DEEPIKAENGLISH MEDIUM SCHOOL

SECTOR-5, ROURKELA
ANNUAL EXAMINATION-2022-23
Time- 3 hrs.
Class-XI
Subiect-CHEMISTRY(043) Full Mark-70

GeneralInstructions:
instructions carefully.
Readthe following this question paper with internal choice.
a)There are 35 questions in
b) SECTION-A
Consists of 18 multiple-choice questions carrying 1 mark each.
sECTION-8 consists of 7 very short answer questions carrying 2 marks each.
a sECTION-C consists of 5 shot answer questions carrying 3 marks each.
el SECTION-D consists of 2 case- based questions carrying 4 marks each.
marks each.
n SECTION-E consists of 3 long answer questions carrying 5
g) Allquestions are compulsory. allowed
h) Use of log tables and calculatorsis not
SECTION-A
The following questions are multiple-choice questions with one correct answer. Each question carries 1
mark. There is no internal choice in this section.

1. The IUPAC name of CH3 -CH (CaHs)-CH(CHs)-CHs is

A) 3,4 -dimethyl hexane B) 2-ethyl-3-methylpentane
C) 2,3-dimethylhexane D)2,3-dimethylbutane
its combustion product (CO2)
2. Which of the following organic compounds has same hybridisation as D) Ethanol
B) Ethane C) Ethene
A) Ethyne
3 Isomerisation of n-hexane on heating with anhydrous AlCh and HCl gas gives
A) 2-methylpentane B)3-methylpentane
C)2-methylhexane D)mixture of 2-methylpentane and 3-methylpentane
The bond order of individual Cartbon-Carbon bond in benzene is
D) two
A) one B) one and two alternately C) between one and two

5. For detection of which element Lassaingne test is used?

A) Nitrogen B) Chlorine C) Sulphur D) All of these

Heterocycic fission of covalent in organic molecule gives D) Free radicals

A) Cations and anions B) only cations C) Only anions
7.
4gm of hydrogen are ignited with 4gm of oxygen. The weight of water formed isD) 2.5g
A) 0.5g B) 3.5g C) 4.5g

Which of the following compounds has same empirical formula as that of glucose
D) Fructose
A) Acetaldehyde B) Acetic acid C) Ethanol
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 second shell is
9. The first shell energy of He+1 ion is -54.4 ev. Then energy of its
A) -54.4 ev B--13.6 ev C) -27.2ev D) 38

10 In NaH, the oxidation state of hydrogen is

A) 2 B) 1 C) -1 D) 0

the application of
11 The chemical reaction in which the yield of the product cannot be increased by
high pressure is
A) Nzg) + Ozg) > B) PClg) + Clzg) ’
2NOlg) PClsg)
C) 2SOz9) + Oz9)> 2503(9) D) Nzg + 3H2g) E> 2NH3g)
formed at equilibrium, according to
12. 4 moles of Aare mixed with 4 moles of B, when 2 moles of C are
the reaction A+ B C+D.The equilibrium constant is
C)0.25 D) 1.0
A4 B) 4

13.
all temperature are
The correct order thermodynamics conditions for the spontaneous reactionD)atAH < 0 and AS >0
A) AH< Oand AS =0 B) AH <0 and AS<0 C) AH>0 and AS <0

14. Which of the following has the largest dipole moment?

A) H20 B) NH3 C) HI D) SO
Reason (R)
15. Given below are twO statements labelled as Assertion (A) and
Assertion (A): 2nd |P of alkaliis maximum in the period
Reason (R): Alkali metals have the smallest atomicsize in period
Select the most appropriate answer from the options given below:
explanation of A
(a Both A and R are true and R is the correct
b. Both A and R are true but R is not the correct explanation of A.
C.A istrue but R is false.
d. A is false but R is true

(A) and Reason (R)

16. Given below are two statements labelled as Assertion
Assertion (A): Size of Ca2* is larger than Kt+
more than K1+
Reason (R): Number of electrons in Cazt is
options given below:
Select the most appropriate answer from the explanation
correct of A
a. Both A and R are true and R is the
correct explanation of A.
b. Both A and R are true but R is not the
c. A is true but R is false.
is false but Ris true
d. A
labelled as Assertion (A) and Reason (R)
1. Given below are two statements
than water
Assertion (A): Density of ice is greater packed
Reason (R): In ice H0 molecule are closer options given below:
the
Select the most appropriate answer from explanation of A
correct
a. Both Aand Rare true and Ris the
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 b. Both Aand Rare true but Ris not the correct explanation of A.
c.A is true but R is false.
d. Ais false but R is true

