28-09-20 CTM-07

Sec: Sr.
IIT_CO-SUPER CHAINA Date: 28-09-20

Time: 3HRS Max. Marks: 300
Name of the Student: ___________________ H.T. NO:
28-09-20_Incoming.SR_CO-SUPER CHAINA_Jee-Adv_CTM-7_SYLLABUS
PHYSICS: PT-7 SYLLABUS (40%) + PT-1 T0 PT-6 SYLLABUS (60%)
CHEMISTRY: PT-7 SYLLABUS (40%) + PT-1 T0 PT-6 SYLLABUS (60%)
MATHEMATICS: PT-7 SYLLABUS (40%) + PT-1 T0 PT-6 SYLLABUS (60%)

Narayana IIT Academy 28-09-20_Sr.IIT_CO-SC _JEE-MAIN_CTM-7_Q’P
PHYSICS MAX.MARKS: 100
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.
1. In a region there is uniform electric field along +ve X- axis and uniform magnetic field
along +ve Y -axis given by E  E0iˆ & B  B0 ˆj . A particle having charge q and mass m is
released from rest from origin. The path of the particle is (neglect gravity)
1) a circle 2) a parabola 3) a helix 4) cycloid
released from rest from origin. It’s x-component of velocity after time t after it’s release
will be (neglect gravity)
E0  B qt  E0  B qt 
1) cos  0  2) sin  0 
B0  m  B0  m 
E0   B0 qt   E0   B0 qt  
3) 1  cos   4) 1  sin  
B0   m  B0   m 
released from rest from origin. Speed of the particle at a general point P  x, y, z  is
(neglect gravity)
1)
2E0 qx
2)
2E0 q x 2
 y2  3)
2E0 qz
4)
E0
m m m B0
4. A charged particle enters a region of space and comes out of the region without any
change in it’s velocity. For this the region of space should not have( E is intensity of
electric field and B is magnetic induction field strength) (neglect gravity)
1) E  0, B  0 2) E  0, B  0 3) E  0, B  0 4) E  0, B  0
SR.IIT_CO-SC Page. No. 2
Education consists mainly of what we have unlearned.

5. An infinite long straight wire carries a current i . A particle having charge q and mass
m kept at a perpendicular distance d from the wire is projected towards the wire with
speed v . The minimum separation between the wire and the particle is (neglect gravity)
 2 mv    mv    mv 
     
 0iq   0iq   2 0iq 
1) 0 2) d e 3) d e 4) d e
6. A particle of specific charge (q/m) is projected from the origin of coordinates with initial
velocity u iˆ  v ˆj  . Uniform electric and magnetic fields exist in the region along the
 y direction, of magnitudes E and B respectively. The particle will definitely return to
the origin once if (neglect gravity)
1) vE / 2 B is an integer 2)  u 2  v 2   B /  E  is an integer

12
3) vB /  E  is an integer 4) uB /  E  is an integer
7. In the given loop length of each side is a. Current flowing through the loop is I  1 amp .
Find its magnetic dipole moment.
 
a2  ^  a 1  2  ^  2  ^ 
2

a2  ^  a 1  2  ^  2  ^ 
2

1)  j i  a k  2) i    j a k 
2  2     2  2    
^ 2
 
^ a  ^ 
 
4) a  j   a 2 1  2  i    k 
2 2
^ ^ a ^
3) a  j   a 1  2  i    k 
2 2
    2      2 

8. Two particles A and B of same mass and having charges of same magnitude but of
opposite nature are thrown into a region of magnetic field (as shown) with speeds v1
and v2  v1  v2  . At the instant particle A escapes out of the magnetic field, angular
momentum of particle B w.r.t. particle A is proportional to (assume both the particles

escape the region after traversing half circle) (neglect gravity)
1) v1  v2 2) v1  v2 3) v12  v22 4) v12  v22
9. A hollow cylinder having infinite length and carrying uniform current per unit length
 along the circumference as shown. Magnetic field inside the cylinder is
0 
2) 0  3) 2 0  4) 30 
1) 2
10. The deflection of a galvanometer falls to 1 / 10th when a resistance of 5 is connected in

parallel with it. If an additional resistance of 2 is connected in parallel to the
galvanometer, the deflection falls to (When compared with initial deflection without
shunt)
1 1 2 3
1) th 2) th 3) th 4) th
6 16 65 36

11. The grid represents a region in a space containing a uniform electric field (each square
of size 1 m x1 m). If potentials at point O,A,B,C,D,E,F,G,H are respectively 0,-1,-
2,1,2,0,-1,1 and 0 volts. Find the electric field intensity.
1)  i  j  V / m 2)  i  j V / m 3)   i  j  V / m 4)   i  j  V / m
^ ^ ^ ^ ^ ^ ^ ^
       
12. A gas is undergoing an adiabatic process. At a certain stage, the volume and absolute
temperature of the gas are V0 , T0 and the magnitude of the slope of V-T curve is m . Molar
specific heat of the gas at constant pressure is [Assume volume of the gas is taken on y-
axis and absolute temperature of the gas taken on x-axis]
1)
mRT0
2)
mRT0
3)
V0  mT0  R 4)
V0  mT0  R
V0 2V0 V0 2V0
13. A vessel of volume V0 contains an ideal gas at pressure P0 and temperature T. Gas is
dV
continuously pumped out of this vessel at a constant volume rate  r , keeping the
dt
temperature constant. The pressure of the gas being taken out equals the pressure inside
the vessel. Find the pressure of the gas as a function of time
 rt rt
1) P  P0e  rt
2) P  P0e V0
3) P  P0 4) P  P0e V0
14. An ideal mono atomic gas is confined in a cylinder A of volume V0 at pressure 2 Patm and
temperature T0. Cylinder A is connected to another cylinder B with the help of tube of
negligible volume. The cylinder B is fitted with movable piston, which can be adjusted
from outside. Initially, piston is in contact with the left wall of cylinder B. Now stop-
cork is opened, this allows a very slow transfer of gas from cylinder A to cylinder B.
Cylinders A, B, connecting tube and piston are made of heat insulting material. Choose
the incorrect option of the following.

