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fact, there is but one literature citation in the structional equipment, animal care, green-

Systems." Following this are derivations of text. The total absence of references to his- house management, laboratory solutions,
the temperature and pressure dependences torically significant papers, data tables, and electronics, hand tools, and power tools.
of fugacity and a description of a method of present day applications is dismaying and Vendors of specific laboratory equipment are
obtaining fugacity values from compress- would d a c e a ereat burden u ~ o nthe in- also mentioned. Unfortunately, because the
ibility data fnr gases. author is British, most are in England.
In order to avoid problems when dealing The sixty-page chapter on laboratory so-
with non-ideal vapors, the ideal solution is lutions is the longest in the 248~pagebook.
defined in Chapter 9, "Properties of Ideal are found only in the examples and problems, Recipes are included for buffer solutions,
Solutions," as a solution in which each con- the clear majority af which are derivations. indicators, analytical solutions, and often
stituent's partial mold volume is the same as used chemistry, biochemistry, and biology
its molar volume a t the same temperature momas C. Ehlen solutiuns. Of the four solutions, this general
and pressure. The other properties of the Marquene Univmity chemistry instructor recently prepared, only
ideal solution are then derived. Raoult's law Milwaukee. W153233 one had a reported recipe.
and, ultimately, Henry's law appear as con- Subjects are discussed a t a hasic level;
sequences of the above definition of the ideal ' "Principles of General Thermodynamics," by G. depth and detail are absent. Specialized
solution and of ideal behavior by the vapor. N. HatsopOUlo~and J. H. Keenan. J. Wiley and chemistry handbooks are not replaced by this
See https://pubs.acs.org/sharingguidelines for options on how to legitimately share published articles.

Boiling point elevation and osmotic pressure Sons, Inc.. 1966. reference.
equations are then derived. Freezing point Educators Gulde to Free Science Untrained laboratory assistants, skilled
depression is ignored. In dealing with non- Materials. Nineteenth Edition technicians, and profe&ional scientists are
ideal behavior in both vapor and condensed the author's expected users of this manual.
Downloaded via 140.213.159.169 on September 18, 2023 at 01:44:08 (UTC).

phase solutions, the author uses the expres- Edited by Mary H. Saterstrorn, Eduea- . .
The book would verv heloful for scientists
sions "solutions involving coexisting phases" tors Proeress Service. Inc.. Randoloh. educated in one discipline and working in
and "two phase solutions" whieh are very WI., 1977. Figs. & tables. 21 x 21 Em: other disciplines. Scientists educated and
confusing since a solution is a single phase. +
rrxix 419pp. $11.95. working in the same discipline would better
Actlvity and the activity coefficient are cov- use the specialized handbooks from their
ered in a page and a half. No indication is This annual publication lists currently particular disciplines.
given as t o how activity may he measured. available free films, filmstrips, slides, trans-
Chapter 10, "Thermodynamics of Reacting parencies, audiotapes, videotapes, scripts, Bill Nickels
Svstems." heeins with a descriotion of the transcriptions, and printed science materials. Schoolcraft Coliqe
More than half of the 1658 items are films Livonia, MI 48152
and a third are printed materials. All items
are fully annotated and eross-indexed ac-
through membranes permeable to single cording to title, subject, source, and avail- Using the Metrlc System
species. This is illustrated by an uncaptioned ability. There are, in addition, source and
figure to which no reference is made. Extent availability indices for Australia and Canada. Wilma E. Rollins, J. Weston Waleh,
~ 1 1 'reaction is used without defining or ex- Although the largest source is the federal Pub., 1978. Figs. & tables. 28X 22.5 cm. 1
plaining the symbolism. Tables of AH?, AG?
rw iC.-",-, ~~
HH".,..l/T datn are absent and
~ ~
government, there are hundreds of other
sources. such as universities. industrv. .. and
+ 69 pp. $3.25.
sources thereof are not mentioned. The dis- state governments. This book appears to he written for stu-
cussion of equilibrium is good. In addition to the annotated lists of mate- dents who are early teenagers, in high school
Topics covered in Chapter 11, "Thermo- rials, there are instructions and suggestions or younger. There is no scientific emphasis,
dynamics of Special Systems,"-"Thermal regarding ordering, a philosophical essay use of powers of ten, nor use of dimensional
Radiation" in which the Stefan-Boltzmann entitled "Children Learning Science" by nnalv*~;. The txilnlplr< n r p usuall) 01 thr
equation is derived, but Planek's radiation Professor dahn W. Renner, and eight ntmscwnrlfic wriety mrl largely restricwd T I ,
equation is not. "Fuel Cells" in which electric teacher-prepared units of study which show
wrrk and Lhermadynamicpropertiesofcells how the materialscan besuccessfully used a t
thv use ,i r,rri~xwfrom mllli- rhroueh - kilw
including deka- and heetu-.
are discussed, "Surface Effects" in which the the elementary, junior, and senior high school In the first two chapters, the author pre-
IWvin-Helmholtz equation is derived and levels. sents an interesting history of the earliest
"Thermodynamics of General Systems"-are As might he expected, most of the materi- measurements followed by the English sys-
lreated in one page plus a table which is an als appear to he designed for use a t the ele- tem nf measurement. The number of prob-
excellent summary of the work possible in mentary and secondary school levels, with lems or exercises included is far more than
simple systems. The treatment of fuels is, a t perhaps a fourth of the items suitable for necessary to justify going to the metric sys-
nine pages, the longest and is quite prac- college students. It seems to me that ele- tem. There are almost no examples illus-
L i d mentsryand secondary school libraries def- trating how these problems are salved.
In Chapter 12, "Introduction to Thermo- initely should subscribe to this Guide. At the The last four chapters are devoted t o the
dynamics of lrreversihle Processes," the universitv level. lecture demonstrators in metric system using approximately the same
transport equations are stated, followed by format as the first two chapters. Unfortu-
I he discussion of weakly coupled flows with nately, the number of errors in these chapters
application to heat and current in thermo- (including the answers to the problems) in-
rlectric circuits, including the Seebeck, Pel- creased significantly. Little reference is made
Stanley T. Marcus
tier, and Kelvin e f f e c k "Direct Energy to the current metric standards. The gram is
c o m a University
Conversion," the last topic in the chapter, incorrectly defined as ".. .the mass occupied
Ithaca. NY 14853
includes an argument for using thermoelec- Ihy 1 cubic centimeter of water." The day is
tric generation on the hasis of efficiency. A Laboratory Manual for Schools and defined as ". . . the length of time for one
Althcmgh the treatment is indeed postu- Colleges revolution of the earth around the sun."
latory, and aside Rom the too frequent use of Cwwersions within the metric system are
undefined terms, rigomus, there are genuine J o h n Creedy, Heinemann Educational dnne exclusively by moving the decimal
reasons tn hesitate to use this book in a Books, lnc., London, 1978. Figs. and tables. point, completely neglecting the use of pow-
graduate or undergraduate class. An ex- +
25 X 19 cm. iii 248 pp. $25.00. ers af ten. When converting between the
lrrrnely terse treatment such as this one metric system and the English system, the
needs the help of illustrations. Yet they are To distinguish this hook from a laboratory use of significant figures was for the most part
larking in key plaeesas discussed above; only manual used by students, the hook might
lwci of the figures have captions, figure la- better be called a "laboratory handhook."

A286 / Journal of Chemical Education

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