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Useful for all Agricultural, Medical, Pharmacy and Engineering Entrance Examinations

held across India.

STD. XI Sci.
Triumph Chemistry
Based on Maharashtra Board Syllabus

Salient Features
• Exhaustive subtopic wise coverage of MCQs
• Quick Review and/or Important Formulae provided for all the chapters
• Hints included for relevant questions
• Various competitive exams questions updated till the latest year
• Includes solved MCQs from JEE (Main), AIPMT / NEET P-I and P-II,
KCET 2015 and 2016
• Evaluation Test provided at the end of each chapter

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P.O. No. 30310

10145_10960_JUP
Preface
“Std. XI: Sci. Triumph Chemistry” is a complete and thorough guide to prepare students for
competitive level examinations. This book not only assists students with MCQs of Std. XI but also helps them to
prepare for JEE, AIPMT / NEET-UG, CET and various other competitive examinations.
The content of this book is based on the Maharashtra State Board Syllabus. Quick Review which
summarizes the important concepts of the entire chapter is provided for all the chapters. Formulae that form a
vital part of MCQ solving are provided for relevant chapters.
MCQs in each chapter are divided into three sections:
Classical Thinking: consists of straight forward questions including knowledge based questions.
Critical Thinking: consists of questions that require understanding of the concept and the applications of the
same.
Competitive Thinking: consists of questions from various competitive examinations like JEE, AIPMT / NEET-
UG, MH CET, KCET, CPMT, GUJ CET, AP EAMCET (Engineering, Medical), TS EAMCET (Engineering,
Medical), Assam CEE, BCECE, WB JEEM, etc.
Hints (i.e., complete solutions broken down to the simplest form possible) have been provided to the relevant
MCQs.
An Evaluation Test has been provided at the end of each chapter to assess the level of preparation of the
student on a competitive level.
In order to understand how chemistry plays an important role in our day to day life, we have made an
attempt to illustrate the same in the form of images/visuals in the related chapters.
The journey to create a complete book is strewn with triumphs, failures and near misses. If you think
we’ve nearly missed something or want to applaud us for our triumphs, we’d love to hear from you.
Please write to us at : mail@targetpublications.org

Best of luck to all the aspirants!


Yours faithfully
Authors

Index
Sr. No. Topic Name Page No.
1 Some Basic Concepts of Chemistry 1
2 States of Matter (Gases and Liquids) 22
3 Structure of Atom 51
4 Periodic Table 85
5 Redox Reactions 103
6 Chemical Equilibrium 119
7 Surface Chemistry 165
8 Nature of Chemical Bond 186
9 Hydrogen 220
10 s-Block Elements 240
11 p-Block Elements (Group 13 and 14) 262
12 Basic Principles and Techniques in Organic Chemistry 290
13 Alkanes 330
14 Alkenes 351
15 Alkynes 369
16 Aromatic Compounds 387
17 Environmental Chemistry 405
Chapter 01: Some Basic Concepts of Chemistry

01 Some Basic Concepts of Chemistry

Subtopics
1.0 Introduction
Platinum alloy as an International Prototype
1.1 Importance and scope of chemistry of the Kilogram

1.2 Historical approach to particulate


nature of matter
1.3 Laws of chemical combination
1.4 Dalton’s atomic theory
1.5 Concepts of elements, atoms and
molecules
1.6 Atomic and molecular masses
1.7 Avogadro’s law, Avogadro’s number
and mole concept
1.8 Percentage composition and
empirical and molecular formula
1.9 Chemical reactions and Have you ever wondered what is the reference for 1
kilogram???? It has been defined as the mass of the
stoichiometry International Prototype of the Kilogram. The
prototype is made of platinum-iridium (Pt-Ir)
cylinder that is stored in an airtight jar at
International Bureau of Weights and Measures in
France. Pt-Ir was chosen because its mass remains
constant for an extremely long time and it is resistant
to the attack of different chemicals. This reference
standard is used to calibrate or standardize different
measuring devices such as analytical balances.

1
Std. XI : Triumph Chemistry

Quick Review
 Branches of chemistry:
Physical chemistry
 Deals with the structure of matter, the energy changes and the
theories, laws and principles that explain the transformation of
matter from one form to another.

