oiat
diaoci at do
alet onpleei Whena
Ex:
0
ul caaninakis
),so4 so fe oaly ist ad Canaite Ex:
A
prsRanbie
nolan nsalt sinale
Sall: Deule
conpaund A
ete ccN)1 Lfe Exxi
change
lk the shich cOnpound
ini A
change.(NHz)1 [Ni Ex:
2+ 3+
aie conpsud
in A conple Catisnie I.
atem. atal cantal Uha
isnA lylecte opai
bond, coodinate yolaule Nabu
atan Atal
copeunda the Thes
INtoducbisn:
COMPOUNDS (oORDLNATLON
Sene Impontt Tninlogy
Coaialion
sehen
centin Cantha igond
atom
Coondinaion titiu
1. (oodinakien ntitin A coanlinatia ntiby
contitute anta mtal ato
nolele
Ex [ Ni (co) 1 ke....
ceondirabion etiky
he atom to whie
dafinite guortia
0- slole paiolie table becaue they hav a uecat
( a ly
aeapk lone pai)
Ligond ue. donse abo Moleclea ain wie
donale
coondrate called
ligonda
chang
CN.B.
Nugabiy hangad
te....
) Nutall Ha NHa
ligarda Ganed dons atonu
a) Unidetate - I7 only do abon is
ceuinate
i ita noll which
Ehen it u alled unidaatake lig ond. (a)
is beud to tal utalL alon
Whe a ligend ator t the igand i
a singl dons
said to l idatate.
NH
L) Didatat - igane
ia
called. disdanta
ligand.
Ca0,2 ©halat ion
NH CH CHa N# hal,2- dianin
Poy daabat Whe (u)
aker Ehe its ealled poydantat ligand.
Exi hescadetate.
edd EDTA(thylan dianin tataaenbate)
Coo
cHa
A) Ardantate Undatake ligand conkaiuy
tha caediaking site (or abom) in
calld alideatabe iqond
M-CN cynato bind witl 'c')
a M NC insyt (bind with 'n')
M- Ne itato - N
o ligand elon ator bo
uhieh rbal i
diskly
Cood
boadd.
ttdutate
Coa, .
didenbat
3+
Coodinakio sple
squan collakiely called coordin
ation sphu.
(sunte isn Tua isisabl gnoup nitte outaide
callad cauntu
ceut is
TE. Csedination polyhedn
dietly atkachac eo tlhe cutral aton
dbline a coondinatien palykaden hia tahdal,i
Honalptie and Hetenolurbie complen- conplu
Gound to suly
Ex: called honoleptie orpla.
Lonple wthie
ak cantal utal aton - 16 is dabinel
i all the ligada
shans wih sontu
2+
ato
+ 2
N
42
2+
Ba = +
NH2
3
NerRdatus:
[Link] at Cationi spies
[Ceadinakio tity) couba ion
Hutal aton (oi.
|Palie 7oL ligandy
2 liganda bhen di t
2 - i
S panba 4- Gbalis
Nam hescanincoalt (m) hlanide
Tü)Pt c (NO) (NH)4 soy
Nae kabao chlonido nito latiun CT) sulehate
Nome dieloido chriun (m) tuate
Nan tsani dia coR (1) sulphate
NmL ti (ekbyler diari)ehsiwn (a) aloia)
NaL - diddordo islyladian) colalt C3) so
Nes
(ouate io Ccoondination bity J
Naning
na + Metol bo ate (orci o
alekabatialy
Na L Co (NO)1
Name sodiu hacanikscoalbat (r)
potanai baionalato fnate (I
[ N CcN) ]
Ne pobansiu eatrayano nichalate (0)
No potasnian btr Briasnin erichlonido plabiate
Waibiag canpsund stuutune hon
N
sodliuhasunibito- - coalbat
Na [Co (NO,)]
+3
Na,lolNO)6]
pokasianpaatayanontrog!funate cm)
kal Fe(cN) NO1
potaahiun tuta chlonidoMate (T)
(m) itate
atka arria didlonidoplatinn (o) babolaidoalati
vi) (Co2 (en) (oNO)]
dalanidotietylendianianitnito -0-cobalt () in
MO compaund hauig
7onla lut dint stauebural borlal
4 his calle insinn
)stuusisin
aomtical isaro
Coondinabion isseriAn 6hkical insnsisn
Stucbul
6orliuation conpSUd containing abidetat
igond,.
Sere ondsilantate ligands -
M NC
Céxty iso ynako)
SCN
(isothio ynabo)
NO (Ntuto- N)
M ONO
(aitito -o)
aRiotion issmuism
Ex
Loisnton
potubial ligard aud displae a ligond ashicl
1Soate
lydrate isorwis.
le is svila to ioninatia inonin
a soleat olel iu
selwut oleele
(violab)
StuSSU chanal boula
poitisn and anosgndk o ligand aul
mtal atom) The a 2 tyne
ot igad asu cantu aton.
he colinaion 4 ad 6 ahou this type of
( ttvahedalys yua planan)
Squan plana corle boula
diarnidiclonido platiun)
NHs,
PL
o.
( octahedaal)
Adaatabe
t
don
otakudal
adjanb poikion ot
When bhe pontion th uici
P.T.0.
Ex
N02
Co
1
ipbiall isorniae
inag that anst Supeiod
canat be supinp
eallad dinal.
callad dootro (a) and laereo (e)
dapsnding us Ehe ditisu they notate the pslan
polanised light.
iNelig didatate ligeud.
Ex: ) Co (en),]
3+ 3+
Las
2+ 24
Laeo
spkically isatise.
