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March 2023

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CONTENTS
March 2023 Volume 28 Number 03 ISSN 1468-9340
03 Guest comment 44 Racing to find the right separation
technology
05 World news Vic Scalco, General Atomics Electromagnetic Systems, USA,
details the importance of selecting the correct separation
10 American gasoline: conditional love technology in order to support growing petrochemical
Nancy Yamaguchi, Contributing Editor, examines changing demand.
production, price and demand in the US gasoline market.
51 Trays for mega towers
18 The next digital frontier: industrial Ang Chew Peng, Hou Peng-Cheng and Senthil Krishnamoorthy,
autonomous operations Sulzer, discuss various types of high-performance trays for
Praveen Sam, Honeywell, USA, introduces a novel digital large diameter propylene fractionators.
operating approach within the oil and gas industry.
59 Lessons in VDU performance
23 Digitalisation with a clearer view Jim Lines, Graham Corp., USA, lists the VDU ejector system
Mika Kulin, Neste, explains how the company’s refinery field lessons learned by a performance improvement
in Porvoo, Finland, is integrating its different digital engineer, through the lens of four specific case studies.
sources and automation systems into a single source of
information. 69 Time for a retrofit?
Nathan Hill, CALGAVIN, UK, discusses how to increase
27 Fending off threat product retention through retrofitting condensers.
Mike Hoffman, Dragos Inc., USA, discusses how refineries
can protect critical ICS/OT systems from cyberattacks. 73 Breaking down the barriers
Dennis Long, Watlow, USA, explains the role that electric
33 Building resilient infrastructure process heaters will have to play in the decarbonisation of
Leo Simonovich, Siemens Energy, USA, lists the important hydrocarbon processing.
steps to be taken in order to develop a more mature
cybersecurity posture. 79 Heater tube cleaning and verification
Tom Gilmartin, Zerosumheater and a consultant for
36 A step change in catalyst development Quest Integrity, considers the effect of fouling on heater
Mark Stuckey, UNICAT Catalyst Technologies LLC, discusses services, and introduces a new approach for confirming coil
the emergence of next generation spherical catalysts and cleanliness.
their impact on yield increases and reduced carbon dioxide
(CO2) emissions in tubular reformers. 85 Monitor, manage and minimise
Mark Naples, Umicore Coating Services Ltd, details how
connected gas detection technology can help companies to
comply with ESG needs.

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Copyright© Palladian Publications Ltd 2023. All rights reserved. No part of this publication may be reproduced,
stored in a retrieval system, or transmitted in any form or by any means, electronic, mechanical, photocopying,
recording or otherwise, without the prior permission of the copyright owner. All views expressed in this journal
are those of the respective contributors and are not necessarily the opinions of the publisher, neither do the
Follow Like Join publishers endorse any of the claims made in the articles or the advertisements. Printed in the UK.
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GUEST COMMENT
CONTACT INFO CHET THOMPSON
PRESIDENT & CEO, AMERICAN
MANAGING EDITOR James Little
FUEL & PETROCHEMICAL
james.little@palladianpublications.com MANUFACTURERS (AFPM)

I
SENIOR EDITOR Callum O'Reilly
callum.oreilly@palladianpublications.com n a tight refined product market – which is
ASSISTANT EDITOR Bella Weetch certainly how we would characterise much
bella.weetch@palladianpublications.com of the past two years – it has been US
SALES DIRECTOR Rod Hardy
refiners that have stepped up. Our industry
rod.hardy@palladianpublications.com ran full-out for most of 2022 making sure American consumers, our domestic
economic centres and our allies had enough gasoline, diesel and jet fuel to keep
SALES MANAGER Chris Atkin
chris.atkin@palladianpublications.com everyone moving. Our refining sector leads the world in liquid fuel production
and is effectively doing more than any other to bring better balance to the
SALES EXECUTIVE Sophie Birss
sophie.birss@palladianpublications.com global market.
This is a utilisation story. The US refining kit (which is how we refer to our
PRODUCTION MANAGER Kyla Waller
kyla.waller@palladianpublications.com collective refining machinery across nearly 130 refineries) is one of the two
largest in the world, with approximately 18 million bpd capacity. It is also the
EVENTS MANAGER Louise Cameron
louise.cameron@palladianpublications.com
most complex, which means we have the greatest capability to refine the
toughest types of crude oil.
EVENTS COORDINATOR Stirling Viljoen Our facilities process more crude oil every day than the US upstream
stirling.viljoen@palladianpublications.com
produces, and we make more finished fuels, collectively, than the US consumes.
DIGITAL CONTENT ASSISTANT Merili Jurivete For a kit of our size, to consistently have at least 90% of our refining muscle
merili.jurivete@palladianpublications.com
actively engaged in fuel production is a tremendous accomplishment, and
DIGITAL ADMINISTRATOR Leah Jones a testament to the men and women of our industry who maintain our
leah.jones@palladianpublications.com
facilities and keep them running safely. To say I am proud of their work is an
ADMIN MANAGER Laura White understatement.
laura.white@palladianpublications.com
Refineries regularly undergo maintenance, and every few years they undergo
CONTRIBUTING EDITOR larger scale ‘turnarounds’ where production is halted and up to 1000 specialised
Nancy Yamaguchi Gordon Cope workers – including engineers, electricians, pipefitters and steelworkers – come
in to inspect entire facilities, refurbish units and complete building projects. As
any veteran refiner will tell you, running full-out for as long as we have can be a
SUBSCRIPTION RATES source of wear and tear on facilities. And to maintain high utilisation rates when
Annual subscription £110 UK including postage the market was at its tightest, some facilities elected to reschedule planned
/£125 overseas (postage airmail).
Two year discounted rate £176 UK maintenance if that could be done safely.
including postage/£200 overseas (postage airmail). Safety is the key word. Everything we do in the refining industry begins and
SUBSCRIPTION CLAIMS ends with safety. While the US refining industry will continue to produce as
Claims for non receipt of issues must be made within 3 months of
publication of the issue or they will not be honoured without charge. much fuel as we safely can, there’s going to be some necessary dialing back for
maintenance. Of course, ‘dialing back’ is relative, because US refineries – even
APPLICABLE ONLY TO USA & CANADA
Hydrocarbon Engineering (ISSN No: 1468-9340, USPS No: 020-998) is while some facilities undergo maintenance – are still likely to maintain much
published monthly by Palladian Publications Ltd GBR and distributed
in the USA by Asendia USA, 17B S Middlesex Ave, Monroe NJ 08831. higher utilisation rates than the rest of the world and continue leading in fuel
Periodicals postage paid New Brunswick, NJ and additional mailing
offices. POSTMASTER: send address changes to HYDROCARBON
production.
ENGINEERING, 701C Ashland Ave, Folcroft PA 19032. Refinery upkeep is a good thing because maintenance is a long-term
investment in safe operations and will help us be ready, if needed, to run
full-out for extended stretches in the future. And as an industry of ‘planners’,
refiners also have arrangements in place before any turnaround starts to make
15 South Street, Farnham, Surrey sure customers have uninterrupted fuel deliveries.
GU9 7QU, UK Even while facilities are being maintained, global fuel supply and demand
Tel: +44 (0) 1252 718 999 will continue rebalancing with our contributions and with significant refining
capacity projects preparing to come online around the world. This next phase
of US refinery leadership in a reconfigured global market is sure to be one to
watch.
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WORLD NEWS
USA | EIA:
US refinery utilisation to average Denmark | Technip
more than 90% in 2023 and 2024 Energies awarded
FEED contract by
I n its February ‘Short-Term Energy
Outlook’ (STEO), the US Energy
Information Administration (EIA)
Global refined product prices and
crack spreads, which represent an
estimate of refinery margins, grew
Arcadia eFuels
forecast that US refinery utilisation
will remain similar to 2022, at above
90% over the next two years.
substantially in the US in 2022,
increasing refinery utilisation.
Slower economic growth is
T echnip Energies has been awarded
a FEED contract by Arcadia eFuels
for the world’s first commercial e-fuels
It is forecast that US refinery predicted in 2023 and 2024, which facility for sustainable aviation fuel (SAF)
utilisation will average 90.8% in 2023, would reduce gasoline and diesel production in Vordingborg, Denmark.
and then decrease slightly to 90.3% in consumption compared with 2022, Pre-FEED and early works recently
2024. leading to a gradual decrease in concluded, and the parties aim to
In 2020, average refinery utilisation petroleum product prices. support plant start-up in 2026.
dropped to 78.8%, the lowest annual It is also forecast that increased Arcadia eFuels will use renewable
rate since the EIA began collecting this production of finished petroleum electricity, water, and biogenic
data in 1997. However, by 2022, products as a result of high refinery carbon dioxide (CO2) to produce
utilisation rates averaged closer to utilisation rates will contribute to e-fuels that can be used in traditional
pre-pandemic levels at more than 91%. lower prices. engines and supplied to the market in
existing liquid fuel infrastructures.
Germany | First
Middle East LNG cargo The FEED covers the engineering of
the first e-fuels plant that will produce
successfully delivered approximately 80 000 tpy of e-jet fuel
and e-naphtha, using novel yet proven

A DNOC and RWE have announced


the successful delivery of the first
shipment of LNG from Abu Dhabi, UAE,
Middle East. This landmark cargo
follows the inaugural ammonia
shipment in October 2022, and
technologies. It also covers the
engineering of a 250 MW electrolyser
plant to produce green hydrogen. The
to the Elbehafen floating LNG terminal furthers cooperation on energy plant will be designed with a flexible
in Brunsbüttel, Germany. security, decarbonisation, and product slate to allow for the
Produced by ADNOC Gas at lower-carbon fuels between the UAE production of e-diesel. These fuels
Das Island, Abu Dhabi, the shipment and Germany. It also marks an allow airlines to cut carbon emissions
of 137 000 m3 of LNG is the important milestone in developing proportionally, therefore providing the
commissioning cargo for the new Germany’s domestic LNG supply ability for airlines and heavy
floating LNG terminal in Brunsbüttel, infrastructure, supporting the transportation to meet voluntary
and the first ever LNG cargo to be country’s energy security with carbon reductions and proposed EU
shipped to Germany from the natural gas. mandates for e-fuels use.

China | Shell Catalysts & Technologies to support CSPC Phase III

S hell Catalysts & Technologies


(SC&T) has announced that it will
provide its technologies and catalysts
new 1.6 million tpy cracker, creating
one of the world’s largest and most
flexible integrated complexes.
first time. The rest of the process
includes the Higher Olefins and
Derivatives (HODer) value chain.
to the China National Offshore Oil In Phase III, some of Shell’s “We are very pleased to further
Corp. (CNOOC) and Shell technologies will be deployed for the support the growth of CSPC which is
Petrochemicals Co. Ltd (CSPC) joint third time in CSPC with the latest a world-scale asset,” said
venture (JV) Phase III expansion. state-of-the-art designs in terms of Seng Yee Loh, Vice President Sales
Incorporated by CNOOC and Shell, energy efficiency, scale and flexibility. Asia Pacific, SC&T. “The collaboration
CSPC is one of the largest In addition, CSPC will build the with the local team will produce
petrochemicals JVs in China. Following largest linear alpha olefins (LAO) plant operational efficiencies and is
the success of the existing Phase I and II ever designed as part of a JV. The LAO expected to help bring economic
projects, CSPC Phase III will include a are being licensed from Shell for the benefits to the facility.”

HYDROCARBON 5 March 2023


ENGINEERING
WORLD NEWS
IN BRIEF Colombia | Ecopetrol
selects Honeywell
technology for carbon capture study
the netherlands
Sulzer has signed an agreement with
circular technology company, Fuenix Ecogy,
H oneywell has been selected by
Ecopetrol S.A. to develop a
pre-feed engineering study for a
capture CO2 from post-combustion
flue gases, which are more challenging
to treat due to the low CO2
to acquire a strategic stake in its plastic HoneywellTM Advanced Solvent concentration and low pressure
upcycling business. The partnership will Carbon Capture (ASCC) modular inherent in these sources.
drive the development, commercialisation demonstration unit, which will be The design target of the
and adoption of advanced, fully-integrated used to evaluate carbon dioxide demonstration unit is to capture
solutions for plastic waste processing. (CO2) capture from Ecopetrol fluid 30 tpd of CO2 from Ecopetrol FCC
catalytic cracking (FCC) units. flue gas. If implemented, the
FCC units are significant sources demonstration unit will provide
south korea of CO2 emissions, accounting for valuable information into the
LOTTE INEOS Chemical has announced plans 15 – 20% of overall emissions in a performance of this technology in
to increase vinyl acetate monomer (VAM) typical FCC-based refinery, including reducing FCC emissions, with
production capacity to 700 000 t with the Ecopetrol’s refineries. learnings that can be used to inform
addition of a third VAM plant. The new plant is Honeywell UOP’s ASCC deployment of commercial-scale
scheduled to start up by the end of 2025. technology has been designed to units in FCC service.

Belgium | INEOS secures financing for


canada Project ONE
Flowserve Corp. has reached an agreement

I
to acquire Velan Inc. in an all-cash transaction
NEOS Olefins Belgium has raised The plant also has the capability
valued at approximately US$245 million. The
€3.5 billion to support the to operate entirely with low-carbon
transaction is expected to close by the end of
construction and operation of hydrogen, and has room for a carbon
2Q23.
Project ONE. capture facility and future electric
This is the largest investment in furnaces.
europe the European chemical sector for a
generation. The new cracker, located
Jason Meers, CFO INEOS
Project ONE, said: “Project ONE is a
Neste and Wizz Air have agreed on the supply in Antwerp, Belgium, will have the game changer for Europe. It will
of Neste MY Sustainable Aviation FuelTM from lowest carbon footprint in Europe bring new opportunities to the
2025 onwards. The agreement gives Wizz Air – three times lower than the average chemical cluster in Antwerp as well
the opportunity to purchase 36 000 tpy of European steam cracker, and less than as strengthen the resilience of the
Neste-produced sustainable aviation fuel (SAF) half that of the 10% of best whole of the European chemical
over a period of three years for the airline to performers in Europe. sector.”
use across its route network in Europe and the
UK.
Europe | Growing LNG demand to intensify
competition with Asia
china
E
Venture Global LNG and China Gas Holdings urope’s increased need for LNG withstand a slump in Russian pipeline
Ltd have announced that the wholly-owned looks set to intensify competition gas imports following its invasion of
subsidiary, China Gas Hongda Energy with Asia for limited new supply Ukraine. A 15 million t fall in Chinese
Trading Co. Ltd, and Venture Global LNG available over the next two years, and imports, combined with reduced
have signed two 20-year LNG Sales and may dominate LNG trade over the imports by South Asian buyers, helped
Purchase Agreements (SPA). Under the longer term, according to Shell’s European countries to secure enough
deals, China Gas will buy 1 million tpy of ‘LNG Outlook 2023’. gas and avoid shortages. Europe’s
LNG on a free on board (FOB) basis from European countries, including the rapidly rising appetite for LNG pushed
Plaquemines LNG, and another 1 milion tpy UK, imported 121 million t of LNG in prices to record highs and generated
from the CP2 LNG export facility – both of 2022, an increase of 60% compared to volatility in energy markets around the
which are located in Louisiana, US. 2021, which enabled them to world.

March 2023 6 HYDROCARBON


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WORLD NEWS
DIARY DATES The Netherlands | Shell
and Hapag-Lloyd sign
multi-year LNG supply agreement
19 - 23 March 2023
AMPP Annual Conference & Expo
Denver, Colorado, USA
ace.ampp.org
S hell Western LNG B.V and
Hapag-Lloyd have announced the
signing of a multi-year agreement
Hamburg (Germany), Singapore, and
Shanghai (China).
Shell and Hapag-Lloyd have also
for the supply of LNG to entered into a strategic collaboration
26 - 28 March 2023 Hapag-Lloyd’s ultra-large dual-fuel agreement intended to accelerate
AFPM International Petrochemical Conference container vessels of 23 500+ 20 ft the further decarbonisation of
San Antonio, Texas, USA equivalent units (TEU). alternative marine fuels. Initial focus
afpm.org/events/IPC23
Bunkering for these 12 new will be given to developing the
12 - 14 April 2023 vessels is expected to commence potential of additional low-carbon
25th International Aboveground Storage Tank during 2H23, and LNG will be fuel solutions including liquefied
Conference & Trade Show supplied in the Port of Rotterdam, biomethane and the
Orlando, Florida, USA the Netherlands. hydrogen-based fuel, liquefied
www.nistm.org The modern ships will be e-methane. Liquefied biomethane as
deployed on Europe-Far East routes a marine fuel has the potential to
25 - 27 April 2023 and call at major ports including reduce greenhouse gas emissions by
Sulphur World Symposium
Rotterdam (the Netherlands), between 65 – 100%.
Edinburgh, Scotland
www.sulphurinstitute.org/symposium-2023
USA | ExxonMobilto utilise Topsoe
08 - 12 May 2023
RefComm
technology for hydrogen facility
Galveston, Texas, USA
events.crugroup.com/refcomm

22 - 24 May 2023
T opsoe has announced that it will
deliver technology to
ExxonMobil’s planned low-carbon
reduce the integrated complex’s
carbon dioxide (CO2) emissions by
up to 30%.
ILTA 2023 International Operating Conference and hydrogen production facility in To produce the large amount of
Trade Show Baytown, Texas, US. hydrogen needed by ExxonMobil,
Houston, Texas, USA
www.ilta.org
ExxonMobil’s low-carbon Topsoe will apply its SynCORTM
hydrogen, ammonia, and carbon technology, which enables mega-scale
07 - 08 June 2023 capture facility is expected to hydrogen production as well as
Valve World Americas Expo & Conference generate up to 1 billion ft3/d of cost-efficient carbon capture.
Houston, Texas, USA hydrogen, delivering low-carbon fuel As technology integrator, Topsoe
www.valveworldexpoamericas.com to the Baytown olefins plant and will guarantee the carbon intensity of
other Houston-area facilities. the integrated low-carbon facility, as
07 - 08 June 2023 Replacing natural gas with hydrogen well as hydrogen production and
Downstream USA 2023
at the Baytown olefins plant could carbon capture.
Galveston, Texas, USA
events.reutersevents.com/petchem/downstream-usa
USA | Freeport LNG to restart operations
13 - 15 June 2023

F
Global Energy Show reeport LNG Development L.P. The restart and return to service
Calgary, Alberta, Canada
www.globalenergyshow.com
has announced that it has of Freeport LNG’s third liquefaction
received regulatory approval to train will require subsequent
10 - 13 July 2023 commence commercial operations regulatory approval once certain
LNG2023 of its natural gas liquefaction and operational conditions are met. A
Vancouver, British Columbia, Canada export facility. conservative ramp-up profile to
www.lng2023.org This authorisation provides for establish three-train production of
the immediate full return to service approximately 2 billion ft3/d is
05 - 08 September 2023 of one liquefaction train that has anticipated to occur over the next
Gastech
already restarted, and the several weeks as stable operation of
Singapore
www.gastechevent.com incremental restart and full return to each incremental train is established
service of a second train. and maintained.

March 2023 8 HYDROCARBON


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Nancy Yamaguchi, Contributing Editor, examines changing
production, price and demand in the US gasoline market.

