangalore in the
rainfall in addition to the significant contribution of middle of the suburbs of Malleshwaram, Vyalikaval
18.53 % from pre-monsoon showers. In general, pre-humid and Sadashiva Nagar, lying in an highly urbanized
to semi-arid climatic conditions prevail in the district. The area. The lake covers a surface area of about 15 ha
mean annual rainfall is 859.6 mm, with three different (37.1 acres) and catchment area of 1.254 km (0.8
rainy periods covering 8 months of the year. June to Sep- mile) with one island within its premise. It is a part
tember being rainy season receives 54 % of the total annual of Vrishabhavathi valley in the Bangalore urban
rainfall in the S–W monsoon period and 241 mm during district with rainfall being primary inflow into it and
the N-E monsoon period (October–November). Bangalore has got one outlet on the southern corner. At its
records high temperatures during April with daily mean widest, the tank has a width of 800 m (2,624.7 ft)
temperatures of 33.4 °C and mean daily minimum in the and a maximum depth of 9.26 m (30.4 ft). The
month of December at 25.7 °C, as the coolest month. The highest point was 929.8 m above mean sea level.
mean monthly relative humidity is the lowest during the The tank was also known as Gandhadhakotikere, as
month of March at 44 % and records highest between the the Government Sandalwood Depot is located near
months of June and October at 80–85 %. The surface the lake. This tank was recently brought under
winds in Bangalore have seasonal characteristics with the restoration programme of BBMP (Bruhat Bangalore
easterly components predominating during one period Mahanagara Palike) by Bangalore Water Supply and
followed by the westerly in the other. The high wind speed Sewerage Board (BWSSB) with other major imple-
averages 17 km/h during the westerly winds in the month mentations such as removing encroachments, alum
of July and a minimum of 8–9 km/h during the months of purification treatment to absorb toxic elements and
April and October. germs, nursery towards the north, paved walkways,
Two surface water bodies namely Mallathahalli lake landscaped parks, special tank for idol immersion
(viz., sewage fed lake) and Sankey tank (viz., rainfed lake) during Ganesh Chaturthi festival and restoration of
were opted for the present study (Fig. 1). swimming pool. The threats posed to the survival of
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250 Appl Water Sci (2013) 3:247–261
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Appl Water Sci (2013) 3:247–261 251
for drinking purposes (Table 2). The highest weight of b. Computing the relative weight (Wi) of each parameter
5 was assigned to parameters which have the major using Eq. 1. Table 2 present the weight (wi) and calcu-
effects on water quality and their importance in quality lated relative weight (Wi) values for each parameter.
(viz., NO3-, F- and TDS) and a minimum of 2 was c. A quality rating scale (qi) for each parameter is
assigned to parameters which are considered as not computed by dividing its concentration in each water
harmful (Ca2?, Mg2?, K?). sample by its respective standard according to the
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252 Appl Water Sci (2013) 3:247–261
Table 2 The weight and relative weight of each of the physico- and Mallathahalli lake (assigned as inlet, centre, and outlet)
chemical parameters used for WQI determination and each sample was analyzed thrice for the period March,
Parameters BIS Weight Relative April and May 2012. The minimum, maximum and mean
desirable (wi) weight (Wi) analytical results for each parameter for each period of
limit (1998) analysis (i.e., March, April and May 2012) for both Sankey
pH 8.5 3 0.0698 tank and Mallathahalli lake are summarized in Tables 3
EC 2,000 3 0.0698 and 4, respectively.
Total dissolved solids 1,000 5 0.1163 pH is a numerical expression that indicates the degree to
(TDS) which water is acidic or alkaline, with the lower pH value
Total alkalinity (TA) 200 2 0.0465 tends to make water corrosive and higher pH provides taste
Total hardness (TH) 300 3 0.0698 complaint and negative impact on skin and eyes (Rao and
Calcium 75 2 0.0465 Rao 2010). The mean pH of Sankey tank water was
Magnesium 30 2 0.0465 8.76 ± 0.73 (March 2012), 8.54 ± 0.40 (April 2012) and
Sodium 100 3 0.0698 8.30 ± 0.18 (May 2012) while the mean pH of Malla-
Potassium 10 2 0.0465 thahalli lake water was 8.65 ± 0.34 (March 2012),
Chloride 250 3 0.0698 8.78 ± 0.73 (April 2012) and 8.94 ± 0.53 (May 2012).
Sulphate 200 3 0.0698 Garg et al. (2010) opines that pH range between 6.0 and 8.5
Nitrate 45 5 0.1163 indicates the productive nature of any water body. But, pH
Fluoride 1 5 0.1163
of both the lakes in the present study crossed the permis-
Iron 0.3 2 0.0465
sible limit of 6.5–8.5 (BIS 1998).