8 Given below are two statements labelled as Assertion (A) and Roason (R)
Assertion (A): Na is more stable than Ng
Reason (R) :N,1" has less electron in antibonding orbital
Select the most appropriate answer from the options glven below:
a. Both Aand Rare true and Ris thecorrect oxplanation of A
b.Both Aand Rare true but Ris not the correct explanation of A.
c. Ais true but R is false.
d. Ais false but R is true
SECTION-B (2 mark each)
19 Calculate the number of electrons present in 60 gm of acetic acid ?
20 Calculate the total number of angular nodes present in 3p orbital?
OR
Name the two conditions which must be satisfied for hydrogen bonding to take place in a molecule.
21 Explain the diamagnetic behaviour of Fa molecule on the basis of molecular orbital theory?
22. For a reaction at 298 k, 2A +B=C, AH =400 KJ Mol and AS=0.2 kj ki mol", At what temperature
willthe reaction become spontaneous considering AH and AS to constant over the temperaturo
range?
OR
Nz +3H2 =2 NH3, lf equilibrium concentratlon of N2 , H2 and NH3 are 0.5M, 1M and 2M respectively
then find equilibrium constant.
23. How to prepare Cis But-2-ene and trans But-2-ene from But-2-yne?
24. What are the necessary conditions for any system to be aromatic?
25. An alkene 'A' on ozonolysis gives a mixture of ethanal and pentan-3- one. Write structure and
IUPAC name of 'A'
SECTION-C(3 mark each)
26 Describe the term
A) The law of conservation energy
B) The law of definite proportion
C) The law of multiple proportion3
(27 For an equilibrium reaction H2 + h= 2HI,10 moles of H) and 20 moles of h is taken initially in a
container of volume 5L. Find Ke and K, for reaction if 40% dissociation of Ha take place?
28. Balance the equation half reactlon method
Fe(aq) +Crn0,2- (aq)= Fe (aq) +Claq) (acidic medium)
29) Asample of 0.50 g of an organic compound was treated according to Kjeldahl's method. The
ammonla evolved was absorbed in 50 mi of 0.5 MHASO. The residual acid required 60 mL of 0.5 M
solution of NaOH for neutralisation. Find the percentage composltion of nitrogen in the compound.
OR
In Dumas' method for estimation of nitrogen,0.3g of an organic compound gave 50mL of nitrogen
collected at 300K temperature and 715mm pressure. Calculate the percentage composition of
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 nitrogen in the compound. (Aqueous tension at 300K=15 mm
30. Write the short notes on
A) Hyperconcjucation
B) Mesomeric effect
C) Inductive effect
SECTION-D (4 mark each)
31. One practical approach to estimate the size of an atom of a
non-metallic element is to measure the
distance between twO atoms when they are bound together by a single bond in a
and from this value, the "Covalent Radius" For metals, we covalent molecule
is taken as half the inter nuclear distance separating the
define the term "Metallic Radius" which
metalcore's in the
Radius to refer to both covalent or metallic radius depending on whether themetallic crystal. Atomic
or ametal. The atomic size generally decreases across a element is a non-metal
period. It is
outer electrons are in the same valence shell and the effective because within the period the
nuclear charge increases as the
atomic number increases resulting in the increased attraction of
electrons to the nucleus Being
monoatomic, Their (non-bonded radii) values are very large. In fact radi of noble gases should be
compared not with the covalent radii but with the van derVWaals radii of other
would be different because of their different nuclear charges. A elements. Their radii
quantitative measure of the
tendency of an element to lose electron is given by its lonization Enthalpy. It
required to remove an electron from an isolated gaseous atom (X) in its groundrepresents the energy
enthalpy is expressed in units of kJ mol-1. Electron gain enthalpy provides a state. The ionization
with which an atom adds an electron to form anion. measure of the ease
Electronegativity
ability of an atom in a chemical compound to attract shared
Aqualitative measure of the
electrons to itself is called
electronegativity. Unlike ionization enthalpy and electron gain enthalpy, it is not a
quantity. Electronegativity generally increases across a period from left to right (say measurable
fluorine) and decrease down a group(say from fluorine to astatine) in the from lithium to
metallic elements have strong tendency to gain electrons. periodic table. Non
related to those non-metallic properties of elements. It canTherefore, electronegativity is directly
be further extended to say that the
electronegativity is inversely related to the metallic properties of elements. Thus, the increase in
electronegativities across a period is accompanied by an
decrease in metallic properties) of elements. Similarly, theincrease
in non-metallic properties (or
decrease in electronegativity down a
group is accompanied by a decrease in non-metallic properties (or increase in metallic properties)
of elements.
A) what is the lowest value of n that allows g orbital to exist?
B) Whysecond electron gain enthalpy of oxygen is positive?
C) Why electron gain enthalpy of fluorine is less negative than that of chlorine?
D) Why electron negativity of fluorine is greater than that of chlorine?

