SDS of UNIKOTE NSX692 A Liquid 1/9

SAFETY DATA SHEET

1. Chemical Product & Company Identification

Name of Manufacturer/Supplier Meiden Chemical Co. Ltd.
Address 2-8-1 Osaki Shinagawa-Ku Tokyo 141-8565 Japan
Name of Section Sales Department
Tel 81-3-6420-8750 Fax 81-3-6420-8729
Prepared By Technical Department
Tel 81-467-78-3212 Fax 81-467-77-7938
Date of Issue/Revision 7. Jan, 2016

2. Chemical Product Name Unikote NSX692 A Liquid

3. Hazards Identification (GHS Classification)

Physical Hazards Flammable liquid Category 2
Hazardous to health
Acute toxicity (Dermal) Category 4
(Inhalation) Category 3
Skin corrosion/irritation Category 2
Serious eye damage/ eye irritation Category 2B
Skin sensitization Category 1
Carcinogenicity Category 2
Reproductive toxicity Category 1A
Specific target organ toxicity-Single exposure
Category 1(Central nervous system)
Category 2(Kidney)
Category 3(Respiratory tract irritation, Anesthetic
action)
Specific target organ toxicity-Repeated exposure
Category 1(Central nervous system, Peripheral
nervous system, Kidney)
Category 2(Hematopoietic system)
Hazardous to the aquatic environment
Category 1(Acute)
Category 1(Chronic)

At this time "classification excluded", or "cannot be classified" other than the above
items, is "classified".

GHS Label element

Symbol or pictogram

Signal words Danger

Hazard statements
General Highly flammable liquid and vapor.
Harmful in contact with skin.
Toxic if inhaled.
Causes skin irritation.
Causes eye irritation.
May cause an allergic skin reaction.
 SDS of UNIKOTE NSX692 A Liquid 2/9
Suspected of causing cancer.
May damage fertility or the unborn child.
Causes damage to central nervous system.
May cause damage to kidney.
May cause respiratory irritation.
May cause drowsiness or dizziness.
Causes damage to central nervous system, peripheral
nervous system, kidney through prolonged or repeated
exposure.
May causes damage to hematopoietic system through
prolonged or repeated exposure.
Very toxic to aquatic life.
Very toxic to aquatic life with long lasting effects.
Prevention See the SDS before use.
Obtain special instructions before use.
Do not handle until all safety precautions have been read
and understood.
Keep away from heat, hot surfaces, sparks, open flames
and other ignition sources. No smoking.
Keep container tightly closed.
Ground and bond container and receiving equipment.
Use explosion-proof electrical/ ventilating/ lighting/ equipment.
Use non-sparking tools.
Take action to prevent static discharges.
Wear protective gloves/ protective clothing/ eye protection/
face protection.
Do not breathe dust/ fume/ gas/ mist/ vapors/ spray.
Use only outdoors or in a well-ventilated area.
Wash hands thoroughly after handling.
Contaminated work clothing should not be allowed out of
the workplace.
Do not eat, drink or smoke when using this product.
Avoid release to the environment.
Response If on skin (or hair): Take off immediately all contaminated
clothing. Rinse skin with water [or shower].
In case of fire: Use the appropriate fire extinguishing agent in
order to extinguish.
If on skin: Wash with plenty of water.
Get medical advice/ attention if you feel unwell.
Take off contaminated clothing and wash it before reuse.
If inhaled: Remove person to fresh air and keep comfortable
for breathing.
If in eyes: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue
rinsing.
If eye irritation persists: Get medical advice/ attention.
If skin irritation or rash occurs: Get medical advice/ attention.
If exposed or concerned: Get medical advice/ attention.
Collect spillage.
Storage Store in a well-ventilated place. Keep cool.
Store locked up.
Disposal Dispose of contents / container in accordance with the rules
 SDS of UNIKOTE NSX692 A Liquid 3/9
of the local / regional / national / international
4. Composition / Information on Ingredients
Ingredients and Composition
Composition Cas Registry UN UN Packing Marine
Ingredient
(%) Number Class Number group Pollutant
BPA type solid
18.5 25068-38-6
epoxy resin
Toluene 9.9 108-88-3
Methyl isobutyl
5.0 108-10-1
ketone
Methyl ethyl
7.0 78-93-3
ketone Class3 1263 II Pollutant
Acetone 6.5 67-64-1
Xylene 3.1 1330-20-7
Ethyl benzene 3.1 100-41-4
Silica 1.5 7631-86-9
Carbon black 0.2 1333-86-4
Fillers, etc. 40~50 Registered

5. First-Aid Measures
Inhalations Remove victim to fresh air and keep at rest in a position comfortable
for breathing.
If not breathing, if breathing is irregular or if respiratory arrest
occurs, provide artificial respiration or oxygen by trained personnel.
If unconscious, place in recovery position and get medical attention
immediately.
Maintain an open airway.
Loosen tight clothing such as a collar, tie, belt or waistband.
Skin Contact Flush contaminated skin with plenty of water.
Remove contaminated clothing and shoes.
Continue to rinse for at least 10 minutes.
Eye Contact Get medical attention immediately.
Immediately flush eyes with plenty of water, occasionally lifting the
upper and lower eyelids.
Continue to rinse for at least 15 minutes.
Ingestion Wash out mouth with water.
Never give anything by mouth to an unconscious person.