P P Electrical conductivity of water is a direct function of its
- wi = 43 Wi = 1.000
total dissolved salts (Harilal et al. 2004) and is used as an
index to represent the total concentration of soluble salts in
guidelines laid down by BIS (1998) and then, the result water (Purandara et al. 2003; Gupta et al. 2008). Excess EC
was multiplied by 100 using Eq. 2. Finally, for com- lead to scaling in boilers, corrosion and quality degradation
puting the WQI, the water quality sub-index (SIi) for of the product. The mean conductivity values was
each chemical parameter is first determined, which is 462.56 ± 68.82 lS/cm (March 2012), 482.22 ± 79.06
then used to determine the WQI as per the Eqs. 3 and 4. lS/cm (April 2012) and 384.67 ± 41.80 lS/cm (May
wi 2012) in Sankey tank water and 1,762.56 ± 79.20 lS/cm
Wi ¼ Pn ð1Þ
n¼1 wi (March 2012), 1,777.89 ± 32.62 lS/cm (April 2012) and
where Wi is the relative weight, wi is the weight of each 1853.33 ± 66.56 lS/cm (May 2012) in Mallathahalli lake
parameter and n is the number of parameters. water. Conductivity value of Sankey tank and Mallathahalli
lake water were well within the permissible limit of
Ci 3,000 lS/cm. Relatively higher EC values were recorded
qi ¼ 100 ð2Þ
Si in the Mallathahalli Lake water, attributed to the high
where qi = quality rating, Ci = concentration of each chem- degree of anthropogenic activities such as waste disposal,
ical parameter in each water sample in mg/L, Si = Indian sewage inflow and agricultural runoff (Pandit 2002).
drinking water standard (BIS 1998) for each chemical Classification of water based on Electrical conductivity
parameter in mg/L except for conductivity (lS/cm) and pH. illustrates that the Sankey tank water belongs to medium
salinity class (C2) and Mallathahalli lake water to high
SI ¼ Wi qi ð3Þ (C3) salinity category (Table 5).
X
n Total dissolved solids (TDS) mainly consists of inor-
WQI ¼ SIi ð4Þ ganic salts such as carbonates, bicarbonates, chlorides,
i¼1
sulphates, phosphates and nitrates of calcium, magnesium,
where SIi is the sub-index of ith parameter; qi is the rating sodium, potassium, iron etc. and small amount of organic
based on concentration of ith parameter and n is the matter. The average concentration of total dissolved solids
number of parameters. in Sankey tank water was 286.78 ± 42.67 mg/L (March
2012), 298.98 ± 49.02 mg/L (April 2012) and 238.49 ±
25.91 mg/L (May 2012) while in Mallathahalli lake water,
Results and discussion it was 1092.78 ± 49.10 mg/L (March 2012), 1102.29 ±
20.23 mg/L (April 2012) and 1149.07 ± 41.27 mg/L (May
The samples were collected from each of the three different 2012). TDS values of Sankey tank and Mallathahalli lake
sites within the Sankey tank (earmarked as A, B, and C) water were below the BIS permissible limit of 2,000 mg/L.
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Appl Water Sci (2013) 3:247–261 253
Table 3 Analytical results of Sankey tank water from March 2012 to May 2012
Parameters March 2012 April 2012 May 2012
Mean SD Min Max Mean SD Min Max Mean SD Min Max
DO 7.83 1.11 6.30 9.01 7.70 1.16 5.80 9.01 6.28 0.42 5.60 6.90
pH 8.76 0.73 7.52 9.63 8.54 0.40 8.00 9.30 8.30 0.18 8.00 8.60
EC 462.56 68.82 391.00 554.00 482.22 79.06 439.00 692.00 384.67 41.80 329.00 430.00
TDS 286.78 42.67 242.42 343.48 298.98 49.02 272.18 429.04 238.49 25.91 203.98 266.60
Colour 8.89 2.20 5.00 10.00 10.00 0.00 10.00 10.00 10.00 0.00 10.00 10.00
Turbidity 0.90 0.30 0.10 1.00 1.00 0.00 1.00 1.00 1.00 0.00 1.00 1.00
BOD 8.05 1.18 6.77 10.20 5.78 0.58 5.01 6.51 5.87 0.57 5.30 6.90
COD 71.44 12.32 50.20 85.20 37.94 1.41 35.80 39.50 21.91 3.19 16.40 26.40
Temp 28.19 0.40 27.70 29.10 30.04 0.50 29.10 31.00 30.13 0.39 29.70 31.00
CO2 7.29 0.64 6.20 8.00 7.50 0.60 6.50 8.50 5.99 0.34 5.40 6.50
TA 158.98 20.64 131.50 196.10 359.78 40.65 328.00 452.00 318.00 18.85 285.00 336.00
TH 148.90 14.18 128.20 168.20 138.93 5.59 130.20 147.30 122.14 5.09 114.20 130.30
CaH 92.32 1.37 91.00 95.20 57.62 6.05 47.21 63.20 38.33 5.73 32.00 46.50
2?
