Conforms to Regulation (EC) No.

1907/2006 (REACH), Annex II, as amended by Regulation (EU)

No. 453/2010 - Europe

SAFETY DATA SHEET

HYDRAZINE HYDRATE 80%
05528771
SECTION 1: Identification of the substance/mixture and of
the company/undertaking
1.1 Product identifier
Product name : HYDRAZINE HYDRATE 80%
Hazardous ingredients : Contains: Hydrazine
1.2 Relevant identified uses of the substance or mixture and uses advised against
Suitable uses : Chemical for synthesis
Reducing agent. (Corrosion inhibitor)
Identified uses Sector of Use Chemical Process Article Environmental
Product Category Category Release
Category Category
Hydrazine.Use as SU03 PC19 PROC01 ERC06a
intermediate in closed SU08 PC32 PROC03 ERC06c
systems. Use as SU09 PROC08b
monomer in closed SU10 PROC09
systems. (Industrial)
Hydrazine.Use as SU23 PC37 PROC01 ERC07
corrosion inhibitor in PROC08b
steam generating and PROC09
heating systems
(Industrial)
Hydrazine.Use as SU03 PC0 PROC01 ERC06b
reducing agent to SU08 PROC08b
remove nitrosyl kations SU09 PROC09
contained in sulphuric
acid (Industrial)
Hydrazine.Use as SU03 PC0 PROC01 ERC06b
stabilising reagent in SU08 PC0 PROC08b
aromatic amines to be SU09 PROC09
further used in synthesis
of dyestuffs (Industrial)
Hydrazine. Use as a SU09 PC21 PROC15 ERC06a
laboratory chemical. SU08 ERC06b
(Industrial) SU10
SU12
SU14
SU23
SU24
Hydrazine .Distribution, SU03 PROC01 ERC02
formulation and (re) PROC03
packing of substances PROC08b
and mixtures (Industrial) PROC09
Hydrazine .Use as SU03 PC0 PROC01 ERC04
reducing agent for metal- SU14 PROC03 ERC06b
based chemicals in PROC08b
closed industrial
systems under
controlled conditions
(Industrial)

1.3 Details of the supplier of the safety data sheet

Supplier : LANXESS Distribution GmbH
D-51369 Leverkusen
Telephone: +49 214 30 65109 Fax: +49 214 30 55787
E-mail: infosds@lanxess.com
1.4 Emergency telephone : +49 214 30 99300 (Sicherheitszentrale CHEMPARK Leverkusen)
number

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SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Classification : Acute Tox. 3, H301
Acute Tox. 3, H311
Acute Tox. 2, H330
Skin Corr. 1B, H314
Skin Sens. 1, H317
Carc. 1B, H350
Aquatic Acute 1, H400
Aquatic Chronic 1, H410
Classification according to Directive 1999/45/EC [DPD]
Classification : Carc. Cat. 2; R45
T; R23/24/25
C; R34
R43
N; R50/53
Human health hazards : May cause cancer. Also toxic by inhalation, in contact with skin and
if swallowed. Causes burns. May cause sensitisation by skin
contact.
Environmental hazards : Very toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment.
2.2 Label elements
Hazard pictograms :

Signal word : Danger

Contains: Hydrazine
Hazard statements : H330 - Fatal if inhaled.
H301 + H311 - Toxic if swallowed or in contact with skin.
H314 - Causes severe skin burns and eye damage.
H317 - May cause an allergic skin reaction.
H350 - May cause cancer.
H410 - Very toxic to aquatic life with long lasting effects.
Additional warning phrases : Not applicable.
Precautionary statements
Prevention : Obtain special instructions before use. Wear protective gloves/
clothing and eye/face protection. Avoid release to the environment.
Do not breathe vapour.
Response : IF INHALED: Remove person to fresh air and keep comfortable for
breathing. Immediately call a POISON CENTER or physician. IF
SWALLOWED: Immediately call a POISON CENTER or physician.
Do NOT induce vomiting. IF ON SKIN (or hair): Take off
immediately all contaminated clothing. Rinse skin with water or
shower. Immediately call a POISON CENTER or physician. IF IN
EYES: Immediately call a POISON CENTER or physician.
Storage : Store locked up.
Disposal : Dispose of contents and container in accordance with all local,
regional, national and international regulations.
2.3 Other hazards
Substance meets the : No.
criteria for PBT according
to Regulation (EC) No.
1907/2006, Annex XIII
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2.3 Other hazards

Substance meets the : No.
criteria for vPvB according
to Regulation (EC) No.
1907/2006, Annex XIII
Other hazards which do : Causes digestive tract burns.
not result in classification

SECTION 3: Composition/information on ingredients

Product definition (REACH) : Mixture
hydrazine solution
contains 80 % hydrazine hydrate, corresponds to 51 % Hydrazine
(aqueous solution)

Classification
Product/ingredient Identifiers % 67/548/EEC Regulation (EC) Type
name No. 1272/2008
[CLP]
Hydrazine REACH #: 51 R10 Flam. Liq. 3, H226 [1]
01-2119492624-31 Carc. Cat. 2; R45 Acute Tox. 3, H301
EC: 206-114-9 T; R23/24/25 Acute Tox. 3, H311
CAS: 302-01-2 C; R34 Acute Tox. 2, H330
Index: 007-008-00-3 R43 Skin Corr. 1B, H314
N; R50/53 Skin Sens. 1A,
H317
Carc. 1B, H350
Aquatic Acute 1,
H400
Aquatic Chronic 1,
H410
See Section 16 for See Section 16
the full text of the for the full text of
R-phrases the H statements
declared above. declared above.

Occupational exposure limits, if available, are listed in Section 8.

Type
[1] Substance classified with a health or environmental hazard
[2] Substance with a workplace exposure limit
[3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII
[4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII
[5] Substance of equivalent concern

SECTION 4: First aid measures

4.1 Description of first aid measures

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Inhalation : Get medical attention immediately. Move exposed person to fresh

air. If it is suspected that fumes are still present, the rescuer should
wear an appropriate mask or self-contained breathing apparatus.
Keep person warm and at rest. If not breathing, if breathing is
irregular or if respiratory arrest occurs, provide artificial respiration or
oxygen by trained personnel. It may be dangerous to the person
providing aid to give mouth-to-mouth resuscitation. If unconscious,
place in recovery position and get medical attention immediately.
Maintain an open airway. Loosen tight clothing such as a collar, tie,
belt or waistband. In case of inhalation of decomposition products
in a fire, symptoms may be delayed. The exposed person may need
to be kept under medical surveillance for 48 hours.
Ingestion : Get medical attention immediately. Wash out mouth with water.
Move exposed person to fresh air. Keep person warm and at rest.
If material has been swallowed and the exposed person is
conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not
induce vomiting unless directed to do so by medical personnel. If
vomiting occurs, the head should be kept low so that vomit does not
enter the lungs. Chemical burns must be treated promptly by a
physician. Never give anything by mouth to an unconscious person.
If unconscious, place in recovery position and get medical attention
immediately. Maintain an open airway. Loosen tight clothing such
as a collar, tie, belt or waistband.
Skin contact : Get medical attention immediately. Flush contaminated skin with
plenty of water. Remove contaminated clothing and shoes.
Continue to rinse for at least 10 minutes. Chemical burns must be
treated promptly by a physician. In the event of any complaints or
symptoms, avoid further exposure. Wash clothing before reuse.
Clean shoes thoroughly before reuse.
Eye contact : Get medical attention immediately. Immediately flush eyes with
plenty of water, occasionally lifting the upper and lower eyelids.
Check for and remove any contact lenses. Continue to rinse for at
least 10 minutes. Chemical burns must be treated promptly by a
physician.
4.2 Most important symptoms and effects, both acute and delayed
See Section 11 for more detailed information on health effects and symptoms.
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician : No special measures required.
See Section 11 for more detailed information on health effects and symptoms.

SECTION 5: Firefighting measures

5.1 Extinguishing media
Suitable extinguishing : Use dry chemical, CO₂, water spray (fog) or foam.
media
Unsuitable extinguishing : Do not use water jet.
media
5.2 Special hazards arising from the substance or mixture
Hazards from the : Combustible liquid. In a fire or if heated, a pressure increase will
substance or mixture occur and the container may burst, with the risk of a subsequent
explosion.
Hazardous combustion : Decomposition products may include the following materials:
products nitrogen oxides
5.3 Advice for firefighters

