Test Bank For Chemistry and Chemical Reactivity 10th Edition by Kotz

Test Bank for Chemistry and Chemical Reactivity 10th Edition by Kotz
Test Bank for Chemistry and Chemical Reactivity

10th Edition by Kotz
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Chapter 08
1. Which of the following groups of molecules contains no ionic compounds?
a. HCN, NO2, and Ca(NO3)2
b. PCl5, LiBr, and Zn(OH)2
c. KOH, CCl4, and SF4
d. NaH, CaF2, and NaNH2
e. CH2O, H2S, and NH3
ANSWER: e
POINTS: 1
QUESTION TYPE: Multiple Choice
HAS VARIABLES: False
TOPICS: 8.1 Chemical Bond Formation
DATE CREATED: 3/5/2014 6:39 PM
DATE MODIFIED: 2/1/2018 7:44 AM
2. Which combination of atoms is most likely to produce a compound with ionic bonds?
a. B and C
b. S and O
c. N and F
d. Si and Cl
e. Mg and O
ANSWER: e
POINTS: 1
DATE MODIFIED: 3/5/2014 6:39 PM
3. Which combination of atoms is most likely to produce a compound with covalent bonds?
a. K and Br
b. Al and S
c. S and Cl
d. Sn and F
e. Li and I
ANSWER: c
POINTS: 1
4. Which of the following pairs of compounds contains ionic bonds?

Copyright Cengage Learning. Powered by Cognero. Page 1
Chapter 08
a. KI and O3
b. NaF and H2O
c. PCl5 and HF
d. Na2SO3 and BH3
e. RbBr and MgS
ANSWER: e
POINTS: 1
HAS VARIABLES: True
NOTES: Dynamic Question
5. Which of the following statements is/are CORRECT?

Ionic bonds form when one or more valence electrons are transferred from one atom to
1.
another.
2. Covalent bonds involve sharing of electrons between atoms.
In most covalently bonded compounds, electrons are NOT shared equally between the
3.
atoms.
a. 1 only b. 2 only c. 3 only d. 1 and 2 e. 1, 2, and 3
ANSWER: e
POINTS: 1
6. Which of the following statements is/are CORRECT?

1. Chemical reactions result in the gain, loss, or rearrangement of valence electrons.
For main group elements, the number of valence electrons equals eight minus the
2.
element’s group number.
3. Core electrons are not involved in bonding or in chemical reactions.
a. 1 only b. 2 only c. 3 only d. 1 and 3 e. 1, 2, and 3
ANSWER: d
POINTS: 1
TOPICS: 8.2 Covalent Bonding and Lewis Structures
7. An atom of He has _____ valence electrons.

a. 5 b. 2 c. 6 d. 8
Chapter 08
e. 14
ANSWER: b
POINTS: 1
HAS VARIABLES: True
8. The given representation of an atom is called the _____.
a. a Lewis dot structure.

b. an ion.
c. a structural formula.
d. an electrostatic potential map.
e. an ionic bond.
ANSWER: a
POINTS: 1
9. In the Lewis formula for sulfur dioxide, SO2, the number of lone pairs of electrons around the sulfur atom is
a. 0. b. 1. c. 2. d. 3.
e. 4.
ANSWER: b
POINTS: 1
QUESTION TYPE: Multi-Mode (Multiple choice)
HAS VARIABLES: True
10. How many lone pairs of electrons are assigned to the carbon atom in CO?
a. 0 b. 1 c. 2 d. 3 e. 4
ANSWER: d
POINTS: 1
Chapter 08
HAS VARIABLES: True

11. What is the total number of electrons (both lone and bond pairs) in the Lewis structure of SO42-?
a. 18 b. 20 c. 32 d. 24
e. 22
ANSWER: c
POINTS: 1
HAS VARIABLES: True
12. How many valence electrons are present in the Lewis formula for the chlorite ion, Cl2–?
a. 26 b. 18 c. 24 d. 20
e. 22
ANSWER: d
POINTS: 1
HAS VARIABLES: True
13. Which of the following molecules or ions are isoelectronic: SO3, NF3, NO3–, CO32–?
a. SO3 and NF3
b. NF3 and CO32–
c. SO3, NF3 and CO32–
d. SO3, NO3– and CO32–
e. SO3, NF3, NO3–, and CO32–
ANSWER: d
POINTS: 1