Ca 36.93 0.55 36.40 38.08 23.05 2.42 18.88 25.28 15.33 2.29 12.80 18.60
MgH 56.58 14.33 37.00 76.20 81.31 9.16 71.00 95.29 83.81 3.92 78.40 89.80
Mg2? 13.80 3.50 9.03 18.59 19.84 2.24 17.32 23.25 20.45 0.96 19.13 21.91
Cl- 55.86 12.53 42.91 71.97 141.66 9.44 127.90 154.30 112.39 6.12 100.20 119.00
NO3- 5.04 0.43 4.31 5.68 18.20 3.44 14.20 23.50 20.23 4.46 14.00 26.20
PO43- 8.86 0.46 8.20 9.50 9.59 0.97 8.60 11.50 9.48 1.51 6.50 11.20
2-
SO4 28.83 3.70 21.21 33.33 29.69 2.84 25.80 33.50 25.03 1.95 20.40 26.30
F? 0.32 0.07 0.20 0.40 0.42 0.22 0.10 0.80 0.47 0.21 0.10 0.80
K? 31.59 1.73 17.52 42.50 36.01 0.31 30.90 40.90 29.58 1.95 22.80 31.20
Na? 45.01 3.58 41.60 51.90 55.79 5.07 50.80 65.30 50.93 1.78 48.00 52.80
SiO2 11.38 0.77 10.50 12.50 11.99 0.44 11.30 12.50 10.39 0.61 9.50 11.50
2?
Fe 0.12 0.01 0.11 0.13 0.17 0.06 0.10 0.30 0.16 0.05 0.10 0.20
HCO3- 193.95 25.18 160.43 239.24 438.93 49.60 400.16 551.44 387.96 22.99 347.70 409.92
Percent sodium 34.36 4.82 30.56 41.67 39.52 1.77 37.67 42.39 40.89 1.50 38.80 43.47
SAR 1.61 0.19 1.44 1.94 2.06 0.18 1.85 2.34 2.00 0.08 1.86 2.12
RSC 0.20 0.47 -0.41 0.86 4.41 0.77 3.74 6.09 3.91 0.31 3.31 4.28
WQI 50.34 6.38 41.66 57.46 63.38 3.56 56.85 67.59 56.54 2.98 52.65 63.21
DO levels in lakes vary according to their trophic levels, 9.26 ± 0.53 mg/L (March 2012), 8.88 ± 0.39 mg/L (April
and depletion of DO in water probably is the most frequent 2012) and 7.54 ± 0.76 mg/L (May 2012). As per USPH,
result of water pollution (Srivastava et al. 2009). Dissolved the DO should be between 4 and 6 mg/L (De 2003) and if
oxygen is the maximum concentration of oxygen that can DO levels in water drop below 5.0 mg/L, many life forms
dissolve in water. As a function of water temperature, it may are put under stress (Raveen and Daniel 2010). The mean
vary from place to place and time to time. DO is an DO values in Sankey tank and Mallathahalli lake water was
important parameter to assess the waste assimilative above the desirable limit of 6 mg/L.
capacity of the waters (Rao and Rao 2010). It fluctuate The average colour of Sankey tank water was 8.89 ±
seasonally, daily and with variation in water temperature 2.20 hazens (March 2012), 10.0 ± 0.0 hazens (April 2012)
(Rao and Rao 2010; Wavde and Arjun 2010), mainly due to and 10.0 ± 0.0 hazens (May 2012) while in Mallathahalli
consumption of DO owing to respiration by aquatic ani- lake water, it was 13.33 ± 5.0 hazens (March 2012),
mals, decomposition of organic matter, and various chem- 15.0 ± 7.50 hazens (April 2012) and 20.0 ± 0.0 hazens
ical reactions. The mean DO concentration in Sankey tank (May 2012). The colour of Mallathahalli lake and Sankey
water ranged between 7.83 ± 1.11 mg/L (March 2012), tank water were below the permissible limit of 25 hazens
7.70 ± 1.16 mg/L (April 2012) and 6.28 ± 0.42 mg/L (BIS 1998), though colour of Sankey tank was close to the
(May 2012) while in Mallathahalli lake water, it was limit.