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HYDRAZINE HYDRATE 80%
Special precautions for
fire-fighters
Special protective
equipment for fire-fighters
SECTION 6: Accidental release measures
6.1 Personal precautions,
protective equipment and
emergency procedures
6.2 Environmental
precautions
6.3 Methods and material for containment and cleaning up
Small spill
Large spill
6.4 Reference to other
sections
SECTION 7: Handling and storage
The information in this section contains generic advice and guidance. The list of Identified Uses in
Section 1 should be consulted for any available use-specific information provided in the Exposure
Scenario(s).
Date of issue
05528771 / 6.01
: Promptly isolate the scene by removing all persons from the vicinity
of the incident if there is a fire. No action shall be taken involving
any personal risk or without suitable training. Move containers from
fire area if this can be done without risk. Use water spray to keep
fire-exposed containers cool. This material is very toxic to aquatic
organisms. Fire water contaminated with this material must be
contained and prevented from being discharged to any waterway,
sewer or drain.
: Fire-fighters should wear appropriate protective equipment and self-
contained breathing apparatus (SCBA) with a full face-piece
operated in positive pressure mode.
: Avoid exposure - obtain special instructions before use. No action
shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected
personnel from entering. Do not touch or walk through spilt material.
Shut off all ignition sources. No flares, smoking or flames in hazard
area. Avoid breathing vapour or mist. Provide adequate ventilation.
Put on appropriate personal protective equipment (see Section 8).
: Avoid dispersal of spilt material and runoff and contact with soil,
waterways, drains and sewers. Inform the relevant authorities if the
product has caused environmental pollution (sewers, waterways, soil
or air). Very toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.
: Stop leak if without risk. Move containers from spill area. Dilute
with water and mop up if water-soluble or absorb with an inert dry
material and place in an appropriate waste disposal container. Use
spark-proof tools and explosion-proof equipment. Dispose of via a
licensed waste disposal contractor.
: Stop leak if without risk. Move containers from spill area. Prevent
entry into sewers, water courses, basements or confined areas.
Contain and collect spillage with non-combustible, absorbent
material e.g. sand, earth, vermiculite or diatomaceous earth and
place in container for disposal according to local regulations (see
Section 13). Use spark-proof tools and explosion-proof equipment.
Dispose of via a licensed waste disposal contractor. Note: see
Section 1 for emergency contact information and Section 13 for
waste disposal. Contaminated absorbent material may pose the
same hazard as the spilt product.
: See Section 1 for emergency contact information.
See Section 8 for information on appropriate personal protective
equipment.
See Section 13 for additional waste treatment information.
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HYDRAZINE HYDRATE 80%
7.1 Precautions for safe
handling
7.2 Conditions for safe
storage, including any
incompatibilities
Seveso III Directive - Reporting thresholds (in tonnes)
Named substances
Name
Hydrazine
Danger criteria
Category
H2: Acute toxicity 2 any route of entry or Acute
toxicity 3 Inhalation route of entry
E1: Hazardous to the aquatic environment - Acute 1
or Chronic 1
C2: Toxic
C9i: Very toxic for the environment
7.3 Specific end use(s)
Recommendations
Industrial sector specific
solutions
Remarks
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: Avoid exposure - obtain special instructions before use. Put on
appropriate personal protective equipment (see Section 8). Eating,
drinking and smoking should be prohibited in areas where this
material is handled, stored and processed. Workers should wash
hands and face before eating, drinking and smoking. Persons with a
history of skin sensitization problems should not be employed in any
process in which this product is used. Do not get in eyes or on skin
or clothing. Do not breathe vapour or mist. Do not ingest. Avoid
release to the environment. Use only with adequate ventilation. Wear
appropriate respirator when ventilation is inadequate. Do not enter
storage areas and confined spaces unless adequately ventilated.
Keep in the original container or an approved alternative made from
a compatible material, kept tightly closed when not in use. Store and
use away from heat, sparks, open flame or any other ignition source.
Use explosion-proof electrical (ventilating, lighting and material
handling) equipment. Use non-sparking tools. Take precautionary
measures against electrostatic discharges. To avoid fire or explosion,
dissipate static electricity during transfer by earthing and bonding
containers and equipment before transferring material. Keep away
from acids. Empty containers retain product residue and can be
hazardous.
: Store in accordance with local regulations. Store in a segregated
and approved area. Store in original container protected from direct
sunlight in a dry, cool and well-ventilated area, away from
incompatible materials (see Section 10) and food and drink. Store
locked up. Eliminate all ignition sources. Separate from acids.
Separate from oxidizing materials. Keep container tightly closed and
sealed until ready for use. Containers that have been opened must
be carefully resealed and kept upright to prevent leakage. Do not
store in unlabelled containers. Use appropriate containment to avoid
environmental contamination.
Notification and Safety report
MAPP threshold threshold
0,5 2
Notification and Safety report
MAPP threshold threshold
50 200
100 200
50 200
100 200
: Not available.
: Not available.
: Transfer and handle product only in a closed system.
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SECTION 8: Exposure controls/personal protection

The information in this section contains generic advice and guidance. The list of Identified Uses in
Section 1 should be consulted for any available use-specific information provided in the Exposure
Scenario(s).
8.1 Control parameters
Exposure limit values : Not available.

Derived effect levels

Ingredient name Type Exposure Value Population Effects Remarks
Hydrazine DNEL Short term 0,133 mg/ Workers Systemic -
Inhalation m³
DNEL Short term 0,133 mg/ Workers Local -
Inhalation m³
DNEL Long term Inhalation 0,013 mg/ Workers Systemic -
m³
DNEL Long term Inhalation 0,013 mg/ Workers Local -
m³
DNEL Long term Dermal 0,006 mg/ Workers Systemic -
kg bw/day
Conclusion/Summary : Not available.

Predicted No Effect Concentration (PNEC)

Ingredient name
Hydrazine
Conclusion/Summary
Recommended monitoring
procedures
8.2 Exposure controls
Risk management measures
Occupational exposure controls
Technical measures
Personal protection measures
Compartment Value Method Detail Remarks
Detail
Sewage Treatment 0,055 mg/l Assessment Factors -
Plant
Marine 0,06 μg/l Assessment Factors -
Fresh water 0,6 μg/l Assessment Factors -
: Not available.
: If this product contains ingredients with exposure limits, personal,
workplace atmosphere or biological monitoring may be required to
determine the effectiveness of the ventilation or other control
measures and/or the necessity to use respiratory protective
equipment. Reference should be made to monitoring standards,
such as the following: European Standard EN 689 (Workplace
atmospheres - Guidance for the assessment of exposure by
inhalation to chemical agents for comparison with limit values and
measurement strategy) European Standard EN 14042 (Workplace
atmospheres - Guide for the application and use of procedures for
the assessment of exposure to chemical and biological agents)
European Standard EN 482 (Workplace atmospheres - General
requirements for the performance of procedures for the
measurement of chemical agents) Reference to national guidance
documents for methods for the determination of hazardous
substances will also be required.
: Use only with adequate ventilation. Use process enclosures, local
exhaust ventilation or other engineering controls to keep worker
exposure to airborne contaminants below any recommended or
statutory limits. The engineering controls also need to keep gas,
vapour or dust concentrations below any lower explosive limits. Use
explosion-proof ventilation equipment.

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Respiratory protection : Use a properly fitted, air-purifying or air-fed respirator complying with
an approved standard if a risk assessment indicates this is
necessary. Respirator selection must be based on known or
anticipated exposure levels, the hazards of the product and the safe
working limits of the selected respirator.
Recommended: Vapour respirator, ammonia filter (Type K)
Hand protection : Chemical-resistant, impervious gloves complying with an approved
standard should be worn at all times when handling chemical
products if a risk assessment indicates this is necessary. After
contamination with product change the gloves immediately and
dispose of them according to relevant national and local regulations
Recommended: (< 1 hour) Polyvinyl chloride - PVC
Eye protection : Safety eyewear complying with an approved standard should be
used when a risk assessment indicates this is necessary to avoid
exposure to liquid splashes, mists, gases or dusts.
Recommended: Tightly fitting safety goggles.

Skin protection : Personal protective equipment for the body should be selected
based on the task being performed and the risks involved and
should be approved by a specialist before handling this product.
Recommended: Wear protective clothing.
Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical
products, before eating, smoking and using the lavatory and at the
end of the working period. Appropriate techniques should be used
to remove potentially contaminated clothing. Wash contaminated
clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Environmental exposure controls
Technical measures : Emissions from ventilation or work process equipment should be
checked to ensure they comply with the requirements of
environmental protection legislation. In some cases, fume
scrubbers, filters or engineering modifications to the process
equipment will be necessary to reduce emissions to acceptable
levels.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
General information
Appearance
Physical state : Liquid.
Colour : Colourless.
Odour : Ammoniacal.
Important health, safety and environmental information
pH : >12 [Conc. (% w/w): 51%]
Boiling point : 117,2 °C (1013 hPa)
Melting point : -57°C (-70,6°F)
Flash point : Closed cup: 91°C (195,8°F) [DIN 51758]
Explosion limits : Lower: 4,8%
Upper: 100%
Vapour pressure : 13 hPa (20℃)
Density : 1,028 kg/L (20℃)
Solubility : Miscible in water.
Viscosity : Dynamic: 1,33 mPa·s
Ignition temperature : 310°C

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Decomposition : Not available.

temperature
9.2 Other information
No additional information.

SECTION 10: Stability and reactivity

10.1 Reactivity
10.2 Chemical stability
10.3 Possibility of
hazardous reactions
10.4 Conditions to avoid
: No specific test data related to reactivity available for this product or
its ingredients.
: The product is stable.
: Under normal conditions of storage and use, hazardous reactions
will not occur.
: Contact with strong oxidising agents may cause hazardous reactions.
Keep away from oxidising and acid substances and from heavy
metal compounds. Contact with cellulose or cotton textiles,
especially at elevated temperatures, may result in ignition.

10.5 Incompatible materials : Reactive or incompatible with the following materials:

acids
10.6 Hazardous : Under normal conditions of storage and use, hazardous
decomposition products decomposition products should not be produced.

