© SET-2 DELHI PUBLIC SCHOOL RUBY PARK, KOLKATA BLOCK TEST - I, 2022-23 Class —XI Time: 3 Hours Subject: CHEMISTRY Maximum Marks: 70 General instructions: Read the following instructions careful a) There are 35 questions in this question paper with intemal choice. b) Section A consists of 18 multiple-choice questions carrying one mark each ©) Section B consists of 7 very short answer questions carrying 2 marks each. 4) Section C consists of 5 short answer questions carrying 3 marks each. ©) Section D consists of 2 case-based questions carrying 4 marks each. f) Section E consists of 3 long answer questions carrying 5 marks each. g) All questions are compulsory. hh) Use of calculators is not allowed. SECTION A The following questions are multiple-choice questions with one correct answer. Each question carries one mark. There is no internal choice in this section. 1, The maximum number of elactrons in a subshell with 1=3 and n = 4s: a) 14 b) 16 ©) 10 d) 12 2. Elements A, B, C, D have the following electronic configuration: A: 1s? 2s*2p* B:1s* 2s2p® C: 1s? 2s?2p°3s?_D: 1s? 2s'2p%3s? 3p? Which of these will belong to the same group of the periodic table? a) A&B b) A&C oc) A&D d) B&C? 3. Anelement with configuration [Ar]3d?4s*belong to: a) d-block b) p-block ©) flock d) s-block 4, An element X has an outer electronic configuration 2s*2p'. What is the formula and the nature of its oxide? a) XOs, basicb) X03, acidic ©) X20s, basic d) XOz, acidic 5. Which of the following species does not have tetrahedral geometry? a) BHyb) NH,’ c) Hs" d) COs” 6. The correct decreasing order of the boiling points of the following hydrogen bonded compounds is: a) HF > H,0 > NHsb) H,0> HF > NHsc)NH> HF > H,0 d) NH> H.0> HF 7. Which of the following angles corresponds to sp” hybridization? a) 90° ') 120° ©) 180° 4) 109.5" 8. Number of sigma and pi bonds in the molecule CHs-CH=CH: a) 81 b) 6,3 ©) 3,6 d) 1,8 9. Which of the following has the highest bond order? a) Oy b) Oz c) 03" d) 0,7 10. In which of the following reactions, the equilibrium remains unaffected on addition of small amount of argon at constant volume?( Consider all components are in gaseous state) a) H;+h= 2HI b) PCls= PCI; + Cl, c) N2 + Hie 2NH3. d) Theul 12; 13. 14. eege 16. 17. 18. 19. 20. equilibrium will remain unaffected in all the three cases. ‘What will happen to the solubility of a gas with rise in temperature according to Le Chatelier principle? 3). Increases b) Decreases) Remains unchanged __) First deereases and then increases. 10 g of MgCOs decomposes on heating to give 0.1 mole of CO; and 4 g of MgO. What is the percentage purity of MgCO,? a) 40 b) 76 84 4) 44 The number of moles in 0.64 g of SOz is: a) 100 b) 10 901 40.01 ‘Under similar conditions, oxygen and nitrogen are taken in the same mass. The ratio of their volumes will be: a)7:8 b)3:3. 6:5 d) 9:2 Question numbers 15-18 have two statements each labelled as Assertion (A) and Reason ® Select the most appropriate answer from the options given below: Both A and R are true and R is the correct explanation of A Both A and R are true and R is not the correct explanation of A Ais true but R is false Ais false but R is true “Assertion: Shielding effect increases as we go down the group. Reason: More is the number of electron in the penultimate shell more is the shielding effect ‘Assertion: Its impossible o determine the exact position and the exact momentum of an clectron simultaneously. Reason: The path of an electron in an atom is clearly defined. “Assertion: According to Fajan's rule, covalent character is favoured by small cation and small anion. Reason: The magnitude of covalent character in the ionic bond depends upon the extent of polarization. ‘Assertion: The endothermic reactions are favoured at low temperature and the exothermic reactions are favoured at high temperature. Reason: when a system in equilibrium is disturbed by changing the temperature, it will tend to adjust itself so as to overcome the effect of change SECTION B ‘This section contains 7 questions with internal choice in two questions. The following questions are very short answer type and carry 2 marks each. )Which law co-relates the mass and volume of a gas ? State the law. b)Give one example where the law of definite proportions is not obeyed. ‘Arrange in the increasing order of number of molecules present in the following: (a) 1g CO2 (b) lg No (©) 1gNO @ 1g CHs Pace 2 of 721, a) What is the ratio of molar volumes of SO, and SOs at STP? ») State the law which deals with the ratio of the volumes of gaseous reactants and products under same condition of temperature and pressure. OR, a) The electric charge on one electron is 1.602 x 10° coulomb. How much charge is present on 0.1 mole of Cu*tions ? b) How many atoms of oxygen and hydrogen are present in 0.15 mole of water ? 