1) Final volume of the gas in two cylinders is 1.6V0
2) Work done by total gas system is 0.6 Patm V0
3) Final temperature of the system is 0.6T0
4) Decrease in internal energy of the system is 0.6 Patm V0
15. A cube made of non-conducting material has uniform charge distribution throughout its
volume. Assuming electric potential due to a point charge at infinite distance from it to
be zero, electric potential at the Centre of the cube due to the charge distribution in the
cube is found to be V0 , then electric potential at one of its corners is
V0 V0 V0
1) V0 2) 3) 4)
2 4 8
16. In the circuit shown in the figure, the incorrect option is
(1) Current passing through 2 resister is 2A
(2) Current passing through 3 resister is 4A
(3)Current in wire DE=0
(4) Potential of point A is 10 V.

17. H 2O is at its triple point. In column-I changes in pressure or temperature are given and as
a result the state of substance H 2O is given in column-II. Then match column-I with
column-II
Column-I Column-II
a) Keeping pressure constant if
p) Solid
temperature is increased
b) Keeping pressure constant if
q) Liquid
temperature is decreased
c) Keeping temperature constant if
r) Vapour
pressure is increased
d) Keeping temperature constant if Substance can exist in three
s)
pressure is decreased states
1) a  p, b  r , c  s, d  r 2) a  q, b  s, c  r , d  p
3) a  r , b  p, c  q, d  r 4) a  r , b  q, c  p, d  s
18. A student measures the length of a simple pendulum as 1m with a scale of least 1 mm to
determine ' g ' the acceleration due to gravity. He uses a stop watch with least count of 1
second and records 40 seconds for 20 oscillations. The incorrect statement of the
following is.
1) Error T in measuring T the time period is 0.05 second
2) Error T in measuring T the time period is 1 second
3) Error in the measurement of 1 the length of the pendulum is 1 mm
4) Percentage error in the determination of g is 5.1%
19. A metal sheet (whose  is positive) has two circular holes as shown in figure. a is
distance between centres of the holes and b is distance between nearest edges of the
holes and c is distance between farthest edges of the holes as shown in figure. On
heating

1) a remains constant b and c increase
2) a remains constant b decreases and c increase
3) All distances a, b, c increase
4) a remains constant, b increases, c decreases
20. A cylindrical vessel is partially filled with a liquid. Coefficient of real expansion of
liquid is  and coefficient of linear expansion of vessel is  . What is the relation
between  and  for the length (height) of liquid column in the vessel to remain same at
all temperature.
3
1)   3 2)   2 3)    4)   
2
SECTION-II
(Numerical Value Answer Type)
This section contains 5 questions. The answer to each question is a Numerical value. If the numerical value has
more than two decimal places, Truncate/Round-off the value of Two decimal places. Answer to each
question will be evaluated according to the following marking scheme:
Marking scheme: +4 for correct answer, 0 in all other cases.
21. Find the magnetic induction field strength due to current i flowing in an elliptical loop at
l
its focus. The equation of ellipse (in polar coordinates as shown) is  1  e cos   . Here
r
e is eccentricity which is a constant. Take l  50 cm, e  0.8 , i  2 A . If your answer
is n 107 T . Find the value of ‘n’?

22. Consider the circuit in Fig. made from identical resistors and voltmeters. First voltmeter
shows V1  10V and the third V3  2V . What reading does the second voltmeter show (in
Volts)?
23. In a verniercalipers 1 main scale division is 1 mm and there are 10 divisions on vernier
scale which match with 9 divisions on main scale. When there is no object between the
jaws (when they are in contact) the zero mark of the vernier scale is to the left of zero th
mark of main scale and 8th division of vernier scale coincided with one of the main scale
divisions. When a plate is kept between the jaws 0th mark of vernier scale crossed 12
mm mark on the main scale and vernier coincidence is 3. The correct thickness of the
plate (in mm)is
24. A body is projected from the Earth’s surface with a velocity equal to half the escape
velocity from that point at an angle 450 with horizontal. The maximum height attained
by the body above the Earth’s surface is nR. Find the value of n.
25. A copper calorimeter of water equivalent 125g contains 150g of water and the system is
at 300 C . If steam at 1000 C is passed into it till the temperature of the system rises to 900 C ,
the mass of steam passed into the calorimeter in gram is

CHEMISTRY MAX.MARKS: 100
SECTION – I
26. Choose the correct statement from the given
1)Sum of locant number of methyl groups of following structure is 7.
2)Number of pi bonds in picric acid is 6.
3)Number of C-C bonds in hexamethylene tetra amine (Urotopine) is zero.
4)Given all statements are correct.
27. The C-C single bond length in ethane is 1.54 A.The single bond length of C-C in
propene is ______________, due to ______________
1) 1.54Angstroms, due to no resonance
2) Less than 1.54A, due to hyperconjugation.
3) More than 1.54A, due to resonance.
4) Less than 1.54A, due to resonance.
28. Choose the correct statement related to the following structure(X)

1) X has more enol content(percentage) than PhCOCH2COCH3.
2) Hydrogens of active methylene group of X are less acidic than hydrogens of active
methylene group of melonic Ester.
3) Rate of reactivity of phenyl rings of compound X is more towards electrophilic

aromatic substitution than the compound benzene.
4) Compound X shows positive response towards NaOCl and Tollens reagents.
29. Which of the following statement is incorrect, regarding the reaction given
NH 2 OH  
H  or
2  Butanone   A 
PCl5
B
1) Compound A obtained as geometrical isomers of two.
2) Compound B is either N-methyl Propanamide or N-ethyl Ethanamide.
3) Compound B is Butanamide.
4) Formation of compound A is nucleophilic addition elimination reaction.
30.

