SAFETY DATA SHEET

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier
Trade name or designation Print Cartridge GC 31 C (RIC)
of the mixture

Registration number -
Synonyms None.
SDS No. 405689
Issue date 21-October-2022
Version number 01
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses The Image Formation of Printing Machine or Copier. ink product Ink Cartridge
Uses advised against No other uses are advised.
1.3. Details of the supplier of the safety data sheet
Company name Ricoh UK Ltd
Address 800 Pavilion Drive, Northampton Business Park Northampton NN4 7YL, UK
Phone +44 330 123 3011
E-mail contactcr@ricoh.co.uk
1.4.Emergency telephone 111 (UK only)
number

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008 as amended
2.2. Label elements
Label according to Regulation (EC) No. 1272/2008 as amended
Hazard pictograms None.
Signal word None.
Hazard statements The mixture does not meet the criteria for classification.
Precautionary statements
Prevention Not available.
Response Not available.
Storage Not available.
Disposal Not available.
Supplemental label information EUH208 - Contains 1,2-Benzisothiazol-3(2H)-one. May produce an allergic reaction.
2.3. Other hazards None known.

SECTION 3: Composition/information on ingredients

3.2. Mixtures
General information
Chemical name % CAS-No. / EC No. REACH Registration No. Index No. Notes
Water 45 - 75 7732-18-5 Excempt -
231-791-2
Classification: -
Glycol 20 - 30 Confidential Confidential -
-
Classification: -
Glycerin 10 - 20 56-81-5 Excempt - #
200-289-5
Classification: -
Organic Pigment(Copper compound) <10 Confidential Confidential -
-
Classification: -

Material name: Print Cartridge GC 31 C (RIC) - 405689 SDS GREAT BRITAIN

405689 Version #: 01 Issue date: 21-October-2022 1/6
 Chemical name % CAS-No. / EC No. REACH Registration No. Index No. Notes
1,2-Benzisothiazol-3(2H)-one <0.05 2634-33-5 - 613-088-00-6
220-120-9
Classification: Acute Tox. 4;H302, Skin Irrit. 2;H315, Eye Dam. 1;H318, Skin Sens.
1;H317, Aquatic Acute 1;H400

List of abbreviations and symbols that may be used above

#: This substance has been assigned Union workplace exposure limit(s).
Composition comments This product does not contain any of the following RoHS substances as ingredients. Cadmium,
Hexavalent Chromium, Mercury, Lead, Polybrominated biphenyls (PBB), Polybrominated
diphenyleters (PBDE), Phthalate esters (DEHP, BBP, DBP, and DIBP), SVHC (substances of very
high concern: published by ECHA).

SECTION 4: First aid measures

General information
4.1. Description of first aid measures
Inhalation
Skin contact
Eye contact
Ingestion
4.2. Most important symptoms
and effects, both acute and
delayed
4.3. Indication of any
immediate medical attention
and special treatment needed
Not available.
Move to fresh air. Get medical attention, if needed.
Wash off with soap and plenty of water. If skin irritation or rash occurs: Get medical
advice/attention.
Rinse with plenty of water. If irritation persists get medical attention.
Rinse mouth thoroughly. Get medical advice/attention if you feel unwell.
Not available.
Treat symptomatically.

SECTION 5: Firefighting measures

General fire hazards Not available.
5.1. Extinguishing media
Suitable extinguishing Water. Foam. Dry chemicals. Carbon dioxide (CO2).
media
Unsuitable extinguishing Not available.
media
5.2. Special hazards arising Not available.
from the substance or mixture
5.3. Advice for firefighters
Special protective Wear suitable protective equipment.
equipment for firefighters
Special fire fighting Not available.
procedures
Specific methods Use standard firefighting procedures and consider the hazards of other involved materials.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
For non-emergency Not available.
personnel
For emergency responders Not available.
6.2. Environmental precautions Avoid discharge into drains, water courses or onto the ground.
6.3. Methods and material for Clean up in accordance with all applicable regulations.
containment and cleaning up
6.4. Reference to other Not available.
sections

SECTION 7: Handling and storage

7.1. Precautions for safe
handling
7.2. Conditions for safe
storage, including any
incompatibilities
7.3. Specific end use(s)
No special precautions are necessary beyond normal good hygiene practices. See Section 8 for
additional personal protection advice when handling this product.
Not available.
Not available.