Boading u Cosndinakis Conpaunds :
1. Weah Tueoy os Ceandinatiw conpund
Wasn prepac and chanetind
Ceondintio oneuda and 4tudiad. Ehi
hi plyniza
aud cherical y sirle enpunintal bhaiqus
Wu
ok mtal isn,
He stud at cMoide anl
wompounda.
asunE)
aiibakl
S
Jaraied,
soution
Cols GNH ( yllo) gau 2mob Ag e
1mol (vioat) q tua isor
The condukiniby ef the solukiona of
Ehat
shausing
Pontulatu
noally isnisall and
(.onidalio nunba)
I) The iws. goup
have dhaacbnatic seakial asagut coepordig bo
Alunt coorlinatie u.
Tueany'
i hy cooreliaon conpounda hase diue
Why only cattain alerta pou bhe aakall
proputy of Bonni condiaation coneaunda,
harateinbie
nagntie and optieal propanbien.
To enlain this
Fld hesy ertgkad te
Valene Bond Thsy -
Poakulate Maia beakuus
Ae. bo this tasy the ubal atom
etahdal Squane lar
Caoinabion
Sp2
Gatonuby
Tetahedaal
Squan plana
Taigonal bayranid
sp atakdl
ottakdal
DLaragtbie Magnebis
-
Gbakadal Gainty-
Hylaidisetisn-
dsp
11
CNA,),1 IloForabin
is Q'ap}
3&
paiig ligand Espinanally
e will NH. 3 o du
11 1
3d 34
[Az]
Soidation
Co 2
skubusetahidal Coondination i)
Gonding
eti weai paaagkia bewil wil 16
eained.
byidiakion. iv)
ustathe upon dapending end cenplees spin)
obibl aute ) Clo bit bonding
bon pain laton donate
Si (3d)
Note
Hue conplex i calee'n ital
'spin paiaud conpl.
CAI 3d'4s onidabin +3
27
[A] 3 d
3d 4s
Epuiholly 4d
3d
sp d hy bridisakto
1,7 1 11
hybaidisakion spd2
octahal
Magti Pananagnbi
Note Sunee high spin
'spia bae' conle
üCoodination no.
E:
P.T.0.
26
NL saidation
Na2
3d
1 1L 1L1
Lalke lace 3d
110|11 4
Sp hybidistian
3d
Hybaidinabion
Gamaty - kalahedal
Mogatin- Paranagki
paticinasing hybidis atbia}
Ni LAn] 3 Sxidalion NG. +2
d spr hynidiabin
Fenatio ot IN(ew
Hybnidisadin -
d sp
Greomuty Squa ploran
Magakin dianaguki
is
Linitatisu Valanee
Valanee Bond Thesy
VeT nlains the fonation, stuucku and
rognatie belhaiour af csendinalim cerpowd
The colo enhilited y coordinotion canpaund
$qpontikakin iabrpkation
Magnkie data
ligoa.
Jugondiag
kou oodintu conplun
Cytal
Ae. to thin Eheoy, bh banelin bots clal
atall aton and ligod a puy ionice (eetokti
Ugonda conidud
O daguate aital
is dantby and is alik nto
spitbing
n cetaked coedination utib
hyiont, he d an
dz onlitala, hic point ouranel Bha
hih a
disubd
upulaio
danatd
3ls bo abo
p.T. O.
M
ENERGY
3tebo
Mtal d- itals
d
sphniea
o-lta i
do dapeada upor th
Ligonda
anlitting
ligonda peoduee seak biald.
Wiale
3d
Srutodhusica soies
sputrohnicall suis.
J < Br
NH a
stog
Hi coinatisn atibia,
e tnie diskilwtion dpad
alatie ogaikud ot
elital
kon high eai coplen.
2) k Ao> P
Notw: Callati ahs Bhas
atitia
splilkiny as
to
fe
diatane. Ab
So Lour sei
coniguatkien
Spittig donbd
Magabie Prory dakami
npaied
spin olbeule
whe Magnabie MoenE
unpaiud e
[anl3d 4 hiatio o, =
(pani wil ot take alau)
J s ( s 2)
S. 42 BM
skould
Coaneliakion conRsund
complun thui wide coloun
So
S at
Long uohite.
The coou cenel is
conplinantag
stich in alanbee. The complinkay colou
colo in
colou is alod comple
ud.
Cood. Comoud Colo albe
2 +
Violub
Bu
Lte CHeo). 1 B
whs
d-onbital
aso an eneite
the complesc
Uain daton in d- oulitl
Du to
yisht cou
cystal ilel splitbiag doe wol o u . Hee bu
sulrtane 3+
coloula.
qaieie Uganl aabually lound ab khe lor end
(As Ehe ganela ae couhidesl point chages tha aioic
Liqonde should eneetb gabuu splilting llk )
1t doea wot talee into account bhe covalert charetn
Banding Metal caalny
canlsoy compsunda containing
metols
canlbayl conpleeA
t
Ni
TeraheAal
Bonding
Mc Goud fonel by dontia lone RaiL
Eh canbol cabon ¿to vacank bital mebal
M-c
ati- bending T* onlital nebad
iN) M- bonding aeatu
bond Glw Co ond Metal.
Stalalty ef coandiaatio copsuda:
inaled in bhe statu at auiliin. spis
M+ hL
We unite atalility at cowtont as holaus
M+ L
ke
[MLILL]
|ML1
[MLa][L]
talilit
Alkenakiely Gwall aalility constot
hus
MLu
LMILLJ
The stuwise anl aall skalli
Jelatel
Iastaliilit oanaki coniko
Fovatio Couub.