Inorganic chemistry
 Deals with chemistry of elements other than carbon and of
Chemistry their compounds.
Study of the composition,
structure and properties of Organic chemistry
matter and the reactions by  Deals with the reactions of the compounds of carbon.
which one form of matter
may be converted into Analytical chemistry
another form.  Deals with the separation, identification and quantitative
determination of the compositions of different substances.

Biochemistry
 Deals with chemistry of compounds and processes occurring in
living organisms.

 Classification of matter:

Matter
 has mass
 occupies space

Pure substances Mixtures


 Fixed composition  Variable composition (that can be
separated by simple physical methods)

Elements Compounds Homogeneous mixtures Heterogeneous mixtures


 Substances that cannot  Substances of definite  Composition is  Composition is not
be decomposed by a compositions which uniform. uniform.
simple chemical can be decomposed  All constituents  Two or more phases
process into two or into two or more present in one are present.
more different susbtances by a phase.  eg. phenol-water
substances. simple chemical  eg. air, ethyl alcohol system, iron filings-
 eg. He (monoatomic), process. and water sand system
H2 (diatomic)  eg. H2O, NaCl

2
Chapter 01: Some Basic Concepts of Chemistry
 Laws of chemical combination:
Law of conservation of mass
 First stated by Lomonosove (1765) and then by Antoine Laviosier (1783).
 Statement: The mass is neither created nor destroyed during chemical
combination of matter.

Law of definite composition/Law of definite proportion


 Stated by Joseph Proust.
 Statement: Any pure compound always contains the same elements in a
definite proportion by weight irrespective of its source or method of
preparation.

Law of multiple proportion


Laws of chemical  Stated by John Dalton.
combination  Statement: If two elements chemically combine with each other forming
two or more compounds with different compositions by mass then the
ratios of masses of two interacting elements in the two compounds are
small whole numbers.

Gay Lussac’s law of combining volumes of gases


 Stated by Gay Lussac.
 Statement: When gases react together to produce gaseous products, the
volumes of reactants and products bear a simple whole number ratio with
each other, provided volumes are measured at same temperature and
pressure.

Avogadro’s law
 Stated by Avogadro.
 Statement: Equal volumes of all gases under identical conditions of
temperature and pressure contain equal number of molecules.

Formulae 6. Number of molecules


= n  Avogadro number (NA)
1 7. Atomicity = number of atoms in a molecule
1. Atomic mass unit (1 amu) = th of a 12C-atom
12
8. Total number of atoms in molecule
= 1.66  1027 kg
= n  NA  Atomicity
2. 1 Mole = 6.022  1023 particles 9. Volume occupied by one mole of a gas at STP
(atoms/molecules/ions/electrons) = 22.4 L = 22.4 dm3
3. Number of moles (n) 10. Molecular formula = r  Empirical formula
Mass of the substance
= Molecular mass
Molar mass of the substance 11. r=
Empirical mass
Atomic mass
4. Mass of an atom = 12. Average atomic mass
6.022  1023
Sum of (Isotopic mass  its % abundance )
=
Molecular mass 100
5. Mass of a molecule =
6.022  1023
13. Avogadro’s law, V  n (At constant T and P)