Chapter 08
14. If two or more species have the same number of electrons, resulting in similar Lewis structures, they are said to be
____.
a. isoelectronic
b. resonant structures
c. ionic
d. neutral
e. covalent
ANSWER: a
POINTS: 1
15. Which of the following has a Lewis structure similar to OCS?

a. NH2− b. O3 c. N2O+ d. SO2
e. ClO2−
ANSWER: c
POINTS: 1
16. Which of the following molecules or ions will have a Lewis structure most like that of phosphorus trichloride, PCl3?
a. ClO3– b. SO3 c. CO32– d. BF3 e. Cl2CO
ANSWER: a
POINTS: 1
17. The correct Lewis structure for Cl2CO is (the 2 Cl's and the O are bound to the C and not to each other):
a. b. c.

Chapter 08
d. e. none of these
ANSWER: a
POINTS: 1
18. Which of the following is the Lewis electron dot structure for carbon monoxide?
a. b. c. d.
e.
ANSWER: a
POINTS: 1
19. Which of the following is a correct Lewis structure for H2SO4?

a. b. c.
d. e.
ANSWER: a
POINTS: 1
20. Which of the following is the correct Lewis structure for the sulfate ion?

Chapter 08
a. b. c.
d. e.
ANSWER: a
POINTS: 1
21. Which is the best Lewis structure of CH2FCO2H (connectivity correct as given)?
a. b.
c. d.
e. none of these is acceptable

ANSWER: d
POINTS: 1
22. How many hydrogen atoms are needed to complete the following hydrocarbon structure?

Chapter 08
a. 10 b. 12 c. 8 d. 14 e. 6
ANSWER: b
POINTS: 1
HAS VARIABLES: True
23. Which of the following is the correct Lewis dash formula for carbon diselenide?
a. b. c.
d. e.
ANSWER: b
POINTS: 1
24. Which of the following is a correct Lewis structure for oxygen?

a.
b.
c.
d.
e.
ANSWER: a
POINTS: 1

Chapter 08
25. Which of the following Lewis structures for nitrogen oxides is incorrect?
a. N2O.
b. N2O4.
c. N2O3.
d. N2O5.
e. All of these are incorrect structures.
ANSWER: c
POINTS: 1
26. Which of the following are possible Lewis structures for a molecule with the formula C2H6O?
a. 1 b. 2 c. 3 d. 2 and 3
e. 1, 2, and 3
ANSWER: d
POINTS: 1
27. The molecule H2S has

a. 2 bonding pairs and 3 lone pairs
b. 2 bonding pairs and 2 lone pairs
c. 3 bonding pairs and 1 lone pair
d. 3 bonding pairs and 3 lone pairs
e. none of these
ANSWER: b
Chapter 08
POINTS: 1
HAS VARIABLES: True
28. The nitrogen atom in the cyanide ion, CN–, is surrounded by:
a. one single bond and three lone pairs of electrons.
b. one double bond and one lone pair of electrons.
c. one double bond and two lone pairs of electrons.
d. one triple bond and one lone pair of electrons.
e. one triple bond and no lone pairs of electrons.
ANSWER: d
POINTS: 1
29. The central atom in N2O is a nitrogen atom. This nitrogen atom is surrounded by
a. two single bonds and two lone pairs of electrons.
b. two single bonds and one lone pair of electrons.
c. one single bond, one double bond, and one lone pairs of electrons.
d. one single bond, one double bond, and one lone pair of electrons.
e. two double bonds and no lone pairs of electrons.
ANSWER: e
POINTS: 1
30. How many different molecules have the molecular formula C6H14?
a. 1 b. 2 c. 3 d. 4 e. 5
ANSWER: e
POINTS: 1
HAS VARIABLES: True