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Potential acute health effects
Inhalation : Fatal if inhaled. May give off gas, vapour or dust that is very
irritating or corrosive to the respiratory system.
Ingestion : Toxic if swallowed. Corrosive to the digestive tract. Causes burns.
Skin contact : Causes severe burns. Toxic in contact with skin. May cause an
allergic skin reaction.
Eye contact : Causes serious eye damage.
Acute toxicity

Product/ingredient Result Species Dose Exposure Test

name
Hydrazine LD50 Oral - Rat - Male 173 mg/kg - -
LD50 Oral - Rat - 108 to 141 - -
Female mg/kg
Hydrazine LC50 - Rat 759 mg/m³ 4 hours -
Inhalation
Vapour
Acute toxicity estimates
Route ATE value (Acute Toxicity Estimates)
Oral 212 mg/kg
Dermal 588,8 mg/kg
Inhalation (gases) 1373,8 ppm
Inhalation (vapours) 1,49 mg/l
Inhalation (dusts and mists) 0,9813 mg/l
Irritation/Corrosion
Product/ingredient Result Species Score Exposure Test Reversibility
name

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HYDRAZINE Skin - Rabbit - 4 hours * Not

HYDRATE 80% Visible reversible
necrosis
Skin : Corrosive. * Test results for a product at higher concentration
Eyes : Risk of serious damage to eyes.
Sensitiser
Product/ingredient Route of Species Result Test description
name exposure
Hydrazine skin Human Sensitising -

Potential chronic health effects

Chronic toxicity
Product/ingredient name Result Species Dose Exposure
Hydrazine Sub-acute NOAEL Rat 1,92 mg/kg 28 days; 7
Oral per day days per week
Carcinogenicity
Conclusion/Summary : Hydrazine:In long−term animal tests and mutagenicity
investigations carried out with several hydrazid compounds
indications of a mutagenic/carcinogenic potential of this substance
group were noted.
Mutagenicity
Product/ingredient name Test Experiment Result
Hydrazine OECD 471 Bacterial Experiment: In vitro Positive
Reverse Mutation Test;
with metabolic activation
and without metabolic
activation
Subject: Bacteria
OECD 473 In vitro Experiment: In vitro Positive
Mammalian
Chromosomal
Aberration Test
Subject:
Mammalian-Animal
Cell: Somatic
OECD 476 In vitro Experiment: In vitro Positive
Mammalian Cell Gene
Mutation Test
Subject:
Mammalian-Animal
Cell: Somatic
Carcinogenicity : May cause cancer. Risk of cancer depends on duration and level of
exposure.

SECTION 12: Ecological information

12.1 Toxicity
Product/ingredient Test Result Species Exposure
name
Hydrazine OECD 209 Acute EC0 5,5 mg/l Bacteria 3 hours
Activated
Sludge,
Respiration
Inhibition Test
- Acute EC50 0,175 mg/l Daphnia - 48 hours
Daphnia pulex

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Product/ingredient Test Result Species Exposure

name
OECD EU C. Acute IC50 0,017 mg/l Algae - 72 hours
3 Desmodesmus
subspicatus
- Acute LC50 0,61 mg/l Fish - 96 hours
Lebistes
reticulatus
OECD 211 Chronic NOEC 0,01 mg/l Daphnia - 21 days
Daphnia Daphnia
Magna magna
Reproduction
Test
OECD EU C. Chronic NOEC 0,006 mg/l Algae - 48 hours
3 Desmodesmus
subspicatus
Conclusion/Summary : Not available.
12.2 Persistence and degradability
Product/ingredient name Aquatic half-life Photolysis Biodegradability
Hydrazine Fresh water <1 days, pH - -
8,2, 21°C
Product/ingredient name Rate of Period (days) Test
degradation/
elimination (%)
Hydrazine 88 % 0,25 days OECD 302B Inherent
Biodegradability: Zahn-Wellens/
EMPA Test
Conclusion/Summary : Not available.
12.3 Bioaccumulative potential
Bioaccumulative potential
Product/ingredient name LogPow BCF Potential
Hydrazine -0,16 - low
12.4 Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)
Mobility : Not available.
12.5 Results of PBT and vPvB assessment
PBT : No.
vPvB : No.
12.6 Other adverse effects
Other adverse effects : Not available.
AOX : The product does not contain organically bound halogens which
could lead to an AOX value in waste water.

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SECTION 13: Disposal considerations

The information in this section contains generic advice and guidance. The list of Identified Uses in
Section 1 should be consulted for any available use-specific information provided in the Exposure
Scenario(s).
13.1 Waste treatment methods
Product
Methods of disposal
Hazardous waste
Packaging
Methods of disposal
Special precautions
: Examine possibilities for re-utilisation. Product residues and
uncleaned empty containers should be packaged, sealed, labelled,
and disposed of or recycled according to relevant national and local
regulations. Where large quantities are concerned, consult the
supplier. When uncleaned empty containers are passed on, the
recipient must be warned of any possible hazard that may be caused
by residues. For disposal within the EC, the appropriate code
according to the European Waste List (EWL) should be used. It is
among the tasks of the polluter to assign the waste to waste codes
specific to industrial sectors and processes according to the
European Waste List (EWL).
: The classification of the product may meet the criteria for a
hazardous waste.
: The generation of waste should be avoided or minimised wherever
possible. Waste packaging should be recycled. Incineration or
landfill should only be considered when recycling is not feasible.
: This material and its container must be disposed of in a safe way.
Care should be taken when handling emptied containers that have
not been cleaned or rinsed out. Empty containers or liners may
retain some product residues. Avoid dispersal of spilt material and
runoff and contact with soil, waterways, drains and sewers.

SECTION 14: Transport information

ADR/RID ADN IMDG IATA
14.1 UN number UN2030 UN2030 UN2030 UN2030

14.2 UN proper HYDRAZINE, HYDRAZINE HYDRAZINE, HYDRAZINE,

shipping name AQUEOUS AQUEOUS AQUEOUS AQUEOUS
SOLUTION SOLUTION SOLUTION SOLUTION
14.3 Transport 8 (6.1) 8 (6.1) 8 (6.1) 8 (6.1)
hazard class(es)/
Marks

14.4 Packing II II II II
group
14.5 Yes. Yes. Yes Yes
Environmental
hazards

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14.6 Special Hazard Hazard Emergency Passenger

precautions for identification identification schedules (EmS) aircraft
user/Additional number number F-A, S-B Forbidden
information 86 86
Cargo aircraft
855: 30 L

14.7 Transport in bulk according to Annex : Not available.

II of MARPOL 73/78 and the IBC Code
Hazard notes:
Corrosive.
Toxic.
Combustible.
Flash point (Closed cup): 91°C (DIN 51758)
Environmentally hazardous substance.
Keep away from acids and oxidizing agents.
Keep separated from foodstuffs.

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture
EU Regulation (EC) No. 1907/2006 (REACH)
Annex XIV - List of substances subject to authorisation
Annex XIV
None of the components are listed.
Substances of very high concern
Ingredient name Intrinsic property Status Reference Date of
number revision
Hydrazine Carcinogen Candidate ED/31/2011 30.06.
2011
Annex XVII - Restrictions on the manufacture, placing on the market and use of certain dangerous
substances, mixtures and articles
Product/ingredient name EC number CAS no. Restriction
Hydrazine 206-114-9 302-01-2 28

Other EU regulations
Seveso III Directive
This product is controlled under the Seveso III Directive.
Named substances
Name
Hydrazine

Danger criteria
Category
H2: Acute toxicity 2 any route of entry or Acute toxicity 3 Inhalation route of entry
E1: Hazardous to the aquatic environment - Acute 1 or Chronic 1
C2: Toxic
C9i: Very toxic for the environment

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HYDRAZINE HYDRATE 80%
15.2 Chemical Safety
Assessment
SECTION 16: Other information
Abbreviations and acronyms : ATE = Acute Toxicity Estimate
Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/
GHS]
Classification
Acute Tox. 3, H301
Acute Tox. 3, H311
Acute Tox. 2, H330
Skin Corr. 1B, H314
Skin Sens. 1, H317
Carc. 1B, H350
Aquatic Acute 1, H400
Aquatic Chronic 1, H410
Full text of abbreviated H
statements
Full text of classifications
[CLP/GHS]
Date of issue
05528771 / 6.01
: Complete.
CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No.
1272/2008]
DNEL = Derived No Effect Level
EUH statement = CLP-specific Hazard statement
PBT = Persistent, Bioaccumulative and Toxic
PNEC = Predicted No Effect Concentration
RRN = REACH Registration Number
vPvB = Very Persistent and Very Bioaccumulative
Justification
Calculation method
Calculation method
Calculation method
Calculation method
Calculation method
Calculation method
Calculation method
Calculation method
: H226 Flammable liquid and vapour.
H301 Toxic if swallowed.
H301 (oral) Toxic if swallowed.
H311 Toxic in contact with skin.
H311 (dermal) Toxic in contact with skin.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H330 Fatal if inhaled.
H330 (inhalation) Fatal if inhaled.
H350 May cause cancer.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
: Acute Tox. 2, ACUTE TOXICITY (inhalation) - Category 2
H330
Acute Tox. 3, ACUTE TOXICITY (oral) - Category 3
H301
Acute Tox. 3, ACUTE TOXICITY (dermal) - Category 3
H311
Aquatic Acute 1, ACUTE AQUATIC HAZARD - Category 1
H400
Aquatic Chronic 1, LONG-TERM AQUATIC HAZARD - Category 1
H410
Carc. 1B, H350 CARCINOGENICITY - Category 1B
Flam. Liq. 3, H226 FLAMMABLE LIQUIDS - Category 3
Skin Corr. 1B, SKIN CORROSION/IRRITATION - Category 1B
H314
Skin Sens. 1, SKIN SENSITIZATION - Category 1
H317
Skin Sens. 1A, SKIN SENSITIZATION - Category 1A
H317
: 2016-03-03 Page: 14/42
HYDRAZINE HYDRATE 80% 05528771 / 6.01

Full text of R-phrases : R10- Flammable.