Material name: Print Cartridge GC 31 C (RIC) - 405689 SDS GREAT BRITAIN

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SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Occupational exposure limits
UK. EH40 Workplace Exposure Limits (WELs)
Components Type Value Form

Glycerin (CAS 56-81-5) TWA 10 mg/m3 Mist.

Biological limit values
Recommended monitoring
procedures
Derived no effect levels
(DNELs)
Predicted no effect
concentrations (PNECs)
8.2. Exposure controls
Appropriate engineering
controls
Individual protection measures, such as personal protective equipment
General information
Eye/face protection
Skin protection
- Hand protection
- Other
Respiratory protection
Thermal hazards
Hygiene measures
Environmental exposure
controls
No biological exposure limits noted for the ingredient(s).
Not available.
Not available.
Not available.
Not available.
If necessary, Wear suitable protective equipment.
Not normally needed.If necessary, Wear appropriate protective goggles.
Not normally needed.If necessary, Wear suitable gloves.
Not normally needed.If necessary, Wear suitable protective clothing.
No personal respiratory protective equipment normally required.
Not applicable.
Wash hands after handling.
Not available.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Appearance
Physical state Liquid.
Form Liquid.
Colour Cyan
Odour No odour
Odour threshold Not available
pH 8 - 10
Melting point/freezing point Not applicable
Initial boiling point and boiling Not available
range
Flash point Not applicable
Evaporation rate Not available
Flammability (solid, gas) Not available.
Upper/lower flammability or explosive limits
Explosive limit - lower ( %) Not available.
Explosive limit – upper Not available.
(%)                                         
Vapour pressure Not available
Vapour density Not available
Relative density Not available.
Solubility(ies)
Solubility (water) Soluble
Partition coefficient Not available
(n-octanol/water)
Auto-ignition temperature Not available.
Decomposition temperature Not applicable
Viscosity 0.01 Pa·s

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Viscosity temperature 25 °C (77 °F)
Explosive properties Not available.
Oxidising properties Not available.
9.2. Other information
Density 1.10 g/cm³
Flammability Not flammable

SECTION 10: Stability and reactivity

10.1. Reactivity
10.2. Chemical stability
10.3. Possibility of hazardous
reactions
10.4. Conditions to avoid
10.5. Incompatible materials
10.6. Hazardous
decomposition products
The product is stable and non reactive under normal conditions of use, storage and transport.
Material is stable under normal conditions.
No dangerous reaction known under conditions of normal use.
Not available.
Not applicable.
No dangerous reaction known under conditions of normal use.

SECTION 11: Toxicological information

General information Not available.
Information on likely routes of exposure
Inhalation Not available.
Eye contact Not available.
Skin contact Not available.
Ingestion Not available.
Symptoms Not available.
11.1. Information on toxicological effects
Acute toxicity
Product Species Test Results
Print Cartridge GC 31 C (RIC)
Acute
Oral
LD50 Rat >= 5000 mg/kg
Components Species Test Results
1,2-Benzisothiazol-3(2H)-one (CAS 2634-33-5)
Acute
Oral
LD50 Rat > 5000 mg/kg
Skin corrosion/irritation
Irritation Corrosion - Skin
1,2-Benzisothiazol-3(2H)-one OECD 404
Result: Not classified.
Species: Rabbit
Irritation Corrosion - Skin: P.I.I. value
Print Cartridge GC 31 C (RIC) <= 1
Species: Rabbit
Notes: Based on other Ricoh products test results of similar
ingredients.
Serious eye damage/eye Not available.
irritation
Respiratory sensitisation Not available.
Skin sensitisation
Local lymph node assay - Lowest concentration producing reaction
1,2-Benzisothiazol-3(2H)-one OECD 429
Result: Negative
Species: Mouse
Germ cell mutagenicity
Germ cell mutagenicity: Ames test
Print Cartridge GC 31 C (RIC) 0, Negative
Notes: Ames test
1,2-Benzisothiazol-3(2H)-one OECD 471
Result: Negative
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405689 Version #: 01 Issue date: 21-October-2022 4/6
Carcinogenicity Not available.
Reproductive toxicity
Reproductivity
Print Cartridge GC 31 C (RIC) 0, Does not contain substances listed as hazardous to
reproductive health.
Specific target organ toxicity - Not available.
single exposure
Specific target organ toxicity - Not available.
repeated exposure
Aspiration hazard Not available.
Mixture versus substance Not available.
information

