Professional Documents
Culture Documents
HANDBOOK OF
INDUSTRIAL TEXTILES
I ,ANCASTER • BASEl.
Published in the Jl!,stem Hemisphere by
Technomic Publishing Company, Inc.
851 New Holland Avenue, Box 3535
Lancaster, Pennsylvania 17604 U.S.A .
ID 9 8 7 6 5 4 3 2
9.0 GEOTEXTILES
9.1 Geotextiles ...................................................... 297
S. Adanur
1. Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 297
2. Geotextile Materials and Manufacturing . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 297
3. Geotextile Properties and Testing . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 302
4. Geotextile Functions ............................................. 311
5. Designing with Geotextiles ......................................... 320
6. Application Examples ofGeotextiles ................................... 321
7. Geotextiles Market ............................................... 324
8. Geosynthetics .................................................. 324
9.2 References and Review Questions ...................................... 325
1. References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 325
2. Review Questions ................................................ 326
Table of Contents vii
10.0 MEDICALTEXTILES
Appendix 1: Air, Tent, and Tensile Structures-Fabric Specification Table ............... 761
Appendix 2: Awnings and Canopies-Fabric Specification Table ...................... 780
Appendix 3: Geotextile Fabric Properties . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 793
Appendix 4: Characteristics, Industrial Uses, and Manufacturers of Major
Generic Fibers and Trade Names .......................................... 812
Appendix 5: Derivation of Mathematical Equations . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 817
Appendix 6: Measurement Units ............................................ 821
Index ............................................................... 825
Foreword
Wellington Sears Company had its beginning textile industry has seen dramatic technological
in 1845 as N. Boynton & Company, an outfitter and scientific changes. Today, there is little in our
of sailing ships. By the late 1800s, a textile mill lives that is not touched by a textile product. The
had been constructed in Langdale, Alabama, and application areas of industrial textiles cover a
was selling large quantities of fabric to N. Boyn- very broad range, from deep inside the human
ton & Company. Unfortunately a fire destroyed body to outer space. Development of man-made
the mill in 1887 leaving N. Boynton & Company fibers with tailored properties opened up new
with no source of fabric. This event led to N. opportunities for the application of industrial
Boynton & Company providing needed capital textiles. Application of new chemicals increased
to rebuild the mill and become exclusive selling the performance of industrial textiles. With the
agent for the mill that had been renamed West ever advancing technology, new manufacturing
Point Manufacturing Company. N. Boynton & methods offered possibilities of producing more
Company's name was changed at the tum of the complex and sophisticated products. As a result,
century to Wellington Sears Company and the the use of industrial textiles is on the rise.
former Ship's Chandlery continued as an ex- The management of Wellington Sears Com-
clusive selling agent until 1966 when it was pany is proud to present this revised edition of
renamed the Industrial Fabrics Division of West the Handbook and is thankful for the opportunity
Point Pepperell Inc. The Wellington Sears name to do so provided by the following people:
was retired at that time only to be revived in
November of 1992 when Jupiter National, Inc.* David L. Chandler
of Rockville, Maryland, purchased the division Chairman, Johnston Industries
from West Point Pepperell Inc. A great tradition Chairman, Jupiter National, Inc.
had been reborn in the Wellington Sears Com- Chairman, Wellington Sears Company
pany.
Another great tradition of Wellington Sears Gerald B. Andrews
Company from 1934 through 1963 was the ~l President & C.O.O., Johnston Industries
lington Sears Company Handbook of Industrial
Fabrics. During these years the book was up- This new edition of the ~llington Sears
dated and republished five times. Over thirty Handbook ofIndustrial Textiles is designed to be
years have passed since the 1963 edition and the a comprehensive resource for professionals and
students in textiles and other industries that use
*Jupiter National, Inc. is a public company (symbol, JPI- textiles. It contains the latest technology. It is not
American Stock Exchange) which is majority owned by a revision but a completely new book.
Johnston Industries, Inc. (symbol, JII-New York Stock We are fortunate to have as author of the hand-
Exchange). Johnston Industries and Jupiter National an-
book, Dr. Sabit Adanur who currently is a
nounced on August 16, 1995 a merger agreement whereby
Johnston would acquire the remaining outstanding shares of professor in the Thxtile Engineering Department
Jupiter National, Inc. of Auburn University. Dr. Adanur holds a Ph.D.
xiii
xiv Foreword
in Fiber and Polymer Science and a Master of Technical University. Before joining Auburn
Science in Textile Engineering and Science from University, he had three years of industry ex-
North Carolina State University as well as a B.S. perience as R&D manager with a major industrial
degree in Mechanical Engineering from Istanbul fabric manufacturer.
L. ALLEN HINKLE
President and C.QO.
Wellington Sears Company
Preface
The 21st century will demand a new kind of in the best possible working environment, so
textile leader, and one of the key attributes will they can manufacture the highest-quality prod-
be the ability to adapt to change. Change is the ucts at the most economical cost. Competitive-
process by which the future invades our lives. ness is a function of the ability of companies to
Those individuals and corporations that are un- continuously improve and innovate their
able to make the transition will be overwhelmed products and processes. The firms, in all major
by what they encounter. Those companies that industries, that can do this are and will continue
are smart, quick, flexible and adaptable will to be world leaders.
grow and prosper. Textile companies have traditionally viewed
In the past few years, the world has become a investment in terms of hard assets: tangible in-
very different place. Monumental events-such vestments that can be measured, such as plants
as the fall of the Berlin Wall, the collapse of and equipment. Yet it is investment in the intan-
Communism, end of apartheid in South Africa, gible assets of the company- such as training,
NAFTA and GATT- have ushered in an era few product development, R&D and supplier/cus-
of us would have dreamed about just a few years tomer relationships-that will help determine
ago. The velocity of change in this small global success in tomorrow's global economy. We have
village in which we live, will impact our quality a tendency to over-invest in some areas and
of life, and shape the decisions of business under-invest in those areas most required for
leaders, educators, and government officials far competitiveness. In the 21st century, greater in-
beyond the end of this century. vestment must be made in innovation, creativity,
Today, we stand on the threshold of the greatest product development and product improvement.
economic revolution and challenge in history. This will mandate a major change in manage-
The rock solid foundation upon which we must ment's perspective of the textile industry.
build our future is education- which leads to Corporations will have to adopt less stringent
innovation and creativity, the keys to a successful strategies and structures to remain competitive.
and competitive nation. These are essential in- Organizations of the future will be less bureau~
gredients in a corporation's recipe to compete in cratic, more entrepreneurial, more flexible and
the rapidly emerging NAFTA and GATT trade creative. These will not be commendable char-
environment. acteristics; they will become essential. The or-
Trade is always about jobs-not economics. ganization will be leaner with a simplified
We can not look in our rear view mirror, we have structure, but also have increased channels for
to look out in the headlights-our front-to the action. Leaders will have to work synergistically
future. The challenge of the next century will not with other divisions, other companies and even
be shutting down factories and replacing men competitors to optimize performance. Corporate
with machines, it will be much more profound strategy will be based not just on products or
and rewarding than that. The ultimate challenge markets, but on competencies that give a com-
of textile executives will be the uniting of the pany access to several markets and are difficult
individual, machines, computers and innovation for competitors to imitate.
XV
xvi Preface
Change itself can really be exciting and in- ing ourselves in existing markets. Creativity and
vigorating. Our consistent aim has to be to create innovation will go just as far as we take it.
products today that anticipate our customer's The Wellington Sears Handbook of Industrial
needs for tomorrow. We believe this adage not Textiles is one of our contributions to the textile
only captures our determination to anticipate the industry. It is our recognition of the significant
needs of a changing world, but also our resolve role that this important industry has played for
to embrace change as an active participant in mankind in promoting free trade and democracy
future growth and prosperity. We have to be more throughout this shrinking world community.
concerned with inventing the future than con- Johnston Industries is very pleased to'be able to
serving the past. We should be more interested in support this progressive effort.
creating new, competitive space, than position-
GERALD B. ANDREWS
President and C. E. 0.
DAVID L. CHANDLER
Chairman
Acknowledgements
This handbook has been prepared with the able assistance from industry professionals,
help of many people. First of all, I would like to professors, students, organizations, companies
thank my colleagues who contributed to the and federal agencies.
handbook by writing some sections indicated I would like to thank Mr. Michael J. Ravnitzky
below. Their help is very much appreciated. of IFAI who spent a considerable amount of his
Some of these sections are co-authored. time and provided excellent data, information and
suggestions for the book. His help made a dif-
Dr. Royall M. Broughton and Mr. Paul H. Brady ference. Special thanks are extended to other as-
• Section 2.1- Fiber Forming Polymers sociatesoftheiFAI including Tim Arens, Juli Case,
• Section 2.2-Natural and Man-Made JeanM. Cook, JosephA. Dieltz, DanetteR. Fettig,
Fibers Joel R. Hoiland, Maike Liekweg, Frank McGinty,
• Section 3.1- Manufacture of Man-Made Robert Meany, Karen Musech, Del Swanson and
Fibers Suzanne M. Zorichak, for their help.
• Section 4.8-Nonwoven Fabrics Many associates from Wellington Sears Com-
Dr. Yehia E. El-Mogahzy pany have provided industry experience and in-
• Section 3.3- Manufacture of Staple Yarns sight to the handbook. I would like to thank Owen
J. Hodges III, Bobby G. Crutchfield, Gayron N.
Dr. David M. Hall Davis, Donald W. Lauderdale, Harold L.
• Section 2.2-Natural and Man-Made Lauderdale, Alan Lightholder, Darwin L. Sears,
Fibers M. Wayne Smith and Tommy B. Strength for
• Section 4.3- Slashing their help.
• Section 20.1- Textile Testing The chapters of the handbook are reviewed
Prof. WarrenS. Perkins and edited by many professionals in industry and
• Section 5.1- Dyeing, Printing and academia. We are most grateful to the following
Finishing people who reviewed the sections in their
specialty areas for their time and valuable sug-
Dr. Lewis B. Slaten
gestions: Peter Alling, The Haartz Corp.; Hilton
• Section 20.1- Textile Testing
Barrett, Red Kap Industries; Jerry Bauerle, On-
Mr. Chettoor G. Namboodri tario Research Foundation; Lutz Bergman, Fil-
• Section 5. 2- Coating and Laminating ter Media Consulting; Royall Broughton,
Prof. Robert P. Walker Auburn University; Ann Brooks, Hamby Textile
• Section 4.1- Classification of Fabrics Research Laboratories; Danny Campbell,
• Section 4.2- Yarn Preparation Hoechst Celanese; Elliot Chaikof, Emory
• Section 4.4- Weaving University Hospital; Tsu-Wei Chou, University
• Section 4.5- Knitting of Delaware; Patricia Christian, Meadox Medi-
• Section 4.7- Tufting cal, Inc.; Barry Christopher, Polyfelt, Inc.; Jerry
Cogan, Milliken Research Center; James Con-
The author requested and received consider- nelly, Highland Industries; Jim Conner,
xvii
xviii Acknowledgements
American Yarn Spinners Association; Dave Cooley, Inc.; Gerhard Seyffer, LTG Tech-
Crawford, J. A. King & Company, Inc.; Payton nologies; John Skelton, Albany International;
Crosby, Asten Dryer Fabrics; Stephen De- Bill Smith, Industrial Textile Associates; Gary
Berardino, LINQ Industrial Fabrics, Inc.; Mar- Smith, North Carolina State University; Tommy
cel Dery, Chemfab; Joseph Dieltz, IFAI; Martin Strength, Wellington Sears Utilization Plant; Jef-
Dodenhoff, Dodenhoff Industrial Text.; Numan frey Stull, International Personnel Protection
Dogan, Tuskegee University; Steve Duerk, JPS Inc.; Thomas Tassinari, U.S. Army Natick R, D
Automotives; David Elton, Auburn University; & E Center; Jerry Tew, AATCC; Rick Walker,
Carole Faria, U.S. Army Natick R, D & E. McMurray Fabrics, Inc.; William Walsh,
Center; Marsha Feldstein, AlliedSignal Inc.; Auburn University; Stephen Warner, IFAI;
Chris Gardner, Inside Automotives; Milton Gil- Adam Varley, Vartest Laboratories, Inc.; Kay
bert, Darlington Fabrics Inc.; Cheryl Gomes, Villa, ATMI.
ILC Dover; Charles Hamermesh, SAMPE; Bill In addition I would like to thank many in-
Hawkins, Reemay Inc.; Heidi Jameson, Sulzer dividuals, R&D centers, associations, govern-
Ruti; Charlie Jones, Hoechst Celanese; Carla ment agencies, institutions and companies who
Kalogeridis, ANCAR Publications; Bill Ken- provided photos, pictures, data and information
nedy, Highland Industries; Andy Kistler, for the handbook. Several pages would be
Bridgestone-Firestone; Alan Lightholder, Wel- needed to list their names.
lington Sears Textest; Jean Martin, Fabric Many of my students have contributed to the
Development, Inc.; Robert Mathis, Hoechst handbook with literature search, critical review,
Celanese; Bob Mcllvane; The Mcllvane Co.; drafting and computer work. I thank all of them
Mansour Mohamed, North Carolina State for their useful work. Special thanks are ex-
University; Terry Montgomery, Springs In- tended to Wanda Barnes, Patricia Smith and Cyn-
dustries, Inc.; Bill. Oxenham, North Carolina thia Jones for administrative work and clerical
State University; Richard Pinelle, Mann In- assistance.
dustries, Inc.; Leonard Pinchuk, Corvita Cor- My sincere apologies to the individuals whose
poration; Michael Ravnitzky, IFAI; Arthur names I might have failed to mention for their
Schwope, Arthur D. Little, Inc.; Robert Seiner, valuable time and contributions.
SABIT ADANUR
Introduction
This handbook is designed to serve a dual in Chapter 17 .0. Chapter 18.0 includes yam
purpose: a resource for people associated with nomenclature, properties and technology. Fabric
the textile industry as well as a textbook for properties and technology are discussed in Chap-
students. The technical level of the book is at- ter 19.0. Textile test methods are listed and dis-
tuned accordingly to accommodate both techni- cussed in Chapter 20.0. To a certain extent, these
cal and non-technical professionals. chapters are built on the 1963 edition of the
The format of the handbook follows the Wellington Sears Handbook of Industrial Tex-
natural flow of textile manufacturing processes. tiles. The author would like to acknowledge the
In Chapter 1.0, definitions, classification and an excellent job done by Mr. Ernest R. Kaswell in
overview of industrial textiles are given. At the fiber, yam, fabric properties and testing more
end of the chapter, several color photographs are than thirty years ago. Some of that information
included to show the typical application areas of is still valid today.
industrial textiles. Several chapters are included to address the
Although this is mainly an industrial textiles new and emerging technologies in industrial tex-
book, some concepts and information related to tiles. Textile waste management and recycling
traditional textiles are also included for con- are included in Chapter 21.0. Chapter 22.0 in-
venience to the reader who may be new to the cludes an introduction and discussion of com-
field of textiles. Polymers and fibers are covered puter technology used in textiles. Standards and
in Chapter 2.0. Chapter 3.0 includes fiber and regulations, which have increasingly more effect
yarn manufacturing techniques. Fabric manufac- on industrial textile markets, are covered in
turing is included in Chapter 4.0. Chapter 5.0 Chapter 23.0. Chapter 24.0 gives a brief descrip-
describes fabric finishing and further processing tion of what textiles might be in the near future.
such as coating and laminating. Every effort was made to include the most
Design, structure, properties and applications recent information and technology available
of industrial textiles for specific markets are throughout the book. Industrial textile markets
described in Chapters 6.0 through 16.0. In- are highly competitive and more proprietary than
dustrial textiles were grouped under usage: ar- traditional textiles, which makes writing a book
chitecture and construction, textile structural in the field a real challenge. The information
composites, filtration, geotextiles, medical tex- available in the literature on industrial textiles is
tiles, military and defense, paper machine cloth- limited compared to consumer or clothing tex-
ing, safety and protective textiles, sports and tiles. There is hardly any reference in the litera-
recreation, transportation and general industrial ture that provides comprehensive coverage of
textiles. The task of grouping industrial textiles industrial textiles. There may be several reasons
was a challenging one because quite often an for this, including the relative young age of in-
industrial textile product may fall under more dustrial textiles, lack of comprehensive expertise
than one category. in the field, and the highly competitive nature of
Fiber properties and technology are described the industrial textiles market. This book is in-
xix
XX Introduction
tended to fill this vacuum and provide the neces- Fabrics Association International (IFAI), who
sary information to both industry and academia showed a personal interest in the successful out-
in a comprehensive package. come of the handbook and made his company' s
This handbook could not have been a reality human and technical resources freely available
without help. I thank God for everything that for it. Last but not least, this handbook would not
made this book possible. I would like to acknowl- have been possible without my wife Nebiye' s
edge the support of a few people who made a big continuous support and encouragement.
difference. First of all, I would like to thank Mr. As can be seen throughout this handbook,
Allen Hinkle, President and C .0.0. of Wellington technical textiles are becoming one of the most
Sears Company, who had the vision to realize the important elements of modern technology and
need for the handbook and initiated this work. lifestyle. There is hardly any place that textiles
His continuous support and encouragement are not used in today' s world. It is my hope that,
during the preparation of this handbook have when the reader is flipping through the pages, the
been very comforting, motivational and are wide application examples of industrial textiles
deeply appreciated. Dr. William K. Walsh, will create brainstorms for new ideas, develop-
Professor and Head of the Textile Engineering ments and application areas of textiles. Finally, I
Department, gave invaluable and timely advice hope that this handbook will help change the
and suggestions from start to finish. His vast minds of those who unfairly consider textiles a
experience and pleasant management style '' sunset'' industry. The last quarter of the 20th
helped greatly to secure the successful comple- century witnessed the ''dawn" of modern in-
tion of the handbook. I would like to thank Mr. dustrial textiles; the 21st century may very well
Stephen M. Warner, President of the Industrial be the" zenith" of industrial textiles.
SABIT ADANUR
1.0
OVERVIEW OF INDUSTRIAL TEXTILES
1.1
Overview of Industrial Textiles
S. ADANUR
~ .. textiles go to war, textiles go to space, widely used term for non-traditional textiles.
become roof, choke an oil spill, imitate a hean, Other terms used are "technical textiles;' "high
hold you safely in your seat, hoist tea bags, performance textiles;' "high tech textiles,"
suppon tires, diaper babies, line roads, keep "engineered textiles;' "industrial fabrics" and
you dry, wrap wounds ... "
"technical fabrics."
American Textile Manufacturers Institute (ATMI)
2. HISTORY
1. DEFINITION OF INDUSTRIAL
TEXTILES
Although the beginning of industrial textiles may
be as old as traditional textiles dating back to several
Industrial textiles are specially designed and
thousand years ago, industrial textiles are con-
engineered structures that are used in products,
sidered to be a little ''younger'' than traditional
processes or services of mostly non-textile in-
textiles. The history of modem industrial textiles
dustries.
probably began with the canvas cloth used to sail
According to this definition, an industrial tex-
ships from the old world to the new across the
tile product can be used in three different ways:
ocean. Later, hemp canvas was used on covered
( 1) An industrial textile can be a component part wagons to protect families and their possessions
of another product and directly contribute to across the land. Fabrics were used in early cars as
the strength, performance and other proper- "rag-tops" to keep out the weather and as seat
ties of that product, e.g., tire cord fabric in cushions for passenger comfort. Fabrics offered
tires. the advantage of light weight and strength for early
(2) An industrial textile can be used as a tool in a flying crafts in the air. The wings of the earliest
process to manufacture another product, e.g., airplanes were made of fabrics. Industrial textiles
filtration textiles in food production, paper are still used in hot air balloons and dirigibles.
machine clothing in paper manufacturing. The invention of man-made fibers in the first
(3) An industrial product can be used alone to half of the 20th century changed the industrial
perform one or several specific functions, textiles market forever. The first truly man-made
e.g., coated fabrics to cover stadiums. fiber, Nylon, was introduced in 1939. By
development of exceptionally strong high perfor-
Another indication of the definition above is mance fibers in the 1950s and 1960s, the applica-
that unlike ordinary textiles which have tradi- tion areas of industrial fibers and fabrics were
tionally been used by the consumer for clothing widened. Man-made fibers not only replaced the
and furnishing, industrial textiles are generally natural fibers in many applications, but also
used by professionals from industries of non-tex- opened up completely new application areas for
tile character in various high-performance or industrial textiles. Synthetic fibers offered high
heavy duty applications. strength, elasticity, uniformity, chemical resis-
The term "industrial textiles" is the most tance, flame resistance and abrasion resistance
3
4 OVERVIEW OF INDUSTRIAL TEXTILES
among other things. New fabrication techniques TABLE 1.1 Percent Share of Technical Textiles
also contributed to the improved performance Production in Total Textile Production.
and service life of industrial textiles. Application 1980 1985 1990
of new chemicals help the design engineers to
U.S.A. 25 33
tailor their products for special uses. 36
Japan 27
Industrial textiles have played a critical role in France 11 16 22
space exploration. Spacesuits are made of a China 13 22
layered fabric system to provide protection and Germany 17 22
comfort for the astronaut. Engineered textiles Western Europe 9 16 22
provided strong and lightweight materials for the
lunar landing module and for the parachutes used
to return the astronauts to earth in 1969. space vehicles are made of textile fibers that can
Military applications, especially during the withstand several thousand degrees Fahrenheit.
global conflicts, expedited the development of These are just some of the many examples which
technical textiles to better protect the soldiers. show the significance of industrial textiles in the
Today technical textiles are used extensively in journey of mankind.
military equipment and protective structures. Table 1.1 shows the percent share of technical
Technical textiles have met the various chal- textiles in total textile production for some in-
lenges created by the advancement of the society dustrialized countries. Industrial textiles account
and by the ever increasing needs of mankind. for one-third of the total textile production in
Industrial textiles have been entering every highly industrialized countries such as the United
aspect of human life. Thanks to advanced medi- States and Japan. The rapid increase of industrial
cal technology, today minute bundles of fibers textiles' share within the last two decades is a
are implanted in human bodies to replace or good indication of their significance.
reinforce parts of the human body. Specially
engineered textiles are used in airplanes, under
highways, in transportation, and for environ- 4. PRINCIPLES OF INDUSTRIAL
mental protection to name a few. TEXTILES
4.2 Fiber Type and Structure other non-traditional fabric manufacturing meth-
(Chapters 2.0, 3.0, and 17.0) ods as well.
A fabric structure can consist of a single layer
Natural and manufactured fibers are the two or multilayers. Each layer can be made of one or
major categories of fibers. Natural fibers are more types of fibers or yarns. There are endless
derived from sources in nature such as wool from numbers of fabric design patterns that provide
sheep and cotton from cotton plants. Cotton and different properties.
other natural fibers such as hemp and jute were
extensively used in early industrial fabrics. 4.5 Manufacturing Parameters
Development of manufactured fibers presented (Chapters 3.0, 4.0, and 5.0)
new opportunities to engineer special properties
into an industrial textile product. Today, most of Special properties can be given to industrial
the industrial textile products are made of textiles by different manufacturing techniques
manufactured or synthetic fibers. such as heatsetting, coating, and application of
Synthetic fibers can be used in many shapes or different finishes.
forms. They can be in the long continuous form A textile engineer can select each of the above
(filaments) or be chopped into shorter lengths variables to produce the best product for its in-
(staple fiber). Filaments provide a smooth sur- tended use. The raw materials for industrial tex-
face and high strength. Fibers can be made with tiles can be in various forms such as wires, spun
different diameters, cross-sectional shapes and a yarns, pulp, fibers, monofilament, multifila-
combination of different polymeric materials ment, rovings and mats. Major textile manufac-
(hybrid or hi-component fibers). turing processes include spinning, twisting,
It is estimated that between 4 and 5 million tons texturizing, weaving, knitting, braiding, needle
of fibers are used annually in the world for tech- felting, bonding, tufting, laying and knotting.
nical purposes. The percentage of fibers going The resulting textile products can be ribbons,
into technical textiles is 38% in Japan, 28% in felts, laid webs, woven fabrics, knitted fabrics,
the U.S. and 21% in Europe [1]. scrims, belts, cord fabrics, mats, nets, non-
wovens, hoses, narrow fabrics, ropes, screens,
4.3 Yarn Type and Structure tapes, cables, carpets, wadding and cords. Dyes,
(Chapters 3.0 and 18.0) films, auxiliaries, impregnating agents, ad-
hesives, plastics and other chemicals can be
A yarn can consist of a single fiber (monofila- added to these textile products to obtain specific
ment yam) or many fibers (multifilament yam). properties. Several chemical, physical and
Staple fibers (natural and manufactured) can be mechanical methods may be involved during the
spun into yarns by twisting (staple yams). Staple process such as coating, extrusion, dyeing, fill-
yarns have more surface texture and softness. A ing, impregnation, calendering, backing, ad-
yarn can be made by blending several different hesive bonding, lamination, metallization,
fibers for unique properties (hybrid or blended stitching, perforation, embossing, prepregging,
yarn). pressing, punching, molding, welding, stretch-
Different staple yarn manufacturing methods ing, vulcanization and cutting.