referred to in sections 2 and R45- May cause cancer.
3 R23/24/25- Also toxic by inhalation, in contact with skin and if
swallowed.
R34- Causes burns.
R43- May cause sensitisation by skin contact.
R50/53- Very toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.
Wording of the instructions : ERC02 Formulation of preparations
ERC04 Industrial use of processing aids in processes and
for use according to Use
products, not becoming part of articles
Descriptor System, to which ERC06a Industrial use resulting in manufacture of another
reference is made in substance (use of intermediates)
paragraph 1: ERC06b Industrial use of reactive processing aids
ERC06c Industrial use of monomers for manufacture of
thermoplastics
ERC07 Industrial use of substances in closed systems
PC0 UCN R0500/R05100 (reduction agents)
PC19 Intermediate
PC21 Laboratory chemicals
PC32 Polymer preparations and compounds
PC37 Water treatment chemicals
PROC01 Use in closed process, no likelihood of exposure
PROC03 Use in closed batch process (synthesis or formulation)
PROC08b Transfer of substance or preparation (charging/
discharging) from/to vessels/large containers at
dedicated facilities
PROC09 Transfer of substance or preparation into small
containers (dedicated filling line, including weighing)
PROC15 Use a laboratory reagent
SU03 Industrial uses
SU08 Manufacture of bulk, large scale chemicals (including
petroleum products)
SU09 Manufacture of fine chemicals
SU10 Formulation [mixing] of preparations and/or re-
packaging (excluding alloys)
SU12 Manufacture of plastics products, including
compounding and conversion
SU14 Manufacture of basic metals, including alloys
SU23 Electricity, steam, gas water supply and sewage
treatment
SU24 Scientific research and development
History
Date of issue : 2016-03-03
Date of previous issue : 2014-12-08
Version : 6.01
Indicates information that has changed from previously issued version.
Notice to reader
The data given here is based on current knowledge and experience. The purpose of this
Safety Data Sheet and its Annex [if required according to Regulation (EC) 1907/2006 (REACh)]
is to describe the products in terms of their safety requirements. The given details do not
imply any guarantee concerning the composition, properties or performance.
Annex to the extended Safety Data Sheet
(eSDS)
Identification of the substance or mixture
Product definition
Code
Product name
Section 1 - Title
Short title/List of use
descriptors
Name of contributing
environmental scenario
and corresponding ERC
List of names of
contributing worker
scenarios and
corresponding PROCs
Additional information
Section 2 - Exposure controls
Contributing scenario controlling environmental exposure for : -ERC06a, ERC06c
Product characteristics
Concentration of substance
in mixture or article
Amounts used
Frequency and duration of
use
Environment factors not
influenced by risk
management
Other given operational
conditions affecting
environmental exposure
Technical conditions and
measures at process level
(source) to prevent release
: Mixture
: 05528771
: HYDRAZINE HYDRATE 80%
: Identified use name: Hydrazine.Use as intermediate in closed
systems. Use as monomer in closed systems. (Industrial)
Process Category: PROC01, PROC03, PROC08b, PROC09
Substance supplied to that use in form of: As such
Sector of end use: SU03, SU08, SU09, SU10
Subsequent service life relevant for that use: No.
Environmental Release Category: ERC06a, ERC06c
Market sector by type of chemical product: PC19, PC32
: -ERC06a, ERC06c
: -PROC01, PROC03, PROC08b, PROC09
: PROCs and ERCs for communication purpose only. Risk
assessment based on Expert judgement.
: Liquid.
Vapour pressure: 19.2 hPa (25 °C) (hydrazine hydrate 100%)
: ≤ 64% (referring to pure hydrazine)
: Annual site tonnage (t/a): Not applicable.
Risk from exposure via the aquatic environment is driven by effluent
discharge to freshwater. Emissions are limited by the daily waste
water independent of the tonnage applied.
: Continuous release (d/a) : 300
: Local freshwater dilution factor: 10
If receiving surface water flow is (m³/d): 18 000
Local marine water dilution factor 100
: The substance shall be rigorously contained by technical means
during handling and use.
: waste water (kg/d) ≤ 0.02(referring to pure hydrazine)
Deviating from the STP size and water body size daily emissions
have to be adjusted.
Based on the applied operational conditions, emission in the air and
soil compartment are negligible.
16/42
HYDRAZINE HYDRATE 80%
Technical on-site conditions
and measures to reduce or
limit discharges, air
emissions and releases to
soil
Organisational measures to
prevent/limit release from
site
Conditions and measures
related to municipal sewage
treatment plant
Conditions and measures
related to external treatment
of waste for disposal
Conditions and measures
related to external recovery
of waste
Contributing scenario controlling worker exposure for : -PROC01, PROC03, PROC08b,
PROC09
Product characteristics
Concentration of
substance in mixture or
article
Physical state
Amounts used
Frequency and duration of
use
Human factors not
influenced by risk
management
Other given operational
conditions affecting
workers exposure
Technical conditions and
measures at process level
(source) to prevent release
Technical conditions and
measures to control
dispersion from source
towards the worker
hydrazine. Use as intermediate in closed
systems. Use as monomer in closed
systems. (Industrial)
: The waste water has to be directed to a dedicated sewage
treatment plant or treated by other suitable techniques.
Waste air should be scrubbed or filtered. (efficiency %): > 95
Floor should be impervious and resistant to liquid.
: Only properly trained and authorised personnel shall handle the
substance.
Substance-handling procedures shall be well documented and
supervised.
: Size of sewage treatment plant (m³/d): 2 000
(efficiency %): > 45
Sewage sludge has not to be disposed on agricultural soil.
: General information on waste disposal see section 13.
: No special measures required.
: Vapour pressure: 19.2 hPa (25 °C) (hydrazine hydrate 100%)
: ≤ 64% (referring to pure hydrazine)
: Liquid
: Not applicable.
: Exposure frequency(d/a) : 230
Exposure duration per day:
PROC01, PROC03 :
8 h (full shift).
PROC08b, PROC09: ≤ 1 hours
Sampling: ≤ 0.25 hours
: Respiratory volume (m³/d): 10 (light activity)
: Indoor setting
Outdoor setting
: Product is handled under closed conditions.
: Local exhaust ventilation required.(efficiency %): > 90 %
Sample via a closed loop or other system to avoid exposure.
Use of closed transfers of liquids from storage to production
equipment (e.g. metered piped or pumped additions).
Use vapour recovery system.
Clear transfer lines prior to de-coupling.
Provide extract ventilation to points where emissions occur.
17/42
HYDRAZINE HYDRATE 80%
Organisational measures to
prevent/limit releases,
dispersion and exposure
Conditions and measures related to personal protection and hygiene
Personal protection
hydrazine. Use as intermediate in closed
systems. Use as monomer in closed
systems. (Industrial)
: Only properly trained and authorised personnel shall handle the
substance.
Substance-handling procedures shall be well documented and
supervised.
Ensure intensive management supervision controls.
Drain down systems and clear transfer lines prior to breaking
containment.
Clean/flush equipment, where possible, prior to maintenance.
Clear up spills immediately.
Regularly inspect, test and maintain all control measures.
Consider the need for risk based health surveillance.
Organize regular exposure monitoring to check that exposure
levels of operators stay beyond the exposure limits (exposure
limits: see Section 8)
: Wear protective clothing as described in section 8.
Wear gloves as described in section 8.
Wear safety goggles as described in section 8.

Sampling:
If the efficiency of the local exhaust ventilation cannot be ensured
or the installation of a LEV is not possible, wear respiratory
protective equipment (efficiency %): 95

During (Dis)connection steps:

Wear respiratory protection as described in section 8. (efficiency
%): 95
(Dis)Connection of non-closed (?) dosing units: Wear coverall
according to section 8.

Section 3 - Exposure estimation and reference to its source

Website: : Not available.

Exposure estimation and reference to its source - Environment: -ERC06a, ERC06c

Exposure assessment : Manual calculated.

(environment):
Exposure estimation : The calculated individual exposure figures are below the PNECs
(RCR ratios < 1).

Exposure estimation and reference to its source - Workers: -PROC01, PROC03, PROC08b,
PROC09

Exposure assessment : Qualitative Assessment.

(human):
Exposure estimation : Applying the stipulated Risk Management Measures and
operational conditions, hydrazine will be highly contained.
Based on these measures, no risk for workers is concluded.

Section 4 - Guidance to DU to evaluate whether he works inside the

boundaries set by the ES

18/42
HYDRAZINE HYDRATE 80% hydrazine. Use as intermediate in closed
systems. Use as monomer in closed
systems. (Industrial)

Environment : Under the above listed conditions the process is deemed safe.
Other conditions should only be considered when measurements or
suitable calculations show that the RCR is < 1.
Health : Under the above listed conditions the process is deemed safe.
Other conditions should only be considered when measurements or
suitable calculations show that the RCR is < 1.

Additional good practice advice beyond the REACH CSA

Environment : Not applicable.
Health : Not applicable.

