1949, 040172023 CHUYEN DE DOT CHAY- HIDROCACBON - THAY NGUYEN VAN THAI (1) Tai xubag sch [1-45 Cae trang | FipHTMLS LUYEN THI :23- NGO HUE- HAI BA TRUNG~ HANO! THAY NGUYEN VAN THAI 9T:09.789.95.825 2k3 CHUYEN DE PHAN UNG DOT CHA HIDROCACBON DT :09.789.95.825 PHAN UNG DOT CHAY HIDROCACBON 1.Ankan. C,H), | Meo, Mio ‘Ankadien > 0,5<7 <1 Khi dét chay ta thu duge {ne 4, Voi a) “ Ankin > gers 4.Day dong ding cia benzen. CHa Too, > Mu,0 Ki 6 chy dupe { 5.Téng quat.C,Hyy.2-2% -Khik oKhik= 1: neo, = Myo -KhIK> 1 ep, > Muy Meo, kD ees *Cu thé véi hidrocacbon thi: x Neo, Pio mit ankin hoc ankadien cho { Fett: pe Meo hop ede ing ding ding cia benzen (hoa Meo, “Myo =3Me, 1g ding cia benzen) cho LMOT SO BAI TAP CO BAN VE PHAN UNG CHAY Vi dy 1: Bét chéy hodn toan 0,15 mol hén hop 2 ankan thu dirge 9,45 gam nude. Cho sin phim chay hap thu vio dung dich nude vdi trong dur thu duge m gam két tia. Gié tri cia mili ABTS B. 52,5 CAs D.42,5 HD: Chon A psp. comtyvuwivutbrbasic 21481949, 040172023 CHUYEN DE DOT CHAY- HIDROCACBON - THAY NGUYEN VAN THAI (1) Tai xubag sch [1-45 Cae trang | FipHTMLS LUYEN THI: 23- NGO HUE - HAI BA TRUNG ~ HA NOL THAY NGUYEN VAN THAI BT :09.789.95.825 Ta.c6 ny. =0,525 mol —> ney, =0,525-0,15=0,375 mol —> Ney, =0,375 mol S Moy, =375 gam Vi dy 2: Dét chiy hoa toin hin hgp X gém 1 s6xicloankan thu duge (a+ 10) gam mrée va (a +36) gam CO». Gis tr) ctiaa La: ALO B.o C8 D7 HD: Chon C Tac Ney, = yg 2836-2410, a =g 44 18, Vi dy 3: Dét chéy hoan toin hén hop 2 anken thu durge 11,2 lit CO» (dkte). Thé tich khi > (dkte, lit) tham gia phan img la: AL2 B.168 C2224 D.5,6 HD: Chon B Tac6 th, 4y =15Mgo, 0,75 mol V = 16,8 it Vi dy 4; Dot chay hoan toan hén hop X gom etilen, xiclopropan, butilen thay c6 6,72 Lit khi O; (fe), Toin 66 sin phim chéy din qua dung dich mede vai trong du thu duge m gam két tia, Gid tri cia m li: A10 B.IS C.20 D.30 HD: Chon C Tac Mg, 9g = 15M, 'gam Vi dy 5: Dét chay hoan toin hén hgp khi X gdm mot anken va mot monoxicloankan thay 3,36 lit khi O (dkte), sin phim chéy thu durgc dn qua dung dich nude voi trong dur thdy khdi hrong binh ting lén m gam va tach duge p gam két tia, Gid tri cia m va p in lug ba mol > Ney, =0,2 mol > Me¢o, A.6,2 gam va 15 gam B.9,3 gam va 15 gam €.6,2. gam vi 10 gam D. 9,3 gam va 10 gam HD: Chon C Mop, =041 MOl=Nexco, [Ming = Meo, +My, = 6,2 gam Tacé > ss Ayo =0,1 mol m, =10 gam Vi dy 6: DOt chiy Lin luot mt s6 mol nher nha c Jrgng COs nhur nat va ti 16s 3 hidrocacbon X, Y, Z ta thu duge mol CO; cia X, ¥, Z tong img li mol nude déi véi s 05:1: 1,5. CTPT ciia X, ¥, Z lin lugt la A.CoHas CoH: C3Hy B. CsHg; CxHy vit CoH C. CsHy; CoH vit Hy D. CoHy:CoHs; CoH HD: Chon D Vi dot chy X, Y, Z déu thu durge Ineng hidrocacbon nhu nhau > X, Y,Zcing © Dot Zita thay duo My, > Ney, —>Z la ankan: CH,.2 psp. comtyvuwivutbrbasic 1451949, 040172023 CHUYEN DE DOT CHAY- HIDROCACBON - THAY NGUYEN VAN THAI (1) Tai xubag sch [1-45 Cae trang | FipHTMLS LUYEN THI: 23- NGO HUE - HAI BA TRUNG ~ HA NOL THAY NGUYEN VAN THAI BT :09.789.95.825 Mts ona2 52:0, Moo, n Ayo _ 0.5m Meo, 2 Dat CTPT ciia X14 C,H, ;Y 1a C,H, > 7 Neo, Tyo O5P IL.CAC BINH LUQNG SAN PHAM CHAY CO,; H,0 *Phuong phip gid ‘chiy hidrocacbon thu duge hin hyp khi CO, vi hoi H,0. Cac 66 thé gp | . -Cho hdn hop sim phim chay lan luot qua binh 1 dying H2SO, dic va dumg dung dich Ca(OH)> dur thi khéi hong binh m6t tng m, gam; bit Meo, =m, gam -Cho hén hop sin phim chéy qua binh dung dung dich Ca(OH), du thi khdi Iuong , gam dung dich ting m, gam, dng théi xuat hign m, gam két tia. +19, =e, -Tinh khéi hrgng cia HO: Am, 2 hang = (iM gp, + Myo) ~My > My -Néud8 cho khdi lugng dung dich gidm, khi a6: AM 5m =M, = (Meo, +My.) F Myo -Cho hén hgp sin phim chdy qua binh dng dung dich Ca(OH); du thi khéi lugng ‘ting m; gam dng théi xuat hién m, gam két tha. Ta cé AM soe = Meo, +my,9 =m, 1.Vi dy minh hoa Vidy 1: Dét chdy hoan toin m gam hdn hgp 2 hidrocacbon, sin phim chdy cho lin lugt qua binh dyng HjSO, duge dur vao binh hai dymg KOH rin du thay khdi lugng binh mot ‘ting Ién 14,4 gam va bink 2 ting lén 22 gam. Gia tr ctia m la Aq B76 C78 D8 HD: Chon B psp. comtyvuwivutbrbasic 41851949, 040172023 CHUYEN DE DOT CHAY- HIDROCACBON - THAY NGUYEN VAN THAI (1) Tai xubag sch [1-45 Cae trang | FipHTMLS LUYEN THI : 23- NGO HUE - HAI BA TRUNG ~ HANOI THAY NGUYEN VAN THAI 91:09.789.95.25, 2 fy, 2 Siem Tac a > m=m, +m, =12.0,5+2.03 6 gam Tyo = 8 mol 18 Vi dy 2: Dot chdy hod tofin V lit (dkte) mét ankin thu durge 10,8 gam nuréc. Néu cho tit ca sin phim chdy hap thu hét vao binh digg nude v6i trong thi Khoi luong binh tng 50,4 A336 B.2,24 C.6,72 D448 HD: Chon C Tacé —™™ 5n,,, =0,9 mol—n,,,, =0,9-0,6 =0,3 mol > V=6,72 lit b.CTPT cia ankinta: AGH, BCH, C.CyHy D.CsHy HD: Chon B Séinguyen tirC Ty : Bat chy hodn toan mét hidrocacbon X rdi hap thy toan bé sin phdm chay vao binh dug dung dich chita 0,15 mol Ca(OH)2, Sau phin img thu duge 10 gam ket tia tring va thiy khdi lvong dung dich ting thém 6 gam so véi khdi lugng ban diu. CTPT cuia X Ia ACH B. CoH, C.CHy D.GH: HD: Chon C (CO, :x mol Goi f? mg, +My = 44x + 18y =1000,1+ 6 = 16(1). Xét 2TH H,O:y mol yeas n, =0,1 mol 2 = 0. — Hidrocacbon [a ankan THI: Ca(OH), di >| 0,644 mol sca Be _ Ol ggg = 0,644 0,1 = 0,544 mol > $6 C = 018+ Loai Ta, O54 , fi os CaCO, :0,1 mol TH2: Ci CO, va Ca(OH), déu hét, phan img tgo 2 mui Ca(HCO, ), :a mol Reger, = Oa BG) 405 mol pn, 12a =0,2 mol 0,4 mol > x > Hidrocacbon [8 ankan; n, = ,2 mol psp. comtyvuwivutbrbasic 514s1949, 040172023 CHUYEN DE DOT CHAY- HIDROCACBON - THAY NGUYEN VAN THAI (1) Tai xubag sch [1-45 Cae trang | FipHTMLS LUYEN THI: 23: NGO HUE- HAI BA TRUNG ~ HA NOI THAY NGUYEN VAN THAI BT :09.789,95,825, Vi dy 4: Dat chiy hodn toin mét lugng hidrocacbon Y cin 8,96 lit O2 (akte). Sin phim chay cho di qua dung dich Ca(OH)s dur thu duge 25 gam kétttia, CTPT ciia X li ACH B.Coth2 C.CsHia D. Cos HD: Chon C Bh ony.g =2No, -2Meo, = 2.0,4-2.0,2 A, a Myo O41 03 Vi dy 5: DOt chy hoan todn mét lung hidrocacbon X. Hip thy toan b9 sin phim chéy vao binh dung dung dich Ba(OH), dir thu durge 29,55 gam két tia vi Khoi lwong binh. giim 19,35 gam. CTPT ciia X la: —> X Wankan 6 dang C,H... > AGHg B. Call, C.CHy D.GHy HD: Chon C 2 ~015.44— TaC6 Neo, = Nye, => = 0,15 mol yg = >= O1SAN— 19035 _ 99 mot 197 18 Dong, X 1ankan CH, ois 0,2-0,15 = 0,05 mol 35C,H, 0.05 Vi dy 6: Dét chdy hoan toan V lit (dktc) hén hgp 2 olefin (anken) la ding ding lién tiép 18i cho san phim chay lin lurgt qua binh 1 dymg HsS0, ic dur va binh 2 dyng NaOH dic dur thy Khoi long binh 1 tng len (m-+4) gam va binh 2 ting Ién (m + 30) ‘Tinh xem méi binh tang lén bao nhigu gam b.Cho V = 6,72 lit tim CTPT moi anken va % khdi lrgmg eta ching HD: Ta c6 neo, 18x m4 14 gam My, 44x m+30 —> Binh 1 tang (14+4) = 18 gam, binh 2 ting len (14+30) = 44 gam 72 Dat CIPTTB ciia 2 anken 1a C,H. CH, :a mol fa+b=0,3 > > > C,H, sb mol” [3a+4b=1” |b Vi dy 7: Dét chy hoin to’n mot hidrocacbon cn V lit kh O2, cho todn bd sn phim. chéy hip thy hét vio nude voi trong thu duge 10 gam két tia vi 100 ml dung dich mudi 1M cé khdi lugng nang hon khéi lurgng nude voi trong da ding la 8,6 gam. Gid tri cua V ta ),3 mol 250,39 = 1+ i= 333 mol [%Mey, = 60% _[tmen I mol” [Gmme,y, =40% A672 B. 8,96 C. 10,08 D.112 psp. comtyvuwivutbrbasic eas1949, 040172023 