March 2023 10 HYDROCARBON


ENGINEERING

Americans love gasoline” is a statement that has been during the summer 2022 driving season. Consumers generally
accepted as a fundamental, evolving from images of a find it easier to adjust to gradual increases in fuel prices than
car-crazy culture enjoying the freedom of a vast to cope with sudden price spikes. The optics have not been
country and the wide-open road. With gasoline helped by the fact that the major oil companies are reporting
demand at approximately 8.8 million bpd, the US is the record-high profits, which were projected to be over
largest market in the world. For comparison, Europe in its US$200 billion in 2022.
entirety consumes only around 1.9 million bpd of gasoline. Yet From the standpoint of ‘Greedy Big Oil’, the US is an
American love for gasoline is not unconditional. Today, a essential market, and the goal is to keep it a profitable one.
more correct statement would read along the lines of The US refining industry evolved largely to produce gasoline
“Americans love cheap, plentiful gasoline, with reduced for US consumers, and the presence of this massive
emissions, in formulations specific to their locations, seasons, consumer base helped it to become the largest and most
and vehicles, with loyalty programmes and clean convenience sophisticated in the world. It is a close, symbiotic relationship,
stores, perhaps from sellers less aligned with Greedy Big Oil.” but also one where both parties take the other for granted,
Recent years have brought extreme volatility to the and have other interests.
gasoline market, bringing back memories of past price spikes Current energy prices are a key contributor to overall
and reviving consumer dissatisfaction. COVID-19 lockdowns price inflation. The US Bureau of Labor Statistics (BLS)
forced a massive collapse in demand, followed by an oil price reported a jump of 29.3% in Consumer Price Index (CPI)
crash. Recovery came in fits and starts, hobbled by supply energy prices in the December 2020 – December 2021 period,
chain problems, waves of COVID-19 variants, rising prices, and declining to 7.3% in the December 2021 – December 2022
inflationary pressures. Then, Russia invaded Ukraine in period. The COVID-19 pandemic caused a huge
February 2022, contributing to record-high gasoline prices collapse-rebound cycle, the impacts of which are still

HYDROCARBON 11 March 2023


ENGINEERING
affecting the market. Additionally, the Russia-Ukraine war 2018 and 2019, before the COVID-19 pandemic prompted a
constrained supply just as demand was rising. This article will drop to 8.742 million bpd output in 2020.
focus on the US gasoline market, examining production, price Yet, while the US industry can easily achieve a 47 – 48%
and demand, and noting how the market is changing. yield of gasoline, there has been a shift away from gasoline
maximisation. In its continual quest to optimise refinery
A gasoline-maximising industry shifts operations, the industry has cut output of low-value fuel oil
away from gasoline and other products, reducing their yield from 13.7% in 2004 to
Serving the world’s largest gasoline market motivated the 9.64% in 2022. This represents an average drop in yield of
US refining industry to invest in a massive amount of -1.9%/yr between 2004 – 2022. In recent years, the focus on
gasoline-oriented technology. Figure 1 compares the ratios maximising gasoline output has also shifted. Gasoline’s
of three key gasoline-maximising technologies with crude percentage yield of output fell modestly, at a rate of -0.1%/yr
distillation unit (CDU) capacity in the US vs the rest of the between 2004 – 2022. In 2004, gasoline accounted for 46.8%
world. In the US, the alkylation to CDU ratio is 6.1%, relative of refinery yield. In 2022, this share declined to approximately
to 1.4% in the rest of the world; catalytic reforming to CDU 46.1%. Yields of kerosene-based jet fuel also declined at
ratio is 18.3%, vs 9.6% in the rest of the world; and catalytic -0.1%/yr between 2004 – 2022. In contrast, the new focus has
cracking to CDU is 28.8% in the US, vs 13.9% in the rest of been on increasing the yield of diesel. Diesel accounted for
the world. 23.9% of output in 2004, and this grew to 30.27% in 2022. This
These technologies helped the US industry to achieve and amounts to an increase in yield of 1.3%/yr on average
maintain an exceptionally high yield of gasoline – the largest between 2004 – 2022. In volume terms, US refiners are
output in the world. Figure 2 shows US refinery yield of producing approximately 1.17 million bpd more diesel than
gasoline since 1993. The yield has ranged from a low of 44.2% in they were in 2004. In 2000, the US was a modest exporter of
2008 to a high of 47.8% in 2021, and it averaged approximately diesel. In 2022 (January – October average), US diesel exports
46.1% in 2022. In volume terms, US refiners and blenders (who had surged to over 1.2 million bpd of diesel, and imports had
finish gasoline-ethanol blends) produced 9.529 million bpd of essentially vanished.
gasoline in 2021, and an estimated 9.574 million bpd of gasoline US refineries are therefore increasingly looking to export
in 2022. Production records of over 10 million bpd were set in markets, and the incremental barrel of crude processed is
processed for export. After years of being a
significant importer of gasoline and gasoline
blending components (GBC), the US has now
transitioned into a net exporter of these materials.
Figure 3 depicts this dramatic shift. In 2000, the US
imported approximately 650 000 bpd of gasoline
and GBC, while exporting 162 000 bpd. Imports
grew to 1.166 million bpd in 2007, while exports
remained flat. As will be discussed in the following
section, oil prices spiked in 2008, and the
Great Recession followed. Gasoline and GBC
imports fell, and exports rose as refiners tried to
cope with burgeoning inventories. Since then,
imports have bumped along in the range of
600 000 – 800 000 bpd, while exports have
continued to grow. In 2016, the two lines crossed,
Figure 1. US refineries focus on gasoline-oriented technologies. and the US became a net exporter of gasoline and
GBC, with exports averaging 932 000 bpd, and
imports averaging 645 000 bpd.
When confronted with high oil prices,
consumers may look at exports with suspicion,
positing that these excess supplies should be sold
at discounted prices in the domestic market rather
than being exported. This is not rational behaviour
for a for-profit company. As domestic demand
stagnates and production rises, exports have risen
for nearly all petroleum products. Crude oil exports
have also risen, particularly in places where
pipelines are available to deliver crude oil to coastal
export terminals. Balancing supply and demand in
the US has always required two-way trades, but in
recent years export markets have become a key
Figure 2. US refinery gasoline yield, % (source: EIA). determinant of the last barrels produced and
processed.

March 2023 12 HYDROCARBON


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Volatility in gasoline prices Figure 4 charts the course of retail gasoline prices over
US consumers sometimes overlook the fact that gasoline the 18-year period from January 2005 through to January 2023
prices are strongly moved by crude oil prices, and that pump (data as of the week of 30 January 2023). The price spike
prices will be influenced by geopolitics. The US Energy experienced in the summer of 2008 brought retail gasoline
Information Administration (EIA) calculated that, in prices to all-time highs of US$4.11/gal. in July. The
December 2022, the national average retail gasoline price was Great Recession in 2007 – 2009 was named the second-worst
US$3.21/gal., and the components of this price were: economic crisis in US history. Gasoline prices collapsed to
nn 58% crude oil cost. lows of US$1.61/gal. in December 2008; unemployment rates
nn 9% refining cost. hit 10% in 2009 – the highest since the Great Depression,
nn 18% distribution and marketing cost. when unemployment rates were estimated at over 24%.
nn 16% taxes. Gasoline prices recovered to the US$2 – 3/gal. range in
2010 – 2011, before surging again to the US$3 – 4/gal. range in
In the US, crude oil prices have a relatively stronger 2011 – 2014, pushed up by economic recovery and strong
influence on pump prices because fuel taxes are low by the demand for oil, particularly in the US and China. Conflict in
standards seen in other OECD countries. The US average the Middle East and Africa constrained the supply side, which
pump price cited includes 16% tax; however, many further bolstered prices.
countries face much higher tax burdens – as high as 50% or Demand growth waned, and the supply side received a
even 75%. A number of European consumers marvel at the surprise when the success of US hydrofracking created a
fact that US consumers find prices of, say, US$4/gal. major rebound in US crude production. Crude prices began
excessive, when they may pay twice this amount. to slide when Saudi Arabia launched its oil price war,
Nonetheless, consumers grow accustomed to what is intending to drive out some of the higher-cost producers.
normal in their own markets, and they assess price swings Prices dropped sharply when sanctions on Iran were lifted.
from their own baseline. Retail prices for gasoline fell below US$3/gal., and did not
recover. COVID-19 lockdowns caused another price
crash in 2020, with prices bottoming out at
US$1.77/gal. in April 2020. It took over a year for
prices to creep back to the US$3/gal. level.
From there, however, post-pandemic economic
recovery was underway, plagued by supply chain
issues. Prices began to climb; inflationary pressures
mounted. According to the BLS, the December 2020
to December 2021 period brought an overall CPI
increase of 7%, with gasoline showing the highest
jump at 49.6%. In 2022, the gasoline CPI fell -1.5%,
bringing some consumer relief, though the CPI for all
items rose 6.5%. In 2022, one of the largest jumps was
seen in airline fares, which rose 28.5%.
Russia’s invasion of Ukraine in early 2022 caused
more market upheaval, and this long-lasting war is
Figure 3. US exports of gasoline and gasoline blending
components, ‘000 bpd (source: EIA). creating untold misery in Europe, where many
consumers are facing a cold winter with high fuel
prices. In the US, gasoline prices spiked to a new
record-high of US$5.01/gal. during the summer
driving season of 2022. Although gasoline prices
retreated to below the US$4/gal. mark, they
trended up during January 2023, and it appears likely
that the 2023 summer driving season could see
prices back in the vicinity of US$4/gal. Consumers
widely perceive prices to be too high, particularly
when contending with what the BLS reports as 2022
CPI increases of 10.4% in food prices, 14.3% in
electricity prices, 19.3% increases in piped natural gas
prices, 8.3% increases in rent, and 28.5% increases in
airline fares. As will be discussed in the following
section, demand has not bounced back.

Gasoline demand flattens and


Figure 4. US retail gasoline price, all regular formulations, falls
US$/gal. (source: EIA). US consumers are feeling the impacts of high fuel
prices and inflation, and a number have felt

March 2023 14 HYDROCARBON


ENGINEERING
powerless as price-takers in the gasoline market. For many, for gasoline from 1960 through to the January – October
gasoline is an essential commodity; switching away is not period of 2022. Demand grew swiftly from 1960 until the
always possible in the short-term. However, each successive Arab Oil Embargo of 1973 – 1974. Demand recovered quickly
price shock has flattened the upward trajectory of demand until the Iranian Revolution in 1979 – 1980, cutting demand
recovery that followed. Figure 5 presents US annual demand once again. US gasoline demand fell from 7.412 million bpd in
1978 to 6.539 million bpd in 1982.
By the mid-1980s, oil prices collapsed, and
demand growth picked up, peaking at
9.286 million bpd in 2007 before the price spike of
2008 and the Great Recession. It then climbed back
to 9.329 million bpd in 2018 and 9.309 million bpd in
2019. COVID-19 then caused a collapse to
8.049 million bpd in 2020 – a loss of 1.28 million bpd.
Demand has not recovered to its pre-pandemic
levels, and the author estimates that 2022 demand
will be 8.755 million bpd.
It is entirely possible that US gasoline demand
will never again recover to the 9.3 million bpd level
seen in the pre-pandemic years. Although the US
will remain the world’s largest gasoline market for
Figure 5. US product supplied of finished motor gasoline, the foreseeable future, the rates of demand growth
‘000 bpd (source: EIA. 2022 is the author’s estimate). have slowed, and have gone negative in recent
years, as illustrated in Figure 6. During the 1960s,
gasoline demand grew robustly at rates averaging
3.8%/yr. The 1970s brought two oil price shocks, and
demand growth rates fell to 1.3%/yr. The downturn
extended into the 1980s, when growth rates
averaged 1.0%/yr. By the mid-1980s, oil prices fell.
During the 1990s, gasoline demand grew at a strong
rate of 1.6%/yr. This was slashed to 0.6%/yr during
the decade 2000 – 2010, which included the
Great Recession.
The 2010 – 2020 decade included the COVID-19
pandemic, and demand for gasoline shrank at an
average rate of -1.1%/yr. The author estimates that
between 2019 – 2022, US gasoline demand shrank
by -2.0%/yr.

Alternatives to gasoline
Switching away from gasoline is a slow process, but
Figure 6. US gasoline supplied, annual growth rates by decade, % it appears that the US has turned the corner.
(source: EIA, and author’s estimate of 2022). Demand has fallen, and Corporate Average Fuel
Economy (CAFE) standards are also having a
sustained impact on cutting fuel use and emissions.
The government of President Biden is vigorously
promoting clean energy technologies and moving
to reduce carbon emissions.
Alternative fuels are picking up pace. The
Alternative Fuels Data Center (AFDC) tracks the
number of fuelling stations each year for
alternatives including propane, methanol, LNG,
CNG, hydrogen, biodiesel, E85 and electric, shown
in Figure 7. Over the years, these alternatives have
contributed to the fuel mix, and many forecasts
expected strong if not spectacular growth across
the board. However, a number of these alternatives
did not flourish, and some seemed to compete
Figure 7. US alternative fuelling stations by type with each other rather than with gasoline. Methanol
(source: Alternative Fuels Data Center). in its M85 blend has vanished; a hydrogen economy
has not materialised; LNG as a transport fuel has

March 2023 16 HYDROCARBON


ENGINEERING
stagnated; propane use has dwindled. Modest growth has
been achieved in stations dispensing CNG and biodiesel.
E85 (blends of approximately 85% ethanol and 15%
OGT | ProTreat®
gasoline) stations have shown recent growth. In contrast,
electric vehicle (EV) charging plugs have emerged in droves,
Process Simulation
and their numbers exceed all others by orders of
magnitude. In 1995, AFDC reported 188 electric charging
stations. In 2021, this number had skyrocketed to 128 474.
There are several alternatives to gasoline, but the
technological and economic advances in EVs have been

n T
astounding, while many other options have failed to gain
traction. The Biden Administration has set a goal to ensure
that 50% of all new passenger cars and light trucks sold in
2030 are EVs. ve e

Pro

ch
Conclusion: a new phase in the
consumer-gasoline relationship

nol
Same
Gasoline is a valuable commodity; a single gallon of this
energy-dense liquid can propel a car and driver for
30, 40 or even 50 miles, in vehicles that are safe and

ogy
comfortable, cool in summer, warm in winter, wherever
and whenever the driver wishes to go. What is all of that
freedom and convenience worth? In some countries, such
as Venezuela and Libya, government subsidies keep
gasoline prices absurdly low – pennies per gallon. In other
countries, governments place hefty taxes on gasoline to
control consumption, and prices may be US$6 – 8/gal., or
higher. In the US, prices are currently under US$4/gal. – well
below all other OECD countries. Yet many consumers
consider prices of US$4 – 5/gal. too high.
Gasoline producers and consumers are interdependent,
but high prices to consumers, when coupled with
record-high profits to oil companies, have heightened
public resentment – despite the fact that the lion’s share of
profits are being made in upstream petroleum, not in
refining and marketing. During the Great Recession and
COVID-19 lockdowns, for example, many refineries suffered
N ow w

negative margins. At the retail marketing level, the

nts
National Association of Convenience Stores (NACS)
s
N ow

reported that 60% of the convenience stores selling fuel


t

were owned by single-store operators rather than big oil


lven

companies. Many of these operators consider themselves


olve
fuel-neutral, and believe that their interests are more
closely aligned with consumers than producers. Price spikes
can squeeze the profits of a single-store operator. It takes a
it h
w it

very patient consumer to listen to these points, however,


So

when confronted with high prices and a possible recession


dS

H y ri
in 2023.

y b ri
The relationship between the American consumer and
h

H
d

gasoline is changing. From the price spikes of the 1970s until

b
now, each wave of demand recovery has been more
sedate. The existing fleet is more efficient and less
polluting; and more alternatives have emerged –
particularly EVs. COVID-19 has popularised remote work,
making it a permanent fixture. Refiners are thinking of
export markets for their marginal barrels of output. Perhaps
the relationship between gasoline producers and
consumers is a mature one, and both parties are pursuing
new interests. US gasoline demand may be on its way to a Optimized Gas Treating, Inc
long, slow decline, but not a farewell. 212 Cimarron Park Loop, Buda, TX 78610
www.ogtrt.com +1 512 312 9424
March 2023 18 HYDROCARBON
ENGINEERING
Praveen Sam, Honeywell, USA, introduces a novel digital
operating approach within the oil and gas industry.

W
e live in a world that continues to change and through self-learning capabilities. These systems and
adapt to different industrial, technological, processes will be bound by guardrails of cybersecurity, safety
political and social realities. As a result of these and reliability, which will be built with explainable artificial
changes, the oil and gas industry will inevitably intelligence (AI) systems that utilise multiple simulation
need to adapt. The industry is responding to unprecedented models serving as digital twins. Together, this will bring the
levels of change driven by factors such as an increased focus next step change for industry, unlocking benefits that current
on improving sustainability, new economic realities, and digital capabilities do not support by intelligently, reliably and
adapting to the future of the workforce. securely closing the loop with people and systems.
As such, it is important to rethink the role of industrial
digital transformation, which is now expected to deliver the Setting objectives for the next digital
next step change in ensuring safety, improving sustainability frontier
and reliability, enabling people, and increasing margin The next frontier in industrial digital transformation will be
predictability. Making this a reality requires a shift towards the move towards intelligent and autonomous operations.
industrial autonomous operations. Industrial autonomous operations will provide a step change
in how the oil and gas industry can create its digital future.
Envisioning industrial autonomous Over the past 40 years, some of the defining moments in the
operations digital evolution of the industry include the adoption of
Industrial autonomous operations is a vision for the future, automation systems and manufacturing execution systems,
where functions in operations embed higher levels of the implementation of applications such as advanced process
intelligence and close the loop with people and systems. This control, and the use of enterprise resource planning systems.
will enable people to focus on higher-level tasks. Although Currently, we are in a phase of broader adoption of cloud
the industry has not reached the highest level of full and AI/ML technologies as more use cases become scalable.
autonomy, technology advancements have provided a good The next major step will be closing the loop between
set of ingredients to allow for autonomous operations. intelligence displayed on a software application and an action
Automation and control systems in a closed loop are through either people or systems. This will allow the industry
becoming pervasive, and they continue to be to envision higher targets for digital transformation. These
complemented by different software-enabled capabilities include:
such as advanced process control, alarm management, asset n Zero-harm operations that keep people away from harm,
performance management, and remote monitoring. As predict operational risk, and ensure the integrity of
automation and control systems move closer towards operations.
software and converge, current advances in cybersecurity, n Significant sustainability improvements, achieved by
self-learning intelligent systems, and digital twins allow for maximising efficiencies or supporting new products such
increased autonomous operations. as renewable fuels.
With industrial autonomous operations, systems and n Maximising human potential by allowing people to focus
processes will have increased adaptive capabilities enabled on higher-level tasks.

HYDROCARBON 19 March 2023


ENGINEERING
nn Unlocking additional margin by optimising across a much technologies continue to mature, they also become more
broader envelope. affordable, secure, and capable of faster value realisation.
nn Eliminating unplanned downtime, made possible by
prevention of failures or autonomous recovery. The need for industrial-grade software
The road to an intelligent, autonomous future will require a
Accelerated innovation in the last decade has allowed us change in how software is built. Industrial autonomous
to create a path toward achieving this vision. As digital operations require industrial-grade software, which adds
greater levels of trust, safety and reliability to software. This
predictability is needed for autonomous operations. Some of
the ingredients that make industrial-grade software are:
nn Zero-trust cybersecurity: cybersecurity must move to a
higher level of zero-trust whereby implied trust within
each interaction is eliminated, and verification is built at
each interaction.
nn Explainable AI: AI provides intelligence, but autonomy
requires AI to be self-learning in order to adapt to
changes in the world over its life cycle. AI should also
be explainable, as workers need to know why AI does
what it does in order to let it autonomously control.
Similarly, AI-enabled actions should always be safe and
reliable.
nn Digital twins: digital twins support deep learning for new
Figure 1. Safety and people first: technologies such AI models, and provide for verification before
as drones and robots will ensure safety and elevate implementation. They can also evaluate many what-if
workers to focus on higher-level tasks. scenarios to verify safety and expected results, before
recommending or performing controlling actions.
nn Secure integration with machines: software must also be
able to safely integrate with smart machines such as
control systems, robots, drones and other systems.
nn Openness and interoperability: software must embrace a
nature of being open, vendor-agnostic, and interoperable
in order to allow industries to maximise their existing
investments in multiple systems.

Opportunities for the industry


The future of autonomous operations is a vision that should
not be relegated to the impossible, or an all-or-none
ultimatum. Several aspects of industrial autonomous
operations have already been implemented, and have
Figure 2. Closing the loop between man and machine:
the next frontier in industrial digital transformation generated value for the industry. Opportunities for applying
will be the move towards intelligent autonomous autonomous operations include:
operations. nn Remote operations: decoupling the need for a physical
presence near the control system or at any part of the
operation is a big step forward – enabling control
remotely, digitally enabling and connecting field
workers with the control room, and permitting
execution away from the control room.
nn End-to-end optimisation: scaling optimisation from a
single unit to multiple sites through integration with
economic planning and scheduling allows for the
achievement of a much broader optimisation envelope.
Plantwide Optimizer is a proven technology in the
market that empowers autonomous operations with
intelligent closed-loop optimisation.
nn Enterprise intelligence: setting the foundation for
closing the loop between man and machine, industrial
Figure 3. Remote operations: decoupling the need for analytics deliver production insights at an enterprise
a physical presence, and connecting field workers so
that actions can be executed away from the control scale, which delivers real-time monitoring of operations
room, is a big step forward. and analysis of multiple what-if scenarios to support
decision making.

March 2023 20 HYDROCARBON


ENGINEERING
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Keeping people at the centre
Moving towards autonomous operations is a journey.
This journey is human-centric and should not be viewed
as a means to replace people. It allows us to rethink the
future of work in the industry and adapt to changing
workforce realities. As the industry continues to struggle
with rebuilding lost expertise, worker enablement
provides support for the emerging workforce through
greater degrees of human inclusion, and elevates the
current workforce to focus on higher-level tasks.
Leaders who embark on a journey of autonomous
operations must continuously embrace a human-centric
approach.

Where to begin?
Realising value through intelligent operations requires a
shift in mindset and the execution of a structured plan. In
addition to setting targets for digital transformation,
leaders should take the following steps:
nn Prioritise the right function to prove value with
autonomous operations: prove value with a
digitally-mature use case of high business value.
Opportunities such as end-to-end process
optimisation or closing the loop with economic
planning and scheduling demonstrate results that can
create interest in attaining even higher objectives.
nn Create an organisational foundation with supporting
policies and practices: adapt organisational policies
and digital practices to support industrial
autonomous operations. Carefully designing
organisational roles and responsibilities, security and

The leader in
audit policies, safety functions, and technology
governance are necessary practices.
nn Create a technology foundation with industrial-grade

Energy Optimization. software: while industries can reuse most of their


technology investments, leaders must strategically
rethink the need to adopt new capabilities.
GEA means worldwide recognized evaporation, Capabilities such as OT cybersecurity, explainable AI,
crystallization and distillation plants, in-house monitoring for AI, and managing digital twins must be
R&D facilities, vast know-how and expertise. set up to ensure reliability of closed-loop functions.
We develop and design multi-stage, TVR & MVR nn Continue to keep people at the centre and organise
heated plant concepts tailored to your specific for change: everyone should be taken along as part
needs. of this journey toward autonomous operations.
Managing change for people, supporting them
through new processes, and elevating them towards
higher-level tasks is necessary to ensure the
long-term success of autonomous operations.
Get in touch today at nn Build the right governance and guardrails: increasing
gea.com/contact levels of AI and self-learning capabilities will require
proper governance and guardrails to manage safety
and reliability, including organisational practices that
monitor the health and functioning of all AI systems.

Honeywell is building towards industrial autonomous


operations with industrial-grade software that profitably
improves safety, sustainability and productivity. The
company brings learnings through its experience in
shifting the industry towards greater levels of
autonomous operations, and can effectively help drive
this transformation.
Mika Kulin, Neste, explains how the company’s refinery in
Porvoo, Finland, is integrating its different digital sources and
automation systems into a single source of information.