19/42
Annex to the extended Safety Data Sheet
(eSDS)
Identification of the substance or mixture
Product definition
Code
Product name
Section 1 - Title
Short title/List of use
descriptors
Name of contributing
environmental scenario
and corresponding ERC
List of names of
contributing worker
scenarios and
corresponding PROCs
Additional information
Section 2 - Exposure controls
Contributing scenario controlling environmental exposure for : -ERC07
Product characteristics
Concentration of substance
in mixture or article
Amounts used
Frequency and duration of
use
Environment factors not
influenced by risk
management
Other given operational
conditions affecting
environmental exposure
: Mixture
: 05528771
: HYDRAZINE HYDRATE 80%
: Identified use name: Hydrazine.Use as corrosion inhibitor in steam
generating and heating systems (Industrial)
Process Category: PROC01, PROC08b, PROC09
Substance supplied to that use in form of: In a mixture
Sector of end use: SU23
Subsequent service life relevant for that use: No.
Environmental Release Category: ERC07
Market sector by type of chemical product: PC37
: -ERC07
-ERC07
: -PROC01, PROC08b, PROC09
: PROCs and ERCs for communication purpose only. Risk
assessment based on Expert judgement.
: Liquid.
Vapour pressure: 19.2 hPa (25 °C) (hydrazine hydrate 100%)
: ≤ 64% (referring to pure hydrazine)
: Annual site tonnage (t/a): Not applicable.
Risk from exposure via the aquatic environment is driven by effluent
discharge to freshwater. Emissions are limited by the daily waste
water independent of the tonnage applied.
: Continuous release (d/a) : 300
: Local freshwater dilution factor 10
Local marine water dilution factor 100
: Direct emission of blow-off water into fresh/ marine water.
Concentration in the blow off-water (mg/L): ≤ 5.47*10-3 (pure
hydrazine)
Deviating from the dilution factors, daily emissions have to be
adjusted.
Based on the applied operational conditions, emission in the air and
soil compartment are negligible.
20/42
HYDRAZINE HYDRATE 80%
Technical conditions and
measures at process level
(source) to prevent release
Technical on-site conditions
and measures to reduce or
limit discharges, air
emissions and releases to
soil
Organisational measures to
prevent/limit release from
site
Conditions and measures
related to municipal sewage
treatment plant
Conditions and measures
related to external treatment
of waste for disposal
Conditions and measures
related to external recovery
of waste
Contributing scenario controlling environmental exposure for : -ERC07
Product characteristics
Concentration of substance
in mixture or article
Amounts used
Frequency and duration of
use
Environment factors not
influenced by risk
management
Other given operational
conditions affecting
environmental exposure
Technical conditions and
measures at process level
(source) to prevent release
Technical on-site conditions
and measures to reduce or
limit discharges, air
emissions and releases to
soil
Organisational measures to
prevent/limit release from
site
hydrazine. Use as corrosion inhibitor in
steam generating and heating systems
(Industrial)
: The substance shall be rigorously contained by technical means
during handling and use.
: Waste air should be scrubbed or filtered. (efficiency %): > 95
Floor should be impervious and resistant to liquid.
: Only properly trained and authorised personnel shall handle the
substance.
Substance-handling procedures shall be well documented and
supervised.
: Not required
: General information on waste disposal see section 13.
: No special measures required.
: Liquid.
Vapour pressure: 19.2 hPa (25 °C) (hydrazine hydrate 100%)
: ≤ 64% (referring to pure hydrazine)
: Annual site tonnage (t/a): Not applicable.
Risk from exposure via the aquatic environment is driven by effluent
discharge to freshwater. Emissions are limited by the daily waste
water independent of the tonnage applied.
: Continuous release (d/a) : 300
: Local freshwater dilution factor: 10
If receiving surface water flow is (m³/d): 18 000
Local marine water dilution factor: 100
: waste water (kg/day) : ≤ 0.02 (referring to pure hydrazine)
Deviating from the dilution factors, daily emissions have to be
adjusted.
Based on the applied operational conditions, emission in the air and
soil compartment are negligible.
: The substance shall be rigorously contained by technical means
during handling and use.
: The waste water has to be directed to a dedicated sewage
treatment plant or treated by other suitable techniques.
Waste air should be scrubbed or filtered. (efficiency %): > 95
Floor should be impervious and resistant to liquid.
: Only properly trained and authorised personnel shall handle the
substance.
Substance-handling procedures shall be well documented and
supervised.
21/42
HYDRAZINE HYDRATE 80%
Conditions and measures
related to municipal sewage
treatment plant
Conditions and measures
related to external treatment
of waste for disposal
Conditions and measures
related to external recovery
of waste
Contributing scenario controlling worker exposure for : -PROC01, PROC08b, PROC09
Product characteristics
Concentration of
substance in mixture or
article
Physical state
Amounts used
Frequency and duration of
use
Human factors not
influenced by risk
management
Other given operational
conditions affecting
workers exposure
Technical conditions and
measures at process level
(source) to prevent release
Technical conditions and
measures to control
dispersion from source
towards the worker
Organisational measures to
prevent/limit releases,
dispersion and exposure
Conditions and measures related to personal protection and hygiene
hydrazine. Use as corrosion inhibitor in
steam generating and heating systems
(Industrial)
: Size of sewage treatment plant (m³/d): 2 000
(efficiency %): ≥ 45
Sewage sludge shall not be disposed on agricultural soil.
: General information on waste disposal see section 13.
: No special measures required.
: Vapour pressure: 19.2 hPa (25 °C) (hydrazine hydrate 100%)
: ≥ 15 % to ≤ 64 % (referring to pure hydrazine)
: Liquid
: Not applicable.
: Exposure frequency(d/a) : 230
Exposure duration per day:
PROC01: 8 hours
PROC08b, PROC09 :≤ 1 h
Sampling: ≤ 0.25
: Respiratory volume (m³/d): 10 (light activity)
: Indoor setting
Outdoor setting
: Process fully enclosed.
: Sample via a closed loop or other system to avoid exposure.
Use of closed transfers of liquids from storage to production
equipment (e.g. metered piped or pumped additions).
Use vapour recovery system.
Clear transfer lines prior to de-coupling.
Provide extract ventilation to points where emissions occur.
: Only properly trained and authorised personnel shall handle the
substance.
Substance-handling procedures shall be well documented and
supervised.
Ensure intensive management supervision controls.
Drain down systems and clear transfer lines prior to breaking
containment.
Clean/flush equipment, where possible, prior to maintenance.
Clear up spills immediately.
Regularly inspect, test and maintain all control measures.
Consider the need for risk based health surveillance.
Organize regular exposure monitoring to check that exposure
levels of operators stay beyond the exposure limits (exposure
limits: see Section 8)
22/42
HYDRAZINE HYDRATE 80% hydrazine. Use as corrosion inhibitor in
steam generating and heating systems
(Industrial)
Personal protection : Wear protective clothing as described in section 8.
Wear gloves as described in section 8. (efficiency %): 90
Wear safety goggles as described in section 8.

Sampling:
If the efficiency of the local exhaust ventilation cannot be ensured
or the installation of a LEV is not possible, wear respiratory
protective equipment (efficiency %): 95

During (Dis)connection steps:

Wear respiratory protection as described in section 8. (efficiency
%): 95

Section 3 - Exposure estimation and reference to its source

Website: : Not available.

Exposure estimation and reference to its source - Environment: -ERC07

Exposure assessment : Manual calculated.

(environment):
Exposure estimation : The calculated individual exposure figures are below the PNECs
(RCR ratios < 1).
Exposure estimation and reference to its source - Environment: -ERC07

Exposure assessment : Manual calculated.

(environment):
Exposure estimation : The calculated individual exposure figures are below the PNECs
(RCR ratios < 1).

Exposure estimation and reference to its source - Workers: -PROC01, PROC08b, PROC09

Exposure assessment : Qualitative Assessment.

(human):
Exposure estimation : Applying the stipulated Risk Management Measures and
operational conditions, hydrazine will be highly contained.
Based on these measures, no risk for workers is concluded.

Section 4 - Guidance to DU to evaluate whether he works inside the

boundaries set by the ES
Environment : Under the above listed conditions the process is deemed safe.
Other conditions should only be considered when measurements or
suitable calculations show that the RCR is < 1.
Health : Under the above listed conditions the process is deemed safe.
Other conditions should only be considered when measurements or
suitable calculations show that the RCR is < 1.

Additional good practice advice beyond the REACH CSA

Environment : Not applicable.
Health : Not applicable.

