M-20199

0191610
Subject Code: 34 (NS)

CHEMISTRY

(Kannadaand English Versions)

[ Max. Marks: 70
Time 3 Hours 15 Minutes] [ Total No. of questions: 37]

(Kannada Version)
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/26 P.T.O.
 (English Version)
ructions1. This question paper has four parts. All parts are compulsory.
2. Part-A carries 10 marks. Each question carries I mark.
Part-B carries 10 marks. Each question carries 2 marks.
Part-C carries 15 marks. Each question carries 3 marks.
Part-D carries 35 marks. Each question carries 5 marks.

3. Write balanced chemical equations and draw diagrams wherever necessary.

4. Use log tables and simple calculator if necessary (Use of scientific

calculators is not allowed).

PART-A

Answer all the questions. Each question carries 1 mark. (Answer each question
in I word or in 1 sentence)
1x10 10

What is the effect of rise in pressure on the solubility of gases in liquid?

2. 95% aqueous ethanol cannot be concentrated further by fractional distillation.

Give reason o o ro
A

He-UO

3. Write the equation for the cathodic reaction during rusting of iron.
0

4. Calculate the overall order of a reaction which has the rate expression,
3
Rate k[A2|B]

5. During adsorption of gases on solids, how does enthalpy vary?

A Fes

6. Give the composition of copper matte.

9 [P.T.O.
 7. Complete the following reaction

XeF+O2F2 143 K +O2

3-esenoa
8. Write the IUPAC name of CH,-CH-CH,Br.

6alluanh-(Cou.

9 Name the following reaction:

CHO
Co, HCI

Anhydrous AlCl3

10. Deficiency of which vitamin causes the disease pernicious anaemia?

i (2

PART-B

I Answer any five of the following questions. Each question carries 2 marks: 2x5

Write the differences between crystalline and amorphous solids with respect
to
shape and melting point.

12. The limiting molar conductivities for NaCl, HCl and CH,COONa are 126-4.
425-9 and 910 S cm mol respectively.
Calculate the limiting molar
conductivity for CH3coOH

13. (a) Define collision frequency.

(b) Give an
example for pseudo first-order reaction.
/26
10 )
 14 What is lanthanoid contraction? Write any one consequence of lanthanoid
contraction.

from cumene? Write equation.

15 How phenol is prepared

the conversion of acetic acid to acetamide. Write equation.

16. Explain

17 Give one example each for-

(a) antioxidant;

b) antiseptics.

18 What are anionic detergents? Give an example.

PART C

marks: 3x5=15
I. Answer any five of the following questions. Each question carries 3

19. Draw a neat labelled diagram of electrolytic cell used in the extraction of
ahuminium by Hall-Heroult process. Write the reactions taking place at cathode
and anode. 3

20. For the manufacture of nitric acid by Ostwald's process, write the equations
with conditions. 3

21. (a Mention any two reasons for the anomalous behaviour of oxygen. 2

(b) Write the structure ofsulphurous acid (H,SO,).

26 11 ) [P.T.O
 22. Complete the following equations

(a) Cl2+F2 437 K

(equal volume)

b P4+6Cl2

723 K
c) 4HCI+O2 cucla +2H20

23. (a) Write 'spin-only' formula to calculate magnetic moment.

(b) What are interstitialcompounds?

(c) Why Zn* is colourless?

24. How potassium permanganate (KMnO, } is prepared from Mno,?

Write equations.

hybridization, geometry
25. On the basis of Valence Bond Theory (VBT), explain
and magnetic property of (CoFcomplex
ion. [Atomic Number of Co 271
=

exhibited by the following pair of

the type of isomerism
26. (a) Identify
compounds
and (Co(NH3)5 SO41Cl
Co[NH3)5CI]SO4

structures of Pt[NH3}2C2
b) Write the cis- and trans-isomeric

12)
/26
1+1 PART-D

Answer any three ofthe following questions. Each question carries S marks
5x3-15

la) Calculate the packing efficiency in face centred cubic lattice. 3

(b) cell.
Calculate the number of particles present in a body centred cubic unit

28 a 200 cm' ofan aqueous solution of a protein contains 126 gofthe protein.
Ine osmotic pressure of such a solution at 300 K is found to be

2 57x103 bar.Calculate the molar mass ofthe protein.

(R 0 083 Lbar molk) 3

(b) Write any two properties of ideal solutions. 2

29. (a) The standard electrode potential for the Daniell cell givern below
is 1-1 V:

Zn(s)|Zn2(ag)| 1Cu (ag)|Cu(s)

Write overall cell reaction and calculate the
standard Gibbs energy for the
reaction. (F =96487 Cmol).