32 The arrangement of electron pairs and the atoms around the central atom can be:
linear, Trigonal
planar, tetrahedral, trigonal-Bipyramidal and octahedral. Valence bond theory was introduced by
Heitler and London (1927) and developed Further by Pauling and others. A discussion Of the
valence bond theory is based on the knowledge of atomic orbitals, electronic Configurations of
elements. partial merging of atomic orbitals is called overlapping of atomic orbitals which results in
the pairing of electrons. The extent of overlap decides the strength of a covalent bond. according to
orbital overlap concept, the formation of a covalent bond between two atoms results by pairing of
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 electrons present
in the valence shell having opposite spins. When orbitals of two
atoms come
closeto form bond, their overiap may be positive, negative or zero depending upon the sign and
direction of orientation of amplitude of orbital wave function in space. Orbitals forming bond should
have same sign(phase) and orientation in space. This is called positive overlap. The criterion of
Overlap, as the main factor for the formation of covalent bonds applies uniformiy to the
homonucleariheteronuclear diatomic molecuBes and polyatomic molecules.
A) How many sigma and pibonds present in Calcium carbide?2o OA
B) Why NaCl is a bad conductor of electricity in the solid state?
C)What is the shape of SF. and CCl?
D) What is the shape XeF2 and XeFa?

SECTION-E(5 mark)
A) An ion with mass number 56 contains 3units of positive charge and 30.4% more neutrons than
electrons. Assign the symbol to this ion. (3mark)
B) (a) How many sub-shels are associated with n=4?(b) How many electrons willbe present in
the sub-shels having spin quantum number value of -1/2 for n=4? (2mark)
C) What is the maximum number of emission lines when the excited electron of a Hatom in n=6
drops to the ground state? (1 mark)
34 A) The combustion of one mole of benzene takes place at 298 Kand 1 atm. After combustion, CO2
(g) and H0 (0) are produced and 3267.0 kJ of heat is liberated. Calculate the standard enthaipy of
formation, Af H° of benzene. Standard enthalpies of formation of CO2 (g) and H20 are -393.5 kJ
moi and- 285.83 kJ mol - respectively. (3mark)
B) Prove that C-Cy=R calorie (2mark)
OR

A) Calculate the enthalpy change on freezing of 1.0 mol of water at 10.0°C to ice at -10.0°C. Afus
H=6.03 kJ moti at 0°C. Cp [H2 O{(0]=75.3 J mol- K- Cp [H20(s)] =36.8 J mol-1 K-, (3mark)
B) Given N2 (g) +3H2 (g) ’ 2NH3 (9); Ar H0 =-92.4 kJ mo-1 What is the standard enthalpy of
formation of NH3 gas? (2 mark)
35. A) Complete the following conversion (each one mark)
a) Benzene to acetophenone
b) Acetylene to Benzene
c) Benzene to toluene
B) What's happen when 2-methylbutene reacts with following reagents
a) HBr b) Ozonolysis

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atger e. cle
DEEPIKA E.M. SCHOOL, SECTOR-5, ROURKELA
UNIT TEST (2022-23)
Time -1½hours
Class-YI
Full Mark - 35
subject-CHEMISTRY (043)
carrying 1 mark each.
Section A consists of 9 muitiple choice questions
questions carrying 2 mark each.
2 Section B consist of 4 very short answer
marks.
2. Section C consists of 3 questions carrying 3
4 mark.
4 Section D consists of 1 case based questions carrying
carrying 5 mark.
5. Section Econsists of 1 long answer questions
Section A