Chapter 08

31. Which of the following statements concerning the formal charge of an atom is/are true?
The formal charge of each individual atom in a molecule or ion is the actual atomic
1.
charge that can be determined experimentally.
The formal charge of each individual atom is always the same for each possible
2.
resonance form.
The sum of the formal charges of each atom in an ion equals the overall charge of the
3.
molecule or ion.
a. 1 only b. 2 only c. 3 only d. 1 and 2
e. 1 and 3
ANSWER: c
POINTS: 1
TOPICS: 8.3 Atom Formal Charges in Covalent Molecules and Ions
32. What is the formal charge on the carbon atom in CO?

a. +2 b. +1 c. 0 d. –1
e. –2
ANSWER: c
POINTS: 1
HAS VARIABLES: True
33. What is the formal charge on each atom in dichloromethane, CH2Cl2?

a. C atom = 0, each H atom = 0, and each Cl atom = 0
b. C atom = –2, each H atom = +1, and two Cl atoms = 0
c. C atom = +4, each H = –1, and each Cl atom = –1
d. C atom = +4, each H = +1, and each Cl atom = –1
e. C atom = –4, each H = +1, and each Cl atom = +1
ANSWER: a
POINTS: 1
Chapter 08
34. What is the formal charge on the O2 atom in the following Lewis structure?
a. 2 b. 1 c. 0 d. –1
e. –2
ANSWER: b
POINTS: 1
HAS VARIABLES: True
35. What is the formal charge of the oxygen atom in the Lewis structure for cyanate shown below?
a. 0 b. −2 c. +1 d. −1 e. 2
ANSWER: e
POINTS: 1
HAS VARIABLES: True
36. One resonance structure for OCN– ion is drawn below. What is the formal charge on each atom?
a. O atom = 0, C atom = 0, and N atom = 0

b. O atom = 0, C atom = 0, and N atom = –1
c. O atom = –1, C atom = 0, and N atom = 0
d. O atom = –1, C atom = –1, and N atom = +1
e. O atom = +1, C atom = 0, and N atom = –2
ANSWER: c
POINTS: 1
Chapter 08

37. Which of the following is not a valid resonance structure for N3–?
a.
b.
c.
d.
e. all are correct

ANSWER: a
POINTS: 1
TOPICS: 8.4 Resonance
38. Which of the following are the correct resonance structures for the formate ion, HCO2–?
a. 1 and 2 b. 2 and 3 c. 3 and 4 d. 1, 3, and 4

e. 2, 3, and 4
ANSWER: c
POINTS: 1
39. Which of the following exhibits resonance?

a. SCl4 b. H2O c. SO2 d. BH3 e. none
ANSWER: c
POINTS: 1
Chapter 08

HAS VARIABLES: True
40. Which of the following molecules or ions does not have one or more resonance structures?
a. O3 b. OCN– c. SO2 d. H2CO e. NO3–
ANSWER: d
POINTS: 1
41. The Lewis structure of which of the following molecules violates the octet rule?
a. SF4 b. NF3 c. OF2 d. HF
e. SiF4
ANSWER: a
POINTS: 1
HAS VARIABLES: True
TOPICS: 8.5 Exceptions to the Octet Rule
42. Which of the following elements is able to form a molecular structure that exceeds the octet rule?
a. C b. N c. O d. F e. Cl
ANSWER: e
POINTS: 1
HAS VARIABLES: True
43. Which of the following elements is most likely to form a molecular structure that disobeys the octet rule?
a. B b. C c. N d. O e. F
ANSWER: a
POINTS: 1
Chapter 08

44. When both of the electrons in a molecular bond originate from the same atom, the bond is called a(n)
a. sigma bond.
b. coordinate covalent bond.
c. pi bond.
d. metallic bond.
e. ionic bond.
ANSWER: b
POINTS: 1
45. How many lone pairs are present around the central atom in the Lewis structure of SF6?
a. 0 b. 1 c. 2 d. 3
e. 4
ANSWER: a
POINTS: 1
HAS VARIABLES: True
46. Which of the following has an incomplete octet in its Lewis structure?
a. SO2 b. F2 c. NO2 d. ICl e. CO2
ANSWER: c
POINTS: 1
HAS VARIABLES: True
47. What is the correct Lewis structure for SF4?