22. Arrange the following in increasing order of the property indicated : (FCI, Brand I (negative electron gain enthalpy) (ii) Br’, Br, Br (size) 23. The energy of an electron in the ground state of hydrogen atom is -2.18x10""J. Calculate the ionization enthalpy of atomic hydrogen in terms of Jmol”. 24, a) Out of Li & Be, which is expected to have higher second lionization enthalpy ?Why? b) Write the atomic number of the element present in the fourth period and 12" group of the periodic table. OR, a) Among the alkali metals, which element do you expect to be least electronegative and why? ! b) Define the term ‘Electron gain enthalpy’ 25. a) From the value of equilibrium constants, indicate in which case, does the reaction go almost to completion : K; = 10°, K>=10", Ky=10° b) Predict the direction of the reaction based on relative values of Qc & Ke for (i) and (iii) Oc Ke Qe Ke Qe Ke SECTION C ‘This section contains 5 questions with internal chi two questions. The following, questions are short answer type and carry 3 marks each.26. 21. 28. 29. 30. ‘A metal forms two oxides. The higher oxide contains 80% metal. 0.72g of the lower oxide gave 0.8 of higher oxide when oxidized show that the data illustrates the Law of Multiple proportions. The general formula of a carbohydrate is caus 3:1g of the carbohydrate on heating in the absence of oxygen yield 1.24g of carbon. The molecular mass of the carbohydrate is 180u, Calculate the molecular formula. 6..) Calculate the amount of KCIO; needed to supply sufficient oxygen for burning 112 L of CO gas at NTP. (Molecular mass of KC1O3 = 122.5u) (b) What is the number of molecules of carbon dioxide which contains 8g of oxygen ? a) What transition in a hydrogen spectrum would have the same wave length as in the Balmer of He*spectrum ? b) What is the maximum number of emission lines when the excited electron of a hydrogen atom transition n=4 to in n=6 drops to the ground state? At 473 K, the equilibrium constant Ke for the decomposition of phosphorus pentachloride (PCIs) is 8.3x10%, If decomposition proceeds as : PCls(g) + PCl(g) + Ch(g) ;AH= 124.0 kImol! (@ Write an expression for Htc of the reaction. (ii) What is the value of Ke for the reverse reaction at the same temperature ? (ii) What would be the effect on Ke if temperature is increased ? a) The bond angles in NH," and CH, are same but NHs has different bond angle. Why ? 'b) When a magnet is dipped in a jar of liquid oxygen, some oxygen clings to it but the same does not happen in case of liquid nitrogen. Assign reason. ¢) Show the orbital diagram of s-p overlapping for sigma bond formation. OR, a) Although both CO» and HO are triatomic molecules, the shape of HO molecule is bent while that of CO> is linear, Explain on the basis of dipole moment. 'b) Write two major conditions for the combination of atomic orbitals. ©) Show the orbital diagram of p-p overlapping for pi bond formation. SECTION D ‘The following questions are case-based questions. Each question has an internal choice. Read the passage carefully and answer the questions that follow.Ve An atom in its lowest energy state is said to be in the normal state or the ground state. The ground state is the most stable state for the atom. The filling of orbitals in the ground state is determined by the following rules: A. The aufbau principle, from the German Aufbauprinzip, also called the aufbau rule, states that in the ground state of an atom or ion, electrons fill subshells of the lowest available , then they fill subshells of higher energy. ' exclusion principle, from this it follows that an orbital cannot have more than two electrons. Moreover, if an orbital has two electrons then they must have opposite spins, >. Hund’ rule of maximum multiplicity, the basis of this rule is that two electrons in a particular orbital feel greater repulsion and hence while filling orbitals of equal energy pairing of electrons is avoided as long as it is possible. Moreover the singly occupied orbitals should have electrons with parallel spin because this corresponds to state of lower energy. Answer the following questions: a) Write the electronic configuration of Mn** and report the number of unpaired electrons in it. 