CHUYEN DE DOT CHAY- HIDROCACBON - THAY NGUYEN VAN THAI (1) Tai xubag sch [1-45 Cae trang | FipHTMLS LUYEN THI: 23- NGO HUE - HAI BA TRUNG ~ HA NOL THAY NGUYEN VAN THAI BT :09.789.95.825 Oo hen, = Meco, +2Meunen,), = Ol +01 0,3 mot 3 mol > Myo = 5, y= Meo, +30 0,45 mol > V=10,08 iit Vi dy 8: Dét chay hoan todn mot hidrocacbon X thu duge CO va HzO véi ti Ig khdi Iugng twong tmg la 88 : 45, Bét 4,9 gam X réi cho toin bG sin phim chy hip thy hét vio dung dich Ba(OH)» thdy khéi lung binh tng Ién m gam, Gi tr} eda m li A126 B.133 C146 D.15,3 HD: Chon B Taos Mo 88_, Meo. > M arny =44.0,2+18.0,25 = 13,3 Vi dy 9: Ba hidrocacbon X, Y, Z ké 1g ding, khéi lugng phan tir ciia Z pip 46i khdi 1 Iwong phan ti X. Dat chéy hoan todn 0,1 mol chét Y rdi cho tain b6 san phim chay hap thy. hoan ton vio dung dich nude véi trong dur thu durge m gam két ta, Gif trj cua m Ta: A30 B.10 C.20 D.40 HD: Chon A Y: CH, Z:C,H, 13 mol > Macy, = 30 gam Tacé My +2.14=2M, >My acai) Omi yy on a Neo, 1 = Meo, = Vidy 10: Hn hop X gém CH; CaH, va CyHe trong 46 CH, va C)H, 06 cing sé mo. Dat chay x mol hin hap X ri hap thy toan bé san phim chdy vio dung dich Ca(OH), der thu duge m gam két tia va khdi lrgng dung dich giam 7,6 gam. Gia tr) cia m la: A.l0 B.20 C.25 D.14 HD: Chon B ‘CO, :b mol —> CaCO, : b mol b mol Set C,H, :a mol >. { —> BO gidim khoi hegng dung dich > 100b—(44 +18) =7,6 > 16 0,2 mol > Mego, =0,2-100 = 20gam Neo, “Moo, +™My,0) psp. comtyvuwivutbrbasic 74s1949, 040172023 CHUYEN DE DOT CHAY- HIDROCACBON - THAY NGUYEN VAN THAI (1) Tai xubag sch [1-45 Cae trang | FipHTMLS LUYEN THI : 23- NGO HUE - HAI BA TRUNG ~ HANOI THAY NGUYEN VAN THAI 91:09.789.95.25, ILCAC DINH LUAT AP DUNG CHO BAI TOAN DOT CHAY HIDROCACBON *Khi dét m@t hidrocacbon hogc hén hgp hidrocacbon A bat ki ta ludn duge S88) om, my, ‘eo: F™My.0 aro) 1 7m, Mo, ps =Meo, +5 MH.0 Mey +Myyq = 129, + 20 *Néu oxi hoa hgp chit hitu eo A (C.H,O,) bing CuO Eom, +Moe49 Men, +My,o Tong A Moo =Moo Mo, *Vi dy minh hga Bai 1: Bot chay hodn toan m gam hén hop X gdm CHy; CsHg va CuHp thu duge 4,4 gam. COx; 2,52 gam nude. a.Gia tri eda m Las A148 B.2,48 C148 D.24,8 HD: Chon A mam, +My = 12M, +2 =12.0,1+2.0,14 = 148 gam b-Tinh thé tich O, (dkte) t6i thiéu edn ding: A3,808 lit B. 7,616 lit €. 5,376 lit D. 2,24 lit HD: Chon A. Pg, ge Meo, +My = O17 mol —> V =3,808 It Bai 2: Dét chiy m gam hidrocacbon A thu duge 2,688 lit khi COs (Akt) vi 4,32 gam nude 2.Gié tr cia ma A192 B.19.2 €.9.6 D.1,68 HD: Chon A m=m, +m, =0,12.12+2.0,24= 1,92 gam b.CTPT cia A Ia A.CHs B. CH, C.CHy D.CH, HD: Chon D Do Ngo, < Myo > A Rankan: 0,24-0,12 = 0,12 mol Moo, _ O12 a S65 nguyen tir C= = 5 = 1 CTPT cia A BCH, Bai 3: Ddt chay hoan toaina 19,8 gam hdn hgp X gdm 2 ankan thu duge 57,2 gam CO: a,Tinh khdi lugng nude tgo thanh va s6 mol O, phan ing b.Néu 2 ankan ld ding ding ké tiép, hy xe dinh CTPY ca hai ankan va tinh % khdi hgng mdi ankan psp. comtyvuwivutbrbasic ais1949, 040172023 CHUYEN DE DOT CHAY- HIDROCACBON - THAY NGUYEN VAN THAI (1) Tai xubag sch [1-45 Cae trang | FipHTMLS LUYEN THI: 23- NGO HUE - HAI BA TRUNG ~ HA NOL THAY NGUYEN VAN THAI BT :09.789.95.825 Tgp, =1,3 mol HD: Ta c6 og, ou = Neo, + Fo =13+0,52,1= (CH, :x mol n= 1,625 198 13 C,H, :y mol my, =16x+30y =19.8 (x=0,3 mol _ [%mey, = 24,245 > > > Neo, y=05mol — \%mey, =75,76% Bai 4; Dét chy hon toan 5,6 lit (dktc) hn hop X (chi chite cde hidrocacbon & thé tich hi). Din todn bd sin phim chdy qua binh 1 dung H;SOy dic va binh 2 chita nude véi trong dur thy khoi luong binh 1 tng 3,15 gam va binh 2 xuét hign 51,25 gam két tia aTinh My b.Trong X chic chin ¢6 chira hidrocacbon nao sau day? ACH, B.GHy +m =0,175.2+0,5125.12. —> Trong X chiic chain chia CH, Bai 5: Hén hgp A gém etan, ctilen, axetilen, buta-1,3-dien. Bat cl dy hét m gam A, cho sin phim chay hap thy hét_vio dung dich nurée vai trong dur thu duge 100 gam két tia va Khoi rong dung dich gidm 39,8 gam. Gié tr cia m la: 58,75 B.138 C.374 D. 60.2 HD: Chon B 100 -39,8~44.1 Tac No, .9 mol 18 Sm, = me +m), =12.142.0,9=138 gam Bai 6: Hn hop X (cé ti khéi so v6i Hy bang 21,2) gm propan, propen, propin. Khi dét chy hoan toan 0,1 mol X thu duge tong khoi lgng CO) va H,0 1a: A186 B. 18,96 C.204 D.168 HD: Chon B psp. comtyvuwivutbrbasic 9s1949, 040172023 CHUYEN DE DOT CHAY- HIDROCACBON - THAY NGUYEN VAN THAI (1) Tai xubag sch [1-45 Cae trang | FipHTMLS LUYEN THI: 23- NGO HUE - HAI BA TRUNG ~ HA NOL THAY NGUYEN VAN THAI BT :09.789.95.825 Goi CTPT trung binh cita hn hgp X 1a CH, 9 12.3+ mM =21,22 > m=6,4 co, _ [Meo, =03 mol i, Meo, 40 =44.0,3+18.0,37 0,32 mol 2.= 18,96 gam, Ay, Bai 7: Dét chdy hoan toan m gam hén hgp khi A c6 ti khéi so voi Hz bang 21,6 gom CoH; CsHe CiHs ri cho toan b6 san phim chy lin lugt qua binh dung 1 dung H;SO, dae; binh 2 dymg Ca(OH), dur thay khdi long binh 1 ving 10,8 gam cdn binh 2 tang x gam, Gid tri cia x Ia A2728 B.264 €.27,2 D.28,6 HD: Chon A ta thay d9 tang khoi luong trong binh 1 18 kh’ luemg eta nue > ny. =0,6 mol Dat CIPT trung binh 1a C,H, :a mol —> Mi, 1 62.44 Bai 8: Hn hgp khi X gém efilen; metan; propin va vinylaxetilen e6 ti khi d8i v6i Hy bing 17. Dét chéy hoan ton 0,05 mol X rdi hdp thy toain b6 sin phdm chdy qua binh ddymg dung dich Ca(OH): dur thi khdi lrgng ting thém m gam. Gid tr} ea m li A66 B73 €.3,39 D.5,85 HD: Chon B Dat CIPT trung binh co, [Meo, =0.05.2,5=0,125 mol — SS Msag = Moo, +M,o = 7 3AM 2 28 gam H,>128+4=Mon Ayo = 0.05.2 =0,1 mol “s Bai 9: Hon hop X gdm anlen, etilen, metan od ti ki6i so véi Hh bing 11,6. Bét chdy hoan toin 0,1 mol hn hop X rdi cho ton b6 san phim chay vio binh dyng dung dich Ba(OH)> du thu duge m gam két tua, gid tri eda m Las A29,55 B.19,7 C394 D.31,52 HD: Chon D Dat CTPT trung binh cia X 1 CH, > 120 +4=23,2 > = 1,6 EB oiteo, =Mgco, =0s16 MOl > Maco, =0,16.197 = 31,52 gam Bai 10: Phan tich 1,47 gam chat hu co B (chi chita C, H, 0) bing CuO sau thi nghigm thu duge H:0; 2,156 gam CO2 va lugng Cu gidm 1,568 gam. Biét ti khéi hoi cia B so véi khéng khi la d (3 Ny. =0,049 mol > n,, =0,098 mol > Ny “ong imy im, =1:2:1-> CTDGN: CH,O > CTTN(CH,0), Vi3 n=3 >C,H,O, VLQUAN HE SO MOL SAN PHAM CHAY VOI SO MOL HIDROCACBON TRONG HON HOP BAN DAU. Bi 1: Dét chdy hoan ton 0,1 mol hn hop X gom CHg; CoH; Cath thu duge 0,14 mol CO; vi 0,23 mol HO a .86 mol cia ankan vi anken c6 trong hén hgp kan larg li: HD: Chon A A.0,09 vi 0,01 B.0,01 80,09 C.0,09 va0,02—_—D. 0,02 va 0,08 TaCE Nyy, =My.g —Ney, =0.23-0,14 =0,09 mol > n,,,, =0,1-0,09 =0,01 mol b.