23/42
Annex to the extended Safety Data Sheet
(eSDS)
Identification of the substance or mixture
Product definition
Code
Product name
Section 1 - Title
Short title/List of use
descriptors
Name of contributing
environmental scenario
and corresponding ERC
List of names of
contributing worker
scenarios and
corresponding PROCs
Additional information
Section 2 - Exposure controls
Contributing scenario controlling environmental exposure for : -ERC06b
Product characteristics
Concentration of substance
in mixture or article
Amounts used
Frequency and duration of
use
Other given operational
conditions affecting
environmental exposure
Technical conditions and
measures at process level
(source) to prevent release
: Mixture
: 05528771
: HYDRAZINE HYDRATE 80%
: Identified use name: Hydrazine.Use as reducing agent to remove
nitrosyl kations contained in sulphuric acid (Industrial)
Process Category: PROC01, PROC08b, PROC09
Substance supplied to that use in form of: As such
Sector of end use: SU03, SU08, SU09
Subsequent service life relevant for that use: No.
Environmental Release Category: ERC06b
Market sector by type of chemical product: PC0
: -ERC06b
: -PROC01, PROC08b, PROC09
: PROCs and ERCs for communication purpose only. Risk
assessment based on Expert judgement.
: Liquid.
Vapour pressure: 19.2 hPa (25 °C) (hydrazine hydrate 100%)
: 40 % (25.6 % hydrazine pure)
: Annual site tonnage (t/a): Not applicable.
Risk from exposure via the aquatic environment is driven by effluent
discharge to freshwater. Emissions are limited by the daily waste
water independent of the tonnage applied.
: Continuous release (d/a) : 300
: Percentage release to waste water: 0
Based on the applied operational conditions, emission in the air and
soil compartment are negligible.
: The generation of waste should be avoided or minimised wherever
possible.
24/42
HYDRAZINE HYDRATE 80%
Technical on-site conditions
and measures to reduce or
limit discharges, air
emissions and releases to
soil
Organisational measures to
prevent/limit release from
site
Conditions and measures
related to municipal sewage
treatment plant
Conditions and measures
related to external treatment
of waste for disposal
Conditions and measures
related to external recovery
of waste
Contributing scenario controlling worker exposure for : -PROC01, PROC08b, PROC09
Product characteristics
Concentration of
substance in mixture or
article
Physical state
Amounts used
Frequency and duration of
use
Human factors not
influenced by risk
management
Other given operational
conditions affecting
workers exposure
Technical conditions and
measures at process level
(source) to prevent release
Technical conditions and
measures to control
dispersion from source
towards the worker
hydrazine. Use as reducing agent to
remove nitrosyl kations contained in
sulphuric acid (Industrial)
: Waste air should be scrubbed or filtered. (efficiency %):> 95
Floor should be impervious and resistant to liquid.
: Only properly trained and authorised personnel shall handle the
substance.
Substance-handling procedures shall be well documented and
supervised.
: Not applicable as there is no release to wastewater.
: General information on waste disposal see section 13.
: No special measures required.
: Vapour pressure: 19.2 hPa (25 °C) (hydrazine hydrate 100%)
: 40 % (25.6 % hydrazine pure)
: Liquid
: Not applicable.
: Exposure frequency(d/a) : 230
Exposure duration per day:
PROC01: 8 hours
PROC08b, PROC09≤ 1 hours
Sampling: ≤ 0.25
: Respiratory volume (m³/d): 10 (light activity)
: Indoor setting
Outdoor setting
: Process fully enclosed.
Product is handled under closed conditions.
: Sample via a closed loop or other system to avoid exposure.
Use of closed transfers of liquids from storage to production
equipment (e.g. metered piped or pumped additions).
Use vapour recovery system.
Clear transfer lines prior to de-coupling.
Provide extract ventilation to points where emissions occur.
25/42
HYDRAZINE HYDRATE 80%
Organisational measures to
prevent/limit releases,
dispersion and exposure
Conditions and measures related to personal protection and hygiene
Personal protection
hydrazine. Use as reducing agent to
remove nitrosyl kations contained in
sulphuric acid (Industrial)
: Only properly trained and authorised personnel shall handle the
substance.
Substance-handling procedures shall be well documented and
supervised.
Ensure intensive management supervision controls.
Drain down systems and clear transfer lines prior to breaking
containment.
Clean/flush equipment, where possible, prior to maintenance.
Clear up spills immediately.
Regularly inspect, test and maintain all control measures.
Consider the need for risk based health surveillance.
Organize regular exposure monitoring to check that exposure
levels of operators stay beyond the exposure limits (exposure
limits: see Section 8)
: Wear protective clothing as described in section 8.
Wear gloves as described in section 8.
Wear safety goggles as described in section 8.

Sampling:
If the efficiency of the local exhaust ventilation cannot be ensured
or the installation of a LEV is not possible, wear respiratory
protective equipment (efficiency %): 95 %

During (Dis)connection steps:

Wear respiratory protection as described in section 8.

Section 3 - Exposure estimation and reference to its source

Website: : Not available.

Exposure estimation and reference to its source - Environment: -ERC06b

Exposure assessment : Qualitative Assessment

(environment):
Exposure estimation : Applying the stipulated Risk Management Measures and
operational conditions, hydrazine will be highly contained.
Based on these measures, no risk for workers is concluded.

Exposure estimation and reference to its source - Workers: -PROC01, PROC08b, PROC09

Exposure assessment : Qualitative Assessment.

(human):
Exposure estimation : Applying the stipulated Risk Management Measures and
operational conditions, hydrazine will be highly contained.
Based on these measures, no risk for workers is concluded.

Section 4 - Guidance to DU to evaluate whether he works inside the

boundaries set by the ES
Environment : Under the above listed conditions the process is deemed safe.
Other conditions should only be considered when measurements or
suitable calculations show that the RCR is < 1.
Health : Under the above listed conditions the process is deemed safe.
Other conditions should only be considered when measurements or
suitable calculations show that the RCR is < 1.

26/42
HYDRAZINE HYDRATE 80% hydrazine. Use as reducing agent to
remove nitrosyl kations contained in
sulphuric acid (Industrial)

Additional good practice advice beyond the REACH CSA

Environment : Not applicable.
Health : Not applicable.

27/42
Annex to the extended Safety Data Sheet
(eSDS)
Identification of the substance or mixture
Product definition
Code
Product name
Section 1 - Title
Short title/List of use
descriptors
Name of contributing
environmental scenario
and corresponding ERC
List of names of
contributing worker
scenarios and
corresponding PROCs
Additional information
Section 2 - Exposure controls
Contributing scenario controlling environmental exposure for : -ERC06b
Product characteristics
Concentration of substance
in mixture or article
Amounts used
Frequency and duration of
use
Other given operational
conditions affecting
environmental exposure
Technical conditions and
measures at process level
(source) to prevent release
: Mixture
: 05528771
: HYDRAZINE HYDRATE 80%
: Identified use name: Hydrazine.Use as stabilising reagent in
aromatic amines to be further used in synthesis of dyestuffs
(Industrial)
Process Category: PROC01, PROC08b, PROC09
Substance supplied to that use in form of: As such
Sector of end use: SU03, SU08, SU09
Subsequent service life relevant for that use: No.
Environmental Release Category: ERC06b
Market sector by type of chemical product: PC0, PC0
: -ERC06b
: -PROC01, PROC08b, PROC09
: PROCs and ERCs for communication purpose only. Risk
assessment based on Expert judgement.
: Liquid.
Vapour pressure: 19.2 2hPa (25 °C) (hydrazine hydrate 100%)
: ≤ 64 %(referring to pure hydrazine)
: Annual site tonnage (t/a): Not applicable.
Risk from exposure via the aquatic environment is driven by effluent
discharge to freshwater. Emissions are limited by the daily waste
water independent of the tonnage applied.
: Continuous release (d/a) : 300
: Percentage release to waste water: 0
Based on the applied operational conditions, emission in the air and
soil compartment are negligible.
: The generation of waste should be avoided or minimised wherever
possible.
28/42
HYDRAZINE HYDRATE 80%
Technical on-site conditions
and measures to reduce or
limit discharges, air
emissions and releases to
soil
Organisational measures to
prevent/limit release from
site
Conditions and measures
related to municipal sewage
treatment plant
Conditions and measures
related to external treatment
of waste for disposal
Conditions and measures
related to external recovery
of waste
Contributing scenario controlling worker exposure for : -PROC01, PROC08b, PROC09
Product characteristics
Concentration of
substance in mixture or
article
Physical state
Amounts used
Frequency and duration of
use
Human factors not
influenced by risk
management
Other given operational
conditions affecting
workers exposure
Technical conditions and
measures at process level
(source) to prevent release
Technical conditions and
measures to control
dispersion from source
towards the worker
hydrazine. Use as stabilising reagent in
aromatic amines to be further used in
synthesis of dyestuffs (Industrial)
: Waste air should be scrubbed or filtered. (efficiency %): > 95
Floor should be impervious and resistant to liquid.
: Only properly trained and authorised personnel shall handle the
substance.
Substance-handling procedures shall be well documented and
supervised.
: Not applicable as there is no release to wastewater.
: General information on waste disposal see section 13.
: No special measures required.
: Vapour pressure: 19.2 hPa (25 °C) (hydrazine hydrate 100%)
: ≤ 64 %(referring to pure hydrazine)
: Liquid
: Not applicable.
: Exposure frequency(d/a) : 230
Exposure duration per day:
PROC01 : 8 hours
PROC08b, PROC09 :≤ 1 hours
Sampling: ≤ 0.25
: Respiratory volume (m³/d): 10(light activity)
: Indoor setting
Outdoor setting
: Product is handled under closed conditions.
: Sample via a closed loop or other system to avoid exposure.
Use of closed transfers of liquids from storage to production
equipment (e.g. metered piped or pumped additions).
Use vapour recovery system.
Clear transfer lines prior to de-coupling.
Provide extract ventilation to points where emissions occur.
29/42
HYDRAZINE HYDRATE 80%
Organisational measures to
prevent/limit releases,
dispersion and exposure
hydrazine. Use as stabilising reagent in
aromatic amines to be further used in
synthesis of dyestuffs (Industrial)
: Only properly trained and authorised personnel shall handle the
substance.
Substance-handling procedures shall be well documented and
supervised.

Ensure intensive management supervision controls.

Drain down systems and clear transfer lines prior to breaking

containment.

Clean/flush equipment, where possible, prior to maintenance.

Clear up spills immediately.

Regularly inspect, test and maintain all control measures.

Consider the need for risk based health surveillance.

Organize regular exposure monitoring to check that exposure

levels of operators stay beyond the exposure limits (exposure
limits: see Section 8)
Conditions and measures related to personal protection and hygiene
Personal protection : Wear protective clothing as described in section 8.
Wear gloves as described in section 8.
Wear safety goggles as described in section 8.

Sampling:
If the efficiency of the local exhaust ventilation cannot be ensured
or the installation of a LEV is not possible, wear respiratory
protective equipment (efficiency %): 95

During (Dis)connection steps:

Wear respiratory protection as described in section 8.

Section 3 - Exposure estimation and reference to its source

Website: : Not available.

Exposure estimation and reference to its source - Environment: -ERC06b

Exposure assessment : Qualitative Assessment

(environment):
Exposure estimation : Applying the stipulated Risk Management Measures and
operational conditions, hydrazine will be highly contained.
Based on these measures, no risk for workers is concluded.

Exposure estimation and reference to its source - Workers: -PROC01, PROC08b, PROC09

Exposure assessment : Qualitative Assessment.

(human):
Exposure estimation : Applying the stipulated Risk Management Measures and
operational conditions, hydrazine will be highly contained.
Based on these measures, no risk for workers is concluded.

