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2 Atoms and
Elements
Review Questions
2.1 Scanning tunnelling microscopy is a technique that can image, and even move, individual
atoms and molecules. A scanning tunnelling microscope works by moving an extremely
sharp electrode over a surface and measuring the resulting tunnelling current, the electrical
current that flows between the tip of the electrode, and the surface even though the two are
not in physical contact.
2.2 The first people to propose that matter was composed of small, indestructible particles were
Leucippus and Democritus. These Greek philosophers theorized that matter was ultimately
composed of small, indivisible particles called atomos. In the sixteenth century modern
science began to emerge. A greater emphasis on observation brought rapid advancement as
the sci-entific method became the established way to learn about the physical world. By the
early 1800s certain observations led the English chemist John Dalton to offer convincing
evidence that supported the early atomic ideas of Leucippus and Democritus. The theory that
all mat-ter is composed of atoms grew out of observations and laws. The three most
important laws that led to the development and acceptance of the atomic theory were the law
of conservation of mass, the law of definite proportions, and the law of multiple proportions.
John Dalton explained the laws with his atomic theory.
2.3 The law of conservation of mass states the following: In a chemical reaction, matter is neither
created nor destroyed. In other words, when you carry out any chemical reaction, the total
mass of the substances involved in the reaction does not change.
2.4 The law of definite proportions states the following: All samples of a given compound,
regardless of their source or how they were prepared, have the same proportions of their
con-stituent elements. This means that elements composing a given compound always occur
in fixed (or definite) proportions in all samples of the compound.
2.5 The law of multiple proportions states the following: When two elements (call them A and B)
form two different compounds, the masses of element B that combine with 1 g of element A
can be expressed as a ratio of small whole numbers. This means that when two atoms (A and
B) combine to form more than one compound, the ratio of B in one compound to B in the sec-
ond compound will be a small whole number.
2.6 The main ideas of John Dalton’s atomic theory are as follows: 1) Each element is composed of tiny,
indestructible particles called atoms. 2) All atoms of a given element have the same mass and
other properties that distinguish them from the atoms of other elements. 3) Atoms combine
in simple, whole number ratios to form compounds. 4) Atoms of one element cannot change into
atoms of another element. They can, actually, through nuclear decay. In a chemical reaction, atoms
change the way that they are bound together with other atoms to form a new substance. The law
of conservation of mass is explained by the fourth idea. Since the atoms cannot change into
another element, and just change how they are bound together, the total mass will remain
constant. The law of constant composition is supported by idea 2 and 3. Since the atoms of a given
element always have the same mass and other distinguishing properties, and they
29
30 Chapter 2 Atoms and Elements
combine in simple whole number ratios, different samples of the same compound will have the same proper-
ties and the same composition. The law of multiple proportions is also supported by ideas 2 and 3 since the
atoms can combine in simple whole number ratios; the ratio of the mass of B in one compound to the mass
of B in a second compound will also be a small whole number.
2.7 In the late 1800s, an English physicist named J.J. Thomson performed experiments to probe the proper-ties
of cathode rays. Thomson found that these rays were actually streams of particles with the following
properties: They travelled in straight lines, they were independent of the composition of the material from
which they originated, and they carried a negative electrical charge. He measured the charge to mass ratio
of the particles and found that the cathode ray particle was about 2000 times lighter than hydrogen.
2.8 In Millikan’s oil drop experiment, oil was sprayed into fine droplets using an atomizer. The droplets were
allowed to fall under the influence of gravity through a small hole into the lower portion of the apparatus
where they could be viewed. During their fall, the drops would acquire electrons that had been produced
by the interaction of high energy radiation with air. These charged drops interacted with two electrically
charged plates within the apparatus. The negatively charged plate at the bottom of the apparatus repelled
the negatively charged drops. By varying the voltage on the plates, the fall of the charged drops could be
slowed, stopped, or even reversed. From the voltage required to halt the free fall of the drops, and from the
masses of the drops themselves, Millikan calculated the charge of each drop. He then reasoned that, since
each drop must contain an integral number of electrons, the charge of each drop must be a whole number
multiple of the electron’s charge. The magnitude of the charge of the electron is of tremendous importance
because it determines how strongly an atom holds its electrons.