Chapter 08
a. b. c.
d. e.
ANSWER: c
POINTS: 1
48. Which of the following is the correct Lewis structure of IF3?

a. b. c.
d. e.
ANSWER: e
POINTS: 1
49. When you draw the Lewis structure for PF2Cl3, how many single bonds, double bonds, and lone pair electrons reside
on the central phosphorus atom?
a. 5 single bonds, 0 double bonds, 0 lone pairs
b. 4 single bonds, 1 double bond, 0 lone pairs
c. 5 single bonds, 0 double bonds, 1 lone pair
d. 4 single bonds, 1 double bond, 1 lone pair
e. 3 single bonds, 2 double bonds, 0 lone pairs
ANSWER: a
POINTS: 1
Chapter 08

NOTES: OWL
50. The central atom in SF6 is surrounded by

a. six single bonds and no lone pairs of electrons.
b. six single bonds and one lone pair of electrons.
c. six single bonds and two lone pairs of electrons.
d. five single bonds, one double bond, and one lone pair of electrons.
e. four single bonds, two double bonds, and no lone pairs of electrons.
ANSWER: a
POINTS: 1
51. Which of the following species has a Lewis structure similar to iodine tetrafluoride, IF4–?
a. XeF4 b. SO42– c. PF4+ d. SF4
e. IO4–
ANSWER: a
POINTS: 1
52. Which of the following molecules or ions are likely to be free radicals: N2O, NO, and NO2?
a. N2O only
b. NO only
c. NO2 only
d. N2O and NO
e. NO and NO2
ANSWER: e
POINTS: 1
Chapter 08

53. What is the molecular geometry around an atom in a molecule or ion which is surrounded by
zero lone pairs of electrons and four single bonds.
a. tetrahedral
b. linear
c. bent
d. trigonal pyramidal
e. trigonal planar
ANSWER: a
POINTS: 1
HAS VARIABLES: True
TOPICS: 8.6 Molecular Shapes
54. What is the electron-pair geometry around an atom in a molecule or ion which is surrounded by
two lone pairs of electrons and three single bonds.
a. trigonal bipyramidal
b. see-saw or distorted tetrahedron
c. T-shaped
d. linear
e. trigonal planar
ANSWER: a
POINTS: 1
HAS VARIABLES: True
55. What is the bond angle in a trigonal planar molecule or ion?

a. 109° b. 180° c. 90° d. 72° e. 120°
ANSWER: e
POINTS: 1
DIFFICULTY: easy
HAS VARIABLES: True
LEARNING OBJECTIVES: CHEM.KOTZ.16.04 - Identify the bond angle of a particular molecular geometry.

Chapter 08
TOPICS: A Summary of Electronic and Molecular Geometries

56. What is the molecular geometry around the nitrogen atom as per the valence shell electron-pair repulsion (VSEPR) theory??
a. Trigonal pyramidal
b. Bent
c. Tetrahedral
d. See-saw or distorted tetrahedral
e. Trigonal planar
ANSWER: a
POINTS: 1
HAS VARIABLES: True
57. What is the molecular geometry around carbon atom C1?
a. tetrahedral
b. trigonal planar
c. linear
d. trigonal pyramidal
e. bent
ANSWER: b
POINTS: 1
Chapter 08
HAS VARIABLES: True

