TEST ;6+7

1. The number of bonds in nitrogen molecule is:

(a)One sigma and one pi bond (b)one sigma and two pi
(c)three sigma only (d)two sigma and two pi
2. Which of the following molecules has zero dipole moment?
(a)NH3 (b)CHCl3 (c)H2O (d)BF3
3. Which of the hydrogen halides has the highest percentage of ionic character?
(a)HF (b)HBr (c)HCl (d)HI
4. Which of the following species has unpaired electrons in antibonding molecular orbitals:
(a)O2-2 (b)N2-2 (c)Br2 (d)F2
5. The octet rule is not followed in the formation of:
(a)NF3 (b)CF4 (c)CCl4 (d)PCl5
6. Noble gases have maximum stability and least reactivity because:
(a)They are very safe (b)their valence shells are complete
(c)they are gases (d)they are present in zero group
Q;1 Attempt the following questions.
1. All spontaneous reactions are exothermic in nature? Justify it.
2. Define heat of neutralization. Give example.
3. Burning of a candle is a spontaneous process.justify.
4. State Hesse’s law of heat summation ? give example
5. What is meant by state function? Give example.
6.Define Octet rule .Give examples of those which do not follow it.
7.Why the bond distance is called as a compromise distance.
8.Define bond order and calculate it for Hydrogen molecule?
9.Why the lone pair electrons occupy more space than bond pair electrons?
10.Why pi bonds are more diffused than sigma bonds?
11.Cationic radius is smaller than the parent atom, while anionic radius is larger than parent atom. Why?

Q;2 Attempt the following long questions.

a)Explain briefly working and construction of BOMB calorimeter.
b)Mention the postulates of VSEPR theory along with AB3 type.