% khoi lurgng ciia CoH, trong X la: HD: Chon A A1443% B.85,57% C.14,66% D.85,34% , 28.0,01 Ta e6 my =12.0,14+0,26 =1,94 gam —> Emo, = 10M = 14.43% Bai 2: Bét chdy hodn toan hin hgp gm 1 ankan va 1 anken, Cho sin phém chiy lén lugt di qua binh dyng P.O; va binh 2 dying KOH rin du; sau phan ting thdy binh mt ting 4,14 gam, binh 2 ting 6,16 gam, S6 mol ankan e6 trong hén hgp li 4.0.03 B. 0,06 C. 0,045 D. 0,09 HD: Chon D Taco binh P.O, hap thy H,O cdn KOH hap thy CO, oy, = 0,14 mol > Magy = 0,23-0,14 = 0,09 mol 44 a Nyy = =0,23 mol eB Bai 3: Dét chat hodn toan hdn hop X gdm mot anken va mot ankin rdi cho san phim chay i qua binh (1) dumg H2SO, dae va binh (2) dung NaOH rin du, sau phan ting thay khdi lugng binh (1) ting 3,6 gam vi binh (2) tang 15,84 gam, Sé mol ankin ¢6 trong X li A015 B.0,16 C.017 D.0,18 HD: Chon B psp. comtyvuwivutbrbasic ms1949, 040172023 psp. comtyvuwivutbrbasic CHUYEN DE DOT CHAY- HIDROCACBON - THAY NGUYEN VAN THAI (1) Tai xubag sch [1-45 Cae trang | FipHTMLS LUYEN THI: 23- NGO HUE - HAI BA TRUNG ~ HA NOL THAY NGUYEN VAN THAI BT :09.789.95.825 gp, = 184 0,36 mol Tacé “4 on, 0,2 mol 136 -0,2 = 0,16 mol To = Tg Bai 4: Cho 2,24 lit hn hop khi A (dkte) gbm etan; propan; propilen sue qua dung dich nude brom du thdy khdi lrgng binh ting 2,1 gam. Dét chay khi con lai thu duge 3,24 gam nude. $6 mol CsHy 06 trong A A.0,05 mol B. 0,02 mol €.0,03 mol D.0,0525 mol HD: Chon C 21 Do tang Khoi lug binh chin Wein anken ny, = 5 = 0,05 mol C,H, :4 mol 1-0,05 =0,05 mol > Goi CH, :b mol 0,02 mol 0,05 - 0.18 0,03 mol Bai 5: Dét chy hoan toan hén hop X gdm 2 anken vi 0,1 mol CHy thu duge 11,2 lit khi CO. (akte) vim gam nude, Gié tri cha m la: A108 Bo C126 D144 HD: Chon A Tac Ney, =Nyyo Meo, =O PM yy =0,1+0,5 Bai 6: Hén hop X gdm mot ankan, mt anken, mt xicloankan trong dé xicloankan vi anken c cing sé nguyén tir cacbon trong phan tit, Bot chiy 0,6 mol hén hop nay thu duge 44 gam CO; va 19,8 gam nude. CTPT va % thé tich cia ankan c6 trong X la: ACH vi 25% —B.CHy vi 50% ——C.CzHg Vi 75% —_D. GH, va 45% HD: Chon A TACO Dyan 0,6 mol > m,,. = 10,8gam 13 mol Meo, = M=1= 0,1 MOL My sentan = ‘Anken va xicloankan: C,H,, :0,3 mol Dat) Ankan:C,,H,,,,. :0,1 mol BEL site, \aesin-1f nzam21 HV cy, = 25% Bai 7: Dét chay hoan toan 18,6 gam hén hop X gom C3Hy; CsHg; CsHyo trong dé s6 mol CsHy bing s6 mol C4Ho thu duge 57,2 gam CO». Khéi lugng clia C)Hy trong X la: Ag B56 C42 D. 126 HD: Chon A 121s1949, 040172023 CHUYEN DE DOT CHAY- HIDROCACBON - THAY NGUYEN VAN THAI (1) Tai xubag sch [1-45 Cae trang | FipHTMLS LUYEN THI: 23- NGO HUE - HAI BA TRUNG ~ HA NOL THAY NGUYEN VAN THAI BT :09.789.95.825 —> $6 mol mB ankan [80,1 mol My, Bai 8: Bdt chdy hon todn 3,16 gam hn hgp X gbm C3H, va mo CO; vi HO trong 46 khdi lugng CO; nhiéu hon nude li'5 gam. % khdi lugng cia CoH, trong X lit A37,9% B. 62,03% €.39,77% D. 60,23% HD: Chon A CO, :x mol {m, =12x+2y=316 a Xmol_, fm, =12x+2y _, [x =0.22 mot ymol |44x-18; > Meyy, =0,26 0,22 = 0,04 mol — Fem, V.PHUONG PHAP TRUNG BIN! Lau § -V6i cdc chat khi thi % theo s6 mol li % theo thé tich ~ Khi goi % theo sé mol chat thir nhat 1a t% thi % chat thir hai 1a (1-t)%. Khi dé ta 6 eng thite sau: (=D, M=1M, +(1-1)M, *Vi dy minh hoa . Vi dy 1: Ti khoi hoi cia hon hop khi X gom CsHg va CsHyo so voi Hz bing 25,5. Tinh % thé tich etia mdi khi CH, 11% CoH 21 — Vi dy 2: Hon sp ee X gdm anken M va ankin N e6 cling sé nguyén tit eacbon trong phan tir, Hén hgp X 6 khéi luong 12,4 gam va thé tich 6,72 lit (akte). S6 mol, céng thire phan tiroua M va N lin lt i A.0,1 mol C)H, va 0,2 mol C)H» B. 0,1 mol CsHy va 0,2 mol CsH, C. 0,2 mol CH, va 0,1 mol C,H> D. 0,2 mol C3Hg va 0,1 mol CsHy HD: Chon B CHU wy =42t+4001—t "cn, d-n% 7M gy 7M =44t 4581-1) = 255.291 = 50% 2 a ey, =F. 03=0.2 mol vA ney, =0,1 mol psp. comtyvuwivutbrbasic 1951949, 040172023 CHUYEN DE DOT CHAY- HIDROCACBON - THAY NGUYEN VAN THAI (1) Tai xubag sch [1-45 Cae trang | FipHTMLS LUYEN THI: 23- NGO HUE - HAI BA TRUNG ~ HA NOL THAY NGUYEN VAN THAI BT :09.789.95.825 V.CAC PHUONG PHAP GIAI BAI TAP 1.Phuong php lip etpt cia hai hidrocacbon 1a ding dang ké tiép Bai 1: Mt hdn hgp X gdm 2 ankan déng ding ké tiép 6 khdi long 24,8 gam. Thé tich tuong img la 11,2 lit (dkte), Xéc dinh céng thite phan tir vi % thé tich cia 2 ankan Goi CT cia ankan e6 dang C,H,,,» 0,5 mol 140 +2 = 49,6 > 1=3,4 { CH, 21% i > Hy 1-0% Bai 2: Dét chy hoan toan hdn hgp X gdm hai ankin déng ding ké HO 6 ti Ié mol twomg ting 14 10: a.Céng thire phan tir cia 2 ankin Bt eat At =0,6 > 60% ip thu duge CO2 va ‘A.CoHa; CoH B.CsHy CiHy C. CHa; CH D. CsHy; CcHio Tinh % s6 mol cia 2 ankin HD: Chon B Dat CPT trung binh la C,H, , > CH, 2t% me) — Hai ankin, O93 + 4,11} CH :-9% CH, :66,67% = C,H :33,33% .Tinh % khéi lugng cia 2 ankin Ney, =2 mol Frey, =59.T% Chon > m, = 134 gam > ey, =1 mol FAI), = 40.3% Bai 3: Bét chiy hn hop X gém 2 ankan mol tong img li 8:11 a.CTPT cita 2 ankan la: A.C3Hg CsHs B. CHy; CoH C. GHy CH io, D.C\Hio; CsHi HD: Chon A Goi CTPT tung binh citaankan la C, Hy, 29 CH, 11% 34 BO 52143.-9), CH, (1-9 % b.Tinh % thé tich 2 ankan A.40%; 60% B. 33,33% vA 66,67% 1 {C,H, 33.33% sis CH, :66,67% psp. comtyvuwivutbrbasic sats1949, 040172023 CHUYEN DE DOT CHAY- HIDROCACBON - THAY NGUYEN VAN THAI (1) Tai xubag sch [1-45 Cae trang | FipHTMLS LUYEN THI: 23- NGO HUE- HAI BA TRUNG - HANOI THAY NGUYEN VAN THAI BT :09.789,95,825, C. 45% va 55% D. 30% va 70% HD: Chon B Bai 4: Dot chay hoan toan 22,2 gam hdn hgp M gom 2 ankan dong ding ké tiép can ding vita hét 54,88 lit khi O, (dkte). Xie dinh CTPT va % khdi long ctia moi ankan Dat CTPT trung binh 2 ankan C,H, CH, :x mol CH :¥ mol so, M4m+2 _ 3+ oa 22,2” 22,45 12+ ata | 86x + 100y =22,2 Fey, TTAB 2% 4n,, = 95x41 ly 105 mol” [seine y, =22,52% Bai S: Dét chay hoan todin m6t lugng hdn hyp A gdm 2 ankan ding dang ké tiép thu durge khdi lung CO, va HO v6i ti leh twong ting la 110/63 a.Céng thire phan tir cia 2 ankan li ACH, vi GH, B. GH va CsHy C.GHy va Cho D. CiFlio va CHiz HD: Chon B b.Tinh % s6 mol ciia 2 ankan AAN% va 60% B. 33,33% vA 66,67% C. 50% va 50% D. 30% va 70% HD: Chon C Goi CTPT trung binh ctia ankan 1 CH, 1% ey : 0143. = =2,5 CH, 00% C,H, :50% 1-055 CH, :50% 2.Phuong phap lip ctpt cia hidrocabon thudc ciing day dng ding a.Phuong phip gi Dt cng thite phan tt eita hidrocacbon ta | 8 CxHaw2-2 4 mol B:C,Hyq,. 4 :b mol at cOng thite trung binh cia 2 hidrocacbon la: gH,» 24 :(@+b) mol ‘ Neo, 86 nguyén tir € trung binh 7 = — Thy b.Vi dy minh hoa psp. comtyvuwivutbrbasic 15451949, 040172023 CHUYEN DE DOT CHAY- HIDROCACBON - THAY NGUYEN VAN THAI (1) Tai xubag sch [1-45 Cae trang | FipHTMLS LUYEN THI : 23- NGO HUE - HAI BA TRUNG ~ HANOI THAV NGUYEN VAN THAI -BT09.789.95.695 Bai 1: Dét chy hoa toin m gam én hgp X gém hai ankan A, B (Ma = 3 2k 6» Alan | t+4(I-t=3>t CH, 50% > C,H, :50% (C,H, :0,5 mol Yom, C,H, :0,5 mol com emnasssins-2 emf Me, Bai 3: M@t hin hgp gdm 2 ankan c6 khéi hrong 10,2 gam. Dét chdy hoan todn hn hop nay edn ding 25,76 lit O2 (dktc) im tng s mol hai ankan b.Tinh khdi lung CO. va H20 tao think ¢.Tim CTPT ciia hai ankan biét khdi Iugng phan tir cia mi ankan khong qui 60 HD: CO,;a mol (44a+18b=10,2+32.115=47 _ [a=0,7 mol Day > > bmol © |—242a4b=115.2 b=0,9 mol 8. yy =Bj9—Nep, =0,9-0,7 =0,2 mol gp {Meo = 0.7.44 = 30,8 gam myo =0,9.18 = 16,2 gam psp. comtyvuwivutbrbasic 16451949, 040172023 CHUYEN DE DOT CHAY- HIDROCACBON - THAY NGUYEN VAN THAI (1) Tai xubag sch [1-45 Cae trang | FipHTMLS LUYEN THI: 23- NGO HUE - HAI BA TRUNG ~ HA NOL THAY NGUYEN VAN THAI BT :09.789.95.825 Da CTPT | Ankin:C,H,,, , :0,15 mol —2240,15n+0,15m = m>2 psp. comtyvuwivutbrbasic 481949, 040172023 CHUYEN DE DOT CHAY- HIDROCACBON - THAY NGUYEN VAN THAI (1) Tai xubag sch [1-45 Cae trang | FipHTMLS LUYEN THI: 23- NGO HUE - HAI BA TRUNG ~ HA NOL THAY NGUYEN VAN THAI BT :09.789.95.825 Bai 7: Dét chy hon toin hn hp A gim CHC. vi 18x gam HO. % thé tich cia CH, trong A la CoH; CuHa thu drge x mol COs 430% B. 40% €.50% D. 60% HD: Chon C Goi gy, =Myo =X mol va cong thee chung ciia hén hgp 1a C,H,» Fy, =F, , = 50% Bai 8: Hn hop khi X gdm mot ankan va mot anken. Ti khdi hoi cia X so véi Hs bing 11,25. Dét chay hodn toin 4,48 lit X thu duge 6,72 lit khi CO: (cde khi déu do 6 diéu kign tiéu chun). CTPT cia ankan va anken lan hugt 1: A.CHg: Cay B. CaHe; CoHy C.CHy CoH D. CHg CoH HD: Chon D ‘Ankan : CH, :a mol > Chie chin 6 CH, +X. Anken: C,H, :b mol Smee es, nay kia thu duge CO. vi HO trong dé khdi lurgng ciia CO; lén hon HO bang 8,28 gam. Tim CTPT ctia hai chit trong X? HD: (CO, :x mol _, Dat H,0:y mol” 12x4+2y =5,16 + 4x ~18y =8,28 1,06 mol =n 0. Ankan: C,Hy..