(ring spun, open-end, friction spun, air-jet spun)
provide different yam structures and hence
properties. The twist level of a yarn is another 5. DIFFERENCES BETWEEN
variable that can affect texture and strength. INDUSTRIAL AND
NON-INDUSTRIAL TEXTILES
4.4 Fabric Type and Structure
(Chapters 4.0 and 19.0) It is reasonable to state that, compared to tex-
tiles for apparel, there is a communication gap
A fabric structure can be woven, nonwoven, between industrial textile manufacturers and the
knit, braided, laminated, or stitched. There are end users, who are often in other industries. A
6 OVERVIEW OF INDUSTRIAL TEXTILES
typical example for this is the situation in geotex- TABLE 1.2 Major Industries That Use Textiles.
tiles. The major geotextiles test methods and • Advertising • Leather
standards have been developed by civil en- • Agriculture • Mechanical engineering
gineers, most of the time without the involve- • Automotive • Medical
ment of textile engineers. This situation is • Aviation • Mining
generally true for almost all of the industrial • Building • Oil industry
Each classification has advantages and disad- • reinforcement fibers for concrete and
vantages which can be a lengthy discussion. In plastics
this book, the classification of industrial textiles • reinforcing domes and covers for
is made mainly on the basis of the final applica- stadiums
tion. The main reason for this selection was the • filaments, yarns, cords and small-wear
convenience to the reader. Therefore, the chapter for reinforcement purposes
titles carry the name of the end use market. There • textile sheet products for reinforcement
is one exception to this which is the "Textile purposes
Structural Composites" in Chapter 7. 0. Textile • textile reinforced structural parts,
composites are increasingly used in so many profiles and pipes
different applications that make it easier to class- • textile reinforced molded articles
ify them as an industrial textiles group. • textiles for reinforcing building
materials, concrete and cement
6.1 Textiles in Agriculture • bridges
• textile reinforced containers
• textiles for landscaping • textile reinforced lightweight building
• textile reinforced plastic and concrete materials
parts, pipes and containers • textiles for subsoil stabilization
• sacks • textile drainage systems
• insect and bird netting, crop covers • fabric sculptures to beautify, reinforce
• belting and protect
• rope wear • noise control in offices
• hoses • textiles in public buildings and
• transport and lifting materials convention halls
• tarpaulins • textile shuttering materials
• flexible and rigid containers • textile facade packing systems
1.1 Overview of Industrial Textiles 9
• textile roofs and roof sheeting • reinforcing materials for soil stabilization
• textile products for building electric • materials for landfllls and the waste
systems industry
• insulation against cold, heat and noise • textiles in drainage systems
• tents and tent frames • membrane materials
• temporary buildings, inflatable buildings • environmental protection products
for warehousing • reinforcing textiles for plastics
• membranes for lightweight plane • reinforcing textiles for concrete
load-bearing structures
• pneumatic structures 6.6 Medical Textiles
• winter building systems
• stay ropes and systems • textiles of bactericidal fibers
• textile acoustic protection systems • hygiene nonwovens
• awning textiles and systems • bandage materials
• textile heating, cooling and air • sutures
conditioning systems • operating and emergency room textiles
• textile planting and irrigation systems for • textile products for surgery
terraces, roof gardens and courtyards • textile reinforced prostheses
• textile reinforced plastic for interior • operating sheets
decoration • hospital bed linen and blankets
• fire protection and rescue systems • mattresses and protective mattress covers
• medical cushions
6.3 Textile Structural Composites • dental floss
• synthetic skin
• textile reinforced lightweight building • general textiles for institutional and
materials hospital use
• textile reinforced structural parts, • doctors' and nurses' clothing
molded articles and profiles • rescue services equipment
• textiles for use in corrosive media • textiles for medical equipment
• textile reinforced motor and machine parts
6. 7 Military and Defense Textiles
6.4 Filtration Textiles
• textile armor
• textiles for cleaning and separating of • parachutes for spaceships
gases and liquids • personnel protection
• textiles for recovery of products • aerospace and electronics components
• textiles for hot air/gas industrial filtration • chemical suits
• filtration in cigarettes • covers
• textiles for filtration in food industry • helmets
• textiles for sewage filtration • air conditioned suits
• ballistic protection
6.5 Geotextiles • military tents
• inflatable buildings
• textiles for earthworks and roadmaking • fabrics for bullet-proof vests
• textiles for bank and coastal stabilization • medical devices
• textiles for hydraulic engineering • flight and tank driver garments
• fabrics for erosion control • marine applications
• textiles to reinforce and line waste ponds • rescue systems for air, water and land
and pits vehicles
10 OVERVIEW OF INDUSTRIAL TEXTILES
12
2.0
POLYMERS AND FffiERS
2.1
Fiber Forming Polymers
R. M. BROUGHTON, JR.
P.H.BRADY
The purpose of this section is to introduce the The type of repeating unit, or mer, defines the
structure of fiber forming polymers used in the overall polymer. Before reacting to form the
production of industrial textiles. polymeric structure, each repeating unit exists as
As atoms are the smallest unit of construction a monomer. Therefore a monomer is a precursor
for molecules, polymer molecules are the small- to the polymer. If a monomer is reacted with and
est unit of construction for fibers. Although not caused to attach to another monomer, and then
all polymer structures are fibers, regardless of the group of two reacts with a third and so on, a
whether natural or man-made, nearly all textile polymer is formed. Because the repeating unit or
fibers are polymer structures. Most of the mer defines its resultant polymer, if the attributes
polymers have a predominantly carbon based of the repeating unit can be interpreted, many of
backbone and are, therefore, organic structures. the performance characteristics of its resultant
polymer structure can be predicted.
1. BASIC DEFINITIONS
2. POLYMER STRUCTURAL
The term polymer means "many parts:' A CLASSIFICATIONS
polymer is a large molecule containing a limited
number of types of repeating units. A repeating A polymer structure may be classified as
unit is a small grouping of atoms which, iflinked either a homopolymer or copolymer. The
together in a repetitive sequence, will reproduce homopolymer configuration indicates that all of
the polymer structure. Repeating units are the repeating units in the polymer are the same,
derived from, and similar to, the small molecules or homogeneous, in nature. Many polymers used
which react together to produce the polymer. The in textile applications are homopolymers. A
small starting molecules are called monomers copolymer configuration requires that two or
(sometimes the repeating unit is referred to as a more different types of repeating units are
mer). The definition of a polymer could be stated present in the structure in some sequence.
as: a large molecule made from a limited number
of different kinds of monomers.
How large is a polymer? Generally if a 2.1 Homopolymers
molecule contains as many as fifty similarrepeat-
ing units it would be considered as a polymer. An If the monomer unit may be represented as A,
oligomer (meaning "few") is similar to a a homopolymer structure can be depicted as
polymer with the exception that it will typically
have no more than ten repeating units in its chain
A-A-A-A-A-A-A-A-A- ...
sequence. Dimer, trimer, and tetramer are some-
times used to describe blocks of two, three, or
four monomer units respectively. Most of the where A would be repeated at least one hundred
polymers in fibers will have at least 100 repeat- times for most fiber applications. It is important
ing units, and some may have thousands. to note that the terminal or end units of a polymer
31
32 POLYMERS AND FIBERS
should not be assumed to be the same as the main with the abbreviated form
body units. Depending on the polymerization
technique, or patented technology of the - [AB]n- or poly(AB)
manufacturer, the terminal units may differ, e.g.,
ferent component comprising the branch. A minable through the description of the repeating
branched polymer's side chain is typically com- unit. However, the conformation may not be so
posed of the same species as the backbone chain. obvious, especially in those polymers composed
There is no common abbreviation for the primarily of singly bonded atoms along the back-
branched polymer. bone chain. Single bonds occurring between
atoms allow for 360° bond-axis rotation of the
Cross/inking and Gelation atoms relative to each other. Carbon atoms in a
chain of carbon-carbon single bonds assume an
Most of the polymers used in fibers are linear, angular displacement of 109° from each other.
at least when the fiber is first produced. Some- When drawn on paper, the conformation is typi-
times the polymers must be crosslinked to be cally shown as a planar arrangement, but in
useful. Crosslinking is the process of producing reality the conformation is three-dimensional.
primary chemical bonds between polymer The importance of the spatial arrangement of the
molecules. A di-functional (or multi-functional) chain segments is in defining the chain segments'
small molecule is caused to react with adjacent ability to assume a position in a regular or crys-
polymer molecules, tying them together. When talline array.
crosslinking is extensive, the mass becomes a When a polymer repeating unit contains pen-
single, large molecular network. These polymer dant or side groups, the orientation of the ele-
networks restrict molecular mobility and cannot ments becomes much more critical in the
be melted or dissolved. Extensive polymer determination of its ability to assume a position
branching may result in a type of structure in a crystalline array. This is particularly true of
similar to that obtained by crosslinking. The term a polymer whose backbone chain is composed
applied to a mass of highly branched polymer is predominantly of methyl groups (CHz). The
gel. When, in the course of polymer manufac- orientation of the pendant groups along the
ture, branching becomes extensive enough that polymer chain is called the tacticity of the struc-
a large fraction of the polymer mass is tied ture. In order to simplify the concept of tacticity,
into infusible, insoluble material, the poly- it is considered in a two-dimensional plane only,
mer reaches the gel point. Figure 2.1 shows where the pendant groups are arranged either up
the schematic representation of branching and or down relative to the main polymer chain. The
crosslinking. atoms to which the pendant groups are attached
are called chiral centers, and therefore tacticity
3. DIMENSIONAL ORDERING is related to chirality.
Complex chemistry is required to control the
The arrangement of a polymer's elements of chirality and therefore the final molecular arran-
construction along its chain length is referred to gement of a polymer. If the chiral centers formed
as its configuration. The spatial or three-dimen- during polymerization are all identical, the con-
sional orientation of the chain segments along the formation of its pendant groups are the same, and
length ofthe polymer is designated as the confor- the polymer formed is isotactic. If the chiral
mation. The configuration is generally deter- centers randomly alternate, the resultant poly-
'"'"'-__..____. . . . .__=-
branching cross linking
FIGURE 2.1 Branching and crosslinking.
2.1 Fiber Forming Polymers 35
atactic syndiotactic
isotactic
FIGURE 2.2 Tacticity in polymers.
mer is atactic. If the two possible arrangements referred to as IUPAC (International Union of
coherently alternate, a syndiotactic structure is Pure and Applied Chemistry) nomenclature, and is
formed. an internationally accepted method of naming
The effect of chirality on tacticity can be seen chemical structures. Many polymers have become
in the polymerization of a substituted ethylene so commonly recognized that their generic or trade
(Figure 2.2). If all of the pendant methyl groups names have been accepted as an adequate descrip-
appear on the same side of the polymer chain, the tion. The decision of whether to use the IUPAC or
arrangement is isotactic. If the groups alternate generic name generally rests upon how accurate the
from side to side, it is syndiotactic, and if they description must be. Polyester is a good example
are random, it is atactic. of a commonly recognized generic name, usually
implying poly(ethylene terephthalate), but in fact
4. POLYMER NOMENCLATURE there are other chemical forms of polyester.
Homopolymers (those having only one kind of
As a general rule, any polymer can be named repeating unit) are usually named according to
according to the chemical components compris- their monomers' chemical designation. The most
ing the chain. This type of polymer naming is familiar of this type are probably the polymer
forms of ethylene and propylene, which are of complex names that are generically renamed.
course polyethylene and polypropylene. In these The polymerization of hexamethylene diamine
simplest cases, it is obvious that the polymer with adipic acid produces poly(hexamethylene
names are derived by adding the prefix poly to adipamide), but is more readily recognized when
the common chemical name of the monomer. described as Nylon 6,6. The complexity of the
Therefore, polymerized vinyl chloride becomes name is further complicated by copolymeriza-
poly(vinyl chloride) (PVC), and tetrafluoro- tion. For example, a copolymer of ethylene and
ethylene becomes poly(tetrafluoroethylene) ethylene oxide would be written as poly(eth-
(PTFE or Teflon®). Though not always common ylene-co-ethylene oxide). In Table 2.1, a list of
practice, it is more correct to include the name some common polymers is shown by molecular
of the monomer in parentheses; poly(propylene) makeup, proper chemical nomenclature, and an
rather than polypropylene. accepted common name.
As would be expected, the more complex the Polymer chemists and textile scientists usually
monomer's precursors, the more complex the use the common name rather than the name
name of the polymer. It is usually these more approved by IUPAC.
2.2
Natural and Man-Made Fibers
D.M.HALL
S. ADANUR
R. M. BROUGHTON, JR.
P.H.BRADY
Mankind has been fortunate that over the eons, In addition to the chemical nomenclature (Sec-
natural materials could be found with suitable tion 2.1), the Federal Trade Commission (FTC)
fiber properties to fabricate clothing for warmth, has defined generic categories of fibers based on
comfort and style depending upon the needs at chemistry and properties. Each category has
the time. The most important fibers in the world been assigned a generic name. Basically, any
until about 1910 were the protein fibers wool and consumer textile item sold in retail commerce
silk, and the cellulosic fibers cotton and linen. must carry a label declaring the generic name and
All of these products are produced from agricul- the percent by weight of all the component fibers
ture. The production of wool, silk and linen has in the composition (which exceed 5% of the
remained static for the last decade owing to the total). Certain items like luggage, carpet back-
fact that land and facilities for cultivating these ing, hats, wiping rags, furniture stuffing, and
fibers are fixed (and for some they are declining). tarps are exempted, as are items intended for
With the world population growing rapidly and industrial applications. A manufacturer may
the supply of these fibers either diminishing or label the fibers with trade names and other infor-
fixed, the cost of using these fibers for ordinary mation specific to the manufacturer, but the
textiles is prohibitive. Only cotton is grown in generic names of fibers and the percent composi-
quantities that enable it to continue to be an tion must always be present. The purpose of a
economical source for textile manufacturing. generic name is to provide the consumer with a
About 1910, discoveries were made which recognized name with which to associate a set of
allowed fibers to be spun from special solutions expected fiber properties. Some fibers find little
of cellulose as continuous filaments. Unlike the or no use in consumer textiles, and may not have
natural products, these fibers could be spun into an established generic name.
varying diameters that were essentially the same Generic names for manmade fibers are
for every fiber in the bale. Further, the filaments defined by the chemistry of the fiber and its
could be cut into any length uniformly unlike that physical properties. New names may be added
of cotton and linen. Later it was found that they and older ones modified in definition as
could be made to have cotton-like properties of demanded by technology and developments.
softness and hand, have ignition, sunlight and rot When believed required, a manufacturer can
resistance among other properties that could be petition the FTC for the establishment of a new
built into the fibers as they were being spun. generic name. In response, the FTC will ex-
Thus, it was found that the fibers could be en- amine the chemistry of the new fiber as well as
gineered to have specific properties depending its properties, and then decide whether a new
upon the desired end uses of the product. Today, name is warranted. Natural fibers are labeled
the number of different genera of fibers that have according to their origin. Thus cotton, linen,
been produced for textile purposes is quite high. silk, wool, etc., are legitimate generic names.
37
38 POLYMERS AND FIBERS
1.2 Trade Names and Trademarks than 90% cellulose, with the remainder being
waxes, monomeric and polymeric sugars,
The terms trade name and trademark may be residual protoplasm, and minerals. The structure
defined as follows [1]. of cellulose is shown below.
trade name: 1 a: the name used for an article
~
among traders, b: an arbitrarily adopted name
that is given by a manufacturer or merchant to an H-C-~ O,r.H
article or service to distinguish it as produced or
sold by him and that may be used and protected HO
as a trademark, 2: the name or style under which H
a concern does business.
Cotton fiber has been around for thousands of
trademark: 1: a device (as a word) pointing
years, hence virtually every type of fabric that
distinctly to the origin or ownership of merchan-
may have industrial applications has been
dise to which it is applied and legally reserved to manufactured at one time or another using this
the exclusive use of the owner as maker or seller.
agricultural based cellulose containing fiber. The
Trademark is registered with the U.S. Depart- fact that it has an agricultural base is the reason
ment of Commerce, Patent and Trademark Of- why the fiber varies so much in diameter (fine-
fice (Washington, D.C. 20231) as a trademark of ness), maturity level, fiber length and uniformity
that company. A product with a trademark is among others (Figure 2. 3). Textile mills are quite
indicated with the sign® on the right-hand comer adept at selecting the proper mix of fibers from
of the trademark. A trademark owned by a com- the billions of pounds of the various varieties
pany cannot be used by other companies for the (American Upland, American Egyptian, Sea Is-
same specific type of product. land and Pima etc.), grown in the United States
The Patent and Trademark Office publishes alone, to obtain those properties required in the
the Trademark Official Gazette regularly which final product. Because of the technical base and
contains an illustration of each trademark pub- know-how for the processing of this fiber, the
lished for opposition, a list of trademarks industrial fabric can usually be made less expen-
registered, and a classified list of registered sively than using other fiber types. Further, it is
trademarks and patent office notices. suitable for blending with many of the other fiber
There may be several trade names for the same types in order to achieve a unique combination
generic fiber manufactured by different com- of properties not available in the cotton alone.
panies. The properties of these fibers may or may The cotton fabrics can be mercerized to en-
not be the same, but they all fit the generic hance their strength, luster, dyeability and resis-
definition of the fiber. tance to shrinkage. They can be colored by a wide
variety of dye classes to give the desired resis-
tance to fading or color changes due to sunlight or
2. NATURAL FIBERS atmospheric contaminants. They are resistant to
strong alkali, organic solvents, bleaches and heat
As mentioned previously, the FTC generic (such as during process treatments and ironing).
name for natural fibers is generally the same as The fibers can be formed into woven, braided,
the common name. Cotton, wool, silk, linen, nonwoven or knitted fabric types.
jute, etc., are all acceptable generic names. Cotton fibers' disadvantages are that they lack
elasticity and resiliency, are weakened by strong
mineral acids, are affected by mildew and are
2.1 Cotton attacked by silverfish-type insects, have poor
sunlight and atmospheric resistance, i.e. , do not
Cotton is the name given to a seed hair fiber weather well, and are not ignition resistant, al-
from the plant genus Gossypium. It is the most though chemical treatments are available that
widely used textile fiber. The structure is more will mitigate most of these problems.
2.2 Natural and Man-Made Fibers 39
of chemicals, and does not have extensive ap- nature. Synthetic fibers have no natural polymeric
plications in industrial fabrics. Other hair fibers precursors. Thermoplastic polymers such as
will differ in size, pigmentation, scale frequency, ny Ion or polyester are examples of this category.
and harvesting methods. Hair fibers are most Table 2 .2lists common man-made fibers. FTC
often used for apparel and carpeting. A general- definition, chemical structure and important
ized structure of a protein is shown below. properties of the fibers are given below.
0 0 0
II II II 3.1 Acetate
-N-C-C-N-C-C-N-C-C-
1 I I
R1 ~ Rn•1 ''A manufactured fiber in which the fiber-
R• Alanine Glycine Phenylalanine Tryptophan forming substance is cellulose acetate. Where
Arginine Histidine Proline Tyrosine
Aspartic Acid Leucine Serine Valine
not less than 92% of the hydroxyl groups are
Cystine Lysine Threonine Isoleucine acetylated, the term triacetate may be used as a
Glutamic Acid Methionine
generic description of the fiber." Two varieties
of acetate are produced which are secondary
Silk
cellulose acetate and cellulose triacetate. As the
name implies, they describe the approximate
Silk is a protein fiber like wool but with a much
number of hydroxy Is of the cellulose which are
simpler structure. It is an extruded fiber which is
replaced by acetyl groups. These acetyl groups
chemically and structurally uniform across its
confer new properties to the cellulosic polymeric
diameter. The amino acids have smaller pendant
chains, chief of which is high loss of water ab-
groups than those found in wool, allowing a
sorbency, i.e., the fibers are hydrophobic (water
pleated-sheet structure rather than helical to
hating) in nature. They are dry spun by spinning
occur.
solutions of the cellulose derivatives dissolved in
0 0 0 low boiling volatile solvents into hot air where-
II II II
-N-C-C-N-C-C-N-C-C- upon the solvent is evaporated resulting in a solid
1 I I continuous thread of the cellulose acetate
R1 ~ Rn.1
R =Alanine, Glycine, Serine, or Tyrosine polymer.
TABLE 2.2 Generic and Trade Names of Common Man-Made Textile Fibers.
Fiber Type Name Manufacturer
Acetate Acetate
Acrylic Acrilan® Monsanto
Creslan® Cytec
MicroSupreme® Cytec
Aramid Kevlar® DuPont
Nomex® DuPont
Carbon Thorne!® Amoco
Fluorocarbon Gore-Tex® W. L. Gore
Teflon® DuPont
Glass Glass
Lyocell Tencel® Courtaulds
Modacrylic SEF® Monsanto
Nylon Nylon6
Nylon6,6
Olefin Polyethylene Hercules
Herculon® Hercules
Marvess® Amoco
Alpha® Amoco
Essera® Amoco
Marquesa Lana® Amoco
Patlon III® Amoco
Spectra 9()0® Allied
Spectra 1000® Allied
Fibrilon® Synthetic Industries
Polybenzimidazole PBI Hoechst Celanese
Polyester ACE® Allied
Compet® Allied
Dacron® DuPont
Fortrel® Wellman
4DG Eastman
Tairilin® Nan Ya Plastics Corp., America
Trevira® Hoechst Celanese
Rayon Fibro® Courtaulds
Cuprarnmonium
Rayon North American Rayon Corp.
Saran Saran® Pittsfield Weaving
Spandex Glospan®/Cleerspan, S-85 Globe
Lycra® DuPont
Sui far Ryton® Amoco (licensed to Phillips)
Their major disadvantages are that they are Numerous non-textile uses for these materials
quite weak compared to cotton or rayon, as well include plastics and films, cigarette ftlter fibers,
as being more flammable (unless treated). They coatings (such as fingernail polish), finishes, and
are considered thermoplastic fibers hence are the like.
more affected by heat (secondary acetate should
not be heated for any appreciable time over 3.2 Acrylic
275°F, triacetateover400°F), have higher static
propensity, and are dissolved or badly affected "A manufactured fiber in which the fiber-
by common solvents such as acetone (found in forming substance is any long-chain synthetic
nail polish removers), acetic acid, some alcohols polymer composed of at least 85% by weight of
and other common ketones and chlorinated acrylonitrile units?' The commercially produced
hydrocarbons. poly(acrylonitrile) (PAN) polymers are typically
42 POLYMERS AND FIBERS
formed through free radical polymerization. The linkages are attached directly to two aromatic
polymer produced by this method is considered rings."
mostly atactic, exhibiting little conventional Commercially available aramid fibers are
crystallinity. Typically the homopolymer is not Nomex® and Kevlar® produced by DuPont and
used for the production of fibers. Fibers usually Twaron® produced by Akzo.
contain up to 15% of a comonomer (vinyl
Ho-fZQ>~.O -@~+.H
acetate, vinyl chloride or an amine functional
group) to improve the dyeability or the flexibility
of the fiber. 0II~ 0 C-N
-f6-6-l
H
I
H
H
ITn
e-N
Meta-Aramid (Nom ex®)
which have been used mostly for clothing and produced by a number of manufacturers and is
have had limited use in industrial textiles. one of the most commonly used industrial fibers.
Originally it was hoped that a man-made protein Glass fibers find widespread use as an in-
fiber might have properties as good as these dustrial fiber because of its excellent ignition
natural fibers, but the results have been disap- resistance, high strength (being stronger than
pointing. Research has continued sporadically steel of the same diameter), sunlight weather,
due to the potential that a fiber might be insect, mildew, bleach and other chemical resis-
developed with the strength or elasticity of that tance. It is not affected by water, has virtually no
produced by spiders and certain caterpillars. Al- shrinkage and is considered fireproof.
though man-made protein fibers have been Its major disadvantage is its low abrasion
produced in the past from bean, milk and com resistance and easy damage by mechanical ac-
protein, none is currently being produced in the tion. Nonetheless it can be made into woven and
United States. nonwoven fabric forms. Glass fibers can cause
skin irritation when the broken fibers penetrate
0 0 0 the skin pores.
II II II
+N-c-c+co+N-c-c+co+N-c-c+
I I I 3. 7 Metallic
R1 Rz R••1
Nomex11
430 Standard, bright yarn for high temperature uses
432 Same as Type 430 but producer-colored ''Olive Green''
433 Same as Type 430 but producer-colored ''Sage Green''
Kevlaril
Kevlar 950 Tire belt reinforcement and radial-tire carcasses
956 High performance mechanical rubber goods, such as hoses, V-belts, precision
drive belts, and conveyor belts
Kevlar 49 965 Woven reinforcement in aerospace composites, hard ballistic armor, and
printed circuit boards
967 Pultrusion and chopping
968 Marine composites, fiber optics, ropes, and filament-wound composites; no
secondary finish
969 Certified product for filament-wound composites in special aerospace uses; no
secondary finish
978 Ropes and cables, with special overlay finish for improved abrasion resistance
989 Tailored length packages for fiber optic cable reinforcement
Kevlar 68 956B High performance mechanical rubber goods, such as hoses, V-belts, precision
drive belts and conveyor belts
965B Woven reinforcement in aerospace composites, hard ballistic armor and printed
circuit boards
968B Marine composites, ropes, filament-wound composites; no secondary finish
975B Fabrics used in pipe liner reinforcement
989B Fiber optic cable reinforcement
Kevlar 149 965A Woven reinforcement in aerospace composites, hard ballistic armor, and
printed circuit boards
968A Marine composites, fiber optics, ropes, filament-wound composites; no sec-
ondary finish
44
2.2 Natural arul Man-Made Fibers 45
vacuum evaporation to coat a plastic film, etc.) ( -CO-NH-) linkages are attached directly to
are employed to produce metallic fibers. Since two aromatic rings." Nylon is the first truly
they are a non-traditional textile product, metal- man-made synthetic fiber. It is produced by
lic fibers are usually produced by companies not either the reaction of an amino acid with itself or
normally associated as a textile operation. between diamines and diacids. They are com-
bined under the influence of high temperature
3.8 Modacrylic and pressure via amide linkages to produce the
fiber forming polymer. The resulting nylon is
"A manufactured fiber in which, when not melt spun into fibers which are oriented by
qualified as rubber or anidex, the fiber-forming stretching to give variants having a wide range
substance is any long-chain synthetic polymer of fiber diameters and cross-sectional shapes,
composed of less than 85%, but at least 35% by strengths, weight, elasticity, and luster among
weight of acrylonitrile units.'' Most often, the other properties that give high versatility to these
comonomer used with acrylonitrile is vinyl fibers (Figure 2.5).
chloride. The main effect achieved through the A large number of distinctly different structures
inclusion of this comonomer is a reduction of is possible and has been commercially developed.
acrylic's flammability. It tends to shrink when These structures are generally represented by the
heated but can be blended with other fibers to word nylon followed by a number designation. If
improve ignition resistance. the nylon is formed solely from an amino acid, a
single number suffix represents the number of car-
H H H H bons in the acid. A two number suffix is used if the
-f c
l
I
- c
I'-1.:-f'c - c'±
n I I n
nylon is made from a diamine and a diacid. The first
H C!iii!iN H Cl number represents the number of carbons in the
diamine, and the second number represents those
3.9 Novoloid in the diacid. If the diacid is terephthalic acid, the
letter" T" is used instead of a number. Nylon 6 and
''A manufactured fiber containing at least 85% nylon 6,6 comprise over 90% of commercial nylon
by weight of a crosslinked novo lac.'' A novo lac fiber production.
is a low molecular weight resin produced by the
reaction between phenol and formaldehyde. The ~ ~ ~
H-fN-(CI )-c..lr.H
5 JnV
phenol-formaldehyde resin produces a branched
H
polymer and eventually a crosslinked product if Poly(hexanolactam) (Nylon 6)
the molecular weight is increased. It is spun as a
low molecular weight product and crosslinked in ~~~~~~
H-fN-(C)-N-C-(Cl-c±oH
fiber form to produce the final product. The H 6 H 4 "
formaldehyde can react at the 2, 4 and 6 carbons Poly(hexamethylene adipamide) (Nylon 66)
on the phenol ring, and each ring is, therefore, a
potential branching site. Nylon can be heatset to impart both crimp
(texturizing and bulking) and high dimensional
-CH~CH-
stability to either the yarns or fabrics. Industrial
applications include air springs, belting, nets and
' ~ ' twine, hose fabrics, filter fabrics, nonwoven
felts and reinforcing fabrics which can be either
...... CH;;····· coated or used alone in such applications as
geotextile uses, artificial grass on athletic play-
3.10 Nylon {Polyamide) ing fields, tentage and in many types of architec-
tural and construction applications. These few
''A manufactured fiber in which the fiber- illustrations of the present day industrial uses for
forming substance is a long-chain synthetic nylon containing fabrics serve only to illustrate
polyamide in which less than 85% of the amide its wide potential as an industrial textile material.
FIGURE 2.5 Various cross-sectional shapes of nylon fibers.
2.2 Natural and Man-Made Fibers 47
integral part of the polymer chain.'' Fairly recent tures. Thus, they are ideal candidates for many
in development, this fiber has found use in a industrial uses. Typical applications include
variety of high temperature applications, or floor coverings, conveyer belts, hoses, ropes,
where non-flammability is desirable. The most tire cord, papermaking fabrics, sewing thread
familiar usage of PBI has been in protective and the like.
suiting for astronauts. Their major disadvantage is their propensity
to absorb oily liquids and soils which are difficult
H H to remove under typical laundry conditions.
[/N'(51 r()rN)-R~ They are considered flammable having a low
L'N~N _j" softening temperature and will melt and drip
(similar to the nylons) before ignition occurs.