58. Use VSEPR theory to predict the electron-pair geometry and the molecular geometry of nitrogen trichloride, NCl3.
a. The electron-pair geometry is linear, the molecular geometry is linear.
b. The electron-pair geometry is trigonal-planar, the molecular geometry is trigonal-planar.
c. The electron-pair geometry is trigonal-planar, the molecular geometry is bent.
d. The electron-pair geometry is tetrahedral, the molecular geometry is tetrahedral.
e. The electron-pair geometry is tetrahedral, the molecular geometry is trigonal-pyramidal.
ANSWER: e
POINTS: 1
59. Use VSEPR theory to predict the electron-pair geometry and the molecular geometry of boron tribromide, BBr3.
a. The electron-pair geometry is trigonal-pyramidal, the molecular geometry is trigonal-pyramidal.
b. The electron-pair geometry is trigonal-planar, the molecular geometry is trigonal-planar.
c. The electron-pair geometry is trigonal-planar, the molecular geometry is bent.
d. The electron-pair geometry is tetrahedral, the molecular geometry is trigonal-pyramidal.
e. The electron-pair geometry is trigonal-pyramidal, the molecular geometry is t-shaped.
ANSWER: b
POINTS: 1
60. According to VSEPR theory, which of the following is the correct statement concerning the electron-pair geometry
and the molecular geometry of sulfur dioxide?
a. The electron-pair geometry is trigonal planar, and the molecular geometry is trigonal planar.
b. The electron-pair geometry is trigonal-planar, and the molecular geometry is bent.
c. The electron-pair geometry is tetrahedral, and the molecular geometry is bent.
d. The electron-pair geometry is tetrahedral, and the molecular geometry is linear.
e. The electron-pair geometry is trigonal bipyramidal, and the molecular geometry is linear.
ANSWER: b
POINTS: 1
Chapter 08

61. Use VSEPR theory to predict the electron-pair geometry and the molecular geometry of xenon tetrafluoride, XeF4.
a. The electron-pair geometry is tetrahedral, the molecular geometry is tetrahedral.
b. The electron-pair geometry is octahedral, the molecular geometry is tetrahedral.
c. The electron-pair geometry is tetrahedral, the molecular geometry is octahedral.
d. The electron-pair geometry is octahedral, the molecular geometry is square-planar.
e. The electron-pair geometry is square-planar, the molecular geometry is tetrahedral.
ANSWER: d
POINTS: 1
62. Use VSEPR theory to predict the molecular geometry of BrO3–.

a. trigonal-pyramidal
b. trigonal-planar
c. bent
d. T-shaped
e. linear
ANSWER: a
POINTS: 1
63. Use VSEPR theory to predict the molecular geometry around either carbon atom in acetylene, C2H2.
a. linear
b. bent
c. trigonal-planar
d. tetrahedral
e. octahedral
ANSWER: a
POINTS: 1

Chapter 08

64. According to VSEPR theory, which of the following is the correct molecular geometry around the carbon atom in
formaldehyde?
a. Linear
b. Bent
c. Trigonal-planar
d. Tetrahedral
e. Octahedral
ANSWER: c
POINTS: 1
65. Use VSEPR theory to predict the molecular geometry of BrF5.

a. tetrahedral
b. see-saw
c. trigonal-bipyramidal
d. square-pyramidal
e. octahedral
ANSWER: d
POINTS: 1
66. Use VSEPR theory to predict the molecular geometry around the nitrogen atom in nitrite ion, NO2–.
a. trigonal-planar
b. tetrahedral
c. trigonal-pyramidal
d. T-shaped
e. bent
ANSWER: e
POINTS: 1
Chapter 08

67. Based on electron-pair geometries, which of the following molecules has the smallest bond angle between any two
adjacent atoms?
a. CH4 b. H2O c. BH3 d. PH3
e. SF6
ANSWER: e
POINTS: 1
68. What are the approximate H−N−H bond angles in NH4+?

a. 109.5°
b. 120°
c. 109.5° and 120°
d. 90°
e. 90° and 120°
ANSWER: a
POINTS: 1
69. What is the O−C−N bond angle in OCN–?

a. 90° b. 107° c. 109.5° d. 120° e. 180°
ANSWER: e
POINTS: 1
70. Which of the following is the approximate O−S−O bond angle in the sulfite ion, SO32–?
a. 90°
b. 109.5°
c. 120°

Chapter 08
d. 180°
e. 150°
ANSWER: b
POINTS: 1
71. What are the approximate F−Br−F bond angles in BrF5?