Section 4 - Guidance to DU to evaluate whether he works inside the

boundaries set by the ES
30/42
HYDRAZINE HYDRATE 80% hydrazine. Use as stabilising reagent in
aromatic amines to be further used in
synthesis of dyestuffs (Industrial)

Environment : Under the above listed conditions the process is deemed safe.
Other conditions should only be considered when measurements or
suitable calculations show that the RCR is < 1.
Health : Under the above listed conditions the process is deemed safe.
Other conditions should only be considered when measurements or
suitable calculations show that the RCR is < 1.

Additional good practice advice beyond the REACH CSA

Environment : Not applicable.
Health : Not applicable.

31/42
Annex to the extended Safety Data Sheet
(eSDS)
Identification of the substance or mixture
Product definition
Code
Product name
Section 1 - Title
Short title/List of use
descriptors
Name of contributing
environmental scenario
and corresponding ERC
List of names of
contributing worker
scenarios and
corresponding PROCs
Additional information
Section 2 - Exposure controls
Contributing scenario controlling environmental exposure for : -ERC06a, ERC06b
Product characteristics
Concentration of substance
in mixture or article
Amounts used
Frequency and duration of
use
Environment factors not
influenced by risk
management
Other given operational
conditions affecting
environmental exposure
Technical on-site conditions
and measures to reduce or
limit discharges, air
emissions and releases to
soil
: Mixture
: 05528771
: HYDRAZINE HYDRATE 80%
: Identified use name: Hydrazine. Use as a laboratory chemical.
(Industrial)
Process Category: PROC15
Substance supplied to that use in form of: As such
Sector of end use: SU09, SU08, SU10, SU12, SU14, SU23, SU24
Subsequent service life relevant for that use: No.
Environmental Release Category: ERC06a, ERC06b
Market sector by type of chemical product: PC21
: -ERC06a, ERC06b
: -PROC15
: PROCs and ERCs for communication purpose only. Risk
assessment based on Expert judgement.
: Liquid.
Vapour pressure: 19.2 hPa (25 °C) (hydrazine hydrate 100%)
: ≤ 64 % (referring to pure hydrazine)
: ≤ 0.5 L/day
: Not applicable.
: Local freshwater dilution factor 10
If receiving surface water flow is (m³/d): 18 000
Local marine water dilution factor 100
: Avoid release to the environment.
In case of incidental aqueous waste, the water has to pre-treated to
reduce hydrazine concentrations prior to emission.
Based on the applied operational conditions, emission in the air and
soil compartment are negligible.
: The waste water has to be directed to a dedicated sewage
treatment plant or treated by other suitable techniques.
Waste air should be scrubbed or filtered.(efficiency %): > 95
Floor should be impervious and resistant to liquid.
32/42
HYDRAZINE HYDRATE 80%
Organisational measures to
prevent/limit release from
site
Conditions and measures
related to municipal sewage
treatment plant
Conditions and measures
related to external treatment
of waste for disposal
Conditions and measures
related to external recovery
of waste
Contributing scenario controlling worker exposure for : -PROC15
Product characteristics
Concentration of
substance in mixture or
article
Physical state
Amounts used
Frequency and duration of
use
Human factors not
influenced by risk
management
Other given operational
conditions affecting
workers exposure
Technical conditions and
measures to control
dispersion from source
towards the worker
Organisational measures to
prevent/limit releases,
dispersion and exposure
Organize regular exposure monitoring to check that exposure
levels of operators stay beyond the exposure limits (exposure
limits: see Section 8)
Conditions and measures related to personal protection and hygiene
Personal protection
hydrazine. Laboratory reagent (Industrial)
: Only properly trained and authorised personnel shall handle the
substance.
Substance-handling procedures shall be well documented and
supervised.
: Size of sewage treatment plant (m³/d): 2 000
(efficiency %): 45
: General information on waste disposal see section 13.
: No special measures required.
: Vapour pressure: 19.2 hPa (25 °C) (hydrazine hydrate 100%)
: ≤ 64 % (referring to pure hydrazine)
: Liquid
: 0.5 L/day
: Covers exposure up to: 8 hours
Exposure frequency (d/a) : 230
: Respiratory volume (m³/d): 10 (light activity)
: Indoor setting
: Handle in a fume cupboard or under extract ventilation.
: Only properly trained and authorised personnel shall handle the
substance.
Substance-handling procedures shall be well documented and
supervised.
Ensure intensive management supervision controls.
Clear up spills immediately.
Regularly inspect, test and maintain all control measures.
Consider the need for risk based health surveillance.
: Wear protective clothing as described in section 8.
Wear gloves as described in section 8. (efficiency %): 90
Wear safety goggles as described in section 8.
33/42
HYDRAZINE HYDRATE 80% hydrazine. Laboratory reagent (Industrial)

Section 3 - Exposure estimation and reference to its source

Website: : Not available.

Exposure estimation and reference to its source - Environment: -ERC06a, ERC06b

Exposure assessment : Qualitative Assessment

(environment):
Exposure estimation : Applying the stipulated Risk Management Measures and
operational conditions, hydrazine will be highly contained.
Based on these measures, no risk for workers is concluded.

Exposure estimation and reference to its source - Workers: -PROC15

Exposure assessment : Qualitative Assessment.

(human):
Exposure estimation : Applying the stipulated Risk Management Measures and
operational conditions, hydrazine will be highly contained.
Based on these measures, no risk for workers is concluded.

Section 4 - Guidance to DU to evaluate whether he works inside the

boundaries set by the ES
Environment : Under the above listed conditions the process is deemed safe.
Other conditions should only be considered when measurements or
suitable calculations show that the RCR is < 1.
Health : Under the above listed conditions the process is deemed safe.
Other conditions should only be considered when measurements or
suitable calculations show that the RCR is < 1.

Additional good practice advice beyond the REACH CSA

Environment : Not applicable.
Health : Not applicable.

34/42
Annex to the extended Safety Data Sheet
(eSDS)
Identification of the substance or mixture
Product definition
Code
Product name
Section 1 - Title
Short title/List of use
descriptors
Name of contributing
environmental scenario
and corresponding ERC
List of names of
contributing worker
scenarios and
corresponding PROCs
Additional information
Section 2 - Exposure controls
Contributing scenario controlling environmental exposure for : -ERC02
Product characteristics
Concentration of substance
in mixture or article
Amounts used
Frequency and duration of
use
Environment factors not
influenced by risk
management
Other given operational
conditions affecting
environmental exposure
Technical conditions and
measures at process level
(source) to prevent release
: Mixture
: 05528771
: HYDRAZINE HYDRATE 80%
: Identified use name: Hydrazine .Distribution, formulation and (re)
packing of substances and mixtures (Industrial)
Process Category: PROC01, PROC03, PROC08b, PROC09
Substance supplied to that use in form of: In a mixture
Sector of end use: SU03
Subsequent service life relevant for that use: No.
Environmental Release Category: ERC02
: -ERC02
: -PROC01, PROC03, PROC08b, PROC09
: ERC only for communication purposes. Risk assessment based on
Expert judgement
: Liquid.
Vapour pressure: 19.2 hPa (25 °C) (hydrazine hydrate 100%)
: ≤ 64 %. (referring to pure hydrazine)
: Annual site tonnage (t/a): Not applicable.
Risk from exposure via the aquatic environment is driven by effluent
discharge to freshwater. Emissions are limited by the daily waste
water independent of the tonnage applied.
: Continuous release (d/a) : 300
: Local freshwater dilution factor: 10
If receiving surface water flow is (m³/d): 18 000
Local marine water dilution factor: 100
: The substance shall be rigorously contained by technical means
during handling and use.
: Maximum load to waste water (kg/d): ≤ 0.02 (referring to pure
hydrazine)
Deviating from the STP size and water body size daily emissions
have to be adjusted. Based on the applied operational conditions,
emission in the air and soil compartment are negligible.
35/42
HYDRAZINE HYDRATE 80%
Technical on-site conditions
and measures to reduce or
limit discharges, air
emissions and releases to
soil
Organisational measures to
prevent/limit release from
site
Conditions and measures
related to municipal sewage
treatment plant
Conditions and measures
related to external treatment
of waste for disposal
Conditions and measures
related to external recovery
of waste
Contributing scenario controlling worker exposure for : -PROC01, PROC03, PROC08b,
PROC09
Product characteristics
Concentration of
substance in mixture or
article
Physical state
Amounts used
Frequency and duration of
use
Other given operational
conditions affecting
workers exposure
Technical conditions and
measures at process level
(source) to prevent release
Technical conditions and
measures to control
dispersion from source
towards the worker
hydrazine. Distribution, formulation and (re)
packing of substances and mixtures
(Industrial)
: The waste water has to be directed to a dedicated sewage
treatment plant or treated by other suitable techniques.
Waste air has to be cleaned by a waste gas scrubber or or a
combustion unit or treated by other suitable techniques. (efficiency
%): > 95
Floor should be impervious and resistant to liquid.
: Only properly trained and authorised personnel shall handle the
substance.
Substance-handling procedures shall be well documented and
supervised.
: Size of sewage treatment plant (m³/d): 2 000(Removal rate %): ≥ 45
Sewage sludge has not to be disposed on agricultural soil.
: General information on waste disposal see section 13.
: No special measures required.
: Vapour pressure: 19.2 hPa. (25 °C) (hydrazine hydrate 100 %.)
: ≤ 64 %. (referring to pure hydrazine)
: Liquid.
: Not applicable.
: Exposure frequency (d/a) : 230.
Exposure duration (h/d):
PROC01, PROC03: 8 h (full shift).
PROC08b, PROC09 :≤1.
Sampling : ≤ 0.25.
: Indoor setting / Outdoor setting
: The substance shall be contained by technical means during
handling and use.
: Local exhaust ventilation required. (efficiency %): 90
Sample via a closed loop or other system to avoid exposure.
Use of closed transfers of liquids from storage to production
equipment (e.g. metered piped or pumped additions).
Use vapour recovery system.
Clear transfer lines prior to de-coupling.
Provide extract ventilation to points where emissions occur.
36/42
HYDRAZINE HYDRATE 80%
Organisational measures to
prevent/limit releases,
dispersion and exposure
hydrazine. Distribution, formulation and (re)
packing of substances and mixtures
(Industrial)
: Only properly trained and authorised personnel shall handle the
substance.
Substance-handling procedures shall be well documented and
supervised.
Ensure intensive management supervision controls.
Drain down systems and clear transfer lines prior to breaking
containment.
Clean/flush equipment, where possible, prior to maintenance.
Clear up spills immediately.
Regularly inspect, test and maintain all control measures.
Consider the need for risk based health surveillance.

