09 11 20-CTM11

Sec: Sr.
IIT_CO-SUPER CHAINA Date: 09-11-20

Time: 3HRS Max. Marks: 300
Name of the Student: ___________________ H.T. NO:
09-11-20_ SR_CO-SUPER CHAINA_Jee-Main_CTM-11_SYLLABUS
PHYSICS: PT-11 SYLLABUS (40%) + PT-1 T0 PT-10 SYLLABUS (60%)
CHEMISTRY: PT-11 SYLLABUS (40%) + PT-1 T0 PT-10 SYLLABUS (60%)
MATHEMATICS: PT-11 SYLLABUS (40%) + PT-1 T0 PT-10 SYLLABUS (60%)

Narayana IIT Academy 09-11-20_Sr.IIT_CO-SC _JEE-MAIN_CTM-11_Q’P
PHYSICS MAX.MARKS: 100
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.
1. An inductor coil stores 32 J of magnetic field energy and dissipates energy as heat at the
rate of 320 W when a current of 4 A is passed through it. Find the time constant of the
circuit when it is formed across an ideal battery
1) t = 0.2 s 2) t = 0.32 s 3) t = 0.5 s 4) t = 1 s
2. Three voltmeters are connected as shown
A potential difference has been applied between A and B. On closing the switch S, reading
of voltmeters?
1) V1 increases
2) V1 decreases
3) V2 and V3 both increase
4) one of V2 and V3 increases and other decreases
3. A point object is kept in front of a plane mirror. The plane mirror is doing SHM of
amplitude 2 cm. The plane mirror moves along the x-axis which is normal to the mirror.
The amplitude of the mirror is such that the object is always in front of the mirror. The
amplitude of SHM of the image is
1) 0 2) 2 cm 3) 4 cm 4) 1 cm
4. When the positively charged hanging pendulum bob is made fixed, the work done in
slowly shifting a unit positive charge from infinity to P is V. If the pendulum is free to
move, the corresponding work done is V ' . Then
1) V = V ' 2) V > V ' 3) V < V ' 4) V £ V '
SR.IIT_CO-SC/ N-C Page. No. 2
Education consists mainly of what we have unlearned.

5. Light travelling through three transparent substances follows the path shown in figure.
Arrange the indices of refraction in order from smallest to largest. Note that total internal
reflection does occur on the bottom surface of medium 2.
1) n1 < n2 < n3 2) n2 < n1 < n3 3) n1 < n3 < n2 4) n3 < n1 < n2

6. A harmonic wave is travelling on a stretched string. At any particular instant, the smallest
distance between two particles having same displacement, equal to half of amplitude is 8
cm. Find the smallest separation between two particles which have same values of
displacement (magnitude only) equal to half of amplitude
1) 8 cm 2) 24 cm 3) 12 cm 4) 4 cm
7. When an object is placed on the principal axis of a convex lens at two different positions,
it produces the images with magnifications +2 and –4 respectively. How many times more
away from the lens the image will be formed in the second position as compared to the
first position?
1) 2 2) 4 3) 5 4) 10
8. An a - particle is moving along a circle of radius R with a constant angular velocity w .
Point A lies in the same plane at a distance 2R from the center. Point A records magnetic
field produce by the a - particle. If the minimum time interval between two successive
times at which A records zero magnetic field is t, the angular speed w , in terms of t, is
2p 2p p p
1) 2) 3) 4)
t 3t 3t t
9. Liquid is filled in a vessel which is kept in a room which temperature 20 0 C. When the
temperature of the liquid is 800 C, then it loses heat at the rate of 60 cal/sec. what will be
the rate of loss of heat when the temperature of the liquid is 40 0 C?
1) 180 cal/sec 2) 40 cal/sec 3) 30 cal/sec 4) 20 cal/sec

'
10. Let r and r denote the angles inside an equilateral prism, as usual, in degrees. Consider
that during some time interval from t = 0 to t = t , r ' varies with time as r ' = 10 + t 2 .
During this time, r will vary as (assume that r and r ' are in degree)
1) 50 - t 2 2) 50 + t 2 3) 60 - t 2 4) 60 + t 2
11. The coefficient of linear expansion of an inhomogeneous rod changes linearly from a 1 to
a 2 from one end to the other end of the rod. The effective coefficient of linear expansion
of rod is
a1 + a 2
1) a 1 + a 2 2) 3) a 1a 2 4) a 1 - a 2
2
12. Consider a sphere of radius R made of glass of refractive index m . A small object moves
along the diameter with a constant velocity u. The speed of the image as seen by an
observer outside when the object passes through the centre
1) u 2) mu 3) u m 4) zero
13. If an artificial satellite is moving in a circular orbit around the earth with a speed equal to
half the magnitude of the escape velocity from the earth, the height of the satellite above
the surface of the earth is
R R
1) 2R 2) 3) R 4)
2 4
14. A convex lens of focal length 20 cm and another plano convex lens of focal length 40 cm
are place co-axially (see Figure). The plano convex lens is silvered on plane surface.
What should be the distance ‘d’ so that final image of the object ‘O’ is formed in O itself?
1) 10 cm 2) 40 cm 3) 20 cm 4) 80 cm

15. In the given circuit, the initial charges on the capacitors are shown in the figure. The
charge flown through the switches S1 and S 2 respectively after closing the switches are
Q0 Q0 Q0 Q0 3 Q
1) zero, 2) , 3) zero, 4) Q0 , 0
6 5 2 2 5 6
16. While measuring the acceleration due to gravity by a simple pendulum, a student makes a
positive error of 1% in the length of the pendulum and a negative error of 3% in the value
of time period. His percentage error in the measurement of g by the relation
g = 4p 2 (l T 2 ) will be
1) 2% 2) 4% 3) 7% 4) 10%
17. An object is placed at f 2 away from first focus of a convex lens where f is the focal
length of the lens. Its image is formed at a distance 3 f 2 in a slab of refractive index 3 2 ,
from the face of the slab facing the lens. Find the distance of this face of the slab from the
second focus of the lens.
1) f 2 2) 3 f 2 3) 2f 4) f
18. The distance between an object and the screen is 100 cm. A lens produces an image on the
screen when the lens is placed at either of the positions 40 cm apart. The power of the lens
is nearly
1) 3 diopter 2) 5 diopter 3) 2 diopter 4) 9 diopter