> Goi CTPT} Xicloankan : C,H. nekm>3 im, CH, > > n=2 ”|C\Hy Bai 10: A 18 ankan, B ld anken (déu 6 thé tich khi 6 digu kign thurmg) -Thi nghigm 1: Dat chay hodn toan 0,1 mol hn hgp chia a mol A va b mol B thu duge khdi rong CO; lin hon khéi long nude la 7,6 gam «thi nghigm 2: Bét chy hoan toan 0,1 mol hn bgp chita a mol B va b mol A thu duge khéi rong CO; lém hom mude 1a 6,2 gam Xée dinh CTPT ciia A, B. Biét sé nguyén tir cacbon trong B Ién hon trong A on. 0,06 mol 0,06 mot"! n,.,, =(m-+n).0,06 =0,36 HD: psp. comtyvuwivutbrbasic 204s,1949, 040172023 CHUYEN DE DOT CHAY- HIDROCACBON - THAY NGUYEN VAN THAI (1) Tai xubag sch [1-45 Cae trang | FipHTMLS LUYEN THI: 23: NGO HUE- HAI BA TRUNG ~ HA NOI THAY NGUYEN VAN THAI BT :09.789,95,825, ‘Ankan : C,H,,,) :a mol ‘Thinghiem 1: Dat CIPT cia Anken :C,H,,, :b mol n> 1m22;m>n a+b=n, =0,l mol = —2-54,(na+ mb) 18,(n-+Da+mb)]}=7,6 Xét thi nghi¢m 2—°> 44(nb + ma) —18.[(n-+ Da+mb] (2) n=2 (CH, Tw (1) ae) ° yeaa fat fl Bai 11: Cho hén hgp A ¢6 khéi lugng 7,6 gam gdm 2,24 lit hidrocacbon mach thing A vi 1,12 lit ankin Y. Bét chay hoan toan hén hyp r6i hip thy toan b6 sin phim chay vao binh dumg dung dich Ba(OH), dur thu durge 108,35 gam két tia aXée dinh day déng ding cia X b.Xée dinh CTPT cia X, Y biét ching hon kém nhau mét nguyén tit cacbon trong phan tir =1 mol ny, =0,5 mol ba X:C\Hayaae 01 mol_, [250,10 +0n05m =0,55 CTT LY Hy, «005 mol ~ |0,L¢n+1-k) +0,05m—1 =0.5 +k =1> Hidrocacbon mach thing X la anken C, CH, CH, VLBAL TAP TONG HOP VE PHAN UNG DOT CHAT HIDROCACBON Bai 1: Ddt chdy hoan toan 20 ml hdn hap khi X gdm CsHg; CHy; CO (thé tich CO gi thé tich CH,) thu durge 24 ml CO, (eéc thé tich do & cing diéu kign nhiét 46 vi m=3 > > Hai hidrocacbon 1a n=4 t). Ti khéi cita X so voi Hy 1a: A129 B.I1I C.25,8 D.22,2 HD: Chon A psp. comtyvuwivutbrbasic 204s;1949, 040172023 CHUYEN DE DOT CHAY- HIDROCACBON - THAY NGUYEN VAN THAI (1) Tai xubag sch [1-45 Cae trang | FipHTMLS LUYEN THI: 23- NGO HUE - HAI BA TRUNG ~ HA NOL THAY NGUYEN VAN THAI BT :09.789.95.825 CH, :x mol Va =x+3¥=20 fxn? Goi {CH, :y mol > > Joo, = 38 +3y =24” Ly CO:2y mol " 2.42-+6.16+ 12.28 9 yg, 2 20.2 Bai 2: Hén hop A gém hidrocabcon X vi O2 c6 ti Ig mol tuong img la 1 :10, Bat chay hodn toan hdn hop A thu duge hén hop khi Y. Cho Y qua dung dich H.SO, die thu duro hn hop hi Z 08 ti khdi so v6i Hy bing 19. CTPT ota X la ACH B.CsHly C.CsHy D. Cis HD: Chon D Dat CIPT iia X la CH, Chon ny =1 mol > ng, =10 mol CO, :x mol 44x +32.(10-(x +2) 2 ¥\ R= 0, asa0-[x+2) mot x0 = scmraiax ACH, y-8 Bai 3: Dét chy hon toa 6,72 lit (ktc) hn hgp gdm 2 hidrocacbon X va Y (Mx < My) thu duge 11,2 lit COs (Akte) va 10,8 gam nude. Cong thite cia X li: ACHs BG CCH DCH, HD: Chon A ,67 > Phi 6 CH, *Bai tip nfing cao Bai 4; Hn hgp X gdm O, va O; c6 ti khdi so véi He bing 10. Tinh thé tich cia hin hgp X dé dt chi hoan toan 25 lithén hop Y gdm 2 ankan ding ding ké tiép thude diy ding dang Ké tiép c6 ti khdi so véi He bing 11,875 (cée thé tich do 6 cing digu kign nhigt 46 va dp suit) A.105,7 B.107,5 c.107 D. 105 HD: Chon B (0, :x mol V, =2x+3y Goi xX} va CTPT trung binh 2 ankan la CpHyy,9 —> 0, :y mol . x=y Vv, =5x - > Vp = 25.31 +1) = 268,75 = 5x. IM, =47,5> 14n+2 5 psp. comtyvuwivutbrbasic 25481949, 040172023 CHUYEN DE DOT CHAY- HIDROCACBON - THAY NGUYEN VAN THAI (1) Tai xubag sch [1-45 Cae trang | FipHTMLS LUYEN THI: 23- NGO HUE - HAI BA TRUNG ~ HA NOL THAY NGUYEN VAN THAI BT :09.789.95.825 > x=53,75 lit > Vy =x + y=2x=2.53,75=107,5 lit Bai 5: Cho hin hop X gdm 3 hidrocacbon X,; Xa; Xs thude 3 day dng ding va hin hop khi Y gm O> vi Os (ti khéi hoi cia Y so véi Hy bing 19). Tron X véi Y theo ti 1g tuong ding 1A 1,5 : 3.2 ri dét chay hdn hop thu duge sau phan img chi cé CO, va H,O 06 ti 1é ich trong img I 1,3 : 1,2.(Cée thé tich khi va hoi do 6 cing digu kien nhiét 46 va dp suit), Ti khéi hoi cia X so véi Hy bing: Ald B.10 C2 D112 HD: Chon C BAI TAP HUAN LUYEN Bai 1: Dot chéy hoan to’n 0,12 mol hén hop A gdm mét s6 ankan thu dirge 0,33 mol ©, viix gam mide. Git tri cia xl A36 B54 e712 D.81 HD: Chon D Ta €6 My, =Masun + Neo, = O12+0,33 Bai 2: Dét chéy hoan toin hén hgp 2 anken thu duge 7,2 gam nude. Cho ton bdi khi CO; vira thu duge vao dung dich Ca(OH): du thi thu duge m gam két tha. Gid tri cua m. la A40 B.20 c.100 D.200 HD: Chon A Tac6 Neco, 4.100 = 40 gam Bai 3: Dét chiy hoan toin 3 hén hgp anken thu duge (m + 3,2) gam CO; va (m— 46) gam muse. Gié trj eda m li A100 B. 102 C.84 D.92 HD: Chon A anken m+32_ 3-46 Bt gg, = Myo P= > m = 100 gam, 4a OB Bal 4: Bét chéy hodn toan 0,15 mol hén hop hai ankan thu duge 9,45 gam nude, Cho toan b6 sin pham chay hap thy vio dung dich Ca(OH). dir thu duge m gam két tia, Gia tri ctia m li: ABTS B.525 CAS D.42,5 psp. comtyvuwivutbrbasic 2645,1949, 040172023 CHUYEN DE DOT CHAY- HIDROCACBON - THAY NGUYEN VAN THAI (1) Tai xubag sch [1-45 Cae trang | FipHTMLS LUYEN THI: 23: NGO HUE- HAI BA TRUNG ~ HA NOI THAY NGUYEN VAN THAI BT :09.789,95,825, HD: Chon A Tacd Moco, = Meo, 0525-041 17,5 gam Bai 5: Dét chiy hodn toin 0,56 lit butan (dkte) va cho toin b§ sin phim chiy hap thy hét vao binh dig 400 ml dung dich Ba(OH)s 0,2M dén khi phan img hoan toa, Hoi khdi Iugng dung dich trong binh thay 45i nhu thé nao? 1.375 mol > m, Agiams,17g B.Tang 428g ——C. tang 6,26g D. gidm 2.56, HD: Chon A Meo, = 0,025.4 =0,1 mol Stet yg = 0,025.5 mol Bg oyn, =O14.0,2 = 0,08 mol aiweT= to Ol <5 [BaCO, :x mol Xét tile ME 1,25 > C6 2 musi Agvou, 0408 Ba(HCO,), :y mol seo, =X 29 = OL frroce mol > > At so, =X = 0,08 Ly =0,02 mol =197.0,06 ~ 44,0,1~18.0,125 = Bi 6: Bét chiy hon todn V lit (dktc) mét hidrocacbon 6 thé Kkhi (trong s6 ankan, anken, ankin) thu duge CO2 va H;O ¢6 tong khdi hong bling 25,2 gam. Néu cho san phim chiy qua dung dich Ca(OH)» du thu durge 45 gam a.Gia trj cua V la: 17 gam A612 B.2,24 C448 D.3,36 HD: Chon D Mey, “Peso, “7 OAS mol Tacs 100 Ny Hidrocacbon la ankin —>n,,,, ~0,45~0,3=0,15mol + V =0,15.22,4 = 3.36 It b.CTPT cia hidrocaebon li ACH B.Call CCl, D.Colly HD: Chon B ‘So nguyen tir C= 2% = 9-45 3 _, crpr acu, OS Dain Bai 7: Bot chiy hodn toan 4,64 gam mét hidrocacbon X (chit khi & diéu kign thuémg) ri dem toan bé sin phim chy hap thu hét vio binh dung dung dich Ba(OH). Sau phan img, thud uduge 39,4 gam két tika va khdi lugng phan dung dich giam bét 19,912 gam, Cong thire phi tr ita X ta psp. comtyvuwivutbrbasic 274s,1949, 040172023 CHUYEN DE DOT CHAY- HIDROCACBON - THAY NGUYEN VAN THAI (1) Tai xubag sch [1-45 Cae trang | FipHTMLS LUYEN THI: 23- NGO HUE - HAI BA TRUNG ~ HA NOL THAY NGUYEN VAN THAI BT :09.789.95.825 Act B.C cats HD: Chon B | [oo =o [HD Fy ado a of jin =I, ~(Ng, 4g 9) 9-44 By = 19,488 Ayo =y mol x= 0,348 mol one My = 0,348: 0,464 = 3:4 > CH, y= 0,232 mol Bai 8: Dét chiy hoan toain 1,12 lit (dktc) mét hidrocacbon