Material Safety Data Sheet

Date of Issue: November 30, 2009

I. Chemical Product and Company Identification

Product Name: LOCK N’POP®

Product Codes: X3258
EU Registration Number (if necessary):
General Use: A liquid cohesive applied to the exterior of packages during stacking operations
for creating bonds to maintain stability for movement and shipping.

Manufacturer: LocknPop
1010 SE Everett Mall Way, Suite 101
Everett, WA 98208
Telephone: 1-425-347-3600
(office hours 9 AM to 3 PM, United States EDT)
Fax: 1-425-290-6464
Contact Individual: Rosanna Cavanaugh
Email Address: rosanna.cavanaugh@locknpop.com

2. Hazards Identification

Acute Health Effects

Swallowed
Considered an unlikely route of entry in commercial/industrial environments. The material is
regarded as moderately discomforting if swallowed. Ingestion may result in nausea, abdominal
irritation, pain and diarrhea.

Eye
The liquid may produce eye discomfort causing smarting, pain, and redness.

Skin
This material may be mildly discomforting to the skin if exposure is prolonged. Irritation and skin
reactions are possible with sensitive skin and may even cause n some cases, sensitization, if
exposure is prolonged. Open cuts, abraded or irritated skin should not be exposed to this
material. The material may accentuate any pre-existing dermatitis condition.

Inhaled
Not normally a hazard due to the non-volatile nature of product. Inhalation hazard is increased at
higher temperatures. the vapor is mildly discomforting to the upper respiratory tract if inhaled.

Chronic Health Effects

Principal routes of exposure are usually by skin contact with the material. Prolonged or repeated
skin contact may cause drying with cracking. Irritation and possible dermatitis. As with any
chemical product, contact with unprotected bare skin; inhalation of vapor, mist, or dust in work
place atmosphere; or ingestion in any form should be avoided by observing good occupational
work practice.
MATERIAL SAFETY DATA SHEET page 2
Product: LOCK N’POP® X3258
Date of Issue: November 30, 2009

3. Composition/Information on Ingredients

Component CAS Number EINECS # % by Weight Classification

Water 7732-18-5 231-791-2 >95% Not Listed

Non-Hazardous Synthetic and Natural

Materials Proprietary Proprietary <5% Not Listed

30% ammonium hydroxide (unreacted)

1336-21-6 215-647-6 <.08% N, R51/53

Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one,
and 2-methyl-2H-isothiazol-3-one
(3:1 ratio) 55965-84-9 Unlisted <0.01% Xi, R43, R52/53

4. Emergency First Aid Measures

Inhalation
If fumes or combustion products are inhaled: Remove to fresh air. Lay patient down .
Keep warm and rested. If breathing is shallow or has stopped, ensure clear airway and
apply resuscitation. Transport to hospital, or doctor.

Ingestion
Rinse mouth out with water. Do not induce vomiting. Give a glass or two of water.
Get immediate medical attention.

Eye Contact
If this product comes in contact with the eyes immediately hold the eyes open and wash
with fresh running water. Ensure irrigation under the eyelids by occasionally lifting upper
and lower lids. If pain persists or recurs seek medical attention. Removal of contact
lenses after an eye injury should only be undertaken by skilled personnel.

Skin Contact
If product comes in contact with the skin remove all contaminated clothing, including
footwear (after rinsing with water). Wash affected areas thoroughly with water. Seek
medical attention in event of irritation.

5. Fire Fighting Measures and Explosion Hazard Data

General Information
This material is not combustible under normal conditions. However, it will breakdown
under fire conditions and the organic component may burn. Not considered to be a
significant fire risk.

Hazardous Decomposition Products

Decomposes on heating and may produce toxic fumes of carbon monoxide (CO). May
emit acrid smoke. Decomposes on heating and produces toxic fumes of carbon dioxide
(CO2).
MATERIAL SAFETY DATA SHEET page 3
Product: LOCK N’POP® X3258
Date of Issue: November 30, 2009

6. Accidental Release Measures

Spills
Slippery when spilled. Clean up all spills immediately. Avoid contact with skin and eyes.
Control personal contact by using protective equipment. Contain and absorb spill with
sand, earth, inert material or vermiculite. Prevent from entering drains or waterways.
Wipe up. Place in a suitable labeled container for waste disposal.

7. Handling and Storage

Suitable Container
Plastic container or packaging as recommended by manufacturer. Check that containers
are clearly labeled.

Storage and Incompatibility

Avoid storage with oxidizers. Avoid contamination of water, foodstuffs, feed or seed.

Storage Requirement
Store in original container. Keep container securely sealed. Store in cool, dry, ventilated
area. Do not allow to freeze. Store away from incompatible materials. Protect
containers against physical damage and check regularly for leaks. Observe
manufacturer’s storing and handling recommendations.

8. Exposure Controls and Personal Protection

Exposure Standards
None assigned. No exposure limits set. Dusts not otherwise classified as inspirable dust:
ES TWA 10 mg/m3.

