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CHEMISTRY0620/43
Paper 4 Theory (Extended) May/June 2020
1 hour 15 minutes
INSTRUCTIONS
●● Answer all questions.
●● Use a black or dark blue pen. You may use an HB pencil for any diagrams or graphs.
●● Write your name, centre number and candidate number in the boxes at the top of the page.
●● Write your answer to each question in the space provided.
●● Do not use an erasable pen or correction fluid.
●● Do not write on any bar codes.
●● You may use a calculator.
●● You should show all your working and use appropriate units.
INFORMATION
●● The total mark for this paper is 80.
●● The number of marks for each question or part question is shown in brackets [ ].
●● The Periodic Table is printed in the question paper.
IB20 06_0620_43/5RP
© UCLES 2020 [Turn over
2
A B C
H
H H H O H H H H
H C
H C C C C H C C C H H
C C
H H H O H H H H H H
D E
H H H H H O
H C C C O H H C C C
H H H H H O H
. ...................................................................................................................................... [1]
(ii) Give the letter of the compound that has the empirical formula CH2.
. ...................................................................................................................................... [1]
(iii) Give the letter of one compound that reacts with bromine in an addition reaction.
. ...................................................................................................................................... [1]
(iv) Give the letter of one compound that reacts with chlorine to form the compound shown.
H Cl H
H C C C H
H H H
. ...................................................................................................................................... [1]
(v) Give the letters of two compounds that can react with each other to form an ester.
(vi) Give the letter of the compound that is in the same homologous series as hex‑1‑ene.
. ...................................................................................................................................... [1]
. ...................................................................................................................................... [1]
[1]
weak ...........................................................................................................................................
acid .............................................................................................................................................
[2]
[Total: 10]
. ...................................................................................................................................... [1]
. ...................................................................................................................................... [1]
(b) The table shows some data for the production of ammonia.
....................................................................................................................................................
....................................................................................................................................................
[2]
(c) E
xplain, in terms of particles, what happens to the rate of this reaction when the temperature
is increased.
....................................................................................................................................................
....................................................................................................................................................
....................................................................................................................................................
....................................................................................................................................................
....................................................................................................................................................
.............................................................................................................................................. [3]
(d) Ammonia, NH3, is used to produce nitric acid, HNO3. This happens in a three-stage process.
reason . ................................................................................................................................
. ............................................................................................................................................
[2]
(ii) In this reaction the predicted yield of NO is 512 g. The actual yield is 384 g.
2NO + O2 → 2NO2
Which major environmental problem does NO2 cause if it is released into the atmosphere?
. ............................................................................................................................................
. ...................................................................................................................................... [1]
Calculate the volume of O2 gas, at room temperature and pressure (r.t.p.), needed to
produce 1260 g of HNO3.
Use the following steps.
moles of O2 = ..............................
●● Calculate the volume of O2 gas that reacts at room temperature and pressure (r.t.p.).
omplete the energy level diagram for this reaction. Include an arrow that clearly shows the
C
energy change during the reaction.
4NO2 + 2H2O + O2
energy
progress of reaction
[3]
[Total: 18]
(i) State why these two isotopes of chlorine have the same chemical properties.
. ............................................................................................................................................
. ............................................................................................................................................
. ...................................................................................................................................... [2]
(ii) omplete the table to show the number of electrons, neutrons and protons in each atom
C
and ion.
17Cl
35
17Cl
37 –
[3]
. ...................................................................................................................................... [1]
(ii) Why is there no reaction between iodine and aqueous sodium bromide?
. ...................................................................................................................................... [1]
omplete the dot-and-cross diagram to show the electron arrangement of the ions in
C
magnesium chloride. Give the charges on the ions.
......... .........
Mg Cl
[3]
(d) Hydrogen and chlorine react to form hydrogen chloride gas, as shown in the equation.
H2 + Cl 2 → 2HCl
bond energy
bond
in kJ / mol
H–H 436
Cl –Cl 243
H–Cl 432
alculate the energy change for the reaction between hydrogen and chlorine, using the
C
following steps.
.............................. kJ
.............................. kJ
.............................. kJ / mol
[3]
[Total: 13]
filtration .......................................................................................................................................
....................................................................................................................................................
chlorination .................................................................................................................................
....................................................................................................................................................
[2]
(b) A student uses anhydrous copper(II) sulfate to test for the presence of water.
(ii) The purity of a sample of water can be assessed by measuring its boiling point.
. ...................................................................................................................................... [1]
solvent front
X
start line
(i) How does this chromatogram show that this substance is not pure?
. ...................................................................................................................................... [1]
(ii) Draw a circle round the correct Rf value for the spot labelled X.