a. 90° and 180°
b. 109.5°
c. 90° and 120°
d. 120°
e. 180°
ANSWER: a
POINTS: 1
72. Place the following molecules in order from smallest to largest H−N−H bond angles: NH4+, NH3, and NH2–.
a. NH4+ < NH3 < NH2–
b. NH4+ < NH2– < NH3
c. NH2– < NH3 < NH4+
d. NH2– < NH4+ < NH3
e. NH3 < NH2– < NH4+
ANSWER: c
POINTS: 1
73. Which of the following bonds would be the most polar?

a. N--C b. N--Si c. N--P d. N--Al e. N--Ga
ANSWER: e
POINTS: 1

Chapter 08

HAS VARIABLES: True
TOPICS: 8.7 Bond Polarity and Electronegativity
74. Which of the following compounds has polar covalent bonds: CCl4, Cl2, HCl, and KCl?
a. CCl4 only
b. Cl2 only
c. HCl and KCl
d. Cl2 and KCl
e. CCl4 and HCl
ANSWER: e
POINTS: 1
75. Electronegativity is a measure of _____.

a. the ability of a substance to conduct electricity
b. the charge on a polyatomic cation
c. the charge on a polyatomic anion
d. the ability of an atom in a molecule to attract electrons to itself
e. the oxidation number of an atom in a molecule or polyatomic anion
ANSWER: d
POINTS: 1
76. Three nonequivalent Lewis structures for carbonyl sulfide, SCO, are given below. Use the concepts of formal charge
and electronegativity to choose the structure that is the best representation.
A B C
a. Structure A, because all the formal charges equal 0
b. Structure B, because all the formal charges equal 0
Chapter 08
c. Structure C, because all the formal charges equal 0.

d. Structure A, because the negative formal charge resides on the most electronegative atom
e. Structure C, because the negative formal charge resides on the most electronegative atom
ANSWER: b
POINTS: 1
NOTES: OWL
77. Choose which central atom in the following molecules is most electronegative.
a. PH3 b. CH4 c. H2S d. H2O e. NH3
ANSWER: d
POINTS: 1
78. Rank the following covalent bonds in order of decreasing polarity: C-H, N-H, O-H, and F-H.
a. F-H > O-H > N-H > C-H
b. O-H > F-H > N-H > C-H
c. N-H > F-H > O-H > C-H
d. C-H > N-H > O-H > F-H
e. C-H > F-H > O-H > N-H
ANSWER: a
POINTS: 1
TOPICS: 8.7 Electronegativity and Bond Polarity
79. Atoms having equal or nearly equal electronegativities are expected to form
a. no bonds
b. polar covalent bonds
c. nonpolar covalent bonds
d. ionic bonds
e. covalent bonds
ANSWER: c
POINTS: 1
Chapter 08

80. Which of the following molecules is nonpolar?

a. sulfur dioxide, SO2
b. hydrogen fluoride, HF
c. phosphorus trifluoride, PF3
d. boron trifluoride, BF3
e. iodine trichloride, ICl3
ANSWER: d
POINTS: 1
HAS VARIABLES: True
TOPICS: 8.8 Bond and Molecular Polarity
81. Which of the following molecules is polar?

a. CS2 b. SO2 c. XeF2 d. XeF4
e. SO3
ANSWER: b
POINTS: 1
TOPICS: 8.8 Molecular Polarity
82. Three possible structures of C2H2Cl2 are shown below. Which of these molecules are polar?
a. 1 only b. 2 only c. 3 only d. 1 and 3 e. 2 and 3

ANSWER: d
POINTS: 1
Chapter 08

83. Linus Pauling noticed that the energy of a polar bond is often greater than expected. He attributed the greater bond
energy to
a. a coulombic attraction between atoms with partially positive and negative charges.
b. the greater bond lengths of the heteronuclear bonds.
c. one of the many unexplainable phenomena that scientists encounter.
d. the ability of heteronuclear species to form double and triple bonds.
e. the greater number of valence electrons found in heteronuclear molecules.
ANSWER: a
POINTS: 1
TOPICS: 8.9 Bond Properties: Order, Length, Energy
84. In molecules, as bond order increases,

a. both bond length and bond energy increase.
b. both bond length and bond energy decrease.
c. bond length increases and bond energy is unchanged.
d. bond length is unchanged and bond energy increases.
e. bond length decreases and bond energy increases.
ANSWER: e
POINTS: 1
85. Determine the bond order of NO+?