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254 Appl Water Sci (2013) 3:247–261
Table 4 Analytical results of Mallathahalli lake water from March 2012 to May 2012
Parameters March 2012 April 2012 May 2012
Mean SD Min Max Mean SD Min Max Mean SD Min Max
DO 9.26 0.53 8.85 10.38 8.88 0.39 8.32 9.51 7.54 0.76 6.50 8.50
pH 8.65 0.34 8.12 9.10 8.78 0.73 7.50 9.51 8.94 0.53 8.10 9.60
EC 1762.56 79.20 1612.00 1870.00 1777.89 32.62 1712.00 1812.00 1853.33 66.56 1792.00 2000.00
TDS 1092.78 49.10 999.44 1159.40 1102.29 20.23 1061.44 1123.44 1149.07 41.27 1111.04 1240.00
Colour 13.33 5.00 10.00 20.00 15.00 7.50 5.00 20.00 20.00 0.00 20.00 20.00
Turbidity 1.00 0.00 1.00 1.00 5.00 0.00 5.00 5.00 5.00 0.00 5.00 5.00
BOD 8.32 0.85 6.51 9.38 7.58 0.70 6.25 8.50 8.84 0.48 8.30 9.40
COD 153.78 27.40 123.00 195.00 40.70 2.63 36.21 44.21 40.48 2.04 37.50 43.20
Temp 28.72 0.97 28.00 30.20 29.98 0.83 28.50 31.20 30.59 0.37 30.00 31.10
CO2 6.11 0.58 5.20 7.20 7.98 1.21 6.20 9.50 6.51 0.93 5.10 7.70
TA 655.89 211.03 400.00 920.00 736.67 48.33 648.00 801.00 556.22 53.44 480.00 605.00
TH 517.22 75.52 420.00 612.00 553.00 32.02 512.00 592.00 429.22 62.41 355.00 508.00
CaH 403.44 55.86 316.00 488.00 366.08 17.36 330.50 388.00 330.56 17.53 300.00 350.00
2?
Ca 161.38 22.34 126.40 195.20 146.43 6.95 132.20 155.20 132.22 7.01 120.00 140.00
MgH 113.78 49.50 51.00 164.50 186.92 37.90 137.50 261.50 98.67 74.03 7.00 175.00
Mg2? 27.76 12.08 12.44 40.14 45.61 9.25 33.55 63.81 24.07 18.06 1.71 42.70
Cl- 240.22 21.17 200.00 265.00 380.77 40.88 339.00 469.04 295.22 55.67 221.00 356.00
NO3- 17.72 2.99 10.01 19.81 33.09 4.92 27.39 40.21 30.39 1.73 28.40 33.50
PO43- 14.35 4.26 8.50 18.90 37.64 2.97 32.66 41.00 40.91 2.56 36.50 45.60
2-
SO4 41.60 9.52 28.80 56.31 90.24 10.01 75.39 102.00 88.90 4.33 81.40 95.40
F? 0.57 0.12 0.40 0.80 0.73 0.13 0.50 0.90 0.79 0.15 0.50 1.00
K? 22.00 1.79 12.40 30.10 40.24 0.22 38.60 43.00 37.20 0.26 31.50 41.00
Na? 178.56 37.35 120.00 231.00 159.67 27.14 123.00 191.00 138.56 28.03 100.00 172.00
SiO2 15.77 0.48 14.80 16.40 16.91 0.52 16.20 17.80 18.26 0.38 17.50 18.70
2?
Fe 0.14 0.02 0.11 0.18 0.26 0.03 0.20 0.30 0.32 0.03 0.29 0.38
HCO3- 800.18 257.46 488.00 1122.40 898.73 58.96 790.56 977.22 678.59 65.19 585.60 738.10
Percent sodium 41.38 5.06 30.95 45.70 36.31 4.24 29.69 41.18 38.53 1.76 35.49 41.01
SAR 3.42 0.63 2.23 4.13 2.96 0.50 2.22 3.50 2.89 0.39 2.31 3.38
RSC 2.78 5.68 -4.23 10.01 3.67 0.76 2.70 5.16 2.54 0.52 1.90 3.65
WQI 111.69 4.61 105.41 118.09 137.09 6.01 126.98 146.03 122.38 9.78 109.08 133.38
Table 5 Classification of
Sl. Type of water Suitability for irrigation
irrigation water based on
No
electrical conductivity
1 Low salinity water (C1) conductivity Suitable for all types of crops and all kinds of soil.
between 100 and 250 lS/cm Permissible under normal irrigation practices except
in soils of extremely low permeability
2 Medium salinity water (C2) conductivity Can be used, if a moderate amount of leaching occurs.
between 250 and 750 lS/cm Normal salt tolerant plants can be grown without
much salinity control
3 High salinity water (C3) conductivity Unsuitable for soil with restricted drainage. Only high-
between 750 and 2,250 lS/cm salt tolerant plants can be grown
4 Very high salinity (C4) conductivity more Unsuitable for irrigation
than 2,250 lS/cm
Turbidity depends on the nature of the water bodies such The mean turbidity of Sankey tank water was 0.90 ± 0.30
as river under flood conditions, lake or other water existing NTU (March 2012), 1.0 ± 0.0 NTU (April 2012) and
under relatively quiescent conditions, wherein, most of the 1.0 ± 0.0 NTU (May 2012) while in Mallathahalli lake
turbidity is due to colloidal and extremely fine dispersions. water, it was 1.0 ± 0.0 NTU (March 2012), 5.0 ± 0.0
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Appl Water Sci (2013) 3:247–261 255
NTU (April 2012) and 5.0 ± 0.0 NTU (May 2012). The 2012) and 556.22 ± 53.44 mg/L (May 2012). It is evident
turbid nature of Sankey tank and Mallathahalli lake water that alkalinity values in Sankey tank water were above the
was well below the permissible limit of 10 NTU. permissible limit of 600 mg/L (BIS 1998) during April and
The average temperature of Sankey tank water was May 2012. In contrast, Mallathahalli lake water showed
28.19 ± 0.4 °C (March 2012), 30.04 ± 0.5 °C (April 2012) alkalinity value higher than the desirable limit for all the
and 30.13 ± 0.39 °C (May 2012) while in Mallathahalli months.