19. A wheel having mass m has charges +q and –q on diametrically opposite points. It
remains in equilibrium on a rough inclined plane in the presence of uniform vertical
electric field E =
1) mg q 2) mg 2q 3) mg tan q 2q 4) mg sin q 2q
20. A concave mirror of radius of curvature h is placed at the bottom of a tank containing a
liquid of refractive index m. An object P is placed at height h above the bottom of the
mirror. Outside the liquid, an observer O views the object and its image in the mirror. The
apparent distance between these two will be
æ 1ö 2h 2h
1) h çç1 - ÷
÷ 2) 3) zero 4)
çè m÷ø m- 1 m

SECTION-II
(Numerical Value Answer Type)
This section contains 5 questions. The answer to each question is a Numerical value. If the numerical value has
more than two decimal places, Truncate/Round-off the value of Two decimal places. Answer to each
question will be evaluated according to the following marking scheme:
Marking scheme: +4 for correct answer, 0 in all other cases.
21. For a prism kept in air, it is found that for an angle of incidence 60 0, the angle of
refraction ‘A’ and angle of emergence ‘e’ become equal. The refractive index of the prism
is
22. A car emitting sound of frequency 500 Hz speeds towards a fixed wall at 4 m/s. An
observer in the car hears both the source frequency as well as the frequency of sound
reflected from the wall. If he hears 10 beats per second between the two sounds, the
velocity (in m/s) of sound in air will be
23. Find the amount of work done (in J ) to increase the temperature of 1 mol of an ideal gas
2
by 300 C if it is expanding under the condition V a T 3
24. Some magnetic flux is change from a coil of resistance 10W. As a result, an induced
current is developed in it, which varies with time as shown in the figure. Find the
magnitude of the change in flux through the coil in weber.
25. In a practical Wheatstone bridge circuit (Figure), when one more resistance of 100W is
connected in parallel with unknown resistance x, then the ratio l1 l2 becomes 2. l1 is the
balance length. AB is a uniform wire. Then the value of x (in W) must be

CHEMISTRY MAX.MARKS: 100
SECTION – I
26. A gas adsorbs 100 J heat and undergoes simultaneous expansion against a constant
external pressure of 104 Pa. If volume changed from 3L to 5L, the change in internal
energy is
1) 50 J 2) 120 J 3) 80 J 4) zero
27. The enthalpy of formation of CO2(g), H2O(l) and propene are –393.5, –285.8 and
20.42 kJ/mol respectively. The enthalpy of isomerization of cyclopropane to propene is
–33 kJ/mol. Then which of the following is the enthalpy change for the combustion of
cyclopropane at 298 K is
1) - 2291 kJ mol–1 2) - 2091 kJ mol–1
3) - 2196 kJ mol–1 4) -2394 kJ mol–1
28. The following energy diagram represents the reaction occurring with and without
positive catalyst , Which of the following statements is correct
1) E4 is the activation energy for the reverse catalysed reaction

2) The forward reaction, which catalyst, is endothermic
3) The enthalpy change of reaction is (E2 – E3)
4) The enthalpy change of reaction is reduced by using a catalyst

29. The entropy of vaporization of benzene is 85 JK–1 mol–1. When 117g of benzene
vaporizes at its normal boiling point, the entropy change of surrounding is
1) –85 JK–1 2) –85 × 1.5 JK–1 3) 85 × 1.5 JK–1 4)85 JK–1
30. When equal volumes of 1M HCl and 1M H2SO4 are neutralized by excess volume of 1M
NaOH solution, x and y KJ of heat is liberated. Then
1) x = y 2) x = 2y 3) 2x = y 4) x > y
31. Consider the following reaction N2O4(g)  2NO2(g)
The energy of the reaction occurring at 298 K and 1 atm has been plotted against the
fraction of N2O4 dissociated as shown adjacent. Mark out the correct statement(s)
1) The conversion of N2O4 into 2NO2 is spontaneous

2) The conversion of 2NO2 into N2O4 is non-spontaneous
3) The attainment of equilibrium from N2O4 and from NO2 both are equally spontaneous
4) The attainment of equilibrium from 2 moles of NO 2 with N2O4 is more spontaneous
than the conversion of 2NO2 into N2O4
32. The difference between heats of reaction of constant pressure and constant volume for
the reaction 2C6H6(l) + 15O2(g)  12CO2(g) + 6H2O(l) at 298K is
1) –7.43 2) +3.72 3) –3.72 4) +7.43
33. If bond energies ‘C = C, and ‘C – C’ at 298 K are 600 and 330 kJ mol–1 respectively, the
enthalpy change when 112 g of ethylene changes into polyethene is
1) -240 kJ 2) -270 kJ 3) -1080 kJ 4) -540 kJ

34. The root mean square velocity of hydrogen is 5 times than that of nitrogen. If T is the
temperature of the gas, then
1) TH  TN
2 2
2) TH  TN2 2
3) TH  TN
2 2
4) TH  7TN
2 2
35. Half-life period of the 1st order reaction is 100 days. After 144 days, concentration of the
reactants is reduced to…. of the original value
1 1 e 3e
1) 2) 3) 4)
e e2 30 30
36. Lead is the final product formed by a series of changes in which the rate determining
state is radioactive decay of uranium –238. This radioactive decay is a first order
reaction with a half-life of 4.5 × 109 years. What would be the age of a rock sample,
originally lead free, in which the molar proportion of uranium to lead is now 1 : 3?
1) 1.5 × 109 years 2) 2.25 × 109 years 3) 4.5 × 109 years 4) 9.0 × 109 years