Engineering Controls
Use in well ventilated areas. General exhaust is adequate under normal operating
conditions.

Personal Protection

Eye
Safety glasses with side shields or as required, chemical goggles. Contact lenses pose a
special hazard, soft lenses may absorb irritants and all lenses concentrate them.

Hands/Feet
Barrier cream with polyethylene gloves or rubber gloves. Safety footwear.

Other
Overalls, eyewash unit.

Respirator
Respiratory protection equipment suitable to work conditions and environment.
MATERIAL SAFETY DATA SHEET page 4
Product: LOCK N’POP® X3258
Date of Issue: November 30, 2009

9. Physical and Chemical Properties

Appearance: Opaque light amber colored liquid

Odor: Slightly sweet, very slight ammonia odor

pH: 8.0 – 9.0

Boiling Point (deg C): 100o+

Flash Point (deg C): Not Flammable

Flammability: Not Available

Melting Point (deg C): Not Available

Lower Explosive Limit (%): Not applicable

Upper Explosive Limit (%): Not applicable

Oxidizing Properties: Not available

Vapor Pressure (kPa): Not available

Specific Gravity: 1.01

Water solubility: Miscible

Partition Coefficient
(n-octanol/water) Not available

Viscosity, average: 1000 centipoise

Vapor Density: Not available

Evaporation Rate: Not available

% VOC: 0.009%

10. Stability and Reactivity

Stability: Stable

Hazardous Polymerization: Will not occur

Conditions to avoid: Excessive heat

Incompatibility: Strong oxidizers

Hazardous Thermal Decomposition Products: Decomposition on heating

11. Toxicological Information

Acute Toxicity
The product represented by this MSDS has not been tested for Toxicological effects.
There are no hazardous ingredients contained in the material and so no cause for
concern is indicated.
MATERIAL SAFETY DATA SHEET page 5
Product: LOCK N’POP® X3258
Date of Issue: November 30, 2009

Sub chronic Effects/Carcinogenicity

The product represented by this MSDS has not been tested for chronic toxicological
effects. There are no hazardous ingredients. None of the ingredients contained are
known to have sub-chronic toxicological effects.

Chronic Effects/Carcinogenicity
The product represented by this MSDS has not been tested for chronic toxicological
effects. There are no hazardous components. The ingredients contained in the product
are not known to cause any harmful effects.

Mutagenicity
The product represented by this MSDS has not been tested for mutagenic toxicological
effects. There are no hazardous components. Ingredients contained in this product
have not been shown to have mutagenic effects.

Reproductive Effects
The product represented by this MSDS has not been tested for reproductive toxicological
effects. There are not hazardous components. The ingredients contained I this product
have not been shown to have reproductive effects

12. Ecological Information

Ecotoxicological Information
This product poses no ecological hazard. When used as prescribed it becomes a part of
the surface to which it is applied and can be recycled with the article in the normal
fashion requiring no additional consideration or preparation.

Persistence and Degradability

No data available.

Bioaccumulative Potential
No data available

PBT (persistence, bioaccumulative and toxicity) Assessment

No data available

13. Disposal Considerations

Dispose of in accordance with local regulations. Empty containers can be recycled or
placed in landfill.

14. Transport Information

Ground Transport (DOT)

Liquid Adhesives NOI NMFC 4620 sub 5 Class 60

Air Transportation (LATA)

Liquid Adhesive NOI NMFC 4620 sub 5 Class 60

Ocean Transport (IMOC)

Other Prepared Glues and Adhesives H.S. 3506. 99.0000.5
MATERIAL SAFETY DATA SHEET page 6
Product: LOCK N’POP® X3258
Date of Issue: November 30, 2009

15. Regulatory Information

Chemical Safety Assessment Completed: Unknown

HMIS Ratings: Health 1, Flammability 0, Reactivity 0

United States
OSHA Classification: Non-Hazardous
TSCA Status: In compliance
CERCLA: Not subject to reporting requirements
RCRA: Non- hazardous
SARA Title III:
313 Reportable Ingredients: None
Clean Air Act Ozone Depleting Chemical Substances: None
Clean Air Act Hazardous Air Pollutants: None
Volatile Organic Compounds: None
CONEG/Heavy Metals: Concentrations below indicated levels
Clean Water Act Toxic Pollutants: None
Clean Water Act Priority Pollutants: None
Clean Water Act Hazardous Substances: None

FDA Status
Ingredients are approved under 21 CFR 175.105, Adhesives, Indirect Food Contact.

USDA Status
This product is not intended for use where it is directly applied to food products. As such
it does not require approval by USDA for prescribed use as cohesive to be applied to the
exterior of primary or secondary packaging.

16. Other Information

Hazard Symbols: Xi, Irritant

N, Dangerous for the environment
Risk Phrases: R43, May cause sensitization by skin contact
R51/53, Toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment
R52/53, Harmful to aquatic organisms, may cause long-term adverse
effects in the aquatic environment
Safety Phrases: None

End of Material Safety Data Sheet