3.14 Polyester Their low moisture absorption can result in high
static accumulations but this can be mitigated by
''A manufactured fiber in which the fiber- employing graphite (or other conductive carbon)
forming substance is any long-chain synthetic core fibers such as those employed to reduce
polymer composed of at least 85% by weight of static with the nylons. Their pilling tendency is
an ester of a substituted aromatic carboxylic quite similar to that for nylon.
acid, including, but not restricted to, substituted
terephthalate units ( -R-O-CO-C6H4- 3.15 Rayon
CO-O- ), and para-substituted hydroxyben-
zoate units ( -O-R-C6H4-CO- ).'' Unlike ''A manufactured fiber composed of regen-
the aliphatic nylons which have a melting erated cellulose, as well as manufactured fibers
temperature sufficiently high enough to be useful composed of regenerated cellulose in which sub-
for textile fibers, polyesters require the inclusion stituents have replaced not more than 15% of the
of an aromatic ring to produce a fiber with a hydrogens of the hydroxyl groups.''
useful melting temperature. Because of its ver-
satility, polyester has the highest volume con-
sumer usage of all man-made fibers, and finds
application in many industrial textile products.
properties (density, flammability, mildew pro- dustrial textiles. In addition to rayon, cellulose is
pensity, moisture absorption) as cotton; in addi- the basis for almost all of the fibers produced in
tion, it competes well with cotton in cost. Figure nature by plants.
2.6 shows a photomicrograph of rayon fibers that
are used in tire cords. 3.16 Rubber
Rayon fibers can be manufactured into any
desired denier either as a continuous filament or "A manufactured fiber in which the fiber
cut into staple of any length and are not subjected forming substance is comprised of natural or
to bysinosis problems. They can be obtained in synthetic rubber.'' The definition may be further
varying luster, have either wet or dry modulus, categorized as follows:
can be made to have fair to excellent strength,
can be manufactured with self crimping variants,
can be engineered to have built-in ignition resis-
tance, cover factor, surface area (important in
absorption) among other properties. It is an ideal • a manufactured fiber in which the fiber
replacement for cotton in a wide range of in- forming substance is a hydrocarbon
dustrial (especially nonwoven) applications. It such as natural rubber, polyisoprene,
certainly should be considered for blending with polybutadiene, copolymers of dienes and
cotton to improve the yam uniformity, surface hydrocarbons or amorphous (non-crystal-
sorption properties, absorbency, bulk and elon- line) polyolefins
gation properties of the blend. • a manufactured fiber in which the fiber
Rayon's relatively low strength and elonga- forming substance is a copolymer of
tion have limited its use in most industrial ap- acrylonitrile and a diene (such as
plications. Recent developments in solvent-spun butadiene) composed of not more than
cellulose may provide more opportunities in in- 50% but at least 10% by weight of
3.20 Vinal
3.17 Saran
''A manufactured fiber in which the fiber form-
''A manufactured fiber in which the fiber ing substance is any long chain synthetic polymer
forming substance is any long chain synthetic composed of at least 50% by weight of vinyl
polymer composed of at least 80% by weight of alcohol units ( -CH2- CHOH- ), and in which
vinylidene chloride units.'' Saran is usually the total of the vinyl alcohol units and any one or
produced in a specialized monoftlament form for more of the various acetal units is at least 85% by
flame retardant and chemical resistance applica- weight of the fiber.'' Although the polymer is
tions. The most familiar consumer usage is in manufactured in large qualities for a variety of
ftlm or coating form. glue and coating applications, there is no vinal
fiber currently manufactured in the United States.
H Cl
-f e-el
H
I I ""'Tn"'
Cl
The water solubility of the vinal fiber must be
overcome (usually by formaldehyde crosslink-
ing) in order to produce a durable product.
3.18 Spandex
H H
~ ~ H H
-f0C-N-R,-N-C-0-Rz-O.l._
II U
0
Tn -f c-t_l_
I I ""'Tn""'
H Cl
2.2 Natural and Man-Made Fibers 51
The fluorocarbon, poly(tetrafluoro ethylene) Typical carbon fiber manufacture involves the
(PTFE), also known by the trade name Teflon®, heating of a precursor fiber in an inert atmo-
can be made into a fiber and finds application sphere. The precursor typically is a ring-type
in chemically and environmentally resistant structure which can, under the appropriate con-
products. Very little fluorocarbon is made in ditions, be converted to graphite. Precursors in-
fiber form for apparel applications. It fmds a clude rayon, PAN, and mesophase (liquid
niche in woven, knitted, braided and felted forms crystalline) pitch. The characteristics of the car-
for specialty applications. Its widest uses are as bon fiber depend on the precursor as well as the
coatings for antistick applications such as on heating conditions. The structure of graphite is a
cookwear and the drying cylinders in the textile planar array of benzene rings. Highly graphitic
mill for sizing and in dyeing/finishing applica- carbon has a very high tensile modulus.
tions. It can also be made as an expanded film for Carbon fibers have super high strength
water and chemical barrier applications under properties and are considered ignition resistant
the trade name Gore-Tex®. These films have the as well as high temperature resistant. Their
advantage of being breathable, allowing water major disadvantages are their lack of elasticity
vapor to transpire through the films but not water and abrasion resistance. Some typical uses which
droplets. Other non-fiber uses include finishes illustrate their potential performance for in-
for antisoil and waterproofing applications, for dustrial applications include reinforced resin
example in raincoats, soil resistant carpet and (and metals), golf club shafts, crossbows, rotor
upholstery fibers and the like. The material also blades and other parts for helicopters, skis, jet
has a very low coefficient of friction and can be engine parts, ship keels among others. The fiber
used to give nearly friction free surfaces. It also can be woven and fabricated as nonwoven tex-
has high ignition resistance and cannot be ignited tiles. Their electrical conductivity can be a prob-
even in a 100% oxygen atmosphere. When ig- lem in some applications.
nited or decomposed at temperatures above
400°C, the fibers will generate dangerous gases, Poly Ether-Ether-Ketone (PEEK)
hence the materials are not used in extreme heat
applications.
product is atactic. There is interest in the fibers vantages in flexibility and fatigue, and improved
for use in optical devices. chemical resistance. The structure for Vectran®
is shown below.
H H
-f9-;& -f-o-©-~-o--r()YQI
HlQJ
~rr+.
0
53
3.0
FIBER AND YARN MANUFACTURING
3.1
Manufacture of Man-Made Fibers
R. M. BROUGHTON, JR.
P.H.BRADY
1664 Robert Hooke proposed invention of artificial fibers better than silk.
1845 Schoenbien invents nitrocellulose.
1855 Audemars invents process for making nitrocellulose fiber.
1868 Hyatt develops plasticized cellulose nitrate (celluloid).
1884 Chardonnet produces first regenerated cellulose.
1889 Chardonnet displays first textiles from regenerated cellulose.
1890 Despeisses invents the cuprammonium process.
1892 Cross, Bevan, and Beadle patent the viscose process chemistry.
1893 Libby produces glass fiber.
1898 Steam and Thpham make the viscose process work to produce fibers.
1907 Production of cellulose acetate "dope"
1919 Henri and Camille Dreyfus begin production of acetate fiber.
1929 Carothers produces high molecular weight polymers for DuPont.
1930 Polystyrene commercialized by I. G. Farben!Dow.
1936 Poly(methyl methacrylate) (PMMA) commercialized by Rohm & Haas.
1937 Vinyon (PVC) fibers produced by American Viscose Corporation.
1938 Carothers develops Nylon 66.
1940 Saran invented by Dow Chemical.
1941 Low density poly(ethylene) developed.
1946 Polyester fiber first produced by DuPont and ICI (Polyester is invented by Wheet-
field and Pickinson).
1948 Acrylic fiber commercialized by DuPont.
1954 Isotactic poly(propylene) process invented.
1955 High density poly(ethylene) process invented.
1966 Poly(p-benzamide) developed.
1968 Poly(p-phenylene terephthalarnide) (Kevlm4) commercialized.
1979 Stamylan UH~ patented.
58
3.1 Manufacture ofMan-Made Fibers 59
hopper for
polymer chip
spin pump
barrel filter pack
extruder (heated)
screw
quenching
(cool air)
finish
appication
godets
winder
FIGURE 3.1 Schematic of melt spinning process.
terns filter the polymer before it passes through flow rate variations will show up as variations in
the fine holes of the spinnerette (Figure 3. 2). If linear density along the filaments and sub-
not filtered out, particulate or gelatinous im- sequently along the yam or tow.
purities in the polymer can produce two un- As filaments emerge from the spinnerette,
desirable effects. The impurities may be large they are accelerated away from the outlet,
enough to block or restrict flow through the stretching the polymer before it cools. The
spinnerette holes. The second, and equally dis- stretched, semi-molten filaments are then cooled
astrous effect would involve the passing of the by a transverse air stream. The speed and
impurity through the spinnerette, allowing it to temperature of the air stream are controlled to
be incorporated into the fiber structure. Inclusion help ensure uniformity along the filament. Ther-
of an impurity creates a discontinuity in the struc- moplastic filaments may be stretched up to 100
ture which may promote breakage of the fila- (typically at least 25) times their original length
ments during the subsequent manufacturing before solidification. One to ten meters below the
processes. This is a particular problem with spin- spinnerette (after solidification), the filaments
nerettes for non-circular fibers. Added benefits
of the filter or screen before the spinnerette in
plastic fiber spinning, are that the mixing action
helps to reduce non-uniformities (temperature
and viscosity) in the melt as well as removing
what is referred to as screw memory. Screw
memory is caused by the long chain polymers
being twist oriented by the screw rotation. Most
extrusion systems also use static mixers in-line
before the spinnerette to ensure that the polymer
melt is uniform in temperature and viscosity.
The spin pump is a positive displacement gear
pump and provides a constant flow rate of
polymer through the spinnerette. Typically one
pump is paired with only one spinnerette. Any FIGURE 3.2 An extrusion spinnerette.
60 FIBER AND YARN MANUFACTURING
are brought together, passed around a series of The design of spinnerettes and spinnerette
godets, and then wound onto a yarn package. As packs is critical, because the process depends
the filaments are brought together before the upon a hydraulic split to ensure delivery of the
godets, a lubricating spin finish is applied. The same volume of polymer to each spinnerette
finish is applied by passing the filaments over a hole. Subtle differences in flow paths can create
hard surface coated with the desired fluid. The major differences between filaments.
yarn collects a small amount ofliquid as it passes Most melt extruded fibers are further pro-
through the liquid film on the coated surface. The cessed by drawing (sometimes referred to as cold
surface may either be a kiss roll, which rotates drawing). Drawing of fibers is a stretching
through the finish and just touches the yarn, or a process which increases the strength of the fiber
thread guide with the finish pumped through a by increasing the orientation of the polymer
hole in the guide. molecules to the parallel axis of the fiber. Draw-
The godets positioned just below the finish ing in the solid state is much more effective at
applicator set the speed at which the fiber is producing orientation of molecules than the
produced. The take-up speed of the godets, in stretching occurring in the molten state during
concert with the extrusion pump, controls the extrusion. Drawing of a yarn must be done at a
diameter of the filaments. If a series of heated temperature above the glass transition tempera-
godets operating at slightly differing speeds are ture (T8 ), and below the melting temperature
used, then drawing of the filaments takes place (Tm). If heat is needed to allow stretch orienta-
which increases polymer orientation, and tion, it may be supplied by heated godets, surface
thereby improves filament strength. Uniform heaters, steam, or in some cases, by the stretch-
speed of the godets is critical to the filament ing process itself. The process of drawing can
uniformity. Package winders which operate in reduce elongation from several hundred percent
concert with the godet system, run at or just of the undrawn original length, to as little as 10
above the speed of the godet. The speed of the to 50%. Drawing is physically accomplished by
winder determines the tension in the thread line the strain created by two godets (or pairs of
between the godet and winder. Slight tension is godets) operating at different preset speeds. The
required for uniform yarn package formation. continuous filament yarn from the extruder is
The control systems of some winders regulate wrapped around the first pair of godet rollers
their speed with such accuracy that the need for running at the lower speed, and is then wrapped
godets may be eliminated. around the faster, second godet pair as shown in
The ratio between the weight of polymer Figure 3.3. Figure 3.4 depicts one model of the
pumped through the spinnerette and the godet (or molecular processes occurring during drawing.
winder) speed determines the linear density of Figures 3.5 and 3.6 show the processes as they
the extruded filament. If a pump delivers 15 occur in filaments and films.
grams of polymer per minute, and the filament is Recent technological advances in extrusion
taken up at 1,000 meters per minute, the linear allow for the combination of the spinning and
density of the yarn produced is drawing processes. This is accomplished by
placing a second set of godet rolls between the
(15 g)/(1 ,000 m) = 15 tex (3 .1) spinnerette and the winder. For the purpose of
speed synchronization, the spinning must usually
or
be slowed, and the winding speed increased to
(15 g)/(1,000 m) x 9 = 135 denier (3.2) greater than 5,000 meters/minute.
Often, a normally flat yarn is crimped or tex-
The definitions of tex and denier are given in tured in order to produce a more interesting
Chapter 18.0. If there are 30 holes in the spinnerette, woven or knitted fabric texture. The basic
then the average linear density per filament is premise of the fiber texturing process is the
deformation and heating of the fiber above its
135 denier/30 filaments = 4.5 denier per glass transition temperature, and then allowing it
filament (dpf) (3.3) to cool in the deformed state. Depending on the
undrawn vam
supply ·
Fibrts torm4td
Cracks fonned, tome~ ~lee
ouc of crv«als, mort ttk,
lip &.twist
>
FIGURE 3.4 Schematic model for drawing processes in a crystalline fiber (Peterlin).
61
62 FIBER AND YARN MANUFACTURING
necking region
texturizing process, the yarn produced may have The preceding descriptions of fiber melt spin-
a high degree of stretch and recovery, or it may ning processes have concentrated on the manu-
just simply appear more like a staple yam. Figure facture of filaments. Conversion of continuous
3. 7 depicts both flat and textured yams. Again, ftlaments into yam is covered in Section 3.2.
the technology has changed as improved ef- Continuous ftlament yarns may be twisted, plied
ficiency is sought. Texturing is sometimes com- and/or textured before being used in fabric for-
bined with drawing to create a combination mation processes. Sometimes, the ftlament yarns
draw-texturing process. With the drawing are cut into staple fiber form, and then reas-
process uncoupled from the potentially faster sembled back into a yarn form. In the manufac-
spinning process, producers have found that in- ture of staple fibers, there is no need to maintain
creased spinning speed equates to better perfor- a yam-sized bundle of filaments. The combina-
mance in the draw-texturing process. tion of filament bundles into a large tow allows
A partially oriented yam (POY) produced by certain economies to be realized in manufactur-
spinning with a high take-up speed (3,000- ing. Spinnerettes with more holes can be used,
5,000 meters/minute), may require only 100 to thus requiring fewer pumps, packs and filters for
200% additional stretch during drawing as com- the same volume of production. A large tow
pared to 300 to 500% stretch for normal undrawn containing many ''yarns'' can be drawn on one
yams. Researchers are experimenting with wind- godet frame rather than a separate set for each
ing speeds in excess of 10,000 meters/minute yarn, and no winders are required. The tow is cut
during spinning. At such high speeds, the need into short lengths after it is crimped (textured),
for secondary drawing may be entirely and dropped into a press for baling. The length
eliminated. The molten polymer exiting the spin- of the chopped staple is dependent upon its end
nerette is deformed so quickly and to such a high use. If the staple fibers are to be blended with
degree and then cooled so rapidly that the cotton or wool, they are cut into lengths about the
molecular relaxation processes do not have time same as the fibers with which it will be mixed.
to take effect before the orientation is locked in. The development of crimp in the tow, which is
FIGURE 3.6 Drawing/elongation of a plastic film. FIGURE 3.7 Flat (top) and texturized yarns.
3.1 Manufacture of Man-Made Fibers 63
polymer/solvent
mix tank
spinnerette
liquid fllamen ts
(solution)
pump
finish
godets
winder
3.2 Wet Spinning tion of the original solution volume. The outside
layer of the fiber liquid precipitates first, and as
Wet spinning is required when the polymer's the interior volume decreases with precipitation,
solvents are not sufficiently volatile to permit a wrinkled or crenelated surface may be caused.
rapid evaporation. To wet spin a polymer, the The complications of the involved chemical reac-
polymer is first dissolved by a solvent into solu- tions and shrinking filaments present both
tion form. The solution is extruded into a second problems and opportunities. The process is much
solvent (the spin bath). The first solvent is more difficult to control than melt spinning;
soluble in the spin bath, but the polymer is not. however, the complicated structures which are
When the solvent is solubilized out, or neutral- possible offer great opportunities for the varia-
ized, the polymer structure precipitates or coagu- tion of fiber properties. The makers of viscose
lates into solid form. A schematic of a wet rayon have exploited these opportunities to
spinning process is shown in Figure 3. 9. produce High Wet Modulus (HWM) variants as
The type of solvent used in the spin bath is well as fibers with an inherent crimp.
dependent upon the polarity of the polymer sol- Drawing of fiber to obtain molecular ori-
vent. Water based solutions are preferred over entation and strength is also desirable for wet
organics, and are often used in the spinning bath spun fibers. Unfortunately, many of the poly-
when the polymer solvent is miscible with water. mers which require wet spinning procedures,
Volatile solution solvents may also be removed also lack the mobility in the solid state which
by wet spinning methods even though they could would allow normal drawing to occur. For these
instead be evaporated. Polymers having high materials, any orientation which is obtained,
melting points also tend to be difficult to solubil- must occur during the extrusion and coagulation
ize. These polymers are likely to require highly processes.
polar solvents such as mineral acids, or alkali- Most wet spinning procedures have the spin-
metal basic solutions. The polar solvents are nerette submerged below the surface of the
typically extracted from the polymer solution coagulating bath. The rapid coagulation may
either by dilution or neutralization in water. restrict the amount of stretch possible in this type
As with dry spinning, avoiding environmental of spinning process. Certain products are best
problems in wet spinning is critical. The used formed by placing the spinnerette some distance
spin-bath liquid must be recovered or at least above the coagulating bath and attenuating or
treated before release to the environment. stretching the fiber solution as it falls through the
Similar to the fiber formation in dry spinning, air before the coagulation process begins. Such
the precipitated solid occupies only a small frac- a process has been named dry-jet wet spinning.
~ !
from
pump
advancing rolls
coagulating wind up
bath
spinnerette
S.ADANUR
The manufacture of continuous filament yarn residual rupture elongation. Excessive elonga-
is a relatively simple matter of collecting the tion at the beginning or end of the yarn package
number of individual filaments necessary to can result in fabrics with visually obvious
produce the desired yarn size. As manufactured defects. Staple yarns, being less uniform, can
by the fiber producing companies, they are called afford more irregularities, without the danger of
''producer's yarns:' They contain minimum the resulting fabrics being considered '' defec-
twist, ranging from about zero to 2.5 turns per tive:'
inch, which is just sufficient to maintain the
yarn' s integrity. 1. THROWING AND TWISTING
Most producer's yarn is delivered with a thin
resinous finish or size which protects the fila- There are so many different filament yarn
ments from damage due to abrasion and snag- constructions required by textile mills that it is
ging. The fmish, amounting usually to less than quite impossible for the man-made fiber manu-
one percent by weight, may or may not be water facturer to have all of them available, or make
soluble. Such finishes should not be confused them on order. Instead the fiber producer sells
with water soluble sizes such as starch, gelatin, several popular sizes, packaged usually on a
or synthetic resins, which are applied to warp standard spool. The textile mill must then ar-
yarns at the mill to give additional protection range to have the producer's yarn converted into
during weaving. Sometimes a light lubricant is the desired yarn of proper weight, twist and ply,
also applied to the yarn by the producer or the properly sized, lubricated, and packaged for sub-
mill. This improves running quality by reducing sequent mill operations. These procedures are
static and friction, and reduces abrasion of the collectively called "throwing." Throwing may
yarn and wear on the textile machinery guides, be carried out by the mill which will ultimately
rollers, etc. weave or otherwise use the yarn, or by a com-
Because of filament uniformity and the com- mission'' throwster:' The term usually applies to
plete absence of protruding fiber ends, con- the preparation of relatively lightweight yarns,
tinuous filament yarns are particularly smooth in contrast to ''twisting' ' which pertains to the
and lustrous. Such properties are advantageous preparation of heavier yarn constructions. More
in the manufacture of many fabrics, but a high recently, the term also applies to a company that
degree of filament and yarn uniformity is neces- specializes in texturing yarns.
sary. Even minor irregularities will be observed It is usually impractical to make a heavy yarn
as fabric defects due to changes in luster, dye by twisting many units or ends of producer's yarn
pickup, irregular yarn twist or yarn spacing. together in the same direction. Such a yarn would
Producers must always be on the alert to insure be soft, bulky, unstable, and might have low
yarn uniformity, both within a package and strength. Instead, plied yarns are constructed.
among packages. Any differences in the amount Several turns of twist are inserted in one direction
that the yarn is drawn during manufacture will be into the singles producer's yarn, and then several
manifested as differences in optical and physical of these are twisted together, usually in the op-
properties, for example, dye absorption and posite direction, to make the plied yarn. Several
66
3. 2 Manufacture of Continuous Filament fums 67
plied yarns can then be twisted together to form of making filament yams more spun-like in char-
a cord. By properly designing the twist relation- acter is to insert into them a multiplicity of ran-
ships among singles, ply, and cord, large size dom permanent bends, loops, or crimps.
stable and balanced yarns, cords and ropes can Texturing produces yarns (and fabrics) which are
be manufactured. The twist relationships are dis- less smooth and uniform than conventional fila-
cussed in Chapter 18.0. The two common ments, but which are soft, lofty, dull, stretchy,
methods for twisting are called ''uptwisting'' warmer, and generally approach the look and feel
and '' downtwisting .'' Downtwisters operate on of spun fabrics.
the ring traveler basis, the name being derived There are several methods of texturing yams
from the fact that the input yarns are placed above including air-jet, edge-crimping, false-twist,
the twisting unit. They feed down to the twister gear crimping, knit-de-knit and stuffer box
bobbin where, via the ring and traveler, they are methods.
twisted and wound up. The number of turns per Most bulk or textured yams can be extended
inch inserted is a function of the traveler velocity or stretched because of the incorporation of so
and the feed roll speed. The uptwister utilizes a much geometric elongation, recovery occurring
vertical bobbin on a spindle which rotates at high when the extending force is removed. This
speed. The yarn is drawn up over the end of the geometric elongation is independent of any in-
bobbin at a constant rate, and is wound upon a trinsic elongation resulting from the stretching of
take-up bobbin. The ratio of spindle speed to the fiber substance per se. Except for isolated
windup speed determines the number of turns per cases, textured yarns are used entirely for ap-
inch inserted. parel rather than industrial purposes.
fiber producer normally heat treats and me- 300°F. This sets and balances the twist in the
chanically draws the fiber to convert it from a plied thread structure, makes it heat stable, and
weak, heavy, amorphous filament into a strong, in addition produces greater strength per weight
tough, textile filament. A heat treating and and lower rupture elongation-desirable prop-
drawing procedure is selected which will permit erties in most sewing thread. By proper manip-
the subsequent yam or fabric manufacturer ulation of temperature, tension, strain (elonga-
further to heat treat and tension his product to tion), and relaxation, the manufacturer can, with
attain thermal stability. In the manufacture of a certain limits, incorporate desired strength,
3-ply nylon thread, for example, after plying, the elongation, and thermal shrinkage properties in
thread is hot stretched at a temperature of about the hot stretched yam.
3.3
Manufacture of Staple Yarns
Y. E. EL-MOGAHZY
In order to convert the bulk of fibers repre- Blending of fibers is done for technological
sented by a fiber bale (about 50 billion fibers) and/or economical reasons. The main tech-
into a long thin yarn (typically, 100 fibers/cross nological reason is to produce a yarn of specific
section), a number of preparatory processes are characteristics. In some cases, two fiber types
used. These processes are listed in Table 3.3. are blended with one of them placed on the yam
Some of these processes are mandatory in all surface while the other is largely presented in the
yarn making operations and others may be yarn core. The advantage of this arrangement is
needed depending on the type of fibers to be to produce a yarn of different surface and core
spun, yam count, and the spinning system uti- characteristics. For example, when cotton fibers
lized. are on the surface while polyester fibers are in
the core, a yarn of cotton-like surface hand and
2.1 Blending, Opening, and Cleaning polyester-like strength can be produced. Eco-
nomical objectives of blending include mixing of
The initial process of spinning preparation fiber components of different prices and dif-
involves three main operations: ferent values of quality characteristics to produce
69
70 FIBER AND YARN MANUFACTURING
a yarn of specified price with respect to its ex- of processing (at the opening line) is that the
pected quality. blend produced is more intimate and more
The blending process should produce a homogenous. When dissimilar fibers are blended
uniform fiber flow throughout the spinning line. (e.g., cotton and polyester), the opening and
Perfect blending may be defined as a condition cleaning equipment for each type of fiber should
in which every fiber characteristic is found in the be different in type and/ or settings. While natural
same proportion within every Wlit cross section fibers require a great deal of cleaning, man-made
of the yarn. Several problems occurring during fibers require no cleaning. Since blending equip-
manufacturing are results of improper blending ment involves opening and cleaning elements,
of the fed fibers. Blending is, therefore, con- settings and speeds of these elements must be
sidered to be the most critical stage of processing selected properly to produce an intimate blend of
in staple yarn manufacturing. the two fiber types while preserving the unique
In practice, there are two types of blending: characteristics of each type.
(1) blending of nominally similar or dissimilar The advantage of draw blending is better con-
components of the same type of fibers, and (2) trol of the proportions of different fiber types in
blending of different types of fibers (e.g., cotton the blend determined by the sliver weight and the
and polyester). The first type of blending is nor- number of slivers of each fiber type. However,
mally achieved at the initial stage of processing the parallel alignment of the fiber strands of each
where bales of the same type of fiber (e.g., fiber type throughout the drawing process
cotton) but of dissimilar fiber properties are ar- produces a less intimate blend than that of the
ranged in a bale laydown and more or less equal initial stage.
proportions of fibers are taken off from each bale Some of the effects that should be taken into
and transported into a blending reservoir. Blend- consideration during blending are as follows:
ing of different types of fibers may be achieved
in the initial stage of processing to provide in- • Finer yarns appear less intimate or more
timate blending or later in the drawing process streaky than coarser yarns with the same
(draw blending) where slivers of the two types of fiber content and blend ratio. This is due
fibers are drawn together. to the fact that in finer yarns, fewer
The advantage of blending in the early stage number of fibers per cross section are
3. 3 Manufacture of Staple Yams 71
used which exaggerate the the circumference speed of the opening roll, and
non-uniformity or irregularity. the number of different working elements (teeth
• For a given yarn count, coarse fibers or pins) per unit area.
lead to more streaky yarns than fine Details on effects of these factors vary depend-
fibers, again, due to the fact that with ing on the type of machinery utilized. Neverthe-
fine fibers, more fibers per cross section less, each yarn manufacturer in conjunction with
can be utilized leading to a better machinery makers should evaluate opening per-
doubling effect. formance through developing relationships be-
• At similar conditions and for the same tween tuft size and the factors mentioned above.
types of fibers, an unbalanced blend
(e.g., 70/30) will appear to be more 2.4 Cleaning
streaky than a balanced blend (e.g.,
50/50). Cleaning is mainly required for natural fibers.