I
n 2019, Neste Corp. started to further develop the digitalisation of its refinery
in Porvoo, Finland. The refinery is in the Kilpilahti industrial area, which is the
biggest chemical industry consortium in the Nordics. Its production capacity is
approximately 12.5 million tpy, with the most important products being
transportation and marine fuels, and base oil. It employs some 1000 people.
It is a very complex plant comprised of four production lines and more than
40 production units, including two units that produce renewable diesel made
from different types of waste. As a single product can have tens of different
qualities, the refinery requires a high level of digitalisation and skilled personnel to
enable efficiency.

High level of digitalisation


The refinery already had a high level of digitalisation and automation before the
new project, Nappi, started up three years ago. The problem was that, for example,
data from the processes, the material flow and the laboratory were split on
different systems, making it hard to obtain an overall view of what was going on at
the different process stages, and to optimise the process at any given time.
When the project started in 2019 it was like a ‘digitalisation rehearsal,’ carried
out as an agile development process in incremental steps. By not having a
predetermined goal for the project, and by continuously listening to the end users,

HYDROCARBON 23 March 2023


ENGINEERING
it was possible to smoothly adjust the solutions according enables more efficient communication within the refinery,
to the input from operators and other staff involved. which in turn leads to continuous performance
The overall goal for the ongoing project is to provide improvements.
the operating personnel, refinery management and supply
chain management with new tools to monitor and adjust Gaining popularity
the processes according to changes in feedstock qualities, An example of how Nappi has evolved over time is that
product requirements, and laboratory readings, the system’s main screen has changed from a view with a
for example. lot of subgroups that was comprehensive but quite difficult
The project started with the panel operators and the to navigate, to a view now consisting of only a few
shift managers in mind, and in the beginning around dropdown menus and two important gauges: the refinery’s
200 people had access to Nappi. Now, the system is utilisation rate, and the number of production key
expanding within the refinery; it has more than 500 users, performance indicators (KPIs) alarming. More precise data is
and this number is rising. then available through the expandable menus beneath the
gauges, where the user can dig into the flows, qualities,
More transparent process scheduled targets, production constraints, blending
Neste has put a lot of effort into digitalising the refinery’s performance and analysers.
process during the last few decades, using state-of-the-art It is now easy for any user to choose only the required
tools to optimise the different processes in a number of information. Initially, Nappi was about providing data for
ways. One of the key suppliers of the software solutions end users, but further development has made it possible for
used at the refinery is NAPCON – a company that end users to write data back into the system. Plant
specialises in solutions for the process industry, and is also engineers are now using Nappi to inform users of changes in
managing the Nappi project. capacity constraints. These background comments enable
The problem was that although all of the systems at the organisation-wide learning. The simplified screen is a result
refinery continuously collected a lot of information and of the fact that the users could offer their input throughout
were great tools for running production, they lacked the project’s progress. Now, it is also possible for
transparency. As such, Neste decided to develop a kind of development ideas to be added into the system through a
parachute system that was able to show a large amount of dedicated menu – a feature that is being used increasingly.
relevant data in a single view that could be expanded when A fundamental consideration when developing Nappi is
needed, and was accessible to anyone involved in that the use of the system is totally voluntary. When
production at the refinery. analysing its usage over a period of two years, it is striking
The term ‘agile’ is the key word in the process, as the how this has constantly grown as new features have been
project is light-footed and open to new ideas at any point introduced to meet the exact needs of the users. This
during the course of the process. By involving operators and demonstrates the strength of agile development compared
other potential end users at the refinery from day one, it to normal, large digitalisation projects with slow feedback
was possible to change direction immediately if the users circles.
felt that the selected path did not live up to the real needs.
This means that Nappi is not just another refinery Complex facility
digitalisation programme; the key thing is the organisational As mentioned, the refinery is a complex plant, producing a
change that the system enables. In essence, the system is an number of different products – from gasoline and diesel, to
online platform that provides real-time situational base oil and renewable diesel. As the product mix is not
awareness, enabling the whole organisation to be more based on four product lines producing strictly one quality
efficient, and making it possible to react quickly to changing each, but rather four production lines sharing the same
market needs, for example. assets while producing several different products, the
system forms a complex four-way, end-to-end supply chain.
Centralised view When all the parameters are right, it is very efficient, but
For different user groups at the refinery, the project means demands a lot of automation and harmonised production.
somewhat different things. While the refinery leadership There were two main reasons why the refinery started
team mainly uses the system for overall performance to develop Nappi as an overall management system that
monitoring, a shift manager may enter production targets utilises multiple pre-existing digital systems: to maintain the
into the system for operators to follow, and to monitor production at a high and profitable level, and to ensure the
how well the targets are achieved. For operators, the system production of just the right quality of any product.
offers an easy way to check the production targets and how Nappi also offers the opportunity to have a long-term,
they are met. future-oriented overview of the production, using
The way a modern refinery is working with the aid of data-based management, to an even larger extent than
digitalisation is not news to anybody working in the before. At the same time, the maintenance systems have
business, but one common challenge is that different also been improved by connecting them to Nappi, thus
systems run different parts of the refineries. With Nappi in enhancing the transparency and improving the predictability
place, it is now possible to gather and share common of production. This has raised the safety and energy
information in a centralised view and to combine it with the efficiency at the refinery, resulting in more carbon-efficient
different dashboards used in production. The system also refining.

March 2023 24 HYDROCARBON


ENGINEERING
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Utilising existing systems in Ukraine. The refinery has successfully and smoothly
However, Nappi does not mean that the traditional way of adapted to the changed world thanks to the overall level of
working itself has changed at the refinery; panel operators digitalisation, and due to the advantages that Nappi offers
are still using the same dashboards as before to make the whole plant with regards to planning the production
fact-based decisions on how to improve performance, and efficiently.
how to utilise the full potential of the feedstock. Instead, it For example, the refinery management, engineers and
is a shortcut to utilising the huge amounts of data that are maintenance have their own information needs, each of
constantly collected in the distributed networks regarding which were addressed during the project. It is now possible
feedstock, flows, temperature and pressure, for example. for maintenance to better plan and schedule service actions
Another big change is that the system provides both through Nappi, so that the production is disturbed as little
the operators and the staff involved in the production with as possible. The next step is to make the system even easier
an instant view over the process and the state of it, without to use, but the refinery’s gap between targeted and realised
them having to dig into different dedicated systems. As an production goals has already decreased thanks to the
example, the numerical targets that previously had to be project.
sent by email or were found in different files can now be
shared within Nappi. When considering all of the different A different project
organisational levels that might need the information, this As a result of the agile development praxis used while
feature alone has hugely streamlined the process at the developing Nappi, feedback from the users was
refinery. continuously sent to the developers at NAPCON. The
project was quite different from most other digitalisation
Smooth transformation projects that the company has been involved in; the biggest
Nappi aims to optimise the processes of the four production difference being that large industrial systems are usually
lines as an entirety at the refinery. Because the system makes developed out of sight of the real users until it is time to
it possible to look at the processes from different angles, it release version A. It can then be a time consuming and slow
also provides an opportunity to optimise the overall product process to change the system if needed. By being
mix by enhancing how the feedstock, energy and additives continuously able to adapt the system according to
are used when producing different products. immediate feedback at every small step along the way, the
Since the project started in 2019, the world has changed system has gradually grown according to the real needs of
significantly due to COVID-19, the energy crisis, and the war the users.
G
Mike Hoffman, eorge, an industrial control systems (ICS) engineer at a large
petrochemical plant, is monitoring operations when he notices
Dragos Inc., USA, discusses something amiss with a burner management system on the
how refineries can protect sulfur recovery unit (SRU)’s thermal reactor, which appears to be
malfunctioning and is on the verge of releasing high amounts of sulfur dioxide (SO2)
critical ICS/OT systems and hydrogen sulfide (H2S) from the incinerator stack.
from cyberattacks. George’s first thought is that it is an equipment failure, but he should have been
alerted by the base layer control system. The safety instrumented system (SIS) that
is monitoring the burner management systems to ensure that processes stay within
their defined engineering limits has failed to trip the unit.
This is the first sign that the incident is not the result of an equipment
malfunction, but rather of a targeted attack – one that George and the plant’s
cybersecurity team are unprepared for. The adversary carrying out the attack has
been lurking in the plant’s network for nearly a year, dwelling unnoticed in the
network and developing malware capabilities targeting emergency shutdown
systems – ultimately leading to the first of two plant shutdowns.
This scenario, drawn from a 2017 TRISIS malware attack on a
Saudi Arabian plant, underscores the potential threats to
oil and gas refineries and the lack of protections and
detections that many plants have for their ICS and
operational technology (OT) environments. The plant,
being unable to identify the TRISIS intrusion, was
blindsided by the attack, and did not have a robust
plan for such a response. Ultimately, the plant was
fortunate that the damage it suffered was not
worse, because it very well could have been.
The question is: how do attacks like this
happen? And what could the plant have
done differently?

The threats are real


The downstream segment of the
oil and gas value chain remains at
risk of cyberattacks. Refining
facilities are a key target for
adversaries due to the
centralised nature of operations,
the presence of control
systems, and the possibility for
damage or destruction from
highly-volatile processes.

HYDROCARBON 27 March 2023


ENGINEERING
All industrial operations are increasingly under attack. A 2021 pipeline for almost a week and caused jet fuel shortages for
Ponemon Institute study of industrial cybersecurity found that many airlines, panic buying of gasoline in southern US states, and
63% of respondents said their organisations experienced an other disruptions.3
ICS/OT cybersecurity incident in the previous two years, at an Attacks can have direct and indirect consequences. Many
average cost of nearly US$3 million per incident.1 refineries have communities that have been built up around
Many industrial facilities are not especially well-prepared for them, which would be affected. Shutting down a refinery will
these types of attacks, owing to a historic cultural divide also affect the supply chain, for instance, because petroleum
between IT and OT security. Most industrial sites have partly byproducts are used as feedstocks in many chemical processes.
integrated their IT systems with ICS/OT to improve efficiencies,
but cybersecurity has not kept pace. Vendor compromises
The study found that only: These facilities receive frequent visits from vendors – for
nn 43% of respondents said that their organisation’s maintenance and for a variety of other reasons. A vendor
cybersecurity policies and procedures were aligned with might be upgrading a vibration monitoring system by installing
their ICS and OT security objectives. a new server into the control network, for example. That
nn 35% said that IT and OT teams have a unified security vendor could very easily plug an infected laptop or USB drive
strategy that secures both the IT and OT environments. into the network and unintentionally introduce malware into
the OT environment.
IT and OT may be linked via a plant’s network, but they are
different. A lot of OT components are older and were not Vulnerabilities of OT systems
designed with security in mind. Whilst newer equipment is Refineries are replete with physical safety systems, such as
designed with security features, it can take a while to replace pressure release valves, flare systems, etc. As plants undergo
hardware that typically will run for 20 – 25 years. IT security process upgrades and debottlenecking projects to increase
methods will not work well with older OT systems, which throughput, these physical systems are often not upgraded due
require a different approach to deal with the type of threats that to cost. As such, they are no longer capable of providing the
it faces. protection required. As a result, plants, realising the need to
In planning to protect ICS and OT, the downstream segment mitigate residual process risks from these changes, have turned
needs to be aware of the following types of attacks: to safety instrumented systems (SIS).
SIS are highly-available systems that include sensors, logic
Targeted disruptions solvers and actuators to monitor critical process systems and
Nation-state attacks on infrastructure and industry, such as those take action to shut the process down if predefined limits are
regularly occurring in the Russia-Ukraine war, can have serious exceeded. These systems provide the ultimate target for an
consequences.2 The Colonial Pipeline ransomware attack, attacker if the goal is to cause a catastrophic event.
attributed to the DarkSide group based in Russia, shut down the In a scenario such as the Saudi Arabian plant attack, an SIS
could be compromised and disabled so that it does not act.
For example, it may be modified so that no trip is issued when a
process reaches unsafe levels. If an attacker then goes after the
distributed control system (DCS) that runs the plant and moves
the pressures, flows or temperatures of a particular process
outside of its operating envelope, an explosion could occur.
Today, plants generally have common architectures with a
demilitarised zone (DMZ) or buffer zone between IT and OT to
allow for remote access, file transfers, and other data movement.
Many plants, however, rely on older ‘best practice’ architectures
that are relatively flat across systems with the same functional
level as opposed to smaller ‘zoned’ networks. These flat
networks are ripe for lateral movement by adversaries, especially
if they are protected with atrophying controls.
Many attacks will start by targeting corporate systems via
phishing and other attempts to gain access, and then try to get
through the DMZ – if one exists. Next, adversaries work to get
past the operations systems (Level 3), supervisory controls
(Level 2), and basic controls such as DCS controllers and
programmable logic controllers (PLCs) (Level 1) to perform their
final action or objective, which may include process
manipulation (see Figure 1).
Firewalls typically sit between each functional level, or zone,
including the firewalls that create the DMZ, but the fact is that
many operators do not properly maintain their firewalls and are
Figure 1. Common plant IT/OT architecture. unaware of the actual data flows going across them, because
they are not monitoring the network. Without having visibility

March 2023 28 HYDROCARBON


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into network traffic flows, it is challenging to ensure that firewall This stage is likely to be when the plant would begin to
rule sets are correct. isolate networks. During the Colonial attack, pipeline operators
separated their OT from IT as part of containment. Isolating the
Preparing for an attack OT network is one of the primary containment steps, but this
Refineries need to be sure that they have a defensible can also have indirect business impacts. Containment can be
architecture, which starts with having equipment in place to broadly applied across OT and processing units, or isolated
monitor operations effectively. Monitoring can help detect down to individual system(s), depending on the respective
attacks early on, before a physical impact is realised. network architecture and intrusion scope.
Adversaries performing targeted attacks must slowly work
their way through an OT environment looking for DCS, SIS or Eradication
PLCs, and they can spend months inside a network before As systems are scoped for intrusion and contained, eradication
acting. Such an attack requires a considerable amount of begins to immediately remove the threat from the
reconnaissance and reverse engineering before realising the environment. There is no clean break in each of these steps,
action on objective. The numerous months that the adversary and containment, followed by eradication, is very much an
spent inside the Saudi Arabian system while developing TRISIS iterative process. After systems are cleaned, monitoring levels
might be unusual, but the average ICS/OT cybersecurity must be drastically increased to ensure that the malware or
incident is a nearly year-long event. adversary is completely removed from the environment.
The amount of time it takes to carry out a targeted attack is Otherwise, the threat may regain a foothold and start
one advantage that defenders have within OT. If the right successive attacks.
protections and monitoring are in place, this gives defenders
that much more time and opportunity to catch the attack Recovery
before equipment or process manipulation occurs. Once systems have been cleaned and the threat removed, the
The necessary steps in preparing for an attack include: plant can bring systems back online. Crucial to this step is
understanding minimal operating requirements and order of
Develop an incident response (IR) plan restoration. For example, domain controllers, application servers,
Plant operators need to have a documented plan in place in and critical human-machine interfaces (HMIs) are often needed
order to respond to unusual activity involving OT. Practically all first before other OT systems are brought online.
organisations have IR plans for IT, but those plans fail when An important part of recovery is having reliable back-ups.
leveraged directly in OT because of the differences in how the This is one area where OT and IT are similar, taking regular
technologies operate and the actions to take on the systems snapshots of servers and databases to aid in recovery.
once an incident is called. A response plan should address One step to consider is having offline back-ups, which are
several important stages. essential in cases of ransomware, for instance. Ransomware
actors will often target connected back-up systems along with
Detection production systems to prevent quick recovery and ensure that
When unusual activity is detected by a SIS, for example, it is ransom payments are made. A secondary back-up that is
important to consider that there may be a cyber element at disconnected or replicated to a secure cloud storage system
play. Equipment malfunctions, but times have changed, and the can help speed up the process of restoring systems.
industrial community is beginning to adopt a cybersecurity
mindset. Conclusion
The first thing to do is determine whether an event is Current adversaries have shown that they can conduct attacks
malicious through network security monitoring, collecting logs in the downstream segment while new, increasingly
from systems and hosts, and analysing them. If the activity looks sophisticated adversaries are emerging. Refineries must adopt
at all suspicious, the event can be raised to the level of an controls to counter these growing threats. A primary control
incident, which will trigger a response from the appropriate that can be implemented is to have a tested incident response
teams. in place for OT, which includes steps for detecting a cyber
An IR plan serves as the foundation for every other stage of event, followed by containment, eradication and restoration.
response, but only comes into play once equipment Network security monitoring is foundational to enabling these
malfunction has been ruled out. incident response steps. Whilst ‘defence is doable’, it takes a
plan with the right protective, detective and responsive
Containment capabilities to safeguard critical refinery operations.
Once an event is raised to the level of an incident, the response
stage shifts to containment. This involves scoping the incident References
to determine affected systems, which often includes collecting 1. ‘2021 state of industrial cybersecurity’, Ponemon Institute,
(November 2021), https://hub.dragos.com/hubfs/Reports/2021-
forensics evidence from systems, reviewing logs, and performing Ponemon-Institute-State-of-Industrial-Cybersecurity-Report.
network monitoring. Foundational to containment is pdf?hsLang=en
2. ‘Relentless Russian Cyberattacks on Ukraine Raise Important Policy
preparation by having contingency plans in place to understand Questions’, (5 October 2022), https://www.darkreading.com/threat-
what systems are required for minimal operation, or when a intelligence/russian-cyberattacks-ukraine-raise-important-policy-
controlled shutdown may be required. Planning for containment questions
3. ‘Colonial Pipeline hack explained: Everything you need to know’,
is a team effort that should involve engineering, ICS/OT (26 April 2022), https://www.techtarget.com/whatis/feature/Colonial-
security, and operations. Pipeline-hack-explained-Everything-you-need-to-know

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Leo Simonovich, Siemens Energy, USA, lists the important steps to be
taken in order to develop a more mature cybersecurity posture.

P
ipelines make money by moving fuel. But on 100 million gal. of fuel went undelivered each day.
9 May 2021, no fuel was moving through the US’ Consumer prices at the pump jumped to seven-year highs,
largest refined petroleum product pipeline. As and gas stations ran dry across the US southeast. Airlines
the Colonial Pipeline’s operators scrambled to rearranged flight schedules; the President of the US
understand the extent of the cyber breach, the pipeline weighed in to prevent further economic disruptions,
– responsible for moving nearly half of the declaring an emergency.
transportation fuel used on the Atlantic Coast – was at a All of these impacts flowed from a single cyberattack
standstill. A ransom of US$4.4 million had already been targeting the billing department of the Colonial Pipeline
paid, but this represented a fraction of the mounting operators. When these operators were confronted with a
economic impacts felt by the breach, as roughly clear breach in their information technologies (IT)

HYDROCARBON 33 March 2023


ENGINEERING
systems, the operational technologies (OT) systems also ransomware attacks target energy infrastructure, while
had to cease operations – the workflows could not be geopolitical motivations lead government-backed
separated. That disruption caused headaches up and hacking groups to seek backdoor access to energy
down the supply chain. As the US Secretary of Energy infrastructure in rival nations.
pointed out, “it certainly is a reminder that we need to
take a hard look at how we need to harden our necessary Problems faced
infrastructure, and that includes cyber threats.”1 For leaders in the hydrocarbon industry, this poses a new
Even after the highly public example of a ransomware set of challenges. Increasingly, chief information security
attack halting real-world operations, it is already clear officers (CISOs) must protect not just IT, but also OT.
that this will not be the last of such incidents. In Even for CISOs who have a background in OT, the
December 2022, a ransomware attack against the cybersecurity needs of a changing asset base, as well as
Copper Mountain Mining Corp. prompted a shutdown of the moving target of regulatory compliance for
its mill while the company’s team determined the effects cybersecurity, pose ongoing challenges. How long will IT
of the attack on their control systems. systems that have support cycles averaging four years
really be able to protect OT systems with expected
The digital age life cycles measured in decades? What is the right
Cybersecurity is now a make-or-break capability for investment strategy when cybersecurity advancements
many companies that do not yet think of themselves as become available years faster than regulatory guidance
digital companies. Workflows seamlessly integrate digital for defending the equipment in question? How can an
tools with physical equipment, and cannot operate safely organisation buy down risk, when cyber insurance
when the digital components of said workflows are offerings do not match the identified risk profile?
compromised. These are high-stakes questions for organisations of
This is particularly true for hydrocarbon supply every size. Moderately-sized companies are particularly
chains. At every stage from wellhead to pipeline, and challenged because they cannot expand budgets to hire
refinery to distribution, digital technologies are deeply more cybersecurity personnel, or research, develop and
integrated with physical systems. The separation deploy their own systems for risk management. Yet even
between IT and OT has blurred. The same capabilities major organisations with resources that are available for
that give pricing algorithms up-to-the-minute reports on internal solutions are susceptible to disruptions when the
how much product has been shipped, for example, also value chain breaks at its weakest link.
unavoidably create connections that bad actors can
exploit. At the same time, the sophistication and scale of Finding solutions
cyberattacks have escalated. Robust for-profit Cyber defences need to evolve. In the wake of the
Colonial Pipeline attack, US government and private
sector officials have moved to prevent and mitigate
future disruptions. A wave of new regulations, policies
and industry actions seek to address key vulnerabilities
and build more resilient cybersecurity into critical
infrastructure. The Transportation Security
Administration (TSA), in particular, has worked to
transform pipeline security in the US.
The TSA’s new risk-based approach, published in the
security directive ‘Pipeline Security Mitigation Actions,
Contingency Planning and Testing’, calls for new
technologies, procedures and planning guidelines to
protect against cyber threats. Companies are encouraged
to leverage artificial intelligence (AI), cloud computing,
and big data for cyber hygiene, incident reporting, and
anomaly detection.
This change is an important paradigm shift. The old
regulatory model was designed around a less
sophisticated operating environment. Networked
physical systems used to be separated from other IT
systems. This air gapping approach aimed to prevent
cyberattacks by ensuring no digital pathway could
connect from the internet to the infrastructure that
actually carries fuels. The TSA collected voluntary
Figure 1. Cybersecurity is a make-or-break capability reports of cyber incidents, but did not have mandatory
to protect hydrocarbon supply chains at every
stage – from wellhead to pipeline, and beyond reporting requirements.
(source: Siemens Energy). Today, the competitive business environment drives
close integration in IT and OT in order to maximise

March 2023 34 HYDROCARBON


ENGINEERING
efficiency and seek every competitive advantage possible. technological assistance. Purpose-built monitoring and
That integration means that attacks can – and will – affect detection technologies can leverage AI and cloud
both IT and OT, even if the attack does not directly computing to identify threats within company networks,
penetrate OT systems. The TSA rightly embraces that notify relevant authorities, and begin impact mitigation.
reality in its new regulatory requirements, emphasising the Using such systems, relatively small analyst teams can
need for expansive and detailed understanding of the IT quickly review anomalies and understand their likely
and OT devices that are connected to their network and consequences for workflows and equipment. This type
the need to identify anomalous behaviour. Instead of of threat hunting shifts the balance of power from
assuming that cyberattacks will not breach air gaps, the attackers toward defenders. In an actively-monitored
idea is for companies to identify and intervene in attacks system, it is difficult for attackers to learn their way
as swiftly as possible, and quickly share information about around operating technologies without alerting
said attacks. defenders to their presence.
In order to comply with regulations and succeed in
the face of escalating cyber threats, CISOs and their Conclusion
security teams must build new capability. There is a need Combining AI-driven automation with reporting
to monitor billions of connections between physical requirements will help to rapidly harden targets across
assets, industrial control systems, and corporate IT the energy ecosystem. These are important steps toward
software on a minute-by-minute basis. Companies need a more mature cybersecurity posture for the industry.
to sift through that information at machine-like speeds This is how defenders diminish the reach and power of
to detect the interactions that could indicate a nascent novel attack methods – by detecting attacks quickly, and
cyberattack. If a breach is detected, pipeline security sharing detailed threat intelligence quickly and widely.
teams must be able to isolate the attack and prevent its This will result in reliable and resilient infrastructure being
spread to other physical or digital assets, and must built and sustained.
report the incident to the Department of Homeland
Security within 24 hours. Reference
Such swift and capable cybermonitoring only recently 1. ‘Remarks as Delivered by Secretary Granholm at the White
House Daily Press Briefing on the Colonial Pipeline Outage’,
became feasible. Teams of human analysts manually
US Department of Energy, (11 May 2021), https://www.energy.
reviewing OT device data would be too slow and costly. gov/articles/remarks-delivered-secretary-granholm-white-
SmartPMHalfPgResize_final.pdf
Meeting the required scale 1 and
8/9/22 12:25
speed callsPMfor house-daily-press-briefing-colonial-pipeline
Mark Stuckey, UNICAT Catalyst Technologies LLC, discusses the emergence
of next generation spherical catalysts and their impact on yield increases and
reduced carbon dioxide (CO2) emissions in tubular reformers.