Difference in the molecular weight of X and Y is P, Y and Z is Q and X and Z is R.

Sum of P, Q, R is
1) Zero 2) 2 3) 1 4) 4
31. A compound with a molecular formula C6H14 has two 3ohydrogen atoms. Number of
primary hydrogens are
1)4 2)16 3)12 4)9
32.
Product P1 and P2 are respectively
1) 2)

3) 4)
33. C7 H14  A 
O3
Zn
 Acetaldehyde  3  Pentanone
C7 H14  B  
O3
Zn
 Propanal  2  Butanone
Compound A and B are aliphatic acyclic hydrocarbons. Choose the correct statement
regarding A and B
1) A and B are geometrical isomers.
2) Structure A exhibits geometrical isomerism
3) Structure B exhibits geometrical isomerism
4) Structure A exhibits geometrical isomerism and also contains one chiral carbon
34. The ease of acid-catalysed dehydration of C2 H5OH , CH3 2 CHOH and CH3 3 COH
follows the order
1) CH3 3 COH  CH3 2 CHOH  C2 H5OH
2) C2 H5OH  CH3 2 CHOH  CH3 3 OH
3) CH3 2 CHOH  CH3 3 COH  C2 H5OH
4) CH3 2 CHOH  C2 H5OH  CH3 2 COH
35. Identify compound A in the following reaction:
1) CH 3CHDCH 2OH 2) CH3CH OH  CH 2 D 3) CH3CHDCH 2OD 4) CH 3CHDCH 2 D

36. Which has the lowest C  H bond dissociation energy?
1) 2) 3) 4)
37. The end product of the given scheme is
1) an optically active compound 2) an optically inactive compound
3) a racemic mixture 4) a diastereomeric mixture
38. Which of the following are not resonating structures of each other?
1) 2)
3) 4)
39. The benzene rings with the most and the least   electron density respectively:

1) 3, 1 2) 3, 2 3) 1, 2 4) 1, 4
40.
1) 2)
3) 4)
41.
Compound X in the above reaction is

1) 2)
3) 4)
42.
1) 2) 3) 4)
43. Relative reactivity of carbonyl compounds towards nucleophile?
1) Acyl halide > Acid anhydride > Aldehyde > Carboxylic acid
2) Carboxylic acid > Aldehyde > Acid anhydride > Acyl halide
3) Acyl halide > Aldehyde > Acid anhydride > Carboxylic acid
4) Acid anhydride > Acyl halide > Carboxylic acid > Aldehyde
44. The major product ‘D’ will be

1) 2)
3) 4)
45. Incorrect statement for the below sequence is
P1  NaOI  P3  yellow ppt   P4
1) P3 on reaction with Ag gives acetylene

2) P4 on reaction with sodalime gives toluene
3) P4 on reaction with sodalime gives benzene
4) P1 on reaction with 2,4-DNP gives colured compound

SECTION-II
46. Action of Grignard reagent on carbonyl compound followed by hydrolysis gives
alcohols. In the preparation of all isomeric (structural) butyl alcohols, the number of
different carbonyl compounds involved is ‘X’ and Grignard reagents is ‘Y’ . Then the
value of X+Y is?
47.
The degree of unsaturation of compound (C) is ……
Compound (A) or (B)   Compound (C )

i ) H 2 Ni
ii ) Conc H 2 SO4 / 
48. Number of oxygen atoms present in organic compound vanillin are
49. Degree of unsaturation of compound phorone is
50. Difference in the molecular weight of first member of aldehyde series and ketone series
is(assume only carbon, hydrogen and oxygen containing compounds, other derivatives
are not considered)

MATHEMATICS MAX.MARKS: 100
SECTION – I
dy
51. The general solution of the differential equation x 4  x3 y  cos ec  xy   0 is (where C is
dx
constant of integration)
1) 2cos  xy   x2  C 2) 2cos  xy   y 2  C
1 1
3) 2 cos  xy   C 4) 2sin  xy   C
x2 x2
52. The curve passing through 1, 2  , whose differential equation is y  x  y 3  dx  x  y 3  x  dy
then the curve also passes through the point.
1)  1, 2  2)  2,1 3) 1, 2 4)  1, 2 
53. Let y  f  x  .g  x  .h  x  be the solution of the differential equation
xdy  ydx  xe x  xln x  1 dx and y 1  0 . f  x  and h  x  are images of each other in the
mirror y  g  x  then the least distance between f  x  and h  x  is
1) 2 2) 2 2 3) 3 2 4) 2
54. The solution of the differential equation  y  x xy  x  y   dx   y xy  x  y   x  dy  0 is

(Where C is constant of integration)
x2  y 2  y x2  y 2  x
1)  2 tan 1    C 2)  2 tan 1    C
2  x  2  y 
x2  y2  y x2  y2  x
3)  tan 1    C 4)  tan 1    C
2  x  2  y 
55. The x-intercept of the tangent to a curve is equal to the ordinate of the point of contact.
The equation of the curve through the point 1,1 is
x x y y
1) ye  e
y
2) xe  e
y
3) xe x  e 4) ye x  e