• Blending of equal proportions of fibers Cleaning may be achieved using mechanical or
of different color does not result in an chemical means depending on the type of natural
intermediate color but rather a color fibers. When natural fibers are to be blended with
which is more biased to the darker synthetic fibers, their cleaning should be per-
component in the blend. formed prior to the blending process with those
• Optimum or intimate blending occurs fibers.
when the number of doubling after Cotton fibers brought to the mill may contain
blending exceeds the number of fibers several types of foreign matter. These include:
per yam cross section. (1) sand, soil and dust which are easy to remove
• Fabrics made from blends of different because of their density and shape, (2) seed coat
fiber types are unlikely to be superior in fragments, bark, and grass fragments; these are
any one property to fabrics produced often difficult to remove during textile process-
from an individual fiber type, but fiber ing. In general, large particles or those of high
blending does enable fabrics to be density can be effectively removed in the open-
produced with combinations of ing and cleaning process. On the other hand,
properties which would be unattainable small particles are extremely difficult to remove
by using only one fiber type. and they are often observed in the final spinning
process. The International Textile Manufac-
2.3 Opening turers Federation (ITMF) has defined cotton
trash and dust in terms of the particle size as
The objective of opening is to divide the tightly follows:
packed fiber assembly into small fiber tufts.
Opening is normally achieved using mechanical Trash >500 p.m (2/lOOth inch)
means in which conveyor lattice or rollers Dust <500 p.m
covered by metallic wires act against the fiber Fine Dust <50 p.m (2/l,OOOth inch)
mass for separation into small tufts. Microdust < 15 p.m (6/lO,OOOth inch)
Opening equipment may range from mild to
fine openers depending on the type of fibers used Cotton trash particles are typically removed
and the density of the input fiber mass (the tuft using mechanical means. The cleaning process
size). In general, as the number of fibers of a begins in the ginning process where fibers are
given mass increases, the number of opening separated from the seeds. Normally, two passes
points (the wire density) should increase. The of lint cleaning are used after ginning to remove
effectiveness of an opening unit should be trash. Cleaning is then continued in the textile
measured by the tuft size produced from this unit. process in the opening and cleaning line. The
In principle, the opening process should provide final stage of cleaning is the carding process.
a gradual reduction in tuft size. Theoretically, the Raw wool fibers also contain a great deal of
tuft size (g/tuft) is a function of the throughput, impurities. These include:
72 FIBER AND YARN MANUFACTURING
(1) Natural impurities, produced by the sheep parameters associated with card slivers are the
itself; these include wool grease, dried sweat sliver weight (grains per yard) and the sliver
and the excretion stains caused by dung and irregularity. The sliver weight is determined by
urine in the breech area the amount of mechanical draft (the ratio be-
(2) Acquired impurities such as those picked up tween the delivery speed and the feeding speed).
by the sheep from its habitat; these include Variation in sliver weight may result from im-
minerals such as sand, dust, soil, and lime; proper machine settings, improper autolevelling
vegetable matter such as burrs, and grass; (fiber control), or inherent variability in fiber
and animal impurities such as insect mass. Irregularity in card sliver can be measured
parasites, and pests by using on-line or off-line evenness monitoring
equipment.
Wool fibers are normally cleaned using both
chemical and mechanical means. Wool grease
may be removed by emulsion scouring or by 2.6 Drawing
organic solvents. Most of the mineral impurity is
attached to the fibers by wool grease and so is The main objective of the drawing process is
released when the grease is removed. Mechani- to improve fiber orientation by aligning the fibers
cal cleaning is used to remove vegetable im- in one direction. Drawing may also be used for
purities. Typically, they are removed during blending slivers of cottons and other synthetic
carding or combing (in the worsted system). fiber slivers (draw blending). The working prin-
Vegetable impurities may also be removed by ciple of this process is based on sliding fibers
carbonizing. This process is commonly used in over one another without elongating or stretch-
woolen processing, and occasionally in worsted ing them. The drawing (or drafting as it is com-
processing. monly called) is gradually achieved by feeding
several card slivers (six or eight slivers) to a
series of drafting rollers. The ratio between the
2.5 Carding delivery roller speed and the feed roller speed
determines the amount of draft or the draft ratio,
The objective of the carding process is to consequently, the size of the output sliver.
further open and clean the fibers delivered from The purpose of feeding several slivers to the
the opening and cleaning line. Fibers undergo a drawing process is to improve the uniformity of
series of dividing and redividing actions using a the output sliver (by applying a "doubling" ef-
large number of pins in an attempt to separate fect) and to enhance fiber blending. Doubling is
each fiber from its neighbors and form a fluffy defined by the number of slivers fed together to
but coherent mass (fiber web). The idea is to the drafting system. For example, if six slivers
facilitate further fiber manipulation and ease are fed to the drafting system, the doubling value
removal of impurities. The critical importance of will be 6. If another drawing pass in which six of
carding lies in the fact that it may represent the the slivers produced from the first pass is util-
last process of cleaning in the spinning line (ad- ized, the total doubling value will be 6 x 6 = 36,
ditional cleaning is achieved if combing is used). and so on. The drawing process reduces the size
After this process, unremoved trash or foreign ofthe fed slivers (collectively) down to the size
matter is likely to adhere to the fibers down the of a single sliver by the amount of draft utilized.
chain of processing. Fiber quality has a great impact on the drawing
The carding process removes a great deal of process and the drawn sliver. Fiber character-
trash, short fibers, and neps. Accordingly, it is istics related to drafting include fiber length,
evaluated using three criteria: (1) the extent of fiber fineness, and fiber cohesion. Brief discus-
fiber damage, (2) the cleaning efficiency, and (3) sions on the effects of these characteristics are
the amount ofneps in output fibers. given below.
The output fiber strand from the carding The draft settings or the distance between dif-
process is called the card sliver. Quality-related ferent pairs of drafting rollers is determined by
3. 3 Manufacture of Staple lilms 73
the staple length. The rule of thumb is that these recent years, combed yams have been produced
settings should not be too wide (longer than the on open-end (rotor) spinning. This new develop-
staple length) to avoid floating fibers or fibers ment has been a result of the continuous strive to
flowing at undetermined speeds. The presence of produce fine yams on open-end spinning. Both
floating fibers is one of the primary causes of trash content and short fiber content represent
sliver irregularity. On the other hand, draft set- obstacles against the production of fme yams on
tings should not be too tight (shorter than. the rotor spinning. Removal of these problems by
staple length) to avoid stretching of fibers and the combing process was found to improve both
fiber breakage. the spinning limit and the quality of rotor yarns.
The effect of fiber fineness on the quality of The combing process is usually preceded by a
drawn sliver lies in the fact that high variability lap forming process in which the drawn sliver is
in fiber fineness is likely to result in a high weight converted into a large roll of fiber lap which is a
variation of the sliver. High variation in fiber flat sheet of fibers. A series of laps is then fed to
fineness is often attributed to improper mixing of the comber in an intermittent fashion. The laps
fibers. When a mix of very fine and very coarse are advanced and then gripped so that fringe of
fibers is presented to the drafting process, poten- fibers is presented to the combing cylinder
tial problems resulting from uncontrolled cling- (toothed half roll) which combs the fibers and
ing forces would be expected. removes short fibers. The output product of the
Since drafting is based on sliding fibers over combing process is called combed sliver.
one another, it is desirable that the fiber strand
has low resistance to the drafting force. Very fine
or very long fibers are likely to increase fiber 2.8 Roving
cohesion; gradual drafting usually assists in
overcoming the high cohesion resulting from the The roving process prepares the drawn sliver
presence of fibers of such extreme charac- for the ring spinning process by converting it into
teristics. Different fibers may also have different an intermediate strand called roving. It involves
surface characteristics which result in variation drafting down to about one cotton count through
in fiber cohesion. This problem is often en- a set of drafting rolls. The produced strand is then
countered in cotton/synthetic blending. slightly twisted to permit winding it on the roving
bobbin.
2.7 Combing
3. SPINNING
The combing process is used to produce a
smoother, finer, stronger, and more uniform yam The spinning process is the final stage of staple
than otherwise would be possible. Combing is, yarn manufacturing. It is the final opportunity for
therefore, confined to high grade, long staple a fiber to interact with the machine. In the spin-
natural fibers. Basic objectives of combing are: ning process, the goodness of fiber preparation
through the different preceding processes can
• reduction in short fiber content
easily be evaluated. A failure in spinning is often
• removal of trash and neps
a result of a default in the preparatory process.
• production of more straight, parallel, and
There are different spinning techniques avail-
uniform sliver
able in today' s technology. Each technique is
In general, combing is used for high quality unique in its principle and in its requirements of
fine ring spun yams. The high quality of combed fiber quality. New spinning techniques involve
yarn is the primary justification for the addition high drafting where the input fiber strand (the
of this process to the spinning line and its as- drawn sliver) is separated, partially or fully, into
sociated cost. Combing may be required for cot- approximately single fibers, flown in an air
ton when it is draw blended with synthetic fibers. stream, and reconsolidated to form the yarn.
This is particularly true for air-jet spinning. In These techniques are, therefore, highly sensitive
74 FIBER AND YARN MANUFACTURING
to fiber quality, and to the presence of fine trash yarn on a package (bobbin or a cone), and build-
and dust. ing the yarn along the length of the package.
Proper yarn winding is extremely important par-
ticularly in weaving preparation. Yarn tension
3.1 The Principles of Spinning should be uniform and the appearance of the
package is a critical factor.
In any spinning method, three main mech-
anisms should be used to convert fibers into a
yarn (Figure 3.10). These mechanisms are 3.2 Classification of Spinning
Techniques
• drafting mechanism
• fiber coherence mechanism There are four major spinning technologies:
• winding mechanism
• ring spinning
The drafting mechanism works on the same • rotor spinning (open-end spinning)
principle as the drawing process: sliding fibers • air-jet spinning
over one another without elongating or stretch- • friction spinning
ing them. The objective of drafting in the spin-
ning process is to reduce the size of the fiber These spinning techniques may be classified
strand down to the desirable size of yarn. in many different ways. In principle, spinning
The fiber coherence mechanism produces techniques may be divided into two main
cohesive forces to hold the fibers together in the categories (Figure 3.11):
yarn by introducing interfiber three-dimensional (1) Continuous spinning
crosslinking. In any spinning system, the co-
(2) Interrupted spinning
herence mechanism is responsible for providing
yarn strength. In continuous spinning, the fiber flow is con-
The winding mechanism involves winding of tinuous from the feeding point to the delivery
point; and fibers are under a full mechanical 3.3 Ring Spinning
control. The conventional ring spinning is a con-
tinuous spinning process. In interrupted spin- Ring spinning is characterized by the con-
ning, fibers undergo a complete or partial tinuity in the fiber strand from roving (the input
separation (rotor, and air-jet spinning, respec- strand) to yarn. The input fiber strand is drafted
tively) before they are reconsolidated into a yarn. using roller-drafting to reduce its size down to
The primary reason for the interruption in fiber the desirable yarn count. The fibers being
flow is to allow separation of the fiber coherence delivered at the nip of the front roller form a
mechanism and the winding mechanism. This triangle called the spinning triangle (Figure
separation results in producing larger yam pack- 3.12). The bottom end of this triangle represents
ages, increasing production, and introducing the twisting point or the point at which twisting
strength at minimum energy consumption. Thble begins. In the spinning triangle, different fibers
3.4 shows comparison of the spinning methods. have different tensions depending on their posi-
Figure 4.21, Chapter 4.0, shows structures of tion in the triangle. Fibers in the center of the
yarns, with equal count, produced with different triangle are usually slack and those in the outer
yarn spinning methods. layers are under maximum tension. When fibers
Drafting
Spinning
lrlangle
PigtaU
1\vlstlng
&
Winding
are released from the nip of the front roller, those this is the increase in the cohesion of fibers as the
exhibiting high tension tend to move toward the twist is increased. This effect holds only up to a
center displacing the initially central fibers to the certain point beyond which further increase in
outer layers. This phenomenon is called fiber twist causes the yarn to become weaker. This
migration. The effect of fiber migration is to results from a decrease in the effective contribu-
enhance fiber crosslinking, and consequently tions to the axial loading of the yarn due to fiber
yarn strength. obliquity. Thus, there is a point of twist at which
The coherence mechanism in ring spinning is yarn strength is at its maximum value. This point
twisting. Twist is inserted to the fibers by a is known as the optimum twist.
traveler rotating around a ring. Winding is made The amount of twist is determined by the ratio
simultaneously with twisting. For each full turn between the traveler rotational speed (or the rota-
of twist, the yarn package must make a full turn tional speed of the spindle carrying the bobbin)
around its axis. Thus, yarn strength is a result of and the delivery speed. Since spindle speed is
twisting, and fiber migration. normally constant, an increase in twist would
mean a reduction in delivery speed, conse-
quently, a reduction in production. This point
Strength-Twist Relationship emphasizes the importance of selecting fiber
characteristics that permit lower optimum twist
The effect of twist on yarn strength is il- (twist at maximum strength). Generally, the use
lustrated in Figure 3.13. Initially, as the twist of longer, finer and stronger fibers permits the
level (number of turns per unit length) increases, use of lower optimum twist (Figure 3.14).
yarn strength will also increase. The reason for The main limitation in ring spinning is the low
1 @) .' ' ---
:l
1::- /
~,t / /
.p (Jo
1
~
"'
~
~
'
------- -···------
Optimum Twist Factor
1\Nist
---
"Fine Fibers"
"Long Fibers"
"Strong Fibers•
-
J [
"Coarse Fibers"
'Short Fibers"
'Weak Fibers"
c
0
u
:::1
'tl
I
Max. E
Strength - D.
Production
(yds/min.)
Twist Level
77
78 FIBER AND YARN MANUFACTURING
production rate resulting from having to rotate 20,000 fibers in its cross section. Before this
the yarn package to simultaneously introduce number of fibers is reduced to a value of about
twist and wind the yarn. The yarn bobbin is of a 100 fibers per cross section in the yarn, it must
small size because of the geometrical limitation first be reduced to as low as two fibers (draft ratio
of ring spinning (the ring size). One solution to of 10,000: 1) to initiate the interruption or the
these limitations is to separate the coherence discontinuity in fiber flux. This immense reduc-
mechanism from the winding mechanism. This tion requires high speed mechanical drafting sup-
approach represents the underlying concept of ported by air drafting (Figure 3 .15). The me-
the new spinning techniques. chanical drafting is achieved using a toothed
opening roll. This opening roll also allows
3.4 Rotor Spinning (Open-End, removal of trash in the input sliver. Upon draft-
OE, Spinning) ing the strand down to about two fibers, conden-
sation of fibers back to the desired number of
In rotor spinning, the drafting mechanism con- fibers per yarn cross section is achieved on the
sists of three different zones: inside wall of the rotating rotor.
The coherence mechanism in rotor spinning is
(1) Mechanical drafting using an opening roll achieved by twist insertion resulting from the
(2) Air drafting using an air stream and trans- high speed rotation of the rotor. The amount of
porting duct twist is determined by the ratio between the rotor
(3) Condensation mechanism speed and the yarn delivery speed. The lack of
tension differential similar to that in ring spin-
The use of a fiber sliver requires a large ning yields no significant fiber migration. In
amount of draft to reduce its size down to that of addition, the lack of full mechanical control,
the yarn size. A sliver may have more than resulting from the creation of an open end, leads
Condensauon
Air-Draft
&lWisUng ·
to less fiber orientation and a yam structure twisting takes place. Thus, with one air nozzle,
consisting of a core that is fully twisted (similar a case of false twisting would be achieved.
to ring spun yarns), and an outer layer that is A second nozzle, a, is positioned between the
partially twisted (Figure 4.21, Chapter 4.0). nip of the front roller and nozzle b, with air
Another disturbing structural feature of rotor rotating in a counterclockwise direction. Now,
yarns is the presence of fiber belly bands (bridg- we have two nozzles applying air rotation in two
ing or belt fibers). These fibers result from the opposite directions. Nozzle b normally has a
interfacing between the processes of laying higher rotational speed than nozzle a to avoid
fibers on the rotor collecting surface and the complete false twist. Thus, the opposite rotation
peeling of the yarn from the collecting surface. of air in nozzle a assists in detaching some fibers
This interface occurs once per rotor revolution. from the input strand. In other words, fibers are
Fiber belly bands are laid at these times. They do partially separated at this point.
not contribute significantly to the coherence of The coherence mechanism involves two main
rotor yams, and they result in clear departure of actions: (1) false twist action, and (2) end open-
rotor yarn structure from that of the conventional ing action. The idea is to transmit the twist in-
ring yam structure. serted by air rotation in nozzle b to the fibers at
The condensation action, on the other hand, the nip of the front roller, and to detach some
resembles a doubling effect of several fibers fibers from the twisted strand by the rotation of
which enhances the uniformity of rotor spun air in nozzle a in the opposite direction. This end
yarns. This is one of the reasons that rotor spun opening action takes place at the moment nozzle
yam exhibits better uniformity than comparable b twist is imparted. As the strand passes through
ring spun yarns. nozzle b, it will consist of detached fibers (outer
The winding mechanism in rotor-spinning is layer) and truly twisted fibers (the core). When
separated from the other two mechanisms. The the fiber strand exits nozzle b, the twisted core
yam package is no longer the rotating twisting will immediateI y tend to untwist and the detached
element as in ring spinning. The rotating twisting fibers will wrap around the core fibers. The net
element is the rotor which is of much smaller size coherence in air-jet spun yam is introduced by
than the yarn bobbin. This allows much higher the wrapping fibers resulting from the end open-
speed in rotor spinning than in ring spinning ing action. Accordingly, yam strength is mainly
(Table 3.4), and consequently higher production. a result of a wrapping effect rather than a twist
Furthermore, there is no limitation on the size of effect.
yarn package; this eliminates further winding of Since only a portion of fibers is detached from
yarn in the weaving preparation. Figure 3.16 the fiber strand, interruption in fiber flow in
shows a rotor spinning machine. air-jet spinning is of a different nature than that
of rotor spinning. Both systems are similar in the
3.5 Air-Jet Spinning principle of winding mechanism; i.e., complete
separation from the coherence mechanism which
Air-jet spinning utilizes high roller-drafting to allows large yarn package. The rotating part in
reduce the size of the input sliver down to the air-jet spinning is air. This allows much higher
desired yarn size (Figure 3.17). The coherence rotational speed than that of the rotor. Conse-
mechanism in air-jet spinning is quite unique. It quently, the production rate of air-jet spinning is
is achieved by blowing out compressed air higher than that of rotor spinning.
through air nozzle holes of about 0.4 mm
diameter to form an air vortex. The air revolves 3.6 Friction Spinning
at high speed (more than 3 million rpm).
To simplify the principle of the coherence As in the case of rotor spinning, friction spin-
mechanism, let us examine the case of only one ning utilizes an opening roll for drafting and
air nozzle (nozzle b). When air rotates in the separating fibers of the input fiber strand (sliver).
clockwise direction, it twists the fibers fed to the After passing the opening roll, fibers are carried
nozzle. When the yam leaves the nozzle, un- to a collecting point between two friction drums
FIGURE 3.16 Rotor (open-end) spinning machine (courtesy of Wellington Sears Company).
/Sliver
Core Rbers
Wrapping
Fibers
Yarn
i1
FIGURE 3.17 Schematic of air-jet spinning.
80
3. 3 Manufacture of Staple lams 81
TABLE 3. 5 Ranking of Fiber Properties According to Their Contribution to the Yarn Quality
for Different Spinning Systems.
Ring Spinning Rotor Spinning Air.Jet Spinning Friction Spinning
by means of air current (Figure 3.18). At this fiber flow by collecting fibers on friction drums
point, the yarn is formed by twisting imparted by prior to making the yarn, a loss of fiber orienta-
the relative rotation between the surface of the tion may be expected. Another factor of disorien-
drums and the yarn end. Thus, the coherence tation results from the landing of fibers at high
mechanism is friction between fibers and the speed on slow moving friction drums. This mode
drum. The rotating element in this case is the of landing immediately prior to twisting makes it
yarn itself. At each turn of the yarn end, the yarn difficult to adjust for fiber disorientation. The
is given one turn of twist. The amount of twist in impact nature of this landing compresses the
friction spinning is determined by the ratio be- fibers against the friction drum which results in
tween the yarn diameter and the drum diameter. a looped yarn structure. Since these loops do not
Consequently, a very high degree of twist may be effectively contribute to the strength of the yarn,
imparted. friction-spun yarns have less strength than com-
Since friction spinning requires interruption of parable rotor spun yarns.
3. 7 Required Fiber Characteristics for tempts have mainly been based on long ex-
Different Spinning Systems perience and understanding of the principle
involved in converting fibers into yams in a
There have been many attempts to establish a particular spinning system. Table 3.5 provides a
ranking of fiber characteristics according to their suggested general ranking of fiber properties
contributions to the quality of yams produced according to their contributions in different
using a particular spinning system. These at- spinning systems.
3.4
References and Review Questions
83
4.0
FABRIC MANUFACTURING
4.1
Classification of Fabrics
R. P. WALKER
S. ADANUR
87
(X)
(X)
111111 ~
(d) warp knit (e) tufted (f) nonwoven
Before forming fabrics that involve the use of parallel sheet of yarns wound onto a
yarns, the yams must undergo various stages of beam or a section beam; used in weaving
preparation. Yams are produced on various types and warp knitting (Figure 4.3)
of packages (bobbins, pims, cones, tubes, etc.) • section warping- winding parallel
and in many cases the yam and/or the package is sections of a yam sheet side by side into
not suitable for further processing. Changing the a wider full sheet; used in weaving
yarn itself or altering the package is often re- • ball warping- combining yams from a
quired before fabric can be produced. The creel into a condensed rope which is
specific preparatory sequence required depends wound as a single strand forming a log-
on the type of fabric being produced. Yam type package called a ball, several of
preparation processes for selected fabric types which are then used in a rope dyeing
are as follows: process; used in weaving typically with
the indigo dyeing process in the
• weaving: winding, warping, slashing, production of denim fabric
drawing-in • heat setting- subjecting many single
• knitting: winding, waxing, steaming, yams to controlled heat conditions to
warping achieve uniform dyeability; used in
• tufting: plying, heat setting, winding or weaving and knitting of thermoplastic
beaming yams and particularly for tufted fabrics
• draw warping- combining the drawing
The processes used to prepare yams for fabric of filament yams with heat setting and
forming vary not only for fabric types, but also warping processes to achieve uniform
for yam types. The more common yarn prepara- stretching and heating for improved dye
tion processes are described below: uniformity, end to end; used for weaving
and knitting of thermoplastic yams
• winding- transferring a yam from one • plying- twisting together two or more
type package to another to combine single yams; used for any system that
smaller packages and clear defects such requires plied yams, most often for
as thick and thin places from the yam industrial woven fabrics and tufted fabrics
(also called spooling); used in one way • waxing-application of lubricant to
or another for all fabric forming types single yams during winding to reduce
(Figure 4.2) frictional forces during further
• quilling- transferring a yam from a processing; used for weft knitting yams
larger package to small quills which are (Figure 4.2)
filling bobbins in a shuttle; used in • conditioning- subjecting yam to
shuttle weaving moisture and heat to offset the liveliness
• warping- transferring many yams from created by twist during yam forming;
a creel of single-end packages forming a used for weft knitting yams
89
90 FABRIC MANUFACTURING
should be noted that variation in a property come critical to good weaving perfor-
is almost always more important than the mance.
average value of that property. (14) A practical understanding of the impor-
(3) Spun yam properties positively affected by tance of size penetration, size encapsula-
slashing are strength (increased though not tion, yam hairiness, residual yam
critically needed), elongation (reduced but elongation, and yam abrasion resistance is
controlled), flexibility (reduced but rea- essential to good slashing practice.
sonably maintained), lubricity (improved), (15) Factors influencing yam hairiness include
hairiness (reduced), and most importantly, hairiness created by the winding process,
abrasion resistance (greatly improved). spinning tensions, location of the yarn on
(4) Modern weaving machines have placed in- the spinning package, yam balloon shape,
creased demands on warp preparation due yarn twist, spindle speed, the yam size
to faster weaving speeds and the use of (count), % synthetics in a blend, end spac-
insertion devices other than the shuttle. ing at slashing, size add-on, slasher creep
(5) The cost to repair a yam failure is much less speed and bottom squeeze roll cover.
if made to occur prior to the weaving (16) Each spot in a warp yam must undergo
process where a yarn failure during produc- several thousand cycles of the various
tion also provides an increased opportunity stresses applied by the weaving machine.
for off-quality. Weaving stresses include dynamic exten-
(6) Often, 80% or more of yarn failures in sion/contraction, rotation (twist/untwist),
weaving will be caused by 20% or less of and clinging of hairs. Additionally, there
the yarns in a warp, called repeater ends. are metal-to-yarn and yam-to-yam flexing
(7) Running the slasher at creep speed which is and metal-to-yam and yam-to-yam
sometimes necessary creates a very un- abrasion stresses.
desirable condition for proper sizing and ( 17) Warp yams closest to the selvages of
should be minimized in every way possible. the fabric undergo more stress due to
(8) Stretch of warp yarns during slashing widthwise contraction of the fabric toward
should be controlled accurately to maintain the center causing linear angular displace-
residual elongation in the yarn which is ment of these outermost yarns. Control of
needed for good weaving. this contraction by the ''temples'' of the
(9) Process studies to determine causes for in- loom is another critical aspect of good
efficiency should be conducted with strict weaving performance (Figure 4.5).
cause analysis techniques by an ex- (18) Warp yams controlled by lifting devices
perienced practitioner and not as part of a closest to the back of the weaving machine
typical stop frequency study for job assign- receive more stress since these yams have
ments. Such studies when combined lead to to be raised and lowered a greater distance
inaccurate data on the causes for stops. to form openings for filling yam insertion
(10) Weaving tensions should be maintained at (Figure 4.6).
minimum levels for best weaving perfor- (19) Spun warp yarns are sometimes stressed
mance. more when they are lowered than when they
(11) The slashing process deals with enhancing are raised during weaving because this
individual warp yam properties not with helps to remove "reed" marks giving the
improving the characteristics of the warp fabric a better appearance (see Figure 4. 7).
sheet. If done improperly, slashing can (20) Spun warps are also timed to interlace the
worsen yarn sheet characteristics. filling yam earlier increasing the force of
(12) Yarn spacing at the slasher size box and on beat-up and increasing the stress on warp
the drying cylinders is very important. yarns to enhance fabric appearance (Figure
(13) Improper splicing and/or knotting can be- 4.8). These extra stresses generally are not
reed
beat-up
warp \Vidth stroke
weaving contraction
FIGURE 4.6 Shed geometry showing A < B < C < D (A: front
harness, D: back).
heddle eye
A B c
tloor
FIGURE 4.7 Raising whip roll makes bottom shed tighter (figure
shows "perfect" shed line, A = B = C).
93
94 FABRIC MANUFACTURING
reed
cloth
FIGURE 4.8 Shed timing, beat-up of interlaced pick (early shed timing).
applied to filament warp yarns since the • check yarn tension controls
uniformity of yam dyeability would be • check static eliminator function
detrimentally affected. • study speed level versus performance
(21) The straightness of individual warp yarns level
and their freedom to act independently as • check beam density (press roll)
they pass through a weaving machine are • check defect scanners and/or counters
important to good weaving performance. • check run-length measurement devices
Yams that are crossed and tangled cannot • check leasing and taping procedures
proceed without excessive stress and yarns • check doffing and handling procedures
that are restricted or influenced by drop- • check housekeeping (especially fan
wire activity, heddle spacing, harness inter- operation)
ference or reed spacing will not weave at • use monitoring system information
top performance. properly
(22) Attention to details in preparation processes • check maintenance schedules and
and in the weaving process should yield procedures
good results. An old rule is that if some • conduct meaningful cause analysis
''perfect'' yam packages can be produced studies
and if some ''good performance'' weaving • establish good operator training
machines can be identified, then these good procedures
practices should be reproducible. A partial
yarn preparation checklist follows: Warp yarn preparation is considered a
• check yarn path conditions (rough "bottleneck" situation in the production of
surfaces, etc.) woven fabric. There are many individual
• check package holder alignment production units in yarn forming and in weaving,
• check package spacing (balloon before and after the preparation processes.
interference) However, there are only a few machines
• check stop motion function involved in preparing warp yarns for the weaving
• check creel to head-end configuration process. If a single production unit is producing
• check beam to head-end alignment bad work in spinning or weaving, the con-
• check braking function (eliminate lost sequence is relatively small. A similar situation
ends) in warp preparation can be disastrous. The key
• check yarn accumulator function word is" consistency," having every warp yarn
• check comb alignment (especially the same as all others. The "chemistry" of
selvages) slashing is discussed in the following section.