Organize regular exposure monitoring to check that exposure

levels of operators stay beyond the exposure limits (exposure
limits: see Section 8)
Conditions and measures related to personal protection and hygiene
Personal protection : Wear protective clothing as described in section 8.
Wear gloves as described in section 8.
Wear safety goggles as described in section 8.

Sampling :
If the efficiency of the local exhaust ventilation cannot be ensured
or the installation of a LEV is not possible, wear respiratory
protective equipment (efficiency %): 95

During (Dis)connection steps:

Wear respiratory protection as described in section 8. (efficiency
%): 95

(Dis)Connection of non-closed (?) dosing units:

Wear coverall according to section 8.

Section 3 - Exposure estimation and reference to its source

Website: : Not available.

Exposure estimation and reference to its source - Environment: -ERC02

Exposure assessment : Calculation method

(environment):
Exposure estimation : The calculated individual exposure figures are below the PNECs
(RCR ratios < 1).

Exposure estimation and reference to its source - Workers: -PROC01, PROC03, PROC08b,
PROC09

Exposure assessment : Qualitative assessment

(human):
Exposure estimation : Applying the stipulated Risk Management Measures and
operational conditions, hydrazine will be highly contained.
Based on these measures, no risk for workers is concluded.

Section 4 - Guidance to DU to evaluate whether he works inside the

boundaries set by the ES

37/42
HYDRAZINE HYDRATE 80% hydrazine. Distribution, formulation and (re)
packing of substances and mixtures
(Industrial)

Environment : Under the above listed conditions the process is deemed safe.
Other conditions should only be considered when measurements or
suitable calculations show that the RCR is < 1.
Health : Under the above listed conditions the process is deemed safe.
Other conditions should only be considered when measurements or
suitable calculations show that the RCR is < 1.

Additional good practice advice beyond the REACH CSA

Environment : Not applicable.
Health : Not applicable.

38/42
Annex to the extended Safety Data Sheet
(eSDS)
Identification of the substance or mixture
Product definition : Mixture
Code : 05528771
Product name : HYDRAZINE HYDRATE 80%

Section 1 - Title
Short title/List of use : Identified use name: Hydrazine .Use as reducing agent for metal-
descriptors based chemicals in closed industrial systems under controlled
conditions (Industrial)
Process Category: PROC01, PROC03, PROC08b
Substance supplied to that use in form of: In a mixture
Sector of end use: SU03, SU14
Subsequent service life relevant for that use: No.
Environmental Release Category: ERC04, ERC06b
Market sector by type of chemical product: PC0
Name of contributing : -ERC04, ERC06b
environmental scenario
and corresponding ERC
List of names of : -PROC01, PROC03, PROC08b
contributing worker
scenarios and
corresponding PROCs

Additional information : ERC only for communication purposes. Risk assessment based on
Expert judgement

Section 2 - Exposure controls

Contributing scenario controlling environmental exposure for : -ERC04, ERC06b

Product characteristics : Liquid.

Vapour pressure: 19.2 hPa (25 °C) (hydrazine hydrate 100%)
Concentration of substance : ≤ 64 %. (referring to pure hydrazine)
in mixture or article
Amounts used : Annual site tonnage (t/a): Not applicable.
Risk from exposure via the aquatic environment is driven by effluent
discharge to freshwater. Emissions are limited by the daily waste
water independent of the tonnage applied.
Frequency and duration of : Continuous release (d/a) : 300
use
Environment factors not : Local freshwater dilution factor 10
influenced by risk If receiving surface water flow is (m³/d): 18 000
management Local marine water dilution factor 100
Other given operational : The substance shall be rigorously contained by technical means
conditions affecting during handling and use.
environmental exposure

39/42
HYDRAZINE HYDRATE 80%
Technical conditions and
measures at process level
(source) to prevent release
Technical on-site conditions
and measures to reduce or
limit discharges, air
emissions and releases to
soil
Organisational measures to
prevent/limit release from
site
Conditions and measures
related to municipal sewage
treatment plant
Conditions and measures
related to external treatment
of waste for disposal
Conditions and measures
related to external recovery
of waste
Contributing scenario controlling worker exposure for : -PROC01, PROC03, PROC08b
Product characteristics
Concentration of
substance in mixture or
article
Physical state
Amounts used
Frequency and duration of
use
Other given operational
conditions affecting
workers exposure
Technical conditions and
measures at process level
(source) to prevent release
hydrazine. Use as reducing agent for metal-
based chemicals in closed industrial
systems under controlled conditions
(Industrial)
: Maximum load to waste water (kg/d): ≤ 0.02(referring to pure
hydrazine)
Deviating from the STP size and water body size daily emissions
have to be adjusted. Based on the applied operational conditions,
emission in the air and soil compartment are negligible.
: The waste water has to be directed to a dedicated sewage
treatment plant or treated by other suitable techniques.
Waste air has to be cleaned by a waste gas scrubber or or a
combustion unit or treated by other suitable techniques. (efficiency
%): > 95
Floor should be impervious and resistant to liquid.
: Only properly trained and authorised personnel shall handle the
substance.
Substance-handling procedures shall be well documented and
supervised.
: Size of sewage treatment plant (m³/d): 2 000(Removal rate %): ≥ 45
Sewage sludge has not to be disposed on agricultural soil.
: General information on waste disposal see section 13.
: No special measures required.
: Vapour pressure: 19 . 2 hPa (25 °C) (hydrazine hydrate 100%)
: ≤ 64 % (referring to pure hydrazine)
: Liquid.
: Not applicable.
: Exposure frequency 230 days per year
Exposure duration (h/d):
PROC01, PROC03 :8 h (full shift).
PROC08b: ≤ 1
Sampling : ≤ 0.25
: Indoor setting/Outdoor setting
: The substance shall be contained by technical means during
handling and use.
40/42
HYDRAZINE HYDRATE 80%
Technical conditions and
measures to control
dispersion from source
towards the worker
Organisational measures to
prevent/limit releases,
dispersion and exposure
Conditions and measures related to personal protection and hygiene
Personal protection
Section 3 - Exposure estimation and reference to its source
Website:
Exposure estimation and reference to its source - Environment: -ERC04, ERC06b
Exposure assessment
(environment):
Exposure estimation
hydrazine. Use as reducing agent for metal-
based chemicals in closed industrial
systems under controlled conditions
(Industrial)
: Local exhaust ventilation required.
Ventilation rate (h-1): 3-5
Ensure samples are obtained under containment or extract
ventilation.
Sample via a closed loop or other system to avoid exposure.
Use of closed transfers of liquids from storage to production
equipment (e.g. metered piped or pumped additions).
Use vapour recovery system.
Clear transfer lines prior to de-coupling.
Provide extract ventilation to points where emissions occur.
: Only properly trained and authorised personnel shall handle the
substance.
Substance-handling procedures shall be well documented and
supervised.
Ensure intensive management supervision controls.
Drain down systems and clear transfer lines prior to breaking
containment.
Clean/flush equipment, where possible, prior to maintenance.
Clear up spills immediately.
Regularly inspect, test and maintain all control measures.
Consider the need for risk based health surveillance.
Organize regular exposure monitoring to check that exposure
levels of operators stay beyond the exposure limits (exposure
limits: see Section 8)
: Wear protective clothing as described in section 8.
Wear gloves as described in section 8.
Wear safety goggles as described in section 8.
Sampling :
If the efficiency of the local exhaust ventilation cannot be ensured
or the installation of a LEV is not possible, wear respiratory
protective equipment (efficiency %): 95
During (Dis)connection steps:
Wear respiratory protection as described in section 8. (efficiency
%): 95
: Not available.
: Calculation method
: The calculated individual exposure figures are below the PNECs
(RCR ratios < 1).
41/42
HYDRAZINE HYDRATE 80% hydrazine. Use as reducing agent for metal-
based chemicals in closed industrial
systems under controlled conditions
(Industrial)
Exposure estimation and reference to its source - Workers: -PROC01, PROC03, PROC08b

Exposure assessment : Qualitative assessment

(human):
Exposure estimation : Applying the stipulated Risk Management Measures and
operational conditions, hydrazine will be highly contained.
Based on these measures, no risk for workers is concluded.

Section 4 - Guidance to DU to evaluate whether he works inside the

boundaries set by the ES
Environment : Under the above listed conditions the process is deemed safe.
Other conditions should only be considered when measurements or
suitable calculations show that the RCR is < 1.
Health : Under the above listed conditions the process is deemed safe.
Other conditions should only be considered when measurements or
suitable calculations show that the RCR is < 1.

Additional good practice advice beyond the REACH CSA

Environment : Not applicable.
Health : Not applicable.

42/42