56. The real value of m for which the substitution, y  u m will transform the differential
dy
equation, 2 x 4 y  y 4  4 x 6 into a homogeneous equation is
dx
1) m  0 2) m  1 3) m  3 / 2 4) No value of m
The solution of the differential equation 3xy '  3 y   x 2  y 2   0 , satisfying the condition
12
57.
y 1  1 is
1) 3cos 1    ln x 2) 3cos    ln x
y y
x x
3) 3cos 1    2 ln x 4) 3sin 1    ln x
y y
x x
58. The solution of the differential equation xy'  2 x e y x  y is
1) e y x  ln cx  0 2) e y x  x  c 3) e y x  ln cx 4) e y x  2ln cx
59. Area bounded by the curve y  sin  x  sin x (where [ ] is greatest integer function),

lines x  1 and x  and the x-axis is
2
  
1) sin1 2) sin1 3) sin1   1 4) sin1   1
2 2  2 
16  x 2
60. Area of the region bounded by the curve y  and y  sec1   sin 2 x  (where [ ]
4
denotes the greatest integer function) is ( in sq units)
3 3 3 3
8 7
1)  4    2 2) 2  4    2 3) 3  4    2 4)  4   2
3 3
 
2
61. The value of the definite integral 1  x3  3 x 2  2 x dx is
0
1)6 2) 0 3) 4 4) 8
 2
sin 2 nx
62. If an  0
sin x
dx , then a2  a1 , a3  a2 , a4  a3 are in
1) A.P 2) G.P 3) H.P 4) A.G.P

1  7 cos x
2
f  x
63.  sin dx   C , then f  x  is equal to (Where C is constant of integration)
 sin x 
7 2 7
x cos x
1) sin x 2) cos x 3) tan x 4) cot x
x2 1
64. x 3
2x4  2x2  1
dx is equal to (Where C is constant of integration)
2 x 4  2 x5  1 2 x4  2 x2  1
1) C 2) C
x2 x3
2 x4  2 x2  1 2 x4  2 x2  1
3) C 4) C
x 2 x2
 sin  x 
  if x  0
 x
65. Let f : R  R be defined by f  x    2 if x  0
 sin x  x 
   if x  0
 
 x
3 
Where [y] denotes the integral part of y . If f is continuous at x  0 , then    
1) -1 2) 1 3) 0 4) 2
66. If  x  denotes the greatest integer function, then the domain of the
x   x
function f  x   is

log x 2  x 
1  5 1  5  1  5 5  1 
1) 1,  2) 1,    Z 3) R   ,  4)  , 
 2 2   2 2 
67.

Let f  x   

2
 max x , x , x 2 
8  2 x ,
 2 x 4
Let S be the set of points in the interval  4, 4  at which f is not differentiable, Then S
1) equals 2, 1,12 2) equals 2, 1,0,1, 2
3) equals 2, 2 4) is an empty set

x  2sin x
68. lim is
x 0
x  2sin x  1  sin 2 x  x  1
2
1) 6 2) 2 3) 3 4) 1
1
69.  
If lim 1  x log 1  b2  x  2b sin 2  , b  0 and     ,   , Then the value of  is
x 0
   
1)  2)  3)  4) 
4 3 6 2
tan   cot    3  5
If y    2 
1 dy
70.  2 ,    ,   then at   is:
 1  tan   sin   4 
2
dx 6
1 4
1) 4 2)  3) 4) -4
4 3
SECTION-II
dy
71. The value of Lt y  x  obtained from the differential equation  y  y 2 where y  0   2
x  dx
is.
 2 x  3 dx 1
where f  x  is of the form of ax 2  bx  c , then
72. If  x  x  1 x  2  x  3  1  C  f  x 
a  b  c equals to
73. Let f and g be differentiable function on R such that fog is the identity function. If for
some a, b, R, g '  a   5 and g  a   b , then f '  b  is equal to
74. The area of the region in the first quadrant in which the points are nearer to the origin
than the line x  3 is
75. If y  y  x  satisfies the differential equation  3 y 2  x 2  x dy  y  3x 2  y 2  dx and

y 1  1, y  0 then y  2  is equal to

Sec: SR.IIT_CO-SC CTM-7 Date: 28-09-20
Time: 3HRS Max. Marks: 300
KEY SHEET
PHYSICS
1 4 2 2 3 1 4 4 5 2
6 3 7 2 8 3 9 2 10 3
11 2 12 3 13 2 14 3 15 2
16 4 17 3 18 2 19 3 20 2
21 8.00 22 4.00 23 12.50 24 0.19 25 30.00
CHEMISTRY
26 4 27 2 28 1 29 3 30 4
31 3 32 3 33 3 34 1 35 2
36 4 37 1 38 1 39 1 40 1
41 2 42 2 43 1 44 4 45 2
46 8.00 47 2.00 48 3.00 49 3.00 50 28.00
MATHEMATICS
51 3 52 4 53 1 54 2 55 1
56 3 57 1 58 4 59 3 60 1
61 1 62 3 63 3 64 4 65 2
66 3 67 2 68 2 69 4 70 1
71 1.00 72 5.00 73 0.20 74 3.00 75 2.00
Narayana IIT Academy 28-09-20_Sr.IIT_CO-SC_JEE-MAIN_CTM-7_KEY&SOL
SOLUTIONS
PHYSICS
1) & 2) Due to electric force particle starts moving along +ve x-axis and as soon as particle comes into
motion magnetic force starts acting on it perpendicular to it’s velocity and magnetic field at any
instant hence the particle moves in x-z plane
^ ^ ^ ^
Let V  Vx i  Vz k be it’s velocity and a  ax i  az k be it’s acceleration at any instant.