6. Fire-Fighting Measures
Extinguishing Media
Carbon dioxide, foam, powder, dry sand is valid.
The initial fire, extinguish with dry sand, powder, carbon dioxide, etc.
Large-scale fire, it is effective method of using the foam fire
extinguishing agent and the like to shut off the air.
Extinguishing agents which must not be used
Use of the rod-like water is a danger there is a possibility to
expand the fire.
Specific Hazards With Regard To Fire-Fighting Measures.
When in contact with the hot metal surface and the like, there can
occur the combustion or explosion by generated steam.
Special firefighting methods
 SDS of UNIKOTE NSX692 A Liquid 4/9
The cool by watering around the facilities.
To prohibit the intrusiveness of other parties around the fire place.
Protection of the person making the fire fighting
Firefighting work was carried out from the windward, to wear the
appropriate protective equipment (self-contained breathing apparatus,
fire protection clothing, disaster prevention, etc.)

7. Accidental Release Measures

Notes on the human body
Retract the leeward of people.
It kept away people from the leakage location.
Protective equipment and emergency procedures
To prohibit the intrusiveness of other parties in the rope, etc. in
the vicinity of spilled location.
During the work, be sure to wear protective equipment, to perform
the work from windward.
Environmental precautions
We get rid of the ones that could be an ignition source in the
vicinity as soon as possible.
Leaking liquid is to prevent the outflow in sandbags, to be careful
so as not to flow into the river.
If you spill on the sea, it is absorbed in the absorber.
In the case of a large amount, to be recovered by preventing the
diffusion in the oil fence.
It will also contact the Coast Guard.
Removal If the leakage amount is a small amount, it is absorbed waste
cloth, sand or the like, and recovered in the empty container.
If the leakage amount is large amount, it is possible to prevent
the outflow in the sandbags, etc., will be collected in the empty
container.
In the recovery work, to use the safe shovel that does not
generate a spark.

8. Handling and Storage

Handling
Technical measures
In the handling place, and that it does not cause fire, static
electricity.
To prevent static electricity, work clothes and safety shoes use a
conductive.
To prevent the divergence of the leakage and vapor of liquid.
Set up a local exhaust ventilation in places where steam is
generated.
When there is a risk of contact or inhalation, wear protective
equipment.
It does not give a shock or by inverting the container.
Precautions Use the explosion-proof ventilation equipment when handling
indoors, to perform ventilation
Safe handling precautions
Take care not to contact with the oxidizing agent.
Storage
Technical measures
 SDS of UNIKOTE NSX692 A Liquid 5/9
To use electrical appliances explosion-proof structure in the storage
location.
Instrumentation to perform the ground.
Avoid the storage in the strong oxidizing materials other incompatible
materials in the same location.
Storage conditions
And store it in a ventilated cool, dark place, so that the temperature
doesn't rise.
During storage, it does the display of dangerous goods.
Once a container opened the stopper, that you always be sealed.
Avoid heat, sparks, flames and static electricity accumulation.

9. Exposure Control / Personal Protection

Control Parameters
ACGIH
TLV-TWA TLV-STEL
Toluene 20ppm -
Methyl isobutyl ketone 20ppm 75ppm
Methyl ethyl ketone 200ppm -
Acetone 250ppm -
Xylene 100ppm 150ppm
Ethyl benzene 20ppm -

Engineering Measures
Seal the source of steam. Or, install a Local exhaust ventilation.
To use electrical appliances explosion-proof structure in the storage location.
By providing a safety shower, hand wash, face wash equipment near the
handling place, to display its location.
Protective equipment
As appropriate, if necessary, to wear the following protective equipment.
Organic gas for the gas mask, oxygen respirator, supplied-air respirator, air
respirator.
Safety glasses, impervious protective gloves, protective boots, protective
clothing.

