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hhne.

mllsunakie Conlihienty inDCCUn


lo, instantane0us
vey d between neachons ModOhate
hust
cQ3(02(9)+,02lg)-
e(ot) H,olg)1 FeCi
eqine rate.dettmhe dihuut
to ihor ushngo er-
diamagnenc) diaignerit
amayhehe molecale puneel sp1n toble thangfhdm
into
trdenyo elechor contalning
od tang invclving
to
neachoro mokecylan ,Naclcals e dast vey CCan O
Asnd olsebNOKOn, beloane bondo no
Sine OnaAA
ion called also iond, only involve Neachond
"Istontarbua
-
Kineh Chemial
Reasoror ditrtnt ates. his because a reochor nyoles
naking and baea uhg bondls- d'Hoent bonds neauine digoent
amauns enesy t6 be baonen-atete cheAol

Rate
ugpiie

CodcesnthoinP'de)

Titne

tine tahen

ime tahta
(in uaitn)

becaue hates are non uniodeptnd cporn he concernh tlon


the nkl
hahon
d concern ehane
in &hnall
time instantqpoohculan aat
Negasue cone
a Ihitial Conc hhalOPactank=
ncemabon therene hime decsees
with Ataluanb
At At
tit- Atz
tzbme Nnthehio
at LA],LBl,
conce
rne at
tybiconçeanta'ons 8J, LA,
Avthagehae
|ONaphial seprernlatlon.
A

- AR--(G-)
t-t,

tano
A
inntontous -tan(180-9)

0t

tang OA
dt dt 2

a dt b dt

Ct
tadors aechng the Nae a achon

Reachond Cur dye to intrmoleuian colisiond. Dae dpahds


layety on tne fhequeny < eallitions. ac0Ns ayes

SConceDntretion Coneanteita (neatan)crae djhih,

Th! i! because the total Buyare aneaa a dolicl inchels

aeachons win Kaaretuta unitolmg iaibuhon o)


hon uagCNin ditibuhon

inTempthalwe- fae of'atemperet


he nate
heactant molgules Ond ne btndo ane ohmel the

adding q dui tehle eatalt


da) mass ach'on

The nae at oblch a


Bonal
to lk acve may and sae o a ehemical eachon
N dihectlg phopotoral to tne phodet oy ne actue

tcMe hmy = oln concerntahon ie the nuyben


4 mohespr itbe o4 tre
the heactant

Denoion - CAl on Ca
pnec'tely a neachon,
At8 praduca
RateaLAJ.[R]

Lwbeng the rere cordtant, vetociy oobeient ok gpeipl e

The sae o a che'al Aechon at any pantcean hihe


ata gven tempeehue, is ph ipatjonel to thephocecs
the conternhebond of heaetas with each conteantnehon
tehn Jnalsed to Che powe Qqual to the nam ben

heacb0N
4nitesog t, ony holae good jon simpie, one- nep

Rteequeion kar tau)


Rare equahoa don a reachon 0` an dlgeSDail eqahbn ahowing
be reaehon deipBncs oh Che molan

only be detrainl phipotndaleg


an only

Rate o

Rate eorhant

doend deped on
tempehw
Rae do Rn

Aeastang a poduch at

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