MSDS Denimcol Spec-Rpd

SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
DENIMCOL SPEC-RPD
Version 1.1 Revision Date 22.08.2014 Print Date 02.09.2014
1. Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier

Trade name : DENIMCOL SPEC-RPD
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the Sub- : Textile auxiliary
stance/Mixture
1.3 Details of the supplier of the safety data sheet

Manufacturer/Supplier
CHT R. BEITLICH GMBH BEZEMA AG

Bismarckstraße 102 Kriessernstrasse 20
72072 Tübingen 9462 Montlingen
Germany Switzerland
Tel.: +49(0)70 71 15 40 Tel.: +41(0)71 763 88 11
info@cht.com bezema@bezema.com
Importer : -
-
-
-
-
-
Responsible Department : CHT R. BEITLICH GMBH

BEZEMA AG
Product Safety
msds@cht.com
product.safety@bezema.com
1.4 Emergency telephone number

Emergency telephone : +49(0)70 71 15 40 (Germany, 24 hours)
number +41(0)71 763 88 11 (Switzerland, 24 hours)
2. Hazards identification
2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008)
Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008.
Classification (67/548/EEC, 1999/45/EC)
Not a hazardous substance or mixture according to EC-directives 67/548/EEC or 1999/45/EC.
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SAFETY DATA SHEET
DENIMCOL SPEC-RPD
2.2 Label elements

Labelling (REGULATION (EC) No 1272/2008)
Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008.
2.3 Other hazards
According to our present knowledge the product does not contain persistent, bioaccumulative and
toxic substances (PBT substances) or very persistent and very bioaccumulative (vPvB substances)
as defined in Annex XIII of the Regulation (EG) No 1907/2006 (REACH), respectively.
3. Composition/information on ingredients
3.2 Mixtures
Chemical nature : Polyvinylalcohol in aqueous dispersion
Remarks : No dangerous ingredients according to Regulation (EC) No.

1907/2006
4. First aid measures
4.1 Description of first aid measures

General advice : Take off all contaminated clothing immediately.
If inhaled : Move to fresh air.

If symptoms persist, call a physician.
In case of skin contact : Wash off immediately with soap and plenty of water.
In case of eye contact : Immediately flush eye(s) with plenty of water.

If swallowed : Rinse mouth with water.

Do NOT induce vomiting.
Call a physician immediately.
4.2 Most important symptoms and effects, both acute and delayed
Risks : Refer to section 2 and 11.
4.3 Indication of any immediate medical attention and special treatment needed
Treatment : Treat symptomatically.
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SAFETY DATA SHEET
DENIMCOL SPEC-RPD
5. Firefighting measures
5.1 Extinguishing media

Suitable extinguishing media : Carbon dioxide (CO2)
Water spray jet
Dry powder
Foam
5.2 Special hazards arising from the substance or mixture

Specific hazards during fire- : Hazardous decomposition products formed under fire condi-
fighting tions.
Can be released in case of fire:
Carbon oxides
5.3 Advice for firefighters

Special protective equipment : In the event of fire, wear self-contained breathing apparatus.
for firefighters
Further information : In case of fire do not inhale smoke, conflagration gases and
steams.
Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.
The material itself does not burn, only after drying in through a
large fire.
6. Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures

Personal precautions : Use personal protective equipment.
Contaminated surfaces will be extremely slippery.
6.2 Environmental precautions

Environmental precautions : The product should not be allowed to enter drains, water
courses or the soil.
Pay attention to local or official regulations.
6.3 Methods and materials for containment and cleaning up

Methods for cleaning up : Soak up with inert absorbent material (e.g. sand, silica gel,
acid binder, universal binder, sawdust).
Clean contaminated surface thoroughly.
Dispose of in accordance with local regulations.
6.4 Reference to other sections

Refer to protective measures listed in sections 7 and 8.
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SAFETY DATA SHEET
DENIMCOL SPEC-RPD
7. Handling and storage
7.1 Precautions for safe handling

Advice on safe handling : Provide sufficient air exchange and/or exhaust in work rooms.
Advice on protection against : No special protective measures against fire required.

fire and explosion
7.2 Conditions for safe storage, including any incompatibilities

Requirements for storage : Do always store in containers which correspond to the original
areas and containers ones.
Keep container tightly closed.
Further information on stor- : Protect from frost.

age conditions Stir well before use.
Advice on common storage : No special precautions required.
German storage class : 12 Non Combustible Liquids
7.3 Specific end use(s)

Note : Consult the technical guidelines for the use of this sub-
stance/mixture.
8. Exposure controls/personal protection
8.1 Control parameters
8.2 Exposure controls

