Comprehensive &) PRACTICAL CHEMISTRY CLASS XIIWIN A CASH AWARD OF ¢ 50 [) Hua come tou noi that soe bates frllotyHllng faked 5 i r fast solling titlos, rie ee eee a you with our gonuine books und lo protoe wy Bai eanrat ed abe igee Pe pula Hologram on the cover of some ot oe eae Tho Hologram displays a unique AD Litho, multicdovel, mules Hts fast ee “ ei following leven lovels of that graphien n i Secrapehaai seems to bo under or behind” Ue Hologram and jive ae Se the fake Hologram on th fuke/duplicnto books, YOU Aang “colour orKed logothor, the illusion of FOREGROUND LITHO EFFECT FOREGROUND, 3D DEPTH LAYER SHRINK-GROw. pris FLIPIFLOP er Mt Lax tix 7 Lens. MACH. AINEMATIC. — SPARKLEDOTS. FLOATING —_ANIMMATION eFrEcriaveR ervecriner "ALE stone” “aver” ghee FS Da Presently, only some titles havo got the Hologe: Chemistry for Class XII has got the Hologram. Ifyou or any of your friends finds anywhere in India/abroad any book of this Edition without . SATIONS [Link], the LP. Hologram, he/she is requested to write to usat M/s LAXMI PUBLICAT IONS. Pvt ui 4 113, Golden House, Gurudwara Road, Daryaganj, New Dell 10002, giving the name an address of the bookseller from where he/she purchased this book, Logether with Ue photocopy she will be sent of the cover and the 4th Page on which the name of the printer is printed, he/she will be sev a cash award of 7 500.00, How to decide if the book is genuine 1. The above information may or m, 2. The counterfeit edition of the without the illusionary depth What is the harm in purchasi; — Po ‘ams. In this case, Compredensive Practical or fake? ay not be printed, mine book may have no LP Hologram or if it. has, it wi as described above, ing duplicate books? er quality of paper and printing — No royalty to authors who book, thus depriving which afte your cyes iting the in writing are scholars and have put their hard labour in wri them of their intellectual rights. bie RCN Ca tee ee LSE a rn sro LP Caron eS NON AOa SO SEM MOCO RnDS BADAA COCs iT Pat Ran eT titeComprehensive PRACTICAL CHEMISTRY FOR CLASS XII Strictly according to new curriculum prescribed by Central Board of Secondary Education (CBSE) and State Boards of Chhattisgarh, Haryana, Bihar, Jharkhand, Kerala, Mizoram, Meghalaya, Uttarakhand and other States following NCERT Curriculum By Dr. N.K. VERMA Formerly, Associate Professor Chemistry Department DAV, College Chandigarh Dr. B.K. VERMANI Dr. NEERA VERMA Associate Professor Formerly, Associate Professor Chemistry Department Chemistry Department DAV, College [Link]. DAV. College Chandigarh Chandigarh K.K. REHANI Formerly, Lecturer of Chemistry S.G.G.S, College Chandigarh LAXMI PUBLICATIONS (P) LTD , (An ISO 9001:2015 Company) BENGALURU ¢ CHENNAI © GUWAHATI ¢ HYDERABAD © JALANDHAR KOCHI © KOLKATA * LUCKNOW © MUMBAI e RANCHI NEW DELHICONTENTS Chapters yllabus |, Introduction to Basic Laboratory Equipment Viva questions with answers 2. Surface Chemistry Exp-2.1: Exp-2.2: Exp-2.3: Exp-2.4: Exp-2.5: Exp-2.6: Exp-2.7: Exp-2.8: Exp-2.9: Exp-2.10: To prepare colloidal solution (sol) of starch To prepare a colloidal solution of gum To prepare colloidal solution (or sol) of egg albumin To prepare ferric hydroxide, [Fe(OH),] sol To prepare aluminium hydroxide, [Al(OH),] sol To prepare colloidal solution of arsenious sulphide, [4s,S,] To study the dialysis of starch sol containing sodium chloride through a cellophane or parchment paper Compare the precipitation values of sodium chloride, barium chloride and aluminium chloride for arsenious sulphide sol To study the effectiveness of different common oils (castor oil, cotton seed oil, coconut oil, kerosene oil, mustard oil) in forming emulsions To compare the effectiveness of agents in forming emulsions a number of emulsifying Viva questions with answers 3. Chemical Kinetics Exp-3.1: Exp-3.2: Exp-3.3: Exp-3.4: {fect of concentration on the rate of reaction nd hydrochloric acid perature on the rate of, te and hydrochloric acid £ iodide ions with To study the e! between sodium thiosulphate ai To study the effect of change in tem] reaction between sodium thiosulphat ‘To study the reaction rate of reaction of io ns with hydrogen peroxide at different concentrations of iodide ions To study the reaction rate of the reaction between potassium iodate (KIO,) and sodium sulphite (Na,SO,) using starch solution as indicator Viva questions with answers Pages (xiii) -Gevi) 1-9 9 10-27 11 12 12 13 15 15 17 19 22 23 24 28-37 29 31 32 34 35wi) ‘Thermochemistry / Exp-4.1: Determine the calorimeter constant (W) of calorimeter (polythene bottle) Determine the enthalpy of dissolution of