K Bn

Ni(NH3) 630 110 0.1

Ni(NH3)2 170 11000
Ni(NH3)3 54 110000
Ni(NH3)4 15 1100000

pL=-log[L] fo=1/a=[M]/Cm f1=B1[L]fo f2=B2[L]*2fo f3=B3[L]*3fo f4=B4[L]4fo

[L] pL fo f1 f2 f3 f4
1 0 8.18926371E-07 9.00819E-05 0.00900819 0.0900819 0.90081901
0.1 1 0.002923976608 0.0321637427 0.32163743 0.32163743 0.32163743
0.01 2 0.301114122252 0.3312255345 0.33122553 0.03312255 0.00331226
0.001 3 0.891972258592 0.0981169484 0.00981169 9.81169E-05 9.81169E-07
0.00038 3.420216403 0.95841030348 0.0400615507 0.00152234 5.78489E-06 2.19826E-08
0.00001 5 0.998900110978 0.0010987901 1.09879E-06 1.09879E-10 1.09879E-14
0.000001 6 0.999890001101 0.0001099879 1.09988E-08 1.09988E-13 1.09988E-18
0.0000001 7 0.999989000011 1.099988E-05 1.09999E-10 1.09999E-16 1.09999E-22
0.00000001 8 0.9999989 1.099999E-06 1.1E-12 1.1E-19 1.1E-26
0.000000001 9 0.99999989 1.1E-07 1.1E-14 1.1E-22 1.1E-30
1E-10 10 0.999999989 1.1E-08 1.1E-16 1.1E-25 1.1E-34
1E-11 11 0.9999999989 1.1E-09 1.1E-18 1.1E-28 1.1E-38
1E-12 12 0.99999999989 1.1E-10 1.1E-20 1.1E-31 1.1E-42
1E-13 13 0.999999999989 1.1E-11 1.1E-22 1.1E-34 1.1E-46
1E-14 14 0.999999999999 1.1E-12 1.1E-24 1.1E-37 1.1E-50
1E-15 15 1 1.1E-13 1.1E-26 1.1E-40 1.1E-54
1E-16 16 1 1.1E-14 1.1E-28 1.1E-43 1.1E-58
1E-17 17 1 1.1E-15 1.1E-30 1.1E-46 1.1E-62
1E-18 18 1 1.1E-16 1.1E-32 1.1E-49 1.1E-66
1E-19 19 1 1.1E-17 1.1E-34 1.1E-52 1.1E-70
1E-20 20 1 1.1E-18 1.1E-36 1.1E-55 1.1E-74

PORCENTAJES
F0 F1 F2 F3
3.8*10^-4 100% 3.8X10^-4 100% 3.8X10^-4 100% 3.8X10^-4
3.96E-04 95.84% 9.49E-03 4.01% 2.50E-01 0.15% 6.57E+01
Sumatoria
1
1
1 DDE Ni2+ /NH3
1 1
1
0.9
1
1 0.8
1
1 0.7

1 0.6
1
1 0.5
1 0.4
1
1 0.3
1
0.2
1
1 0.1
1
0
1 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14
1
fo f1 f2 f3 f4

F4
100% 3.8X10^-4 100%
0.0005785% 1.73E+04 0.0000022%
/NH3

11 12 13 14 15 16 17 18 19 20

2 f3 f4
 K Bn
Ni(En) 33000000 11000000 0.1
Ni(En)2 1900000 1.1E+13
Ni(En)3 18000 1.1E+017

pL=-log[L] fo=1/a=[M]/Cm f1=B1[L]fo f2=B2[L]*2fo f3=B3[L]*3fo

[L] pL fo f1 f2 f3 Sumatoria
1 0 9.0900001E-18 9.999E-11 9.999E-05 0.99990001 1
0.1 1 9.0818272E-15 9.99001E-09 0.000999 0.99900099 1
0.01 2 9.0008912E-12 9.90098E-07 0.00990098 0.99009803 1
0.001 3 8.2637115E-09 9.090083E-05 0.09090083 0.90900826 1 1.2
0.00038 3.4202164 1.3108735E-07 0.0005479451 0.20821915 0.79123277 1
0.00001 5 0.00075700227 0.0832702498 0.8327025 0.08327025 1
1
0.000001 6 0.04327131112 0.4759844223 0.47598442 0.00475984 1
0.0000001 7 0.45246616684 0.4977127835 0.04977128 4.97713E-05 1
0.00000001 8 0.90000891099 0.0990009802 0.00099001 9.9001E-08 1 0.8
1E-09 9 0.98910892156 0.0108801981 1.08802E-05 1.08802E-10 1
1E-10 10 0.99890109891 0.0010987912 1.09879E-07 1.09879E-13 1
1E-11 11 0.999890011 0.0001099879 1.09988E-09 1.09988E-16 1 0.6
1E-12 12 0.99998900011 1.099988E-05 1.09999E-11 1.09999E-19 1
1E-13 13 0.9999989 1.099999E-06 1.1E-13 1.1E-22 1
0.4
1E-14 14 0.99999989 1.1E-07 1.1E-15 1.1E-25 1
1E-15 15 0.999999989 1.1E-08 1.1E-17 1.1E-28 1
1E-16 16 0.9999999989 1.1E-09 1.1E-19 1.1E-31 1 0.2
1E-17 17 0.99999999989 1.1E-10 1.1E-21 1.1E-34 1
1E-18 18 0.99999999999 1.1E-11 1.1E-23 1.1E-37 1
0
1E-19 19 1 1.1E-12 1.1E-25 1.1E-40 1 0
1E-20 20 1 1.1E-13 1.1E-27 1.1E-43 1

PORCENTAJES
F0 F1 F2 F3
3.8X10^-4 100% 3.8X10^-4 100% 3.8X10^-4 100% 3.8X10^-4 100%
2900 0.0000131 69.34 0.000548 1.8x10^-3 20.82% 4.8x10^-6 79.12%
 Andrés Job Méndez López
Estefania Cárdenas Lara

DDE NI2+/En
1.2

0.8

0.6

0.4

0.2

0
0 2 4 6 8 10 12 14 16

fo f1 f2 f3
14 16 18 20