Engineering measures
Solids with occupational exposure limits in liquid preparations do not cause an exposure in the work-
place, because they are not present in a respirable form. Exposure can occur in the form of aerosols
or after drying of the liquid the solids remain, possibly in a finely dispersed form.
Provide sufficient air exchange and/or exhaust in work rooms.
Personal protective equipment

Respiratory protection : In case the work place is not ventilated sufficiently and during
spray processing, it is necessary to wear respiratory protective
equipment.
Combination filter AX/P
Hand protection : Neoprene
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SAFETY DATA SHEET
DENIMCOL SPEC-RPD
Protective index Class 6

Break through time: > 480 min
Glove thickness: >= 0,5 mm
: butyl-rubber
Protective index Class 6
Break through time: > 480 min
Glove thickness: >= 0,5 mm
: The choice of an appropriate glove does not only depend on

its material but also on other quality features and is different
from one producer to the other.
The obtained break through times according to EN 374 Part III
are not measured under normal operating conditions. There-
fore a maximum usage time of 50% of the break through time
is recommended.
Eye protection : Safety glasses
Skin and body protection : Wear suitable protective clothing.
Hygiene measures : Avoid contact with skin, eyes and clothing.

Do not breathe vapours, aerosols.
Take off all contaminated clothing immediately.
Handle in accordance with good industrial hygiene and safety
practice.
Environmental exposure controls

General advice : The product should not be allowed to enter drains, water
courses or the soil.
Pay attention to local or official regulations.
9. Physical and chemical properties
9.1 Information on basic physical and chemical properties

Appearance : viscous
Colour : colourless
slight
yellowish
cloudy
Odour : odourless
Flash point : Not applicable
Lower explosion limit : Not applicable

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SAFETY DATA SHEET
DENIMCOL SPEC-RPD
Upper explosion limit : Not applicable
Oxidizing properties : Not applicable
Auto-ignition temperature : not auto-flammable
pH : 4,7 - 7,9
at 20 °C
(undiluted)
Solidification / Setting point : ca. 0 °C

at 1.013 hPa
Boiling point/boiling range : ca. 100 °C

at 1.013 hPa
Vapour pressure : ca. 23 hPa

at 20 °C
Density : ca. 1 g/cm3

at 20 °C
Water solubility : completely miscible
Partition coefficient: n- : Not applicable

octanol/water
Viscosity, dynamic : 1.900 - 2.625 mPa.s

at 20 °C
Brookfield RVT, spindle 3, 20 rpm
Relative vapour density : Not applicable
Evaporation rate : Not applicable
9.2 Other information

Conductivity : Not determined
10. Stability and reactivity
10.1 Reactivity
No hazards to be specially mentioned.
10.2 Chemical stability

The product is chemically stable.
10.3 Possibility of hazardous reactions
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SAFETY DATA SHEET
DENIMCOL SPEC-RPD
Hazardous reactions : No dangerous reaction known under conditions of normal use.
10.4 Conditions to avoid

Conditions to avoid : Not applicable
10.5 Incompatible materials

Materials to avoid : Not applicable
10.6 Hazardous decomposition products

Hazardous decomposition : No decomposition if stored and applied as directed.
products
11. Toxicological information
11.1 Information on toxicological effects

Acute toxicity
Acute oral toxicity : LD50: > 5.000 mg/kg
Species: Rat
Argument by analogy
Acute dermal toxicity : No data is available on the product itself.
Skin corrosion/irritation
Skin irritation : Prolonged skin contact may cause skin irritation.
Serious eye damage/eye irritation

Eye irritation : Contact with eyes may cause irritation.
Respiratory or skin sensitisation

Sensitisation : No known sensitising effect.
Further information : If used and handled according to specifications, the product

does not have any harmful effects according to our experience
and the information provided to us.
12. Ecological information
12.1 Toxicity
Toxicity to fish : No data is available on the product itself.
Toxicity to daphnia and other : EC50: > 100 mg/l

aquatic invertebrates Exposure time: 48 h
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SAFETY DATA SHEET
DENIMCOL SPEC-RPD
Species: Daphnia magna (Water flea)

Method: OECD Test Guideline 202
Toxicity to algae : No data is available on the product itself.
Toxicity to bacteria : EC50: > 1.000 mg/l

Species: activated sludge
Method: Retarded respiration test (OECD 209)
Argument by analogy
12.2 Persistence and degradability

Biodegradability : O2 measuring
63 %
Method: OECD 301 F (mineralisation)
: DOC-CO2 measuring
> 90 %
Method: OECD 302 B with CO2 (elimination)
Argument by analogy
The product is "readily biodegradable" according to the criteria
of the OECD.
Biochemical Oxygen De- : < 5 mg O2/g

mand (BOD) 5d
Method: DIN EN 1899-1 (H 55)
Argument by analogy
Chemical Oxygen Demand : ca. 140 mg O2/g