10. Physical and Chemical Properties

Appearance Black viscous liquid
Melting point -95°C (Toluene), -84°C (Methyl isobutyl ketone),
-86°C (Methyl ethyl ketone)
Boiling point 111°C (Toluene), 80°C(Methyl isobutyl ketone),
56°C (Acetone)
Flash point 5°C (Toluene), -9°C(Methyl ethyl ketone),
-20°C(Acetone)
Explosive range 1.3~7.0% (Toluene), 2.1~13.0% (Acetone)
Vapor pressure (20°C) 2.9kPa (Toluene), 10.5kPa (Methyl ethyl ketone)
24.7kPa (Acetone)
Vapor density 3.2 (Toluene), 2.41(Methyl ethyl ketone)
Specific gravity (25°C) 1.00
Ignition point 480°C (Toluene), 465°C (Methyl isobutyl ketone)
>432°C (Xylene)
 SDS of UNIKOTE NSX692 A Liquid 6/9
11. Stability and Reactivity
Chemical stability It is stable under normal handling conditions.
Possibility of hazardous reactions There is a risk that reacts on contact with
oxidizing substances.
Conditions to avoid Heating or contact with contraindicated products.
The dangerous substances that should not be mixed
Oxidizing substance.
Hazardous decomposition products
During combustion, smoke and carbon monoxide
is generated.

12. Toxicological Information

There is no relevant information for NSX692 A Liquid.
Toxicological information of acetone which is one of materials for NSX692
A Liquid.
Acute Toxicity (Oral) LD50: 5,800mg/kg (Rat)
(Inhalation) LC50: >32,1000ppm (Rat)
(Dermal) LD50: >5,000mg/kg (Rabbit)
Corrosion / Irritation Skin: Non-irritant (Rabbit)
Serious eye damage/ eye irritation
Severe irritation (Rabbit)
Germ cell mutagenicity In vivo mutagenicity test: Negative.
Carcinogenicity ACGIH: A4
Specific target organ toxicity-Single exposure
The anesthetic effect and respiratory tract irritation are
considered
Specific target organ toxicity-Repeated exposure
Impact on the blood system can be considered.

Toxicological information of toluene which is one of materials for NSX692

A Liquid.
Acute Toxicity (Oral) LD50: 636mg/kg (Rat)
(Inhalation) LC50: 49g/m3/4H (Rat), LC50: 400ppm/24h (Mouse)
(Dermal) LD50: 14,100µL/kg (Rabbit)
Skin corrosion/irritation 435mg; Mild, 500mg; Moderate, 20mg/24h; Moderate (Rabbit)
Serious eye damage/ eye irritation
870µg; Mild, 2mg/24H; Severe, 100mg/30S; Mild (Rabbit)
Germ cell mutagenicity In vivo mutagenicity test: Negative.
Carcinogenicity IARC: Group3, ACGIH: A4
Specific target organ toxicity-Single exposure
Effects on the central nervous system is considered.
The anesthetic effect and respiratory tract irritation are
considered
Specific target organ toxicity-Repeated exposure
Effects on the central nervous system and the kidneys
and liver can be considered.
Aspiration hazard If enters airways, there is a possibility of danger to life.

Toxicological information of methyl isobutyl ketone which is one of materials for

NSX692 A Liquid.
Acute Toxicity (Oral) LD50: 1,900mg/kg (Mouse), LD50: 2,080mg/kg (Rat)
(Inhalation) LC50: 100g/m3 (Rat), LC50: 23,300mg/m3 (Mouse)
 SDS of UNIKOTE NSX692 A Liquid 7/9
(Dermal) LD50: >3g/kg (Rabbit)
Skin corrosion/irritation 500mg/24H; Mild (Rabbit)
Serious eye damage/ eye irritation
40mg; Severe, 100µL/24H; Moderate (Rabbit)

Toxicological information of methyl ethyl ketone which is one of materials for

NSX692 A Liquid.
Acute Toxicity (Oral) LD50: 2,737mg/kg (Rat), LD50: 3,000mg/kg (Mouse)
(Inhalation) LC50: 23,500mg/m3/8H (Rat)
(Dermal) LD50: 6,480mg/kg (Rabbit)
Skin corrosion/irritation 500mg/24H; Moderate (Rabbit)
Serious eye damage/ eye irritation
80mg; Mild (Rabbit)
Skin sensitization Mouse Ear Swelling Test; Negative
Germ cell mutagenicity Micronucleus test using mammalian red blood cells; Negative
Carcinogenicity EPA: I (inadequate)
Specific target organ toxicity-Single exposure
Effects on the central nervous system is considered.
The anesthetic effect and respiratory tract irritation are
considered
Specific target organ toxicity-Repeated exposure
Causes damage to central nervous system, peripheral
nervous system.
Aspiration hazard If enters airways, there is a possibility of danger to life.

Toxicological information of Xylene which is one of materials for NSX692

A Liquid.
Acute Toxicity (Oral) LD50: 3,500mg/kg (Rat)
(Inhalation) LC50: 29.08mg/L (Rat)
(Dermal) LD50: >4,350mg/kg (Rabbit)
Skin corrosion/irritation Moderate Irritation (Rabbit)
Serious eye damage/ eye irritation
Moderate Irritation (Rabbit)
Germ cell mutagenicity Negative
Carcinogenicity IARC: Group3, ACGIH: A4
Specific target organ toxicity-Single exposure
Is considerd that the anesthetic effect of respiratory, liver,
central nervous system, kidneys.
Specific target organ toxicity-Repeated exposure
There is a danger of causing a chemical pneumonia due
to aspiration.
Aspiration hazard There is a danger of causing a chemical pneumonia due
to aspiration.