x ri cho toan bd chay hip thy hét vao binh dung dung dich Ca(OH), thay tgo ra 10 gam két tita, khdi Iugng dung dich trong binh 1én hon 2,4 gam so véi dung dich Ca(OH)s ban du. Mat khac néu dun dung dich Y dén phan img hoan toan lai thu duge 5 gam ket tia nv, Cong, thire phi tr etta X ta AGHs ie C.GHy D.CiHs HD: Chon D E5165, = Meco, +2Meu ico, =041+0,05.2=0,2 mol 2 mol binh kin: binh 1 dymg dung dich H,SO, dic thy khdi Iuong binh tang 6,3 gam;binh 2 dung dung dich Ca(OH), thay toa ra 10 gam két tia. CTPT cia X 1a: A.CiHe B.CHy C.CiHa D. Callie HD: Chon D "neo, CTPT eta X li ankan dang C,Ha,,. Myo m1 _ 0,35 co BOB Bai 10: Dt chy hodn toa 0,336 lit khi (dkte) mot ankadien lién hop X ri cho toan b6 sin phim chéy hdp thy hodn to’n vio 40 ml dung dich Ba(OH): 1,5M thu dugc 8,865 gam két tia, CTPT ctia X la AGH B. CH, C.CsHs D. GHs hoje CsHy o> 5n=6> CIPT cia XB CH, psp. comtyvuwivutbrbasic 204s1949, 040172023 CHUYEN DE DOT CHAY- HIDROCACBON - THAY NGUYEN VAN THAI (1) Tai xubag sch [1-45 Cae trang | FipHTMLS LUYEN THI: 23- NGO HUE - HAI BA TRUNG ~ HA NOL THAY NGUYEN VAN THAI BT :09.789.95.825 HD: Chon D Manon), 1,04.1,5 = 0,06 mol Tees > Mav, > Masco, C6 2 treme hi go, = 2888 = 0,045 mol “ , 1s hop 197 THI: Ba(OH), du 6 3-9 CTPT citaX 1 CH, 0,06 -0,045 1,015 mol TH2: Ba(OH), hét > }—™5n,,, = ,045 + 0,015.2 1.075 mol Noo, _ 0,075 ny 0,015 Bai 11: Bét chay hodn toan 20,4 gam hin hop X gdm hai diing 51,52 lit khi 03 (dkte) a.Tinh thé tich cita CO, (dktc) va khdi lugng mrée tao thinh b.Xée dinh CTPT va tinh % thé tich cde hidrocacbon, biét céc hidrocacbon déu 6 > %C > CH, idrocacbon no mach hé can thé khi 6 didu kign thutmg HD: Moo, =Xmol_— [my =m, +my > 12x +2y = 20,4 = bat Me My PDF = 204 [x= 1,4 mol Myo =y mol” |>x+0,5y=2,3 y=L8 mol > Veo, =31,36 lit va my, =32,4 gam —> C > COC Hy CH, :1% Xét cap ong =t44 (lt) ot = 16,67% C\Hy 11-9% CH 125% (CyH, 150% ‘Tuong tur v6i 2 tnxdmg hop cdn lai tas | C\Hyy 175% “* [C,H 150% Bai 12: Dot chay hoan toan 0,5 mol hn hgp 2 ankin ding ding ké tiép thu duge 1,2 mol CO, a.Tinh thé tich O, (dkte) cn li: ADA it B. 3346 lit 34,72 lt D. 44,8 lit HD: Chon C TACO My. =Meo, ~May =0.7 mol" ng, =Me, 5m 9 = 155 mol > V=1,55.22,4=34,72 lit b Xe dinh CTPT cia 2 ankin? psp. comtyvuwivutbrbasic 204s1949, 040172023 CHUYEN DE DOT CHAY- HIDROCACBON - THAY NGUYEN VAN THAI (1) Tai xubag sch [1-45 Cae trang | FipHTMLS LUYEN THI: 23- NGO HUE - HAI BA TRUNG ~ HA NOL THAY NGUYEN VAN THAI BT :09.789.95.825 AGH: vaCsHy B.CsHyva Hy C.CiHevaCsHy DL GH: va Cas MD: Chon A CH, Tacéii=24 > CH, c.Tinh % thé tich 2 ankin? A.50%; 50% ——-B. 60%; 40% C. 35%: 65% D. 45%; 55% HD: Chon B CH, 11% t=0,6 > CH, :60% Goi | > > “ lems 1-0% {on 0% ‘bt chdy hoain ton hén hop gdm 0,02 mol anken va 0,03 mol ankan rdi cho ton 6 san phim chdy hip thy vio dung dich Ca(OH); du thu duge 12 gam két tia, Cong thire phan tr eta hai hidrocacbon li: A.CHg Hs B.C Hy CGH GaHs —D. GHCaHs HD: Chon C ‘Anken :C,H,, 20,02 mol ney Dat Mo sng, =0,02n-+0,03m =0,12 Ankan :C,,H,,, £0.03 mol in=3 (CH, > > m=2” |C,H, Bai 14: Hn hop A gm ankadien A va ankin B, Bét chdy hodn toin 0,4 mol hn hop X thu duge 54,8 gam hén hgp CO; va HO. CTPT cua A va B Lin lugt k AGHgCHe BCH CHy C.CdHg GHz. Cols: Gy HD: Chon C Dat CIPT trung binh cia 2 hidrocacbon 1a C,H, Ne, “Myo =0.4 mol —_ [neo, =1 mol Tacé > 44 co, + 18M yg =54,8 Tyo =0,6 mol ‘ya 2,7 gam nude. Tinh thé tich khi O2 (dkte) da tham gia phan img la: A28 lit B. 4,48 lt C.3,92 lit D. 5.6 lit HD: Chon C 50 0,1+0,5.0,15 =0,175 mol > V,, =3,92 lit Bai 16: Dét chiy hodn to’n m gam mét hidrocacbon thu dirge 44 gam CO> va 18 gam. nude. Gid tri ctia m li All B12 c.13 D.14 HD: Chon D Tacém=m, +m, =12.neo, +29 =12.1+2.1=14 gam psp. comtyvuwivutbrbasic 30451949, 040172023 CHUYEN DE DOT CHAY- HIDROCACBON - THAY NGUYEN VAN THAI (1) Tai xubag sch [1-45 Cae trang | FipHTMLS LUYEN THI: 23- NGO HUE- HAI BA TRUNG - HANOI THAY NGUYEN VAN THAI BT :09.789,95,825, BA 17; Bét chy hodn toin a gam hin hgp gdm hidrocacbon thu duge 33 gam COs va 27 gam nude. Gis tr cia a la All B12 C3 D.14 HD: Chon B Tacé m=me +My =12.ne, +249 =12. Bai 18: Hén hop X gom mét ankan, m6t anken va Hy. Dét chay hoin toan 8,96 lit khiX (Aktc) thu due 22 gam CO, va 14,4 gam nude. Ti khdi hoi etia X so véi khong kh i A.0,555 B. 0,655 €..0,565 D. 0,567 HD: Chon B 12 29 Bai 19: Hn hop Y gdm ba hidrocacbon 6 ti khdi so véi Hy bing 16,5. Khi dét chay hoan toin 0,2 mol hn hgp Y, sin phim chdy Hin gt cho qua binh (1) dymg dung dich H,SO, dae va binh (2) dmg dung dich Ba(OH)> du. Sau phan img khéi Ivong binh (1) tng 10,8 gam va binh (2) thu durge m gam két tia, Gid tri cua m gan nhat véi: AMS B.59,1 C.88,7 C.78,8 HD: Chon C 0,655 Ta c6 mg =me +m, =12.0,5+20, 19 dy, 33.0,2=6,6 gam Feo, =0.45 mol > Meo, =0,45 mol Bai 20: Dét chdy hoan ton hn hgp khi A cé ti khéi hoi so véi H bing 21,2 gm C;Hy; CH; C3H, thu dage 52,8 gam CO; va x gam nue. Gi tr ct x Ha A216 B. 23,04 C225 D. 198 HD: Chon B Tacé M, =42, 32, sep, = 28 =1,2 mol > Dat CTPT trung 44 ih fa C,H, :a mol >My 2.34+H= 2.4 > 9=6,4 >, 1,28 mol > m,,, =23,04 gam Bai 21: Hin hop X gdm C;Hy; CsHg; CsHy ¢6 ti khdi so véi H, bing 21, Dot chdy hoan ton 1,12 lit hin hop khi X (dktc) ri din sin phim chiy vao binh dymg dung dich nude -v6i trong dv thi khéi lirgng binh ting lén bao nhieu? A27 B. 66 C73 D.93 HD: Chon D Tac6 kh6i lugng binh tang =meo, +My, =9.3 gam psp. comtyvuwivutbrbasic as1949, 040172023 CHUYEN DE DOT CHAY- HIDROCACBON - THAY NGUYEN VAN THAI (1) Tai xubag sch [1-45 Cae trang | FipHTMLS LUYEN THI: 23: NGO HUE- HAI BA TRUNG ~ HA NOI THAY NGUYEN VAN THAI BT :09.789,95,825, Bai 22: Hn hop X gim CsH; CsHy; C:Hs 06 khéi long phan tr trung binh la 28. Bét chiy hoan ton 0,5 mol hén hop X réi din toan b6 sin pham chéy qua dich KOH dur thay khéi long binh ting Ién m gam. Gia tri eta m Las ABI B. 62 B.27 D.32 HD: Chon B Taco kh6i luong binh tang = Meo, + Myo =62gam Bai 23: Hn hop khi X gm CoH; CsHy va CyH. Ti khdi etia X s0 v dich Ba(OH), 0,05M, Sau phan img thu duge m gam két tia, Gia tr A985 B.5,91 C.13,79 HD: Chon B Dat CTPT trung binh la CH, —> 1211+48 = 48 > Ng, =0,07 moking, gy), =0,05.1=0,05 mol > T= HCO, :amol [Mp =a+b > Team > CO, :bmol [ng =a+2 Ngo, = 0403 mol > Myo, =0,03.197 = 5,91 gam Bai 24: Hin hgp X gdm propin, propan va propilen c6 ti khéi vi H, bing 21,2. Dét chay hoin toan 15,9 gam X sau 46 hap thy ton b9 sin phim vio binh dung 1 lit dung dich Ba(OH), 0,8M thdy khéi lugng binh ting Ién m gam va ob a gam két tia, Gid tri cia mva a Kin wot li: 71,1 gam va 93,575 gam B. 71,1 gam va 73,875 gam C. 42,4 gam va 63,04 gam D. 42,4 gam va 157,6 gam HD: Chon A Dat CIPT tnung binh la GH, > 12.3+y =42,4 >y=6,4 > eo, =1125 mok:ny,o =12 mol—> Khoi lung binh tang: 44.1,125+18. > Mayo, =08:1=0,8 mol T= "a = L6 <1 49 Meo, bl25 _[HCO, :a mol _ {fiqo,=2+b=1125 fa =0,65 mol > Tao 2 musi > > CO; sb mol ng. =2+2b=1,6 — [b=0,475 mol Maco, = 0,475 mol > Maco, = 0,475.197 = 93,575 gam Bai 25: Hn hop X gdm CH; Cab; Cully va Clo. Ti kh6i ctia X so voi Hy bing 27. Dt chay hoan to’n X cin diing vita dii V lit khi O2 (dkte) thu duge CO, va 0,03 mol nude. Gid tri ciia V la A3,696 B. 1,232, ©7392 D.2464 psp. comtyvuwivutbrbasic 3251949, 040172023 CHUYEN DE DOT CHAY- HIDROCACBON - THAY NGUYEN VAN THAI (1) Tai xubag sch [1-45 Cae trang | FipHTMLS LUYEN THI: 23: NGO HUE- HAI BA TRUNG ~ HA NOI THAY NGUYEN VAN THAI BT :09.789,95,825, HD: Chon B Dat CTPT trung binh la C,H, > 12.4-+y =54— y=6—> C,H, :0,01 mol 1g, 4, = 0,055 mol Vo, =0,055. 