(COD) Method: DIN 38409-H-41
Argument by analogy
12.3 Bioaccumulative potential

Bioaccumulation : No data is available on the product itself.
12.4 Mobility in soil

Mobility : No data available
12.5 Results of PBT and vPvB assessment

According to our present knowledge the product does not contain persistent, bioaccumulative and
toxic substances (PBT substances) or very persistent and very bioaccumulative (vPvB substances)
as defined in Annex XIII of the Regulation (EG) No 1907/2006 (REACH), respectively.
12.6 Other adverse effects
Adsorbed organic bound : The product does not increase the AOX-value of the waste
halogens (AOX) water.
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SAFETY DATA SHEET
DENIMCOL SPEC-RPD
Additional ecological infor- : According to our knowledge, the product does not contain
mation heavy metals and other compounds of EC directive 2000/60
EC.
13. Disposal considerations
13.1 Waste treatment methods

Product : Pay attention to local or official regulations.
Contaminated packaging : Pay attention to local or official regulations.
14. Transport information
14.1 UN number
ADR : Not dangerous goods
IMDG : Not dangerous goods
IATA : Not dangerous goods
14.2 Proper shipping name

14.3 Transport hazard class

14.4 Packing group

Segregation group : -
14.5 Environmental hazards

14.6 Special precautions for user

see chapter 6 - 8
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Remarks : Not applicable
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SAFETY DATA SHEET
DENIMCOL SPEC-RPD
15. Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mix-
ture
Components In accordance : This product is not subject to the Regulation on Detergents.
with Regulation (EC) No.
648/2004 on detergents
15.2 Chemical Safety Assessment

not required
16. Other information

Further information
Other information : This data sheet contains changes from the previous version in
section(s):
9
The information provided in this Safety Data Sheet is correct to the best of our knowledge, infor-
mation and belief at the date of its publication. The information given is designed only as a guid-
ance for safe handling, use, processing, storage, transportation, disposal and release and is not to
be considered a warranty or quality specification. The information relates only to the specific mate-
rial designated and may not be valid for such material used in combination with any other materi-
als or in any process, unless specified in the text.
This safety datasheet only contains information relating to safety and does not replace any prod-
uct information or product specification.
10 / 10

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SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

1. Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

1.3 Details of the supplier of the safety data sheet

CHT R. BEITLICH GMBH BEZEMA AG

Responsible Department : CHT R. BEITLICH GMBH

1.4 Emergency telephone number

2.1 Classification of the substance or mixture

2.2 Label elements

Remarks : No dangerous ingredients according to Regulation (EC) No.

4. First aid measures

4.1 Description of first aid measures

If inhaled : Move to fresh air.

In case of eye contact : Immediately flush eye(s) with plenty of water.

If swallowed : Rinse mouth with water.

5.1 Extinguishing media

5.2 Special hazards arising from the substance or mixture

5.3 Advice for firefighters

6. Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

6.2 Environmental precautions

6.3 Methods and materials for containment and cleaning up

6.4 Reference to other sections

7. Handling and storage

7.1 Precautions for safe handling

Advice on protection against : No special protective measures against fire required.

7.2 Conditions for safe storage, including any incompatibilities

Further information on stor- : Protect from frost.

Advice on common storage : No special precautions required.

German storage class : 12 Non Combustible Liquids

7.3 Specific end use(s)

8. Exposure controls/personal protection

8.1 Control parameters

8.2 Exposure controls

Personal protective equipment

Hand protection : Neoprene

Protective index Class 6

: The choice of an appropriate glove does not only depend on

Eye protection : Safety glasses

Skin and body protection : Wear suitable protective clothing.

Hygiene measures : Avoid contact with skin, eyes and clothing.

Environmental exposure controls

9. Physical and chemical properties

9.1 Information on basic physical and chemical properties

Flash point : Not applicable

Lower explosion limit : Not applicable

Upper explosion limit : Not applicable

Oxidizing properties : Not applicable

Auto-ignition temperature : not auto-flammable

Solidification / Setting point : ca. 0 °C

Boiling point/boiling range : ca. 100 °C

Vapour pressure : ca. 23 hPa

Density : ca. 1 g/cm3

Water solubility : completely miscible

Partition coefficient: n- : Not applicable

Viscosity, dynamic : 1.900 - 2.625 mPa.s

Relative vapour density : Not applicable

Evaporation rate : Not applicable

9.2 Other information

10. Stability and reactivity

10.2 Chemical stability

10.3 Possibility of hazardous reactions