 E0iˆ  q  q V  B 
a  
m
Eq
m m
q

 a  0 iˆ  Vxiˆ  Vz kˆ  B0 ˆj  
 E q  ^ qB ^ qB ^
 a   0  i  0 Vx k  0 Vz i
 m  m m
^ ^ q ^ qB ^
 ax i  az k   E0  B0Vz  i  0 Vx k
m m
dVx q dVz qB0
   E0  B0Vz  ..... 1 and  Vx .....  2 
dt m dt m
Differentiating equation (1)
2
d 2Vx q dVz qB0 qB0 d 2Vx B q
i    B0    Vx     0  Vx  Vx isvarying simple harmonically
 m 
2 2
dt m dt m m dt
Bq
with angular frequency   0
m
 Vx  A sin t   
At t  0, Vx  0    0  Vx  A sin t
dVx dVx qE0
 A cos t , At t  0, Vz  0  from 1 
dt dt m
qE0 Bq E
 A cos 0  A  0  A  0  amplitude
m m B0
E0
 Vx  sin t   3
B0
z V t
dVz qB0 E0 Eq
From (2) and (3)   sin t   dVz   0 sin t dt
dt m B0 0 0
m
E0 q E0 q E0
   cos t 0   1  cos t  1  cos t 
t
Vz   Vz 
m  B0 q  B0
m 
 m 
E0   B0 q  
 Vz  1  cos  m t     4
B0   
The equations of Vx and Vz represent that the path is a cycloid
3. Magnetic field does not do work on the particle.
Work done by electric field = change in kinetic energy of the particle
SR.IIT_CO-SC Page 2

1 2 2E0 qx
mv  E0 qx  v  ( Displacement in the direction of electric field is x )
2 m
4. As there is no change in velocity (either in direction or in magnitude) net force on the particle should
be zero
A) If E  0, B  0 in that region F  0
B) Even though both fields are there, they might be perpendicular to each other and perpendicular to
velocity so that net force on it is zero
C) Magnetic field might be there parallel to velocity, then F  0
D) If only electric field is there net force on the particle can’t be zero
qvB
5. Acceleration of the particle at any instant is and let v makes angle  with x-axis at that
m
instant, vx , v y be the x-and y-components of velocity of the particle repectively and a x , a y be the x-
and y-components of acceleration of the particle
qVB dv qvcos B
ay  cos   y 
m dt m
dx dv qBVx dV qB qB q 0i
  y   Vx y  Vx  dVy  dx  dVy  dx
dx dt m dx m m m 2  d  x 
Initially V y =0 and when separation is minimum V y becomes v. Let x0 be the minimum separation.
d  x0
 iq  n  d  x  
d  x0
q 0i dx 0iq  x0 
V
 dV
0
y  
0
m 2  d  x 
V  0 
2 m  1

0
 V 
2 m  d 
n
 2 mV   2 mV 
   
x0  0iq   0iq 
e  x0  d e
d
qE mu 2 mu 2 m qE 2
6. ay  , quB  r  Also T  , y  vt  t
m r qB qB 2m
qE 2 2mv
At origin, x=0, and y=0  0  vt  t  t
2m qE
For returning at the origin,
2mv 2n m 2mv 2mvqB vB

nT     n 
qE qB qE qE  2 m   E
SR.IIT_CO-SC Page 3

  ^
  ^
  ^
^
7. M  Ia 2   k   Ia 2   j   Ia 2 cos 450   i   Ia 2 sin 450  j 
       
Ia 2  ^   Ia 2 2
^
2
^

 
  
i   Ia  j  Ia 
  k
2   2   


a2  ^  a 1  2 ^ 2  ^ 
2

i   j a   k 
2  2  
8.
2mv1 2mv2
d1  2r1  and d 2  2r2 
Bq Bq
Angular momentum of B relative to A is

L  rBA  PBA  L  rBA  mV2iˆ  mV1 (iˆ)   L  rBA  m  v2  v1  iˆ
L  rBA sin   m  v2  v1   d  m  v2  v1    d1  d2  m  v1  v2 
 2mv1 2mv2  m2 2 2
L   m  v1  v2   2 
v1  v2  
 L  v12  v22 
 Bq Bq  Bq
Ni
9. B  0 ni  0  0 
L
10. Let G be the resistance of the galvanometer.
1
If deflection falls to th , range becomes n times
n
G
i.e., s   G  s  n  1  5  10  1  45
n 1
5  2 10
If an additional shunt of 2 is connected, effective shunt s '   and let range becomes n '
52 7
times then
SR.IIT_CO-SC Page 4

G G 45 63 65
s'  '  n'  1  '    n' 
n 1 s 10 2 2
7
1 2
 Deflection falls to '
i.e., falls to th
n 65
11. CG, OEH & AF are equipotential surfaces with potentials 1V, 0 V & -1 V respectively. The uniform
electric field must be perpendicular to these equipotential surfaces pointing from higher to lower
potential as shown.
^ ^ 
dV   0  1 i  j  1 ^ ^ 
E   2 Vm1 ; E  2  Vm  E   i  j  Vm 1
dr 1cos 45  2   
 
12. For adiabatic process TV  1 = constant. Differentiating with respect to T
dV dV V dV
T    1V   2  V  1.1  0   m
dT dT T    1 dT T0 ,V0
V0 V0
 m   1 
T0   1 T0 m
R RT m  T m
CV   0 and CP  CV  R  1  0  R
 1 V0  V0 
13. As the temperature in the process is constant PV  k
dV dP
Differentiating w.r.t time, P V 0
dt dt
dV
Upon substituting  r and V  V0 (which is constant)
dt
dP dP  r
Pr  V0   dt
dt P V0
rt  rt
P t
dP r
Integrating above equation     dt  nP P   nP  nP0 
P
P0
P V0 0 0
V0 V0
 rt 
 P  rt  
 n    P  P0 e  0 
V
 P0  V0
SR.IIT_CO-SC Page 5