lake water, it was 28.72 ± 0.97 °C (March 2012), 29.98 ± Total hardness values was 148.90 ± 14.18 mg/L (March
0.83 °C (April 2012) and 30.59 ± 0.37 °C (May 2012). 2012), 138.93 ± 5.59 mg/L (April 2012) and 122.14 ±
BOD and COD are important parameters that indicate 5.09 mg/L (May 2012) and in Mallathahalli lake water, it
contamination with organic wastes (Siraj et al. 2010). was 517.22 ± 75.52 mg/L (March 2012), 553.00 ±
Biochemical oxygen demand (BOD) is the amount of 3!2.02 mg/L (April 2012) and 429.22 ± 62.41 mg/L (May
oxygen required by bacteria while stabilizing decompos- 2012). Total hardness values in Sankey tank and Malla-
able organic matter under aerobic conditions (Sawyer and thahalli lake water was below the permissible limit of
McCarty 1978). It is required to assess the pollution of 600 mg/L (BIS 1998). The degree of hardness of drinking
surface and ground water where contamination occurred water has been classified (WHO 2004) in terms of its
due to disposal of domestic and industrial effluents. equivalent CaCO3 concentration (Table 6) and accordingly,
According to WHO drinking water standard, BOD should both Sankey tank and Mallathahalli lake water respectively,
not exceed 6 mg/L (De 2003). BOD values in Sankey tank belong to hard and very hard category (Sawyer and
water ranged from 8.05 ± 1.18 mg/L (March 2012), McCarthy 1967).
5.78 ± 0.58 mg/L (April 2012) and 5.87 ± 0.57 mg/L In Sankey tank, the calcium hardness values of 92.32 ±
(May 2012) while in Mallathahalli lake water, it was 1.37 mg/L (March 2012), 57.62 ± 6.05 mg/L (April 2012)
8.32 ± 0.85 mg/L (March 2012), 7.58 ± 0.70 mg/L (April and 38.33 ± 5.73 mg/L (May 2012), were well below the
2012) and 8.84 ± 0.48 mg/L (May 2012). It is evident permissible limit of 200 mg/L (BIS 1998) except for
from the results that BOD values of both the lakes were March 2012. In Mallathahalli lake water, it was 403.44 ±
well above the standard limit of 3 mg/L. 55.86 mg/L (March 2012), 366.08 ± 17.36 mg/L (April
Chemical oxygen demand (COD) determines the oxy- 2012) and 330.56 ± 17.53 mg/L (May 2012), which were
gen required for chemical oxidation of most organic matter very high compared to their permissible limit.
and oxidizable inorganic substances with the help of strong The magnesium hardness in Sankey tank water was
chemical oxidant. In conjunction with the BOD, the COD 56.58 ± 14.33 mg/L (March 2012), 81.31 ± 9.16 mg/L
test is helpful in indicating toxic conditions and the pres- (April 2012) and 83.81 ± 3.92 mg/L (May 2012), while in
ence of biologically resistant organic substances (Sawyer Mallathahalli lake water, it was 113.78 ± 49.50 mg/L
and McCarty 1978). COD values in Sankey tank water was (March 2012), 186.92 ± 37.90 mg/L (April 2012) and
71.44 ± 12.32 mg/L (March 2012), 37.94 ± 1.41 mg/L 98.67 ± 74.03 mg/L (May 2012).
