Scribd Logo
Upload

Welcome to Scribd!

  • States of Matter

    Uploaded by

    bharad waj
    12 views14 pages

    Original Title

    States of matter

    Copyright

    © © All Rights Reserved

    Available Formats

    PDF or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    Report this Document

    Copyright:

    © All Rights Reserved
    Download as PDF or read online from Scribd
    Flag for inappropriate content
    12 views14 pages

    States of Matter

    Uploaded by

    bharad waj

    Copyright:

    © All Rights Reserved
    Download as PDF or read online from Scribd
    Flag for inappropriate content
    of 14
    os td es fs oman ocepyitg SFA, r —o6l solid stale = —— ‘ ; : t ~~ | tiquid state ~ RON me @ | Gianeour state. — x ©| Terral energy. (reanure of #6) po Vanderwaal’s For: interaction energy + olism ei aie a Xe Y Ye Dipole-pipoele (covsting ) * epee eee —_ 7? i i — ’ + [Thermal energy? (KE) TEKT KEAT “pue to rootidd. ‘ - | The stater of, rooster ja the vesult of balance bebe? Ioter molecwar Force, and Terral energy. I 7 —_ A - ae I ~ FF Te Is dominant , i ~ zp mF 16 domn|pants | soltd => Liguid. > Gob ow uiqua SO he ir? (emma . * | Gas laws: os Dil ee ai Gia lag Inter velate the sanunable ropertes of goo. Ei (P\V,T and n) a fl @ | Boylers law f n,T constant. i ME| pOOE Or we abnog: j Planet Fl tan 1 ot 6 i! Pv=constant pviz Kk — depends.on n and T, | PIV = PaVo also on unite of P and v. f P tel O [‘Grapher CF ra ! Ta>Te>T w ii | Ts i r ti | TS x uo > 13 T3> TI i Te tr Ti ire wo oo! Ii ir eee yt gy te nn ‘SZ [earn - ) oneun ee foo] a a - y <— @ | charlers laur : , vam Pn constant. eed VeT ! S fv = kT aepentia p ands au and units of volume. v Mis V2 ; tT bg) = 6 Tmustibe taken in kelvin only. Pr t rn ay Pos V [Tey Isobar» = y ff 5 7 ae) Wale ; a x w= 7 = > x va viol sa e) T Tsobor OK ? 7 v = + ‘Taee iS te 4) Y eV TT Pepe uy M y ——— T ba y T | 1 7a : 7. Vo 7 al Avagadro7s law : oo P,T constant van v =k — _ depends on PandT 2 Ybor | unites of V. Mis Vo mn fe ett ber mn D2 ay) 1 Ideal ga» equation + v The gas which’ strictly obeys ABC ia Rocwn os Edeal goa > ; | A’ — vko | ) SV OY OeT 8— vel t P ! P V= ROT PV= DRT ee MET P Tdeal_gas equatin R= Universal Gia» constant. R= 8-314 Joule mol) K=! R= 0-082) tit atm mol~! Kol r R= 2 cal mol-! Ko! Gray lusgac>s lauy : V,9 constant rf Px T y¥ P=k +~ depends on Vandn S| . i and unitg of P __ 4 «P= Po ? : 2 In T T2 JS | | P Isochore Zz es ee vepiaatoy ant A ay eG M5509" . Density ofrTdeal gor: ® Combined ge lou + ul de PM 4 PM Pe Va ‘ . RTE uticaob | OV OTDIc 6 OSTREAM rIg Oy TF p= 02 T hai bP poixtonsial VRIES P8Ve * | daltons Lane c}! WAT oTe + lah partial pressures ¢ ive ipuerd applicable to mixture of nan- reducing qaxes The ‘total pressure exerted by a gaseous state mixture ig equal to sum of the feaia prensuney of al the goes present in the mixture: 7") The pressure exerted by an individuol ea inthe mixture ig partial pressure. 