Sr. No. 250 / 03, Sankalp Park, Near Shashwat Hospital Opp D.A.V. Public School, gate No.

04, Aundh, Pune – 007.

SUBJECT: CHEMISTRY Std. : XI
TOPIC: STRUCTURE OF ATOM Date : 21/08/2021
Total Marks: 25 TEST Time: 01:30 Hrs.

Q.1. Select and write the correct Answer: [4]

(i) The total number of orbitals in N-shell is
(a) 4 (b) 8 (c) 9 (d) 16

(ii) Which of the following series of transitions in the spectrum of hydrogen atom falls in
visible region?
(a) Balmer series (b) Paschen series (c) Brackett series (d) Lyman series

(iii) The distance between two consecutive crests or troughs is called

(A) wavenumber (B) frequency (C) wavelength (D) amplitude

(iv) For the electron present in 2s orbital of lithium atom, the correct set of values of quantum
numbers is
(A) 2,0,0,+1/2 (B) 2,1,0, +1/2 (C) 2,1, 1,+1/2 (D) 1,0,0,+1/2

Q.2. Answer the Following [03]

(i) Write condensed orbital notation of electronic configuration of silicon (Z=14)
(ii) What are the values of ml for f-subshell?
(iii) If an element 'X' has mass number 11 and it has 6 neutrons, then write its representation.

SECTION - B

Attempt any four [08]

Q.3. Mention the demerits of Bohr’s atomic model.

Q.4. Complete the following table:
Element No. of Neutrons
40
18 Ar
-----------------
14
6 C -----------------
40
19 K -----------------
14
7 N -----------------

Q.5. Write a short note on azimuthal quantum number.

Q.6. Explain the anomalous behavior of copper.
Q.7. Differentiate between isotopes and isobars.
Q.8. Complete the following chart:

ml = 0
2p subshell
ml = -
n=2 1

l=0

SECTION - C
Attempt any two: [6]

Q.9. State and Explain Pauli’s exclusion principle.

Q.10. What is the wavelength of the photon emitted during the transition from the orbit of
n = 5 to that of n = 2 in hydrogen atom?
Q.11. A light emitted from a lamp has a wavelength of 510 nm. Find the frequency and wave
number of this light.

SECTION D
Attempt any one: [4]
Q.12. (i) Write orbital notations for electrons in orbitals with the following quantum numbers.
a. n =2, l= 1 b. n= 4, L=2
(ii) Describe the shape of 2p orbitals.

Q.13. (i) Define isotones.

(ii) State Heisenberg uncertainty principle.
(iii) Write a short note on electron spin quantum number.

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