(April 2012) and 21.91 ± 3.19 mg/L (May 2012). In Ma- The dissolved CO2 in Sankey tank water was 7.29 ±
llathahalli lake water, it was 153.78 ± 27.40 mg/L (March 0.64 mg/L (March 2012), 7.50 ± 0.60 mg/L (April 2012)
2012), 40.70 ± 2.63 mg/L (April 2012) and 40.48 ± and 5.99 ± 0.34 mg/L (May 2012), while in Mallathahalli
2.04 mg/L (May 2012). Khuhawari et al. (2009) associated lake water, it was 6.11 ± 0.58 mg/L (March 2012),
higher values of COD with increased anthropogenic pres- 7.98 ± 1.21 mg/L (April 2012) and 6.51 ± 0.93 mg/L
sures on lakes and it is evident from the results that COD (May 2012). Similarly, the mean concentration of silica in
values of both the lakes were very high, an indication of Sankey tank water was 11.38 ± 0.77 mg/L (March 2012),
flooded organic matter. 11.99 ± 0.44 mg/L (April 2012) and 10.39 ± 0.61 mg/L
Alkalinity is a measure of the ability of water to neu- (May 2012), while in Mallathahalli lake water, it was
tralize acids. It is due to the presence of bicarbonates, car- 15.77 ± 0.48 mg/L (March 2012), 16.91 ± 0.52 mg/L
bonates and hydroxide of calcium, magnesium, sodium, (April 2012) and 18.26 ± 0.38 mg/L (May 2012). It is
potassium and salts of weak acids and strong bases as
borates, silicates, phosphates, etc. Large amount of alka- Table 6 Classification of water depending upon the hardness (WHO
2004)
linity imparts a bitter taste, harmful for irrigation as it
damages soil and hence reduces crop yields (Sundar and Classification Hardness range (mg/L)
Saseetharan 2008). In Sankey tank water, the total alkalinity
Soft 0–75
values was 158.98 ± 20.64 mg/L (March 2012), 358.78 ±
Medium hard 75–150
40.65 mg/L (April 2012) and 318.00 ± 18.85 mg/L (May
Hard 150–300
2012) and in Mallathahalli lake water, it was 655.89 ±
Very hard Above 300
211.03 mg/L (March 2012), 736.67 ± 48.33 mg/L (April
123
256 Appl Water Sci (2013) 3:247–261
evident that Mallathahalli lake water showed higher con- composition (viz., major anions and cations) in Sankey
centration of silica, might be due to accumulation of more tank and Mallathahalli lake are presented by Figs. 3 and 4.
of sediment/silt in comparison with Sankey tank.
Chemistry of cations
Major Ion Chemistry
The mean concentration of calcium in Sankey tank water was
In Mallathahalli lake water, the predominant cation trend 36.93 ± 0.55 mg/L (March 2012), 23.05 ± 2.42 mg/L
was in the order of Ca2? [ Na? [ Mg2? [ K? with cal- (April 2012) and 15.33 ± 2.29 mg/L (May 2012), while in
cium being dominant cation and the predominant anion Mallathahalli lake water, it was 161.38 ± 22.34 mg/L
trend was in the order of HCO3- [ Cl- [ SO42-, with (March 2012), 146.43 ± 6.95 mg/L (April 2012) and
bicarbonate being the dominant anion (Fig. 2). Contrast to 132.22 ± 7.01 mg/L (May 2012). It is apparent that Malla-
this, in Sankey tank water, the predominant cation trend thahalli lake water showed higher calcium content compared
was in the order Na? [Mg2? [ Ca2? [ K? with sodium to Sankey tank water. However, calcium content in both the
being dominant cation and the predominant anion trend lake water was below the permissible limit of 200 mg/L.
was HCO3- [ Cl- [ SO42-, with bicarbonate being the The average magnesium values in Sankey tank water was
dominant anion (Fig. 2). Spatial trend of water 13.80 ± 3.50 mg/L (March 2012), 19.84 ± 2.24 mg/L
Fig. 2 Schoeller diagrams illustrating major ionic dominance in the surface water of Mallathahalli lake and Sankey tank
Fig. 3 Radial diagram showing spatial trend in water composition (viz., major anions and cations) of Sankey tank water
123
Appl Water Sci (2013) 3:247–261 257
Fig. 4 Radial diagram showing spatial trend in water composition (viz., major anions and cations) of Mallathahalli lake water
(April 2012) and 20.45 ± 0.96 mg/L (May 2012), while in Chemistry of anions
Mallathahalli lake water, it was 27.76 ± 12.08 mg/L
(March 2012), 45.61 ± 9.25 mg/L (April 2012) and The mean bicarbonate values in Sankey tank water was
24.07 ± 18.06 mg/L (May 2012). It is evident that Sankey 193.95 ± 25.18 mg/L (March 2012), 438.93 ± 49.60 mg/L
tank and Mallathahalli lake water had magnesium con- (April 2012) and 387.96 ± 22.99 mg/L (May 2012). In
centration within the permissible limit of 100 mg/L. Mallathahalli lake water, it was 800.18 ± 257.46 mg/L
The mean sodium concentration in Sankey tank water (March 2012), 898.73 ± 58.96 mg/L (April 2012) and
was 45.01 ± 3.58 mg/L (March 2012), 55.79 ± 5.07 mg/L 678.59 ± 65.19 mg/L (May 2012). The Mallathahalli lake
(April 2012) and 50.93 ± 1.78 mg/L (May 2012). The water showed higher bicarbonate values compared to
mean sodium value in Mallathahalli lake water was Sankey tank water.