SECTION 12: Ecological information

12.1. Toxicity
Components Species Test Results
1,2-Benzisothiazol-3(2H)-one (CAS 2634-33-5)
Aquatic
Acute
Algae EC50 Algae > 100 mg/l, 72 hr
Crustacea LC50 Daphnia magna > 100 mg/l, 48 hr
Fish LC50 Fish > 100 mg/l, 96 hr
12.2. Persistence and Not available.
degradability
12.3. Bioaccumulative potential Not available.
Partition coefficient
n-octanol/water (log Kow)
Glycerin -1.76
Bioconcentration factor (BCF) Not available.
12.4. Mobility in soil Not available.
12.5. Results of PBT and vPvB Not a PBT or vPvB substance or mixture.
assessment
12.6. Other adverse effects Not available.

SECTION 13: Disposal considerations

13.1. Waste treatment methods
Residual waste Not available.
Contaminated packaging Not available.
EU waste code Not available.
Disposal methods/information Dispose of contents/container in accordance with local/regional/national/international regulations.

SECTION 14: Transport information

ADR
14.1. - 14.6.: Not regulated as dangerous goods.
RID
14.1. - 14.6.: Not regulated as dangerous goods.
ADN
14.1. - 14.6.: Not regulated as dangerous goods.
IATA
14.1. - 14.6.: Not regulated as dangerous goods.
IMDG
14.1. - 14.6.: Not regulated as dangerous goods.
14.7. Transport in bulk Not applicable.
according to Annex II of
MARPOL 73/78 and the IBC
Code

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Retained direct EU regulations

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 Regulation (EC) No. 1005/2009 on substances that deplete the ozone layer, Annex I and II, as amended
Not listed.
Regulation (EU) 2019/1021 On persistent organic pollutants (recast), as amended
Not listed.
Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 1 as amended
Not listed.
Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 2 as amended
Not listed.
Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 3 as amended
Not listed.
Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex V as amended
Not listed.
Regulation (EC) No. 166/2006 Annex II Pollutant Release and Transfer Registry, as amended
Not listed.
Regulation (EC) No. 1907/2006, REACH Article 59(10) Candidate List as currently published by ECHA
Not listed.
Authorisations
Regulation (EC) No. 1907/2006, REACH Annex XIV Substances subject to authorization, as amended
Not listed.
Restrictions on use
Regulation (EC) No. 1907/2006, REACH Annex XVII Substances subject to restriction on marketing and use as amended
Not listed.
Other EU regulations
Directive 2012/18/EU on major accident hazards involving dangerous substances, as amended
1,2-Benzisothiazol-3(2H)-one (CAS 2634-33-5)
15.2. Chemical safety Not available.
assessment

SECTION 16: Other information

List of abbreviations
References
Information on evaluation
method leading to the
classification of mixture
Full text of any statements,
which are not written out in full
under sections 2 to 15
Revision information
Training information
Not available.
ACGIH Documentation of the Threshold Limit Values and Biological Exposure Indices
HSDB® - Hazardous Substances Data Bank
Japan Society for Occupational Health, Recommendation of Occupational Exposure Limits
JIS Z 7252:2019 Classification of chemicals based on “Globally Harmonized System of
Classification and Labelling of Chemicals (GHS)”
JIS Z 7253:2019 Hazard communication of chemicals based on GHS - Labelling and Safety Data
Sheet (SDS)
Taiwan. OELs. (Standards on Workplace Atmosphere of Dangerous and Hazardous Materials)
National Toxicology Program (NTP) Report on Carcinogens
US. IARC Monographs on Occupational Exposures to Chemical Agents
Not available.
H302 Harmful if swallowed.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H400 Very toxic to aquatic life.
Product and Company Identification: Product and Company Identification
Composition / Information on Ingredients: Ingredients
Physical & Chemical Properties: Multiple Properties
Regulatory Information: Regulatory Information
HazReg Data: Europe - EU
Not available.

Material name: Print Cartridge GC 31 C (RIC) - 405689 SDS GREAT BRITAIN

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