4.3
Slashing
D.M.HALL
FIGURE 4.10 Control of yarn hairiness with sizing; top: unsized; middle:
improperly sized; bottom: properly sized.
96
(a)
(b)
97
98 FABRIC MANUFACTURING
FIGURE 4.12 Cornstarch granules (left) and potato starch granules (right).
must be removed from the fabric during the is cornstarch derived from yellow dent corn,
finishing operation. while in Europe, potato starch is employed (Fig-
Along with the film formers, other products ure4.12).
are included as part of the size mixture. One The starch granules are shipped to the plant in
important ingredient that is generally always bulk or in bags. In order to be useful for sizing,
added to the size mix is a lubricant in order to the starch must first be cooked to release the
assist in reducing abrasion; specifically that starch molecules within the granules to form a
resulting from yarn to loom interactions. Some water dispersion. The yarn is passed through the
lubricant products can be especially troublesome hot size solution followed by drying to form a
in later operations such as heat setting or dyeing protective film or coating around the yarn
if they are not completely removed during finish- bundle. This coating will glue down the protrud-
ing. Other ingredients will be added to the size ing fibers and act to protect the yarn bundle from
mixture depending upon the particular loom re- the loom's abrasive forces.
quirements (air-jet, projectile, etc.) or if a par- The starch granules contain two types of chain
ticular finishing requirement is required once the structures. About 25 % of the chains are linear
cloth is woven. These other size additives in- assemblies of glucose molecules (called
clude humectants, antistatic and antifoam amy lose) and the remaining chains are highly
agents, removable tints (for warp or style iden- branched chains (called amylopectin) (Figure
tification), binders, preservatives (if the warps or 4.13). The starch granule is not water soluble.
the cloth is to be stored for long periods of time), Thus, the granules must be cooked at tempera-
penetrating agents (to allow the size to penetrate tures at or near the boil in order to release the
into tightly constructed styles), viscosity mod- compressed chains within the granule into the
ifiers, weighting agents (to make the cloth size solution.
heavier, usually used on loom fmished goods), The monomer or building block of the chain
among others. Thus the size mixture can be quite structure of starch is identical to that of cellulose;
complex. The general rule of thumb is to keep thus, the adhesion of starch films to cotton,
the sizing mixture as simple as possible and only rayon, linen or other cellulosic fibers or blends
add other ingredients when there is a definite containing high levels of these fibers is quite
need for them. good. Figure 4.14 compares the polymer chain
structure of cellulose and starch. These two
2.1 Starch materials differ only in the manner in which the
glucose units of the polymers are attached to each
Starch was the very first film forming material other. Yet, the manner of attachment provides for
which was used as a sizing agent for cellulosic considerable differences in their properties.
fibers. In the United States the starch of choice After the cloth has been woven all of the starch
4. 3 Slashing 99
based size must be completely removed by a ilar to the ones in the mouth) can be used to break
finishing process called desizing. Fabrics con- down the starch chain structure without damag-
taining starch sizes are treated with chemicals ing the cotton cellulose (Figure 4 .15). That is,
that will preferentially break down both the the glucosidic bonds in the cellulose molecule are
linear and branched chains into shorter frag- stable to these reagents but those in the starch
ments which then become soluble in the hot polymer are not. Thus the insoluble chains are
washing step that follows and thus are removed broken down into smaller water soluble frag-
from the fabric. These chemicals employed will ments that can be washed out of the cloth. Both
have a minimal effect on the other fibers of the amylose and amylopectin are broken down in a
fabric. similar fashion with the exception that the
Starch is a food material (carbohydrate). This amylopectin residues may still have some
allows the starch to be broken down in the same branching. Use of these reagents allows the
manner as the starch eaten by animals and bac- desizing process to be accomplished at near room
teria. Thus weak acids (similar in concentration temperature although the desizing reaction can
to that found in the stomach) and enzymes (sim- be accomplished at a faster rate if these processes
Linear Starch-Amylose
Branched Starch-Amylopectin
FIGURE 4.13 The starch granule contains about 25% linear chains (amylose)
and about 75% branched chain (amylopectin).
100 FABRIC MANUFACTURING
;.-t----Cellobiose
.... Unit---..
.
'o
o:~~:
44 :4
' 1
n 0 4
1
0
j
..
'+----Maltose Unit---.-
Note: See insert for locations of hydrogens (H) and Hydroxyls (OH)
FIGURE 4.14 Comparison of the glucosidic chain structures of cellulose ({3) and starch (a).
are done at elevated temperatures. This is the natural product has limitations that must be ac-
prerogative of the finishing plant. cepted if the product is to be employed for sizing.
Starch consists of polymerized sugar (glu- For example, the size films are very sensitive to
cose). Thus, the wastewater contains nutrients weave room moisture levels and require high
having a high Biological Oxygen Demand weave room humidities in order not to dry out
(BOD) which can affect the ecological balance of and lose their flexibility. They are also sensitive
rivers; hence, the water must be treated to to mildew and have other shortcomings.
remove (destroy) these materials prior to being PVA gives size films that are very strong,
released into the nations waterways. This is an abrasion resistant and easily desized in hot water.
added cost of the slashing process. In fact, in some sizing applications the PVA ftlms
may actually be too strong and the ftlms may
2.2 Polyvinyl Alcohol (PVA) need to be modified by the addition of weaker
film forming polymers (including starch) to the
PVA is synthesized from petroleum and is sizing mixture. PVA forms true solutions with
man-made. This allows one to engineer specific water, hence, desizing requires only that the
properties into the molecule. Starch being a polymer redissolves in the hot desize water.
During desizing it is not necessary to degrade the have been developed for specific uses. One size
PVA chains in order to remove the size film, thus that was utilized in high volume years ago is
it is possible to recover the size by one of several carboxymethyl cellulose or CMC (Figure 4.17).
recovery processes for reuse. This is probably This size had high water solubility and
the single most important property of PVA. resolubility, hence, was easily desized as well as
About 10-12 U.S. textile companies are having low BOD-type pollution. It has been lar-
routinely recovering and reusing PVA sizes. gely supplanted as a size by PVA. CMC has since
PVA can be obtained in one of several found many other uses including uses as food
modifications or "grades." It is synthesized additives and in laundry detergents such that the
from polyvinyl acetate. If all of the acetate textile sizing market could not compete because
groups are removed from the vinyl chains after of price considerations except where specific
the polymerization, a PVA grade called ''Fully requirements dictate its use.
Hydrolyzed" (FH) is obtained. Some acetate Another family of sizes based upon poly-
groups can be left on the molecule resulting in a acrylic acid (polyacrylates and polyacryl-
family of'' Partially Hydrolyzed'' (PH) grades. amides), find use in sizing the hydrophobic fibers
The PVA can also be co-polymerized with methyl and their blends such as nylon, acrylics, acetate,
methacrylate among other comonomer groups to polyester and the like. Their advantage, in addi-
give grades of PVA having unique sizing proper- tion to having good binding to these fibers is that
ties and recovery stability. The various reactions they can be made water insoluble during the
are summarized in Figure 4.16. sizing operation which allows them to be used for
water jet weaving applications. During the
2.3 Other Film Formers desize operation the size is resolubilized using an
alkaline desize. If acetate yarns are being sized,
Starch and PVA constitute the bulk of the size a solvent de size may be necessary. The structures
materials used in the United States. Other sizes of the various acrylic-type sizes are given in
-CHz- CH-
I
0
I 0
C:O 0 0 0
I I I I
C=O C:O C=O C=O
I I I I
Cll 3 CH 3 Cll 3 Cll 3
POLYVINYL ACETATE
~
011
011
011
I 011
011 OH 0
011
CJIJ
I
c =0
I
()
Oil
FULLY IIYDROLYZED POLYVINYL ALCOHOL • 98~
I
C:O
I
CJIJ
PARTIALLY IIYDROLYZED POLYVINYL ALCOHOL • 88%
•Carbon and hydrogen atoms on the backbone chain omitted for clarity. (See insets)
Figure 4.18. Other vinyl polymers and copol- sonnel if they are to do an effective job of sizing
ymers are provided in Figure 4.19 while Figure the yarns.
4.20 shows the synthesis and structure for pol- For a ring spun yarn the amount of twist (twist
yester type binders. Table 4.1 compares the prop- per inch, tpi) will affect the ability of the size to
erties of various size materials while Table 4.2 penetrate into the yam for proper anchoring of
compares their BOD contents. the size film. Tightly twisted yarns may require
less viscous size solutions or the use of a penetrat-
ing agent to achieve the proper penetration of the
2.4 Other Factors Affecting Sizing size to effectively anchor it onto the yam sur-
faces. Thus the slashing personnel should be
The size must coat the yams and protect them notified when even small changes in the yarn
during weaving. Yarns can be made by one of specifications are to be made since they will
several spinning methods (air-jet, open-end or invariably affect the sizing process.
ring spinning). The yams produced by these Numerous other factors, including the blend
methods differ considerably in their surface levels of fibers, will influence sizing. Obviously
structure and porosity. Figure 4.21 compares a 50/50 polyester/cotton blend will not have the
yarns spun by the three spinning methods. Ob- same sizing characteristics as a 65/35 blend.
viously, the sizing considerations will be dif- Since the polyester has lighter density than the
ferent for each of these yarns even though they cotton (polyester = 1.38, cotton = 1.52), there
may have the same yarn count. For example, the will actually be more polyester fibers in the yarn
more open and porous surface structure of the bundle in the 50/50 blend and not the same num-
open-end spun yarn will require the size mixture ber of each fiber as the blend level may imply. In
to have a higher viscosity in order to insure that fact the 65/35 polyester/cotton is actually closer
the size penetration into the yarn bundle is not to an 80/20 blend based upon the number of
excessive. Also the diameter of the open-end fibers actually present. Thus the yarn should be
yarn will generally be 10-15% larger than the sized with a size material that has good adhesion
equivalent ring spun yam. This affects the num- to the polyester fibers in order to have the size
ber of yams that can be sized in a single size box film adhere adequately to the surface of the yarn
without undue crowding, the amount of yarn that bundle and not shed off during weaving.
can be placed on a section beam or loom beam Even the shape and diameter of the fibers can
among other considerations. All of the yarn fac- cause changes in the sizing characteristics of the
tors will need to be known by the slashing per- yarn. Smaller fibers actually have more surface
-cH,tH;·
H H H H H H CH • CH •
I I I I I I I 3 I 3
-c- -c- -c- -c- -c- -c- -c- -c-
I I I I I I I I
C=O C=O C=O C=O C=O c C=O C=O
I I I I I Ill I I
OH 0 NH2 0 NH N 0 NH
I I I I I
Na CH 3* CH3• CH3* CH3•
(C) Acrylamide
·Derivatives other than methyl include ethyl, propyl, n-butyl, isobutyl, and
2-ethylhexyl among others
103
.
Pnmary Structure
1-----
I Typical Comonomers used i n - J
Vinyl Acetate Polymerization I
CH3
+ CH2-CH+CH-CH-CH-CH-CH-b-CH
0
I
I
I
C=O
I
I
C=O C=O
I
I
I
I
Cl
I
C=O
I
I
C=O
I
I
OH
C=O OH 0 OH 0 0
I I I I
CH3 @ [B) Lfu.
(a) (b) (c) (d) (e) (f) (g)
H- 0 - (CH2)x - (CH2)y - OH
+ H-0-C ~ C-~H
9~9
Glycol ether
x, y = 1, 2 or 3 S03H or C=O
I
OH
JTAfter Condensation
and Neutralization with NaOH
t 0II 0II
0- (CH,),-0-(CH,)y -0 -C L9rC~O- n'
j
S03 or C=O
I I
Na ONa
104
TABLE 4. 1 Comparison of the Properties of Some Film Forming Sizes.
Moisture Content at
*At70°Fand65% RH.
**Depending upon the degree of hydrolysis.
Starch
Pearl com 500,000
B2 gun (starch dextrins) 610,000
Keofilm No. 40 550,000
Penford Gum 300 (starch ether) 360,000
wheat starch 550,000
Polyvinyl alcohol (PYA) 10,000 to 16,000
Carboxymethyl cellulose (CMC) 30,000
Polyvinyl acetate (PVAc) 10,000
Hydroxyethyl cellulose (HEC) 30,000
Sodium alginate 360,000
Acrylic 205,800
105
FIGURE 4.21 Comparisons of open-end (top), ring spun (middle) and air-jet spun yarns.
106
4.3 Slashing 107
area/fiber than do larger diameter fibers. low enough to allow for good penetration
Trilobal fibers have more surface area than into the fllament bundle.
round fibers. Surface roughness due to high • The size must have good adhesion to the
delusterant content can also affect the amount of particular fllaments being sized.
size picked up by the yarn. Thus changes in the • The sizing agent must be quick drying
shape, denier, and delusterant level of the fibers without delayed set or producing a tacky
used to manufacture the yarn can cause a change surface.
in the size pickup of the yarn. • The size should produce elastic and
One final factor that should be addressed is flexible films that match the elasticity
yarn quality. Excessive hairiness, thick and thin and flexibility to which the yarns are
places and other non-uniformities in the yarn will subjected during weaving.
result in a poorer job of sizing. A well sized • The size should be antistatic or at least
quality warp on the loom is said to be half woven. not contribute toward additional static
buildup.
• Size shedding on the loom resulting in
3. FILAMENT SIZING
buildup on the heddles, reeds or other
loom parts should be avoided, or held to
Multifllament yarns have essentially a con-
a minimum.
tinuous thread line that is as free as possible from
• Size fllm should not be subject to drastic
individual broken fllaments. The yarns are
changes in properties due to the extremes
generally smooth and have a producer applied
of humidity changes. Ideally, the size
finish that protects the yarns against abrasion and
should be brittle when bone dry on the
static during processing. Because of their smooth
slasher in order to achieve a soft break at
and lubricated surfaces, high twist fllaments may
the bust rods and when equilibrated to
not require sizing. The norm however, is low
the weave room conditions the size
twist, thus should a single filament become
should be tough and flexible.
broken it can peel back to initiate a fuzz ball, float
• The size should be easily removable
or skip that will ultimately cause a loom stop.
during desizing.
If the multifilaments were spot welded (glued
• The size should not be detrimental to the
together at multiple points along the yarn length,
yarn, processing equipment or human
a single broken filament could peel or strip back health.
only to the spot weld and stop and not continue
• The size should be easily prepared
to form a loom stoppage.
(mixed) in a short time without the need
At the lease rods when the yam sheet is
for special equipment or costly
separated in the ''dry'' state, the spot welds
preparation controls.
should be weak and brittle for easy separation
• The size properties should not be
without causing any monofllament breaks. But, changed by the producer spin finish oils.
after regaining moisture on the loom beam, the
welds should now be strong and flexible and Table 4.3 shows size considerations for ftla-
possess good multiftlament bundle cohesion so mentyarns.
as to prevent any broken single filament separa- The concentration of the size, which controls
tion on the loom. Size requirements for fllament the number of spot welds, depends on [2]:
yarns are as follows: • yarn denier- Lower deniers have more
• The size solution must be wet out and fiber surface area and require more size.
penetrate the fllament bundle. This may • number of ends/inch- A higher sley
not be an inherent property of the size requires more size.
since this may be achieved through the • type of weave-Plain weaves are more
use of binders and additives such as difficult to weave than those with long
emulsifiers, wetting agents, etc. floats, e.g., satins.
• The viscosity of the size solution must be • the loom type and condition- Some
108 FABRIC MANUFACTURING
Type of Loom
shuttleless looms are more abrasive to A slasher machine and schematic of a typical
the warp. slasher configuration are shown in Figure 4.22.
• type of slasher and drying arrangement The configuration of the slasher can be changed
employed- Each type (conventional, such that each section will be designed to provide
predryer-type, single end beamer) has optimum results for whatever the mill may be
different constraints. running. For example, several types of creel
designs (over and under, stationary, equitension)
4. THE SLASHER are available. The mill can employ multiple size
boxes. The slasher can have a wide variety of dry
The size material is applied to the yams on a can designs for more efficient drying of the
machine called the slasher. The major parts of the yarns. In addition, the slasher will be designed to
slasher are the creel, where the supply of yarns reduce yarn tensions and have electronic read-
on section beams is passed through the size box out indicators of speeds, tensions, temperatures
containing the hot water solution or mixtures of etc.
sizing agents. The yarn picks up the requisite The slasher is a fairly complicated machine
quantity of size solution, any excess being where numerous variables must be controlled for
squeezed off as the yarns pass through squeeze effective and efficient slashing. For example,
rolls. The yarns are then passed into a drying excessive tensions in any of the slashing zones,
section. The wet yarns are preferably predried but more specifically when the yarn is wet can
by using hot air, infrared radiation or the like and cause yam stretch which will reduce the ability
the drying finished on steam heated hot rolls of the yarns to elongate on the slasher. Tempera-
(called drying cylinders). Exiting the drying sec- ture control in the size box is important for
tion, the sheets of yam are stuck together and proper size pickup. Excessive dry can tempera-
must be separated back into their individual ends. tures can cause the size to become overdried and
This is accomplished using bust rods to first brittle. Excessive size pickup or penetration into
separate the individual sheets of yarns from each the yarn bundle will cause the energy of break at
section beam followed by pins to separate the the bust rods to be high and can lead to excessive
yarns within each sheet. The now sized, dried hairiness and even yam breakage. Slasher per-
and separate ends enter the beaming section of sonnel who are skilled in their job are perhaps
the slasher where they are wound onto a loom one of the most important assets of a mill. A
beam ready for weaving. poorly slashed warp that does not weave well,
4. 3 Slashing 109
resulting in numerous loom stops will increase is not to be recovered then the effluent from the
the costs of weaving and could cause an increase finishing plant will contain the size and will
in the seconds produced. require treatment before it can be discharged.
Such factors as ease of removal and the as-
5. FINISHING CONSIDERATIONS sociated costs of de sizing (chemicals to break
down the size into water soluble fractions, the hot
After the size has done its job, it must be water and steam needed to dissolve the size and
removed in the finishing process unless it is a remove it from the cloth, the wastewater treat-
loom finished material such as denim. Remov- ment process to allow it to be discharged) will
ability is perhaps one of the most important differ for each size material. Also to be con-
properties a size material must have. If the size sidered are the other ingredients in the size mix-
drying creel
size
box
beaming
FIGURE 4.22 A slasher machine (courtesy of West Point Foundry) and schematic of a simple slasher configuration.
11 0 FABRIC MANUFACTURING
ture. For example, the type of lubricant em- important that the finishing plant be made aware
ployed will affect the fmishing process since of any changes in the sizing process that could
these materials should be completely removed in result in incomplete or a more expensive
order not to have them interfere with other fmish- finishing process. In this case it is quite necessary
ing and dyeing processes. that the right hand knows what the left hand is
Some sizes are affected by the heat setting doing in order to obtain the best possible
treatment given to the hydrophobic fibers such as finishing process for the woven cloth. It does not
nylon and polyester. This process is usually done make sense to use materials in the slashing
prior to the desizing step in the finishing plant. If process because they seem to save money, then
such sizes are employed, a change in the usual to lose the advantage because of increased
finishing procedures may be required. It is finishing costs.
4.4
Weaving
R. P. WALKER
S.ADANUR
Harness
FIGURE 4.23 Loom elements dealing with warp delivery, filling insertion and fabric removal.
a different weaving pattern. In the case where and repeating on as many as 5,000 picks. Jac-
every end weaves a different pattern a harness quard heads generally are equipped to handle
cord is provided for each heddle. There are three over 1,200 harness cords with patterns repeating
common systems used to provide manipulation on about 5,000 picks and multiple heads can be
to the warp yams; harnesses controlled by cams, employed over a single weaving machine to in-
harnesses controlled by a dobby and harness crease the weave pattern capability.
cords controlled by a jacquard. Cams with weave To control the weave of a fabric, two aspects
pattern profiles rotate to deliver lifting and of the shedding mechanism must be specified.
lowering instructions to harnesses in a cam sys- First, the order of entering in which warp yams
tem which typically can handle weave patterns are threaded or drawn into heddles (or harnesses)
with no more than fourteen different harnesses and second, the order of lifting by which the
and patterns that repeat in no more than ten picks. harnesses are raised and lowered. For the il-
Recent, more modem dobbies and jacquards uti- lustration in Figure 4.24, the most common
lize electronic systems for input of the harness weave pattern, a plain weave, was chosen. The
lifting and lowering patterns. Dobbies can weave warp yams are drawn into the two harnesses in a
patterns requiring up to about thirty harnesses ''harness 1 -harness 2'' order since the plain
harness I
harness 2
weave contains only two different warp yarn another weave, a warp rib, different from either
weaving patterns; those that weave above and of the other two.
those that weave below a given filling yarn. By combining the draw for the filling rib with
These two groups of warp yams swap positions the lifting pattern of the warp rib, a basket weave
on each successive pick insertion as seen in the is produced (Figure 4.27).
fabric of Figure 4.24. Two warp yams and two In designing of woven fabrics, a symbolic
filling yarn insertions are required to repeat the notation is used to illustrate weave patterns. Ver-
complete interlacing pattern order. One unit of tical columns of squares on a grid or point paper
an interlacing pattern is called a repeat and is represent warp ends while horizontal rows of
referred to as the order of interlacing, a defmition squares represent picks. A marked square on the
for weave. The minimum number of harnesses point paper symbolizes that the warp end repre-
required for a weave is determined by this repeat sented by that particular vertical column is raised
size, e.g., two harnesses are required for the above the pick represented by that particular
plain weave. horizontal row. Leaving a square unmarked or
As can be seen in Figure 4.25, drawing the blank means the warp end is lowered under the
warp yarns in an order different from the order pick during weaving. The same four weaves
shown in Figure 4.24 results in a different illustrated graphically in Figures 4.24 through
weave, in this case a filling rib or oxford weave. 4.27 are shown symbolically in Figure 4.28.
In Figure 4.25 ends are shown weaving in The number of weave patterns is endless.
pairs, first up then down or vice versa. This new Other basic or common weaves include the twill
weave was accomplished simply by redrawing and satin weaves which are illustrated in Figure
warp yams from the '' harness 1-harness 2'' 4. 29. At least three harnesses are required to
order of Figure 4.24 to the "harness 1, harness weave a twill and at least five harnesses are
1-harness 2, harness 2" order of Figure 4.25. needed for a satin. Satin weave is a warp face
Notice that the two weaves were accomplished weave and sateen is a filling face weave.
with the same order of lifting.
The order of entering shown in Figure 4.24 is 2.3 Filling Insertion (Picking)
used again in Figure 4.26, but with a different
lifting sequence of two-up, two-down or vice The picking motion places filling yams into
versa. This change in lifting order produces yet the warp sheet between those warp yarns that
harness l
harness 2
~ i\'. ,. "'
'.0-.1':/.1'/)'///ij;
'qq////~ ~......./~
'U'**/~/.o?//,
~...., ....,..-! ;;-,,///,~;
~"'*"'~"'
--
~.........,,.,. Yl"/'1'//;,.
'/qq/q~/"0,.//q;
-.. ,/,
1!~ ....,.,
" ........ ~
~ ''
llh...
~'
~ ~ '-'
~
~ ' "
I...,_
~ . ,,,,. \>
.......
~
~' '
oxford weave
harness 2
114
4. 4 ffl?aving 115
FIGURE 4.28 Symbolic notation for plain, rib, and basket weaves.
have been raised and those warp yarns that have • needle looms (for narrow fabric weaving)
been lowered as shown in Figure 4.30. For • multi-phase looms
fabrics requiring different types or colors of fill- • circular looms
ing yarns, a separate filling selection mechanism • others
assists in presenting the proper filling yarn in the
correct order to the insertion device. Weaving machines for many years of textile
There are several types of filling insertion, history depended on the shuttle as the primary
which is the main factor in classification of weav- insertion device. Although the shuttle (Figure
ing machinery: 4.31) is still used in existing shuttle looms, new
shuttle looms are no longer manufactured for
• shuttle looms consumer textiles by the major weaving machine
• air-jet producers in the world. However, manufacture
• rapier of some industrial textiles such as paper machine
• projectile clothing still depends on shuttle technology. The
• water-jet modern technology of weaving machines has
•
• ••
212 twill weave • 4/1 satin weave·
FIGURE 4.29 Graphic and symbolic illustrations for twill and satin weaves .
116 FABRIC MANUFACTURING
filling selection
Iabrie
turned to three other prominent devices for fill- speeds over wide widths offabric, often weaving
ing insertion as shown in Figure 4. 32: projectile, more than one panel of fabric with one insertion
rapier and air-jet. mechanism.
A gripper projectile transports a single filling Figure 4.34 illustrates filling insertion by two
yarn into each shed as shown in Figure 4. 33. The flexible rapiers with filling carriers, a giver and
gripper projectile draws the filling yam into the a taker. The filling is inserted halfway into the
shed. Energy required for picking is built up by shed by one carrier and taken over in the center
twisting a torsion rod. On release, the rod imme- by the other carrier and drawn out to the opposite
diately returns to its initial position, smoothly side of the fabric. A spatial crank gear drives the
accelerating the projectile through a picking oscillating tape wheels to which the rapier tapes
lever. The projectile glides through the shed in a are attached. In the shed, the tapes move without
rake-shaped guide. Braked in the receiving unit, guides. The grippers assume the correct clamp-
the projectile is then conveyed to its original ing position automatically.
position by a transport device installed under the The most popular method of filling insertion
shed. The projectile's small size makes shedding is illustrated in Figure 4.35 where a jet of air is
motions shorter which increases operating used to "blow" the filling yarn into the shed.
FIGURE 4.33 Schematic of filling insertion with FIGURE 4.34 Schematic of filling insertion with
projectile (courtesy of Sulzer Ruti). two flexible rapiers (courtesy of Sulzer Ruti).
117
118 FABRIC MANUFACTURING
This small mass of insertion fluid enables the number of spaces or" dents" per inch. Specifying
mechanism to operate at extremely high insertion the number of ends per dent with a certain reed
rates. The picks are continuously measured and number dictates the construction (density) of ends
drawn from a supply package, given their initial per inch in the fabric on the loom. It should be
acceleration by the main air nozzle and boosted noted that interlacing causes a natural contraction
or assisted across the fabric width by timed of yarns in the fabric such that density of warp
groups of relay air nozzles. Other fluid systems ends (epi) off the loom will be higher than in the
use water as the insertion medium, but the use of reed, generally about 5 %higher depending on the
a water jet is generally limited to hydrophobic weave, tensions and yarn sizes involved.
yarns such as nylon or polyester filament.
A comparison of approximate insertion rates for 2.5 Take-up
the various picking methods is given in Table 4.4.