(b) State Faraday's first law of electrolysis. How many Faraday of

is required for the reduction of one mole of
electricity
A13*? 2

30. (a) Derive integrated rate equation for the first-order reaction.
3

(b) The rate constant of a first-order reaction is

life of the reaction.
5 5x10s Find the half-
2
/26
13)
P.T.O.
 31. (a) Write any two differences
between lyophilic colloids and
colloids. lyophob
(b) What is shape selective catalysis? Give an
catalyst. example for shape selective

(c) What is peptization?

V. Answer any
four ofthe following questions. Each question carries 5marks: 5x

32. a) Explain SN' mechanism involved in the conversion oftertiary butyl bromiae
into tertiary butyl alcohol.

b) Explain Finkelstein reaction. Write the general equation.

(cWhat is racemic mixture?

acid and
How does anisole react with a mixture
of concentrated sulphuric
33 (a)
the chemical equation for the
reaction.
concentrated nitric acid? Write
mechanism of acid
Write the equations for the three steps
involved in the
(b)
of ethanol to ethene.
catalysed dehydration

Cannizzaro reaction with an example. Write equation.

34. a) Explain
acidic and
and4-nitrobenzoic acid which is m o r e
Between benzoic acid
b)
why?

following equation:
(c) Complete the

CHa c=0+NaHSO3-

CH

(14
26
35. a) Explain Hoffmann bromamide
methanamine. Write equations.degradation reaction for the preparation of
2

(b) How does aniline react with bromine water at room

temperature? Give
equation. 2

c) Name the product formed when aniline reacts with nitrous acid at low
temperatures (273-278 K).

36. (a) Write the Haworth structure of lactose. 2

b) What is meant by denaturation of proteins? Give one example for it. 2

c) Name the pentose sugar present in RNA molecule. 1

37. (a) Howis neopreneprepared? Give equation. 2

(b) Name the monomers present in Nylon 6, 6. 2

(c) What is vulcanization?

** *

ND DDD9-215750
/26 15
34 (NS) -10-

(English Version)
Instructions:1. The question paper has four parts. Al parts are
compulsory.
2. Part-A carries
10 marks. Each
question carries one mark.
Part-B carries 10 marks. Each
question carries two marks.
Part-C carries 15 marks. Each
marks.
question carries three
Part-D carries 35 marks. Each
question carries five marks.
3. Write balanced chemical
equations and draw diagrams
wherever necessary.
4. Use log tables and the
simple calculator if
of scientific calculator is not necessary: [Use
allowed.]

PART-A
Answer all the questions. Each question carries one mark. [Answer each
question in one word orin one
sentence] (10 x 1 10)

1) How does molarity varies with temperature?

2)
2) 10 mL of liquid 'A' is mixed with 10 mL of liquid 'B', the volume of the
resultant solution is 19.9 mL. What type of deviation expected from
Raoult's law?

3)
3) Write the mathematical expression for limiting molar conductivity of
sodium chloride [NaC|].

4) Define collision frequency.

Name the adsorbent used to removal of colouring matter from solution.

5)
Give an example of a metal purified by Mond process.
6)

7) Which noble gas is most abundant in atmospheric dry air?

 -11 34 (NS)

8) What is the name of the following reaction?

X
Ether
2 +2Na
-2Nax

9 Formaldehyde [HCHO] undergoes Cannizzaro reaction: Give reason.

10) Deficiency of which vitamin causes the disease scurvy.

PART B

I1. Answer any five ofthe following. Each question carries 2 marks: (5x2 10)

11) Give the differences between crystalline and amorphous solids With
respect to shape and melting point.

12) Write the cathodic and anodic cell reactions of Hydrogen-Oxygen fuel
cell.

13) From the following graph, identify order of reaction and mention the unit
of its rate constant.

In[R]o

In [R]
Slope =-k

Time
14) What is lanthanide contraction? Mention
the cause for it.

15) How anisole reacts with acetyl chloride

[CH COCI] in the presence of
anhydrous AICI,? Write the chemical equation for the reaction.
34 (NS) 12-

16) What is the action of ammonia [NH] on benzoic acid? Write equation.

17) Give an example for i) Non-narcotic analgesics i)

Antiseptics.
18) What are anionic detergents? Give an example.