37. C12 H 22O11  H 2O 

H
 C6 H12O6  C6 H12O6
Sucrose Glu cos e Fructose
Hydrolysis of sucrose is proceeded at a certain temperature and, volume of solution is

maintained as 1L. At the beginning, the initial rotation is found 34º, after 30 min the
total rotation of the solution is 190 and after sufficient time, the total rotation is –11º.
After what time the solution becomes optically inactive?
1) 135 min 2) 103.7 min 3) 38.7 min 4) 45 min
38.
The rate of haloform reaction is found the fastest with
1) X2 = Cl2 2) X2 = Br2
3) X2 = I2 4) All are the same rate, rCl  rBr  rI

2 2 2

39. The produced formed in the reaction
1) 2)
3) 4)
40. The most likely mechanism for the below reaction is
1) SN1 2) SN2 3) E1 4) E2
Br2  KOH
41. CH 3CH 2COOH 
NH3
 
Heat
 H 2O
   A . Product ‘A’ is
1) CH3CH2CH2NH2 2) CH3CH2CH2COOH
3) CH3CH2Br 4) CH3CH2NH2
42. The basic character of the alcohols
1) IV > I > II > III 2) II > III > IV > I

3) IV > II > III > I 4) I > II > III > IV

43.
Here, X and Y are respectively
1) 2)
3) 4)
44.
1) 2)
3) 4)
45. CH3CHO + NH2OH  CH3 – CH = N – OH
The above reaction occurs satisfactorily at
1) pH = 1 2) pH = 12 3) pH = 4.5 4) Any value of pH

SECTION-II
An ordinary D(+) glucose has melting point 146ºC and specific rotation,  O  112º .
25
46.
One another form of D(+) glucose has melting point 150ºC and specific rotation
 O  18.7º . The two forms have significantly different optical rotations but when an
25
aqueous solution of either form is allowed to stand, its rotation changes. The specific
rotation of one form decreases and rotation of other increases, until both solutions show
the same value of +52.7º. This change in rotation towards an equilibrium value is called
mutarotation.
What percentage of -D-(+) glucopyranose is found at equilibrium in the aqueous

solution?
47. The heats of solution of anhydrous CuSO4 and CuSO4.5H2O are –70 and +12 kJ mol–1,
respectively. The heat of hydration of CuSO4 to CuSO4.H2O is
48 If H2S2(g)  H2(g) + 2S(g) ; H = 240 kcal
H2S(g)  H2(g) + S(g); H = 160 kcal
Then, the enthalpy change for the reaction, 8S(g)  S8(g), is - 16x then the value of x is
49. In presence of a catalyst, the activation energy is lowered by 2 kcal at 127ºC. Hence, the
rate as compared to the old rate is eX times, then the vaue of x is
NaOH  CaO
50. A 
 CH 3COONa 
Electrolysis
 B . What is the difference between molar masses of B
to A

MATHEMATICS MAX.MARKS: 100
SECTION – I
51. If A is non –null diagonal matrix of order 3 such that A4  A2 then the possible number of
matrices A are
1) 27 2) 8 3) 7 4) 26
a b c 
52. If A  b c a  ; abc  1and AT A  I then the value of a3  b3  c3 is (Where a,b,c> 0 and
 c a b 
AT denotes transpose of matrix A)
1) 2 2) 0 3) 1 4) 4
 3 2
53. let A and B are square matrices of order 2 such that A  adj  BT     and
 2 3
 2 1
AT  adj  B     then A2  2 A3  3 A4  5 A5  (Where AT is transpose of A and adj is
 1 2
adjoint of matrix of same order)
1) 4A 2) 11A 3) 7A 4) 9A
54. x4 f  x   1  sin  2 x   f  x   2 f  x  then f  2  is equal to
1 1 1
1) 2) 3) 4) 0
17 11 2
55. Let f  x    2 x     2 x  cos x. If the value of

3 d
dx
 f 1  x   at x   can be expressed in the
p
form of ( where p and q are natural numbers in their lowest form), then the value of
q
(p + q) is
1) 1 2) 2 3) 3 4)4

 cos 2   2  4 x  , x 1

56. Let  ,  are positive numbers and f  x    x  4 2 , 1 x  3 is continuous

        x  2, x3
2
1  c
function x  R . If maximum value of cos is , c, d  N , then
d
1) c = d 2) 4c = 5d 3) 16c = 5d 4) c + d = 6
x 2  l  ln x 
57.  l n 4 x  x 4 dx equals
1  x  1 1 lnxx 1 1  l n x 
  l n l n x  x   C   tan  C
2 2
1) l n 2) l n
2 lnx 4 2 lnxx 2  x 
1 lnxx 1 1  l n x  1 lnxx 1  l n x  
3) l n   tan 
4 lnxx 2
C 4)  l n   tan    C
 x  4 lnx x  x 
cos 4 x sin 4 x 1 d
58. If   , then 2 equals (where x is not dependent on 1 &  2 )
1 2 1   2  d 1
1) sin 2 x 2) cos 2 x 3) tan 2 x 4) sec 2 x
 tan x  2 cot x  
Let  tan 1 
tan x  
 dx   then the value of  tan
1
59.   dx equals to :  0  x  
 2   3   2
x x2 x x2
1)    c 2)    c
2 2 2 2
x x2 x x2
3)    c 4)    c
2 2 2 2
60. If the tangent to the curve 2y3  ax2  x3 at the point (a,a) cuts off intercepts  and  on the
coordinate axes such that  2   2  61 , then a=
1) 30 2)  5 3)  6 4)  61
e x f ''  x   e x f '  x 
61. Let f be a twice differentiable function satisfying  1 and
e2 x
1
f  x
f  0  0, f  0  1 , then the value of
'
 dx is
0
x
1) e 2) e  1 3) 1 4) 0

  1  
 x 2  2  I
Let I   e dx, J   e  x dx then
2
 x 
62. equal to
0 0
J
1 1
1) e2 2) 2e2 3) 4)
e2 2e 2
1
sin 1 x 2
63. If the value of the integral 0 x2  x  1dx is
n
where n  N , then the value of ‘n’ is
1) 105 2) 204 3) 108 4) 155

64. If the system of equation x  ky  3z  0,3x  ky  2 z  0, 2 x  3 y  4 z  0 has non trivial
xy
solution, then 
z2
5 5 6 6
1) 2) 3) 4)
6 6 5 5
0 1
65. Consider the matrix B    , then B1027
1 0 
 1 0 0 1 1 0   1 0 
1)  2)  3)  4) 
0 1 
 1 0 

0 1 

 0 1
66. Let a, b, c be three vectors such that a  0 and a  b  2a  c, a  c  1, b  4 and b  c  15.