232 lit Bai 26: Cho m gam mét hidrocacbon X va CO; vio binh phan img chira 2,5 lit Os (du). Bat tia lira dign dé phan img hoan toan thu duge 3.4 lit hén hgp A gom khi va hoi. Neung, tu hoi mrde con 1,8 lit hn hop khi B. Din B vao dung dich KOH dur thay cn 0,5 lit khi D thosit ra. Céc thé tich khi do 6 ciing digu kign nhigt d6 va dp suit. CTPT cia X la AGH, B. CsHy C. CH D. CH HD: Chon B Dy,g =34-1,8=1,6 mol (2) sascy Tac6 |g, =1,8-0,5=1,3 mol Ny, ,, =05 mol Mg, 4, = Ta thy noo, X lankan ny =Ny.o — Mo, = 16-12 =0,4 mol ce Bo 12 > $6 nguyen tirC 4 35H, ny in hgp khi A gdm mot hidrocacbon X vi CO» eting 250 ml O: (dur) dua vio binh phan tmg r6i dét chéy tao 380 ml hdn hep Khi vi hoi B. Dan B qua binh. Bai 27: Cho VI yng H;S0, dic théy con 200 ml hén hop khi D thost ra, Dn D vio binh dyng dung dich KOH der thay con 10 ml khi F di ra. Cac khi do 6 dktc. Tim CTPT eiia X va % thé tich hdn hop A Bai 28: Dét chy hod toan 2,24 lit (Aktc) hdn hgp khi X gdm CHy; CoHa; CoHy; CsHy va CiHlj thu durge 6,16 gam CO, va 4,14 gam H,O. $6 mol cia C,H, cé trong hén hgp X la: 4.0.09 B. 001 €.0,08 D.0,02 HD: Chon B fe =0,14 mol Tacs \co, = 0,23-0,14 = 0,09 mol mol CO; vi 0,23 mol H,0. $6 mol ciia anken c6 trong hén hgp li: 40,03 B, 0,06 C.0,01 D.0,09 HD: Chon C TACO, yeas =Reu, +Reny =0.23 -0,14 =0,09 mol — Ney, Bai 30; Dot chay hodn toan 0,11 mol hén hgp gdm CHy; CsHs; CzHg thu duge 0,17 mol CO; va 0,25 mol nude. $6 mol cia ankan vi anken trong hdn hop lin lrgt la A.0,09 vi 0,02 B.0,02 v0.09 C.0,08 va0,03 0,03 va 0,08 psp. comtyvuwivutbrbasic 33s1949, 040172023 CHUYEN DE DOT CHAY- HIDROCACBON - THAY NGUYEN VAN THAI (1) Tai xubag sch [1-45 Cae trang | FipHTMLS LUYEN THI: 23- NGO HUE- HAI BA TRUNG - HANOI THAY NGUYEN VAN THAI BT :09.789,95,825, HD: Chon C Tacén,,, Bai 31: Dét chay hoan toan hén hgp 3 ankin A, B, C ta thu due 3,36 lit CO» (dkte) vi 1,8 gam H,0. $6 mol cua hdn hgp ankin bj d6t chay 1a: AIS B. 0,25 C.0,08 D.0,05 TACE My, suin =Meo, Myo =0,15-0,1=0,05 mol Bai 32: Bét chdy ho’n todn 0,1 mol ankin thu duge 0,2 mol HO. Néu hidro héa hodn ton 0,1 mol ankin nay rdi dat chéy thi sé mol H,O thu duge li C.0,5 D.06 Ty, ~Mco, =025-0,17=0,08 mol >n,,., =! Bii 33: Dét chiy hon toi V lit mt ankadien duge 4V lit khi CO; 6 cing diéu kign nhigt d6 va ap sudt. Néu hidro héa hoan toan 0,1 mol ankadien nay rdi dem dét chay hét san pham thi sé mol CO; thu duge la: A03 B04 c.05 D.06 HD: Chon B Meo, AV 45 ney, =0,14=0,4 mol feasts WV Bai 34: Bét chiy hon toan 0,1 mol ha hop propen va xiclopropan thu duge 0,35 mol nue. % theo thé tich eva propan trong hn hgp ban dit la Ta c6 s6 nguyen tit C 450% B. 40% C.30% D.25% HD: Chgn A Ney, xMOl [my =x+¥=O.1 x =0,05 mol —> 50% Tac > > Pon, 2¥ Mol” [Myo =4x+3y=0,35 ly =0,05 mol — 50% Bai 35: at chay hon toin 0,2 mol hén hgp X gm m6t ankan va mét anken thu duge 0,35 mol CO, vi 0,4 mol HzO. % s6 mol eda anken trong X la: A40% B. 50% €.25% D. 75% HD: Chon D 0,05.100 0,05 mol — %n, 02 Bai 36: Dét chay hoan toan 3,36 lit (dkte) hin hop gdm mét ankan va hai anken (cé sé mol méi chat bing nhau) thu durgc p gam COs va 10,8 gam nude. Gid tri cla p la A22 B.242 C.41,22 D. 42,26 HD: Chon B psp. comtyvuwivutbrbasic 4s1949, 040172023 psp. comtyvuwivutbrbasic CHUYEN DE DOT CHAY- HIDROCACBON - THAY NGUYEN VAN THAI (1) Tai xubag sch [1-45 Cae trang | FipHTMLS LUYEN THI: 23- NGO HUE - HAI BA TRUNG ~ HA NOL THAY NGUYEN VAN THAI BT :09.789.95.825 = 280.6 mot Tacé is ous Ne, =Nhyo ~ Bean = 0,6 0,05 =0,55 mol 9 aaa = Pua = 5 = 0405 mol > Meo, = 24,2 gam Bai 37: Hn hop khi A gém mdt ankan va m6t anken, Cho 3,36 lit khi A (dkte) qua murée: bbrom dur thay 06 8 gam Brs. Mat khdc, néu dét 6,72 lit A (dkte) durge 39,6 gam CO2 va p gam nue. Gid tr cia p la A162 B18 C198 D216 HD: Chon C Ta 6 Nygun =0,15~0,05 =0,1 mol stnimahiem 2, {1" 7030! engi 2g ag BHO = Bai 38: Dot chdy hoan toin 39 gam hdn hgp A gdm CsHg; CyHo; CHs (trong dé 86 mol tia CyHig va CH, bling nhau) tao 2,7 mol CO2. Tinh khdi hong CsHs trong hén hop A? 2+0,9 = 1,1 mol > myo =p =19,8gam A168 B.21 C126 D.232 HD: Chon A CH 2x mol atmol Tacé 1C,Hy :y mol 34" * {REDE mol Meo, y=03 mol CH, :y mol > Mey, =16,8 gam Bai 39: Bot chay hodn toan 4,84 gam hdn hop X gdm CsHys C4Ho vi mot sé anken trong dé s6 mol C:Hy vi C4Hho bing nhau tao ra 0,38 mol nude. Tinh tng khdi long. ctia cde anken trong X? A204 B28 C56 D. 1,02 HD: Chon B 5 4,08 Tac m, =4,84—0,38.2 = 4,08 gam Ne, =~ = 0,34 mol 12 > Mya = Mio —Meo, = 0,38 0,34 =0,04 mol > My, sua =0402 mol A Me ten = My ~My = 4,84—0,02.(44 + 58)= 2,8 gam BAi 40: Dét chay hodn toan 5,4 gam hn hop X gam C.Hg; CaHyo; CsH)» trong d6 s6 mol C4Hjo bang s6é mol CsH)> thu durge 8,512 lit CO, (dkte). Khéi lugng cua CyHy trong X Liz ASG B.28 C84 D.41 HD: Chon B 36451949, 040172023 CHUYEN DE DOT CHAY- HIDROCACBON - THAY NGUYEN VAN THAI (1) Tai xubag sch [1-45 Cae trang | FipHTMLS LUYEN THI: 23- NGO HUE - HAI BA TRUNG ~ HA NOL THAY NGUYEN VAN THAI BT :09.789.95.825 Hi ym, = 5,4-12.0,38 =0,84 gam — ny =0,84 mol ny, =0,42 mol Moog =Mhig Neo, =0.42—0,38 =0,04 mol > 1. gun =0,02 mol Fm, =My =M,,,, =5,4-0,02.(58 + 72)=2,8 gam Bai 41; Dét chy hodn toan 4,3 gam hin hop X gbm CsHy va CsHig thu duge CO, vi HO trong d6 higu khdi long ciia CO2 va HO bang 6,9 gam. Khéi Itong cua C3Hs vai CoH trong X Lin hiat li A22va2,1 B.2,1va2.2 C.1,76va2,54 ——D.1,32-va 2,98 HD: Chon A gq {O02 :X mol f12x+2y=4,3 __ [x=0,3 mol Dat > > “|H,O:y mol” |44x~18y=6,9 ” |y=0,35 mol san 0,35- 5 mol > Me,.,, =4.3~44.0,05 = 2,1 gam Bai 42: Dét chy hoan toin mot lrgng hdn hgp A gdm 2 ankan la déng ding ké tiép thu duce COs vi HO e6 ti Ig thé tieh 1a 28 : 33 (cdc thé tich do 6 cing digu kign mhigt d6 va 4p suit). Céng thite phan tir cia hai ankan la A.CsHix; Cog B. GHevi GHy C.GHy va CHio D. CiHo vi CHa HD: Chon A Deo, 28 CH, Dat CTPT ciia ankan la C,H, =S5 ay 2g H+ 33 CH, Bai 43: Bét chiy hon toin 2.34 gam hin hgp X gdm 2 ankan li dng ding ké tip thu duge 3,584 lit khi CO: (Ate), CTPT cit hai ankan li: A.CH, va CoH, B. CyHg va CsHy C. CH va CsHio D. CyHyo va CsHi> HD: Chon C 4n+2_ a 2.34 0.16 Bai 44: Dét chy hon toan 0,03 mol hdn hop X g duge 2,88 gam nuée. CTPT cia hai xicloankan Li: Dit CIPT cia ankan li C,H, 2 xicloankan déng ding ké tiép thu A.CiHe vi Calls B. CiHy va Cho C. Celio vi Cath D. CiHlo va CH HD: Chon C ae te CSHyy TacbE= 2% = 916 5 35, 03 CH: Bai 45; Bot chay hoin toan 3,04 gam hén hgp A gém hai ankan la déng ding ké tigp ri cho toan bo sin phim chéy hap thy vio binh dung dung dich Ca(OH): dur thay khéi Iuong binh ting lén 13,92 gam, CTPT cia 2 ankan li psp. comtyvuwivutbrbasic 36451949, 040172023 CHUYEN DE DOT CHAY- HIDROCACBON - THAY NGUYEN VAN THAI (1) Tai xubag sch [1-45 Cae trang | FipHTMLS LUYEN THI: 23- NGO HUE - HAI BA TRUNG ~ HA NOL THAY NGUYEN VAN THAI BT :09.789.95.825 ACH, vi GH, B. CoH va Cy C. GH, va Hig D. CuHlyo va Csthiz HD: Chon D | {CO,:x mol [m=12x+2y=3,04 1 mol pat}? > > H,O:y mol” |m,,,, =44x+18y= 13,92” |y =0,26 mol Mg etag = 0,26 -0,21 =0,05 mol. Goi CTPT TB la C,H. Meo, _ 0,21 CHo 42 The 0,05 CH, Bai 46: Dét chdy hoan toan 0,15 mol