D
esigns of tubular steam methane reformers (SMRs) plain spheres, with 12 years of operation in a 450 Tube DRI
have, wherever possible, been optimised around the reformer. The second is a US refinery installed with UNICAT’s
limitations of key component capabilities, i.e. Magcat Textured Sphere technology.
dimensions and high temperature creep of tubes,
together with the pressure drop and activity of the Background
conventional catalysts within the tube. Over the years, tube and The overarching efficiency of a reformer is derived from the
catalyst manufacturers have improved their respective products, efficiency of heat transfer through and into the tube. This heat
but limitations of conventional catalyst carrier manufacturing energy, combined with the catalyst, promotes the reaction
processes have slowed any significant developments over the between the process gas (steam and methane) to produce
last 20 years. hydrogen.
The next generation of catalyst required a step change in The effectiveness of getting heat into the tube and
carrier manufacturing processes. It is generally known that facilitating the efficiency of the reforming process is highly
spherical shapes pack better in tubes than alternate cylindrical dependent on the flow of the process gas through the tube.
types, but it has been difficult to manufacture spheres in The aim is to facilitate the lowest amount of process gas flow
volume, so all conventional carriers have been non-spherical. restriction whilst allowing for sufficient time for the reforming
However, 12 years ago, UNICAT, knowing the packing benefits, reaction to take place.
introduced the first spherical catalyst into a tubular steam The catalyst shape and how the thousands of individual
reformer. catalysts pack impact the flow dynamics of the process gas.
This article will detail two industrial cases which Conventional catalysts pack chaotically due to their
demonstrate the effect of catalyst shape optimisation – moving non-spherical shape, and this leads to uneven flow, flow
to spheres from non-spheres. The first case will be UNICAT’s bottlenecks, and sub-optimal heat transfer.

March 2023 36 HYDROCARBON


ENGINEERING
Conventional catalysts are produced using either extrusion tube, all of the active surface area is available and involved in
or hydraulic pressing. As a result of these manufacturing the reforming.
techniques, only mono-directional shapes are able to be UNICAT’s plain spheres (see Figure 1) have a low geometric
manufactured. Holes are added to try and reduce the shape surface area (GSA) relative to their volume, and so deliver the
pressure drop issues and to introduce mathematically-calculated pressure drop benefits but are not optimised for active surface
geometric surface area. area. The Magcat technology added golf ball-like surface
However, this has a limited benefit. Firstly, the texturing, maintaining all of the process flow distribution
mono-directional shape and alignment of holes within that benefits of spheres whilst optimising the active surface area.
shape will not pack within a tube with the holes aligned to the Tubular SMRs are used extensively in the production of
process gas flow. Secondly, process gas will always look to hydrogen, generating 96% of hydrogen produced worldwide.1
follow the easiest path through a restricted tube. The majority On average, 65% of global refinery hydrogen demand is satisfied
of the flow will preferentially look to find the voids between by reforming and cracking processes, and 32% is provided by
the shapes, and these voids in a tube packed with conventional on-purpose units.2
catalysts are chaotic.
Spheres pack uniformly, naturally resulting in the voids being Sphere catalyst technology
the same shape and size, meaning even distribution of the Generation 1.0 technology is based on plain four-holed spheres,
process gas across and through the tube. The benefit of this under the brand MYD-S (see Figure 1). The sphere was
even distribution effect with spheres is that the process gas introduced to facilitate uniform packing and flow. The holes
restriction (pressure drop) is lower, allowing for significantly were added for customer visual acceptance rather than any
more flow through the tube. Additionally, because the process process benefits. The sphere manufacturing technology is
gas evenly reaches every individual catalyst sphere within the economically-viable for the larger > 20 mm spheres, and as such

HYDROCARBON 37 March 2023


ENGINEERING
was only offered to the Direct Reduction of Iron (DRI) market in Next generation SMR sphere catalyst
July 2012. technology
27 mm four-holed spheres were supplied into a Magcat Textured Spheres’ manufacturing processes and shapes
450 x 11 in. dia. tube DRI SMR in the Americas. Tubes were were designed to optimise the compromises of plain spheres.
loaded with the same-sized 28 mm MYD-S sphere containing Essentially, the manufacturing process was developed to enable
between 8 – 11 wt% nickel. They replaced a previous charge of the mass production of any sized spheres with surface textures.
ribbed cylinder-shaped catalysts. Magcat is compatible with all tubular steam reformers
The customer referenced the following differences in (primary reformers) used for SMR, and is now installed in over
performance in March 2018: 27 hydrogen plants worldwide.
nn The overall reformer pressure drop had fallen by 60% as Generation 1.0 spheres and Generation 2.0 Magcat have
compared to the previous charge. been shown to increase hydrogen production and reduce
nn Reformer gas quality remained equal. carbon dioxide (CO2) emissions by 10 – 20% in ways that are
nn Approximately 15% energy savings were achieved. easily implemented, and which avoid equipment investment
nn An increase in total plant capacity to 210 tph from 190 tph.costs. Spheres demonstrate lower pressure drop than previous
nn No intermediate plant shutdown was required over the charges, which in turn allows for higher process gas flows.
five years for dust removal. Traditionally, SMR pressure drop is reduced by moving to larger
catalyst pellet sizes. Larger pellets provide more voids, which
The customer could have increased plant capacity further, translates to lower pressure drop. However, the trade-off of
however they were limited due to the compressor capacity. larger size pellets is lower total bed surface area, which results in
The change from cylinders to spheres delivered other physical higher methane slip, particularly late in cycles. The use of
benefits which will be explained in the following sections. spheres and, more recently, externally-textured spheres,
decouples concerns with surface area and
pressure drop.
This premise is supported by SMR
operating data (see Figure 2) for a site that
installed Magcat in early 2022. The data
demonstrates that, for fixed conditions, this
technology generates 10 psi (0.7 bar) lower
pressure drop at all corresponding feed rates,
compared to previous installations of
conventional, cylindrical SMR catalyst.
Counterintuitively, Magcat of smaller size
than the previous catalyst was loaded into
this reformer to prove the advantage of
Figure 1. Examples of SMR catalysts in traditional cylindrical shapes, spherical shaped catalyst in promoting
UNICAT’s Gen 1.0 plain spheres and Gen 2.0 textured sphere (left to right uniform flow. To make use of this benefit,
conventional cylinders, MYD-S plain spheres, Magcat® textured sphere). total feed to the reformer (feed gas plus
steam, at constant or lower steam-to-carbon
ratio) can be increased 10% at
constant pressure drop or
observed hydraulic limit.
Operating at constant feed rate,
this pressure drop benefit
significantly offloads feed gas
compressor duty at fixed
reformer outlet pressure, reducing
unit power consumption. Magcat
and MYD-S spherical shapes have
no straight edges, reducing
excessive pressure drag associated
with cylindrical pellets. Plain
spheres have a drag coefficient of
0.47, textured spheres 0.27, and
cylinders between 0.82 – 1.15.3 The
lower the drag coefficient, the
lower the pressure drop.
Additionally, a regular surface
Figure 2. Operating data from a top five US refiner comparing throughput to unit flow over the sphere is
pressure drop with different SMR catalysts. maintained (see Figure 3/4),
adding symmetrical spheres into a

March 2023 38 HYDROCARBON


ENGINEERING
excellent mixing and intimate gas-to-surface
contact. More crucially, lateral movement
promotes heat collection from the tube wall and
transportation of heat energy to the core of the
tube to satisfy endothermic reforming reactions
and equilibrium conditions favouring conversion
to hydrogen at high temperatures.
In comparison, tubes packed randomly with
cylinders induce high pressure drag over bluff
bodies in most aspects, and generate chaotic
fluid flow paths, resulting in dead spots;
back-eddies; bypassing; and hosing through
catalyst holes when vertically orientated, thus
diminishing lateral movement that is critical for
effective radial heat transfer.4 Spherical catalysts
Figure 3. Flow simulation comparison of gas passing over a smooth
spherical catalyst next to Magcat® textured spherical catalyst (gas generate numerous, predictable pellet-wall
moving from bottom to top). contacts disturbing convectional boundary layer
thickness along the wall and redirecting heated
flows laterally into the bed (see Figure 5).
Magcat’s SMR catalyst does not incorporate holes. Literature
lists the advantages of multiple holes in cylindrical pellets as:
increased voids (associated with lower pressure drop in
conventional loadings), and increased active surface area.
Magcat is not limited in either, due to expanses of surface area
from external texturing and internal porosity, and substantial
and regular voids between particles when packing solid
spheres.5
Another benefit is lower inherent pressure drop imparted
by spheres in comparison to other common SMR catalyst
shapes. Further, observed void increases during bed movement
of textured sphere packing during heat up, which allows smaller
Magcat sizes to be selected than would be traditionally
expected for an application.3 Smaller spheres further increase
surface area, wall contact points, and promotion of radial flow
without compromising overall system pressure drop compared
to a loading of larger cylinders.
Disadvantages for holes that are listed in literature are
particle weakness and reduced radial flow. Additionally, holes
will not offer the gains proposed unless available to flow by
being orientated vertically or near-vertically. Random packing
results in proportions of pellets not oriented in ways that are
beneficial. Without strength, surface area or pressure drop
concerns, Generation 2.0 Magcat spheres exclude holes to
Figure 4. Flow simulation of gas passing over a
half, static Magcat® textured spherical catalyst (gas maximise radial heat transfer, which benefits steam reformers
moving from bottom to top) and a half ribbed cylinder the most.
showing the flow differences. Radial heat transfer is key for efficient hydrogen production
in SMR. Energy movement from externally-heated tube surfaces
tube naturally generates repeatable and predictable packing to the inner bed core replenishes energy debts generated by
patterns not otherwise associated with random loadings of net endothermic reforming reactions. UNICAT’s Generation 1.0
cylindrical pellets. and Generation 2.0 Magcat applications observe much lower
Effects on fluid flow from uniform packing vs chaotic tube wall temperatures (TWT), typically decreasing tube failure
packing are profound. Gases entering tubes filled with spheres due to creep by at least 40%. Further, hot spots and red bands
divide evenly to flow around full hemispheres of each sphere. are less likely in spherical catalyst loadings as uniform packing
Uniformity of spherical packing creates unbiased and equal flow minimises bridging. This means further increased tube lifetimes
paths for the entire cross-section. Upon exiting the initial layer and the avoidance of common points of failure.
of spheres, via regular and homogeneous void apertures The same industrial user observed that, after switching to
between adjacent spheres, reactant gas flow immediately Magcat, the same methane slip could be achieved at
encounters the next layer of uniformly-packed spheres, over significantly lower combustion outlet temperature under other
which it will again divide and reconnect with contiguous flow constant conditions as a result of the heat transfer
paths. This ‘snaking’ fluid flow across spheres encourages improvements discussed (see Figure 6). It is this unlocking of

March 2023 40 HYDROCARBON


ENGINEERING
constraints, particularly the most challenging
and most limiting factor of improved radial heat
transfer, that allows MYD-S and Magcat users to
increase hydrogen production above nameplate
capacity and historical maximums via increased
throughput.
A further advantage of spherical catalysts
can be seen in Figure 7. As the tube cycles from
hot to cold for any number of reasons, it exerts
radial pressure on the catalysts packed in the
tube. The sphere packing, due to its uniform
nature, provides support for all of the spheres.
This limits the voids between the pellets to less
than half the diameter of an individual sphere,
Figure 5. Simulation of gas flow in packed tubes with Magcat® (left) and creates a relaxing effect with subsequent
and cylindrical catalyst (right), emphasising preferential flow path hot/cold/hot tube movements. As there is
differences.
nowhere for the spheres to go, the radial
pressure pushes the spheres closer to each
other on cooling, and opens up the voids
slightly during heating – stopping the catalysts
from crushing each other. The opposite
happens with a conventional cylinder packed
system, i.e. on heating, holes are opened up
between catalysts, allowing corners or edges to
drop into gaps that have opened up; and on
cooling the tube diameter closes, crushing
catalysts against each other.

Conclusion
UNICAT’s MYD-S and Magcat spheres are
demonstrating excellent performance in tubular
SMR reformers, as shown in one such example
operated by a top five refiner in the US, and as
referenced by a global steel company operating
a DRI reformer. These benefits can be clearly
Figure 6. Increases in reformer outlet temperature through operating understood from underlying effects on fluid
cycle using conventional SMR catalyst compared to low outlet dynamics, thermodynamics, and heat transfer of
temperature with Magcat® installed. spheres vs conventional shapes. Energy
efficiency, lower CO2 emissions, increased
hydrogen production, and extended tube life
are some of the advantages of next generation
spherical catalysts.

References
1. TAGLIABUE, M., ‘Refinery off-gas in hydrogen
production’, Air Liquide, PTQ (Q1 2022), https://cdn.
digitalrefining.com/data/articles/file/1002727-q1-
air-GBPiquide-dr.pdf
2. ‘Low-carbon hydrogen demand in refining could
reach 50 Mtpa by 2050’, Wood Mackenzie,
(June 2022), https://www.woodmac.com/press-
releases/low-carbon-hydrogen-demand-in-refining-
could-reach-50-mtpa-by-2050/
3. HOERNER, S. F., ‘Fluid-Dynamic Drag : Practical
Information on Aerodynamic Drag and
Hydrodynamic Resistance’, 2nd Edition, (1965),
pp. 3 – 17.
4. DIXON, A., BOUDREAU, J., ROCHELEAU, A., TROUPEL, A.,
ERTAN TASKIN, M., NIJEMEISLAND, M., and STITT, E. H.,
‘Flow, Transport, and Reaction Interactions in Shaped
Cylindrical Particles for Steam Methane Reforming’,
Figure 7. Cut through tube view of spherical catalyst (left) showing Industrial & Engineering Chemistry Research, (2012).
even and supported fill, and conventional catalyst (right) showing 5. TURNER, J., ‘Hydrogen Consumption for Fuels
crushing impact of tube thermal cycling due to lack of support Production’, National Renewable Energy Laboratory
facilitating catalyst dropping and crushing. (NREL), (2013), p. 5, https://www.hydrogen.energy.
gov/pdfs/htac_oct13_9_turner.pdf

March 2023 42 HYDROCARBON


ENGINEERING
March 2023 44 HYDROCARBON
ENGINEERING
Vic Scalco, General Atomics
Electromagnetic Systems, USA, details
the importance of selecting the correct
separation technology in order to
support growing petrochemical demand.

T
he global pandemic, economic slowdown,
and instability caused by regional conflicts
have significantly impacted the
approximately 735 petroleum refineries
worldwide. Today’s highly complex and competitive
refining environment, coupled with eroding profits and
difficulty maintaining a positive bottom line, is forcing
over half of these refineries to seek new market
opportunities from the bottom of the barrel in order
to remain competitive. In addition to this, compliance
with tougher climate regulations is further taxing
refineries’ ability to invest in technology innovations
to help keep pace with changing market demands,
while maintaining profitability.1
Refining management’s balancing act between new
technology investment and increasing revenue
potential is driving a trend toward utilising severe
catalytic cracking technology to increase profits while
taking advantage of the existing crack spreads. Over
18 million bbl of crude oil are processed daily through
a fluidised catalytic cracking (FCC) system, along with
three-quarters of worldwide gasoline. FCC systems
have become the refinery’s most versatile operating
units to improve the bottom line. With the increase in
crude prices, environmental compliance cost, and
current International Maritime Organization (IMO)
2020 regulation enforcement, the spread between
lighter, less severe crudes and heavier, opportunistic
crudes will become a bigger part of the refining
sector’s economics. The FCC’s capability to convert
heavy atmospheric gas oils, vacuum gas oils, and
atmospheric resids into more valuable gasoline and
middle distillates can be exploited to support more
positive profit margins.2
Heavier, opportunity crudes are pushing the limits
of catalytic cracking. Refiners are increasingly
considering the utilisation of more complex
technologies for deeper conversion of challenging
feedstocks arising from the processing of opportunity
crudes. There are a range of technologies tailored for
processing heavier crudes and producing high-quality
final products. As the future of refining has the
industry moving towards the use of higher severity
conversion units and synthetic crudes, the FCC will
remain the workhorse of the refinery.