2.9 Rutherford’s gold foil experiment directed positively charged a particles at an ultrathin sheet of gold foil.
These particles were to act as probes of the gold atoms’ structures. If the gold atoms were indeed like plum
pudding—with their mass and charge spread throughout the entire volume of the atom—these speeding
probes should pass right through the gold foil with minimum deflection. A majority of the particles did
pass directly through the foil, but some particles were deflected, and some even bounced back. He realized
that to account for the deflections, the mass and positive charge of an atom must all be concentrated in a
space much smaller than the size of the atom itself.
2.10 Rutherford’s nuclear model of the atom has three basic parts: 1) Most of the atom’s mass and all of its pos-
itive charge are contained in a small core called the nucleus. 2) Most of the volume of the atom is empty
space, throughout which tiny negatively charged electrons are dispersed. 3) There are as many negatively
charged electrons outside the nucleus as there are positively charged particles within the nucleus, so that
the atom is electrically neutral. The revolutionary part of this theory is the idea that matter, at its core, is
much less uniform than it appears.
2.11 Matter appears solid because the variation in its density is on such a small scale that our eyes cannot see it.
2.12 The three subatomic particles that compose atoms are as follows:
Protons, which have a mass of 1.67262 x 10 –27 kg or 1.00727 u and a relative charge of +1
Neutrons, which have a mass of 1.67493 x 10 –27 kg or 1.00866 u and a relative charge of 0
Electrons, which have a mass of 0.00091 x 10 –27 kg or 0.00055 u and a relative charge of –1
2.13 The number of protons in the nucleus defines the identity of an element.
2.14 The atomic number, Z, is the number of protons in an atom’s nucleus. The atomic mass number (A) is the
sum of the neutrons and protons in an atom.
2.15 Isotopes are atoms with the same number of protons but different numbers of neutrons. The percent natural
abundance is the relative amount of each different isotope in a naturally occurring sample of a given element.
2.16 Isotopes can be symbolized as AZX, where A is the mass number, Z is the atomic number, and X is the chem-ical
symbol. A second notation is the chemical symbol (or chemical name) followed by a dash and the mass
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2.18 Atomic mass represents the average mass of the isotopes that compose that element. The average calculated
atomic mass is weighted according to the natural abundance of each isotope.
Atomic mass = a (fraction of isotope n) x (mass of isotope n)
n
2.19 In a mass spectrometer, the sample is injected into the instrument and vaporized. The vaporized atoms are
then ionized by an electron beam. The electrons in the beam collide with the vaporized atoms, removing
electrons from the atoms and creating positively charged ions. Charged plates with slits in them accelerate
the positively charged ions into a magnetic field, which deflects them. The amount of deflection depends on
the mass of the ions—lighter ions are deflected more than heavier ones. Finally, the ions strike a detector
and produce an electrical signal that is recorded.
2.20 The result of the mass spectrometer is the separation of the atoms in the sample according to their mass,
pro-ducing a mass spectrum. The position of each peak on the x-axis gives the mass of the isotope, and the
inten-sity (indicated by the height of the peak) gives the relative abundance of that isotope.
2.21 A mole is an amount of material. It is defined as the amount of material containing 6.0221421 x 1023
particles (Avogadro’s number). The numerical value of the mole is defined as being equal to the number of
atoms in exactly 12 grams of pure carbon-12. It is useful for converting number of atoms to moles of atoms
and moles of atoms to number of atoms.
2.22 The mass corresponding to a mole of one element is different from the mass corresponding to a mole of
another element because the mass of the atom of each element is different. A mole is a specific number of
atoms, so the heavier the mass of each atom, the heavier the mass of one mole of atoms.
2.23 The periodic law states the following: When elements are arranged in order of increasing mass, certain sets
of properties recur periodically. Mendeleev organized all the known elements in a table consisting of a
series of rows in which mass increased from left to right. The rows were arranged so that elements with
similar properties were aligned in the same vertical column.
2.24 Metals are found on the left side and the middle of the periodic table. They are good conductors of heat and
electricity; they can be pounded into flat sheets (malleable), they can be drawn into wires (ductile), they are
often shiny, and they tend to lose electrons when they undergo chemical changes.
Nonmetals are found on the upper-right side of the periodic table. Their properties are more varied: Some
are solids at room temperature, while others are liquids or gases. As a whole they tend to be poor conduc-
tors of heat and electricity and they all tend to gain electrons when they undergo chemical changes.
Metalloids lie along the zigzag diagonal line that divides metals and nonmetals. They show mixed proper-
ties. Several metalloids are also classified as semiconductors because of their intermediate and
temperature-dependent electrical conductivity.