3
Std. XI : Triumph Chemistry
10. The phlogiston theory was suggested for
Classical Thinking _______ reaction.
(A) neutralisation (B) oxidation
1.0 Introduction
(C) reduction (D) combustion
1. _______ chemistry deals with the chemistry of
elements other than carbon and of their 11. Substances which CANNOT be decomposed
compounds. into two or more different substances by
(A) Organic (B) Physical chemical process are called _______.
(C) Inorganic (D) Bio (A) alloys (B) molecules
(C) elements (D) compounds
2. The branch of chemistry which deals with the
separation, identification and quantitative 12. The arbitrarily decided and universally
determination of the composition of different accepted standards are called _______.
substances is called _______ chemistry. (A) fundamentals (B) units
(A) organic (B) inorganic (C) measures (D) symbols
(C) analytical (D) bio
13. There are _______ fundamental SI units.
1.1 Importance and scope of chemistry (A) 3 (B) 5
(C) 6 (D) 7
3. _______ pigment acts as a photosensitizer in
plants. 14. SI unit of temperature is _______.
(A) Xanthophyll (B) Chlorophyll (A) K (B) C
(C) Carotene (D) ATP (C) F (D) D
4. _______ CANNOT be carried out in a lab. 15. SI unit of velocity is _______.
(A) Photosynthesis (B) Reduction
(A) km s1 (B) km hr1
(C) Oxidation (D) Hydration 2
(C) m s (D) m s1
5. Solar energy can be converted into electrical
energy using _______ cell. 1.3 Laws of chemical combination
(A) Daniel (B) lithium ion
(C) photovoltaic (D) nickel cadmium 16. The sum of the masses of reactants and
products is equal in any physical or chemical
6. In computers, _______ chips are used as reaction. This is in accordance with law of
microprocessors. _______.
(A) carbon (B) phosphorus
(A) multiple proportion
(C) titanium (D) silicon
(B) definite composition
1.2 Historical approach to particulate (C) conservation of mass
nature of matter (D) reciprocal proportion
7. Which one of the following is NOT a mixture? 17. If the law of conservation of mass was to hold
(A) Iodized table salt true, then 20.8 g of BaCl2, on reaction with
(B) Gasoline 9.8 g of H2SO4 will produce 7.3 g of HCl and
(C) Liquefied Petroleum Gas (L.P.G.) _______ of BaSO4.
(D) Distilled water (A) 11.65 g (B) 23.3 g
8. If two or more phases are present in a mixture (C) 25.5 g (D) 30.6 g
then it is called a _______ mixture.
(A) heterogeneous (B) homogeneous 18. Pure water can be obtained from various
(C) homologous (D) heterologous sources, but it always contains hydrogen and
oxygen, combined in a ratio of 1:8 by weight.
9. Phenolwater system is a/an _______. This is an example of _______.
(A) element (A) law of conservation of mass
(B) compound (B) Avogadro’s law
(C) homogeneous system (C) law of definite composition
(D) heterogeneous system (D) Gay Lussac’s law
4
Chapter 01: Some Basic Concepts of Chemistry
19. Two containers of the same size are filled 27. A/an _______ is an aggregate of two or more
separately with H2 gas and CO2 gas. Both the atoms in definite composition which are held
containers under the same T and P will contain together by chemical bonds.
the same _______. (A) ion (B) molecule
(A) number of atoms (C) compound (D) mixture
(B) weight of gas
1.6 Atomic and molecular masses
(C) number of molecules
(D) number of electrons 28. Every atom of an element consists of fixed
20. In SO2 and SO3, the ratio of the masses of number of _______.
oxygen which combine with a fixed mass of (A) protons (B) neutrons
sulphur is 2:3. This is an example of the law of (C) electrons (D) all of these
_______. 29. The unit of atomic mass amu is replaced by
(A) constant proportion _______.
(B) multiple proportion (A) u (B) mol
(C) reciprocal proportion (C) g (D) kg
(D) Gay Lussac
30. Mole is the SI unit of _______.
21. Which of the following reactions has the ratio (A) volume
of volumes of reacting gases and the product (B) pressure
as 1:2:2? (C) amount of substance
(A) 2CO(g) + O2(g)  2CO2(g) (D) density
(B) O2(g) + 2H2(g)  2H2O(g)
31. 1 amu is equal to _______.
(C) H2(g) + F2(g)  2HF(g)
1 1
(D) N2(g) + 3H2(g)  2NH3(g) (A) of C – 12 (B) of O – 16
12 14
22. The volume of oxygen required for complete (C) 1 g of H2 (D) 1.66  10–23 kg
combustion of 0.25 cm3 of CH4 at S.T.P is
_______ cm3. 32. ________ is the sum of the atomic mass of all
(A) 0.25 (B) 0.5 the atoms as given in the molecular formula of
(C) 0.75 (D) 1 the substance.
(A) Molecular mass (B) Atomic weight
1.4 Dalton’s atomic theory (C) Percentage weight (D) Percentage volume
23. Greek philosopher _______ had suggested that 1.7 Avogadro’s law, Avogadro’s number
matter is composed of extremely small and mole concept
a-tomio.
(A) Dalton (B) Aristotle 33. NA = _________ atoms mol1.
(C) Ptolemy (D) Democritus (A) 6.021  1021 (B) 6.024  1024
24. Dalton assumed that _______ are the smallest (C) 6.051  1015 (D) 6.022  1023
particles of compound. 34. One _______ is the collection of 6.022  1023
(A) atoms (B) molecules atoms /molecules/ions.
(C) ions (D) elements (A) kg (B) g
1.5 Concepts of elements, atoms and (C) mole (D) cm
molecules
35. Avogadro’s number is ________.
25. Atoms have a mass of the order _______. (A) number of atoms in one gram of element.
(A) 1026 kg (B) 1015 kg (B) number of millilitres which one mole of
(C) 1026 g (D) 1015 g a gaseous substance occupies at N.T.P.
(C) number of molecules present in one
26. Atoms have a radius of the order _______. gram molar mass of a substance.
(A) 1026 m (B) 1015 m (D) number of elements in one gram of
(C) 1015 mm (D) 1015 m compounds.