If b  2c   a then value of  =
1) 4 2) 3 3) 2 4) 1
67. Let A be the set of all 3 3 skew symmetric matrices whose entries are either -1, 0 or 1.
If there are exactly three 0’s three 1’s and three (-1)’s, then the number of such matrices
is
1) 9 2) 4 3) 6 4) 8
68. A and B are two non-singular matrices so that A6  I and AB2  BA  B  I  . A value of K
so that B K  I is
1) 31 2) 32 3) 63 4) 64
 7  5  x 2  3 
69. The maximum value of sec   is1
 2  x2  2 
 
5 5 7 2
1) 2) 3) 4)
6 12 12 3
70. A square matrix A of order 3 satisfies A2  I  2 A, where I is an identity matrix of order 3.
If An  29 A  12 I then n=
1) 3 2) 4 3) 5 4) 6

SECTION-II
 2 4 0 6 2 4

71. Let A  2 B   6 3 3 and 2 A  B  6 1 5  then tr  A  tr  B  is equal to

 5 3 5 6 3 4
(Where tr  A  trace of matrix A)
 x 
If f  x   cot 
x  n
72. n 
2 
then lim

x 
 f  x   
r 1
cos ec r 1  equal to
2 
4
The area of the region bounded by the parabola  y  2   x  1 , the tangent to it at the
2
73.
point with the ordinate 3 and the x-axis is
74. In a ABC , P, Q, R are points on BC, CA and AB respectively, dividing them in the ratio
AP  BQ  CR
1:4, 3:2 and 3:7. The point S divides AB is the ratio 1: 3 .Then 
CS
^ ^ ^
75. Let position vectors of point A, B and C of triangle ABC respectively be i  j  2 k ,
^ ^ ^ ^ ^ ^
i  j  k and 2i  j  k . Let l1 , l2 , l3 be the length of perpendicular drawn from the orthocenter
‘O’ on the sides AB, BC and CA, then the value of 4  l1  l2  l3  .

2

Sec: SR.IIT_CO-SC CTM-11 Date: 09-11-20
Time: 3HRS Max. Marks: 300
KEY SHEET
PHYSICS
1 1 2 3 3 3 4 2 5 4
6 4 7 3 8 2 9 4 10 1
11 2 12 2 13 3 14 3 15 1
16 3 17 4 18 2 19 2 20 3
21 1.73 22 404.00 23 166.28 24 2.00 25 100.00
CHEMISTRY
26 3 27 2 28 3 29 2 30 3
31 4 32 1 33 1 34 3 35 1
36 4 37 2 38 4 39 4 40 3
41 4 42 1 43 2 44 3 45 3
46 64 47 -82 48 40 49 2.5 50 14
MATHEMATICS
51 4 52 4 53 2 54 1 55 4
56 4 57 2 58 3 59 2 60 1
61 2 62 3 63 3 64 2 65 2
66 1 67 3 68 3 69 4 70 3
71 5.80 72 1.00 73 9.00 74 0.40 75 6.00
Narayana IIT Academy 09-11-20_Sr.IIT_CO-SC_JEE-MAIN_CTM-11_KEY&SOL
SOLUTIONS
PHYSICS
1 2
1. Magnetic field energy stored = U = Li
2
1 2
32 = L(4) (or )L = 4 H
2
Power dissipated as heat is P = i 2 R
320 = 42 R or R=20W
L 4
Time constant of circuit = t = = = 0.2s
R 20
2. Initially, when switch is open, V2 and V3 will be out of circuit or they are short-circuited. So no
potential difference is across V2 and V3 . On closing the switch, all three voltmeters will be in
parallel. Now, there is some potential difference across V2 and V3 . So potential difference across
V2 and V3 increases and potential difference across V2 remains the same.
3.
4. If bob is positively charged, it will be repelled by unit positive charge and in second case, distance
between charges may increase. Thus final energy in second case may be less than in first case.
Hence, less work may be done in second case.
5. As the ray moves toward the normal while entering medium 2 from 1, we have n2 > n1
For total internal reflection at interface of 2 and 3, n2 > n3 .
Besides n3 should also be less than n1 or else ray would have emerged in medium 3, parallel to its
path in medium 1. Hence n3 < n1 < n2 is the correct order.
6. Consider the wave as shown in figure. The six
particles (1 – 6) have been shown which all
have displacements equal to ± A 2 form their
equilibrium positions.
To get the separation between two particles

having displacement of amplitude A 2 , we
have
A
= Asin (kx - wt ), at t = 0
2
SR.IIT_CO-SC/N-C Page 2