2.25 (a) Noble gases are in group 18 and are mostly unreactive. As the name implies, they are all gases in their
natural state.
(b) Alkali metals are in group 1 and are all reactive metals.
(c) Alkaline earth metals are in group 2 and are also fairly reactive.
2.26 Main group metals tend to lose electrons, forming cations with the same number of electrons as the nearest
noble gas. Main group nonmetals tend to gain electrons, forming anions with the same number of electrons
as the nearest following noble gas.
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Problems by Topic
The Laws of Conservation of Mass, Definite Proportions,
and Multiple Proportions
2.27 Given: 1.50 g hydrogen; 11.9 g oxygen Find: grams water vapour
Conceptual Plan: total mass reactants = total mass products
Solution: Mass of reactants = 1.50 g hydrogen + 11.9 g oxygen = 13.4 grams
Mass of products = mass of reactants = 13.4 grams water vapour.
Check: According to the law of conservation of mass, matter is not created or destroyed in a chemical reac-
tion, so, since water vapour is the only product, the masses of hydrogen and oxygen must combine to form
the mass of water vapour.
2.28 Given: 21 kg gasoline; 84 kg oxygen Find: mass of carbon dioxide and water
Conceptual Plan: total mass reactants = total mass products
Solution: Mass of reactants = 21 kg gasoline + 84 kg oxygen = 105 kg mass
Mass of products = mass of reactants = 105 kg of mass of carbon dioxide and water.
Check: According to the law of conservation of mass, matter is not created or destroyed in a chemical reac-
tion, so, since carbon dioxide and water are the only products, the masses of gasoline and oxygen must com-
bine to form the mass of carbon dioxide and water.
2.29 Given: sample 1: 38.9 g carbon, 448 g chlorine; sample 2: 14.8 g carbon, 134 g chlorine
Find: are results consistent with definite proportions?
Conceptual Plan: determine mass ratio of sample 1 and 2 and compare
mass of chlorine
mass of carbon
448 g chlorine 134 g chlorine
Solution: Sample 1: 38.9 g carbon = 11.5 Sample 2: 14.8 g carbon = 9.05
Results are not consistent with the law of definite proportions because the ratio of chlorine to
carbon is not the same.
Check: According to the law of definite proportions, the mass ratio of one element to another is the same
for all samples of the compound.
2.30 Given: sample 1: 6.98 grams sodium, 10.7 grams chlorine; sample 2: 11.2 g sodium, 17.3 grams chlorine
Find: are results consistent with definite proportions?
Conceptual Plan: determine mass ratio of sample 1 and 2 and compare
mass of chlorine
mass of sodium
2.31 Given: mass ratio sodium to fluorine = 1.21:1; sample = 28.8 g sodium Find: g fluorine
Conceptual Plan: g sodium : g fluorine
mass of fluorine
mass of sodium
1 g fluorine
Solution: 28.8 g sodium x 1.21 g sodium = 23.8 g fluorine
Check: The units of the answer (g fluorine) are correct. The magnitude of the answer is reasonable since it
is less than the grams of sodium.
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terminating December, 1841, I trust you will not consider that I am
needlessly trespassing upon your columns in placing before you a few of
the more prominent results emanating from those labours, especially as it
would appear, from the recent publication, that our Government is more
alive to the importance of preserving reliable works on the dialect of the
aboriginal language that it was at the time of their publication.
“The Rev. L. E. Threlkeld’s first production was ‘Specimens of the
Aboriginal Language,’ printed and issued for publication (as mentioned
by you) in 1827.
“In 1829, under the auspices of the Venerable Archdeacon Broughton
(subsequently Bishop of Australia), he completed the translation of the
Gospel of St. Luke, which was revised in 1831, and the MSS. forwarded
to the Archdeacon.
“In 1832 a selection of prayers from the Ritual of the Church of
England was translated.
“In 1835 his ‘Australian Grammar, being a Dialect of the Languages
of the Aborigines,’ was completed, a copy of which was presented to His
late Majesty King William IV, and placed in the Royal Library.
“In 1836 the ‘Australian Spelling Book’ was completed and printed
for the use of the aborigines. Two of the youths then attending the
Mission School could read and write in their native tongue. In the same
year ‘Selections from the Old Testament’ were also translated to form
reading lessons for the native youth.