The fabric take-up removes cloth at a rate that
2.4 Beat-up controls filling density, picks per inch (ppi) or
picks per centimeter (ppc). Two factors deter-
The filling yarn beat-up motion pushes with a mine filling density: filling insertion rate (loom
reed each filling yarn through the warp sheet and speed) and rate of fabric take-up. Generally, the
into the edge of the fabric called the fell (Figure pick insertion rate of a loom is fixed at the time
4. 36). The reed is also used to control warp yarn of purchase based on the range of fabrics it is
density (closeness) in the fabric. Warp density is intended to produce, the type of insertion
expressed as either ends per inch (epi) or ends mechanism and the loom width. Loom speed is
per centimeter (epc). The reed is a comb with expressed as picks per minute (ppm) and rate of
metal wire blades spaced equidistantly apart take-up as inches per minute (ipm). The ppm
identified by a reed number corresponding to the divided by the ipm equals the ppi. Warp density
TABLE 4.4 Approximate Rates for Different Filling Insertion Methods (Fabric Width = 60 inches).
and filling density together are referred to as the • a drop wire assembly, one wire for each
''construction'' of the fabric, expressed as epi X warp yarn, to stop the loom when a warp
ppi as illustrated in Figure 4.37. end is slack or broken
Again, it should be emphasized that both the • a tension sensing and compensating whip
ends and picks contract because of interlacing roll assembly to maintain tension in the
causing construction in the loom and off the loom warp sheet
to be different. Subsequent fabric finishing steps • a mechanism to stop the loom when a
also introduce changes in the fabric construction filling yarn breaks
which must be considered in setting up loom • filling feeders to control tension on each
specifications. pick
• pick mixers to blend alternate picks from
2.6 Auxiliary Functions two or more packages (up to eight)
• filling selection mechanism for feeding
In addition to the five basic motions of a loom, multi-type filling patterns
there are many other mechanisms on typical • filling selvage devices such as trimmers,
weaving machines to accomplish other func- tuckers, holders and special weave
tions. These include harnesses for selvage warp ends
tilling
insertion
rate
(ppm)
downtime, fewer operators in the weave The automatic filling break repair motion
room and therefore lower weaving costs. enables repair of the faulty pick within a short
time without damaging the warp threads. The
Typical characteristics of modern weaving
electronically controlled filling thread brake
machines are given below. These characteristics
enables the braking force and braking duration to
are not specific to any particular manufacturer' s be adapted to the requirements of the individual
machine except the projectile machine which is
filling yarn. High fabric quality is assured by the
manufactured only by Sulzer Ruti. The informa-
reversible, electronically controlled warp let-off
tion below is given to demonstrate the state-of-
and the programmable automatic shed leveling
the-art technology in weaving.
motion, which, by closing the shed at stoppages,
relieves the warp threads.
3.1 Projectile Weaving Machines For shed formation, there is a range of
mechanical or electronically controlled shedding
Figure 4.39 shows a P 7200 projectile weaving motions available:
machine by Sulzer Ruti. P 7200 is designed to be
• tappet motions for up to fourteen shafts,
functional, modern with central microprocessor
with weave repeats of up to ten picks
control and automated subunits. The micropro- dobbies, electronically controlled, for up
cessor terminal informs about all logged data and
to ten shafts
programmed parameters, and receives com-
• name-selvage jacquard machines,
mands for the modification of settings. The
electronically controlled
monitor display shows the operational state of the
• jacquard machines, electronically
machine, and, in case of stoppage, its cause.
controlled, with all standard numbers of
One of the important new developments is the
hooks
projectile made of composite material. This
reduced the weight of the projectile and in- Warp stop motion pinpoints the broken warp
creased its speed. Composite projectile is espe- end on the digital display. The electronic ftlling
cially suited to economically produce very stop motion can be adapted to any type of filling
delicate fabrics. Figure 4.40 shows steel and yarn. Projectile weaving machines are very ver-
composite projectiles. satile and adaptable to various fabric styles from
122 FABRIC MANUFACTURING
FIGURE 4.40 Composite (top) and steel projectiles (courtesy of Sulzer Ruti).
finest silk shirting to heavy denim styles and high the microprocessor terminal. Cloth take-up and
performance industrial fabrics. warp let-off are synchronized. The warp tension
to be set, is calculated and displayed by the
3.2 Rapier Weaving Machines microprocessor according to the style data. Op-
timum compensation of the warp tension is main-
Although there have been different variations tained by the lightweight warp tensioner.
of rapier insertion mechanisms such as single Together with the electronically controlled warp
rigid rapier and double rigid rapier, double let-off, the lightweight warp tensioner guaran-
flexible rapier machines are the most common. tees optimum warp tension. The electronically
Rapier machines are very versatile weaving controlled filling thread brake reduces yarn
machines. The central microprocessor system strain measurably.
regulates and monitors all electronically con- Rapier weaving machines can weave a wide
trolled functional units, logs the machine speed, range of demanding fabrics with natural and man-
the number of picks and calculates the machine's made yarns and their blends. Some machines can
efficiency. Permanently stored and frequently accommodate dobbies of up to sixteen, alterna-
used weaves and color sequences as well as tively twenty-eight shafts as well as for combina-
various auxiliary functions necessary for starting tion with jacquard machines and positive tappet
to weave, can be readily activated via the motion. Selvages can be formed either by means
microprocessor terminal. If the filling yarn of leno motion, sealing or tucking units. Figure
breaks before the feeder, the microprocessor 4.41 shows a rapier weaving machine.
simply switches over to another feeder with the
same and intact filling yam, without stopping the 3.3 Air-Jet Weaving Machines
loom. Electronically controlled cloth take-up
with freely programmable filling densities op- Figure 4.42 shows a microprocessor con-
timizes the fabric quality. Any filling density trolled air-jet weaving machine. An extremely
from 6 to 200 picks/em is infinitely adjustable at flexible program of styles, short style changing
FIGURE 4.41 Rapier weaving machine (courtesy of Nuovo Pignone).
123
124 FABRIC MANUFACTURING
FIGURE 4.43 Programmable air blowing times (1) with automatic correction at speed changes and automatic
pressure optimization due to individual air supply (2) (courtesy of Sulzer Ruti).
times and a minimum of attendance and main- dividual air supply provides air-saving and
tenance requirements guarantee high economical gentle filling insertion (Figure 4.43). During the
efficiency with air-jet looms. Gentle handling of filling insertion process, thread velocities of 50
warp and filling yarns permits highest speeds. In to 80 m/s are attained [4]. The processor-con-
these machines, due to optimized air consump- trolled filling thread brake dampens the filling
tion, power requirement is modest and filling tension peak by approximately 50%. The
yarn waste is surprisingly little. Compressed air electronically controlled warp let-off assures
control and warp let-off are processor con- uniform tension from full to empty warp beam.
trolled. The automatic filling fault removal Changing filling densities on the running
reduces downtimes and enables more machines machine is possible due to electronically con-
to be assigned to a weaver. trolled cloth take-up. High quality of selvages is
The robust and compact construction allows assured by the various selvage forming units
for high speeds as well as the weaving of the most such as full and half leno selvage devices and
heavy fabrics. Start marks are prevented by the mechanical-pneumatic tucking unit.
swift acceleration of the main motor of the weav- The electronically controlled filling feeder
ing machine to full speed. The warp stop motion guarantees exact metering of the required filling
with LED display for each contact bar facilitates thread length, thus ensuring a minimum of filling
locating broken filling threads. The optoelec- yarn waste.
tronic filling stop motion detects reliably every
filling yarn breakage.
3.4 Water-Jet Machine
Integrated artificial intelligence is incor-
porated in some of these machines. The control
Water-jet machines offer very high speed
terminal serves as communication element be-
which can be around 1,500 ppm. Features like
tween man and machine. Setting data can be
filling insertion with a minimum influence over
transferred from one machine to the other by
the warp yarn, shedding devices with much less
means of the memory card. If no setting data is
heddle vibration, fully super high speed com-
available for a style which had not been woven
patible let-off and increased durability in the
previously, the microprocessor can calculate
beating motion, improve fabric grade. Figure
standard parameters from the entered fabric
4.44 shows a water-jet machine. Figure 4.45
specification and transfers them automatically to
shows a modem weaving mill.
the electronically controlled function units.
Profile reed and relay nozzles, which are the
most common, assure safe filling insertion even 3.5 Multi-Phase and Circular
with larger weaving widths. The air pressure in Weaving Machines
the nozzles adjusts itself automatically to the
insertion conditions. Programmable blowing Innovative approaches to weaving have been
times with automatic correction at speed changes introduced through several design modifications
and automatic pressure optimization due to in- of shedding and filling insertion compone!lts of
FIGURE 4.44 Water-jet machine (courtesy of Nissan).
125
126 FABRIC MANUFACTURING
the traditional weaving machine. These devel- the filling direction of the structure coupled with
opments include the circular loom and several progressive, simultaneous filling insertions. Al-
different multi-phase weaving systems such as though some of these new multi-phase systems
warp direction shed waves and weft direction and circular looms are being used in limited
shed waves. These multi-phase concepts offer an fabric markets, none of them has challenged
advantage in production rate, gained by pro- traditional weaving machines in major fabric
viding segmented sheds along either the warp or markets so far [5].
4.5
Knitting
R. P. WALKER
S. ADANUR
in turn pulls down on the new yarn and uses the ing plain [Figure 4.1(c)], tuck, purl (reverse),
previous yarn loop to close the latch trapping the and float (miss) stitch which are shown in Figure
new yarn inside the hook. The previous loop is 4.49. The plain stitch fabric has all of its loops
now in a position to ride over the outside of the drawn through to the same side of the fabric. The
latch and be cast off the needle head, thus becom- plain fabric has a very smooth face and a rough
ing a part of the fabric while the new yam loop back. Other stitches produce different effects
is pulled through the previous loop. depending on the arrangement of the loops. Spe-
Depending on the structure in weft knitting, cial stitches are also available to prevent runs.
several types of knitting stitches are used includ- Weft knitting machines may be either flat or
circular, the former knitting a flat single layer of • yarn break sensors
fabric, the latter knitting a continuous tube. No • fabric hole detectors
matter which machine configuration is used, • needle "closed latch" sensors
weft knit manufacturing involves the same fun- • air blowing systems to keep needles clear
damental functions: of lint
• centralized lubrication dispensing unit
• yam selection and feeding • computer interfaces for production
• needle knitting action monitoring
• fabric control during knitting • computer interfaces for pattern entry
• needle selection • computer aided design systems
• fabric take-up and collection
Knit fabrics can be classified as single knits
There are several devices added to weft knit- and double knits. Single weft knits have one layer
ting machinery for improving quality of the of loops formed with one yam system. Three
product and/or operation of the process. A par- major types of single weft knits are jersey, rib and
tial list of these added features includes: purl structures. Double knits have two insepa-
structures (DOS) or no-crimp fabrics. The rein- hinges (which is a problem when crease
forcement fibers can be oriented at various direc- is needed).
tions including oo, 90°, 45°, etc., as shown in • Relaxation shrinkage of knit fabrics can
Figure 4.54. Some of these structures are used be high, especially if the fibers are
for composite reinforcement (Chapter 7.0). hydrophilic.
• Pliability and form-fitting due to the loop
structure and to the low twist in some
4. KNIT FABRIC CHARACTERISTICS weft knit yarns.
• Pilling and snagging due to ease of
The basic knit structures have the following catching a loop and pulling it to the
general characteristics: fabric surface.
• insulative ability and air permeability:
• High extendibility is seen. Knit fabrics, which are open structures,
• elastic recovery: Knit fabrics recover well are ideally suited for providing thermal
from deformation since the loops attempt insulation in still air conditions. Knit
to return to their original position. structure contributes a desirable cooling
• shape retention: When the loops do not effect in summer and a chilling effect in
recover from deformation, the fabric winter due to wind.
stretches out of shape or it bags. • running or laddering: Knit fabrics may
• Knits generally crease or wrinkle less run or ladder if a yarn in the structure is
than woven fabrics since the loops act as broken.
4.6
Braiding and Narrow Fabrics
S.ADANUR
mandrel
yam spools
3. THREE-DIMENSIONAL BRAIDING
137
138 FABRIC MANUFACTURING
warp yarn. Heavy webbings are often made with regular loom. In narrow fabric weaving, a single
stuffer warps embedded between the webbing warp beam or multiple warp beams can be used.
face and back. In essence, such webbings are The warp yarn can also be taken directly from
double or tubular fabrics with reinforcing warp the creel for simple designs with small number
yarns lying between the two layers, and inter- of ends.
secting both sufficiently to bind the composite In narrow fabric weaving, a hairpin loop of
structure together, forming an integral unit. filling is inserted into the shed at very high speed
Although some shuttle looms are still used, by the needle. Then the filling yam is locked in
narrow woven fabrics are generally manufac- at the opposite selvage by a knitting latch needle.
tured on needle looms. Because of the impor- Due to the loop of the filling yarn, the fabric
tance of a good selvage, shuttleless methods are always has double picks. The selvage on the
generally not used. Figure 4.63 shows a needle filling insertion side is a woven selvage and the
loom whose functions are very similar to a selvage on the latch needle side is a knit selvage.
4.7
Tufting
R. P. WALKER
S. ADANUR
A tufted fabric involves a system of yams that of fabric motion to allow the formed loops to
are sewn into a fabric (primary backing) leaving move off the looper after forming. Cut pile
yam loops below the primary backing (Figure surface is produced by changing the type of
4.64). Sewing is accomplished by a solid bar of looper with corresponding knives. As shown in
needles extending the full width of the primary Figure 4.64(b), the loops are formed on the
backing fabric with each needle threaded with a looper and must progress through the knives and
yarn. Because the needles are spaced a certain be cut free of the looper which points opposite
distance apart (called the needle gauge), the the direction of fabric flow. In all cases of level
yarns will be aligned in the structure in precise loop surfaces, the feed rate of yams must be
vertical rows across the width (or horizontal adjusted to accomplish the desired pile height (in
direction) of the fabric. The rate of reciprocal up conjunction with the bed plate setting) and to
and down motions by the needle bar is referred obtain a secure (tight) backstitch between sur-
to as ''stitches per minute'' or the speed of the face stitches.
needle bar in revolutions per minute (rpm). Spac- Multi-level textured designs can be created on
ing of these needle bar stitches is controlled by the fabric surface by introducing variable yam
the feeding rate of the primary backing fabric feed to selected needles. In these patterned sur-
resulting in a specified number of" stitches per faces a special looper and knife assembly is used
inch" along the machine (or vertical) direction which allows yarns with unrestricted feed rates
of the fabric. The primary backing fabric is sup- to process as normal length loops, either cut or
ported by a bed plate which may l?e lowered or uncut. Restriction of the yam feed causes loops
raised to control the depth of needle penetration to be drawn back off the looper allowing them to
through the fabric carrying the yam loops to a pass over the looper as lower level uncut loops.
desired distance below the primary fabric (the In all cases a low level loop is produced by a
fabric is made upside down). The distance of the process called "stitch robbing" where a needle
loops below the primary fabric constitutes the with restricted yam feed steals yarn from the
"pile height" of yam tufts. These surface tufts previous stitch causing the previous stitch to be
represent the face or use side of the fabric after low. Two yam feed systems are commonly used
the fabric is removed and finished. to produce these high-low stitch patterns.
Different type tufting elements are used to Another feed system called a ''scroll'' uses
produce various surface effects. Fabrics may photoelectric cells to read an acetate film pattern
have surfaces of level loops, multi-level loops, which in tum controls two drive rolls for fast or
level cut loops, multi-level cut and uncut loops slow yarn feed to produce high or low loops. The
or level cut and uncut loops. These variations are slat system is more suited to long production runs
made possible by the types of loopers, knives and of the same pattern while the scroll system works
yarn feed controls used. A simple uncut loop better for short runs of often changing styles.
surface is produced as shown in Figure 4.64(a) Both systems must operate with an individual
when the loopers take yams from the needles and package creel rather than a beam creel since each
hold the loops formed while the needles retract. yarn is supplied to the machine at a variable rate.
Notice that the looper is facing in the direction Still other special looper assemblies can be
139
140 FABRIC MANUFACTURING
needle needle
yarn
fablic
pile piles
FIGURE 4.64 Tufting elements (a) loop pile and (b) cut pile.
employed to create cut and uncut loops at the Color may be added prior to fiber manufactur-
same level. ing, to the fiber or to the yarn before tufting.
Since the fabric is tufted upside down, a system Usually, coloration is done after tufting. How-
of rolls is used to guide the fabric up and over an ever the color is applied, the fabric is processed
inspection zone so that the surface of the fabric can through a final back-coating where latex and a
be observed prior to final roll up. This provides not secondary backing fabric is added to secure the
only an opportunity for inspection but also an op- entire surface yam, primary backing and sec-
portunity to repair lines in the surface which may ondary backing assembly. In some cases only the
have been too tight, too loose or missing entirely. latex is added and in others a foam rubber coating
This surface mending is done with a single needle, is applied. Most tufted fabrics are composed of
hand-held gun and scissors (for cut pile). a woven primary backing fabric (split film
After the tufting process, the unfinished rolls polypropylene yams) and a woven secondary
of fabric are stored to await orders for coloration backing fabric (either spun jute or fibrillated
before final back-coating. polypropylene yams).
4.8
Nonwoven Fabrics
R. M. BROUGHTON, JR.
P.H.BRADY
TABLE 4.8 End Uses and Production Methods of Selected Nonwovens [7].
Fabric End Use Production Method
would be a consumer product, while the same is more favorable because a nonwoven fabric
fabric used for a tent or tarp would be an in- usually fmds one place where it definitely fits
dustrial fabric. There does seem to be general within the system.
agreement that filtration products, medical tex- Many of the properties of a nonwoven fabric
tiles, coating and laminating substrates, and are derived directly from a similar property in its
geotextiles all qualify as industrial textiles. fibers. The translation of fiber properties into
fabric properties is dependent upon the geometri-
cal arrangement of the fibers in the fabric and the
2. CLASSIFICATION OF NONWOVENS properties of any adhesive or other bonding
agent present. The methods of producing a non-
Nonwovens can be broken into groups based woven fabric depends upon the form of the raw
on the fiber type, method and type of reinforce- material. Nonwoven textiles are usually made
ment, web preparation, and method of bonding from fibrous materials, and therefore, most of
between fibers. The presence of reinforcement this section will center on the production of
implies a composite structure. Table 4.9 is a fibrous webs. In order to be considered a non-
classification scheme for nonwoven fabrics. woven, a film must either be treated to make it
Other schemes have been 17roposed, but, this one fiber-like, or the film must be combined with
fibrous material. Likewise, a sheet of foam is not
considered a nonwoven unless combined with
fibrous materials.
TABLE 4. 9 Classification of Nonwovens.
By ...
3. PRODUCTION OF NONWOVENS
Fiber
Chemical type Rayon, polyester, etc.
Physical form Filament, staple, file, foam There are two major steps in the manufacture
Web formation Mechanical of nonwovens: web formation and bonding of
Fluid: air, water fibers in the web.
Electrostatic
Film extrusion
Monomer casting
3.1 Web Formation
Bonding of fibers Mechanical: needle, fluid
Chemical: adhesive, self Figures 4.66 through 4.69 show some of the
Reinforcements None mechanical methods of nonwoven fabric forma-
Filaments tion. All of these methods involve the use of
Fabric rotating, wire covered cylinders to pick up in-
Foam
dividual (staple) fibers, and transport and deposit
1 WORKER ROLlS
~'
nlj.,..J(-L_)ft:,'.:/
\
I
~/ ~\ WEB TAKE-OFJ
.J.,\- L, "~-\\
FEED ROll
LIC:,ERI:-1
DOFTER ROLL
FIBER .I'EB OUT
':\~'MAIN CYU:lDER
FEED liAT __:;.
FEED ROLL
UCKER!N DOFFER ROLL CONVEYOR TABLE I
FIGURE 4.67 Flat-top cards in tandem.
RoUs
Individualized
Fibers in
Air-Slream
Batt Condenser
Air-La1d
Batting
Conveyor
Tumbler/ Pre-Feeder
Air-Stream
Out
144
4. 8 Nonwoven Fabrics 145
them in a sheet or batt form. A typical roller-top to fall through the air and land on a moving
or flat-top card produces a web too thin to be used conveyor, a nonwoven batt will be produced. A
in a single layer form for most applications. large number of filaments (perhaps from multi-
Consequently, card webs from multiple cards are ple spinnerettes) are required to produce a web
often stacked or the web from a single card is of reasonable width, and care must be taken to
folded in a crosslapper form to create a multi- promote random dispersion of the filaments. The
layered batting. use of electrostatics may be used to keep the
A card usually operates to align fibers in the filaments separated and dispersed in the web.
direction of web travel (machine direction or Bonding of the fibers (usually thermal bonding
MD). Card webs have a higher strength in the or needlepunching) is done in line before take-up
machine direction than in the cross-machine of the batt.
direction (CD). The ratio of MD/CD strength Melt blowing is similar to spunbonding, ex-
may be as high as 10/1. If the web is crosslapped, cept that a high velocity stream of air is used to
the orientation is changed from the direction of force the filaments away from the spinnerette
web travel to the cross direction. There is some face (Figure 4. 71). The air stream can attenuate
dispersion of fiber orientation as the web con- the fibers to a degree of fineness smaller than
veyance continues while the web is being folded typically extruded textile fibers. The fibers (nor-
(Figure 4.68). Still there is a high ratio of mally less than one denier) are deposited onto a
CD/MD strength in crosslapped webs. Through moving condenser/conveyer belt and bonded
the addition of extra cylinders or rollers, some before take-up. This type of process allows for
cards allow for the manipulation of roll speeds in the creation of a web having a very fine pore
an attempt to minimize the fiber alignment. A structure and large surface area. Such fabrics are
garnet is a card-like machine, but having a generally suitable for absorption and filtration
heavier wire than a typical card. It is designed to applications.
tear yarn and small pieces of fabric into in- Air is not the only fluid which can be used to
dividual fibers and form a web or batt. deposit a fibrous web onto a condenser screen.
The most effective way of minimizing fiber Paper has been produced for centuries by
alignment is to sweep the opened fibers from a suspending fibers in water and then draining the
wire wound roll (either card or opening system) suspension through a condensing screen (Chap-
into a stream of air, and then condense the fiber ter 12.0). The high density, viscosity and surface
on a slowly moving screen or perforated drum. tension of water (compared to air) causes wet-
This type of product is referred to as an air-laid laid nonwovens to be very dense in structure
web. Normal cards with add-on air handling and compared to those which are air laid. Wet-laid
condensing attachments were often constructed fabrics have some directional character, being
in-house in yarn manufacturing operations to stronger in the machine direction than the cross
allow the production of a marketable product direction. The directionality (usually less than
from manufacturing waste. As the products be- carded systems) is introduced when the fiber
came more sophisticated and profitable, ma- suspension is accelerated by contact with the
chinery specifically for air laying was designed.
Air-lay machinery is now offered by a variety of
companies including Rando Machine Co.,
D.O. A., and Fehrer. Figure 4.69 shows the inter-
nal operation of a typical air-lay machine. ci I
MELT EXTRUDER 1
Air can also be used as a dispersing medium ~BONDING
FIBER ATTENUATION
for continuous filament fibers. This type of AND DISPERSION-~
' , HEATED CALEND!:R
moving screen. The greater the acceleration to holes in the ftlm, making it porous and flexible,
machine speed, the greater is the directionality it may qualify as fabric. There are two manufac-
in the fabric. turing processes which can produce a fUm having
A second major difference between wet-lay sufficient flexibility and porosity. These are the
and air-lay systems is that in the wet-lay system, fibrillated film process and a process originally
water must be removed in a drying zone. Several developed by Smith and Nephew Ltd., which
geometries of the condensing zone are possible. embosses and then stretches the film until it rup-
Fourdrinier, inclined wire, and cylinder machines tures in its thin spots. The embossing may, in the
are typical of the various types of machinery in extreme, punch holes in the fUm. A diagram of
use. Figures 12.2 and 12.3 (Chapter 12.0) show the fibrillated fUm extrusion process appears in
schematics of Fourdrinier machine. After forma- Figure 4. 72.
tion, water is removed from the web by gravity, If a film of polyolefm is stretched to a high
vacuum extraction, pressing and finally by heat- degree in the machine direction, it develops
ing. strength in that direction, and weakness in the
Paper is typically made from fibers which are cross-machine direction. If the ftlm is then
less than 0.25 inch in length. Textiles normally mechanically worked, splits may appear along
use fibers which are an inch or more in length. the machine direction, causing the film to be-
When flexible fibers of longer than an inch in come more like a web of fiber. The splitting (or
length are suspended and stirred in water, they fibrillation) process can be accelerated by either
tend to become entangled. Only through very abrading the ftlm along the machine direction,
high dilution ratios can long fibers (0.5 to 1 inch) passing the oriented film over a pinned or bladed
be processed on a paper machine. The processing roller, or extruding the film onto a profiled roller,
of fibers longer than one inch is impractical on which has grooves parallel to the machine direc-
ordinary paper machines. A variety of saturation tion. A highly embossed film, or a ftlm with an
substrates, containing glass fiber or mixtures of array of holes punched in it tends to form a
wood pulp and other fibers are made on paper porous network when stretched biaxially. This
machines. These mixtures of wood and other may produce a fine netting, or even a tough
longer fibers are often used to create absorbent plastic netting suitable for fences and sieves.
wiping materials. Glass fiber mats produced on In the extrusion of film, the polymer is
wet-lay machinery are used for roofmg products. processed through an extruder equipped with a
Some production processes bypass the fiber thin, flat die. It is possible to start the production
manufacturing step and produce a flat sheet of a film from a monomer spread on the surface
(ftlm) directly. Since some porosity is usually of a solid or liquid. In this case, the monomer is
required of a fabric, a flat, impervious ftlm polymerized directly into the film shape. This
would not likely be considered to be a fabric. technique is particularly useful when producing
However, if there are a sufficient number of microporous films or fUm coatings on substrates.
4.8 NonwovenFabrics 147
11LM DIE
EMBOSSING ROLLS. or
PINNED ROLLS, or
~
BLADED ROLLS
11BR!Il.ATED FILM
,!'\1/
to a fabric substrate. The fibers can be made to ELECTROSTATIC
CH"RCING DEVJCE
stand on end either by vibration of the sheet, or !>fECHAN~~Jo.L
VTBRATOR _ / /
{BEATER BARS)
by electrostatics which cause the fibers to fly
through the air, impinging end first into the glue FIGURE 4.73 Flocking.
on the fabric surface. Patterning possibilities are
introduced when the glue is applied in the desired
pattern on the fabric surface.
A particularly ingenious, nonwoven produc-
tion method involves the direct extrusion of a
fabric. Two concentric circles of spinnerette
holes which rotate in opposite directions can
produce a web that appears similar to a loosely
woven, bagging material. The cylindrical ma-
terial is frequently used for food packaging. Rotating concentric spinnerettes
Larger versions, when split, can be used for net-
ting, fencing and geotextile grids. This method
of production is referred to as the Netlon process.
A schematic diagram of the process is shown in
Figure4.74.
