NEET CHAPTER TES T

C HEMIS TRY
Subject : Chemistry Topic : Hydrogen M.M. : 180

Marking Scheme: Q.8 In context with the industrial preparation of

(i) Each question is allotted 4 (four) marks for hydrogen from water gas (CO+H2), which of
each correct response. the following is the correct statement?
(ii) ¼ (one fourth) marks will be deducted for (1) CO is removed by absorption in aqueous
indicating incorrect response of each question. No Cu2Cl2 solution
deduction from the total score will be made if no (2) H2 is removed through occlusion with Pd.
response is indicated for an item in the answer
(3) CO is oxidized to CO2 with steam in the
sheet.
--------------------------------------------------------------- presence of a catalyst followed by
absorption of CO2 in alkali.
Q.1 Temporary hardness may be removed from (4) CO and H2 are fractionally separated using
water by adding
differences in their densities.
(1) CaCO3 (2) Ca (OH)2
Q.9 From the following statement regarding H 2O2,
(3) CaSO4 (4) HCl
choose the incorrect statement
Q.2 The volume of oxygen liberated from 0.68gm (1) It decomposes on exposure to light
of H2O2 is (2) It has to be stored in plastic or wax lined
(1) 112ml (2) 224ml glass bottles in dark.
(3) 56 ml (4) 336ml (3) It has to be kept away from dust
Q.3 Saline hydrides react explosively with water, (4) It can act only as an oxidizing agent
such fires can be extinguished by Q.10 In which of the following properties hydrogen
(1) Water (2) Carbon dioxide does not show similarity with alkali metals?
(3) Sand (4) None of these (1) Electropositive character.
Q.4 1ml of H2O2 solution gives 10 ml of O 2 at (2) Reducing nature.
NTP. It is (3) Electronic configuration (ns1)
(1) 10 vol. H2O2 (2) 20 vol. H2O2 (4) Diatomic nature of molecule
(3) 30 vol. H2O2 (4) 40 vol. H2O2 Q.11 Which of the following ions will cause
hardness in water sample?
Q.5 H2O2 is always stored in black bottles because
(1) Ca2+ (2) Na+
(1) It is highly unstable (3) Cl– (4) K+
(2) Its enthalpy of decomposition is high Q.12 Which of the statements given below are true
(3) It undergo auto-oxidation on prolonged for the water molecule structure?
standing.
(i) Oxygen undergoes sp3 hybridisation.
(4) None of these
(ii) Due to presence of two lone pairs of
Q.6 Which of the following process will produce
electrons on oxygen the H – O – H bond
hard water ?
angle is 118.4°.
(1) Saturation of water with CaCO3
(iii) Due to angular geometry the net dipole
(2) Saturation of water with MgCO3 moment of water is not zero,  = 1.84 D.
(3) Saturation of water with CaSO4 (1) (i) and (ii) (2) (ii) and (iii)
(4) Addition of Na2CO3 water (3) (i) and (iii) (4) only (ii)
Q.13 Which compound is formed when calcium
Q.7 In a permutit, the calcium and magnesium ions
carbide reacts with heavy water?
of hard water are exchanged by
(1) C2D2 (2) CaD2
(1) CO32– and HCO3– ions of permutit.
(3) CD2 (4) Ca2D2
(2) Na+ ions of permutit.
Q.14 Which of the following reactions shows
(3) Al3+ ions of permutit.
reduction of water?
(4) Si4+ ions of permutit. (1) 2H2O + 2Na  2NaOH + H2