a. 2 b. 1.5 c. 1 d. 2.5
e. 3
ANSWER: e
POINTS: 1
HAS VARIABLES: True

Chapter 08
86. Use Lewis structures to predict the bond order for a sulfur-oxygen bond in SO32-?
a. 1 b. 4/3 c. 5/2 d. 2
e. 3/2
ANSWER: a
POINTS: 1
HAS VARIABLES: True
87. Use Lewis structures to predict the bond order for a sulfur-oxygen bond in the sulfite ion?
a. 1 b. 3/2 c. 4/3 d. 2 e. 5/2
ANSWER: c
POINTS: 1
HAS VARIABLES: True
88. Based on the following data, what is the F-F bond energy?
H2(g) + F2(g) → HF(g); ΔrH = –272.5 kJ/mol-rxn
Bond Bond Energy (kJ/mol)
H-H 435
H-F 565
a. 500 kJ/mol b. 150 kJ/mol c. –150 kJ/mol d. –695 kJ/mol e. 695 kJ/mol
ANSWER: b
POINTS: 1
HAS VARIABLES: True
89. Using bond-energy data, what is ΔrH for the following reaction?
CH4(g) + 2Cl2(g) → CCl4(g) + 2H2(g)
C-H 413
H-H 432
Cl-Cl 242
C-Cl 328
Chapter 08
a. –40 kJ/mol-rxn
b. –150 kJ/mol-rxn
c. 40 kJ/mol-rxn
d. 1415 kJ/mol-rxn
e. 150 kJ/mol-rxn
ANSWER: a
POINTS: 1
HAS VARIABLES: True
90. Using the following data reactions:

ΔH° (kJ/mol-rxn)
H2(g) + Cl2(g) → 2HCl(g) –184
H2(g) → 2H(g) 432
Cl2(g) → 2Cl(g) 239
calculate the energy of an H-Cl bond.
a. 92 kJ/mol b. 855 kJ/mol c. 487 kJ/mol d. 428 kJ/mol e. 244 kJ/mol
ANSWER: d
POINTS: 1
HAS VARIABLES: True
91. Which of the following species has the shortest carbon−nitrogen bond?
a. CH3CN b. CH3N2 c. CH2NH d. CH3CONH2
e. CH3NH3+
ANSWER: a
POINTS: 1
TOPICS: 8.9 Bond Properties: Order, Length, and Dissociation Enthalpy
NOTES: OWL
92. Use the bond energies provided to complete the following statement.

Chapter 08
________ when all of the bonds in acetic acid (CH3COOH) are broken.

C-H 413
C-O 358
O-H 463
C=O 745
C-C 348
C=C 614
a. 3153 kJ/mol of energy is consumed
b. 3153 kJ/mol of energy is released
c. 2805 kJ/mol of energy is released
d. 2805 kJ/mol of energy is consumed
e. 2766 kJ/mol of energy is consumed
ANSWER: a
POINTS: 1
HAS VARIABLES: True
93. The molecular geometry of a molecule whose central atom has four single bonds and one lone pair of electrons is
________.
ANSWER: trigonal-bipyramidal
POINTS: 1
QUESTION TYPE: Subjective Short Answer
94. If a molecule has a positive and negative end, the molecule is said to have a(n) ________ moment.
ANSWER: dipole
POINTS: 1
95. In PCl5, the Cl−P−Cl bond angle between an axial and an equatorial chlorine atom is ________ degrees.
ANSWER: 90
POINTS: 1
Chapter 08