p 5p l
Þ kx = , ,... and x2 - x1 =
6 6 3
l
Separation between particles 1 and 2 comes out to be , where l is the wavelength. Between
3
l
particles 1 and 3, it is . From given information, separation between 1 – 2, 3 – 4 or 5 – 6 is 8 cm.
2
l
= 8cm Þ l =24cm
3
The separation between 2–3 which is equal to separation between 1–3 minus separation between 1–2
l l l
= - = = 4cm
2 3 6
7. m = + 2; u = - x
v = - 2x
1 1 1
- + = ....(i )
2x x f
Similarly, m = - 4, u = - y and v = + 4 y
1 1 1
+ = .....(ii)
4y y f
1 5
Equating (i) and (ii), =
2x 4 y
x = 0.4 y or y = 2.5x
Required ratio of images = 4 y : 2 x = (4)(2.5): 2 x = 5:1
8. Point A shall record zero magnetic field when
the a - particle is at positions P and Q as
shown in figure. The time taken by
a - particle to go from P to Q is
T 1 2p 2p
t= = ´ or w =
3 3 w 3t
æD Q ö ÷
Rate of loss of heat ç ÷
9. ççè ÷a temperature
t ø
difference D q
æD q ÷ ö
çç ÷
çè t ÷ø1 D q2 60 80 - 20
= Þ =
æD Q ö ÷ D q1 æD Q ö÷ 40 - 20
çç ÷ çç
çè t ø ÷ èç t ø÷÷
2 2
æD Q ÷ö 20 cal
Þ çç ÷ = sec
÷
çè t ø
2
In a prism : r + r = A Þ r = A - r
' '
10.

\ r = 600 - (10 + t 2 )= 50 - t 2
æa 2 - a 1 ö
÷x
The effective value of a at a distance x from the left end is a x = a 1 + ç
çè L ÷
ç
11.
÷
ø
L
æa 1 + a 2 ö
÷
çç
DL = ò x
a dx D t Þ L =
çè 2 ø ÷LD T
÷
0
a1 + a 2
a eff =
2
1 m 1- m 1 1- m m
12. - = Þ = +
- y - x - R y R x
When object is at center : x = R

Putting x = R, we get
2
1 dy m dx dy æy ö ÷ dx
= - Þ = mç
ççè ø÷
- y 2 dt x 2 dt dt x ÷ dt
2
æR ö
Þ v = mçç ÷ u Þ v = mu
çè R ÷
÷
ø
GM 1 2GM
13. = Þ h= R
R+ h 2 R
1 1 (m- 1)
14. For plano convex lens; = ...(i )
f 40 R
1 1 1
For left lens : - = Þ v1 = - 20cm
v1 - 10 20
So image is formed 20 cm to left of lens. Distance of image from plano-convex lens is d + 20 . For
left surface of plano-convex lens:
m 1 m- 1 1 1
- = Þ =
¥ - (d + 20) R d + 20 40
Þ d = 20cm
15. Let q1 charge flows through S1 and q2 through S 2 . For capacitor of capacitance 2C ,
Q0 + q1 = 2CV = Q0 or q1 = 0
For capacitor of capacitance C,
Q0 Q Q
+ q2 = CV = 0 or q2 = 0
3 2 6
Dl DT
16. Given that ´ 100 = + 1% and ´ 100 = - 3%
l T
Percentage error in the measurement of g is
é4p 2l ù
ê 2 ú= 100 ´ D l - 2 ´ D T ´ 100 = 1% - 2[- 3% ]= + 7%
êT ú l T
ë û

æ fö 3f
17. u = - çç f + ÷÷
÷= -
çè 2ø 2
3
Distance of final image from slab is f . Distance of
2
image formed due to convex lens from faces of the slab
(3 2) f
facing the lens = = = f
m
Let F2 S = x
V = 2f + x
1 1 1
From - =
v u f
1 1 1
- = or x = f
(x + 2 f ) (- 3 f 2) f
18. At first position of lens, let the distance of lens from object and screen be x and y, respectively.
\ x + y = 100....(i )
\ At second position of lens, the distance of lens from object and screen shall be y and x,
respectively.
\ y - x = 40...(ii )
Solving eq (i) and (ii), we get
70
y = 70cm = m
100
30
and x = 30cm = m
100
Therefore, the power of lens is
1 1 1 100 æ 100 ö 100

= + = + çç ÷ ÷= » 5diopter
f y x 70 çè 30 ÷ø 21
19. Balancing torque about –q is
mg
qE 2 R sin q = mg sin qR or E =
2q

20. There will be two images on by direct observation n other by reflection

through mirror.
Realdepth
Apparent depth =
mrel
Realdepth d - h
= =
æm ö
çç incident ÷ ÷
çèmrefractive ÷
÷
ø
( )
m
1
(d - h)
d app =
m
Object P is placed at the centre of curvature of the mirror. Its image will be
formed at P itself.
So, for image also,
(d - h) (d - h)
d app = - =0
m m
21. given i = 600 , A = d = e
d= i + e- AÞ d= i
(Q e = A)and d = i = e
æA + dm ÷
ö
sin ççç ÷
÷
è 2 ø
m=
A
sin
2
Here, angle of deviation is minimum (Q i = e)
æ600 + 600 ÷
ö
sin çç ÷
÷
çè 2 ÷
ø
m= = 3
600
sin
2
22. The frequency that the observer receives directly from the source has frequency n1 = 500 Hz . As
the observer and source both move towards the fixed wall with velocity u, the apparent frequency of
the reflected wave coming from the wall to the observer will have frequency
æ V ö
÷
n2 = çç ÷500 Hz
çèV - u÷
ø
Where V is the velocity of sound wave in air. The apparent frequency of this reflected wave as heard
by the observer will then be
æV + uö æV + u öæ ö æV + u ö
n3 = çç ÷
÷ ç ÷
÷çç V ÷
÷500 Hz = ç ÷
÷
çè V ÷n2 =
ø èçç V ÷çV -
øè u÷
ø ÷500 Hz
èççV - u ø
It is given, that the number of beat per second is n3 - n1 = 10

æV + u ö÷
\ (n3 - n1 )= 10 = çç ÷
÷500 - 500
çèV - u ø
éV + u ù
Þ 10 = 500 ê - 1ú
êëV - u ú û
2´ u ´ 500
Þ 10 =
V- u
Hence 10V = 1000u + 10u = 1010u
Putting u = 4 m ,
s
1
V = [4040]= 404 m
10 s
23. PV = RT for 1 mol
RT
W = ò PdV = ò dV
V
V = CT 2 3
2 dV 2 dT
dV = CT - 1 3dT or =
3 V 3 T
T2
æ2 ö
W = ò RT çç ÷
çè 3 ÷
÷R (T2 - T1 )= 166.28 J
T
ø
1
24. D f = R(D q)= R ò i dt