14. Loss in internal energy of the system is equal to work done by the gas against atmosphere
nR T1  T2   Patm V f  Vi    2 PatmV0  PatmV f   Patm V f  V0   8V0  5V f  V f  1.6V0
f 3
2 2
Wgas  Patm V f  V0   0.6 Patm V0
f
U   2 PatmV0  Patm1.6V0   0.6 Patm V0
2
Q
15. Let Q be the total charge in the cube and a be the side length, then V0  . Let V be the electric
a
potential at one of its corners. Consider a combination of 8 such identical cubes with same volume
charge density kept in contact so that a corner of these cubes is Centre of new cube of side length 2a .
Electric potential at the Centre of the new cube is 8V which is equal to 4V0 ( potential at center of
8Q
the new cube  )
2a
V
V  0
2
16. VE  VD  0 (as they are earthed )
VB  2V ,VC  10  2  12V ,VA  12  6  6V
V  VB
Current through 2  A  2A
2
V  VD
Current through 3  C  4A
3
From Kirchhoff’s junction rule we can show that current through wire DE=0
17. At triple point substance exits is three states in equilibrium
Keeping pressure constant if temperature is increased substance will be in vapor state and if
temperature is decreased substance will be solid state. Keeping temperature constant if pressure
increased substance will be in liquid state and pressure decreased substance will be vaporstate.
40
18. Time period of the pendulum is equal to time for one oscillation   2 S . Error in the
20
measurement of time for 20 oscillations=1 second. Therefore error T for one oscillation is
1
 0.05 second. Error in the measurement of length of the pendulum-least count of the scale =1
20
mm.
l
g  4 2
T2
SR.IIT_CO-SC Page 6

g l T 0.001 0.05
100  100  2 100  100  2  100  5.1%
g l T 1 2
19. Any gap in a material behaves as if there is material and expands on heating, hence all distances
a, b, c increase
20. A be the area of cross section of the vessel and h be the height of liquid column.
Increase in volume of liquid V  V t  Aht
For h to remain constant V  Ah  Aht  At  h      2
21.
dl sin   rd 
Magnetic induction field strength due to element dl at focus is
0 i  dl  sin  0 ir d  id
dB    dB   2  dB  0 
4 r2 4 r 4 r
0i d 0i 2  1  0.8cos  

  dB    B     d   B  8  107 T
4 r 4 0
 l 
SR.IIT_CO-SC Page 7

22.
x  10 x  2 x  0 2 x 20
   0 ….. (1) And   0 …. (2)
R R r R r
2 x2 R x
   1
r R r 2
From (1) 2 x  12   0   2 x  12   x   1  0  4 x  24  x 2  2 x  0
xR x
r 2 
 x  2 x  24  0  x  6, 4  x  4
2
23. 10VSD=9MSD=9mm.
Least count =1MSD-1VSD=0.1mm.
Zero error= 0.1 10  8  0.2 mm.
Thickness= Main scale reading +L.C  V.C+error.
i.e, Thickness= 12  0.1 3  0.2  12.5mm
24. Let h be the maximum height attained and v be the velocity at maximum height. From conservation
of angular momentum
Ve
m cos 45  R  mvr (where r  R  h )
2
Ve 1 V R 1 2GM R GMR
 R  vr  v  e   v
2 2 2 2 r 2 2 R r 4r 2
From conservation of energy
GMm 1 Ve
2
 mv  GM  1  1  2 GM   GM  1  GMR
GMm 1 2
 m 
R 2 4 r 2 R 2 4 R r 2 4r 2
3 8r  R
  2
 6r 2  8rR  R 2  6r 2  8rR  R 2  0
4R 8r
8R  64 R 2  4  6  R 2 8R  2 10 R 4 R  10 R
r r  Rh  h  0.19R
12 12 6
25. Let m be the mass of steam passed
m  540  m  100  90 1  150  125 1 90  30
 m 550  275  60  m  30 g
SR.IIT_CO-SC Page 8

CHEMISTRY
26. 1,6-dimethyl cyclohexene
27. Alkene bond length influenced by Hyperconjugation.
28. The compound contains deactivated rings due to carbonyl group. Because of ketonic group, the
given compound will not respond towards Tollens reagent.
29. In Beckmann rearrangement N- substituted amides formed
30. In compound X, two deuterium atoms, and in compound Y, one deuterium atoms are present.
31.
32. 1,6-dicorboxidacid on heating cyclic ketone formed

33. Conceptual
34. Conceptual
35. Conceptual
36. Residual species option 4 is more strurcturablel
37. Conceptual
38. Conceptual
39. Conceptual
40. first step is cannizaro reaction and second step is esterification
41. Conceptual
42. Conceptual
43. Acyl halide > Acid anhydride > Aldehyde > Carboxylic acid
44. Conceptual
SR.IIT_CO-SC Page 9

45. P2 is the phenolic compound and P3 is chloroform
46.
47. Conceptual
48.
49. phorone is 2,6-dimethyl, 2,5 heptadihen- 4-one