HYDROCARBON 45 March 2023


ENGINEERING
Asia joins the race Slurry oil is the lowest-value stream produced by an
In Japan, approximately 30 petroleum refining FCC unit (FCCU), representing only 3 – 7 vol% of the total
companies are utilising FCC or resid fluid catalytic products. A typical 50 000 bpd FCCU would produce
cracking (RFCC) units to produce propylene, LPG, 2000 bpd or 125 000 tpy of slurry oil as a byproduct. The
gasoline and light oil. S-Oil Korea installed its first high quality varies according to numerous factors including
severity FCC, and PERTAMINA Indonesia is investing in crude oil origin, FCC design, and fractionation
new RFCC units to increase overall international market equipment. The two most important factors affecting
supply. India is expanding its ability to produce quality are catalyst type and conversion level. Quality
polypropylene through RFCC units, as petrochemical may also vary for marketing reasons by dilution in the
feedstock production is in high demand. New products FCC fractionator with heavy cycle gas oil. Table 1 shows
generated from these RFCC units can be consumed in the typical concentration range of catalyst in marketable
the global market for transportation, power generation, slurries.3
and petrochemical supply, or shipped as a product
blended for marine fuel. With years of operation in the Meeting market demands
RFCC market, Asia is now faced with a need to generate Severe FCC feed hydrodesulfurisation can reduce the
increased profits in a competitive environment, and will sulfur content of slurry oil to less than 0.5 wt%, however
have to address applications for the bottom of the the hydrotreating would result in decreased slurry
barrel streams from these units ladened with aromaticity unless conversion is greatly increased.
concentrated catalyst.1 Currently, approximately 40% of the US FCC feed is
hydrotreated primarily at mild conditions so that slurries
The challenge contain 0.5 – 1.5% sulfur. Refiners do not desulfurise FCC
Creating greater profits from an FCC unit comes with a feed just to lower the slurry oil’s sulfur content; they
cost. Driving the FCC technology into higher severity for have other objectives such as lowering gasoline sulfur,
increased propylene demand for petrochemical reducing sulfur emissions from catalyst regeneration,
feedstocks is a growing trend. Along with fuel gas, C3S improving product yields and quality, or meeting new
and C4S, FCC units also produce a 650+°F heavy aromatic market requirements. Efforts to meet the IMO 2020
oil, known as slurry oil, as a byproduct. Slurry oil marine fuel regulation entail a joint process of
nomenclature refers to the catalyst fines carried over hydrodesulfurisation to less than 0.5%, and fines removal
from the FCC reactor which end up in these bottoms. to comply with less than 50 ppm catalyst fines required
Because catalyst fines must be separated or be allowed by MARPOL IV.2, 5
to settle out of the oil, the product is more correctly Sediments are composed of large particles that are
referred to as main column bottoms (MCB), decant greater than 20 µm, while filterable solids are composed
clarified oil (DCO), clarified oil (CO), or clarified slurry oil of smaller particles typically in the range of 20 µm to
(CSO).3 submicron level. The sources of the solids are iron
sulfide, silica, clays, scales, ash, coke, and catalyst
fines. Feedstock contamination starts upstream
after the desalter, reaching downstream of the
catalytic cracking unit. While new catalysts,
co-catalysts and additives benefit the process,
they simultaneously add more sediments, solids,
and poisoning metals to the bottom of the
barrel, creating more challenges facing the
removal of these contaminants. Severe catalytic
cracking activities come with the challenge of
Figure 1. Carbon black industry supply.3 producing a higher concentration of these
sediments and filterable solids within the slurry
oil stream.6
Table 1. Typical slurry market feedstock properties4
Ash, or catalyst fines, are a particular problem
CSO market/opportunity CSO clarity (ppm) for slurry, especially for heavy and viscous oils
Carbon fibre feedstock 5 – 10 that require long residence time to allow for
Carbon black feedstock (specialty) 10 – 20 catalyst settling. Obtaining low ash (less than
Hydrotreater feedstock 10 – 50
0.05 wt%) requires dedicated techniques, such as
specialised catalyst selection, heating, chemical
IMO 2020 marine fuel 50 – 60
additives, separation technology, electrostatic
Pitch feedstock 25 – 100 precipitators, centrifuges and cyclones. The
Needle coke feedstock 25 – 100 selection of an attrition-resistant catalyst helps
Refinery fuel 50 – 100 to a great extent, and a few refiners buy
higher-priced hard catalysts to alleviate ash
Carbon black feestock (tyre) 100 – 500
problems in slurry oil. If a higher-priced catalyst
Hydrocracker feedstock 200 – 300
or the idea of a new upper cyclone system is not

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an option, the challenge of catalyst fines separation and increased cost over time for the refinery. One tank per
the recovery of lost profits can be efficiently addressed year can cost a refinery US$40 000 in settling agent,
by adopting the right (MCB) separation technology.7 US$500 000 in cleaning and maintenance, and US$150 000
in landfill and waste disposal fees. This represents
The race for profits approximately US$690 000 in increased costs to
Higher severity FCC units operate at critical conditions and accomplish a bunker fuel at 500 ppm. DCO resulting from
concentrations in the production of higher ends for the settling tank process will continue to experience rising
petrochemical feedstock supply. This makes the process costs as environmental laws direct the handling of
more challenging, especially at the bottom of the barrel hazardous waste, and as the decline in construction causes
where high concentrations of solids, contaminants and stockpiles of dried catalyst to collect at concrete kilns.8
catalysts are undermining the possibility of upgrading the In addition to recovering profits eroded by tank settling,
slurry oil stream. Upgrading catalytic cracking technology by installing catalyst fines separation technology at the
must coincide with increasing efficiency, reducing outlet of the FCC slurry oil rundown, most of the fines can
maintenance cost, and improving the catalyst equilibrium be collected and sent back to the riser. With this
cycle. Removing solids and ultimately increasing the technology in place, the returned catalyst fines would
lifespan of the FCC system is part of this equation, and is support fresh catalyst reactivity while finding more
directly related to incrementing the bottom line in acceptable avenues of escape via gas scrubbers,
refining. electrostatic precipitators, and spent catalyst collection
The success of higher severity production relies on hoppers, ultimately leaving through the flue stack.
providing clarified slurry oil at < 50 ppm to maintain a Additional profit recovery occurs by removing fines from
marketable DCO. Several different filtration and separation escaping through the bottoms circuit and rundown to tank
technologies have been reviewed to find the most suitable settling. By keeping the fines out of this process, the refiner
solution capable of upgrading the challenging DCO stream. can realise additional profit by adding the now-retired
Many refiners ‘de-ash’ with chemical aids to accelerate ash settling tank to a refinery’s marketable inventory tank list.
settling in storage. These chemicals are polymeric This is an added benefit to any refinery, and could be worth
compounds that adhere to the catalyst surface, causing as much as US$1 million in annual revenue.9
agglomeration of the fine particles to accelerate World demand for refined products is unique to the
separation.8 For some time, refiners have found it domestic market and international demand for each region.
economical to cat crack increasing quantities of 1000+°F North American FCCs operate at high severity to maximise
boiling material. Current analysis shows that approximately gasoline and polypropylene. The result is a very heavy,
40% of the industry is cracking some resid. Cracking an aromatic decant oil. Due to low fuel oil production and
unhydrotreated resid might result in a heavier, more specific-gravity limits, US refineries are only able to blend
viscous slurry oil with low aromaticity and high metals low quantities of decant oil in resid, allowing the excess to
content. When resid is added to an existing FCC, ash be sold for other uses such as carbon black feedstock.10
separation might be more difficult because the catalyst The quality of CSO for carbon black feedstock can
removal system must handle a greater volume of more generate as much as US$18.00/bbl of increased revenue,
viscous slurry.9 and increase middle distillate inventory. With separation
Settling tanks for decanting slurry oil have been in use technology in place, a refiner can increase annual revenue
for more than 40 years, and this remains the most popular by not having to use heavy cycle oil (HCO) or light cycle
separation process for removing catalyst in slurry oil. oil (LCO) as cutter stock with the CSO to meet lower
Today, over 61% of refineries use settling tanks to separate concentration specifications, and more middle distillate
catalyst and other contaminates from slurry oil. The can be used to produce lighter products such as diesel.
settling process is very lengthy and creates a larger Regarding the use of LCO, mechanical filtration is limited
challenge once the tank is full of sediment. Refineries must in backwash mediums, and costly HCO/LCO is required for
resort to using settling agents to assist in speeding up the back washing the filters. Electrostatic separation, however,
process. This creates sludge, hazardous waste, and provides an economic advantage over other processes.
This technology uses raw feed from the FCC/RFCC for
back flushing and does not decrease the overall
production of the reactor or rob valuable lighter products.
Middle distillate production is therefore increased, along
with profitability.3
CSO used as carbon black feedstock carries the best
value in lower conversion markets. When sourcing markets
for MCB production, whether it is marine fuel or
highly-profitable specialty carbon black feedstock, a
refiner must decide to increase the quality of the CSO to
meet the unique specification for each market. The
efficiency and reliability of the fines removal technology is
Figure 2. Slurry oil settling tanks. critical to realising increased profits from these markets.
The properties of MCB make it difficult to find a solution

March 2023 48 HYDROCARBON


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without understanding the downsides of each technology. added to the FCC. With constant unit operation, cyclones
Centrifuges have been found to be unsafe and inefficient in the reactor release fines and, over time, larger catalyst
over time. Decanting or settling is only able to provide can escape through this process. With the proper
bunker-grade products with long residence time. With the separation technology in place, lost catalyst, especially in
heavy asphaltene and coke content in severe RFCC or FCC older FCC units, can be recovered and sent back to the
operation, mechanical filtration solutions become blocked riser. This adds greater attrition to the life of the catalyst
or severely eroded, requiring complete disassembly or equilibrium cycle in the FCC, and assists in better
replacement of costly cartridges in order to continue production and operation of the unit. With the recovery
operating. Other technologies are susceptible to plugging of 1900 tpy, savings of over US$1.6 million could be
or blocking due to the inherent plugging properties.6,7 claimed just in catalyst loss and environmental savings.
An electrostatic separator system, referred to as the
‘Gulftronic® Electrostatic Slurry Separator’, has been found Conclusion
to work in concentrated slurries without plugging or The evolution of the refining industry is racing toward
blockage. The electrostatic separator for slurry oil more severe catalytic cracking technologies that are
operates continuously without plugging or blockage from capable of processing heavier opportunistic crudes and
asphaltenes, with an efficiency at the outlet averaging meeting the profitable petrochemical demand. Refining
< 10 ppm catalyst fines after separation. To successfully improvements and petrochemical integrations are allowing
increase refinery profits from the bottom of the barrel, for refineries to make increased profits from every barrel
proven robust technologies such as electrostatic separator processed. Implementing more severe catalytic
technologies are needed to handle the challenges technologies is an important step toward improving
accompanying high severity processing while driving the refinery flexibility. However, as licensors begin to develop
FCC to increase propylene yield.2 new innovative processes and the demand for new
synthetic pyrolysis oil blended crudes becomes more of a
Active response reality, the need for selecting the right separation
There are three factors that should be considered when technology is critical.
determining the feasibility of separation applications to Regardless of the separation path chosen, spent
downstream refinery processes. The first is refinery catalyst removal and waste management will remain one
economics. Not all refineries with the FCC or RFCC of the most difficult processes in the refinery. Settling is
process have the economic parameters needed to justify expensive in terms of lost time and profits. Mechanical
the installation of a catalyst fines removal system. The separation processes are limited and come with costly
second is the severity of the fines. Controlling the quality downtime and maintenance schedules. The refining
of the slurry oil produced can influence the refinery’s industry has evolved away from centrifuges, and filtration
marketable products and downstream maintenance. The technology is becoming harder to operate in the more
third is the cost associated with the environmental impact concentrated slurries. Electrostatic separation is a proven
of removing catalyst fines and particulates from the solution for trouble-free separation of high severity FCC
settling tank. and RFCC slurries. The solution exists with the technology
Not all refineries using FCC/RFCC have a market or of today to increase profits from new markets or recover
economic requirement for producing CSO < 100 ppm. profits from lost revenue for every refinery with an FCC or
Slurry oil is typically 6% of the overall production of the RFCC. It is now up to the refiner to take advantage of this
FCC when the focus is on making transportation solution.
feedstock. If an FCC is smaller than 30 000 bpd, the
economic driver to upgrade a small amount of slurry is not References
1. Website data from http://abarrelfull.wikidot.com/
beneficial, and it becomes more economical to blend 2. SCALCO, V. M., ‘The plight of the modern refinery: racing to meet
cutter stock to meet desired specifications. Larger IMO 2020 regulations’, Hydrocarbon Processing, (November 2019),
complex refineries processing over 30 000 bpd are in the pp. 69 - 73.
3. GUERICO, V. J., ‘US Producing, exporting more slurry oil’,
best economical position to increase profits from Oil & Gas Journal, (4 October 2018).
departiculating process streams such as slurry oil.10 4. ‘Methodology and Specifications Guide, Petroleum Product & Gas
Liquids: US Caribbean and Latin America’, Platts, (January 2021).
Aside from the profitability of increased production 5. SCALCO, V., ‘AFPM ‘19: IMO 2020 and beyond’, (19 March 2019),
and middle distillates, consideration should also be given https://www.hydrocarbonprocessing.com/conference-
news/2019/03/afpm-19-imo-2020-and-beyond
to decreasing downstream maintenance and downtime. 6. HOUSER, T., GIBSON, S., and SCALCO, V., ‘Confronting
With over 60% of the fines in slurry oil’s distribution being unconventional oil’, Hydrocarbon Engineering, (October 2018),
pp. 57 - 62.
< 15 µm, it is very difficult for mechanical filtration or 7. BAI, Z., WANG, H. L., and TU, S. T., ‘Removal of Catalyst Particles
centrifuges to capture smaller fines. Instead, these from Oil Slurry by Hydrocyclone’, Separation Science and
processes allow them to pass through. The corrosive Technology, (2009), pp. 2067 - 2077.
8. MINYARD, W. F., and WOODSON, T. S. ‘Upgrade FCC
element of catalyst passing downstream erodes valves and Slurry Oil with Chemical Settling Aids’, World Refining,
other critical piping systems. (November/December 1999).
9. SILVERMAN, L. D., WINKLER, S.., TIETHOF, J. A., and WITOSHKIN, A.,
‘Matrix effects in catalytic cracking’, presented at the 2018 AFPM
Taking control Annual Meeting, (23 – 25 March 2018).
10. ‘S&P Global Commodity Insights’, S&P Global, https://www.platts.
A reactor running at 80 000 bpd can produce 5600 bpd of com/IM.Platts.Content/InsightAnalysis/IndustrySolutionPapers/
slurry. At this production level, over 16 t of new catalyst is SR-IMO-2020-Global-sulfur-cap-102016.pdf

March 2023 50 HYDROCARBON


ENGINEERING
Ang Chew Peng, Hou Peng-Cheng
and Senthil Krishnamoorthy,
Sulzer, discuss various types of
high-performance trays for large
diameter propylene fractionators.

T
he demand for ethylene and propylene is
growing at approximately 4% annually due to
the rapid increase in demand for polymer and
plastics material used in the packaging,
construction and automobile industries. These basic
raw materials are produced either in gas- or liquid-based
crackers, and propane dehydrogenation units. With the
increase in the capacity of world-scale olefins plants,
the column diameters for ethylene and propylene
splitters are also increasing.
Propylene fractionators, operating in the range of
8 – 20 bar, are characterised by a high number of trays
and high reflux rates. The low relative volatility between
propane and propylene requires tall columns with
200 – 300 actual trays in order to meet the stringent
product specifications of more than 99.5 mol% for
polymer-grade propylene. While minimising the
propylene loss to usually less than 1 mol% in the bottom
stream, these propylene fractionators normally operate
at high reflux ratios, typically in the range of 10 – 15. Due
to the high liquid loads and large diameter in these
columns, high-capacity trays with high-performance
valves and enhanced downcomers are the preferred
mass transfer equipment for these super-fractionators
for an optimised column design.

HYDROCARBON 51 March 2023


ENGINEERING
Propylene fractionators can be designed with different downcomer area, while the weir length only doubles.
types of trays. These columns, with low density difference Increasing the number of liquid passes of the 2 m column
between the vapour and liquid phases, require careful tray to two, while maintaining the same downcomer area,
design that is optimised to handle the high liquid and would increase the overall tray weir length by at least 70%.
vapour volumetric flow rate. Similarly, the weir length of a 4-pass tray will be 2 – 3 times
This article will discuss the various types of longer than that of a 1-pass tray, with the same column
high-performance trays that Sulzer designs for large diameter, downcomer and active area. The longer weir
diameter propylene fractionators. It will also describe the length will result in lower weir loading, thereby reducing
selection of the number of liquid passes as well as the the tray clear liquid height on the deck. This will also
type of downcomers and tray valves, and share a few increase the vapour capacity of the trays.
successful case studies of commercial propylene splitters. As such, as the column diameters increase for the
same service, the number of liquid passes progresses
Selection of number of liquid passes from 2-pass to 4-pass, and even to 6-pass.1 Case study 1
As with any large columns, the propylene fractionators details two propylene fractionators in a series that were
may require multi-pass trays with chordal downcomers. designed with both 4-pass and 6-pass trays, for different
The number of liquid passes usually increases with column diameters.
diameter. For example, 2-pass trays for column diameters
in the range of 3 – 4 m; 4-pass trays for column diameters Case study 1
in the range of 5 – 6 m; and 6-pass trays for column This propylene splitter, built in 2014, is equipped with 228
diameters of more than 7 m. Increasing the number of tray actual trays in two physical columns. The end user
passes as the column diameter increases is the natural preferred conventional straight or sloped downcomer
geometrical progression. As the requirement for tray trays for these new columns, for the possibility of
active area increases to meet the higher vapour loads, the revamping to high-performance trays for future capacity
downcomer area and weir length also need to increase expansion. The upper column, C3 rectifier of 8.8 m dia.,
proportionally to handle the corresponding high liquid was designed with 6-pass MMVGTM trays, while the lower
loads. column, C3 stripper of 6.3 m dia., was designed with 4-pass
Figure 1 shows the geometrical comparison between a MVGTM trays.
1 m and 2 m 1-pass tray. The image illustrates that doubling The tray flow path lengths of these trays are
the column diameter quadruples the active area and approximately similar, at 0.9 m. MMVG and MVG are
Sulzer’s high-performance V-GridTM valves, as seen in
Figure 2. To ensure that the multi-pass trays were
balanced for the optimum mass transfer, Sulzer applied
picket fence weirs to the centre and off-centre
downcomers, to control the liquid split. This propylene
splitter achieved a top propylene specification of more
than 99.7 mol%, while the propylene loss in the bottom
stream was less than 1 mol%, achieving an overall tray
efficiency of 95%.

Application of enhanced downcomer to


improve hydraulic performance
Multi-pass trays such as 2, 4 and 6-pass have two layouts,
Figure 1. Geometrical comparison of 1 m and 2 m whereby the layout with the side downcomers will have
1-pass trays. the shorter total tray weir length. For example, in 4-pass
trays the layout with two off-centre downcomers will have
a longer total weir length, compared to the layout with
one centre and two side downcomers. To increase the
total weir length of the tray, Sulzer ModArcTM
downcomers, as seen in Figure 3, can be applied to the
side downcomers of multi-pass trays. Application of the
ModArc side downcomers will minimise the weir length
difference between the layouts, ensuring consistent
hydraulic behaviour on all trays in the section.
The ModArc profile also improves the distribution of
liquid exiting the bottom of the downcomers. Push valves
are applied at specific locations, especially at the tray
inlets, to ensure that liquid is well distributed across the
tray decks for optimum tray performance. Case study 2
Figure 2. Sulzer high-capacity V-Grid. details a successful application of 6-pass trays designed
with these downcomers.

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Case study 2 new trays, 6-pass trays with ModArc downcomers were
This new propylene splitter, built in 2017, is equipped with applied, as seen in Figure 4. This propylene splitter
248 trays in two physical columns: Tower 1 with 127 trays of achieved a top propylene purity of 99.94 mol% as
7.8 m dia., and Tower 2 with 121 trays of 8.2 m dia. For these compared to the design specification of 99.6 mol%, and
the bottom propylene loss was less than 0.5 mol% as
compared to the design specification of maximum 2 mol%,
obtaining a high overall tray efficiency of 100%.

Application of high-performance trays


with high-capacity fixed valves
For new columns, reducing the column diameter through
the use of high-performance trays, especially when the
column diameters are large, can result in significant savings
in capital investment. Sulzer high-performance trays,
VGPlusTM, as seen in Figure 5, are designed for multi-pass
propylene fractionators. They feature high-capacity MVG
or MMVG fixed valves which boost vapour handling
capacity while minimising tray pressure drop. This is
essential for super-fractionators with high tray count.
Figure 3. 1-pass tray with ModArc downcomers. These trays also feature enhanced downcomers such as
ModArc side downcomers, as well as truncated
downcomers to maximise bubbling area.
The efficacy of the tray technology has been
demonstrated at the independent Fractionation Research
Institute (FRI), in the iso-butane/n-butane system at both
7 and 11 bar. The trays deliver approximately 30% higher
capacity than conventional round valve trays.
For revamps, Sulzer VGPlus high-performance trays are
effective in debottlenecking columns that are fitted with
conventional trays, with proven successes in the revamps
of numerous propylene fractionators. Case study 3
summarises the revamp of propylene fractionators from
4-pass conventional trays to 4-pass VGPlus with ModArc
downcomers for higher capacity, while case study 4
Figure 4. 6-pass trays with ModArc side downcomers. discusses the revamp of propylene fractionators from
4-pass sieve trays to 4-pass VGPlus with ModArc
downcomers for higher tray efficiency.

Case study 3
This propylene splitter is equipped with 263 trays:
C3 rectifier with 170 trays of 7.8 m column dia., and
C3 stripper with 93 trays of 6.6 m column dia. These
columns were originally equipped with 4-pass
conventional float valve trays before being revamped to
4-pass VGPlus trays with MVG valves to handle a 30%
increase in capacity in 2019. ModArc downcomers were
also applied to increase the tray weir length. The
propylene splitter achieved a top propylene purity of
99.79 mol% as compared to the design specification of
minimum 99.6 mol%, and the bottom propylene loss was
less than 4.07 mol% as compared to the design
specification of maximum 4.3 mol%, obtaining a high tray
efficiency of 95%.

Case study 4
This propylene splitter is equipped with 200 actual trays in
two physical columns of approximately 8 m dia. The
column was originally equipped with 4-pass sieve trays.
Figure 5. Sulzer 4-pass VGPlus with ModArc side
downcomers and MVG fixed valves. During the operation, the column suffered significant loss
of propylene in the bottom product at more than

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15 mol%, as compared to the design specification of less trays have multiple downcomers and can have more
than 2 mol%. The calculated tray efficiency was around downcomers than chordal downcomer trays (2-pass,
64%. The original sieve trays with tray dimensions specified 4-pass, 6-pass) at the same column diameter. A Shell HiFi
by the engineering company did not employ any tray tray of 5 m dia. can have eight downcomers, analogous to
balancing techniques, resulting in different vapour/liquid a 7-pass tray, while a Shell HiFi tray of 7 m dia. can have
ratio in each flow pass of the tray design. 12 downcomers, analogous to an 11-pass tray. Their large
Sulzer revamped the columns with 4-pass VGPlus with downcomer top area can handle high liquid loads, while
MMVG tray decks and ModArc side downcomers, applying the longer weir length results in a lower weir loading,
picket fences to the centre downcomers to control the which may improve vapour handling capacity, thereby
liquid split to the panels. After the revamp, the column reducing the column diameters. These trays are also
achieved the top propylene specifications of more than self-balanced as they allow for liquid communication on
99.6 mol%, and the bottom propylene loss was less than the tray decks.
0.98 mol%. Based on the match back of operating Case study 5 summarises one successful application of
condition with measured reflux flow rates, the propylene Shell HiFi Plus trays in propylene fractionators. These are
splitter achieved a tray efficiency of more than 95%, which Shell HiFi trays enhanced with Sulzer high-capacity valves
is an increase of more than 30%. Additionally, the steam such as MVG or MMVG.
flow rate used to drive the heat pump compressor was
reduced by 25%, resulting in substantial savings. Case study 5
This new propylene splitter is equipped with 238 trays in
Multi-downcomer trays for propylene two physical columns: C3 rectifier with 187 trays of
fractionators 6.9 m dia., and C3 stripper with 51 trays of 5.2 m dia. These
Multi-downcomer trays such as Shell HiFiTM trays, as seen columns were designed with Shell HiFi Plus trays with
in Figure 6, are also often applied in columns with high high-capacity MVG valves for an optimum column size.
liquid loads – including propylene fractionators. These The C3 rectifier had 10 downcomer boxes, and the C3
stripper of smaller diameter had eight downcomer boxes.
The propylene splitter achieved the top propylene
specifications of 99.66 mol% as compared to the design
specification of minimum 99.5 mol%, and the bottom
propylene was less than design, achieving a high overall
tray efficiency of 100%.
All of these propylene fractionators success stories are
summarised in Table 1.