178.56 ± 37.35 mg/L (March 2012), 159.67 ± 27.14 mg/L The average chloride concentration in Sankey tank water
(April 2012) and 138.56 ± 28.03 mg/L (May 2012). It is was 55.86 ± 12.53 mg/L (March 2012), 141.66 ± 9.44
evident that Sankey tank and Mallathahalli lake water mg/L (April 2012) and 112.39 ± 6.12 mg/L (May 2012). In
showed sodium values within the permissible limit of Mallathahalli lake water, it was 240.22 ± 21.17 mg/L
200 mg/L. The average potassium concentration in Sankey (March 2012), 380.77 ± 40.88 mg/L (April 2012) and
tank water was 31.59 ± 1.73 mg/L (March 2012), 36.01 ± 295.22 ± 55.67 mg/L (May 2012). The Mallathahalli lake
0.31 mg/L (April 2012) and 29.58 ± 1.95 mg/L (May water showed higher chloride values compared to Sankey
2012). The mean potassium value in Mallathahalli lake tank water, but both the lake water had chloride values well
water was 22.0 ± 1.79 mg/L (March 2012), 40.24 ± below the permissible limit of 1,000 mg/L.
0.22 mg/L (April 2012) and 37.2 ± 0.26 mg/L (May The mean sulphate concentration in Sankey tank water
2012). Both Sankey tank and Mallathahalli lake water was 28.83 ± 3.70 mg/L (March 2012), 29.69 ± 2.84 mg/L
showed very high potassium content compared to the (April 2012) and 25.03 ± 1.95 mg/L (May 2012). In
permissible limit of 10 mg/L (BIS 1998), favouring the fact Mallathahalli lake water, it was 41.60 ± 9.52 mg/L
that both lakes were eutrophic in condition and higher (March 2012), 90.24 ± 10.01 mg/L (April 2012) and
content of sodium and potassium in freshwaters is due to 88.90 ± 4.33 mg/L (May 2012). Both Sankey tank and
domestic sewage contamination (Bhat et al. 2001). Mallathahalli lake water showed sulphate values below the
The mean ferrous iron (Fe2?) values in Sankey tank permissible limit of 400 mg/L.
water was 0.12 ± 0.01 mg/L (March 2012), 0.17 ± Nitrate concentration in groundwater and surface water is
0.06 mg/L (April 2012) and 0.16 ± 0.05 mg/L (May normally low but can reach high levels as a result of agricul-
2012). The mean ferrous iron values in Mallathahalli lake tural runoff, refuge dump runoffs, or contamination with
water was 0.14 ± 0.02 mg/L (March 2012), 0.26 ± human or animal wastes (Nas and Berktay 2006). The mean
0.03 mg/L (April 2012) and 0.32 ± 0.03 mg/L (May nitrate concentration in Sankey tank water was 5.04 ±
2012). Both Sankey tank and Mallathahalli lake water 0.43 mg/L (March 2012), 18.20 ± 3.44 mg/L (April 2012)
showed mean ferrous iron concentration below the per- and 20.23 ± 4.46 mg/L (May 2012). In Mallathahalli lake
missible limit of 1.0 mg/L (BIS 1998) except for Malla- water, it was 17.72 ± 2.99 mg/L (March 2012), 33.09 ±
thahalli lake water during April 2012. 4.92 mg/L (April 2012) and 30.39 ± 1.73 mg/L (May 2012).
123
258 Appl Water Sci (2013) 3:247–261
Table 7 Classification of
Sl. Types of water and SAR value Quality Suitability for irrigation
irrigation water based on SAR
No
1 Low sodium water (S1) SAR Excellent Suitable for all types of crops and all types of soils,
value: 0–10 except for those crops, which are sensitive to sodium
2 Medium sodium water (S2) Good Suitable for coarse textured or organic soil with good
SAR value: 10–18 permeability. Relatively unsuitable in fine textured
soils
3 High sodium water (S3) SAR Fair Harmful for almost all types of soil; Requires good
value: 18–26 drainage, high leaching gypsum addition
4 Very high sodium water (S4) Poor Unsuitable for irrigation
SAR value: above 26
Both Sankey tank and Mallathahalli lake water showed nitrate given in Table 7, both Sankey tank and Mallathahalli lake
values below the permissible limit of 45 mg/L. water showed mean SAR value below 10, indicating that
The mean phosphate values in Sankey tank water was lake waters are excellent (S1) for irrigation.
8.86 ± 0.46 mg/L (March 2012), 9.59 ± 0.97 mg/L (April
2012) and 9.48 ± 1.51 mg/L (May 2012). In Mallathahalli Residual sodium carbonate
lake water, it was 14.35 ± 4.26 mg/L (March 2012),
37.64 ± 2.97 mg/L (April 2012) and 40.91 ± 2.56 mg/L The sodium hazard also increases, if the water contains a
(May 2012). Both Sankey tank and Mallathahalli lake water high concentration of bicarbonate ion. As the soil solution
showed high phosphate concentration compared to the per- becomes more concentrated, there is a tendency for cal-
missible limit of 0.3 mg/L, illustrating the existence of cium and magnesium to precipitate as carbonates thus,
eutrophic condition in both the lakes. PO43- enters the lakes increasing the relative proportion of sodium as a conse-
through domestic wastewater, accounting for the accelerated quence. RSC can be calculated using the equation below
eutrophication (Vyas et al. 2006) and the augmented con- employing data of alkalinity, calcium and magnesium.
centration of PO43- and NO3–N in lakes resulted in enhanced RSC ¼ ðAlkalinity 0:0333Þ ðCa2þ 2þ
meq þ Mgmeq Þ ð6Þ
phytoplankton productivity (Pandit and Yousuf 2002).