“In 1837 the first translation of the Gospel of St. Mark was finished.
“At the close of the yearly report ending 1838 the following subjects
are alluded to as having occupied his attention—
Specimens of the
“1.
Language In print. The copies were then
“2.
An Australian } expended.
Grammar
“3. The Gospel of St. Luke.
“4. The Gospel of St. Mark.
“5. The Gospel of St. Matthew to the 5th chapter.
“6. A Selection of Prayers for Morning and Evening Service.
“7. A Selection of Reading Lessons from the Old Testament.
“8. The Australian Spelling Book.
“In 1856 (some fifteen years after the close of the Mission) he
completed and published his last work—‘The Key to the Structure of the
Aboriginal Language’—and at the time of his death, in 1859, he had
nearly completed the final revision of the Four Gospels, with a view to
their publication. At the request of Sir George Grey, who has always
taken a lively interest in aboriginal languages, I forwarded the
manuscript to him, under the impression that he would have it printed
and forward me a copy.
“In the annual report of 1839 allusion is made to the similarity of the
aboriginal language with the Cherokee Indian, where specimens of the
dual are given; the Cherokee habitual form of the verb agreeing with the
modification in the Australian Grammar, page 29. A comparison of
dialects is also made of the aborigines at Lake Macquarie, Manila River,
Swan River, and King George’s Sound.
“Burwood House, March 16.
L. E. THRELKELD.”
In April, 1844, the Society for propagating the Gospel in Foreign Parts
proposed to Lord Stanley to combine with the Colonial Government for
supporting missions and schools for the European and aboriginal
population of New South Wales, the Society offering to defray a certain
portion of the expense. Four clergymen were to be maintained by the
Church Societies on a salary of £250 per annum, and £50 for horse
allowance, each; total, £1,200. Expenses to be borne by Government of
four additional clergymen as before, £1,200. Two missionaries—one for
the whites, and the other for the aboriginal population—were to be
placed at each station: at Western Port, two; at Goulburn, two; at Mount
Rouse, two; at River Lodden, two. At each station, four schoolmasters.
The missionaries at each station were to devote themselves to the white
and black population within a reasonable distance.
From the report of the Port Phillip District Committee of the Society
for promoting Christian Knowledge, the following tables represent the
numbers and localities of the white and aboriginal population in and
about the Port Phillip District in 1844:—
W P B .
Mount The The
Dandenong. Total.
Rouse. Lodden. Goulburn.
Within Circuits 1,046 1,102 750 290 3,188
Beyond Circuits 270 270 250 167 957
Moving
250 250 250 250 1,000
population
—— —— —— ——
Totals 1,566 1,622 1,250 707
Total British population entirely destitute of religious
5,145
ordinances
On purchased lands 1,000
In villages and farms near town 2,000
——
3,000
——
Total British population 8,145
A B P .
Mount The The
Dandenong. Total.
Rouse. Lodden. Goulburn.
At stations 400 300 400 200 1,300
Accessible
beyond the limits 800 800 1,000 ... 2,600
of occupation
—— —— —— —— ——
Totals 1,200 1,100 1,400 200
Total black population 3,900
White population 8,145
——
12,045
These proposals were communicated to His Excellency Sir George
Gipps, together with a letter from the Immigration Office with the views
of the Land Commissioner on the project; but the result of this truly
liberal and Christian proposal seems to have met with no response.
I may here venture to add my own testimony to that of the Rev. Mr.
Threlkeld and Mr. Robinson upon this subject, as given in evidence
before a Committee of the Legislative Council, in the year 1838; also
Captain Grey’s opinion. I fear Mr. Robinson’s evidence is not obtainable;
but the wonderful achievement of that gentleman in accomplishing
single-handed what the whole power of the Van Diemen’s Land
Government could not succeed in with a large military force, backed by
the settlers, and at a heavy cost, is one of the noblest triumphs of moral
over physical power probably ever accomplished. I have described this
in the “Reminiscences of Tasmania.”
Thus the aboriginal natives melted away like snow before the sun; from
no congenial heat, but from the practices of inhuman selfishness.
What a contrast the European settlement in 1858! Scarce a black in
existence for 3 miles, while the white population numbered 488,769
souls, with 4,000,000 sheep, 400,000 head of cattle, 184,000 horses, with
imports and exports of £14,000,000 and £13,000,000 respectively, on the
graveyard of the aborigines.