50. Conceptual
MATHS
51. x dy  x ydx  cos ec  xy  dx  0
4 3
x3  xdy  ydx   cos ec  xy  dx  0

xdy  ydx dx
 0
cos ec  xy  x3
1
 cos  xy   C
2 x2
1
2 cos  xy   2  C
x
52. xydx  y dx  xy 3dy  x 2 dy
4
x  ydx  xdy  y 3  xdy  ydx 


x2 x2
SR.IIT_CO-SC Page 10

ydx  xdy y  y 
 d 
x2 y 2 x x
d  xy  y  y
  xy 2   x d  x 
2
 y
1  x 
  c
xy 2
1 4 5
1, 2     c  c  
2 2 2
2
1 y 5
  2 
xy 2 x 2
1 y 2  5x2
 
xy 2x2
2 x  y 3  5x 2 y  y 3  5x 2 y  2 x  0
xdy  ydx  1
53.  x 2
  e x  ln x  
 x
y
 e x ln x  c
x
y 1  0 c  0
y  e x x ln x
f  x   e x , h  x   ln x, g  x   x
Least distance  2
54. ydx  xdy  xy  x  y  xdx  ydy   0
ydx  xdy  x x
2
 1    xdx  ydy   0
y  y y
x
d 
 y 0
 x dx   y dy   x x
1  y  y
 
x
Put  t2
y
x2 y 2 2tdt
  c
2 2 t 1 t2  
x2  y 2 x
 2 tan 1 c
2 y

55. Y  y  m  X  x  . For X- intercept Y=0
y
X  x
m
y
Therefore., x  y
m
dy y
or 
dx x  y
dv v
Put y  vx v  x 
dx 1  v
dv v v  v  v2
x  v 
dx 1  v 1 v
1 v dx
 v 2 dv   x
1
  ln v  ln x  C
v
x y x
  ln  ln x  C    ln y  C
y x y
x  1, y  1  C  1
x
1   ln y  y  e.e x y
y
e
e x y   ye x y  e
y
dy du
56. y  um   mu m1
dx dx
du
Since, 2 x 4 .u m .mu m 1.  u 4 m  4 x 6
dx
du 4x  u
6 4m

dx 2mx 4 u 2 m1
3
4m  6  m 
2
3
and 2m  1  2  m 
2

dy 3 y  x 2  y 2
  dy
12
57. 3xy '  3 y  x 2  y 2  0  3x  3 y  x2  y 2   …….(1)
dx dx 3x
dy dv
Put y  vx . Then vx
dx dx
dv 3vx  x 2  v 2 x 2 3v  1  v 2 dv 3v  1  v 2 1  v2
(1)  v  x   x  v  
dx 3x 3 dx 3 3
3 dx y
 dv   3cos1 v  log x  c  3cos1  log x  c
1 v 2 x x
y
Now y 1  1  c  0 . The required solution is 3cos 1  log x
x
dy y
58.  2e y x 
dx x
Put y  vx
dv
vx  2 v  v
dx
dx
 e dv  2 x
v
ev  2log x  c
e y x  2log cx

59. 1 x 
2
 x  1, sin x  0

2
y  sin1  A   sin1 dx
1
60. y  sec   sin x   

1 2
4 y  16  x 2  x 2  16  4 y
 4  y  4
x 2  16  4
x  2 4  
2 4 
 16  x 2  8 3
  4    dx   4    2
2 4    3

61. Let f  x   1  x3 , then f  0  1, f  2  3
and f 1  x    x 2  1
13
2 f  2
 f  x  dx   f 1  x  dx  2 f  2   0 f  0 
0 f  0
2 3
 1  x dx   x 2  1  
13
3
dx  6
0 1
Put x 1  t
dx  dt
 
2 2 13
 1  x3 dx    t  1  1 dt  6
2
0 0
2 2
 1  x3 dx   x 2  2 x 
13
dx  6
0 0
 2
sin 2 nx  sin 2  n  1 x
62. an  an1   0
sin x
dx
 2
sin  2n  1 x sin x
 0
sin x
dx
 2
 2
 cos  2n  1 x 
  sin  2n  1 x dx    
0  2n  1  0
1

2n  1
1 1 1
a2  a1  , a3  a2  , a4  a3 
3 5 7
1  7 cos x
2
 sec x
2
7 
63.  sin7 x cos2 xdx    sin7 x  sin 7 x  dx
sec2 x 7
  7 dx   7 dx  I1  I 2
sin x sin x
sec2 x tan x tan x.cos x
Now I1   7
dx  7
 7 dx
sin x sin x sin8 x
tan x
  I2
sin 7 x
tan x
 I1  I 2  C  f  x   tan x
sin 7 x
 1 1 
 3  5  dx
x x 
64.  2 1
2 2  4
x x

2 1 1 dz
Let 2  2  4  z  
x x 4 z
1 1 2 1
 z C  2 2  4 C
2 2 x x
2 x4  2 x2  1
or C
2 x2
65. f is continuous at
 sin  x    sin x  x  
x  0  Lt f  x   Lt f  x   f  0   Lt      Lt        2

3
x0 x0 x0
 x  x0
 x 
     1  2    2,   3      1
66. We have,
x   x
f  x 

log x 2  x 
It is defined
log  x 2  x   0  x   x   0,  x R 
 x2  x  1  x2  x 1  0
1 5
x2  x 1  0  x 
2
 1 5   1 5 
 x   ,  ,  
 2   2 
1  5 1  5 
 Domain of f  x   R   , 
 2 2 
67.
not differentiable at x  2,  1, 0
x  2sin x 0 
68. Let P  lim  form 
x 0
x 2  2sin x  1  sin 2 x  x  1  0 
on rationalization, we get
 x  2sin x 
P  lim 2  x2  2sin x  1  sin 2 x  x  1
x 0 x  2sin x  1  sin 2 x  x  1
x  2sin x
 2  lim 2
x 0 x  sin 2 x  2sin x  x

Now applying the ‘L’ Hospital rule, we get
1  2 cos x
P  2  lim
x 0 2 x  sin 2 x  2 cos x  1
  1x
 
