CLASS-XI /CHEMISTRY/WORKSHEET

CHAPTER-6/ THERMODYNAMICS
Q1- Define them-
(a) Heat capacity (b) Enthalpy of atomization (c) Extensive and intensive
properties (d) Spontaneous process (e) Entropy (f) Hess’s law of constant heat
summation (g) Gibb’s Helmholtz equation
Q2-(a)What are the enthalpies of all elements in their standard states?
(b) What is the physical significance of the free energy change of a system?
(c) What is the relation between the enthalpy of reaction and bond enthalpy?
(d) Many thermodynamically feasible reactions do not occur under ordinary
conditions.Why?
Q3-For an isolated system, ΔU=0, what will be ΔS?
Q4- For the reaction – 2Cl(g)→ Cl2(g), what are the signs of ΔH and
ΔS?
Q5-Give relation between Cp and Cv for an ideal gas.
Q6-Calculate the number of KJ of heat necessary to raise the temperature of
60.0g of aluminium from 350C to 550C.Molar heat capacity of Al is 24 J mol-1
K-1.
Q7-For oxidation of iron, 4Fe(s) + 3O2(g) → 2Fe2O3(s) entropy change is -
549.4 JK-1 mol-1 at 298 K.Inspite of negative entropy change this reaction,why is
the reaction spontaneous? ( ΔrH0 for this reaction is -1648x103 Jmol-1)
Q8-Calculate ΔrG0 for conversion of oxygen to ozone, 3/2 O2(g) → O3(g) at
298K.If Kp for this conversion is 2.47x10 -29.
Q9-The combustion of one mole of benzene takes place at 298 K and1 atm.
After combustion,CO2(g) and H2O(l) are produces and 3267.0 KJ of heat is
liberated. Caculate the standard enthalpy of formation, Δ fH0 of benzene.
Standard enthalpies of formation of CO2(g) and H2O(l) are -393.5 KJ mol-1 and
-285.83 kJ mol-1respectively.
Q10- Calculate the heat of combustion of ethylene (gas) to from CO 2 (gas)
and H 2 O (gas) at 298k and 1 atmospheric pressure. The heats of formation of
CO 2, H 2 O and C 2 H 4 are – 393.7, - 241.8, + 52.3 kJ per mole respectively.
Q11- Calculate the enthalpy change for the process
CCl 4 (g) → C (g) + 4Cl (g)
and calculate bond enthalpy of C – Cl in CCl 4 (g)
Δ vap H° (CCl 4 ) = 30.5 kJ mol -1
Δ f H°(CCl 4 ) = -135.5 kJ mol -1
Δ a H°(C) = 715.0 kJ mol -1 , where Δ a H° is enthalpy of atomisation Δ a
H°(Cl 2 ) =242 kJ mol -1
Q12- For the reaction-
2A (g) + B (g) → 2D (g) , ΔU° = -10.5 kJ and ΔS° = – 44.1 JK -1 .Calculate
ΔG°
Q13- The enthalpy of atomisation for the reaction CH 4 (g) → C(g) + 4H(g) is
1665 kJ mol -1 . What is the bond energy of C – H bond?

Q14- (a) For a reaction at 298 K

2A + B————->C ∆H = 400 kj mot1 and AS = 0.2 kj K mol-1.
At what temperature will the reaction become spontaneous considering ∆H and
∆S to be constant over the temperature range?
(b)When is the entropy of a perfectly crystalline solid zero?
Q-15

Q16-(a) How is a non-spontaneous process made spontaneous?

(b) What is the expression for entropy change for a phase transition?
Q17- Discuss the effect of temperature on the spontaneity of reactions.
Q18 -Find out the value of the equilibrium constant for the following reaction at
298 K. Standard Gibbs energy change, ΔrG° at the given temperature is – 13.6
kJ mol-1.
Q19- Calculate the standard entropy change for the reaction X ⇌ Y if the value
of ΔH° = 28.40 kJ and equilibrium constant is 1.8 × 10-7 at 298 K and ΔrG° =
38.484 kJ.
Q20- For the reaction X2Y4(I) → 2 XY2(g) at 300 K the values of ΔU and ΔS
are 2 kCal and 20 cal k-1 respectively. What is the value of ΔG for the reaction
?