5
Std. XI : Triumph Chemistry
36. Which of the following law states that equal 45. 1 atom of an element weighs 1.792  10–22 g.
volume of all gases contain equal number of The atomic mass of the element is _______.
molecules? (A) 1.192 (B) 17.92
(A) Boyle’s law (C) 64 (D) 108
(B) Charles’ law
(C) Avogadro’s law 46. What is the mass of 0.5 mole of ozone molecule?
(D) Gay Lussac’s law (A) 8 g (B) 16 g
(C) 24 g (D) 48 g
37. According to Avogadro’s law, ________.
1 47. The number of molecules in 16 g of oxygen
(A) V  (B) V  T gas is _______.
P
(A) 6.022  1023 (B) 3.011  1023
(C) V  n (D) all of these 22
(C) 3.011  10 (D) 1.5  1023
38. Volume occupied by 1 g molecular weight of
any gas is called _______. 48. Which of the following weighs the least?
(A) gram molecular volume (A) 2.0 gram mole of CO2
(B) gram atomic volume (B) 0.1 mole of sucrose (C12H22O11)
(C) gram molecular weight (C) 1 gram atom of calcium
(D) gram atomic weight (D) 1.5 mole of water

39. Avogadro’s law distinguishes between 49. Which one of the following pairs of gases
_______. contains the same number of molecules?
(A) cations and anions (A) 16 g of O2 and 14 g of N2
(B) atoms and molecules (B) 8 g of O2 and 22 g of CO2
(C) atoms and ions (C) 28 g of N2 and 22 g of CO2
(D) molecules and ions (D) 32 g of O2 and 32 g of N2
40. The number of atoms present in a molecule of 50. One mole of oxygen gas weighs _______.
a substance is called its ________. (A) 1 g (B) 8 g
(A) atomicity (B) volume (C) 32 g (D) 6.023  1023 g
(C) density (D) mass
51. Under similar conditions, same mass of
41. How many molecules are present in one gram oxygen and nitrogen is taken. The ratio of
of hydrogen gas? their volumes will be _______.
(A) 6.02  1023 (B) 3.01  1023 (A) 7 : 8 (B) 3 : 5
23
(C) 2.5  10 (D) 1.5  1023 (C) 6 : 5 (D) 9 : 2
42. One mole of CO2 contains _______. 1.8 Percentage composition and empirical
(A) 6.022  1023 atoms of C and molecular formula
(B) 6.022  1023 atoms of O 52. Chemical formula CANNOT be determined
(C) 18.1  1023 molecules of CO2 by using _______.
(D) 3 g atoms of CO2 (A) Raman spectroscopy
43. One mole of H2O corresponds to _______. (B) nuclear magnetic resonance
(A) 22.4 litres at 1 atm and 25 C (C) Titration
(B) 6.02  1023 atoms of hydrogen and (D) ultraviolet spectroscopy
6.02  1023 atoms of oxygen 53. The mass percentage of each constituent
(C) 18 g of H2O element present in 100 g of a compound is
(D) 1 g of H2O called its _______.
44. The gram molecule of benzene is equal to (A) molecular composition
_______ g C6H6. (B) atomic composition
(A) 70 (B) 72 (C) percentage composition
(C) 10 (D) 78 (D) mass composition