PART C
IL. Answer any five of the following. Each question caies 3 marks: (5 x3= 15)

19) During the extraction of aluminium by Hall-Heroult process

Write neat labelled diagram of electrolytic cell (1)
i) Write over all cell reaction. (1)
i) At which electrode oxygen gas is liberated? (1)

20) In the manufacture of ammonia by Haber's process, write the flow chart
and chemical equations with optimum conditions. (3)

21) i) Mention any two reasons for the anomalous behaviour of oxygen. (2)
ii) Write the balanced chemical equatilon for the action of concentrated
sulphuric acid on copper metal. (1)

22) ) Complete the following equations (2)

a) 2NaOH+Cl
(cold and dit)

K
b) Cl +3F,
(exoea)
) Write the structure of chlorous acd [HOCIOJ (1)
 -13- 34 (NS)
IHUN moment of Fes". [Atomic numbe
23) i) Calculate the spin-only magnetic (2)
of iron = 26].
oxidation state? (1)
series exhibits maximum
i) Which element of 3d

permanganate] is prepared from MnO?

How is KMnO[Potassium
24) (3)
Write equations.

ion
and magnetic property of [Ni(CN)4I
25) Explain hybridization, geometry (3)
number of Ni is 28].
using Valence Bond Theory (VBT). [Atomic

Write the cis and trans isomeric structures of [Fe(NH3)2 (CN)4]. (2)
26) i)
i)ii) What is the co-ordination number of Fe in [FeCl2(en),]Cl? (1)

PART D
Each question carries 5 marks
V. Answer any three of the following.
(3 x 5 15)

27) a) Calculate packing efficiency in simple cubic lattice. (3)

b)An element having atomic mass 63.1 g/mol hasface
centred cubic
unit cell with edge length 3.608x10 cm. Calculate the density of
unit cell. [Given: NA =6.022x10 atoms/mol]. (2)

28) a) 1.0 g of non-electrolyte solute dissolved in 50 g of benzene lowered

the freezing point of benzene by 0.4 K. Find the molar mass of the
solute. [Given: Freezing point depression constant of benzene
5.12 K. kg mol). (3)
b) How solubility of a gas in liquid varies with i) Temperature and
i) pressure? (2)
 34 (NS)
14
29) a) The electrode potential for the Daniell cell
1.1 V. given below is

Zn(s) Zn (aq) Cu(aq) Cus)

Write overall cell
reaction and calculate the
for thereaction. [F=96487 standard Gibb's energy
c/mol].
b Mention any two factors which (3)
affects the
solution. conductivity of electrolytic
(2)
30) a) Derive an
integrated rate
reaction. equation for rate constant of a zero, order
b) Write (3)
i) Arrhenius equation. (2)
i) The formula to
calculate half life period of zero order
reaction.
31) a) Give any two differences
between lyophilic and
b) Write the two steps involved in
lyophobic colloids. (2)
the mechanism of
reaction. enzyme catalysed
c) What is the (2)
entropy change (As) for adsorption? (1)
V. Answer any four of the
following. Each question carries 5 marks: (4x 5 =
20)

32) a) Write SN mechanism for conversion of

alcohol. methyl chloride to methyl
(2)
b)Aryl halides are extremely less reactive towards
substitution reactions. Give any two reasons. nucleophilic
(2)
c)What is asymmetric carbon?
(1)
33) a). Explain Kolbe's reaction with equation.
(2)
b) Write the three steps involved in the mechanism
of acid
dehydration of ethanol to ethene. catalysed
(3)
 34 (NSs
-15-
Gatterman-Koch

into b e n z a l d e h y d e by
How b e n z e n e is converted 2)
34) a) reaction? Write equation.
reaction.
(2)
Complete and
name the following
b)
C O Zn-Hg>
HCI
on the acidity
effect of electron withdrawing group
c) What is the (1)
carboxylic acid?

bromamide
bromamide
Hoffmann
prepared by
is
How primary amine (2)
35) a) Write equation.
degradation reaction?
IUPAC name of CHCH2NH2.
Write
b) i)
amines in the order of their increasing
i)
ii) Arrange the following
solution.
basic strength in aqueous
(CH)N, (CH3)2 NH,CH NH2. (2)

c) Complete the following equation.

273-278K (1)
CsHsNH2 +NaNO,+2HCI

Write the Haworth structure of maltose.

(2)
36) a)
Give example for (2)
b) an

) Globular proteins.
amino acid.
ii) Naturally occurring optically inactive
c) Name the nucleic acid which is responsible for genetic information.(1)
c)

Explain the preparation of Buna-N

with equation. (2)
37) a)
Name the monomer present in the following polymer (2)
b)
Poly vinyl chloride.
i)
i) Natural rubber.

c) Give an example of bio-degradable polymer. (1)