1

lim x log 1b2
69. Here, lim 1  x log 1  b 2 x
 e x0
x0
   1 b
e
log 1b2
  2
……………………………….(i)
 
1
Given, lim 1  x log 1  b2

x 0
 x
 2b sin 2 
 
 1  b 2  2b sin 2 
1  b2
 sin 2  
2b
1
b 1
By AM  GM , b   b. 1  2
 
2  b
b2  1
 1
2b
From Eqs (ii) and (iii)
sin 2   1

    , as     ,  
2
70. y    2
 tan   cot   
1  3 
,    , 
1  tan  sin 
2 2
 4 
sin   cos    sin   cos  
 
sin  sin 
 1  cot 
 5 
y '    cos ec 2 y'  4
 6 
dy dy
71.  dx   dx
y 1  y  y  y  1
 y   y  1 
  y  y  1  dy   dx
 
log  y  1  log y   x  c
y  1  x c
e
y
1 y  1 e x
y  0  2   ec  
2 y 2

2e x
 y  1  y  y  2e x

 1  2e x
2
y
2  e x
2x  3
72.  x 2

 3x x 2  3x  2  1
dx

Put x2  3x  t   2 x  3 dx  dt
dt dt 1 1
 t  t  2   1    t  1 2
C
t 1
C 2
x  3x  1
 a  1, b  3, c  1  a  b  c  5
73. f  g  x   x
f '  g  x  g '  x   1
Put x  a
1
f ' b  g '  a   1 f ' b  
5
74. x2  y 2  3  x
3
2
0
9  6 x dx  3 sq units
dy dv
75 Put y  vx . Then vx ,
dx dx
dy 3x y  y3
2
dv 3x3v  v3 x3
Then equation is  2  v  x 
dx 3 y x  x3 dx 3x3v 2  x3
3v  v3  3v3  v 4v  4v 3 4  v  v 
3
dv 3v  v3 3v 2  1 dx
x  2 v     3  4
dx 3v  1 3v  1
2
3v  1
2
3v  1
2
v v x
3v  1
2
dv  4  log  v3  v   4log x  log c  x 4  v3  v   c  x  y 3  x 3  c
dx
 3
v v x

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Sec: Sr.

IIT_CO-SUPER CHAINA Date: 28-09-20

Name of the Student: ___________________ H.T. NO:

PHYSICS: PT-7 SYLLABUS (40%) + PT-1 T0 PT-6 SYLLABUS (60%)

CHEMISTRY: PT-7 SYLLABUS (40%) + PT-1 T0 PT-6 SYLLABUS (60%)

MATHEMATICS: PT-7 SYLLABUS (40%) + PT-1 T0 PT-6 SYLLABUS (60%)

1) a circle 2) a parabola 3) a helix 4) cycloid

SR.IIT_CO-SC Page. No. 2

Education consists mainly of what we have unlearned.

 y direction, of magnitudes E and B respectively. The particle will definitely return to

the origin once if (neglect gravity)

1) vE / 2 B is an integer 2)  u 2  v 2   B /  E  is an integer

3) vB /  E  is an integer 4) uB /  E  is an integer

SR.IIT_CO-SC Page. No. 3

Education consists mainly of what we have unlearned.

momentum of particle B w.r.t. particle A is proportional to (assume both the particles

1) v1  v2 2) v1  v2 3) v12  v22 4) v12  v22

10. The deflection of a galvanometer falls to 1 / 10th when a resistance of 5 is connected in

SR.IIT_CO-SC Page. No. 4

Education consists mainly of what we have unlearned.

SR.IIT_CO-SC Page. No. 5

Education consists mainly of what we have unlearned.

1) Final volume of the gas in two cylinders is 1.6V0

2) Work done by total gas system is 0.6 Patm V0

3) Final temperature of the system is 0.6T0

4) Decrease in internal energy of the system is 0.6 Patm V0

16. In the circuit shown in the figure, the incorrect option is

(1) Current passing through 2 resister is 2A

(2) Current passing through 3 resister is 4A

(3)Current in wire DE=0

(4) Potential of point A is 10 V.

SR.IIT_CO-SC Page. No. 6

Education consists mainly of what we have unlearned.

1) Error T in measuring T the time period is 0.05 second

2) Error T in measuring T the time period is 1 second

3) Error in the measurement of 1 the length of the pendulum is 1 mm

4) Percentage error in the determination of g is 5.1%

SR.IIT_CO-SC Page. No. 7

Education consists mainly of what we have unlearned.

1) a remains constant b and c increase

2) a remains constant b decreases and c increase

3) All distances a, b, c increase

4) a remains constant, b increases, c decreases

SR.IIT_CO-SC Page. No. 8

Education consists mainly of what we have unlearned.

plate (in mm)is

the mass of steam passed into the calorimeter in gram is

SR.IIT_CO-SC Page. No. 9

Education consists mainly of what we have unlearned.

1)Sum of locant number of methyl groups of following structure is 7.

2)Number of pi bonds in picric acid is 6.

3)Number of C-C bonds in hexamethylene tetra amine (Urotopine) is zero.

4)Given all statements are correct.

1) 1.54Angstroms, due to no resonance

2) Less than 1.54A, due to hyperconjugation.

3) More than 1.54A, due to resonance.

4) Less than 1.54A, due to resonance.

28. Choose the correct statement related to the following structure(X)

SR.IIT_CO-SC Page. No. 10

Education consists mainly of what we have unlearned.

1) X has more enol content(percentage) than PhCOCH2COCH3.

3) Rate of reactivity of phenyl rings of compound X is more towards electrophilic

4) Compound X shows positive response towards NaOCl and Tollens reagents.

1) Compound A obtained as geometrical isomers of two.