The earth was never intended to be kept waste, but the evil is as to the
way of settling it—this is the perplexing question.
One of the singular circumstances of a European of the name of
Buckley living with these aboriginals for a long period is worthy of
mention here. Buckley enlisted as a soldier, but was transported for
having in his possession a parcel of stolen clothes, which a female had
asked him to take charge of. He was sent to Westport, and with two
others effected his escape from the ship, and after wandering about the
bush nearly starved, he fell in with a family of the aborigines, with
whom he lived a month or two, but being desirous of reaching Sydney,
he left them and wandered to the Yan Yean, where Melbourne now
stands; from thence he wandered to Geelong, where he met a tribe of
blacks, who were much astonished to see him, but treated him with
kindness, and took him with them to the Barwon River, where they, 200
blacks, viewed him with much astonishment. The blacks supposed he
had been a black, changed to white—a supposition very general. They
treated him kindly and gave him a wife, but fearing jealousy, he
transferred her to another man. Shortly afterwards, he and one of his
companions, long separated, met, but this man behaved so badly towards
the women, that Buckley insisted on his leaving the tribe, which he did,
and he heard afterwards that he was dead. Buckley lived some years with
the Geelong tribe, and acquired their language, always impressing on
them that he had been a blackfellow, so as to secure his safety. He says,
“Having the best hut, and a good fire, the children congregated about me,
and I told them of English ships, tools, and wars, &c., to which both
adults and children listened with wonder, but they did not like the idea
that I should leave them. On their missing me once, when I went to
wash, they made great search, and when they found me, an old man burst
into tears, and rejoiced at the discovery. Their numbers had greatly
decreased, owing to their wars and cruelties. Their expeditions are
generally in the night; men, women, and children are then murdered
wholesale. I often reflected on the goodness of Providence in preserving
me, but I did not venture to instruct them, fearing that they would injure
me; they do not think of a superintending Providence.”
They believe, he says, in two spirits, whom they treat with great
respect. One of these they believe resides in a certain marsh, and is the
author of all their songs; he communicates by his songs, and these songs
are circulated through the tribes, and they have them new every year. The
other spirit they believe has charge of the pole that props up the sky, and
they stand in dread lest the sky should fall down and destroy them. Just
before the Europeans came to Port Phillip, in 1836, there was much
conversation about this spirit—that he had sent a message to the effect
that in order to repair the sky-props, he needed immediately some
tomahawks, which were to be made out of the carts used by the sealers at
Western Port. On this report, the natives went down to Western Port and
stole a cart, such as the sealers used, and made tomahawk handles out of
the spokes of the wheels.
Although Buckley had heard that the whalers now visited Western
Port, he had become so reconciled to his way of living, that he lost all
desire to return to civilization, and feared meeting with any of the white
people.
He became such an adept at fishing, that he supplied not only his own
tribe but others with food. The tribe he lived with were cannibals. They
ate the flesh of enemies they had slain, not to satisfy hunger, but from a
belief that they obtained some particular virtue thereby; but some were
content with rubbing the fat into their bodies.
Promiscuous intercourse was common, and the husband often
consented to it, and then beat his wife for submitting to it.
They warned their children from going where the dead were buried;
and when an infant they loved died, they placed the body in a hollow tree
until it had shrunk up so that they could carry it about. The same practice
exists in the north.
Their principal food is the wombat, an animal that burrows, which
they kill by thrusting a boy feet foremost into the hole, who, when
reaching the animal, pushes it to the end of the hole, and then makes a
noise so that the men above may mark the spot, and make an entrance for
the purpose of seizing the animal. The porcupine is another dainty,
roasted on the fire; the flesh is excellent.
About eight years before the settlement at Port Phillip, some
Europeans had gone up the river in a boat, landed, and left a tomahawk
behind them. Buckley was much agitated at the news.
When the European settlers with Mr. Batman arrived, Buckley did not
discover himself for some time, as he had no desire to leave the blacks.
He, however, suddenly appearing to some horsemen with his spears and
opossum cloak, and being a very large man, astonished the whites by his
visit. For some time he could not endure European clothing. He was
appointed by the Governor as overseer of the blacks at the mission
institution, at a salary of £60 per annum, having received his freedom,
but never appeared happy. He afterwards was appointed as constable at
Hobart Town, where he died. It appears he had lived nearly thirty years
in that savage condition.
CHAPTER VI.