hn hgp X gém hai anken A va B (Ma < Mg), hip thy toan bé sin phim chay vio dung dich Ca(OH), du thu duge 4 gam ket tia. Biét ny ny=2: 1. CTPT cia B li AGH, B.CsHy C.Culy D. CsHio HD: Chon C - Tac6 eo, = Regn, = 0,4 mol > Dat CPT cdn lai cia anken la C,H, 3 3 BAI 47; Bét chy hodn ton hén hgp Q gim 2 ankin X va Y. Hap thy todn b6 sim phim vvao 4,5 lit dung dich Ca(OH); 0,02M thu duge két tha va khéi hugng dung dich ting 3,78 gam so véi ban diu, Cho dung dich Ba(OH): vita ii vio dung dich thu thém két tia, ‘Téng két tia 2 lan la 18,85 gam. Biét ring s6 mol cua X bing 60% tng sé mol cia X va Y trong hn hop Q. Cac phan img xay ra hodn toan. Céng thire ciia X va Y lan lugt la: A.CoH: va Cals B. CuHe vi CoH: C. GH. va CsHy D, CsHy vi CoH HD: Chon A CaCO, :x mol HO) yyy = savin ng 02m | { x+y =0,09 Ca(HCO,), :y mot” [100(x +y) +197y = 18,85 X=0,04 mol yc) > i ¥=0,05 mol > Myo =3,78 +100.0,04 = 44.0,14 =1,62- 14 = 009 hay, =0414 0,09 Meo, _ O14 Mann 005 i, =0,6.2+0,4n=2,8->n=4 >Y CH, Nop, =X +2y=0,14 mol =2,8> Ankin la C,H. Dat CTPT cita ankin cdn lai & C,H psp. comtyvuwivutbrbasic as1949, 040172023 CHUYEN DE DOT CHAY- HIDROCACBON - THAY NGUYEN VAN THAI (1) Tai xubag sch [1-45 Cae trang | FipHTMLS LUYEN THI: 23- NGO HUE- HAI BA TRUNG - HANOI THAY NGUYEN VAN THAI BT:09.789,95.825 Bai 48: Bét chiy hodn to’n hin hgp 2 hidrocacbon mach hé trong cing diy ding ding thu duge 11,2 lit khi CO; (dkic) va 9 gam nuéc. Hai hidrocacbon thude diy ding ding nto? A.Ankan B. Anken C. Ankin D. Ankadien hode ankin HD: Chon B Bai 49: Dét chiy hon toin hin hgp 2 hidrocacbon mach hi trong eimg diy dng ding thu durge 19,712 lit COs (dkte) va 8,1 gam nude. Hai hidrocacbon dé thude diy déng dang nio? ‘A.Ankadien B. Ankin C. Aren D. Ankadien hoe ankin HD: Chon B Dong, >My. > Hai hidrocacbon thuge ankadien hog ankin Noo, Dy =0,88~0,45 = 0,43 mol > H,. = Bai 50: Dét chy hoan ton V lit(dkte) m6t ankin & thé khi thu duge CO. va H2O cé té kndi lugng 1a 25,2 gam. Néu cho san ph 45 gam két tha ig m chéy di qua dung dich Ca(OH)» dur thu dug tricia V It A672 B. 2,24 c.4,48 D.3,36 HD: Chon D Tac6 Meo, = Moco, = 0,45 mol" ny, >My, = Meco, ~Mryo = 0.45~0,3 = 0,15 mol —> V =0,15.22, b.CTPT cia ankin la: AGH: B.GsHy C.Cule D. CsHls HD: Chon B 2, Sénguyen icc = "% — O45 3 _, Crpr cita ankin la CH, O15 Bai 51: Dot chay hoan toin hén hgp X gdm hai hidrocacbon dang thu duge 11,2 lit khi CO> (dkte) va 12,6 gam nude ién tiép trong day déng a.Hai hidrocacbon dé thude diy ding ding nio sau day A.Ankan B. Anken C. Ankin D.Aren HD: Chon A Ta thay go, Hai hidrocacbon thude ankan psp. comtyvuwivutbrbasic es1949, 040172023 CHUYEN DE DOT CHAY- HIDROCACBON - THAY NGUYEN VAN THAI (1) Tai xubag sch [1-45 Cae trang | FipHTMLS LUYEN THI: 23- NGO HUE - HAI BA TRUNG ~ HA NOL THAY NGUYEN VAN THAI BT :09.789.95.825 b.CTPT ciia hai hidrocacbon la: A.GHy va GH B. C3Hs va Cato C. Cio va CHa D. CHa val Collis HD: Chon A Tacén,,,, =0,7-0, Bai 52: Dot chdy hodn toin hn hp X g6m hai hidrocacbon lién tiép nhau trong day déng ding thu duge 2,24 lit khi CO, (dkte) va 3,24gam nude. Cong thire phan ttr cia hai hidrocabeon li AGHpvaGHy B.CHyvaGH, — C.GHvaGH, DL GHy va Hy HD: Chon B Ta thay Neg, 2 hidrocacbon la ankan: ny =0,18—0,1= 1.08 mol oct Pi a1as-4[ 0,08 CH, Bai 53: Dét chéy hodn toan hdn hop A gém hai hidrocacbon lién tiép nhau trong diy dng dang thu dug 20,16 lit khi CO; (dkte) va 20,7 gam nurée. Cong thite phan tir cha hai idrocabcon li AGH VAGHs —B.CSHyvaCdHy —C.CHyva GMs. GsHs va Cato HD: Chon D Ta thay neo, < Myo —> 2 hidrocacbon la ankan: ny, = 1,15~0,9= 0,25 mol = CH, 0.9 36, [Cth 0,25 CH, Bai 54; Dot chay hoan toin 0,1 mol hén hop X gom hai hidrocacbon thude cing day dng ding c6 phan tr khdi hon kém nhau 28 dvC thu duige 8,96 lit khi CO; (dkte) va 7,2 gam muse. Céng thire phan tir cia hai hidrocacbon li: A.GsHsVACsHhz BCH, vACyHs —C.CsHevaCaHye —D. Cals va Cobiz HD: Chon C Ta thi neo, 1,0 > Hai hidrocacbon [8 anken hoge xicloankan Meo, _ 04 GH, 45 ny, Ol Hy Bai 55: Dét chay hoan toin hon hgp hén hgp X gém hai hidrocacbon thude cing diy déng ding, c6 phan tir khéi hon kém nhau 14 avC thu durge 7,84 lit khi CO, (dktc) va 8,1 gam nuée. CTPT cia hai hidrocacbon ta ACH, viGHe —B.C3Hg vaCsHy—C.CsHy va Cute D. Calls va CsHia > CTPT trung binh CjH,; >i psp. comtyvuwivutbrbasic 3951949, 040172023 CHUYEN DE DOT CHAY- HIDROCACBON - THAY NGUYEN VAN THAI (1) Tai xubag sch [1-45 Cae trang | FipHTMLS LUYEN THI: 23- NGO HUE - HAI BA TRUNG ~ HA NOL THAY NGUYEN VAN THAI BT :09.789.95.825 Tathily ng, Hai hidrocacbon Id ankan > CTPT trung binh Ia C,H. CH, =3,53 Th CsHiy Bai $6: Bét chiy hoiin ton hin hop X gdm hai hidrocacbon thuge cing diy dng 6 phan tir khéi hon kém nhaw 14 dvC tha durge Sm gam CO; vi 3m gam nue. COng thite phan tir cia hai hidrocacbon la: A.CsHy va CcHia BB. CzHg va Css. C. CH; va CsHy D. C3H, va CaH, HD: Chon B Ta thily nog, Hai hidrocacbon thuge day déng ding ea ankan 4.0.45 -0,35 sm 44 CH, -4 =n : 18 44 Bai 57: Dét chy hodn toin 0,05 mol hin hgp X gdm hai hidrocacbon thuge cing day déng ding thu due 7,392 lit khi CO; (dkte) va 3,24 gam nude, a.Hai hidrocacbon thuée diy dng ding A.Ankin B. benzen C. Ankan D. Anken hai hidrocacbon ding ding ké tigp. Xe dinh CTPT cia hai hidrocacbon Bai 58: Dét chéy hodn toin hin hop X gém mot ankan va mot anken e6 #1 [@ mol 1:1 thu duge 11,2 lit khi CO> (dkte) va 10,8 gam H,0. Cong thite phan tir eta hai hidrocacbon la: ACH, iis B.CsHy vaC2Hy CCG HgvasHy —-D. Ca3 du ding HD: Chon D gg = Myo Meo, =0,6-0,5= 0,1 mol... = Nyy = Os mol ‘Ankan : C,H,,,. 20,1 mol prGrr Haya ares anken :C,,H,,, :0,1 mol CH, cH, CH, > hoe hoae | — Dat CTPT trug binh la CH, Ng, = 0,1n+0,1m = 0,5 CH, cH, CH, Bai 59: Hn hgp khi A gdm m@t ankan vi mot anken, Cho 3,36 lit A (dkte) qua nude bbrom dur thay e6 8 gam Br: phan img. Mat khdc, néu dt chdy 6,72 lit khi A (dkte) duro 39,6 gam CO> va p gam nude a.CTPT ciia 2 hidrocacbon la: ACH va CH, B.CsHy vaCsHy CCH Va Cus. CsHi2 va Cstho HD: Chon B ‘Ankan :C,H,,,. :@ mol Dit CTPT { Anken:C,H,,, :b mol — lens4; : fe 0.1 5 =0,05 mol” [b= 0,05 160 a psp. comtyvuwivutbrbasic 404s1949, 040172023 CHUYEN DE DOT CHAY- HIDROCACBON - THAY NGUYEN VAN THAI (1) Tai xubag sch [1-45 Cae trang | FipHTMLS LUYEN THI: 23- NGO HUE - HAI BA TRUNG ~ HA NOL THAY NGUYEN VAN THAI BT :09.789.95.825 sit n=3 | (CH, BO 5ngy, = 0,2n+0,1m =0,9> > m=3 |CH, Gi tr) ctia p li: A162 B18 C198 D.216 HD: Chon C CH, 20,2 mol yrs, Tacd A Dy =11 mol > my, =19,8 gam. CH, :0,1 mol i hop X gm mét ankan va mét anken e6 ciing sé nguyén tir eacbon trong phan tir va c6 cing sé mol. Néu dem m gam hdn hop nay cho vao dung dich nude brom dur thay €6 16 gam Br. phan tmg, Néu dem dét chéy hoan ton hdn hop nay thu duge 0.6 mol CO; vi a gam nue. tricia a li A108 B. 1,08 126 D. 1.26 HD: Chon C TAC6 Myo =p, pp 2° =041 mol —>n,,,, = 0,1 mol ies Mo “355 a yj =o, + Mag = 01 +0,6= 0,7 mol > Myo = 12.6 gam b.Céng thie phan tir cia ankan va anken li: A.CoHe vi Hy B.CsHy vie C.CyHyo va CyHy DD. CsHy2 vat CsHho HD: Chon B ‘Ankan : C,H, o CH, Dat ‘ u2) 16 n=3> Anken :C,H,, :0,1 mol GH, Bai 61: Ddt chiy ho’n toan 1 lit hn hgp A gém ankin X va hidrocacbon Y cin ding 2,25 lit O sinh ra 1,5 lit khi CO} (cae khi do & cling dieu kign nhigt 46 va dp suat). Cong thite phn tir cia X va Y Hin hag ACH) va CH, B. CsHy va CHy C. CoH2 va CHy D. CH, va CoH. HD: Chon C Bg = 2M, —> Hon hgp A g6m ankin va ankan ¢6 s6 mol bing nhau va bing 0,5 mol (C,H. 2 10,05 mol : mes n=2__ (CH, >} C Hyg 10,05 mol" png, =0,5.