7 A,B andc —3 ganea’. Pr= Pat Pat Pe , ' a =) — — | Lon applying ideal gasrequatiom, jy in | —_—_— [ Pr=mrRtTpasonRT Po=npeT Pe = Och OT=0At OBt+NC Wy, Pas ean Tesi ih fo ane pel fe ig r v— 7% > = ites velocity iprssibed by: Maximum Fraction of the molecule Vp = Sasi = pow = Tar Fors mole | — Nw Ver Nig oP ideal gas) Vrs = sae = [a= Jap = ™ \ aren A : 1p IN = | On Thcremping ‘7’ graph ishiftg ito GH ide Peak becomer broader. culled _pessesing | ighew velocities > nT ~T inceeardes Fraction oo oa = a Tey increades oF Z ——Tyelodty deckeanes. me a — 'rt pe pel el prea under the graph Ess OT (Total 90+ of poolsules) 7 yernaing same. i te pensity will: be bighest ob “Tigh aeaaa Taeeaten —Z\ ver < Vavg < VRMs deviation of a zo from ideal oe Ideal gas “Non- ideal Creal) rT) bo ebeye eran ©¥) GA F9) writsvpoes nok obey “KTS! Vol: occupies by god ate ~ volume occupied by gos molecules ig negligible 3 molecules ig. significant No attyaction forces = Thee ig atkvaction or amang the gas molecule yepulsion force - Obeys ideal gor ' T= obeys vondexsaale ga» PV = nRT 1S Ino p+ an?) (v-0b) = oRT Verg tour P and very ve] T high ‘temp - > SF a —_* | Gompressib easibiliti eo (4) a oe ja iin Mg fon a ‘ MP ea _ aan |_ Ht gives the > padure 2 oa Page No. a; =~ / I Olwz=1 (pvenrt) " i 1 |p the gap is ideal. po Lene NY IL = No attraction annong “the ga% molecules. eis y © | Fz #4 ( PV¥oRT) — Real. ' i 44 7 et 5 ' ‘ Tae, 9) | tf 244), gas ig veal shouwg -ve deviation from ideal behayigg~/ PV< PRT - attyaction forces are darotnatingy be ee 4 roa , / b) [IP z>4, gan ig veal shows +ve deviation from ideal eh / ‘PYi> ORT. Repulsion] forces axe deminakirig: Y q i pua¥ > eva > amy 4 (| ® | Vanderwaal’s Gas quate ¢ 2 4 5 ; | - pediel) From cect go> equal oy coreg P Pond v feng i clr | Yandensoals Gas aia (P+ ap) (V+ a = DRT q AP — pressure CovecHan Mu AY- “Volume correction Pressure ‘conection, Due'to molecular. cttyactiang , a = [doy 1 P Real < P tdeal Padedl = Preal + AP ap- the pressure reduced due to moleadar athractan') AP = an? v2 AP % colliding molecules. 5 & molecules attaching ‘Whe colliding molecules = 2. AP & ne ele a v2 4 an 1 \ yd. Heh e| | _ a = vanderwaals constant signifies abtvaction Forces units of a = ‘atm lit? mo/=2 Volume: correction at —V gon = Veontnines — nb nb— vol- eaigat by gor molecules ig ; (excluded ‘volume ) ' vy Hous. b- vanderwaal*s constant signifies size of molecules . ~ Units + ‘lit mol-! amu : , : Nous, Vandenwaal’s Gias equation = (p+an?) (v- a) = DRT ve filer ol at «| b= excluded volume per mol ot yay B15 exduded vol due to 1 molewle = 4X 4 xX TY? bdcit Bl cual Volume of each gas moleade = 4 x Ty3 faa 3 Volusne of 4 mol of moleawles = 4x 4 XTY3XNA'= b foo) fon 3 * | For ganes like: CO» ;CH4', S02 t- ~ | Size is move 4 _ 2 F1 Neen Ell ~|Qis move (att clian) - _ 4 es i ——— ies Page Na, Dm low P Vis very high [bis degligible. nigh P 1 wis very Jour” " -| a ig not negligible v2 Ja ininoo V2 VEne -| (P+a) W) = RT ~_ p(v-b) = RT CO wayiape ai Pye 1 Pb i PVed- a whART ori ORT RT VRT fat Zh mov -J “oz<1 W Zed tRb Z=l-a i= SIRT + oHaty VRT = bis not negligible Ta Wa valine I ~ Real, -ve deviation 740 © | For gars like Ho,He and No :- — Real , +ve deviation ai > uy 1 - | size ig very less. -| a is low. TX vy f oub lev _ Lous P° High P = {VFS very bigh Evite ole rNg tour fo ance = | b ig negligible - ai a negligible. = | a ie’hegligible : Ve = sea! F v2 * whys ial STnevSRT = Spee ible. : Ped ewe 7 ~ PV = 14 Pb RT RT ~ lo mpa Z= VReal a 4 Videal +ve deviatian . he ssSs—CsFsSCOee a { Page No = | Uquificotion of gares > (Depend upon 'T and P) i | critical temp (Te) - The temp above which a gas canrt be 9 liquified what ever the pressure ig‘applied: 01 * Te= 8a (Varderwaalg constant) Dyegot 27Rb Thay Te KO ways Liquified easily if

    You might also like