given solid copper sulphate (CuSO,.5H,O) in water at room temperature Exp-4.3: Determine the enthalpy of neutralisation of hydrochloric acid with sodium hydroxide solution Exp-4.2: Exp-4.4: Determine the enthalpy change during the interaction (hydrogen bond formation) between acetone and chloroform Viva questions with answers Electrochemistry Exp-5.1: To set up simple Daniell cell and determine its EMF Exp-5.2: To set up simple Daniell cell using salt bridge and determine its EMF Exp-5.3: To study the variation of cell potential in Zn | Zn™ || Cu | Cu cell with change in concentration of electrolytes (CuSO, and ZnSO,) at room temperature Viva questions with answers Chromatography Exp-6.1: To separate the coloured components present in the mixture of red and blue inks by ascending paper chromatography and find their R, values Exp-6.2; To separate the coloured components present in the given grass/flower by ascending paper chromatography and determine their R, values Exp-6.3: To separate Co’? and Ni ions present in the given mixture by using ascending paper chromatography and determine their R, values Viva questions with answers Preparation of Inorganic Compounds Exp-7.1: To prepare a pure sample of ferrous ammonium sulphate (Mohr’s salt), [FeSO,.(NH,),SO,.6H,O] ‘To prepare a pure sample of potash alum (Fitkari), [K,SO,,AL(6O,),.24H,0] ‘To prepare a pure sample of the complex potassium trioxalatoferrate(II1), K[Fe(C,0,),].3H,O Viva questions with answers 2a: Exp-7.2: Exp-7.3: 47-(wit) 8. Preparation of Organic Compounds 10-77 Exp8.1: To prepare acetanilide from aniline = 70 Exp-8.2: To prepare dibenzalacetone Eqp-8.3: To prepare panitroacetanilide fiom acetanilide ExpSa: To prepare 2-naphthol aniline dye Bs 18 Viva questions with answers ne vt 9. Tests for the Functional Groups Present in Organic Compounds 78-96 Exp-9.1; To identify the functional group present in the given oxanic compound oa go Viva questions with answers a 98 10, Tests of Carbohydrates, Fats and Proteins in Pure Samples and Detection of their Presence in Given Food Stufts 97-106 Exp-10.1: To study some simple tests of carbohydrates 8 Eyp-10.2: To study some simple tests of oils and tats = too Exp-10.3: To study some simple tests of proteins 5 Ww? Exp-104: To detect the presence of in the following food stutts: rbohydrates, fats and proteins Grapes, potatoes, tice, butter, biscuits, milk, groundnut, boiled egy = Los Viva questions with answers , toa 11. Volumetric Analysis 1o7-150 Exp-1L.1: Prepare 250 ml of 0.1 M solution of oxalic acid trom talline oxalic acid we wy Exp-11.2: Preparation of 250 ml of 0.05 M solution of Moht’s salt os 0 Exp-1L.3: Prepare 0.05 M solution of ferrous ammonium sulphate (Mohr's salt). Using this solution find out the molarity and strength of the given KMnQ, solution . wr Exp-11.4; Prepare a solution of ferrous ammoniun sulphate (Mohr’s sat) containing exactly 17.0 g of the salt in one litre, With the help of this solution, determine the molarity and the concentration of KMn0, in the given solution we te Exp-11.5: Prepare 0.05 M ferrous ammonium sulphate (Moht's salt) solution, Find out the percentage purity of impure KMaO, sample 2.0 g of which have been dissolved per litte es Wt Exp-11.6: Determine the number of molecules of water of crystallisation in a sample of Moh’s salt, FeSO, (NH,),SO,.nH,0. Provided 0.01 M KMnO, “ 133 Exp-11. Prepare x solution of oxalic acid, With its help, determine the molarity and strength of the given solution of potassium permanganate (KMnO,) e Assee (viii) Exp-11.8: Find out the percentage purity of impure sample of oxalic acid. You are supplied 0.01 M KMn0O, solution Exp-11.9: The given solution has been prepared by dissolving 1.6 g of an alkali metal permanganate per litre of solution. Determine volumetrically the atomic mass of the alkali metal. Prepare 0.05 M Mohr’s salt solution for titration Exp-11.10 : Determine the percentage composition of a mixture of COONa COOH sodium oxalate| | and oxalic acid] | .2H,0 |. COONa COOH Provided 0.01 M KMnO, solution Exp-11.11: You are provided with a partially oxidised sample of ferrous sulphate (FeSO,.7H,0) crystals. Prepare a solution by dissolving 14.0 g of these crystals per litre and determine the percentage oxidation of the given sample. Given 0.01 M KMn0, solution Exp-11.12: Calculate the percentage of Fe* ions in a sample of ferrous sulphate. Prepare a solution of the given sample having strength exactly equal to 14.0 g/litre. Provided 0.01 M KMnO, Viva questions with answers 12. Qualitative Analysis Exp-12.1: To analyse the given salt for acidic and basic radicals Exp-12.2: To analyse the given salt for acidic and basic radicals Viva questions with answers INVESTIGATORY PROJECTS Projects 1 Study of Oxalate Ion Content in Guava Fruit Exp-1: To study the presence of oxalate ion content in guava fruit at different stages of ripening ‘Study of the Quantity of Caesin Present in Different Samples of Mill Exp: To study the quantity of caesin present in different samples of milk Preparation of Soyabean Milk and its Comparison with Natural Milk Exp-1: Preparation of soyabean milk and its comparison with the natural milk with respect to curd formation, effect of temperature and taste ‘139 141 144 146 148 151-200 188 190 94 202 208 20! 