SUPER 3000 MCQS

For JEE Main 2021

Day 01

Mole Concept
RK ROY SIR
(ISC, BHU ALUMNUS)
 Reaction Based (% yield)

01 For the reaction

2x + 3y + 4z → 5w
Initially if 1 mole of x, 3 mole of y and 4 mole of z is taken. If 1.25
mole of w is obtained then % yield of this reaction is _______.
 Mixing of solution

02 125 ml of 8% w/w NaOH solution (sp. Gravity 1) is added to 125

ml of 10% w/v HCL solution. The nature of resultant solution
would be _________ .
 Composition Based

03 Ration of masses of H2SO4 and Al2(SO4)3 is grams each containing

32 grams of S is __________ .
 Stoichiometry Reaction

04 A 10 mg effervescent tablet containing sodium bicarbonate and

oxalic acid releases 0.25 ml of CO2 at T = 298.15 K and p = 1 bar. If
molar volume of CO2 is 25.0 L under such condition, what is the
percentage of sodium bicarbonate in each table ? [Molar mass of
NaHCO3 = 84 g mol-1]
 Hydrocarbon Combustion

05 A definite amount of gaseous hydrocarbon was burnt with just

sufficient amount of O2. The volume of all reactants was 600 ml,
after the explosion the volume of the products [CO2(g) and
H2O(g)] was found to be 700 ml under the similar conditions. The
molecular formula of the compound is :
(A) C3H8 (B) C3H6 (C) C3H4 (D) C4H10
 Hydrocarbon Combustion

06 At 300 K and 1 atmospheric pressure, 10 mL of a hydrocarbon

required 55 mL of O2 for complete combustion and 40 mL of CO2 is
formed. The formula of the hydrocarbon is :
(A) C4H8 (B) C4H7Cl (C) C4H10 (D) C4H6
 Limiting Reagent

07 For a reaction,
N2(g) + 3H2(g) → 2NH3(g) ;
identify dihydrogen (H2) as a limiting reagent in the following
reaction mixtures.
(A) 14g of N2 + 4g of H2 (B) 28g of N2 + 6g of H2
(C) 56g of N2 + 10g of H2 (D) 35g of N2 + 8g of H2
 Conc. Of Solution

08 The mole fraction of a solvent in aqueous solution of a solute is

0.8. The molality (in mol kg-1) of the aqueous solution is :
(A) 13.88 x 10-1 (B) 13.88 x 10-2
(C) 13.88 (D) 13.88 x 10-3
 AAM

09 The vapour density of a mixture of gas A (Molecular mass = 40)

and gas B (Molecular mass = 80) is 25. Then mole % of gas B in the
mixture would be _______ .
 Combustion

10 The minimum number of moles of O2 required for complete

combustion of 1 mole of propane and 2 moles of butane is _____.
 Conc. Of Solution

11 6.023 x 1022 molecules are present in 10 g of a substance ‘x’. The

molarity of a solution containing 5 g of substance ‘x’ in 2 L solution
is ______ x 10-3.
 Conc. Of Solution

12 The mole fraction of glucose (C6H12O6) in an aqueous binary

solution is 0.1. The mass percentage of water in it, to the nearest
integer, is _____ .
 Conc. Of Solution

13 The ratio of the mass percentages of ‘C & H’ and ‘C & O’ of a

saturated acyclic organic compound ‘X’ are 4 : 1 and 3 : 4
respectively. Then, the moles of oxygen gas required for complete
combustion of two moles of organic compound ‘X’ is ____ .
 PPM

14 Ferrous sulphate heptahydrate is used to fortify foods with iron.

The amount (in grams) of the salt required to achieve 10 ppm of
iron in 100 kg of wheat is _________.
Atomic weight : Fe = 55.85; S = 32.00; O = 16.00
 POAC

15 The ammonia (NH3) released on quantiative reaction of 0.6 g urea

(NH2CONH2) with sodium hydroxide (NaOH) can be neutralized by
(A) 200 ml of 0.02 N HCl (B) 100 ml of 0.2 N HCl
(C) 100 ml of 0.1 HCl (C) 200 ml of 0.4 N HCl
 Molecular Formula