Toxicological information of ethyl benzene which is one of materials for NSX692

A Liquid.
Acute Toxicity (Oral) LD50: 3,500~4,769mg/kg (Rat)
(Inhalation) LC50: 17.2mg/L (Rat)
(Dermal) LD50: 15,400mg/kg (Rabbit)
Skin corrosion/irritation Mild irritation (Humas)
Serious eye damage/ eye irritation
Minor to mild Irritation (Rabbit)
 SDS of UNIKOTE NSX692 A Liquid 8/9
Germ cell mutagenicity Negative
Carcinogenicity IARC: Group2B, ACGIH: A3
Specific target organ toxicity-Single exposure
It is considered to have an anesthetic effect on the central
nervous system.
Specific target organ toxicity-Repeated exposure
Is considerd that effects on the respiratory and nervous
system.
Aspiration hazard There is a danger of causing a chemical pneumonia due
to aspiration.

Toxicological information of silica which is one of materials for NSX692 A Liquid.

Acute Toxicity (Oral) TDLo: 120g/kg (Rat)
(Inhalation) TDLo: 200mg/kg (Rat), TCLo: 40mg/kg (Mouse)
Mutagenicity Micronucleus: Positive (Hamster)
Carcinogenicity IARC: Group1, ACGIH: A2
Specific target organ toxicity-Single exposure
If high intake concentration in short-term exposure in
humans affects the respiratory system.
Specific target organ toxicity-Repeated exposure
Affect the respiratory system, the kidney in a human.
Note: Product is containing silica, but respirable dust is not generated. Therefore
the hazards are not applicable.
Also, management concentration and allowable concentration are omitted.

13. Ecological Information

Show the information of acetone in the component.
Ecotoxicity LC50 (96H): 580~8,120ppm (freshwater fish)
LC50 (96H): 11,000ppm (saltwater fish)
Degradability 96% (by BOD)

Show the information of toluene in the component.

Ecotoxicity LC50 (carassius auratus) 27.6mg/L (48H), 22.7mg/L(72H)
LC50 (Pink salmon) 6.19mg/L (48H)
Degradability 123% (by BOD)

Show the information of methyl isobutyl ketone in the component.

Degradability 84% (by BOD)

Show the information of methyl ethyl ketone in the component.

Ecotoxicity LC50 (Water flea) 530mg/L (48H)

Show the information of xylene in the component.

Ecotoxicity Fish toxicity LC50: 3.3mg/L (96H)
Degradability It is estimated to easily biodegraded.

Show the information of ethyl benzene in the component.

Ecotoxicity Fish toxicity LC50: 4.2mg/L (96H)
Degradability It is estimated to easily biodegraded.
 SDS of UNIKOTE NSX692 A Liquid 9/9
14. Disposal Consideration
The generation of waste should be avoided or minimised wherever possible.
Disposal of this product, solutions and any by-products should at all times comply
with the requirements of environmental protection and waste disposal legislation
and any regional local authority requirements.
Dispose of surplus and nonrecyclable products via a licensed waste disposal
contractor.
Waste should not be disposed of untreated to the sewer unless fully compliant with
the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible.
This material and its container must be disposed of in a safe way.
Care should be taken when handling emptied containers that have not been cleaned
or rinsed out.
Empty containers or liners may retain some product residues. Avoid dispersal of
spilt material and runoff and contact with soil, waterways, drains and sewers.

15. Transport Information

Follow the regulations of your country.

16. Regulatory information

Japan Control Law
Fire Service Law Class 4: Type 1 petroleum
Danger class II

16. Other Information

This SDS was prepared sincerely on the basis of the information we could
obtained, however, any warranty shall not be given regarding the data contained
and theassessment of hazards and toxicity.
Prior to use, please investigate not only the hazards and toxicity information but
also the laws and regulations of the organization, area and country where the
products are to be used, which shall be given the first priority.
The products are supposed to be used promptly after purchase in consideration of
safety.
Some new information or amendments may be added afterwards.
The stated cautions are for normal handling only.
In case of special handling, sufficient care should be taken, in addition to the
safety measures suitable for the situation.
All chemical products should be treated with the recognition of "having unknown
hazards and toxicity", which differ greatly depending on the conditions and handling
when in use and/or the conditions and duration of storage.
The products must be handled only by those who are familiar with specialized
knowledge and have experience or under the guidance of those specialists
throughout use from opening to storage and disposal.
Safe usage conditions shall be set up on each user's own responsibility.