Conclusion
Large propylene splitters with high liquid loads have been
designed with a variety of tray designs, ranging from
4-pass and 6-pass high-performance trays, to
multi-downcomer trays.
This article has discussed the selection of a number of
passes and how the features of VGPlus high-performance
Figure 6. Shell HiFi Plus trays with MVG valves. trays, such as high-capacity MVG and MMVG fixed valves
and enhanced ModArc downcomers, can deliver high
vapour and liquid
handling capacity as
Table 1. Summary of Sulzer propylene fractionators well as enhanced
separation
Case study New/revamp Column Column dia. (m) Tray type Overall tray
performance. As
efficiency (%)
evidenced by the five
1 New C3 rectifier 8.8 6-pass MMVG 95
case studies, optimised
C3 stripper 6.3 4-pass MVG design of high-capacity
2 New Tower 1 7.8 6-pass VGPlus 100 trays is crucial to
Tower 2 8.2 6-pass VGPlus achieving superior
3 Revamp C3 rectifier 7.8 4-pass VGPlus 95 performance of these
super-fractionators.
C3 splitter 6.6 4-pass VGPlus
4 Revamp Upper column 8.0 4-pass VGPlus 95
Reference
Lower column 8.0 4-pass VGPlus 1. ANG, CP., and PILLING, M.,
‘Tray design for high
5 New C3 rectifier 6.9 Shell HiFi Plus trays 100 liquid load applications’,
Digital Refining,
C3 stripper 5.2 Shell HiFi Plus trays
(July 2014).

March 2023 56 HYDROCARBON


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Jim Lines, Graham Corp., USA, lists the VDU ejector system
field lessons learned by a performance improvement
engineer, through the lens of four specific case studies.

R
eliable vacuum distillation unit (VDU) performance rests on a number of
variables and equipment that support the distillation process. Proper
ejector system performance is vital to successful operation of the VDU,
and for a refiner to achieve economic goals. For decades, ejector systems
have been the mainstay for evacuating vacuum column overhead vapours and
ensuring that desired column pressure is maintained. Much has been written about
ejector systems – how they operate, what variables impact performance, how to
troubleshoot performance, and best practices. This article discusses recent ejector
system performance issues that a refiner experienced, how the root cause was
diagnosed, and the steps taken to achieve required performance.
Actual VDU process operation is often different from the original design,
especially over two or three decades of service. Process simulations,
request for purchase (RFP) design data sheets, crude slate characteristics, utility supply
conditions, and extent of fouling over time, as examples, all may be different in
operation than was originally designed. The lessons learned from the four case studies

HYDROCARBON 59 March 2023


ENGINEERING
outlined in this article are not unusual as they cover fouling, given the operating pressure of the second and third stage
overhead loading composition, replacement parts that are not ejectors. Both the second and third stage ejectors were
from the original equipment manufacturer (OEM), and operating at pressures below design values, while cooling water
mechanical failure. Fouling is common in a process such as crude temperature was essentially at the design inlet temperature,
oil vacuum distillation, be it shell side or tube side fouling. indicating low cracked gas level and low air leakage.
Overhead load variation from design is typical with changing As time progressed, pressure of the vacuum column
crude slate or as refiners strive to push for more yield or overhead increased to above 20 torr, and the first stage ejectors
throughput. For expediency or cost, local fabricated equipment broke performance. This increased vacuum tower residium and
suppliers may provide replacement equipment rather than the lowered gas oil yield, causing economic loss for the refiner.
OEM. Mechanical issues can arise with ejectors or condensers Fouling was suspected, however this could not be completely
over the life of this equipment, which is typically 30+ years. Each confirmed without inspecting the tube bundles. An engineer
can create ejector system performance shortfall, with significant was dispatched to the site to conduct a pressure and
economic consequences for a refiner. temperature survey ahead of the shutdown, and they remained
The cases that will be covered are from the many sites onsite to inspect the tube bundles once they were removed
visited and performance assessments conducted by ejector from the shells. Tube side fouling was expected due to pressure
system performance improvement engineers. The author wishes drop, as the first intercondenser on the tube side was
to acknowledge that these case studies are from Graham approximately three times design. Figure 1 illustrates the design
performance improvement engineer reports where detailed pressure and temperatures, along with those from the
notes, observations and customer exchange were documented. benchmarking and last survey before shutdown.
No two performance issues may be exactly alike and it is best to From the benchmarking survey (red) nothing stood out as a
consult with specialists in ejector system design, construction, problem. It is observed that the first intercondenser had an
integration into process units, and troubleshooting. Failure to do elevated shell side pressure drop. That does not necessarily
so may extend the search for root cause or lead to corrective suggest a problem. The system is operating with fewer
action that may not resolve a particular performance non-condensible gases than design, as evidenced by the lower
shortcoming. The original equipment supplier is typically the pressure for both the second and third stage ejector. What
best choice for diagnosing what is causing a performance occurs in such a circumstance is the ejector downstream of a
shortcoming with equipment. If the cause is upstream of the condenser that will set the condenser’s outlet temperature,
ejector system, then it makes sense to bring in other outlet pressure, or both in order to match that ejector’s mass
stakeholders, such as a process licensor or process flow handling capacity. It is referred to as ‘over venting’. The
troubleshooting specialist, to complement the ejector OEM. ejector pulls more mass flow rate from the condenser than if the
condenser could independently establish its thermal equilibrium.
Case study 1: intercondenser excessive When this is occurring and the ejector system has parallel
fouling ejectors in operation, one can observe that the pressure drop is
A refiner observed deteriorating vacuum column pressure reduced in the preceding intercondenser and vapour outlet
between turnarounds (see Figure 1). Shortly following initial temperature may lower, when taking one of the ejectors offline.
commercial operation, a benchmarking pressure and Note: this should only be done if over venting is appreciable,
temperature survey was conducted. Column pressure was 1 torr suggesting one of the ejectors may be shut down.
above design, however this was acceptable given that the charge The survey just ahead of the shutdown (purple) highlights a
rate was higher than design. Performance throughout the system problem at the first intercondenser. Tube side pressure drop is
appeared satisfactory, with cracked gases below design level up significantly, and shell pressure and vapour outlet temperature
are elevated compared
to the benchmarking
survey. It was believed
that fouling was the
issue. The tube bundle
was pulled for inspection
and cleaning, and
extensive fouling
build-up was evident on
the shell side of the first
intercondenser. The
cooling water inlet side
of the tubesheet had
substantial debris and
tube hole blockage. As a
result, operating pressure
for the first
intercondenser rose to
Figure 1. Case study 1: pressure and temperature survey. 112 mm HgA. This was
well above the

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maximum discharge capability of the first stage ejector information on the slop oil from the three-phase separator in
and, consequently, performance broke down, resulting in order to understand mass flow rate and composition of the
vacuum column pressure increasing to an undesirable level. hydrocarbon carried over from the vacuum column.
When thermal efficiency declines due to fouling, a Hydrocarbon loading was confirmed to be excessive – three
condenser will respond by increasing its operating pressure. times the design level. Additionally, it was much heavier (higher
This in turn increases log mean temperature difference (LMTD) MW and higher normal boiling point composition). The
to compensate for a lower overall heat transfer rate hydrocarbon in the overhead had a composition more weighted
(Uobserved < Udesign). Tube hole blockage may render a toward kerosene/diesel cut point material.
portion of the surface area unutilised. Hereto, condenser A rough estimate of vapour-liquid equilibrium indicated that
operating pressure will rise. It must be understood that a at 12 – 15 torr and 150˚F, the hydrocarbon in the overhead load
condenser downstream of an ejector will reject the exhaust would consist of 8500 pph liquid mist droplets, and 5500 pph
duty of the ejector. What is important is the pressure at which vapour.
that occurs. If it is below the maximum discharge capability of The engineer and refiner discussed what might be causing
the preceding ejector, then there should not be a problem. such unusual levels of overhead hydrocarbon load, and why it is
However, if above, then the ejector may break operation and two-phase flow. The refiner advised that the tower top reflux
dissipate its compression shockwave. spray distributor was allowing a lot of liquid entrainment in the
overhead load. The engineer discussed their concerns, which
Case study 2: excessive hydrocarbon flow were two-fold. Liquid droplets in the overhead load would
A refiner was unable to achieve VDU column pressure from the negatively impact ejector performance; and the excess
commencement of commercial operation. Design column hydrocarbon and the fact that it enters the condenser as a
overhead pressure was 10 mm Hg abs. For most of the year, the two-phase flow would suppress the overall heat transfer rate
overhead pressure was in the 12 – 15 mm Hg abs range. In the within the condenser.
summer months, when cooling tower water was warmest, There are two adverse consequences from excess
pressure would jump higher, to 20 torr or greater. The refiner was two-phase hydrocarbon loading in the overhead. One is that the
losing approximately US$10 million/yr in lost yield, due to first stage ejector maximum discharge pressure capability is
increased vacuum tower bottoms. reduced. Steam ejectors are momentum transfer devices,
There were a number of site visits by an engineer to perform transferring momentum from high-velocity steam to entrain and
pressure and temperature surveys of the ejector system (see accelerate vapours/gases. The presence of liquid droplets or mist
Figure 2). A pressure and temperature survey of the ejector diminishes the momentum transferred to gases due to the
system in operation identified that the exhaust temperature for density of liquids being so much greater than that of gases.
the first stage ejector was well below what is expected. The second is that the first intercondenser overall heat
Measured exhaust temperature was 190˚F, but was expected to transfer rate will become suppressed due to the presence of
be above 300˚F. There are two possibilities for the low exhaust much greater mass flow rate of hydrocarbon that initially wets
temperature: poor quality motive steam supply conditions (wet the tubing at a much hotter temperature.
steam), or liquid in the VDU overhead load. Steam supply In this case, 8500 pph of entrained liquid in the overhead
conditions proved to be perfectly fine, with steam to the reduced the maximum discharge capability of the first stage
ejectors dry and superheated. This left two-phase VDU ejector 4 to 5 torr. Additionally, the first intercondenser operated
overhead as a possibility. The engineer requested trend with a reduced overall heat transfer rate due to the excess
hydrocarbon. The design
outlet temperature was
95˚F, yielding 3400 pph
of steam equivalent load
to the second stage
ejector. Due to excess
hydrocarbon, the
condenser was thermally
limited, only able to cool
and condense down to
100 – 101˚F. This resulted
in the steam equivalent
load to the second stage
ejector increasing
approximately 35% to
4500 pph. To reject the
necessary heat and
match the capacity of
the second stage
ejector, first
Figure 2. Case study 2: pressure and temperature survey. intercondenser
operating pressure

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rose 3 to 4 torr, thereby increasing LMTD to compensate for a removable bundle replaced in the late 2000s (see Figure 3). The
lower overall heat transfer rate. As a result, the first stage ejector bundle was designed, built and supplied to the refiner by a local
operated in a broken condition during the summer months. shell and tube company rather than the OEM. The company did
The refiner understood the issues at that point. Next came not have the OEM fabrication details for an in-kind replacement.
how to resolve the poor performance problem to achieve After installing the new bundle, the refiner was unable to achieve
design capacity and yield from the VDU. Both the engineer and required vacuum column operating pressure. Vacuum column
refiner felt that it was necessary to address the excessive overhead pressure was more than twice the expected operating
hydrocarbon two-phase flow in the overhead. This would be pressure, holding 24 torr at the overhead at 50% of charge rate vs
addressed by adding a trough distributor into the vacuum a design of 10 torr at full charge rate. The economic impact on
column during an upcoming shutdown in order to reduce liquid the refiner was untenable.
entrainment. The refiner returned to the ejector system OEM for
The refiner then asked whether it was possible to provide assistance. A performance improvement engineer was
greater summertime flexibility and ensure no breakdowns during dispatched, and a partial system pressure and temperature
operation, and jump up into the 20 – 25 mm Hg range. The survey was completed for a quick assessment of how the system
engineer felt that eliminating the excessive hydrocarbon loading was performing. The first intercondenser was operating above its
along with droplets would be enough. However, the ejector design operating pressure, even though the refiner was running it
motive steam nozzles could be replaced. Using the same motive at about 50% charge rate. Motive steam supply condition was
steam consumption and the installed first stage ejectors, the good; the first intercondenser performance did not hint at
new motive steam nozzles would have 5 mm Hg greater fouling or cooling water supply issues.
discharge capability – 80 mm Hg in lieu of current 75 mm Hg. A thermographic scan of the first intercondenser was carried
Providing this added discharge capability would safeguard against out. It was clear that there was maldistribution that lead to poor
performance break for up to 2.5 – 3˚F increase in water performance, as it appeared that flow was compartmentalised
temperature above the design basis. However, the trade-off was with certain cross passes unable to vent non-condensible gases.
1.5 – 2 mm Hg increase vacuum column overhead pressure. The The engineer requested the replacement bundle drawings or
refiner went in that direction, willing to trade off 1.5 – 2 mm Hg in any pictures of it before they were installed. The drawings
operating pressure to avoid 15 mm Hg higher tower pressure in indicated that while a longitudinal baffle was included, as was
the summer months. true for the original design, the baffling was actually full tube
The revamp added a trough distributor and the new steam supports. This resulted in compartmentalising flow. Each
nozzle for the first stage ejectors. Vacuum column overhead cross flow section of the bundle – the space between full tube
pressure after the revamp was 7 – 10 mm Hg, and slop oil rates supports – trapped gases and uncondensed vapour, as they were
confirmed hydrocarbon overhead load was closer to the unable to pass longitudinally to the condenser vapour outlet
4000 pph design basis. The refiner realised anticipated economic connection, rendering a large percentage of the effective surface
gains from the revamp, and did not have summertime area unusable.
performance breakdown. In circling back to the refiner, it was The shell and tube supplier, unfamiliar with vacuum
confirmed that performance of the VDU was on-spec and there condenser design, built the bundle like a complete condenser
had not been a summertime performance break since the revamp. without noncondensible gases, assuming 100% of the flow
would condense. That is never the case for ejector system
Case study 3: non-OEM replacement condensers operating in VDU service or simply operating under
equipment vacuum. There was no way to make the existing new bundles
A refiner had a vacuum distillation ejector system that was work aside from adding a vapour outlet connection for each
originally supplied in 1980 but that had its first intercondenser cross flow compartment, which was not practical. On an
emergency basis, the
refiner ordered a
replacement bundle
from the OEM, built to
the original design.
Performance
returned to satisfactory
condition upon installing
a correctly-built first
intercondenser bundle.
It was a costly
undertaking for the
refiner to replace
recently-purchased tube
bundles, and the process
incurred lost revenue
from an unscheduled
Figure 3. Case study 3: pressure and temperature survey. shutdown between
turnarounds.

March 2023 64 HYDROCARBON


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Case study 4: mechanical damage Conclusion
A refiner was experiencing poor vacuum column performance An ejector system does provide reliable performance and enable
and had noted differences in the thermal scan imagery between refiners to achieve the established operating objectives for
parallel 50% precondensers. The imaging suggested that there VDUs. As with any process equipment, performance limitations
was some type of flow maldistribution negatively impacting one or shortcomings can arise. Having trend data for the ejector
precondenser (see Figure 4). Flow maldistribution led to poor system, as well as system performance surveys that collect
condensation and heat rejection by the precondenser, ultimately relevant pressures, temperatures and flow rates, is always helpful.
increasing vacuum column pressure. It is best to not jump to conclusions or take corrective action
It was not necessary to conduct a performance survey. It hastily, but rather to conduct a methodical performance
was evident that there was a mechanical issue with one of the evaluation and outline potential root causes, working through
precondensers; most likely there was failure at the seal strips, the analysis with the ejector system OEM and process licensor
which aid in blocking flow from entering a particular section of when appropriate. Ejector system suppliers with staff dedicated
the tube bundle and directing flow into the primary condensing to field performance assessment and improvement have a
section. wealth of experience that can be brought to bear for a unique
The engineer requested that the bundle be pulled from the performance shortcoming. Additionally, suppliers with R&D and
poorly-performing precondenser. It was confirmed that the Production Test Facilities will have thousands of data sets for
sealing strips had failed, and this permitted short circuiting of the
how ejectors respond to various operating conditions.
vapour flow bypassing the primary condensing section of the It is always beneficial to have a benchmarking performance
bundle and flowing directly to the vapour outlet connection survey during summer months. This is when an ejector system
(see Figure 5). is usually operating under the most extreme conditions, when
Sealing strips can become damaged during bundle insertion cooling water is warmest. From a planning perspective, carrying
or pulling, and due to corrosion or erosion. In this case, the brass
out a performance survey approximately 18 – 24 months
sealing strips experienced corrosion or erosion damage where before a planned shutdown/turnaround is also a good idea. If
the vacuum column overhead vapours entered the large maintenance CAPEX is needed, this planning will permit
precondenser at 300 ft/sec. To provide operational reliability, the
ample time to identify opportunity for performance
bundles were replaced with a design that did not require seal improvement and to fabricate required replacement or
strips. An alternative consideration was to replace the tube upgraded equipment.
bundles with duplex tubing, bundle cage and sealing strips. Bringing ejector system suppliers into troubleshooting early
However, the refiner elected to utilise a TEMA ‘E’ vs an ‘X’ shell
can quickly help a VDU to perform well. Bringing together three
configuration. key stakeholders to discuss the performance issue is also
valuable. It is not
uncommon that the
views and
interpretation of the
observations or root
cause will vary.
Sometimes this is
because data and
background may
unwittingly not be fully
provided by
stakeholders. Through
healthy and open
dialogue among the
Figure 4. Thermographic image of properly and improperly performing parallel vacuum
precondensers. stakeholders, a deeper
understanding evolves,
resulting in consensus
for root cause and
remedy. All three
stakeholders have the
same objective: enable
the refiner to achieve
operating and
economic objectives.
When all three come to
the troubleshooting
table with refiner needs,
ahead of self interest,
Figure 5. Failed sealing strips (left), proper flow pattern (middle), and improper flow (right). the best outcome for
the refiner is found.

March 2023 66 HYDROCARBON


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Nathan Hill, CALGAVIN, UK,
discusses how to increase
product retention through
retrofitting condensers.

T
he processing and refining industries commonly use Condensers: an introduction
tube-side condensers when driven by requirements Condensers are an important piece of equipment for the
such as low inventories, use of expensive pressure- or chemical processing and refining industries. They are a necessary
corrosion-resistant materials, or as a necessity in component of many processes, i.e. overhead condensers for
air-cooled heat exchangers. distillation columns, and as separators of volatile and
When condensing single-component vapours, heat transfer condensable products. They are also a key feature of HVAC-R
coefficients tend to be high. The situation changes when systems.
condensing multi-component mixtures. Under such conditions, There are different options for the design of shell-and-tube
the performance of condensers is often controlled by the condensers in particular, with condensation possible on the
additional limitations of vapour cooling and mass transport shell-side or tube-side, and in vertical or horizontal
between the liquid and vapour phases, particularly when arrangements. When the condensing fluid is allocated to the
designing for low vapour velocities. tube-side, the presence of two-phase flow introduces
It is possible to improve several aspects of the tube-side complexities in the thermal design. An incremental calculation is
condensation process. The flow regime can be significantly needed, and it becomes necessary to consider how different
altered, allowing for potential benefits to heat and mass transfer. flow regimes will affect the heat and mass transfer within the
This article will use an industrial case study as an example of tubes. This can make the creation of an efficient and reliable
how to ascertain which variables are important to consider in design more difficult.
order to determine whether it would be beneficial to install The application of tube-side enhancement devices can
tube-side enhancement technology. provide significant benefits in many applications.

HYDROCARBON 69 March 2023


ENGINEERING
CALGAVIN’s hiTRAN® Thermal Systems technology is a form
of a removable wire matrix-type enhancement device,
consisting of a pattern of wire loops supported by a central
core wire (see Figure 1). In general, it increases the single-phase
convective heat transfer coefficients, helping to accelerate the
rate of vapour cooling. Also important in multi-component
condensation, the device improves mass transfer and disrupts
the interface between the two phases. This can ensure that
condensable vapour is continually transferred toward the cold
tube wall, and that the liquid is redirected into the bulk flow.
Figure 1. A hiTRAN wire matrix element.
Pure component condensation
It is useful to first consider the simplest case of pure
component condensation – where there is only a single
substance present within the tubes – and how the
characteristics affect heat transfer.
In pure component condensation, there is no change in the
concentration of the condensing substance throughout the
tube. As such, there is no mass transfer resistance preventing
the vapour from reaching the cold liquid interface. Meanwhile,
the bulk temperature is uniform and equal to the saturation
temperature at the corresponding vapour pressure.
As the vapour condenses, a layer of liquid forms on the
tube wall (see Figure 2). The thermal conductivity of the liquid
film causes additional thermal resistance, reducing the rate of
heat transfer from the condensing vapour. The thermal
resistance through the liquid condensate often dominates.
Only at near-complete condensation, where the vapour
velocities are much slower, does the convective heat transfer
of the vapour become a significant factor.
Because the thermal conductivity is an intrinsic property of
the liquid, applying hiTRAN in pure component condensation
Figure 2. Temperature profile across a vapour-liquid tends to have a minimal effect on the heat transfer rate. The
interface. increase in pressure drop also tends to decrease the saturation
temperature, therefore reducing the effective temperature
difference, which often offsets any heat transfer increase. An
overall benefit may be realised towards the end of the
condensation process, where the flow velocities are lower, by
enhancing the convective heat transfer.