(m-+n) =1,5 > aya caeei J m=1 (CH, Bil 62: Bét chay hodn toan hn hop A gdm 2 lit khi CsH, va 2 lit mét hidrocacbon X cin vita di 18 lit O» thu duvge thé tich khi CO> biing thé tich hoi nude (cic khi do 6 cing diéu kign nhigt d6 va ap suat). CTPT cia Y la: AGH, B. Cilio CGH D.CsHy psp. comtyvuwivutbrbasic ans,1949, 040172023 CHUYEN DE DOT CHAY- HIDROCACBON - THAY NGUYEN VAN THAI (1) Tai xubag sch [1-45 Cae trang | FipHTMLS LUYEN THI: 23- NGO HUE - HAI BA TRUNG ~ HA NOL THAY NGUYEN VAN THAI BT :09.789.95.825 HD: Chon B Tacd gy, > CIPT cia XC,H,,,> Bai 63: Bét chay hodn toi 0,05 mol hén hgp X gm C:Hs vi hidrocacbon Y. Hap thy hét ton b6 san phim chay vao dung dich Ca(OH), du thu duge 15 gam két tua va khdi ung dung dich giam 5,7 gam, CTPT cia Y la ACH B. Cus C. CHa D.CsHie HD: Chon A Np, = Neco, = 0415 mol Tacé 15-5,7-0,15.44 > Y pha 1 ankan v8 ey, = Mag = 0,025 a, ).15 mol 0 iz BS 5neo, = 2 +1).0,025=0,15 + =4 > CTPT cia ¥ 14 CHyy Bal 64: Bt chy hodn todn 0,3 mol hén hop X gdm mét ankan va mét ankin ri cho sin phim chay di qua binh dung dung dich HSO, dic va binh hai dyng dung dich NaOH du Sau phan img thay khdi luong binh ting lén 13,5 gam; binh hai ting 33 gam, CTPT ca hai hidrocacbon li: ACH ViGH, — B.GHgVaCHy — C.GHyviGH, D.C 3 déu ding HD: Chon D Tacé Neo, =Myyo =0.75 MOL > Nig =Myin = O15 mol Ankan :C,Hay,2 Dat CTPT cia hdn hop X 12 oe? HO 5, =0,15(n-+m) = 0,75 Ankin:CHyy 5 J > C63 nghigm (nm) Ba (134); (2:3); (3:2) cH, CH, CH, + howe |? hove CH, CH, CH, Bai 65: Bét chéy hoan toin hén hgp M gdm 1 ankan X va mét ankin Y thu duge sé mol CO; bing s6 mol nude. % s6 mol cua X, Y trong hén hop M lan uot la: A50% vi 50% —-B. 75% vA25% —C.20%VA80% —_—D. 35% vA6S% Bal 66: Bét chéy hoan toan hén hop X gém ba hidrocacbon trong 26 ankan, anken vA ankin e6 ti mol 1 : 1: 1 thu duge s6 mol CO. bing sé mol HO. Hén hgp X cé thé gom AB anken, B. Ankan, Aken va ankin CC. Lankan va 2 ankin D. Ci A va B déu dang Bai 67: Dét chiy hoan toin hén hgp X gdm 2 hidrocacbon mgch h, e6 thé Li ankan, anken vi ankin, ankadien. Bét chy hon ton hin hop X thu durge s6 mol CO: bing s6 ‘mol HO. Gist} eta m li ‘A.1 ankan va | ankadien B. | ankan va I ankin C. Lankan va 1 aren D. Ca 3 déu ding psp. comtyvuwivutbrbasic 424s,1949, 040172023 CHUYEN DE DOT CHAY- HIDROCACBON - THAY NGUYEN VAN THAI (1) Tai xubag sch [1-45 Cae trang | FipHTMLS LUYEN THI: 23- NGO HUE - HAI BA TRUNG ~ HA NOL THAY NGUYEN VAN THAI BT :09.789.95.825 HD: Chon D ‘Dot ankan thu duge n, > Hidrocacbon edn BE thu duge n, Jt chay thu dUBE Ney, > Mya Bai 68: Hin hop X gém 2 hidrocacbon mach hd 6 thé 1a ankan, anken, ankin va ankadien. Dét chay hodn toan thu duge mét long X thu duge sé mol CO; bing sé mol nude. X khéng thé gbm: A.Ankan va ankin: B. Ankan va ankadien Chai anken D. Ankan viv anken Ai 69: Bét chiy hodn toin hn hop A gdm 1 ankan vi 1 anken thu duge x mol H,0 va y mol COs. Quan he gitta x vay lis Axey B.xsy Cxy Bai 70; Dot chdy hodn toin hin hop A gdm I litankan X thu duvge 2 lit anken A va 7 lit CO; (cae khi do 6 cling diéu kign nhigt 46 va dp sudt). Biét Mx > My, CTPT etia X va Y in hot La AGH VAC Hg C.CHyVaCH, — C.CHy VAGH, DCH vA CH, HD: Chon A ankan X: C,H,,, :1 mol ‘at CIPT { Anken:C,,H,,,:2 mol —““sno, =n+2m=7 n>im22 n=3 | [X:C,H, ma My > m Y:CH, BA 71: Dét chéy hodn toan 4,24 gam hn hgp X gdm mgt ankan A va xicloankan ¢6 cing s6 nguyén tir cacbon va e6 ti If mol twong img 1a 1 : 2. Sau phiin img thu duge Khoi lung cia CO, Idn hon H,0 bing 7,44 gam. CTPT ctia A va B lan lugt la: A.CsHiz VACsHio B.CsHio va CsHy CC. C3HyvaCsHy —D. CoHua va CeHhz HD: Chon A. Mog, =X mol 12x42 be [Me =12x42y=4.24 | (x =0,3 mol iyo =y mol” [44x—18y =7,44 y=0,32 mol yay =Myyo “Neo, =0,32-0,3= 0,02 MO! > N ggysay =0.04 MOL ‘ankan : C,H,,,» :0,02 mol Dat CTPT cita { Xicloankan :C,H,, :0,04 mol" >1n¢q, =0,02n +0,04n = n>3 CAs n=5> CoH psp. comtyvuwivutbrbasic anus,1949, 040172023 CHUYEN DE DOT CHAY- HIDROCACBON - THAY NGUYEN VAN THAI (1) Tai xubag sch [1-45 Cae trang | FipHTMLS LUYEN THI: 23- NGO HUE- HAI BA TRUNG ~ HANOI THAY NGUYEN VAN THAI 91:09.789.95.25, Bai 72: Hén hop X c6 ti khéi hoi so véi Hz bing 19,875 gém mt ankan A vi mot xicloankan B, Bot chay hoa toin 3,18 gam hénhgp X thu duge 0,27 mol nuge, CTPT cota A va B lan ligt li: ACH, vas B.C: HD: Chon B Tacé My =39,75:n, = VaCyHy —C.CsHy va CsHio DD. CyHio vi CsHs =0,08 mol > m, =3,18-0,54 =2,64 gam 0 Meo, = 0:27 -0,22 = 0,05 mol ‘Ankan : C,H,,,, :0,05 mol Dat CTPT Xicloankan : C,,H. EE sry =(n +1).0,05+0,03m n2km23 n=2 (CH, > > m CH, Bai 73: Hin hop khi A gdm m@t_ankan va mét anken, Dét chy hodn toin 9 gam hén hop A (6 thé tich 8,96 lit) thu duge 13,44 lit khi CO, (c tu do & digu kign tiéu chuan). Céng thire phan tir va % s6 mol méi hidrocacbon Lin ligt La: A.CH, 75% vi CoH 25% B. CH, 25% va CsH, 75% C. CaHls 75% vai CsHs 25% D. CoH 25% vi CsHs 75% HD: Chon A 2.0.6. Tacém, =m +My =12M¢, +2My, =9 Ny 19 mol 2 yan =My,0 Meo, =0,9-0,6=0,3 mol Ankan:C,H,,,. :0.3 mol > — dat CPT ives Pygen =Pyy Bagg =Os1 MOL |Anken:C,H,,, :0,1 mol FD png, = 0,340.1 =0,6 187! 5 {Cs 20.3 mol > 75% 7 m=3-” |C\H, :25% Bai 74: Hon hop X c6 ti khdi so v6i H, bing 18,8 gdm mot ankan A va mét xieloankan B. Dot chay hodn toan 3,76 gam hdn hop X thu duye 0,26 mol COs. Cong thie phan tir cia A va B Kin lugt Ia: ACH CsHig BL CsHas Cully CCH; CaHg ——_D. Caltyo vai CH HD: Chon A Tacé My ).1 mol > m,, =3,76— asan = Mio ~ Mo, = 0432-0126 Msgein =O =0,06=0,04 mol psp. comtyvuwivutbrbasic 404s,1949, 040172023 CHUYEN DE DOT CHAY- HIDROCACBON - THAY NGUYEN VAN THAI (1) Tai xubag sch [1-45 Cae trang | FipHTMLS LUYEN THI: 23- NGO HUE - HAI BA TRUNG ~ HA NOL THAY NGUYEN VAN THAI BT :09.789.95.825 ‘Ankan : C,H,,,. :0,06 mol at CPT} Xicloankan :C,,H,,, :0,04 mol", =0,06.n +0,04m =0,26 n2hm23 CoH, va CJH, thu duge CO) va hoi nue c6 thé tich bing nhau (cée thé tich do @ cing digu kign nhigt khac, cho 0,3 mol hén hop X trén vio 100 ml dung dich Br; 1M thy khéi long dung dich ting m gam va e6 5,04 lit khi (Aktc) thodt ra khdi bin. Gi tr eta m li A195 B26 C13 D.39 HD: Chon A Ta thay oo, =Riyo Ney, om, 5.04 0,225 mol Mey, yay #03 0,225 = 0,075 mol 1,95 gam Bai 76: Dét chy hodn toan 1 Iit hn hop A gdm hai hidrocacho X,Y thu dugic 1,6 lit CO; va 2 lit hoi nude, Thé tich ofc ki va hoi do cimg didu kiga nhigt d% va dp sudt. Bidt Y nang hon X hai nguyén tir cacbon. Céng thie phan tir ctia X va Y Lan Lugt la AGH va CH B.CHyvaCsHe CCH, vials. CHa va Cols HD: Chon D Noo, 6 TacéC 6» XIACH, > ¥ 6 3 nguyén tir eacbon stessyicity BANG DAP AN ip | 2A | 3A | #a | SA | Gad | 6b-B | 7B [ 8D | OD 10-D | i2a-C | 12b-A | 12e-B | 13-C | 14-C | 15-C [16D | 17-B | 18-B 19-C | 20-B | 21-D | 22-B | 23-B | 24-4 | 25-B | 26-B | 28-B | 29-C 30-C | 31-D | 33B | 34-A | 35-D | 36-B | 37-C | 38-4 | 39-8 | 40-B 41a | 42-a | 43-C | 44-C | 45-0 | 46-C | 47-4 | 48-8 | 49-8 | 50a-D 50b-B | S1-A | §2-B | §3-D | 54-C | 58-C | 56-B | 57-B | 58D | 59a-B 59b-C | 60a-C | 60b-B | 61-C | 62-B | 63-4 | 64-D | 65-4 | 66D | 67-D 68D | 69-D | 70-A | 71-A | 72-B | 74-A | 75-4 | 76-D psp. comtyvuwivutbrbasic 4545