1
 (2) 6CO2+ 12H2O  C6H12O6+6H2O+6O2
(3) 2F2 + 2H2O  4H+ + 4F– + O2
(4) P4O10 + 6H2O  4H3PO4
Q.15 Radioactive elements emit ,  and  rays and
are characterised by their half–lives. The
radioactive isotope of hydrogen is
(1) protium (2) deuterium
(3) tritium (4) hydronium
Q.23
Q.16 Pure nascent hydrogen is best obtained by
(1) Na and C2H5OH (2) Al and NaOH
(3) Zn and dil.H2SO4 (4) All of these.
Q.17 Hydrogen burns in air with a
(1) light bluish flame (2) yellow flame
(3) crimson red flame (4) green flame
Q.18 Elements of which of the following group(s) of Q.24
periodic table do not form hydrides.
(1) Groups 7, 8, 9 (2) Group 13
(3) Groups 15, 16, 17 (4) Group 14
Q.19 The isotopes of hydrogen have different
physical properties due to difference in mass.
They have almost same chemical properties
with a difference in their rates of reactions
which is mainly due to
(1) their different enthalpy of bond dissociation.
(2) different electronic configurations.
(3) different atomic masses.
(4) different physical properties. Q.25
Q.20 Which gas is produced when calcium nitride
(Ca3N2) is hydrolysed by water?
(1) N2 (2) NH3
(3) H2 (4) O2 Q.26
Q.21 Presence of water can be detected by
(1) adding a drop to anhydrous copper
sulphate which changes its colour from
Q.27
white to blue.
(2) by boiling and testing for the presence of
H2 and O2.
(3) by seeing its colour and transparency.
(4) by checking the production of lather when Q.28
mixed with soap.
Q.22 Consider the reactions:
(i) H2O2 + 2HI  I2 + 2H2O
(ii) HOCl + H2O2  H3O+ + Cl– + O2
2
Which of the following statements is correct
about H2O2 with reference to these reactions?
Hydrogen peroxide is
(1) an oxidising agent in both (i) and (ii).
(2) an oxidising agent in (i) and reducing agent
in (ii).
(3) a reducing agent in (i) and oxidising agent
in (ii).
(4) a reducing agent in both (i) and (ii).
Which of the following statements is correct
regarding hydrogen?
(1) Hydrogen shows +1 & –1 oxidation states.
(2) Hydrogen is never liberated at anode.
(3) Hydrogen has same ionisation enthalpy as
that of alkali metals.
(4) Hydrogen has same electronegativity as of
halogens.
Hydrogen resembles halogens in many respects
for which several factors are responsible. Of the
following factors which one is the most
important in this respect?
(1) Its tendency to lose an electron to form a
cation.
(2) Its tendency to gain a single electron in its
valence shell to attain stable electronic
configuration.
(3) Its low negative electron gain enthalpy
value.
(4) Its small size.
The order of reactivity of halogens towards
hydrogen is
(1) F2 > Cl2 > Br2 > I2 (2) I2 > Br2 > Cl2 > F2
(3) Cl2 > Br2 > I2 > F2 (4) Br2 > Cl2 > F2 > I2
Hydrogen peroxide is obtained by the
electrolysis of –
(1) water (2) sulphuric acid
(3) hydrochloric acid (4) fused sodium peroxide
The temporary hardness of water due to
calcium bicarbonate can be removed by adding
(1) CaCO3 (2) CaCl2
(3) HCl (4) Ca(OH)2
Correct order of increasing bond dissociation
enthalpy is –
(1) D –D < H – H < F – F
(2) F –F < D – D < H – H
(3) F –F < H – H < D – D
(4) D –D < H – H < F – F
Q.29 Peroxodisulphate, on hydrolysis yields Q.38 Which of the following have the highest
(1) water (2) dihydrogen magnitude of hydrogen bonding
(3) hydrogen peroxide (4) deuterium (1) NH3 (2) H2O
Q.30 Non-stoichometric hydrides are produced by (3) HF (4) All have same magnitude
(1) palladium, vanadium(2) manganese, lithium Q.39 Choose the correct order of increasing electrical
(3) nitrogen, fluorine (4) carbon, nickel conductance.
Q.31 Polyphosphates like sodium hexameta- (1) BeH2 < CaH2 < TiH2
phosphate (calgon) are used as water softening
(2) CaH2 < BeH2 < TiH2
agents because they –
(1) form soluble complexes with anionic (3) BeH2 < TiH2 < CaH2
species. (4) TiH2 < CaH2 < BeH2
(2) precipitate anionic species. Q.40 Choose the correct order of increasing ionic
(3) form soluble complexes with cationic character.
species. (1) LiH < NaH < CsH (2) NaH < LiH < CsH
(4) precipitate cationic species. (3) LiH < CsH < NaH (4) CsH < NaH < LiH
Q.32 Which of the following equations depict the Q.41 Choose the correct order of increasing bond
oxidising nature of H2O2? dissociation enthalpy.
(1) 2MnO4– + 6H+ + 5H2O2 (1) H – H < F – F < D – D
(2) F – F < D – D < H – H
 2Mn2+ + 8H2O + 5O2
(3) F – F < H – H < D – D
(2) 2Fe3++2H+ + H2O2  2Fe2++2H2O+O2 (4) D – D < H – H < F – F
(3) 2I– + 2H+ + H2O2  I2 + 2H2O Q.42 Choose the correct order of increasing reducing
property.
(4) KIO4– + H2O2  KIO3 + H2O + O2
(1) MgH2 < H2O < NaH
Q.33 Hydrogen will not reduce –
(2) NaH < MgH2 < H2O
(1) heated cupric oxide
(2) heated ferric oxide (3) H2O < NaH < MgH2
(3) heated stannic oxide (4) H2O < MgH2 < NaH
(4) heated aluminium oxide Q.43 Ca3N2(s) + 6H2O() 3Ca(OH)2 + 2NH3
Q.34 What mass of hydrogen peroxide is present in is classfied as
2litre solution of 4M strength ? Calculate the (1) Redox reaction (2) Hydrolysis reaction
volume of oxygen at S.T.P. liberated upon (3) Hydration reaction (4) None of these
complete decomposition of 400 cm3 of the Q.44 Nature of hydrides if formed by elements of
above solution. atomic numbers 15 with dihydrogen is –
(1) 172g, 0.92 L (2) 272g, 1.32 L (1) Molecular (or Covalent)
(3) 272g, 17.92 L (4) 172g, 15.14 L (2) Ionic
Q.35 The decomposition of H2O2 is accelerated by – (3) Metallic
(1) Glycerine (2) Alcohol (4) None of these
(3) Phosphoric acid (4) Pt powder Q.45 Choose the correct statement –
Q.36 H2O2 acts as antiseptic due to its – (1) Syngas is a mixture of carbon monoxide
(1) Reducing property (2) Oxidising property and dihydrogen.
(3) Bleaching property (4) Acidic property (2) Water shift reaction is a reaction of carbon
Q.37 Choose the correct statement – monoxide of syngas mixture with steam in
(1) BeH2, BH3 are electron deficient hydrides. the presence of a catalyst.
(2) CH4, SiH4, GeH4 are precise hydrides. (3) Hydrogenation is the addition of
dihydrogen to another reactant.
(3) NH3H2O is an electron rich hydrides. (4) All of these
(4) All of these