STRIPPER PLATE •
(
BARBED NEEDLES
necessary if strength is to be developed. Fiber during the impingement of the water stream. The
entanglement can be provided by either need- size, spacing, and height of the knuckles on the
lepunching (Figure 4.75) or by hydroentangle- conveyor or plate surface have a major influence
ment (Figure 4. 76). on ability of the fibers to entangle, and the ap-
In needlepunching, barbed needles are pushed pearance of the fabric. In general, a stream of
through the web. The barbs catch fibers on the water does not exert as great a force on fibers as
surface of the batt, and push them into the center, that produced in needlepunching. Therefore,
densifying the structure and producing strength hydroentangled structures are usually less dense
through entanglement. The machine requires a and more flexible than those produced by need-
bed plate to support the web as the needles lepunching. Hydroentangled nonwovens are
penetrate, and a stripper plate to strip the fabric often referred to as spun laced fabrics. Hydroen-
off of the needles as they are withdrawn. Nee- tanglement has an advantage over needlepunch-
dling can be done from both sides of the fabric, ing in that it can be used to bond relatively thin
and penetration of needles does not have to be fabrics.
perpendicular to the sheet structure. An alternative to mechanical entanglement to
Hydroentanglement employs fine jets of water provide structural integrity to a nonwoven
to push fibers from the surface toward the inte- material is the addition of an adhesive to bind the
rior of the fabric. A more powerful jet may fibers together. The adhesive may be included as
produce an apertured fabric, while less forceful either a secondary treatment, or in the form of
jets tend to produce entanglement without com- adhesive-containing fibers which are manufac-
pletely penetrating the fabric. As with the need- tured into the structure. Adhesives in the finished
lepunching process, the batt must be supported fabric are solid like the fibers they bind together,
~.~
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CYLINDER OR
CONVEYOR • \. , ~"
.
\".~"''
'
i
1.
L
. d==:!
\~-\FILTER
I \___/~
I
I'
WATER RECYCLE
'l I
Jl "'~ ,,
II
hesive, it must exist as a liquid at some predeter- UNBONDED BATT +'' WEB TO "CURING" OVEN
\
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~ L ~' CONVEYOR
POWDER METERING
,: ROTATING BRUSH
'-'------'·"'i·_;,o , .._. / ---._ r:- ~ r [
/ INFRARED OVEN
(OR OTHER HEAT souRcE)
.;_;:;:::. (QHQ\!Q\iC\
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150
4. 8 Nonwoven Fabrics 151
HOT AIR
OVEN
ELECTROSTATIC PLATES
o "e .
specific for a particular solvent and fiber type either convective, conductive, or radiant heating
(HCl vapor and nylon). methods. Passing the web over a heated cylinder
Except for vapor-activated adhesives, all solid (conduction) can provide the required heat, but
application processes require heating at some also compresses the fabric (pressure is an essen-
point during the process. Thermoplastic ad- tial ingredient in this type ofbonding). A calender
hesives must be heated to cause flow and stick- with engraved roll provides point bonding, while
ing. Adhesive/solvent systems require heating to a smooth roll tends to bond the entire area (Figure
remove the solvent after adhesion. Heat may be 4.86). Hot air can be forced through the fabric
applied from hot, circulating fluids (usually air, (convection) to melt the adhesive without pro-
shown in Figure 4.85), heated and rotating ducing excessive compression. Infrared heating
cylinders (Figure 4. 86), or radiant (infrared) (radiant) also minimizes compression, but works
sources (Figure 4.82). Microwave/RF heating best on relatively thin or low-density materials.
has also been investigated for use in bonding. Ultrasonic energy can also be used to fuse
Thermoplastic adhesives may be activated by materials, usually in a point bonded pattern.
Core Fiber
(High Melting)
Core Aber
Exposed Non-binder Abers
r
\HEATER
\ ____/ \
\ ( ) rONVEYOR - •
Several factors are important in determining pendence in the structure. Application of any
the effectiveness of an adhesive in a given fabric: adhesive interferes with fiber movement. Small
islands of bonding separated by unbound areas
• distribution of adhesive in web provide for fabric-like properties. Bonding only
• viscosity of adhesive while in the liquid at fiber intersections (as with the sheath/core
state bicomponent fibers) may also produce textile-
• specific adhesion to fiber like properties, provided that the intersections
• physical and chemical properties of are not too numerous. As an adhesive begins to
adhesive (particularly T8 , solvents) fill the spaces between fibers, the structure
• adhesive stability to environment begins to behave more like a fiber reinforced
plastic than a fabric.
The distribution of adhesives can range be- The viscosity of the adhesive while liquid
tween the extremes of complete saturation of the within the web is significant. As viscosity in-
structure, to bonding only at inter-fiber intersec- creases, the ability of a given material to flow is
tions (Figure 4.84). Area and point bonding are reduced. Absent proper flow, the adhesive will
terms sometimes used to describe the distribution not sufficiently wet the surfaces that are desired
of the bonding sites. One of the characteristics to be bonded. Low viscosity materials, which
that distinguishes fabric from paper or film is the would readily flow, may migrate to the bottom,
ability of fibers to move with relative inde- or even out of the sheet under the force of gravity.
/
/
Mechanical Pressure Web Containing /
Thermoplastic Fibers
or Adhes1ve . /
¥
Pressure Roll
(~
Bonded Web /~Healed Roll
/ to Take-Up /
or other /.
Process
~' /// Note The pressure roll rnay be heated
,_..--,,,_,/\/ Either roll may be engraved
Abrasives Lofty or dense construction, large denier fibers, binder holds both fibers and abrasive
Acoustic materials Dense to moderately lofty, often contain an impermeable film layer
Agricultural covers Lightweight, thin, controlled porosity depending on temperature
Athletic mats Lofty, resilient, relatively thick
Protective apparel Limited porosity, restrict the passage of particles, liquids, gases
Automotive Liners, carpet, mostly needlepunched, colored
Bandages White, sterilizable, frequently hydroentangled
Brake linings Resin impregnated, heat resistant
Thermal insulation Glass, mineral wool, specialty fibers, moderate loft, mostly air laid, resin bonded
Envelopes Typically spunbonded polypropylene, better tear resistance than paper
Ceiling tiles Typically resin bonded fiberglass, non-flammable
Erosion control Temporary- biodegradable, inexpensive; permanent- environmentally resistant
Drainage (geotextile) Acts as a filter to keep soil out of drai'nage channel, bulky, environmentally resistant
Roofing shingles Wet-laid fiberglass, some resin bonding, saturated with asphalt
Roofing felt Typically polyester spunbonded or needled felt, moderate loft, saturated in situ
Filters For oil, gas, food, air, etc. Loft and porosity depend on the materials to be filtered.
Highly engineered product in terms of porosity, pore size and material chemistry
Papermaker' s felt Smooth needled layer on top of woven conveyor belt used in paper manufacture
Pond liners Provide cushion to prevent puncture of the plastic liner
Road bed "support" Needled heavyweight felt; provides permanent separation between soil and ballast
Flooring Base material for asphalt or vinyl saturant in flooring for kitchens, etc.
Thnts Strong, water repellent, frequently layers of different fabric types
Paint applicators Flocked or specially needled materials
Upholstery padding High resilience, moderate to low loft, sufficient to support sitting or reclining person
Upholstery separators Thin spunbonded or carded and resin bonded, separates layers of materials
Instrument wrap Keeps surgical instruments sterile, similar to barrier fabrics, very water repellent
Computer disks Extreme product uniformity required
Reinforced plastics Glass or specialty fibers saturated with plastic resin (frequently thermosets)
Synthetic leather Relatively dense, frequently needled, saturating substrate for vinyl or polyurethane
Home, industrial wipes Bonded, reinforced air-laid pulp, or melt blown calender bonded absorbent sheets
While many of these decisions are primarily products into industrial or consumer products is
based in common sense, the selection of the best quite subjective. The authors have surveyed a list
materials and manufacturing processes to use in of nonwoven products compiled by Holliday and
a particular situation require extraordinary atten- have selected a good cross section of industrial
tion to detail. nonwoven fabrics [8]. The list appears in Table
4.10 with some comments about these products.
5. INDUSTRIAL APPLICATIONS OF Obviously Thble 4.10 omits many of the in-
NONWOVENS dustrial nonwoven products, but it should give
the reader an idea of the diverse industrial ap-
As mentioned earlier, the classification of plications of nonwoven products.
4.9
References and Review Questions
4. Match the proper terms from the list with the A loom beam made up in sections
statements that follow. arranged side by side
Measurement of degree that size
Thrms
encircles warp yarn
1. Winding (spooling)
Entering of ends through weaving
2. Warping
elements
3. Slashing
Process where warp stripe patterns are
4. Drawing-in
developed from different solid colored
5. Repeater End
sheets of yam
6. Cause Analysis
Passing of cord through a yam sheet
7. Abrasion Resistance
in order to separate sheet from sheet
8. Creep Speed
or end from end
9. Shed Timing
Usually a more important statistical
10. Shed Geometry
consideration than the ''average
11. Woven Fabric
value'' of a yam property
12. Package Quality
Phrase used to describe slowing of
13. Variability
slasher
14. Section Beam
Combining yams from single-end
15. Size Box
packages onto a beam
16. Encapsulation
As or more important to good weaving
17. Braided Fabric
as yarn quality
18. Draw Warping
Increases the length of yam on a
19. Section Warp
single-end package by combining
20. Cloth Fell
smaller packages, spliced end to end
21. Reed Plan
Warp yam that breaks over and over
22. Leasing
during weaving
23. Lost End
Section of the slasher where chemicals
24. Tying-in
are added
25. Creel
Two yarn systems interlaced at 90
Product of the warping process degrees with fabric produced 45
Process used to replenish a warp of degrees to either yam direction
the same style Section of the slasher where section
The interlacing of a pick relative to beams are placed
beat-up
5. Why is yarn preparation and slashing neces-
A broken warp yam embedded in a
sary for weaving? Explain.
beam
6. What are the main factors to consider when
Term used to describe the beginning of
selecting a sizing agent for a particular yarn?
the cloth
7. How does the yarn structure (i.e., ring spun,
Two yam systems interlaced at 90
open-end, air-jet spun, friction spun) affect
degrees with fabric produced parallel
size pickup?
to the warp direction
8. Match the proper terms from the list with the
Ends per dent and dents per inch
statements that follow:
Technique used to determine reason
for yam failure Terms
Filament yam process to provide 1. Tucked Selvage
better end-to-end dye uniformity 2. Cotton Count
The configuration of warp yams 3. Construction
resulting from their manipulation by 4. Weft Density
multiple harnesses 5. The Fabric Weave
Most important warp yarn property 6. Weft Yam
enhancement 7. Drop Wire
4. 9 References and Review Questions 157
W. PERKINS
Greige fabric as it comes from the manufac- Typical processes for preparation of materials
turing machine may or may not be ready for its for dyeing and finishing are as follows:
end-use function. If fabrics are to be dyed,
• heat setting
coated, impregnated, preshrunk or otherwise
• singeing
finished, it is usually necessary to remove the
• desizing
warp size and other impurities which may inter-
• scouring
fere with dyeing or prevent proper adhesion of a
• bleaching
coating or finish.
• mercerizing
The sequence shown is common but many
variations may be used. Virtually all materials go
1. PREPARING FABRICS FOR DYEING through some of these processes prior to dyeing
AND FINISHING and some materials in fabric form are subjected
to all of them.
Most textile materials and fabrics require
pretreatments before they can be dyed and
fmished. The required preparatory treatments 1.1 Heat Setting
depend on the type of fiber in the material and
particular dyeing and finishing treatments that The dimensional stability, dyeability, and
are to be done. Generally, fibers containing the other properties of thermoplastic fibers are af-
most types and the greatest amount of impurities fected by repeated heating and cooling, or the
require the greatest amount of preparation for heat history, of the material. The main purposes
dyeing and finishing. of heat setting are as follows:
Most preparatory processes for dyeing and • to stabilize the material to shrinkage,
finishing involve heating the fabric or treating it
distortion, and creasing
with chemicals. Therefore, the potential is
• to crease, pleat, or emboss fabrics
present for thermal and chemical damage to the
• to improve the dyeability of fabrics
fibrous polymer comprising the fabric. Fabrics
can also be damaged mechanically in most Heat relieves stresses in the amorphous re-
preparatory processes. High temperature ther- gions of thermoplastic fibers. When the fiber is
mal treatments are often beneficial to fabrics heated above its glass transition temperature, the
containing thermoplastic fibers while these treat- molecules in the amorphous regions can move,
ments are not beneficial or desirable on fabrics and the material can be formed into a new shape.
containing only non-thermoplastic fibers. When the temperature is decreased, the material
The following discussion of preparation for stays in its new shape. Thus, creases that have
dyeing and finishing is general and reference developed in the fabric can be pulled out, and the
is made to many types of fibers and textile width of the fabric can be changed somewhat in
materials. the heat setting process. Creases can be per-
161
162 FABRIC FINISHING AND COATING
manently set in the fabric by heat setting if mon in size formulations. Starch is not very
desired. Heat setting is used to permanently set soluble in water and must be chemically
twist and crimp in yarns. degraded in order to remove it from the fabric.
Problems or defects that may be caused by heat Starch used in sizing is often modified to improve
setting or improper control of the heat setting its properties and removability in desizing.
process include the following: Lubricants added to size formulations to enhance
the fabric manufacturing process may be more
• permanent set wrinkles difficult to remove than the size itself. Virtually
• strength loss all size formulations contain lubricants derived
• improper hand or feel in the fabric from natural fats and waxes. Virtually complete
• permanent set stains removal of these lubricants is required before the
• non-uniform dyeing fabric can be dyed. The desizing step removes
• improper fabric width or weight mostly size and not much lubricant. Most of the
lubricant is removed in the scouring process.
1.2 Singeing Fabrics containing only water soluble sizes can
be desized using hot water perhaps containing wet-
In singeing, the fibers that protrude from the ting agents and a mild alkali. Fabrics that contain
fabric are burned away to give the fabric a starch are usually desized with enzymes. Enzymes
smoother surface. Singeing is usually done by are complex organic substances that catalyze
passing the fabric through a burning gas flame at chemical reactions in biological processes. They
high speed followed by quenching in water or the are formed in the living cells of plants and animals.
desizing bath to extinguish the smoldering fibers. A particular enzyme catalyzes a very specific reac-
Alternatively, the fabric may be passed close to tion. An enzyme is usually named by the kind of
a very hot plate to ignite the protruding fibers. substance degraded in the reaction it catalyzes.
Singeing is sometimes done after scouring since Thus, enzymes that hydrolyze and reduce the
heating of the fabric in the singer can increase the molecular weight of starch are called amylases
difficulty of removing size and soil from the because they hydrolyze the amylose and amylopec-
fabric. tin molecules in starch. The hydrolysis of starch
Extreme care must be taken when singeing catalyzed by amylase enzymes produces starch
fabrics containing thermoplastic fibers. Ther- fragments that are soluble enough to be washed
moplastic fibers such as polyester melt when from the fabric. Mineral acids and oxidizing agents
singed, and the fiber ends form beads on the can also be used to degrade starch so that it can be
fabric surface. removed in desizing.
Yams, sewing threads, felts, and carpet back-
ing can also be singed. Yam singeing is usually 1.4 Scouring
called gassing.
Scouring of textile materials refers to removal
1 .3 Desizing of impurities by wet treatments so that the im-
purities do not interfere with dyeing and finish
Desizing is the process of removing the size applications. The amounts and types of im-
material from the warp yams in woven fabrics. purities present depend on the type of fiber in the
Most of the size must be removed before the material. Materials containing only synthetic
fabric can be dyed satisfactorily. Residual size fibers usually contain only the lubricants that
prevents the yams and fibers from wetting have been added to aid in manufacturing of the
quickly and can affect dye absorption in either material and soil deposited on the material in
batch or continuous dyeing. Most synthetic sizes manufacturing processes and handling. Up to 2/3
are water soluble by design so that they can be of raw wool is impurities such as suint (dried
easily washed from the fabric. Typical synthetic perspiration), dirt, and fat or grease. Most of
sizes are polyvinyl alcohol, acrylic copolymers, these impurities must be removed; so prepara-
and carboxymethyl cellulose. Starch is also com- tion of wool is quite different from and more
5.1 Dyeing, Printing and Finishing 163
extensive than preparation of cotton and syn- Cleaning of textile materials requires both
thetic fibers. removal of the soil and suspension of the soil in
Cotton contains natural impurities which must the bath. Suspension of soil in the bath to prevent
be removed in scouring and bleaching. The exact its redeposition on the substrate is just as impor-
composition of cotton fiber depends on its tant as removal of the soil in most cases.
source, maturity, and other factors. Typical com-
position of dry cotton fiber is as follows [1]: 1.5 Bleaching
a solution of sodium hypochlorite causes the materials. Fluorescent whitening agents, which
formation of hypochlorous acid which is are sometimes called optical brighteners, absorb
believed to be the active species in hypochlorite ultraviolet (UV) light. Some of the absorbed
bleaching. The pH chosen for hypochlorite energy is emitted at longer wavelengths. If the
bleaching is usually 9.5 to 10.0, but the bleach- wavelengths at which the energy is emitted are
ing action is greatly accelerated by lowering the in the visible region, the brightness of the textile
pH slightly. Hypochlorite bleaching is most often substrate is increased. If the emitted energy is in
done at room temperature, but slight heating the blue region, its addition to the light reflected
greatly accelerates the bleaching rate and by the yellowish substrate makes the substrate
reduces the concentration of hypochlorite re- appear whiter.
quired. After hypochlorite bleaching, residual Fluorescent whitening agents are like dyes in
chlorine must be removed to prevent damage to that they have affinity for the fibers to which they
the fibers. This treatment is called the antichlor are applied. Therefore, the chemical nature of
and is done with a mild reducing agent such as the fiber must be considered in selection of a
sodium bisulfite. fluorescent whitening agent.
Sodium chlorite is an effective bleach for both Fluorescent whitening agents may be added to
natural and synthetic fibers. Sodium chlorite is a the bleach bath or applied in a separate step.
white powder which when mixed with an alkali Fluorescent whitening agents are often added
such as sodium carbonate can be stored in- during the manufacture of synthetic fibers and
definitely. A solution of sodium chlorite in water are a common ingredient in laundry detergents.
decomposes when acidified and heated forming
chlorine dioxide, the active bleaching species. 1. 7 Tests for Scoured and
Cotton may be bleached with sodium chlorite at Bleached Fabrics
pH of 4.0 to 4.5. Synthetic fibers usually require
lower pH of2.0 to 4.0 and higher concentration Many different analytical methods may be
of sodium chlorite than does cotton. Thmperature useful in evaluating quality of preparation, con-
near the boiling point of water is generally used trolling preparation processes, and detecting
in chlorite bleaching. Since chlorine dioxide is damage caused by preparatory treatments [3].
very corrosive to metals (including stainless Following are some tests commonly done for
steel), fiber glass equipment is preferred for quality control and detection of problems in
bleaching with sodium chlorite. Sodium chlorite preparation processes.
is used mostly on synthetic fibers such as acrylic,
polyester, and nylon which are difficult or impos- Whiteness
sible to bleach with hydrogen peroxide. Acrylic
fibers may yellow if heat set after bleaching with Reflectance of visible light from the fabric is
sodium chlorite. compared to that from a white standard such as
various peroxygen compounds can also be used magnesium oxide. Standard methods for mea-
as bleaches. Peracetic acid may be used to bleach surement and reporting of whiteness are avail-
polyamides. Accelerated and combination de- able[4].
size/scour/bleach processes based on persulfate
and perphosphate chemistry have been devised for pH
cotton and polyester/cotton blends [2].
Fabric is extracted with water, and the pH of
1.6 Use of Fluorescent the extract is measured. A standard method for
Whitening Agents pH measurement is the AATCC Method 81, pH
of Water-Extract from Bleached Textiles.
The creamy, yellowish color of textile ma-
terials can be partially, but not completely, Absorbency
destroyed by bleaching making the material ap-
pear whiter. Fluorescent whitening agents can be Absorbency is affected by many variables.
used to further improve the whiteness of textile AATCC Method 79, Absorbency of Bleached
5.1 Dyeing, Printing and Finishing 165
Textiles uses the length of time required for the devised to detect carboxyl groups in cellulose. In
fabric to absorb a droplet of water carefully one of these methods, the fibers are dyed with
placed on the surface of the fabric as a measure methylene blue, a basic dye. Since the carboxyl
of absorbency. groups are dye sites for methylene blue, cellulose
containing carboxyl groups is dyed. The depth to
Fluidity which it dyes with methylene blue is a measure
of the carboxyl group content of a cellulose
Fluidity is inversely related to viscosity. The sample.
viscosity of a polymer solution is a function of
the molecular weight (and degree of polymeriza- 1.8 Continuous Preparation Range
tion) of the polymer. Viscosity of a solution of
cellulose in cuprammonium hydroxide (CUAM) The preparatory processes described in the
or cupriethylene diamine (CUEN) can be used to preceding sections may be done in a continuous
detect depolymerization of cellulose. The results manner by placing the appropriate stages in tan-
are usually expressed as fluidity values where dem so that the material proceeds from one stage
higher fluidity means that the molecular weight to the next without interruption. Figure 5.1
of the polymer is lower, indicating that damage shows a schematic of the process. The wet steps
has occurred. Fluidity measurement is difficult of the process are usually done in three separate
and time consuming and is not done routinely in stages-desizing, scouring, and bleaching. Knit
most plants. A standard test method is AATCC fabrics that normally do not contain sized yarn
82, Fluidity of Dispersions of Cellulose from would require only the scouring and bleaching
Bleached Cotton Cloth. stages.
Continuous preparation processes provide the
Presence of Aldehyde Groups time required for diffusion of chemicals and
chemical reactions by using J-boxes or bins to
Chemical damage from overoxidation or accumulate and hold fabric for extended periods
hydrolysis of cellulose produces aldehyde of time in a stage. J-boxes are often heated to
groups. Fehling's test may be used to detect accelerate chemical reactions and lower the dwell
aldehyde groups in cellulose. Aldehyde groups time required. Open width steamers may also be
in oxidized cellulose reduce copper ions to cop- used to heat and hold fabrics for the time required
per which is deposited on the fibers as a reddish- for chemicals to accomplish their function.
brown solid. The test can be used as a qualitative Washing of the fabric between stages is impor-
spot test or can be done quantitatively. When tant so that carryover of decomposition products
done quantitatively, the result is called the copper and chemicals from one stage to the next is
number. minimized.
Sometimes two, or even all three, stages in a
Presence of Carboxyl Groups preparation range are combined to save energy
and processing time. Combination of stages
Severe overoxidation of cellulose produces usually results in a compromise between better
carboxyl groups. Several methods have been quality of preparation with the three stage pro-
A A
c~~
~~
DESIZING STAGE SCOURING STAGE BLEACHING STAGE
A- SATURATOR
B· J-BOX
C· WASHER
cess and savings of time and energy that may be washing, laundering, dry cleaning, light, per-
achieved in a combined stage process. spiration, rubbing (crocking), atmospheric con-
taminants, weathering, and other conditions are
1.9 Mercerization all important. The end use of the product deter-
mines the level of importance and what particular
The process of treating cotton with a con- type of fastness properties a textile product must
centrated solution of sodium hydroxide is called have. For example, colorfastness to dry cleaning
mercerization because it was discovered by John may not be very important for fabrics going into
Mercer in 1850. Treatment of cotton with alkali automotive seat covers, but lightfastness require-
has many beneficial effects including: ments might be very high for this application.
Uniformity and colorfastness requirements
• increased tensile strength
are major determining factors in selection of dyes
• increased softness
and dyeing methods for textile materials. The
• increased luster (if done under tension)
task that must be accomplished in dyeing is to
• improved affinity for dyes
transfer dye from the dyebath to the fiber. The
• improved dyeability of immature fibers
term exhaustion is used to express the degree of
• higher water sorption
dye transfer from dye bath to fiber. Exhaustion is
The chemical effect of concentrated caustic usually expressed as a percentage of the amount
soda solutions is unusual because the crystalline of dye originally placed in the dyebath. For ex-
as well as the amorphous regions of the fiber are ample, if 3/4 of the dye originally added to the
affected while most beneficial treatments of cot- dyebath transfers to the fiber, the exhaustion is
ton affect only the amorphous regions of the 75%. For economic and environmental reasons,
fiber. Treatment of cellulose with caustic soda a high degree of exhaustion is desirable. Dyes are
forms soda cellulose. expensive, and dye which is left in the bath is
wasted. Furthermore, dye left in the dyebath is a
Cell-OH + NaOH- Cell-O-Na+ + H20 pollutant which must be controlled and disposed
of along with the wastewater from the plant.
(5.1)
Often auxiliary chemicals are added to the
dyebath to improve exhaustion.
Subsequent neutralization of the soda cel-
Dye distributes between the dyebath and the
lulose regenerates cellulose forming a hydrated
fiber because it has an inherent attraction for both
cellulose which when dried has a slightly dif-
of these phases. The attraction of dye to the fiber
ferent arrangement of the glucose units in the
is often referred to as the affinity of the dye.
crystal structure than does unmercerized cel-
Actually, the dye has affinity for both the fiber
lulose. This change in the crystal structure is
and the dyebath. The driving force for transfer
responsible for the difference in properties of
of a dye molecule from one phase to the other
mercerized and unmercerized cotton. Mer-
(dyebath to fiber or fiber to dyebath) is the con-
cerization of fabrics is usually done in a con-
centration of dye in the two phases. Since dye
tinuous process.
adsorption is concentration dependent, the rela-
tive amounts of dyebath and fiber used influences
2. DYEING the exhaustion.
The term liquor-to-fiber ratio or just liquor
2.1 Dyeing Principles ratio is used to express the relative amounts of
dyebath and fiber. The liquor ratio is the mass of
Colorfastness properties of colored products dyebath used per unit mass of material being
have a direct impact in the everyday use of textile dyed. If one kilogram of dyebath is used per 0.1
products. The color must be durable for the life kilogram of material being dyed, the liquor ratio
of the product in many cases or in other cases is 10 to 1. Liquor ratio varies over a wide range
must fade in a predictable and pleasing manner depending on the type of dyeing process and
with use. Colorfastness of the dyed material to equipment used. Typical values range from
5.1 Dyeing, Printing and Finishing 167
about 50- 1 for some batch processes to as low Hydrophobic fibers like polyester and some
as 0.3-1 for some continuous processes. Low polyamides do not swell much in water. Water
liquor ratio, smaller amount of bath relative to plays a less active role in the dyeing of these
the amount of fiber being dyed, gives higher fibers. Water may still be needed as the medium
dyebath exhaustion other factors being equal. to dissolve the dye so that the particles or
Therefore, utilization of dye is usually better molecules of dye are small enough to diffuse into
under lower liquor ratio dyeing conditions. the fibrous polymer. Water may also serve as the
Many factors determine the optimum liquor ratio heat transfer medium in dyeing of polyester
for a given dyeing process. which is often dyed at temperatures of about
130° C. In continuous dyeing of polyester, water
2.2 Dyes in Water is simply the medium through which dye is
deposited on the surface of the fibers and serves
The two general types of dyes with regard to no active role in transporting dye into the fibers.
their behavior in water are ionic dyes and non-
ionic dyes. Ionic dyes may be either anionic or 2.4 Dyes in the Fiber
cationic. In anionic dyes the part of the molecule
primarily responsible for color has a negative Dyes and the fibers to which they are applied
charge, Dye-Na+. In cationic dyes, the colored usually have an inherent attraction for one
part of the dye molecule is positively charged, another. This natural attraction promotes trans-
Dye+cl-. fer of dye from the dyebath to the fiber and is
Non-ionic dyes do not interact strongly with sometimes important in holding the dye in the
water and are usually used as dispersions in fiber. Dyes are attracted to fibers because of
water. Although non-ionic dyes are usually chemical interactions between the dye molecule
thought of as being insoluble in water, they are and the fiber. The bonding between the dye and
often very slightly soluble in water. This fibers may result from weak secondary interac-
solubility, although small, may be vital to adsorp- tions such as hydrogen bonding or van der Waals
tion and diffusion of dye in the fiber. Non-ionic forces.
dyes are manufactured to have very small par-
ticle size and are formulated with surfactants so 2.5 Variables in Dyeing
that they are easily dispersible in water.