6
Chapter 01: Some Basic Concepts of Chemistry
54. _______ of a compound is the chemical 64. _______ reactant is the reactant that reacts
formula indicating the relative number of completely but limits further progress of the
atoms in the simplest ratio. reaction.
(A) Empirical formula (A) Oxidizing (B) Reducing
(B) Molecular formula (C) Limiting (D) Excess
(C) Empirical mass 65. _______ reactant is the reactant which is taken
(D) Molecular mass in excess than the limiting reactant.
55. The percentage composition of carbon in urea, (A) Oxidizing (B) Reducing
[CO(NH2)2] is _______. (C) Limiting (D) Excess
(A) 20% (B) 40% 66. The _______ coefficients are the coefficients
(C) 50% (D) 80% of reactants and products in the balanced
56. What is the % of H2O in Fe(CNS)33H2O? chemical reaction.
(A) 19 (B) 25 (A) balanced (B) chemical
(C) stoichiometric (D) molar
(C) 30 (D) 45
Miscellaneous
57. The percentage of oxygen in NaOH is
_______. 67. Which of the following relations for expressing
(A) 8 (B) 10 volume of a sample is NOT correct?
(C) 40 (D) 60 (A) 1L = 103 ml (B) 1dm3 = 1L
3 3
58. A compound made of two elements A and B (C) 1L = 10 m (D) 1L = 103 cm3
are found to contain 25% A (Atomic mass 68. Which out of the following is NOT a
12.5) and 75% B (Atomic mass 37.5). The homogeneous mixture?
simplest formula of the compound is _______. (A) Solution of glucose in water.
(A) AB (B) AB2 (B) Solution of salt in water.
(C) AB3 (D) A3B (C) Mixture of glucose solution and salt
solution.
59. _______ indicates the actual number of
(D) Mixture of oil and water.
constituent atoms in a molecule.
(A) Empirical formula 69. The molecular mass of hydrogen peroxide is
(B) Molecular formula 34. What is the unit of molecular mass?
(C) Empirical mass (A) g (B) mol
(D) Molecular mass (C) g mol1 (D) mol g1
60. Which of the following has same molecular Synthetic fabrics
formula and empirical formula?
(A) CO2 (B) C6H12O6
(C) C2H2 (D) C2H2O4
61. Empirical formula of glucose is _______.
(A) C6H12O6 (B) C6H11O6
(C) CHO (D) CH2O
1.9 Chemical reactions and stoichiometry
62. The starting material which takes part in
chemical reaction is called _______.
(A) product (B) reactant
(C) catalyst (D) starter
63. ________ is the quantitative relationship
Synthetic fabrics like nylon, terylene, etc., are man-
between the reactants and products in a made fabrics. They are very elastic and dry quickly
balanced chemical equation. after washing. They are mainly popular because of
(A) Stoichiometry (B) Complexometry their crease free nature i.e., they don’t need to be
(C) Chemistry (D) Reactions ironed !!!