Multi-component condensation
When condensing mixtures containing multiple – or
non-condensable – components, the process can change
fundamentally. Firstly, the vapour temperature is not constant
along the condensing path. As each component condenses,
the mole fraction and partial pressure of the less volatile
components in the vapour reduce, and this in turn decreases
the associated saturation temperature. This introduces a
Figure 3. Temperature profile across a vapour-liquid requirement for sensible cooling of the vapour, in addition to
interface with inert components. the removal of the latent heat, in order to advance the
condensation process.
The second major difference vs single-component
Table 1. Geometry of the heat exchanger for case condensation is that the concentration of the different
study components is not necessarily uniform over the cross-section
TEMA type AEM of the tube. The less volatile components condense close to
Orientation Vertical the cold liquid film, depleting the region of condensable
Number of tubes 76 molecules (see Figure 3). Due to the change in concentration,
the local saturation temperature decreases and reduces the
Tube length 3.677 m
temperature difference across the vapour-liquid interface.
Tube diameter 19.05 mm Furthermore, the concentration gradient also creates a mass

March 2023 70 HYDROCARBON


ENGINEERING
transfer resistance, preventing condensable components from the condensing product on the tube-side was much lower
reaching the liquid film. than that of the evaporating feed stream on the shell-side.
Both of these effects can substantially affect the heat flux, Hence, the overall heat transfer coefficient was more strongly
particularly towards the end of the condensation path where controlled by the tube-side, which meant that applying
the lower vapour velocities lead to lower vapour phase heat enhancement to the tube-side would likely have a significant
transfer coefficients. It is in under these conditions that the use effect overall.
of hiTRAN can offer the greatest benefit. Enhancement of the Focusing on the tube-side heat transfer performance, a
single-phase heat transfer coefficients aids cooling of the plot of the cumulative duty against temperature and vapour
vapour, and the induced turbulence improves mixing of the fraction highlighted the areas of concern (see Figure 4).
different components. Furthermore, the lower velocities in this Throughout the full length of this condenser, the vapour
region bring about a lower pressure drop penalty and less temperature decreases rapidly as the condensation proceeds,
effect on the condensing temperature. Due to the effect of indicating a significant requirement for vapour cooling. In total,
momentum recovery, it is sometimes the case that the more than 40°C of sensible cooling was required simply to
pressure drop penalty with hiTRAN will be lower, compared to maintain the vapour mixture at the condensing temperature, in
an empty tube. addition to the latent heat removal. Under these conditions,
the vapour phase heat transfer was controlling thermal
Case study resistance.
CALGAVIN was contacted by a customer to evaluate the Owing to the nature of the mechanical design of the
potential for correcting the observed under-performance of a exchanger, which was made in three sections that were then
vent gas recovery condenser. The condenser was part of a fixed together to form the body of the whole heat exchanger,
refrigeration system that utilised a mixture containing liquid a full-length installation of hiTRAN elements was not possible.
polypropylene as the refrigerant. It was a crucial component to Using the thermal design model that CALGAVIN had created, it
recovering the polypropylene from a waste stream, as this was established that the section of the interchanger where the
stream would otherwise continue onto a flare header, resulting most significant duty took place was the bottom third. As
in the irrecoverable loss of the product. The objective was to such, the hiTRAN elements were designed to fit only the
reduce the mass fraction of polypropylene in the vapour by bottom section of the exchanger in order to provide the
increasing the degree of condensation. maximum level of enhancement within these limitations.
Tables 1 and 2 show the key geometry information and After start-up, the measured plant data was able to
process conditions of the heat exchanger in question. The first confirm the predicted increase in performance. The outlet
important observation is that the heat transfer coefficient of temperature of the condenser decreased from 10°C to -23°C

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with the hiTRAN elements installed. The mass fraction of
Table 2. Process conditions of the heat exchanger
for case study polypropylene of the outlet stream correspondingly reduced
from 25% to 6%. The reduction in mass fraction was equivalent
Shell-side Tube-side
to a quantity of 476 tpy of the polypropylene at the design
Fluid Feed stream Waste stream flow rate. This led to a substantial improvement in operating
Mass flow (kg/hr) 412 843 costs of the process, as more product was able to be
Temperature in/out (˚C) -38 -21 27 -23 recovered, and less vapour flared off.
Economic evaluations carried out by site engineers
Vapour fraction in/out 0.1 1 0.74 0.41
concluded that the propylene savings made from this
Inlet pressure (bar) 1.55 40.3 installation had a payback period for the project of less than
Heat transfer 1000 160 one month, which exceeded initial expectations.
coefficient (Wm2-K)
Conclusion
Through in-house experimental data and customer feedback,
CALGAVIN has seen that the performance of hiTRAN can be
modelled reliably in condensing processes. Through modelling
and analysis, cases where there is a potential for enhancement
can be identified. While there is limited potential in pure
component and shear-controlled conditions, there are much
greater benefits in multi-component applications involving
gravity-controlled flow. The installation of hiTRAN can also be
targeted specifically in areas of the tubes where there is the
greatest benefit overall.
This article has demonstrated the benefits that
enhancement technology can offer to improve the
performance of existing condensers. The use of such
Figure 4. Integral condensing curve and vapour technology is not restricted to retrofitting existing equipment;
fraction along the condensing path. it may also be utilised in new designs to reduce the size of a
condenser and alleviate uncertainties in the calculations.

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Dennis Long, Watlow,
USA, explains the role
that electric process
heaters will have to play
in the decarbonisation of
hydrocarbon processing.

P
rocessing and refining hydrocarbons ultimately What is holding back Scope 1 emission
requires the use of high heat for a number of critical reduction?
steps, and heaters based on fossil fuels have An informal survey of Watlow® customers and prospects has
traditionally filled those roles. But with mounting revealed that 90% of oil and gas leaders are already actively
pressure to mitigate carbon dioxide (CO2) emissions and engaged in decarbonisation efforts. Hydrocarbon processors
advance long-term decarbonisation goals, engineers have been are no longer focused on whether they should decarbonise,
exploring the potential for electric process heaters. This would but rather on how they will decarbonise.
allow several heating steps to be completed using clean The question is: why are electric process heaters not
electricity from renewable sources. more ubiquitous in the energy sector today? Surprisingly,
Importantly, replacing fossil fuel heaters with electric familiarity might be the main reason. Until now, such heaters
heaters would allow for a reduction in Scope 1 CO2 emissions. have only played very limited roles in hydrocarbon processing
Scope 1 emissions are the direct result of burning fuels such as and have tended to be smaller, operating at lower voltages.
natural gas or fuel oil for process heating. Scope 2 emissions Although larger heaters are easily imaginable, engineers
result from the need to import energy, while Scope 3 emissions recognise that a number of questions then arise when it
are produced while using a product (e.g. emissions from car and comes to their control and maintenance. In short, no one
truck tailpipe emissions). All three types of emissions must be wants to be first when it comes to running larger
reduced in order to hit decarbonisation targets. medium-voltage thermal systems.

HYDROCARBON 73 March 2023


ENGINEERING
What engineers might not know is that medium-voltage depend on fossil fuels. Many of those processes would require
process heaters have been developed and used, and their larger electric heaters well above the well-known 1 MW variety,
operation is already well understood. Implementing such for example:
heaters simply requires having the right technical experience, nn Feed/product exchanger, 2 MW (or larger).
and this is experience that is made possible by contracting with nn Dehydration inlet preheater, 3 MW (or larger).
the right partners. nn Heater treater, 4 MW (or larger).
The good news for industry is that modern electric heaters nn Molecular sieve regenerator, 6 MW (or larger).
can provide the same – or improved – performance that nn Waste gas heater, 6 MW (or larger).
hydrocarbon engineers have come to expect from nn Once-through steam generator, 20 MW (or larger).
fossil fuel-powered heaters, and thus can play a key role in nn Crude heater, 28 – 200 MW (or larger).
decarbonisation efforts. nn Hot oil heater, 32 MW (or larger).
nn LNG vaporiser, 34 MW (or larger).
Rethinking the size and scope of nn Thermal oxidiser, 54 MW (or larger).
electric heaters nn Hot water heater, 56 MW (or larger).
To even consider replacing fossil fuel-burning heaters, there nn FCC heaters, 150 – 200 MW (or larger).
needs to be a clear understanding of the current capabilities of
electric process heaters. Replacement does not make sense to Fortunately, heaters that can handle these power
begin with if electric heaters do not come with the required requirements do exist. In terms of physical size, 60 in. nominal
size and power needed to heat processes that currently pipe size (NPS) tubesheets are highly attainable. Nothing
prevents even greater sizes; the technology exists to produce
electric heat exchangers of physical size comparable to a shell
and tube heat exchanger. An electric heat exchanger of the
same physical size (as a shell and tube) will have a larger
available heating duty, due to the constant heat flux
technology.
With equipment of this size, a single vessel can have two
heat exchanger bundles. Such a set-up can produce a single
Figure 1. An electric heat exchanger. process vessel with a 15 MW duty rating or more. The few
suppliers providing electric heaters at this scale can raise or
lower the duty rating as technical requirements dictate. This
kind of size and power presents a viable alternative for
operations currently fired by fossil fuels.

What about control?


Some of the most common questions about larger process
heaters have to do with control:
nn What additional elements are needed to ramp up the
heater?
nn How does turn-on/ramp-up affect the existing electrical
system?
nn How is temperature monitored and controlled?
nn What additional safety precautions are needed?

Just because larger electric heaters have not traditionally


been used to heat all processes in the petrochemical industry
does not mean that the technology is theoretical or untested
– far from it. Field-proven power switching devices have been
in use for low-voltage electric process heaters and electric
medium-voltage motors in a number of industries for years,
and the ability to control voltage is well established.
Programmable logic controllers (PLCs) and similar power
management systems bring heaters online in ways that do not
cause problems for other devices connected to the same
power source. The heater and controller are part of one
closed-loop system, which streamlines integration and yields
more control over the entire system. This technology’s tried
and true nature in other applications reduces the risk for
petrochemical process heating.
Figure 2. The POWERSAFE solution. Watlow’s engineers have built such controls into the
company’s POWERSAFETM solution. This is a medium-voltage

March 2023 74 HYDROCARBON


ENGINEERING
10-13 JULY
10-13 JULY
heating and control solution that combines both an electric OPEX
heat exchanger and a control system. The system has been OPEX includes things such as routine maintenance, as well as the
proven to operate safely and reliably even at 4160 V and higher. cost of electricity itself. The routine maintenance cost of electric
It also offers a flexible combination of a silcone controlled heating systems is typically lower than a natural gas or
rectifier (SCR) and contactor circuits of up to 25 MW within a similarly-fired system. Electrical systems have no burner to
single control package, delivering high-efficiency power greater maintain, and the heat exchanger bundle cleaning schedule is
than 99%, which reduces the overall size and weight of the typically the same as a non-electric shell and tube technology.
power controller solution. Medium-voltage connections result As for electricity, costs will vary by region if electricity is bought
in much lower amperage as compared to low-voltage, so the from the existing grid. That said, the cost of renewable
end user realises much lower connection cabling costs. generation systems themselves has dropped dramatically since
The system meets strict requirements for safety and 2010, and continues to fall. Many organisations may well choose
reliability, too. It has been designed with a high-speed to generate their own renewable power anyway.
protective relay, rapid shutdown breaker, optimal fluid
dynamics, and safety interlocks to maintain control over a wide Human capital and the learning curve
variety of thermal processes. Thus, control and safety are built Finally, there is the question of human capital and the
into the technology, offering a clean, safe and long-lasting availability of relevant engineering expertise. Manufacturing
asset for engineers tasked with decarbonising thermal systems. processes with fossil fuels are ubiquitous; as is the equipment
that runs said processes. Additionally, while most companies
The other consideration: investment will have electrical engineers or staff familiar with large
and cost electrical equipment such as motors, not all will have extensive
While familiarity might be the biggest barrier to implementing field experience with electric process heaters. This means
electric heaters into hydrocarbon processing, one cannot ignore something of a learning curve, though that learning curve is
the fact that cost is also a huge consideration. There are three much easier when an organisation can team up with a
primary types of expenses to consider when transitioning to knowledgeable partner.
electric-powered equipment: CAPEX, OPEX, and human learning
expenditures. Electrification is even more
worthwhile now
CAPEX to change equipment The discussion of costs might trigger some decision makers to
The equipment itself is the first significant cost associated with get their spreadsheets out. If there is going to be significant
electrification. Beyond the cost of new equipment, there is also CAPEX, not to mention operating costs and human capital costs,
the cost of integrating electric process heaters into the existing when can operators begin to see a return on investment (ROI)?
electrical grid and ensuring their smooth operation, including What is the break-even point?
technology to store electricity that comes from renewable Of course, every organisation will have to factor in their own
sources as well as control technology to ensure that the local local regulations and incentives, and so the mathematics might
grid is not stressed or overloaded. look different in each instance. However, the pressure to reduce
emissions leaves little doubt that the pace of electrification will
only intensify.
There are other benefits of electrification to consider, too,
as well as new developments in the technology. Today,
processors are in an even better place when it comes to efficient
electric heaters for hydrocarbon processing than, say, five years
ago.

Additional advantages of electrification


Besides reducing the use of fossil fuels, electric heaters and
heat exchangers have other well-documented advantages,
including the following:
nn Less thermal lag: temperature is controlled through direct
application of electricity.
nn Safer operation: no fossil fuels to burn or combust.
nn Less coking/fouling: with the right electric heater,
coking/fouling becomes a thing of the past, meaning longer
heater life.
nn Increased watt densities: higher watt density ratings allow
equipment to be designed smaller, thus lowering capital
equipment costs, keeping costs down, and reducing the
overall footprint – while meeting temperature requirements.
Figure 3. The HELIMAX solution. Top: CHF technology. nn Smaller overall footprint: constant heat flux capability results
Bottom: fully-developed flow pattern. in a smaller footprint as compared to the non-constant heat
flux in shell and tube heat exchangers.

March 2023 76 HYDROCARBON


ENGINEERING
Different technologies heat flux emanating from the effective heater surface, while a
An example of a heater that achieves all of the above is Watlow’s heater’s watt density rating is used in thermal calculations to
HELIMAXTM, which uses Continuous Helical Flow (CHF) determine approximate heater skin temperatures in the
TechnologyTM. With CHF, the baffles within the heater do not application. Smaller heater package designs using higher watt
exist as discrete elements, but rather as a single continuous spiral densities will always meet critical specifications for sheath
winding around the interior of the shell side of the heater. This temperature, shell temperature, and other customer
further forces the flow to be rotational and helical, resulting in an constraints – while also reducing overall footprint.
even better heat transfer coefficient per unit pressure drop
compared with more traditional segmental baffles. Conclusion
Because the flow is continuous and uniform, the heater does Now is a good time for engineers who are not already familiar
not experience dead zones or areas with insufficient flow. There with electric process heating systems and heat exchangers to
are no disruptions to flow either, and so there is dramatically less introduce themselves to new technologies. Gaining familiarity
likelihood that hot spots can develop. Without hot spots or with electric process heating systems now will reduce the
dead zones where material can collect and adhere, there is burden of the energy transition later.
potential for greatly reduced fouling rates. The improved heat Specifically, engineers are realising two things. First, there
transfer compared to legacy technologies also means that these are far more opportunities to use electric process heating
heaters have a much smaller footprint, thus allowing the process systems – and with far fewer size constraints – than previously
machinery to make a much more efficient use of space. imagined. Second, control of these MW-size heating systems is
A single, removable HELIMAX bundle can supply up to demonstrated in field applications, with precise control of
5 MW of power duty range, even with a smaller footprint than process and skin temperatures.
fuel-based heat exchangers. Combining this efficiency with the Companies such as Watlow are solving the world’s most
reduced need for maintenance to address coking creates a challenging and essential thermal problems. The work includes
product that increases productivity even as it contributes to breaking down the barriers to energy transition to provide
decarbonisation efforts. This heat exchanger can also last longer clean, efficient and reliable ways to electrify processes
and avoid system failure because it is not as susceptible to traditionally heated with fossil fuels. Working with a reliable
fouling. partner to electrify process heating systems is one of the
Finally, modern heaters such as HELIMAX have been proven surest ways to progress toward climate action goals without
to achieve higher watt density ratings. Note: watt density is the interrupting productivity or profitability.

Travelling from sea depths to outer space


with simulation and diagnostics since 1991

Predictive diagnostics, simulation and knowledge extraction


from telemetry data of hydrocarbon and energy systems

Santa Croce 664/a, 30135 VENICE (ITALY)


www.sate-italy.com
HYDROCARBON 77 March 2023
ENGINEERING
MAY
I N T E R N AT I O N A L
O P E R AT I N G
CONFERENCE

2023
& T R A D E S H OW

22-24
Houston, TX

Keynote Speakers
CLOSING KEYNOTE
Tuesday, May 23

Daniel Yergin
Global Authority on Energy, Geopolitics and the Business,
Economic and Societal Impacts of the Changing Energy
World; Pulitzer Prize-Winning, Bestselling Author;
Vice Chairman, S&P Global; Chairman, CERAWeek; Director, Council on
Foreign Relations; Trustee, Brookings Institution; Author, The New Map (2020),
The Prize (2011, Pulitzer Prize Winner), The Quest (2011) and The Commanding
Heights (2002); 2020 Energy Writer of the Year.

OPENING KEYNOTE KEYNOTE BREAKFAST


Monday, May 22 Tuesday, May 23

Jason Dorsey Captain Scott Kelly


Leading researcher, advisor and author History-making NASA Astronaut;
focusing on uncovering hidden insights First to complete a Year-in-Space mission.
and new strategies that future-proof A former U.S. Navy fighter pilot, test pilot,
organizations. He has led nearly 100 and veteran of four spaceflights, Kelly
research studies to separate myth from commanded the space shuttle ENDEAVOUR
truth for leaders.Author, Zconomy: in 2007 and twice commanded the Interna-
How Gen Z Will Change the Future of tional Space Station. Author, Endurance:
Business and What to Do About It. A Year in Space, a Lifetime of Discovery.

Register today! ilta.


JOIN US AT THE PREMIER ANNUAL EVENT for liquid terminal
owners and aboveground storage tank operators. org
Tom Gilmartin, Zerosumheater and a consultant for
Quest Integrity, considers the effect of fouling on heater services,
and introduces a new approach for confirming coil cleanliness.

H
eater tube inspection is almost The consequences of some strategies that
exclusively looked after by the may be used to alleviate high tube temperatures
inspection team at a facility. Innovative caused by fouling will be expanded upon – from
inspection techniques such as smart running the furnace inefficiently, to cutting coil
pigging and, most recently, Quest Integrity’s outlet temperature and finally throughput. The
Advanced Decoking and Cleanliness Verification commercial impact of this will be discussed for
(ADCVTM) inspection (Figure 1), offer additional these cases. In short, using a more advanced
information that is particularly useful to a cleaning method, as compared to convection
process engineer in order to avoid production mechanical decoking, can provide many benefits.
slowdowns or unplanned mechanical cleaning
(pigging) outages. Example simulations and cases
Even a small amount of fouling in the radiant Using a range of coke thermal conductivities and
section of a vacuum heater adversely affects thicknesses, a vacuum heater was simulated to
nitrogen oxides (NOx), production run times, and show the effect of coke laydown on heater
overall performance of the fired heater. What is tubes, and its impact on heater performance in
sometimes not realised is that even a localised terms of fired and process duty and
area of 5 mm of coke left in a coil can have a environmental emissions.
significant impact on margin capture. This could A 27.9 MW process duty vacuum furnace was
lead to a yearly loss in production of used to demonstrate the effect of fouling on the
US$12.6 million, or significantly more. Test results overall heater performance. The heater coils are
discussed in this article will demonstrate the horizontal, with four passes and incremental
benefit of knowing where fouling (e.g. coke and tube sizes increasing in size towards the outlet.
scale) has formed in a heater coil, and why being The tube material used is 5% chromium (Cr) with
confident that the coils are cleaned properly a maximum design temperature of 650˚C. A coil
after a decoke or descale is crucial. outlet temperature (COT) of 383˚C was selected,

HYDROCARBON 79 March 2023


ENGINEERING
as this bridges the temperature range used in vacuum and the thermal properties of coke, which changes with the
crude heaters. temperature and morphology of the accumulated coke. As a
Nine cases were considered: comparison, the thermal conductivity of 5% Cr is around
nn Base case (no internal fouling). 40 W/mK at 20˚C.
nn 1 mm and 5 mm fouling throughout the entire radiant The process duty was maintained during this exercise,
section tubes, with coke thermal conductivities of with the firing rate adjusted to compensate.
1.5 and 3 W/mK. The effect of the fouling on key aspects of the fired
nn Localised fouling with 1 mm and 5 mm coke, again in the heater radiant and convection section performance is shown
radiant section, with coke thermal conductivities of in Table 1 for fouling throughout the entire radiant section.
1.5 and 3 W/mK.
Review of data for heater performance
Fouling thickness was held constant at 1 mm and 5 mm
for widespread and localised fouling, using the Environmental – NOx
aforementioned coke thermal conductivities. This reflects nn 1.5 W/mK case: 2.4% increase (1 mm fouling) and 12%
increase (5 mm fouling) in the radiant section.
n 3 W/mK case: 1% and 6% increase. The driving
source is the added fire box temperature.