20: 20! 20110. 1. 12, 13, 3) Study of Effect of Potassium Bisulphite as Food Preservative Under Various Conditions Exp-1: To study the effect of potassium bisulphite as food preservative under various conditions (Concentration, time and temperature) Comparative Study of the Rate of Fermentation of Various Food Materials Exp-1: To compare the rates of fermentation of the following fruit or vegetable juices (i) Apple juice (ii) Orange juice (tif) Carrot juice Exp-2: To compare the rates of fermentation of the given samples of wheat flour, gram flour, rice and potatoes Extraction of Essential Oils Present in Saunf (Aniseed), Ajwain (Carum) and Illaichi (Cardamom) Exp-1: To extract essential oils present in Saunf (Aniseed), Ajwain (Carum) and Illaichi (Cardamom) Study of Adulterants in Food-Stuffs Exp-1: To detect the presence of adulterants in fat, oil and butter Exp-2: To detect the presence of adulterants in sugar Exp-3: To detect the presence of adulterants in samples of chilli powder, turmeric powder and pepper Preparation of an Alum from Scrap Aluminium Exp-1: To prepare potash alum from scrap aluminium Study of the Effect of Metal Coupling on the Rusting of Iron Exp-1: Tostudy the effect of metal coupling on rusting of iron Preparation of Rayon Thread from Filter Paper Exp-1: To prepare rayon threads from filter papers using cuprammonium process Dyeing of Fabrics Exp-1: To dye wool and cotton clothes with malachite green Sterilization of Water with Bleaching Powder Exp-1; Determination of the dosage of bleaching powder required for sterilization or disinfection of different samples of water Setting of Cement Exp-1: ‘To study the setting of mixtures of cement with lime, sand of different qualities, rice husk, fly-ash, etc. (with respect to volume and strength) ‘To study the setting of mixtures of cement with sand, lime and fly-ash with respect to time and strength Exp-2: 209 209 212 213 214 216 216 218 218 219 219 220 220 222 223 225 225 227 228 230 230 234 235 2361 () 14, Study of Prononce of Tnmectichtos and Boatieldes in Headta and Vegetabtos ) . Hyp Toatudy the prorence of iiieetteiden/port ictdon Caitrayeny contalatyg) tn vaio (ruiteand vegetable co ) 18, Comparative Study of Commoevelal Autactda y BiypeEyYoanalywe the piven mamplew of commmoretal antares by! detorminiag the amotnt of hydrocttoric vet they cau } noutralllxe } 1G, Study of Constituents of an Alloy » li Hype ‘Noanalyse a sample of brane qualitatively 7 Q i i APPINDICHS DAD ADPENDIX1 Atomic Masses of Some Common Klement: i APPRNDIX-I1 ; Preparation of Common Reayents used in the Chemical haboratory: LOGARITHMIC TARLKS: W(PREFACE wyised edition of the ‘Zamérefenscue Practical Chemistry’ for tan strictly according to the new syllabus prescribed by that the book will be quite helpful to the students in s. Some of the outstanding features of the book are: We are pleased to present the re ase XII students, The book has been wri tral Boatel of Secondary Balucation, We hope quiring the skills of various laboratory techniques @ Singple language and lucid style. & Wherever required, a large number of illustrations have been given to clarify the use of various apparatuses used in laboratory «the theoretical aspects of each experiment have be en discussed briefly along with the experiment. lations based on normality aswellas on molazity have been given. ¢ Involumetricanalysis calcu the various tests have been given in a systematic way m © In qualitative inorganic analyst tabular form, « morder to guide the students about recording the experiment in the notebook, a specimen record of analysis of a salt has been given in the chapter on qualitative analysis. 4 questions have been included in each chapter. © Alarge number of solved vi We sincerely hope that the book will be appreciated by our Jearned colleagues and students. Wie shal be glad to receive constructive suggestions for the farther improvement of the book. —AUTHORS