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    The document is an end semester examination from the Department of Chemistry at the National Institute of Technology Rourkela. It contains 20 multiple choice questions worth 40 marks total and 5 short answer questions worth 10 marks total, for a total of 50 marks. The multiple choice questions cover concerted and non-concerted reaction mechanisms. The short answer questions cover specific reaction types: a) Ireland-Claisen rearrangement, b) Fischer-Indole synthesis, c) Oxy-cope rearrangement, d) Thermal [2+2]-cycloaddition, and e) Nazarov cyclization.

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    The document is an end semester examination from the Department of Chemistry at the National Institute of Technology Rourkela. It contains 20 multiple choice questions worth 40 marks total and 5 short answer questions worth 10 marks total, for a total of 50 marks. The multiple choice questions cover concerted and non-concerted reaction mechanisms. The short answer questions cover specific reaction types: a) Ireland-Claisen rearrangement, b) Fischer-Indole synthesis, c) Oxy-cope rearrangement, d) Thermal [2+2]-cycloaddition, and e) Nazarov cyclization.

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    © All Rights Reserved
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    6 views2 pages

    CY412

    Uploaded by

    abcdbicky
    The document is an end semester examination from the Department of Chemistry at the National Institute of Technology Rourkela. It contains 20 multiple choice questions worth 40 marks total and 5 short answer questions worth 10 marks total, for a total of 50 marks. The multiple choice questions cover concerted and non-concerted reaction mechanisms. The short answer questions cover specific reaction types: a) Ireland-Claisen rearrangement, b) Fischer-Indole synthesis, c) Oxy-cope rearrangement, d) Thermal [2+2]-cycloaddition, and e) Nazarov cyclization.

    Copyright:

    © All Rights Reserved
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    Department of Chemistry

    National Institute of Technology Rourkela – 769 008.


    End Semester (supplementary) Examination 2019
    Subject: Concerted and non-concerted reactions Subject Code: CY 412
    Full marks: 50 Duration of Examination: 3 h

    Q. No. Answer All Questions Marks

    1. Derive the product of the following reactions with suitable mechanism 20 x 2


    = 40
    Ph
    a) ? k) ?
    Ph

    CH3 CO2Me
    b) H3C ?
    l) H3CH2C CHN2 + ?
    O
    H+ CO2Me
    ?
    c)
    O
    190 C
    O m) ?

    d)
    FeCl3 O
    ?
    SiMe3 CHO
    n) ?
    Ph
    e) O
    ?
    Ph
    o) + ?

    f) ? O
    Me
    p) + BnN3 ?

    g) I CF3COOAg / SO2 Me
    + ? O
    hv
    1. Et3N q) +
    Cl O ?
    ?
    h) Ph O CO2Me
    N
    Cl Cl 2. O
    H3C
    O
    + 3000C
    0 r) O
    i) 120 C ?
    + O ?
    O
    O

    Me s) Cl Et3N
    H3C ?
    j) CO2Me O
    + ?
    CO2Me MeC(OEt)3
    Me t) ?
    OH H+

    1
    2. Write short notes on :

    a) Ireland-Claisen rearrangement 5x2=


    10
    b) Fischer-Indole synthesis
    c) Oxy-cope rearrangement
    d) Thermal [2+2]-cycloaddition
    e) Nazarov cyclization

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