7
Std. XI : Triumph Chemistry
8. Two elements, A and B, combine to form a
Critical Thinking compound in which ‘a’ g of A combines with
‘b1’ and ‘b2’ g of B respectively. According to
1.1 Importance and scope of chemistry law of multiple proportion _______.
(A) b1 = b2
1. Azidothymidine drug is used for treating
(B) b1 and b2 bear a simple whole number ratio
_______ patients.
(C) a is always equal to b1
(A) diabetes (B) AIDS
(D) no relation exists between b1 and b2
(C) jaundice (D) tuberculosis
9. After a chemical reaction, the total mass of
2. Which of the following indicates CORRECT
reactants and products _______.
reaction for photosynthesis?
(A) always increases
(A) C + O2 + H2O  Sunlight
Products (B) always decreases
(B) O2 + H2O  Products
Sunlight
(C) does not change
(C) CO2 + H2O  Sunlight
Products (D) always increases or decreases
(D) CO + H2O  Products
Sunlight
10. Two samples of lead oxide were separately
1.2 Historical approach to particulate reduced to metallic lead by heating in a
nature of matter current of hydrogen. The weight of lead from
one oxide was half the weight of lead obtained
3. Which of the following statements is from the other oxide. The data illustrates
INCORRECT? _______.
(A) Constituent substances in a mixture (A) law of reciprocal proportions
retain their separate identities. (B) law of constant proportions
(B) Composition of a mixture can be varied (C) law of multiple proportions
to any extent. (D) law of equivalent proportions
(C) Mixture of liquids are example of
homogeneous mixtures. 11. The law of multiple proportions is illustrated
(D) Mixtures can be separated into pure by the compounds _______.
components by simple physical (A) carbon monoxide and carbon dioxide
methods. (B) potassium bromide and potassium chloride
(C) ordinary water and heavy water (D2O)
4. The revised metric system in which units are
(D) calcium hydroxide and barium
expressed is _______.
hydroxide
(A) CGS (B) MKS
(C) FPS (D) SI 12. How many litres of ammonia will be formed
5. Electrochemical equivalence has unit when 2 L of N2 and 2 L of H2 are allowed to
_______. react?
(A) kg m s1 (B) kg m2 s1 (A) 0.665 (B) 1.0
(C) 1.33 (D) 4.00
(C) kg C1 (D) kg m1 s2
6. Magnitude of ‘pico’ is _______. 1.4 Dalton’s atomic theory
(A) 1012 (B) 1015 13. Which of the following statements is TRUE
(C) 10 12
(D) 109 according to Dalton’s atomic theory?
1.3 Laws of chemical combination (A) A chemical reaction involves only the
separation, combination or rearrangement
7. Hydrogen and oxygen combine to form H2O2 of integer number of atoms.
and H2O containing 5.93% and 11.29% of (B) Law of conservation of mass can be
hydrogen respectively. The data illustrates explained by assuming that total number
_______. of atoms in the reactants and products
(A) law of conservation of mass remain same.
(B) law of definite composition (C) During chemical reactions atoms are
(C) law of reciprocal proportion neither created nor destroyed.
(D) law of multiple proportion (D) All of these.

8
Chapter 01: Some Basic Concepts of Chemistry
1.5 Concepts of elements, atoms and 21. 1 mol of CH4 contains _______.
molecules (A) 6.02  1023 atoms of H
(B) 4 g atom of H
14. Which of the following statements is
(C) 1.81  1023 molecules of CH4
INCORRECT?
(D) 3.0 g of carbon
(A) Atoms may or may not have free
existence. 22. The mass of 1 atom of hydrogen is _______.
(B) A molecule may contain atoms of same (A) 1 g (B) 0.5 g
elements or different elements. (C) 1.6  1024 g (D) 3.2  1024 g
(C) A molecule can be divided into the its 23. 1 gram atom of nitrogen represents _______.
constituent atoms by simple methods. (A) 6.02  1023 N2 molecules
(D) The properties of constituent atoms and (B) 22.4 L of N2 at N.T.P.
the compounds formed from them are (C) 11.2 L of N2 at N.T.P.
completely different. (D) 28 g of nitrogen
1.6 Atomic and molecular masses 24. The number of molecules in 22.4 dm3 of
nitrogen gas at STP is _______.
15. Isotopes are the atoms of the same element
(A) 6.023  1020 (B) 6.023  1023
having _______.
(C) 22.4  1020 (D) 22.4  1023
(A) different number of protons
(B) different number of electrons 25. 27 g of Al (Atomic mass = 27) will combine
(C) different number of neutrons with _______ of O2 to form aluminium oxide.
(D) same number of neutrons (A) 24 g (B) 8 g
(C) 40 g (D) 10 g
16. Which of the following indicates natural
abundance of neon – 20 isotope? 26. How many moles of electrons weigh one kilogram?
(A) 90.92 u 1
(A) 6.022  1023 (B)  1031
(B) 90.92 % 9.108
(C) 90.92 gm mol–1 6.022 1
(D) 90.92  0.012 kg of 12C (C)  1054 (D)  108
9.108 9.108  6.022
17. In chemical scale, the relative mass of the 27. Which of the following has maximum number
isotopic mixture of oxygen atoms (16O, 17O, of atoms?
18
O) is assumed to be equal to _______. (A) 18 g of H2O (B) 16 g of O2
(A) 15.002 (B) 16.00 (C) 4.4 g of CO2 (D) 16 g of CH4
(C) 17.00 (D) 18.00 28. The number of sulphur atoms present in
1.7 Avogadro’s law, Avogadro’s number 0.2 moles of S8 molecules is _______.
and mole concept (A) 4.82  1023 (B) 9.63  1022
23
(C) 9.63  10 (D) 1.20  1023
18. The number of moles of sodium oxide in
29. What will be the volume of CO2 at NTP
620 g is _______.
obtained on heating 10 grams of (90% pure)
(A) 1 mol (B) 10 moles
limestone?
(C) 18 moles (D) 100 moles
(A) 22.4 litre (B) 2.016 litre
19. The number of water molecules in 1 litre of (C) 2.24 litre (D) 20.16 litre
water is _______. 1.8 Percentage composition and empirical
(A) 18 (B) 18  1000 and molecular formula
(C) NA (D) 55.55 NA
30. If two compounds have the same empirical
20. How many atoms are contained in one mole of formula but different molecular formula, they
sucrose (C12H22O11)? must have _______.
(A) 45  6.023  1023 atoms/mole (A) different percentage composition
(B) 5  6.623  1023 atoms/mole (B) different molecular weights
(C) 5  6.023  1023 atoms/mole (C) same viscosity
(D) None of these (D) same vapour density