Note that some units may have a fixed


maximum environmental-permitted NOx limit that
may lead to a consequential reduction in firing.

Fired duty increases slightly with


fouling added
Figure 1. Quest Integrity ADCV service. The overall heater efficiency decreases a small
amount with fouling, with a more significant
decrease in radiant section
Table 1. Fouling throughout the radiant section only (no fouling in convection) absorbed duty (0.7 – 3.5%
reduction for the 1.5 W/mK
1.5 W/mK thermal conductivity 3 W/mK thermal conductivity
case and 0.4 – 1.7% for the
No fouling 1 mm Change 5 mm Change 1 mm Change 5 mm Change
3 W/mK case). The reason
(base) thick thick thick thick
for this is less effective
Firing rate (MW) 33.55 33.56 +0.1% 33.7 +0.4% 33.57 +0.1% 33.6 +0.1%
heat pick up in the radiant
Bridge wall 736 746.3 +10.3 789.6 +53.6 741 +5.1 762.3 +26.3 section.
temperature
(BWT) (˚C)
As the radiant
Tube skin 419 463 +44 635 +21 441 +22 530 +111 section fouls, several
temperature (°C) *
things happen:
NOx (ppm) 25 25.6 +2.4% 28.2 +12% 25.3 +1% 26.5 +6% n Efficiency drops. The
Absorbed fire box 74.6 73.9 -0.7% 71.1 -3.5 74.2 -0.4 72.9 -1.7 effective heat pick up
duty (%) in the radiant section
Stack temperature 324.6 325.9 +1.1 330.4 +5.6 326.8 +0.6 327.6 +2.8 decreases. The
(°C) process duty
Total heater fired 82.9 82.9 - 82.6 -0.3 82.9 - 82.7 -0.2 absorbed in the
efficiency (%) radiant section
Note: a constant process duty of 27.9 MW was used for all cases reduces, dropping
*A bulk process temperature of 383°C is calculated at the referenced skin thermocouple location from a base level of

Table 2. Alleviating skin temperatures by running furnace at maximum oxygen


4% oxygen: no fouling 4% oxygen: 5 mm thick, 1.5 W/mK 9.7% oxygen: 5 mm thick, 1.5 W/mK
Firing rate (MW) 33.5 33.7 37.1
BWT (°C) 736 790 768
Skin (383˚C bulk) 419 635 606
NOx (ppm) 25 28.2 34.4
Absorbed fire box (%) 74.6 71.1 62.3
Stack temperature (°C) 324.8 330.4 364.2
Efficiency (%) 82.9 82.6 74.9

March 2023 80 HYDROCARBON


ENGINEERING
74.6% to 71.1% in the most fouled case. As such, an increase Visual inspection and thermography of the fire box can
in flue gas temperature to the convection section, as well provide further insights on fouling.
as an increase in NOx production, will occur. In addition to this, there is severe impact on tube
nn Tube skin temperatures increase. In the worst case temperature limits and heater performance. In this service,
scenario (1.5 W/mK, 5 mm) there is a significant impact tubes are typically 5 – 9% Cr with tube metal temperature
despite the fouling thickness remaining minor. Tube metal (TMT) limits of usually 650˚C (5% Cr) and 705˚C (9% Cr). In
temperatures increase from 419˚C to 635˚C to achieve the this simulation, using 5% Cr, API530 gives a limiting design
same COT with a less effective radiant section. This is temperature of 650˚C, however this is for creep properties.
close to the tube temperature limits for a 5% Cr tube A more commonly used limit is 593˚C to avoid rapid
(650˚C). This article will go on to discuss why some oxidation of the tube external surface. In this case, if 593˚C
end users may use a lower temperature limit of 593˚C. was used instead of 650˚C, a cut back in heater operation
nn Radiant section fire box temperature is still acceptable may be required. Options are considered in the next
at a maximum case of 789.6˚C. Typically, fired heaters section.
have a maximum fire box temperature of 850 – 900˚C
in this service, partially to protect the tube hangers, and Options to deal with high tube skin
also to reduce coking tendency of the feed in the temperatures
radiant coil. This limit is important when processing nn Material choice: 9 Cr steel (705˚C limit) would provide
opportunity feeds, which may be more sensitive to some headroom, but not much.
thermal breakdown. Fouling is driving the radiant section nn Special operational techniques: used to mitigate and
closer to these limits. maintain run time – sometimes they work, sometimes
they do not. Increasing oxygen, cutting COT, and
The following is a process engineer’s perspective on cutting rate are discussed.
these numbers during routine monitoring:
nn Tube skin temperatures: the largest noticeable change, A technique sometimes used to alleviate skin
but assumes thermocouples are in the correct location. temperatures is to run the furnace at maximum oxygen in
nn BWT or fire box temperature: the next indicator with a order to move furnace duty from the radiant to the
significant change. convection section. Table 2 lists an example of this.
nn Fired duty and heater efficiency: changes too small to Skin temperatures have dropped by approximately
notice.
Hallwood_HE_March_05.pdf 1 15/02/2023 08:50 30˚C, but at the cost of a significant increase in fired duty.



     

      

    

     


Additional fuel duty and furnace efficiency drop off The 1.5 W/mK case
significantly. The NOx is likely to go up as well, requiring The tube temperature needs to come down below the
correction. oxidation temperature of 593˚C for 5% Cr, rather than the
API 530 limiting metal temperature of 650˚C. Increasing
Some critical comments on these oxygen in the previous example worked to an extent, but
results reached a draft limitation. Shutdown for a mechanical
This is just a simulation. It is unrealistic to lay coke down cleaning to remove this coke is not preferred. The other
through the whole radiant section, with two exceptions: options are as shown in Table 4:
nn There are times where an entire coil can coke up nn Drop COT by 10˚C: tube temperatures reduced by 10˚C
quickly, such as a low flow situation occurring in a coil; to 626˚C, which did not help much, and column cuts
a coil control valve closing or jamming; incorrectly-set may go off specification.
low flow trips; or a slow response to a low flow event. nn Cut the rate: a 20% cut brings tube temperatures back
nn The heater has never been pigged and does not suffer to the tube limit.
from high skin temperatures. In this situation, coke may
be present but has been accepted as the normal Commercial consequences of a 20%
baseline for heater operation. rate cut
The more common situation Example: 3250 bpd rate cut example at
Although fouling across an entire heater coil is not typically US$10/bpd margin. US$12 million/yr
seen, there tends to be specific areas that are most exposed A unit must be ready to take advantage of margin capture
to formation in terms of heat flux. Data is reviewed again in whilst it lasts. Even a small amount of fouling affects the
Table 3, this time ignoring all changes apart from skin overall ability of the heater, reducing margins and run time.
temperatures. The localised coke is driving up skin A special case is outlined in Table 5, where just a 2 mm
temperatures. An important thing to note is that tube increase in coke can have a dramatic effect on heater
temperatures are controlled by the effective heat transfer operation. 7 mm coke is not that abnormal to find (in fact
across the tube. 10 – 15 mm is more common) after tubes have been
removed following a coking event. In this case, the heater
Dealing with localised fouling will need to go offline for unplanned pigging, with an
Here, only the simulated cases are used without the estimated outage of 10 days – not including time to replace
additional allowance for skin thermocouple type. damaged tubes.

Routinely pigged
Table 3. Localised fouling in radiant section only (no fouling in convection) heaters
A coke layer increases tube
Tube skin temperatures 1.5 W/mK thermal conductivity 3 W/mK thermal conductivity
only metal temperature. Above
593˚C (5% Cr) the external
Constant 0 mm thick 1 mm Change 5 mm Change 1 mm Change 5 mm Change
process duty (no fouling) thick thick thick thick surface of the tube starts to
oxidise, removing tube
Tube skin 419°C 463°C +44°C 635°C +216°C 441°C +22°C 530°C +111°C
temperature thickness. Over time, the
for a tube develops a classic
383°C bulk bulge profile. The coke sits
process feed in that bulge (see Figure 2).
temperature
This is well documented:
Adding 439°C +64°C 655°C +236°C 461°C +42°C 550°C +131°C leaving this coke in place or
allowance for
in other places on the tube
thermocouple
design +20°C wall where conventional
mechanical decoking
Adding 459°C 503°C +84°C 675°C +256°C 481°C +62°C 570°C +151°C
allowance for cannot detect and remove
thermocouple it can lead to instant regret
design +40°C at start-up. Pressure drop
and coke fines during a
pigging operation is a very
Table 4. Dropping COT to reduce tube temperatures subjective method of
Condition Skin (˚C) BWT (˚C) Average heat flux Peak film cleanliness verification, and
(W/m2) temperature (°C) is rarely supervised by plant
Start COT 383°C 636 789 32 777 402 personnel.
COT reduction 10°C cut 626 - - - A question to ask is
Rate reduction -10% 612 761 30 078 400 whether it is sufficient to
carry out an ultrasonic (UT)
Rate reduction -20% 590 731 27 275 398
smart pigging run after

March 2023 82 HYDROCARBON


ENGINEERING
NISTM
NATIONAL INSTITUTE FOR STORAGE TANK MANAGEMENT
mechanical pig cleaning in order to confirm cleanliness. other areas. These areas may have coke present. Hard
The answer is that whilst this works, operators have no fouling left over from previous cleanings can be left
idea where the fouling was and what tubes were exposed behind in areas of non-deformed tubing, going
to it before the start of mechanical cleaning. Knowing this completely unnoticed during current mechanical cleaning
information provides insight into the firing profile, correct operations.
skin temperature indicator (TI) placement, where The ability of a mechanical pig to clean tubes is
thermography readings should be taken, future run time typically based on two things:
forecasting, and possible carburisation and oxidation nn Size and type of mechanical pig (studs).
damage locations – to name a few. nn Number of cleaning cycles required to grind out coke
(500 – 1000 cycles).
Innovative techniques
Standard mechanical pigging uses hard body metal For stubborn areas of coke, there is a risk of damaging
studded pigs that are oversized. There is an oversize limit (grooving) the actual tube in clean areas. ADCV has the
– too large, and tube metal is removed. advantage of identifying areas of coke and allowing for
How does a pigging contractor know whether tubes close attention of the pigging cycle in only those areas.
are clean? This can be accomplished by monitoring water
quality during cleaning operation and looking at the Initial inspection results
pressure traces for each pass. However, this approach Localised areas of 5 mm coke were found in several crude
leaves a lot of doubt. If there are bulges in the tube, and vacuum heaters. ADCV was used to identify these
these will not show as being significantly different from areas and selectively target them for coil cleaning,
completely removing the coke. The process impact of
these areas was not reported by the end users, however
the previous simulations offer a good indication of
potential consequences. Integrating the ADCV results
with heater process data before and after will assist with
the optimisation of the heater.

Outline of the process steps:


nn Initial ADCV survey using smart pigs ultrasonically
maps the location and thickness of the fouling.
nn Mechanical cleaning team removes the bulk of the
fouling using studded pigs.
nn Cleanliness verification using the smart pig checks the
result, fine tuning any additional mechanical pigging
operations.
nn Areas that were not able to be cleaned are reported
to the client for further investigation. These are
important areas; any bulging or major deformation in
a tube caused by overheating may not be cleanable
Figure 2. Coke in bulged tube. by a mechanical pig.

Conclusion
Table 5. Localised fouling in radiant section only Fouling in a heater makes a significant difference to a
excerpt (no fouling in convection) heater’s safety, environmental and commercial
Tube skin temperatures 1.5 W/mK thermal conductivity performance. As coke is the dominant reason for high
only tube skin temperatures for normal furnace parameters,
Constant 0 mm thick 5 mm Change 7 mm thick the thickness of the coke matters. Knowing that all of the
process duty (no fouling) thick fouling has been removed and where it initially formed
Tube skin 419°C 635°C +216°C 727°C – and where it did not – allows an informed view on past
temperature and future heater operations, and most importantly
for a 383°C bulk avoids running the heater sub-optimally until the next
process feed
temperature
turnaround.
Adding 439°C 655°C +236°C 747°C
allowance for
Notes
1. The original expanded version of this article is available as a
thermocouple white paper on Hydrocarbon Engineering’s website. Download a
design +20°C copy for added insights: https://www.hydrocarbonengineering.com/
Adding 459°C 675°C +256°C 767°C whitepapers/quest-integrity/heater-tube-cleaning-and-verification-
the-effect-of-fouling-on-heater-services-that-are-prone-to-coking-
allowance for
from-a-process-engineers-perspective/
thermocouple 2. The author of this article, Tom Gilmartin (Bsc, Msc, C.Eng), is a 30-year
design +40°C BP veteran and the company’s former fired heater and flare advisor.

March 2023 84 HYDROCARBON


ENGINEERING
Figure 1. Capturing the natural gas or methane wasted
each year across the oil and gas industry would mean
progress for both the climate and energy crisis.

W
Mark Naples, Umicore Coating Services e cannot always see the
consequences of air pollution around
Ltd, details how connected gas detection us, and there are communication
technology can help companies to comply issues surrounding efforts to get
people to see the invisible costs of pollution. The
with ESG needs. global economy loses more than US$8 trillion
annually, according to The World Bank1, but action
to identify its presence and catalogue its make-up
and levels still lags.

HYDROCARBON 85 March 2023


ENGINEERING
closely at their health and safety,
environmental, and social practices to
ensure compliance with legislation and
ethical expectations.
By embracing data, the industry can be
empowered to make more informed
decisions to improve processes and drive
efficiencies. The net result is more
sustainable performance, heightened
productivity, better quality products,
reduced energy usage, fewer emissions,
and less landfill, and this is the sort of
future that we all need to invest in.
Technology is now more affordable
and accessible than ever, and can help
companies to comply with ESG needs.
Connected gas detection is not the
Figure 2. Corporations leading on climate action are looking for the technology of the future anymore; it is
next generation of climate technologies to invest in and scale to meet right here, and more money-saving,
deep decarbonisation targets. sustainable and straightforward than one
might think.
Industrial gas is used extensively by
The problem is that when we visualise air pollution, various industries – from medical oxygen in hospitals, to
we tend to picture a blanket of smoke. However, just being used in the production process to manufacture
because we cannot see visible clouds of pollution does chemicals, electronics and metals. Its critical position at
not mean that it is not affecting us. Not only are these the heart of the industry presents an opportunity to
harmful pollutants invisible to the human eye, but they better track, monitor and assess gas usage to reduce
are sometimes odourless and tasteless. Yet another the industry’s environmental impact and boost its
layer of difficulty is that they are often found in volatile efficiency.
and inaccessible environments. The most common The gas detection system market is expected to
types of toxic gases found in modern industrial grow at a CAGR of 8.64% through to 20262, and for
workplaces include ammonia, methane, hydrogen good reason. With increasingly critical decisions reliant
sulfide (H2S), chlorine, carbon monoxide (CO), and upon gas and particulate monitoring, the appetite for
carbon dioxide (CO 2). meticulous IR gas sensing is growing.
Thankfully, huge advances in sensor technology have It remains vital that technology is adapted to the
activated a range of reliable options for gas detection, application. Increasingly, Umicore Coating Services is
and the enormous advantages of infrared (IR) working with clients at an early stage of sourcing, and
spectroscopy in detecting hydrocarbons and hazardous defining optimum solutions.
chemicals are now well established. The hardware and firmware configuration can also
significantly affect the performance and stability of an
Mitigating risks IR gas detector. The use of processors, algorithms and
It is incumbent on all of us across our industries to optical hardware configurations can distinguish between
deliver improvements in efficiency, embrace a highly stable device that minimises cross-interference
technological advances, streamline our work, and from other gases such as CO 2, and compounds such as
ultimately reduce the environmental impact of our water, or a device that produces spurious alarms and
activities. The rise in environmental, social and other operational issues.
governance (ESG) focus is driven by a growing urgency Industrial gas detection is a mature market that
for individuals and corporations alike to tackle one of continues to expand as devices become cheaper at the
the world’s most pressing problems: climate change. compliance end of the market, and smarter at the top
Many companies are committing to the incorporation end. On the one hand, Umicore works with original
of ESG and net zero targets into operations as they face equipment manufacturers (OEMs) – stripping their
increasing investor and consumer pressure, mandatory devices back to basics, focusing on functionality and
government climate risk disclosure, and stricter cost for low-cost markets. On the other, the company
environmental regulations. By adopting measures based assists in driving advances to open up new
on data provided by intelligent sensors, organisations opportunities and allow end users to use their devices
can improve their ESG compliance and enhance their in ways that have not been considered before.
contributions to people, the planet and profit. In today’s industrial workplace, if you are a safety or
With increased levels of corporate transparency, operations manager looking to build or sustain a robust
organisations are exercising a high degree of moral and safety culture, it is no longer a ‘nice-to-have’, but rather
ethical leadership, and companies are looking more a key requirement of the business.

March 2023 86 HYDROCARBON


ENGINEERING
Keep sensing it absorption of IR radiation as it passes through a volume
Climate change and its perceived impacts – from of the gas.
projected warming of the Earth through to Among their benefits are fast response times and
anthropogenic global warming – have instituted accurate results, without the requirement of additional
profound changes in how the world approaches energy gases for operation. Technological advances have also
sources. The primary focus is on reducing CO2 and resulted in detectors that continuously monitor
methane – CO2 because it is by far the most prevalent combustible gases and vapours within the lower
greenhouse gas (GHG), and methane because of the explosive limit, and provide alarm indications. These can
intensity of its impact in the first several years after it is be deployed within oxygen-deficient or enriched areas,
emitted into the atmosphere. GHGs are generated at require little calibration, and are immune to sensor
almost every step in production, delivery, processing or poison, contamination or corrosion.
refining, and especially the consumption of fossil fuels. Newer gas analyser instruments use a laser diode
Companies that are proactive in minimising leaks and mounted on a thermo-electric cooler to tune a laser
eliminating vents must acknowledge that the effort is a wavelength to the specific absorption wavelength of a
long-term investment, requiring a multi-tool approach particular molecule. They exploit their high-frequency
and active engagement. resolution, which results in enhanced sensitivity – more
Regulation enforcement has increasingly restricted significant levels of interaction between gas molecules
the emissions that oil and gas producers may release, and light in the order of parts per billion (ppb) – and
but industry opinion and corporate responsibility have selectivity, as they are tuned to a specific compound of
pushed that objective further. gas. This absorption technology ensures precise gas
In the market for measuring emissions, there are recognition, eliminating the potential for false alarms,
many different measuring technologies. Umicore’s IR gas which is an issue with other commonly used gas
detection filters are essential to many of these. detection technologies.
IR emitters within the sensor generate beams of IR
light. And, having passed through a sampling chamber, a Safety is not expensive; it is priceless
filter in front of the detector blocks out light that is Even with the most reliable instruments, the likelihood
not at the desired wavelength. In contrast, the detector of workers being injured or killed on the job remains
measures the intensity or attenuation. This is then used high if the devices are not used properly. In an
to determine the concentration based on the organisation with a weak safety culture or poor

Keep Updated

Discover

Keep up to
date with us to
hear the latest
downstream oil From prototype design to In-house dicing capability
production scale-up services
and gas news NIR to FIR filter expertise
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For more news visit:
Tel: +44 1382 833 022 HYDROCARBON 87 March 2023
www.hydrocarbonengineering.com Email: coatingservices@umicore.comENGINEERING
Website: eom.umicore.com/infrared-solutions
processes, team members might not use gas detectors forefront and drive growing demand for Umicore’s
correctly. Worse yet, they might not use them at all. high-precision, thin-film optical filters from OEMs.
All teams – even those with the highest skills, Ultimately, companies can positively influence their
experience, and best intentions – need to be supported bottom lines via responsible operations. Investors are
by safety-conscious management. Too often, gas careful to avoid risk: if an oil and gas producer’s
detection data is collected, stored, and never reviewed. contribution to climate change represents a business or
Or worse yet, it is not reviewed until a catastrophic public relations risk, investors are less likely to judge it
event forces a post-mortem investigation of the worthwhile over the long-term.
numbers. The best way to improve safety culture is by From increasing disclosures to stronger investor
using data. It is essential to take corrective action and sentiment, we continue to see upward growth of ESG
mitigate the hazards before it is too late. initiatives in energy-intensive industries. Regulation
As an increased focus on controlling emissions has enforcement has progressively restricted the emissions
matured, concerns about evaluating the true depth of that can be released, but industry opinion has become a
individual company commitment to the cause have driving force pushing that objective further. Many
arisen. These are driven in some measure by businesses now view their emissions detection through
environmental activists’ impatience with the rate at the lens of ESG. In effect, they hold themselves
which companies have made the energy transition a accountable to their own responsibly-set targets.
core part of their focus.
In industry, corporate emissions mitigation metrics References
are set at the C-level, while the critical details tied to the 1. ‘The Global Health Cost of PM2.5 Air Pollution : A Case
for Action Beyond 2021’, World Bank, (31 January 2022),
detection and quantification of GHG emissions are https://openknowledge.worldbank.org/handle/10986/36501
found at ground level. Optical gas imaging (OGI) cameras 2. ‘Gas Detection System Market Evolving Technology and Growth
Outlook 2020 to 2025’, Market Insights Reports, (8 April 2020),
excel at discovering and identifying such information, https://www.openpr.com/news/2102892/gas-detection-
which might otherwise be overlooked. They are at the system-market-evolving-technology-and-growth

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BUCHEN-ICS GmbH // Emdener Str. 278 // 50735 Cologne // Germany // T +49 221 7177-0 // vertrieb.ics@buchen.net // buchen-ics.com
A company of the REMONDIS Group

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