= R[area under i - t graph ]
1
= (4)(0.1)(10)= 2Wb
2
25. The Wheatstone bridge is in balanced condition, so
100 x
100 100 + x
=
l1 l2
l
\ 1 = 2 or x = 100 W
l2

CHEMISTRY
26. dQ = + 100 J
dV = 5 - 3 = 2Lit = 2´ 10- 3 m3
dW = - PdV = - 104 ´ 2´ 10- 3 = - 20 J
dE = dQ + dW = 100 - 20 = 80 J
27. C(S ) + O2(g ) ® CO2(g ), D H = - 393.5KJ
1
H 2(g ) + O2 ® H 2O(l ), D H = - 285.8KJ
2 (g )
3C(S ) + 3H 2(g ) ® C3 H 6(g), D H = 20.42KJ
D (g ) ® C3 H6(g ), D H = - 33KJ
9
D (g ) +
O ® 3CO2(g ) + 3H 2O(g ), D H = - 2091KJ
2 2(g )
28. H = E2 – E3 = E1 – E4
117
29. No of moles of Benzene = = 1.5
78
\ D Ssystem = 1.5´ 85 J K
Hence \ D Ssurrounding = - 1.5´ 85JK
- 1
30. 1M H 2 SO4 gives twice equivalents of H + ions than 1M HCl (Volume is constant)
\ 2x = y
31. 2NO2 N2O4 , Gº  6.24 kJ
2 NO2  N 2O4 , G º  5.40 kJ
32. D H - D E = D n ×RT = - 3´ 8.314´ 10- 3 ´ 298 = - 7.43kJ

33. n(CH 2  CH 2 )  (CH 2  CH 2 )n
H = nBEC = C – 2n BEC – C
= n × 600 – 2n × 330
= –60 n
For 112 grams of ethylene n=4
Therefore Enthalphy change D H= - 60X4 = - 240KJ
T
3RT CH 2 H 2 M N2 5 T
H 2 28
34. C   M
T   T

M CN 2 H2 N2 1 N2 2

T T
H2 H 5
5 T
14  T 2   T N 2  T H 2
N2 N 2 14
35. t = 144 = 1.44 × 100 = 1.44 t ½
1
 tavg = 144 min and  
tavg
1 C
l = ln 0
t Ct
1
C0 Ct - l×
Þ =e Þ
lt
=e =e
- lt l
= e- 1
Ct C0
Ct 1
\ =
C0 e
1 3 1 3
36. Molar ratio of U : Pb = 1 : 3 = :  :
1 3 1 3 4 4
1 t1 1 t 12 1
Hence amount of U left in of original 1  2
  
4 2 4
Hence age of rock = 2t 1  2  4.5 109  9 109 years
2
2.303  r  t0  2.303  3 2 
37. K log   log --- (1)
t r 
  tr 30
When solution is optically in active rt = 0
2.303  45 
K  log   --- (2)
t  11 
On solving (1) & (2) t = 103.7 min.
38. The haloform reaction rate is independent of nature of halogen and conc. of halogen.
39. It is an S N 2 reaction.
40. Condition suggest E1, elimination mainly due to heat.

41. CH 3CH 2COOH 
NH3
 CH 3CH 2COONH 4 
 H 2O
 CH 4CH 2CONH 2  Br2 / KOH
Hoffmann bro modeg radation
 CH 3CH 2 NH 2
42. Conjugate of a weak acid is strong base

1
43. Acid catalysed reaction proceeds through SN where as in presence of CH 3ONa (Strong
2
nucleophile) proceeds through SN mechanism
44.

45. Optimum P H for nucleophilic addition reactions in aldehydes is 4.5

46. Let  forms by ‘x’ then -form is (100 – x)
[18.7 × x] + (100 – x)112 = 52.7
x = 64%
47. CuSO4(s) + water  CuSO4(aq) H = –70 kJ
CuSO4.5H2O(s) + water  CuSO4(aq) H = +12 kJ
CuSO4(s) + water  CuSO45H2O H = –82 kJ
48. From the data H2S bond energy = 160 K.Cal
 Each S–H bond energy = 80 K.Cal
Further
2 BFS  H  1BES  S  H H 2 S2
2  80  BFS S  240 K .Cal

 Each S–S bond energy = 80 K.Cal
S8 molecule in cyclic containing 8 S–S bonds
 Enthalpy change for formation of S8 = –640 K.Cal
 x =40
E1  E2
K2
49.  e RT
K1
E1  E2 2 1000
  2.5
RT 2  400
K2
  e 2.5
K1
50. B = C2H5 and A = CH4 Ans = 14

MATHS
 d1 0 0
51. Let A   0 d 2 0 
 0 0 d3 
 d12 0 0   d14 0 0 
   
A2   0 d22 0  and A4   0 d22 0 
0 0 d32  0 0 d32 
 
A4  A2  d1  d1
2 4
 d1  0, 1,1
Similarly d 2  0, 1,1
& d3  0, 1,1
A can’t be a null matrix
The no of possible matrix = 33  1
= 27 1
= 26
52. A A I
T
 A2  I
 a 2  b2  c 2  1 and ab  bc  ca  0
a  b  c  1  2  0  1  a  b  c  1
2
a 3  b3  c3  3abc   a  b  c   a 2  b 2c 2  ab  bc  ca 
= 11  0  3 1  4
3 2  2 1
53. Let x    and y   1 2
2 3  
A  adjB  x and A  adjB  y  A  adj BT  yT
T T
1 1
2 A  x  yT   
1 1
1 1 1
 A 
2 1 1
 A2  A  A3  A  A4  A5  A
54. We shall consider two cases
Case –(i) : when f  x   0, so
x 4 f  x   1  sin 2 x  f  x   2  f  x  
1  sin 2 x
 f  x 
1  x4 
1
Hence, f  2  
17
Case – (ii) : when f  x   0, so
1  sin 2 x
x4 f  x    0 ( not possible)
x4  3