16 10 ml of a compound containing ‘N’ and ‘O’ is mixed with 30 ml of

H2 to produce H2O(l) and 10 ml of N2(g). Molecular formula of
compound if both reactants reacts completely, is
(A) N2O (B) NO2 (C) N2O3 (D) N2O5
 Reaction Based

17 Mass of sucrose C12H22O11 produced by mixing 84 gm of carbon,

12 gm of hydrogen and 56 lit. O2 at 1 atm & 273 K according to
given reaction, is C(s) + H2(g) + O2(g) → C12H22O11(s)
(A) 138.5 (B) 155.5 (C) 172.5 (D) 199.5
 Duma’s method

18 In the quantitative determination of nitrogen using Duma’s

method, N2 gas liberated from 0.42 gm of a sample of organic
compound was collected over water. If the volume of N2 gas
100
collected was ml at total pressure 860 mm Hg at 250 K, % by
11
mass of nitrogen in the organic compound is
[ Aq. tension at 250K is 24 mm Hg and R = 0.08 L atm mol-1K-1]
10 10 5 100
(A) % (B) % (C) % (D) %
11 3 3 3
 Reaction Based

19 The minimum mass of mixture of A2 and B4 required to produce at

least 1 kg of each product is :
(Given At. mass of ‘A’ = 10; At mass of ‘B’ = 120)
5A2 + 2B4 → 2AB2 + 4A2B
(A) 2120 gm (B) 1060 gm (C) 560 gm (D) 1660 gm
 Conc. Of Solution

20 Assuming complete precipitation of AgCl, calculate the sum of the

molar concentration of all the icons if 2 lit of 2M Ag2SO4 is mixed
with 4 lit of 1 M NaCl solution is :
(A) 4M (B) 2M (C) 3M (D) 2.5 M
 Molecular Formula

21 A gaseous compound is composed of 85.7% by wt. of carbon and

14.3% by wt. of H. Its density is 2.28 gL-1 at 300K and 760 torr
pressure. Determine the molecular formula of the compound.
(Use R = 0.082 L atm mol-1K-1)
 Density

22 The density of mercury is 13.6 g/ml. Calculate the diameter of an

atom of mercury assuming that each atom of mercury is
occupying a cube of edge length equal to the diameter of the
mercury atom.
[Hg = 200] (Use : NA = 6.02 x 1023)
 Conc. Of Solution

23 8.05 x 10-2 kg of Glauber’s salt is dissolved in water to obtain 1

dm3 of a solution of density 1077.2 kg/m3. Calculate the molarity,
molality and mole fraction of NA2SO4 in solution.
 Conc. Of Solution

24 In what volume ratio, 1.2 (M) Ca(NO3)2 and 1.8 (M) NaNO3
solutions should be mixed together to get a solution having total
molarity of anions 1.5 times the total molarity of cations?
 Combustion

25 A mixture of ethane (C2H6) and ethene (C2H4) occupies 40 litre at 1

atm and 400 K. The mixture reacts completely with 130 gm of O2
to produce CO2 and H2O. Assuming ideal behaviour calculate the
mole fraction of C2H4 and C2H6 in the mixture.
(Use R = 0.082 L atm mol-1 K-1)
 Kjedahl’s Method

26 0.6 gm of an organic compound was analysed. The ammonia thus

𝑁
produced was absorbed in 100 ml of H2SO4. The remaining
10
acid required is 20 ml of 0.1 (N) NaOH for neutralization.
Calculate the percentage of nitrogen in the organic compound.
 Conc. Of Solution

27 What volumes should you mix of 0.2 M NaCl arid 0.1 M CaCl2
solution so that in resulting solution the concentration of positive
ion is 40 % lesser than concentration of negative ion. Assuming
total volume of solution 1000 ml.
(A) 400 ml NaCl, 600 ml CaCl2 (B) 600 ml NaCl, 400 ml CaCl2
(C) 800 ml NaCl, 200 ml CaCl2 (D) None of these
 Formula Mass

28 The pair of species having same percentage (mass) of carbon is :

(A) CH3COOH and C6H12O6
(B) CH3COOH and C2H5OH
(C) HCOOCH3 and C12H22O11
(D) C6H12O6 and C12H22O11