(iii)
State how a colourless substance can be made visible on a chromatogram.
. ...................................................................................................................................... [1]
[Total: 8]
(b) The graph shows the change in temperature as a sample of a gas is cooled.
A B
temperature
time
.............................................................................................................................................. [1]
After some time, the perfume is smelt at the back of the room.
1 .................................................................................................................................................
2 .................................................................................................................................................
[2]
[Total: 6]
. ...................................................................................................................................... [1]
test . ............................................................................................................................................
....................................................................................................................................................
result . .........................................................................................................................................
....................................................................................................................................................
[3]
[Total: 5]
7 Aluminium is extracted by electrolysis. Iron is extracted from its ore by reduction with carbon.
....................................................................................................................................................
.............................................................................................................................................. [2]
.............................................................................................................................................. [1]
(c) (i) Explain why aluminium cannot be extracted by reduction with carbon.
. ...................................................................................................................................... [1]
. ...................................................................................................................................... [1]
. ...................................................................................................................................... [1]
(iv) Write the ionic half-equation for the reaction at the negative electrode.
. ...................................................................................................................................... [2]
Give two properties of aluminium that make it suitable for use in overhead electricity cables.
1 .................................................................................................................................................
2 .................................................................................................................................................
[2]
. ...................................................................................................................................... [2]
(ii) Give two ways in which the properties of transition elements differ from the properties of
Group I metals.
1 . .........................................................................................................................................
2 . .........................................................................................................................................
[2]
[Total: 14]
O O O O O
C C N N C C N N C
H H H H
(ii) Complete the structures of the two monomers that react to form nylon.
[2]
. ...................................................................................................................................... [1]
(b) Items made from nylon are often disposed of by burying them in the ground. This is called
landfill.
....................................................................................................................................................
.............................................................................................................................................. [1]
.............................................................................................................................................. [1]
[Total: 6]
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Assessment International Education Copyright Acknowledgements Booklet. This is produced for each series of examinations and is freely available to download
at www.cambridgeinternational.org after the live examination series.
Cambridge Assessment International Education is part of the Cambridge Assessment Group. Cambridge Assessment is the brand name of the University of
Cambridge Local Examinations Syndicate (UCLES), which itself is a department of the University of Cambridge.
© UCLES 2020
I II III IV V VI VII VIII
1 2
H He
hydrogen helium
Key 1 4
3 4 atomic number 5 6 7 8 9 10
Li Be atomic symbol B C N O F Ne
lithium beryllium name boron carbon nitrogen oxygen fluorine neon
7 9 relative atomic mass 11 12 14 16 19 20
11 12 13 14 15 16 17 18
Na Mg Al Si P S Cl Ar
sodium magnesium aluminium silicon phosphorus sulfur chlorine argon
23 24 27 28 31 32 35.5 40
19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
potassium calcium scandium titanium vanadium chromium manganese iron cobalt nickel copper zinc gallium germanium arsenic selenium bromine krypton
39 40 45 48 51 52 55 56 59 59 64 65 70 73 75 79 80 84
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54
Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
rubidium strontium yttrium zirconium niobium molybdenum technetium ruthenium rhodium palladium silver cadmium indium tin antimony tellurium iodine xenon
16
85 88 89 91 93 96 – 101 103 106 108 112 115 119 122 128 127 131
55 56 57–71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86
0620/43/M/J/20
lanthanoids
Cs Ba Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
caesium barium hafnium tantalum tungsten rhenium osmium iridium platinum gold mercury thallium lead bismuth polonium astatine radon
133 137 178 181 184 186 190 192 195 197 201 204 207 209 – – –
87 88 89–103 104 105 106 107 108 109 110 111 112 114 116
actinoids
Fr Ra Rf Db Sg Bh Hs Mt Ds Rg Cn Fl Lv
francium radium rutherfordium dubnium seaborgium bohrium hassium meitnerium darmstadtium roentgenium copernicium flerovium livermorium
– – – – – – – – – – – – –
57 58 59 60 61 62 63 64 65 66 67 68 69 70 71
lanthanoids La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
lanthanum cerium praseodymium neodymium promethium samarium europium gadolinium terbium dysprosium holmium erbium thulium ytterbium lutetium
139 140 141 144 – 150 152 157 159 163 165 167 169 173 175
89 90 91 92 93 94 95 96 97 98 99 100 101 102 103
actinoids Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr
actinium thorium protactinium uranium neptunium plutonium americium curium berkelium californium einsteinium fermium mendelevium nobelium lawrencium
– 232 231 238 – – – – – – – – – – –
The volume of one mole of any gas is 24 dm3 at room temperature and pressure (r.t.p.).