'b) What is the number of electrons in 3d subshell for an element with atomic number 262 ©) Which quantum number determines the shape of an orbital? d) How many electrons will be present in the subshells having m, value of -1/2 forn =42 oR, 4) what is the atomicnumber of the element whose outermost electronic configuration is represented by 3d”? 32. Periodic trends are specific pattems that are present in the periodic table that illustrate different aspects of a certain element. They were discovered by the Russian chemist Dmitri Mendeleev in the year 1863. Major periodic trends include atomic radius, ionization enthalpy, negative electron gain enthalpy, electronegativity, valency and metallic character. These trends exist because of the similar electronic configuration of the elements within their respective groups or periods and because of the periodic nature of the elements. these give a qualitative assessment of the properties of each element. Given below the general trends, though there are some exceptions. Characteristic Period Group Ionization enthalpy Increases Decreases Metallic property Decreases Increases Atomic radius Decreases Increases Electronegativity Increases Decreases Negative electron gain Increases Decreases enthalpy33. 34, Shielding effect Increases Decreases Answer the following questions: ‘a) Show the correct increasing order of metallic character of the elements B, Al, Mg, K. b) Inbetween F and Cl, which has a more negative electron gain enthalpy? ©), Why Oxygen has lower first ionization enthalpy value than that of Nitrogen? 4) Mention two factors due to which the ionization enthalpy of the main group elements tends to decrease down the group’ OR, 4) Mention the increasing order of shielding effect of s, p, d, f orbitals. SECTION E The following questions are long answer type and carry 5 marks each. Two questions have an internal choice. 4) Calculate the wave length of an electron moving with a velocity of 2.05 x 107 ms". (me 9.1 x 10°" kg) }) (i) What is the lowest value of n (principal quantum number) which allows ‘g” orbital to exist 2 (ii) An electron is in one of the 3d orbitals. Give the possible values of “I” and ‘m,". (iii) Find out the number of Spherical nodes for (A) 2s and (B) 4p orbitals. OR, a) The uncertainty in the position and velocity of a particle are 107m and5.27 x 10% ms™ respectively. Calculate the mass of the particles. ) i) How many electrons in an atom may have the following quantum numbers ? n=3,m=+% (ii) How do 1s and 2s orbitals differ in number of spherical nodes? (iii) How many orientations are possible for the orbitalspresent in the f-sub-shell ? 4) Write the expression for the equilibrium constant Ke for the reaction = 2Cu(NO,)2 (s) # 2CuO(s) + 2NOxAg) + O2 (8) b) A sample of HI(g) is placed in flask at a pressure of 0.2 atm. At equilibrium, the partial pressure of HI(g) is 0.04 atm. What is the Kp for the given equilibrium ? ©) For the following reactions at equilibrium, at temp T, @Ae BKi=3 (i) BAC; K2=2 What will be the value of equilibrium constant K; for the reaction, A #C? Rose Dave nf 736. 4) For the equilibrium, 2NOCI(g) + 2NO(g) + Cl: (g) the value of Ke is 3.75 x10° at 1069K, Calculate the Kp for the reaction at this temperature. OR, ) Write the expression for the equilibrium constant Kp for the reaction : 2Fe(s) + 3H;0(g) + Fe,0s(s) + 3Hx(e) b) A pure sample of PCI; was introduced into an evacuated vessel at 473K. After equilibrium ‘was attained, concentration of PCls was found to be 0.5x10" mol. If value of Ke is 8.3x10", what are the concentrations of PCl; and Cl, at equilibrium ? PClx(g) = PCl(g) + Clas) ©) Given the equilibrium, Nz0.(g) # 2NO2(g) with K,= 0.15 atm at 298 K. What is the value of K2 4) When hydrochloric acid is added to cobalt nitrate solution at room temperature, the following reaction takes place and the reaction mixture becomes blue. On cooling the mixture, it becomes pink. [CO(H20)6}** (aq)+4CI'(aq) [CoCli]*(aq)+6H20(1) (Pink) (Blue) Predict whether the reaction is endothermic or exothermic? 4) Predict the shape of CIF; molecule, on the basis of VSEPR theory. ) Show the resonating strubtures of CO;*ion. «) What is the change in hybridization of Al atom in the reaction AICIs + Cl AICL’? 4) Explain by Molecular orbital theory that Bez molecule does not exist. ¢) Calculate the formal charge on each oxygen atom in the Lewis structure of ozone molecule.