1
Hence, f  2  
17
55. g  x   f 1  x 
 1
f  f  x    x  g1  f  x   , f 1  x   1  g1  f  x   
1
x 
f  x 2 3
56. Continuous at x = 1
 cos 2   2  4   1  4  2
 a 2 cos2   4 2  4cos2   1 ………(i)
Continuous at x = 3
3  4 2     2  3 2  2
   1
Use A.M.  G.M
 2 cos2   4 2
 2 cos 
2
1  4cos2   4 cos 
2 1
 Maximum value of cos  
2
x 2 1  l n x  1 l n x
57. I  dx   dx
  l n x 
4
   l n x 
4

x4    1 x2    1
  x     x  
   
lnx 1 l n x
Put t  dt
x x2
dt dt
I  4  2
 t  1  t  1 t 2  1
1  t  1   t  1
2 2
2   t 2  1 t 2  1
dt
1  dt dt  1  1 t  1 
I   2  2   ln  tan 1 t 
2  t 1 t 1  2  2 t 1 
1 lnxx 1 1  l n x 
 l n   tan  C
2 lnxx 2  x 
 cos4 x sin 4 x 
58. 1  2     1
 1 2 
 
cos 4 x  sin 4 x  2 cos 4 x  1 sin 4 x  
1 2
 
1  2sin 2 x cos 2 x  2 cos 4 x  1 sin 4 x  0
2 2
2
 2  
 cos 2 x  2 sin 2 x   0
 1 2 

2
tan 2 x 
1
 2  1 tan 2 x
d 2
 tan 2 x
d1
1  tan x  2 cot x 
59.  tan  3
 dx

1  tan x  2 
2
 tan  3tan x  dx
  tan x 1 
  x  tan x  
1  
 tan  tan x t  dx
1
 2 tan x 
1  tan x 1  1 
 tan  2  tan  tan x   dx
 1 
   tan 1   dx
 tan x 
 
     cot 1 cot x  dx
2 
 
     x  dx
2 
 x 2
  x c
2 2
dy 2ax  3x 2 5a 2 5
60.   2  at (a,a)
dx 6 y2 6a 6
5
Equation of ta tangent is y  a   x  a   5 x  6 y  a  0
6
  a / 5,   a / 6
a2 a2
 2   2  61    61  61a 2  61 25 36   a  30
25 36
d  f '  x 
61. Given   1
dx  ex 
f '  x
  xC
ex
Put x=0
1
 0  CC  1
1
 f '  x   e x  x  1  f  x   xe x  k
Put x  0  k  0  f  x   xe x
f  x x
 e
x

1
  e x dx  e  1
0
1  1    1 
 x 2  2   x 2  2 
62. I  e  x 
dx   e  x 
0 0
  1
1 1  t 2  t 2 
In the first integral let x  to get
t 1 t 2 e dt
  1 
 1   x2  x2  1
 I   1  2  e dx let t  x 
1
x  x

 t 2  2  J 1 1
 e dt  2   2
0
e J e
sin 1 x
1
63. I  dx …………….(1)
0
x2  x  1
sin 1 1  x cos1 x
1 1
I  dx  0 x2  x  1 ………….. (2)
0
x2  x  1
b b
Applying  f  x  dx   f  a  b  x  dx
a a
On adding 1 and 2 we get

1
sin 1 x  cos 1 x  1 dx 1 dx
2I   dx    
0
x  x 1
2
2 0 x  x 1 2 0 
2
1  3
2 2
x   
 2  2 
1
  1  2 x  1  
1 2
2I  .  tan   
2  3  3 0 3 3
 
 2 
2 2 2 2
Hence I      n  108
6 3 108 n n
1 k 3
33
64. 3 k 2  0  k 
2
2 3 4
x y 3
By cross multiplication rule using the last 2 equations,  
6  4k 8 9  2 k
x y z xy 5
    
15 2 6 36 6
0 1 2  1 0
B ,B   0 1
65. and
1 0  
1 0 
B4   I
0 1 
B1027   B 4 
256
.B3

 1
255
.B3
 I . B3
 B3
 B. B 2
0 1  1 0   0 1 
   
1 0   0 1  1 0
66. b  c  15
b c sin 2 b, c  15 
 
sin b, c 
15
4
 
 cos b, c 
1
4
2 2
b  2c   2 a
 
2 2
b  4 c  4 b c cos b, c   2
1
16  4  4  4  2   2
4
16   2
  4
67. For skew symmetric matrix of order 3  3
i) All principal diagonal elements must be zero
ii) aij  a ji
So number of such matrices is 3!  6
68. A5  AB 2   A5 BA.
 B 2  A5 BA
 B 4   A5 BA  A5 BA   A5 B 2 A  A5  A5 BA  A
 B 4 A4 BA2
 B8   A4 BA2  A4 BA2   A2 B 2 A2  A2  A5 BA  A2
 B8  A3 BA3
 B16   A3 BA3  A3 BA3   A3 B 2 A3  A3  A5 BA  A3  A2 BA4
A32   A2 BA4  A2 BA4   A2 B 2 A4  A2  A3 BA  A4  ABA5
A64   ABA5  ABA5   AB 2 A5  A  A5 BA  A5  B  A63  I
7  5  x 2  3
69. Let y 
2  x2  x 
  4 y  3
x2  0
y2
3
  y  2
4
 1  2
Max. value of sec 1 y is sec 1  2   cos 1   
 2  3