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Std. XI : Triumph Chemistry
31. Which pair of species have same percentage of Miscellaneous
carbon?
40. Which of the following is a compound?
(A) CH3COOH and C6H12O6
(A) Diamond
(B) CH3COOH and C2H5OH
(B) Charcoal
(C) HCOOCH3 and C12H22O11 (C) Baking powder
(D) C6H12O6 and C12H22O11 (D) 22 Carat Gold
32. Percentage of nitrogen in urea is about 41. The number of atoms in 6 amu of He is
_______. _______.
(A) 46 % (B) 85 % (A) 18
(C) 18 % (D) 28 % (B) 18  6.022  1023
(C) 54
33. Two elements X (Atomic mass 75) and Y
(D) 54  6.023  1023
(Atomic mass 12) combine to give a
compound having 75.8% X. The empirical 42. Two elements, X (Atomic mass 16) and Y
formula of the compound is _______. (Atomic mass 14) combine to form compounds
(A) XY (B) XY2 A, B and C. The ratio of different masses of Y
(C) X2Y2 (D) X2Y3 which combine with fixed mass of X in A, B and
C is 1:3:5. If 32 parts by mass of X combine
34. The molecular mass of an organic compound with 84 parts by mass of Y in B, then in C, 16
is 78. Its empirical formula is CH. The parts by mass of X will combine with _______.
molecular formula is _______. (A) 14 parts by mass of Y
(A) C2H4 (B) C2H2 (B) 42 parts by mass of Y
(C) C6H6 (D) C4H4 (C) 70 parts by mass of Y
(D) 82 parts by mass of Y
35. The empirical formula of a compound is
CH2O. 0.0835 moles of the compound 43. Which of the following is the value of amu?
contains 1.0 g of hydrogen. Molecular formula (A) 1.57  1024 kg (B) 1.66  1024 kg
of the compound is ________. (C) 1.99  1023 kg (D) 1.66  1027 kg
(A) C6H12O6 (B) C5H10O5
(C) C4H8O4 (D) C3H6O3
The Search for God Particle!!!
1.9 Chemical reactions and stoichiometry
36. Calculate the number of moles of methane
required to produce 33 g of carbon dioxide gas
on its complete combustion.
(A) 0.15 moles (B) 0.50 moles
(C) 0.75 moles (D) 0.95 moles
37. The volume of ammonia obtained by the
combination of 10 mL of N2 and 30 mL H2 is
_______.
(A) 20 mL (B) 40 mL
(C) 30 mL (D) 10 mL
The experiment for the search of the Higgs boson,
38. What mass of CaO will be obtained by heating
known as ‘God particle’, using Large Hadron
3 mole of CaCO3? [Atomic mass of Ca = 40]
Collider (LHC) was an international effort involving
(A) 150 g (B) 168 g
thousands of people, with physicists and engineers.
(C) 16.8 g (D) 15 g
The LHC is the world's largest and most
39. 3 g of H2 reacts with 29 g of O2 to yield water. powerful particle collider that consists of a 27-
Which is the limiting reactant? kilometre ring of superconducting magnets with a
(A) H2 (B) O2 number of accelerating structures to boost the
(C) H2O (D) none of there energy of the particles along the way.

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