The mean fluoride concentration in Sankey tank water where concentration of Ca2? and Mg2? are in meq/L and
was 0.32 ± 0.07 mg/L (March 2012), 0.42 ± 0.22 mg/L alkalinity values in mg/L. The mean RSC concentration in
(April 2012) and 0.47 ± 0.21 mg/L (May 2012). In Ma- Sankey tank water was 0.20 ± 0.47 (March 2012), 4.41 ±
llathahalli lake water, it was 0.57 ± 0.12 mg/L (March 0.77 (April 2012) and 3.91 ± 0.31 (May 2012). In Malla-
2012), 0.73 ± 0.13 mg/L (April 2012) and 0.79 ± thahalli lake water, it was 2.78 ± 5.68 (March 2012),
0.15 mg/L (May 2012). Both Sankey tank and Mallathah- 3.67 ± 0.76 (April 2012) and 2.54 ± 0.52 (May 2012).
alli lake water showed fluoride concentration well below Both Sankey tank and Mallathahalli lake water showed
the permissible limit of 1.5 mg/L. mean RSC value above 2.50, illustrating that these waters
are unsuitable for irrigation (Table 8).
Irrigational quality parameters
Percent sodium
Sodium absorption ratio
It has been widely recommended that the percentage of
sodium in irrigation water should not exceed 50–60, in
If the SAR ratio of the water samples in the study area is
order to avoid its deleterious effects on soil. When the
less than 10, it is excellent for irrigation purposes. The
percent sodium exceeds 60, the water is considered to be
SAR values for each water sample was calculated using the
unsuitable for irrigation purposes. It is considered, that
following equation (Richards 1954).
water is of class I quality if the % sodium is less than 30 %,
Naþ class II quality if the % sodium is between 30 and 75, and
SAR ¼ qffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi
2þ
ffi ð5Þ
ðCa þMg2þ Þ
2 Table 8 Water quality based on RSC (after Richards 1954)
The mean SAR concentration in Sankey tank water was RSC (epm) Remark on quality
1.61 ± 0.19 (March 2012), 2.06 ± 0.18 (April 2012) and
\1.25 Safe/good
2.00 ± 0.08 (May 2012). In Mallathahalli lake water, it
1.25–2.50 Marginal/doubtful
was 3.42 ± 0.63 (March 2012), 2.96 ± 0.50 (April 2012)
[2.50 Unsuitable
and 2.89 ± 0.39 (May 2012). According to classification
123
Appl Water Sci (2013) 3:247–261 259
Table 9 Sodium percent water class (Wilcox 1995) Mallathahalli lake water, it was 41.38 ± 5.06 (March
Sodium (%) Water class
2012), 36.31 ± 4.24 (April 2012) and 38.53 ± 1.76 (May
2012). Sankey tank water belongs to good category during
\20 Excellent March and April months and to permissible category dur-
20–40 Good ing May 2012. In contrast, Mallathahalli lake water
40–60 Permissible belongs to good category during April and May and to
60–80 Doubtful permissible category during March 2012 (Table 9).
[80 Unsuitable
Water quality index
of class III quality if it is more than 75. Percent sodium can
be determined using the following formula: The computed WQI values are classified into five types
Na namely, excellent water (WQI \ 50), good water (50 [
%Na ¼ 100 ð7Þ WQI \ 100), poor water (100 [ WQI \ 200), very poor
ðCa þ Mg þ K þ NaÞ
water (200 [ WQI \ 300) and water unsuitable for drinking
where the concentration of Ca2?, Mg2?, Na? and K? are (WQI [ 300). In the present study, the computed WQI values
expressed in milliequivalents per litre (epm or meq/L). Soil in Sankey tank water was 50.34 ± 6.38 (March 2012),
permeability has been found to be affected by high sodium 63.38 ± 3.56 (April 2012) and 56.54 ± 2.98 (May 2012),
ratio. Water quality reflected by sodium percentage values while in Mallathahalli lake water, it was 111.69 ± 4.61
can be categorized as shown in Table 9. (March 2012), 137.09 ± 6.01 (April 2012) and 122.38 ±
The mean percent sodium concentration in Sankey tank 9.78 (May 2012). It is evident from the results that Sankey
water was 34.36 ± 4.82 (March 2012), 39.52 ± 1.77 tank water fall under good water class while Mallathahalli
(April 2012) and 40.89 ± 1.50 (May 2012). In lake water fall under poor water category (Fig. 5).
Fig. 5 Spatio-temporal variation in WQI for Sankey tank and Mallathahalli lake waters
123
260 Appl Water Sci (2013) 3:247–261
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