70. A  A . A  A  I  2 A
3 2
= A  2 A2
 A  2  I  2 A
= A  2I  4 A  5 A  2I
Similarity find A4 , A5 ,--------
71. Let A  2B  x
2A  B  y
1
 A   x  2y
5
1
and A   2 x  y 
5
16 10 12
A  B    x  3 y   12 6 12
1 1
5 4
 1 6 7 
29
tr  A  B    5.80
5
n n
x 1
72. We have  cos ec r 1  
r 1 2 r 1  x 
sin  r 1 
2 
 x x
sin  r 1  r 
2 2 
n

r 1  x  x 
sin  r  sin  r 1 
2  2 
 x   x  x   x
sin  r 1  cos  r   cos  r 1  sin  r 
 
n
2  2  2  2 
r 1  x  x 
sin  r  sin  r 1 
2  2 
n
  x  x 
  cot  r  cot  r 1 
r 1  2  2 
  x   x x  x cot x   x
  cot    cot x    cot 2  cot   ....   cort n  n1   cot  n   cot x
 2   2 2  2 2  2 
n
 x 
 f   x    cos ec  r 1   cot x
r 1 2 
Hence lim cot x  1

x
4
Given parabola is  y  2   x  1
2
73.
1
Tangent at  2,3 is y  3   x  2y  4  0
2
By the graph
 
3 3
 y  2   1 dy    2 y  4  dy
2
0 0

c  4b 3a  2c 3b  7a  10c b  3a  4c
74. OP  ; OQ  , OR  , CS 
5 5 10 4
c  4b  5a 3a  5B  2c 3b  7a  10c b  3a  4c
AP  ; BQ  , CR  , CS 
5 5 10 4
AP  BQ  CR 4 2
   2:5
CS 5 5
75. l1  l2  l3
3
 2
2
 1
Now in –radius r   4 
s 3
2
 2 6
3 6
  l1  l2  l3   
6 2
2
 6
4  l1  l2 3   4     6
2
 2 

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Sec: Sr.

IIT_CO-SUPER CHAINA Date: 09-11-20

Name of the Student: ___________________ H.T. NO:

09-11-20_ SR_CO-SUPER CHAINA_Jee-Main_CTM-11_SYLLABUS

PHYSICS: PT-11 SYLLABUS (40%) + PT-1 T0 PT-10 SYLLABUS (60%)

CHEMISTRY: PT-11 SYLLABUS (40%) + PT-1 T0 PT-10 SYLLABUS (60%)

MATHEMATICS: PT-11 SYLLABUS (40%) + PT-1 T0 PT-10 SYLLABUS (60%)

1) t = 0.2 s 2) t = 0.32 s 3) t = 0.5 s 4) t = 1 s

2. Three voltmeters are connected as shown

1) V = V ' 2) V > V ' 3) V < V ' 4) V £ V '

SR.IIT_CO-SC/ N-C Page. No. 2

Education consists mainly of what we have unlearned.

1) n1 < n2 < n3 2) n2 < n1 < n3 3) n1 < n3 < n2 4) n3 < n1 < n2

1) 180 cal/sec 2) 40 cal/sec 3) 30 cal/sec 4) 20 cal/sec

SR.IIT_CO-SC/ N-C Page. No. 3

Education consists mainly of what we have unlearned.

SR.IIT_CO-SC/ N-C Page. No. 4

Education consists mainly of what we have unlearned.

1) 3 diopter 2) 5 diopter 3) 2 diopter 4) 9 diopter

SR.IIT_CO-SC/ N-C Page. No. 5

Education consists mainly of what we have unlearned.

apparent distance between these two will be

SR.IIT_CO-SC/ N-C Page. No. 6

Education consists mainly of what we have unlearned.

SR.IIT_CO-SC/ N-C Page. No. 7

Education consists mainly of what we have unlearned.

1) - 2291 kJ mol–1 2) - 2091 kJ mol–1

3) - 2196 kJ mol–1 4) -2394 kJ mol–1

1) E4 is the activation energy for the reverse catalysed reaction

SR.IIT_CO-SC/ N-C Page. No. 8

Education consists mainly of what we have unlearned.

1) –85 JK–1 2) –85 × 1.5 JK–1 3) 85 × 1.5 JK–1 4)85 JK–1

31. Consider the following reaction N2O4(g)  2NO2(g)

1) The conversion of N2O4 into 2NO2 is spontaneous

1) -240 kJ 2) -270 kJ 3) -1080 kJ 4) -540 kJ

SR.IIT_CO-SC/ N-C Page. No. 9

Education consists mainly of what we have unlearned.

37. C12 H 22O11  H 2O 

Hydrolysis of sucrose is proceeded at a certain temperature and, volume of solution is

1) 135 min 2) 103.7 min 3) 38.7 min 4) 45 min

The rate of haloform reaction is found the fastest with

3) X2 = I2 4) All are the same rate, rCl  rBr  rI

SR.IIT_CO-SC/ N-C Page. No. 10

Education consists mainly of what we have unlearned.

40. The most likely mechanism for the below reaction is

1) IV > I > II > III 2) II > III > IV > I

SR.IIT_CO-SC/ N-C Page. No. 11

Education consists mainly of what we have unlearned.

Here, X and Y are respectively

45. CH3CHO + NH2OH  CH3 – CH = N – OH

The above reaction occurs satisfactorily at

1) pH = 1 2) pH = 12 3) pH = 4.5 4) Any value of pH

SR.IIT_CO-SC/ N-C Page. No. 12

Education consists mainly of what we have unlearned.

What percentage of -D-(+) glucopyranose is found at equilibrium in the aqueous

48 If H2S2(g)  H2(g) + 2S(g) ; H = 240 kcal

H2S(g)  H2(g) + S(g); H = 160 kcal

SR.IIT_CO-SC/ N-C Page. No. 13

Education consists mainly of what we have unlearned.

AT denotes transpose of matrix A)

54. x4 f  x   1  sin  2 x   f  x   2 f  x  then f  2  is equal to

55. Let f  x    2 x     2 x  cos x. If the value of

SR.IIT_CO-SC/ N-C Page. No. 14