96. In benzene, C6H6, the six carbon atoms are arranged in a ring. Two equivalent Lewis structures can be drawn for
benzene. In both structures, the carbon atoms have a trigonal planar geometry. These two equivalent structures are
referred to as ________ structures.
ANSWER: resonance
POINTS: 1
97. One might expect PCl3 to have a trigonal planar molecular geometry since its central atom is surrounded by three
outer atoms. However, PCl3 has a trigonal pyramidal geometry. Explain.
ANSWER: The shape of a molecule is dependent upon the number of electron-pairs surrounding the central
atom. The phosphorus atom in PCl3 has four electron-pairs which are distributed around the
phosphorus atom in a tetrahedral geometry. Thus, the bond angles are approximately 109°, not
120°.
POINTS: 1
98. The backbone of DNA consists of the atoms O—P—O—C—C—C. Each atom has a(n) _____ electron-pair geometry.
a. tetrahedral
b. trigonal bipyramidal
c. trigonal-planar
d. linear
e. octahedral
ANSWER: a
POINTS: 1
TOPICS: 8.10 DNA, Revisited
99. The rings in the nitrogen-containing bases in DNA are all flat with _____ electron-pair geometry around each atom.
a. trigonal-planar
Test Bank for Chemistry and Chemical Reactivity 10th Edition by Kotz
Chapter 08
b. tetrahedral
c. trigonal bipyramidal
d. linear
e. octahedral
ANSWER: a
POINTS: 1
TOPICS: 8.10 DNA, Revisited
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4. Which of the following pairs of compounds contains ionic bonds?

5. Which of the following statements is/are CORRECT?

6. Which of the following statements is/are CORRECT?

7. An atom of He has _____ valence electrons.

8. The given representation of an atom is called the _____.

a. a Lewis dot structure.

HAS VARIABLES: True

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DATE MODIFIED: 3/5/2014 6:39 PM

15. Which of the following has a Lewis structure similar to OCS?

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19. Which of the following is a correct Lewis structure for H2SO4?

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e. none of these is acceptable

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24. Which of the following is a correct Lewis structure for oxygen?

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27. The molecule H2S has

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NOTES: Dynamic Question

32. What is the formal charge on the carbon atom in CO?

33. What is the formal charge on each atom in dichloromethane, CH2Cl2?

DATE MODIFIED: 3/5/2014 6:39 PM

a. O atom = 0, C atom = 0, and N atom = 0

TOPICS: 8.3 Atom Formal Charges in Covalent Molecules and Ions

e. all are correct

a. 1 and 2 b. 2 and 3 c. 3 and 4 d. 1, 3, and 4

39. Which of the following exhibits resonance?

QUESTION TYPE: Multiple Choice

QUESTION TYPE: Multiple Choice

47. What is the correct Lewis structure for SF4?

48. Which of the following is the correct Lewis structure of IF3?

QUESTION TYPE: Multiple Choice

50. The central atom in SF6 is surrounded by

TOPICS: 8.5 Exceptions to the Octet Rule

55. What is the bond angle in a trigonal planar molecule or ion?

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TOPICS: A Summary of Electronic and Molecular Geometries

57. What is the molecular geometry around carbon atom C1?

HAS VARIABLES: True

HAS VARIABLES: False

62. Use VSEPR theory to predict the molecular geometry of BrO3–.

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TOPICS: 8.6 Molecular Shapes

65. Use VSEPR theory to predict the molecular geometry of BrF5.

DATE CREATED: 3/5/2014 6:39 PM

68. What are the approximate H−N−H bond angles in NH4+?

69. What is the O−C−N bond angle in OCN–?

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71. What are the approximate F−Br−F bond angles in BrF5?

73. Which of the following bonds would be the most polar?

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QUESTION TYPE: Multiple Choice

75. Electronegativity is a measure of _____.

c. Structure C, because all the formal charges equal 0.

QUESTION TYPE: Multi-Mode (Multiple choice)

80. Which of the following molecules is nonpolar?

81. Which of the following molecules is polar?

a. 1 only b. 2 only c. 3 only d. 1 and 3 e. 2 and 3