bonding that awater molecule can form is

1. The maximum number of hydrogen
b) 2 c) 3 d) 4
a) 1
hydrogen bond be strongest?
2. In which of the following substances will
(i) HCI
(ii) H,0
(ii) HI
(iv) H,S
are
3. The shapes of SF4 and Xef, respectively
bipyramidal
a) Triangular bipyramidal&triangle
(c) T-shape and linear
b) Sec saw and linear
bipyramidal.
c) Square planar and trigonal /mol, -393.5 KJ /mol and -
combustion of methane, graphite and dihydrogen are -890.3 KJ
4. The enthalpy of
Cululate he enlhalyo
285.8 KI/mol respectively.b) -52.27 KJ/mol c) +74.8 KI/mol d) 52.26 KJ/mol
ra) -74.8 KI/mol
standard states are . Eetetetehe
5. The enthalpy of all elements in their A c) <O
a) Unity b) Zero
b) d) Different for each element
highest oxidation state ?
6. In which of the following compound, nitrogen exhibit
b) N, c) NO, d) NCI,
a) NH3
electrons, its oxidation number will be.
7. Ametal ion loses 3
a) +3 yb) +6 c) 0 d) -3

statement of Reason
In each of the folowing questions, a statement (A) is given followed by a corresponding
answer as
(R) just below it. Of the statements, mark the correct
a) lf the both assertion and reason are correct and reason is the correct explanation of the assertion
correct
b) If the both assertion and reason are correct, but reason is not the correct explanation of the
explanation of the assertion.
c If assertion is correct, but reason is
incorrect
d) If both assertion and reason are incorrect
8. Assertion: BF3 molecule is planar but NFg is pyramidal
Reason:N atom is smaller than B
9. Assertion: For the reaction 2NH, +N, + 3H,, AH> AU
Reason: enthalpy change is always greater than internal energy change
Section B

10. Although both CO, and H,0 are triatomic molecules, the shape of H,0 molecule is bent while that of Co, is
linear. Explain these on the basis of dipole moment.
11. Describe the hybridization in case of PCls. Why are the axial bonds longer as compared to the equatorial bonds?
12. Calculate the number of kJ necessary to raise the temperature of 54 gm of Aluminium from 35 to 55°C.
Molar heat capacity of Aluminium is 24j mol K1
OR
For the reaction, 2Cl (e) Clz (e) what are the signs of AH and AS ?
13. Predict the oxidation number of the underlined atom in the following species
a) NH,NO, b) CaOC,
Section C

14. Draw the MOT diagram of N,' and O,

15. Calculate the standard enthalpy of formation of CH,OH(0) from the following data:
CH,OH () +3/2 0, (g) ’ co, (e) +2H,O(0) ; ArH 0 =-726 kJ mol1
C(graphite) +O, (&) CO, (g); AcH O=-393 kJ mol
H, (e)+1/2 O, (8) ’ H,O(); AfH°=-286 kJ mol!
16. Permanganate ion reacts with bromide ion in basic medium to give manganese dioxide and bromate ion.
Write the balanced ionic equation for the reaction. (Oxidation Method)
Mn0 (aq) +Br (aq) + MnO(s) +BrO- (aq)
OR
Permanganate (VIl) ion, Mn0 in basic solution oxidises iodide ion, I- to produce molecular iodine (12) and
manganese (IV) oxide (Mn02). Write a balanced ionic equation to represent this redox reaction. (Electon-ion
Method)
Mng" (aq) +1 (aq) MnO,(s) + l,(s)
Section D
17.A process or change is said to be reversible, if a change is brought out in such a way that the
process could, at any moment, be reversed by an infinitesimal change. A reversible process
proceeds infinitely slowly by a series of equilibrium states such that system and the surroundings
are always in near equilibrium with each other. Processes other than reversible processes are
known as irreversible processes. Isothermal and free expansion of an ideal gas For isothermal
(T = constant) expansion of an ideal gas into vacuum ; w = 0 since pex = 0. Also, Joule
determined experimentally that q = 0; therefore, AU = 0, A=+Uqw can be expressed for
isothermal irreversible and reversible changes as folows:
A) calculate the internal energy change if a system absorbs 15 KJ of heat and does 5KJ work.
(2)
B) Wamount of work is done by the system and q amount of heat is supplied to the system, what type of
system would be?
C) Define adiabatic system.
(1)
(1)
Section E

18. Give reasons for the following

A) PCI, is possible but NCI, is not possible
B) Why Be, is not possible?
C) Which out of NH, and NF, has higher dipole moment and why?
D) Why ortho nitro phenol is more volatile than that meta nitro phenol
E) Why lce floats on water? pana