Because of the complex interactions of the
2.3 Fibers in Water components in a dyeing system, many variables
must be controlled in order to produce high
Water is usually the dyeing medium. Hy- quality dyeing. Variables in dyeing may be of
drophilic fibers like cotton, rayon, and wool several types including substrate variations,
attract water. Water molecules diffuse into the variations in chemicals (including water), varia-
amorphous regions of the fiber and break internal tions in preparation of the substrate for dyeing,
hydrogen bonds. Swelling of the fiber results. and procedural variations.
Swelling of the fiber by water may also be im- Several types of substrate variations may
portant in dyeing of some of the more cause variations in dyeability of textiles. Cotton
hydrophilic synthetic fibers such as nylon. maturity is an excellent example of a variation in
Swelling increases the size of openings and in- raw material that can have a major effect on
creases the mobility of the polymer molecules in dyeability. The secondary wall in the immature
the amorphous regions of the fiber making pos- cotton fiber is not completely developed. Since
sible the diffusion of dye into the fibers. Swelling dyes adsorb on the cellulose molecules in the
of the fiber in water is enhanced by higher fiber, immature fibers do not dye the same as
temperature. The effect of temperature on swell- mature fibers. Different dyes are adsorbed to
ing of fibers in water is probably a major reason different degrees on very immature cotton fibers.
why increasing dyeing temperature increases Although the synthetic fiber manufacturer
dyeing rate. may have good control over the manufacturing
168 FABRIC FINISHING AND COATING
process, synthetic fibers are subject to some dyes that migrate and level easily also tend
variations which affect dyeability. For example, to have poorer washfastness than dyes that
the manufacturer of synthetic fibers such as do not migrate and level well.
nylon and acrylics builds in a specific number of
dyesites during polymer synthesis. A small A hypothetical dye cycle is shown schem-
variation in the number of dyesites in these fibers atically in Figure 5.2. Actual dye cycles vary
can affect the dyeability of the fibers with certain greatly depending on the type of dye and fiber as
types of dyes. Variation in dyeability resulting well as the type of equipment used. In a typical
from differences in number of dyesites in the dyeing procedure, the dyebath and the material
fiber come from differences in affinity of the to be dyed are placed in contact. The system is
fiber for the dye. Such differences cannot be then gradually raised to some predetermined
corrected by dyeing for longer times or at higher temperature over a predetermined period of
temperatures. By judicious dye selection, the time.
dyer can sometimes compensate for these fiber The system is held at this elevated temperature
differences that are related to affinity for dyes. for some period of time after which the dyebath
Variation in yarn and fabric structure can also is drained or washed away. The system may be
cause dye defects. For example, wetting and dye cooled some before the dyebath is drained. Re-
uptake in highly twisted yarns will usually be quired aftertreatments are then done to the dyed
slower than that in soft twist yarns. In continuous material.
dyeing or non-equilibrium batch dyeing, these
differences can cause streaks or other dye
defects. Incorrect blend level in a blended yarn 2.7 Dyes
can cause dyeing differences. Contamination by
either fibrous or non-fibrous substances can also Colorants for textile materials may be clas-
cause dyeing defects. sified as either dyes or pigments. The terms dye
and pigment, while almost interchangeable in
common use, have distinctly different meanings
2.6 Adsorption of Dye from in coloration of textiles. A dye is a substance
the Dyebath which at least during some stage of its application
has inherent affinity for the textile material. Dyes
Several distinct identifiable events take place are soluble in the dyeing medium during or at
in the dyeing of a textile material. The events are least in some stage of dyeing process. A pigment
as follows: is simply a substance used to impart color and
which does not have inherent affinity for the
(1) Diffusion in solution-Dye must move or
diffuse through the dyebath in order to estab-
lish contact with the textile material being
dyed.
(2) Adsorption on fiber surface- Dye molecules
are attracted to the fiber and are initially
deposited on the fiber surface.
(3) Diffusion in the fiber- Dye deposited on the
surface creates a concentration gradient
which is the driving force for movement of
dye from the surface toward the interior of
the fiber. During diffusion, dye molecules 10 20 30 40 so 60 70 80 90 100 11 0 120
Acid dyes contain acidic groups, usually Basic dyes are sometimes called cationic dyes
-S03H, and are used on fibers containing basic because the chromophore in basic dye molecules
groups that can interact with these acidic groups. contains a positive charge. These basic or
The fibers that are dyeable with acid dyes are cationic groups react with acidic groups in
polyarnides containing some free amino, - NH2, acrylic, cationic dyeable polyester, cationic dye-
groups. Nylon is the most important synthetic able nylon, or occasionally protein fibers. A
fiber having this characteristic. Wool, silk, and limitation of basic dyes is that their fastness to
other protein-based natural fibers also have light is sometimes not satisfactory, especially on
amino groups that can bond with acid dyes. The protein fibers.
bonds formed between the dye and fiber are salt Although they can be applied to other fibers,
linkages. the major use of basic dyes is on acrylic fibers
which have sulfonic acid groups in their struc-
Fiber-NH2 + HS03-Dye- Fiber-NH3+_ tures. Since the number of dye sites is limited,
S03-Dye the amount of dye that can be absorbed by acrylic
Fiber with basic Dye with acidic Dyed fiber with salt fibers is limited. Basic dyes in mixtures must be
amino group sulfonic acid linkage between dye and
group fiber carefully selected to avoid incompatibility which
may cause non-uniform or otherwise unsatisfac-
(5.2) tory dyeing.
In nylon the dye sites are mainly the amino end Disperse Dyes
groups on the polyamide molecule. Wool and
other protein fibers have amino groups in the side Disperse dyes are used mostly for polyester,
chains of amino acid units which make up the nylon, and cellulose acetate although they will dye
polypeptide molecules. some other fibers. The name disperse dye comes
Nylon is a thermoplastic fiber. The rate of from the fact that these dyes are almost insoluble in
dyeing of thermoplastic fibers is very dependent water and have to be dispersed in water to make the
on dyeing temperature. Acceptable rate of dyebath. Disperse dyes were developed when cel-
dyeing is achieved only at temperatures well lulose acetate was first marketed. Disperse dyes are
above the second order transition temperature of the only acceptable dye class for acetate and un-
the polymer. In the case of nylon, the absorption modified polyester fibers.
of dye by the fiber begins as low as 40°C and is The most widely accepted mechanism for dis-
rapid at temperatures below the boiling point of perse dyeing of hydrophobic fibers contends that
water. Therefore, dyeing can be done at tem- the fiber absorbs dye molecules that are dis-
peratures below 100°C and pressurized dyeing solved in the dyebath. When a dissolved dye
equipment is not required. Although nylon is molecule is absorbed from the dyebath, it is
readily dyeable at temperatures below 100°C, replenished by a molecule of dye from the dis-
higher dyeing temperature increases the migra- persion of dye particles in the dyebath.
5.1 Dyeing, Printing and Finishing 171
movement of the material being dyed. Fiber, the latter stages of the range using a pad-steam
yarn, and fabric can all be dyed in machines process.
which hold the material stationary and circulate Fabric which was previously prepared for
the dyebath. Jet dyeing is the best example of a dyeing enters the dye range from rolls. A scray
machine that circulates both the fabric and the is used to accumulate fabric entering the range so
dyebath. Other examples of batch dyeing ma- that the range can continue to run while a new
chines are becks, jigs, package dye machines, roll offabric is sewn to the end of the strand being
skein dye machines, beam dye machines, paddle run. Uniformity of application of dye requires
machines, rotary drums and tumblers. that continuous dyeing be done in open width.
Typical line speed in a continuous dyeing is 50
Continuous Dyeing Processes to 150 meters per minute.
up in a separate container. After dyeing, each by a blade or roller called a squeegee through a
individual warp is back wound onto a warper permeable screen onto a fabric underneath the
beam (section beam) and becomes a supply pack- screen. Screen printing may be done with either
age for the slasher. flat or cylindrical screens.
The printing mechanism in roller printing
3. PRINTING (gravure printing) is intaglio. A print roller is
engraved with a pattern. Color deposited in the
Printing produces localized coloration of tex- engravings is transferred to the fabric in the
tile materials. Each color applied in a printing printing process.
process must be applied in a separate step or
position in the printing machine. Printing meth- 4. FINISHING
ods may be classified as direct, discharge, or
resist. Finishing is a general term which usually
refers to treatments on textile fabrics after dyeing
(1) Direct printing-Dye in a thickened for- or printing but before the fabrics are cut and sewn
mulation is applied to selected areas of the into final products. However, many of the finish-
fabric producing a colored pattern. ing principles covered in the following sections
(2) Discharge printing- A discharging agent apply to treatment of yams and garments as well.
destroys dye on selected areas on a fabric Finishes have a wide variety of functions all of
which was previously dyed a solid shade. A which are intended to make the fabric more
white pattern remains where the dye was suitable for its intended use. Functions of fin-
discharged. Alternatively, a discharge for- ishes include the following:
mulation containing dyes that are resistant to
• Accentuate or inhibit some natural
discharging produces a second color where
characteristic of the fabric. Examples are
the discharge is applied to the previously
softening, stiffening (firming),
dyed fabric.
delustering, brightening, and changing
(3) Resist printing-Dye is applied to a fabric surface characteristics.
but not fixed. A resist formulation is printed • Impart new characteristics or properties
on selected areas of the fabric. The resist to the fabric. Durable press finishes,
agent prevents fixation of the dye in sub- flame retardant finishes, and many other
sequent processing. The unfixed dye is chemical treatments are examples of
washed away leaving a white pattern. If the finishes which impart new characteristics.
resist agent is applied before the dye, the • Increase life and durability of the fabric.
method is called a preprint process. If the dye • Set the fabric so it maintains its shape
is applied first followed by the resist for- and structure.
mulation, the method is called an overprint • Set dyes.
process.
Finishes may be categorized as mechanical or
Printing methods may also be classified ac- chemical. Often, mechanical finishing is thought
cording to the process used to produce the pat- of as modification of dry fabric by a machine and
tern. Screen printing and roller (gravure) chemical finishing as treatment of fabric with
printing are the two most common printing aqueous solutions of chemicals. However, this
methods used in textiles. Ink jet printing, heat distinction sometimes fails because water and
transfer printing, and methods based on reliefs chemical formulations are often used in treat-
are also practiced in textiles. ments that are best classified as mechanical
Screen printing uses the principle of stencils. finishes. Furthermore, most chemical finishes
It is a resist method in the sense that the screen is involve the use of machines which subject the
made to resist penetration by the print formula- fabric being finished to various degrees of
tion in areas where printing is not desired. Dye mechanical action. Perhaps finishes can best be
or pigment in a thickened formulation is forced classified as mechanical or chemical depending
174 FABRIC FINISHING AND COATING
on whether the mechanical treatment or the in woven fabrics is mostly lengthwise (warp
chemicals added are most responsible for impart- direction) rather than width wise, compressing
ing the desired characteristics to the fabric. Some the filling yarns closer together stabilizes the
overlap in classification of finishes as mechani- fabric against further shrinkage. The term com-
cal or chemical may be inevitable. pressive shrinking is used because the process
mechanically pushes the yarns in the fabric
4.1 Mechanical Finishes closer to one another. Sanforizing is the best-
known compressive shrinkage process. Fig-
Calendering ure 5.4 shows the principle of compressive
shrinkage.
Calendering consists of passing the fabric be- The thick rubber belt passes around a small
tween rolls under pressure. Luster of the fabric guide roller which causes the rubber to stretch
is increased because the yarns are flattened extending the belt on its outer radius. The heated
making the fabric surface smoother and better shoe presses the previously wetted fabric against
able to reflect light. Adding moisture to the the stretched surface of the rubber blanket as
fabric and heating the calender rolls accentuate the fabric enters the compressive shrinkage
the effects of calendering. machine. When the belt straightens as it emerges
Calender rolls may be steel, paper covered, from the compression zone, it relaxes and con-
rubber covered, polished or engraved, cold or tracts. Since the fabric is held firmly against the
heated depending on the surface characteristics belt, the filling yarns move closer together so the
desired in the fabric. The rolls on a calendering fabric conforms to the shorter length of the
machine are sometimes called bowls. A simple relaxed belt. The thickness of the blanket deter-
calender usually has three bowls while a more mines the degree of compression achieved.
complex, high production calender may have Fabric is dried on a cylinder before leaving the
several rolls allowing multiple nips of the fabric. compressive shrinkage machine. The compres-
One of the rolls at each nip point in a calender sive process must be controlled so that the
must be a compressible material such as rubber residual shrinkage is slightly less than 1%. If
or paper so that thick places in the fabric are not compression of the fabric is excessive, the pre-
damaged. shrunk fabric will stretch when laundered.
In simple calendering the rolls run at the same
speed and simply press the fabric. In friction Raising
calendering the surface speed of the rolls is dif-
ferent. Friction calenders polish the surface of Raising refers to the lifting of fibers from
the fabric producing a shiny effect. yarns near the surface of the fabric to produce a
hairy or fuzzy surface. Teaseling, napping, sued-
Mechanical Stabilization ing, and shearing are names commonly used for
specific raising processes. Napping uses small kle. Wrinkling occurs when the fiber is severely
wires to pluck fibers from the yarns near the bent. Hydrogen bonds between the molecular
fabric surface. chains in the amorphous regions of the fibers
Either one or both sides of a fabric may be break allowing the chains to slip past one another.
raised in napping, and the fabric may be pro- The bonds reform in new places and hold creases
cessed through the napper more than once to in the fiber and fabric.
achieve the desired effect. Napping must be con- Resistance to creasing is imparted to cellulosic
trolled well to prevent excessive strength loss in fibers by restricting the slippage of molecular
the fabric. Napped fabrics are very soft. The air chains. Chain slippage can be restricted by add-
pockets between the raised fibers in a napped ing chemical crosslinks between the molecular
fabric produce a good insulating effect making chains in the amorphous regions of the fiber or
napped fabrics warm to wear. by deposition of a polymeric substance in the
Sueding subjects the fabric to sandpaper amorphous regions. Permanent creases may be
covered rolls producing a surface resembling placed in a fabric by creasing the fabric at the
suede leather. Suede cloth may be raised on desired location before the crosslinks are
either one side or both sides. formed.
Shearing is used to cut away a portion of the Durable press (DP), wash-and-wear, crease
fibers on a fabric having a raised surface to resistant, wrinkle free and other terms are used
produce a level fabric surface. Cut-pile carpet is for easy-care finishes. DP finished fabrics may
commonly sheared to level the tuft length. still form creases while the product is being used
but are designed to return to a smooth and crease-
Mechanical Softening free configuration after washing and drying.
Since crosslinking affects the mobility of the
Fabrics are stiff if the fibers and yams are not molecular chains in the amorphous regions of the
flexible and able to move freely in the fabric fiber, many properties of the fiber are affected.
structure. Drying of fabrics under tension tends Furthermore, durable press resins are reactive
to set fibers making them stiffer and chemicals, substances and may themselves undergo changes
agents such as size materials, printing thick- as treated fabrics age. Some effects of applica-
eners, film forming finishes, and durable press tion of durable press finishes are as follows:
finishes bind fibers and yams together making • Flexibility, tensile strength, tear strength,
the fabric stiff. and abrasion resistance of the fabric are
Mechanical softening simply consists of bend-
usually decreased.
ing, flexing, or pounding the fabric to cause • Swelling in water is inhibited, and the
adhesions between the fibers and yams to break. fibers are less absorbent.
A variety of machines can be used for mechanical • Since dyes and other chemicals cannot
softening. penetrate crosslinked fibers easily,
dyeing must usually be done before the
Flocking crosslinking finish is applied.
• On the positive side, crosslinking helps
Flocked fabric is made by gluing short fibers
to trap dye molecules in the fiber and can
to the surface of a base fabric. Flock can be thereby enhance the washfastness of the
applied to the entire surface of the fabric to
dye.
produce a raised surface or to only certain areas • Durable press finishing may accentuate
to produce a pattern (Section 4.8). soil retention by the fabric.
ing agents. Problems with odor, chlorine re- gases. If the amount of heat produced by the
tention, lightfastness of dyes, and dye shade burning gases is sufficient, further decomposi-
changes are usually minimized by judicious tion of cellulose takes place, and combustion is
selection of the finish and dyes. self-supporting. One of the tarry components of
the decomposition of cellulose is levoglucosan.
Flame Retardant Finishes Upon further heating, levoglucosan decomposes
to low molecular weight flammable gases.
A limitation of many textile fibers, especially Treatment of cellulose (and other fibers) with
cellulosics, is their tendency to burn readily. certain chemicals alters the mechanism of ther-
Flammability of textile products is regulated by mal decomposition so that combustion is not
federal and state governments. The federal self-supporting. Therefore, when the ignition
Flammable Fabrics Act of 1953 requires virtu- source is removed the flame extinguishes.
ally all textile products to meet minimum stan- Generally, flammability standards require that
dards of flame retardancy. A series of textile products be self-extinguishing under
amendments to the Flammable Fabrics Act of specified conditions. This means that the
1953, require children's sleepwear, carpets, and material must not support combustion for very
mattresses to meet stringent standards for resis- long after the ignition source is removed even
tance to burning. though it may continue to burn as long as an
Textile fibers vary greatly in flammability. All external ignition source is present.
organic fibers burn if the conditions are severe Several chemical treatments have been used
enough. Cellulosic fibers ignite at relatively low successfully as flame retardants on textile
temperature and burn rapidly. Polyamide and materials. However, inherently flame retardant
polyester fibers do not ignite easily because they fibers are used in lieu of chemical treatments in
melt and recede from a flame. However, in a many applications requiring flame retardancy
blend with cellulosic fibers which prevent them because of questions regarding threats of chemi-
from receding from the flame they burn cal flame retardant treatments to human health.
vigorously. Often a blend of cellulose with a Flame retardant chemical treatments may be
synthetic fiber will burn more readily than a non-durable or durable. Non-durable treatments
fabric made from either of these individual fiber may be used where the treated material will not
types. Acrylic fibers are difficult to ignite but be exposed to water or where only temporary
burn rapidly with much evolution of heat after flame retardance is needed. Durable treatments
ignition takes place. Wool has a high ignition are used where the fabric must be washed. Flam-
temperature and low heat of combustion mak- mability standards for apparel and household
ing it naturally flame retardant. Aramid and textiles require that the treatments be durable to
modacrylic fibers are very flame retardant, and laundering.
most of their uses are the result of their outstand- Simple water soluble acidic ammonium phos-
ing resistance to thermal decomposition. phates, ammonium chloride, borax/boric acid
Three conditions must exist for textile ma- mixtures and other inorganic salts function as
terials to support combustion. There must be a non-durable flame retardants. These chemicals
source of ignition, oxygen, and a fuel source (the are believed to inhibit the formation of levo-
textile material). Generally, not much can be glucosan when cellulose decomposes. There-
done about sources of ignition and elimination of fore, less volatile gases and more solid char are
oxygen in the vicinity of textile materials so the formed, and burning is impeded. Additionally,
propensity of the textile fiber to burn must be the borax/boric acid treatment may form a thin
altered in order to make the material flame retar- glassy coating on the fibers excluding the oxygen
dant. required for combustion of the fibers.
When the temperature of cellulose is raised to Durable flame retardant finishes based on the
about 350°C by the ignition source, cellulose presence ofboth nitrogen (N) and phosphorus (P)
begins to decompose producing solid char, liquid are effective on cotton. Like the non-durable
products called tar, and a mixture of combustible flame retardants, the durable N/P flame retar-
5.1 Dyeing, Printing and Finishing 177
dants are believed to inhibit the formation of not block the interstices. Therefore, the fabric
volatile decomposition products when cellulose remains porous to air and water vapor.
is pyrolyzed by preventing the formation of Some important types of water repellent fin-
levoglucosan. The most common NIP flame ishes are wax emulsions, pyridinium com-
retardant system uses tetrakis (hydroxymethyl) pounds, N-methylol compounds, silicones, and
phosphonium chloride as the source of phos- fluorochemicals. These finishes may be used to
phorus. impart water repellency to various natural and
The sulfate may be used in lieu of the chloride. synthetic fibers.
In this case the material is referred to as THPS. Wax emulsion formulations usually contain a
THPC and THPS react with cellulose and are zirconium salt such as zirconium acetate in addi-
thus durable to washing. These substances also tion to the wax and emulsifying agents. Addition
react with amino groups to form polymers within of film forming polymers or crosslinking reac-
the fiber. Amino compounds commonly used as tants to wax emulsion formulations improves the
the nitrogen source in NIP flame retardant sys- durability of the wax emulsion water repellent
tems are methylolated urea and melamine. finish.
Nitrogen/phosphorus flame retardant systems Pyridinium-type water repellents consist of a
containing the nitrogen and phosphorus atoms in long chain hydrocarbon group attached to a
the same molecule have also been successful. pyridinium ring. The pyridinium compound
Antimony/halogen treatments also produce reacts with cellulose leaving its hydrocarbon
durable flame retardants. The fabric is treated group attached to the fiber. The resulting fiber
with a mixture of antimony oxide, a chlorinated surface is more hydrophobic and water repellent.
wax, and a binder chemical. Antimony/halogen N-methylol groups can also be used to chemi-
flame retardants are believed to function either cally attach a long hydrocarbon group to fibers
by scavenging free radicals which propagate making the fibers water repellent.
combustion or by a dehydration mechanism Polymerized siloxanes are good water repel-
which promotes the formation of solid char lents. Dimethyl polysiloxane, methyl hydrogen
during the thermal decomposition of cellulose. polysiloxane, or a mixture of these two sub-
stances is often used.
Application of Flame Retardants Fluorochemical finishes impart both water
repellency and oil repellency to fabrics while the
Flame retardant finishes are usually applied by silicone and repellents based on hydrocarbon
a pad-dry-cure process. Some flame retardants hydrophobes provide only water repellency. The
for synthetic fibers have affinity for the fibers performance of fluorocarbon repellents results
and can be applied by exhaust methods. These from the very low surface energy surface that they
types of finishes may be applied in a batch produce. The surface of the fibers must be
process immediately after exhaust dyeing. covered by the fluorocarbon groups. Fabrics con-
taining fluorocarbon finishes are often referred to
Water and Soil Repellent Finishes as being stain repellent or stain resistant.
so that adhesion between the fiber and hydro- strength by decreasing fiber cohesion. On the
phobic soil is lowered. other hand, softeners usually improve abrasion
Several approaches have been used to increase resistance and tear strength of fabrics. Abrasion
the hydrophilic nature of cellulose fibers. The resistance is improved because oflubricity of the
surface of polyester can be modified by grafting fabric surface or improved mobility of fibers in
on a substance having hydrophilic tails. Partial the softener-treated fabric. Tear strength is im-
hydrolysis of the polyester surface forms proved because of better mobility of fibers so that
hydrophilic carboxyl groups. One approach to the load imparted by tearing action is better
improving the hydrophilicity and soil release distributed over the individual fibers in the
capabilities of polyesters is the use of am- fabric.
phiphilic substances. These substances are either Synthetic fibers such as nylon and polyester
non-ionic surfactants where the hydrophile- tend to accumulate static charge because they
lipophile balance has been judiciously selected or absorb little water. On the other hand, cellulosic
block copolymers containing both hydrophobic fibers having higher moisture content tend to
and hydrophilic blocks. The hydrophobic part of dissipate static charge. Surface active agents help
the finish molecule has affinity for polyester and to spread the small amount of moisture on the
is sorbed into the fiber much like a disperse dye. surface of fibers into a continuous ftlm which can
The hydrophilic part does not have affinity for dissipate charge. Therefore, surfactants used as
polyester and extends outward from the fiber softeners are also effective as antistatic treat-
surface making the surface more hydrophilic. ments. Cationic, anionic, non-ionic surfactants
High application temperature is required to all exhibit some antistatic behavior. The dur-
achieve good penetration and bonding of these ability of antistatic treatments is improved by
agents to polyester. using them along with N-methylol compounds
Soil release agents in durable press finishes are which chemically bond them to the fibers.
often anionic polymers, fluorocarbon polymers, Hand building is the opposite effect of soften-
or mixtures of the two. Copolymers of acrylic ing. Hand builders add stiffness to the fibers and
and methacrylic acid are effective as soil release fabric. Agents that stiffen fibers, bind fibers
agents when co-applied with durable press together, or increase interfiber friction all
finishes or top-applied to durable press-finished produce stiffness. Hand builders usually in-
fabrics. Soil release finishes for durable press crease tensile strength and abrasion resistance of
finishes are often not entirely satisfactory. fabrics but may decrease tear strength because of
increased stiffness in the fabric.
Softeners, Antistatic Agents, and
Hand Builders Antimicrobial Finishes
The way a fabric or garment feels to the touch Growth of bacteria and fungi in textile fabrics
is referred to as its hand. Hand of fabrics is is usually undesirable. Laundering with hot
subjective to some extent and is often difficult to water and use of disinfectants such as chlorine or
describe meaningfully with words. Neverthe- peroxygen bleaches destroys many microor-
less, hand is important, and hand modification is ganisms in textile products. Chemicals that
one of the most common goals of finishing of prevent growth of bacteria and fungi are referred
textiles. to as antimicrobial agents. Many chemicals are
Treatments that make the fabric more flexible effective antimicrobial agents for fabrics used in
and pliable impart the impression of softness. environments where growth of microorganisms
Softness generally comes from making the fibers must be prevented. Quaternary ammonium sur-
themselves more flexible and from decreasing factants and antibiotics function as antimicrobial
interfiber friction. Therefore, agents that plas- agents. Many chlorinated organic compounds
ticize fibers and lubricate the surface of fibers and organometallic compounds containing cop-
produce softness. Since softeners lubricate per, silver, iron, manganese, or zinc also make
fibers, they may decrease yarn and fabric tensile textile materials resist growth of microor-
5.1 Dyeing, Printing and Finishing 179
ganisms. However, many of these agents are also Therefore, the wet pickup must be controlled
toxic to higher organisms and may resist across the width and along the length of fabric in
degradation in the environment for long periods order to achieve uniform add-on of chemicals.
of time. Chlorinated organic compounds are also Applicators in textile chemical processes in-
effective in inhibiting attack of insects on natural clude padder, kiss rolls, foam applicators, wired
fibers composed of protein and cellulose. blade applicators and vacuum extraction ap-
AATCC Method 100, Assessment of Antibac- plicators.
terial Finishes on Textile Materials is a standard
method to evaluate the above products. 5.1 Dryers
5. TEXTILE CHEMICAL PROCESSES Textile materials are usually wetted and dried
several times in preparation, dyeing, and finish-
Chemical treatment of textile materials is done ing processes. Moisture can be removed from
in batch, continuous, and semicontinuous pro- textile materials to some extent by mechanical
cess. The principles discussed below can be ap- methods such as squeezing, centrifugal extrac-
plied to various processes including slashing, tion, or vacuum extraction. These mechanical
preparation of materials for dyeing, dyeing, and methods remove only the moisture which is very
chemical finishing. loosely bound to the textile material such as that
A batch process treats a specific amount of which is located in the interstices between the
material with chemical formulations for a yarns comprising the fabric. Water droplets
specific length of time. Several different treat- trapped within the fibers and yams and water
ments may be done sequentially by draining and molecules bound to the fibers by secondary
refilling the bath between treatments. The com- forces such as hydrogen bonding are not remov-
plete process may all be done in one machine or able by mechanical means and must be vaporized
the batch may be transferred from one machine in order to be removed from the material during
to another for various steps in the process. Batch the drying process.
wet processing machines for fiber, yam, fabric, Vaporization of water requires a large amount
and garments are discussed earlier in Dyeing of energy so good removal of loosely bound
Processes. water using mechanical means usually is de-
Continuous processes treat materials by pass- sirable to minimize cost of drying. Most drying
ing the material in a continuous strand through processes for textile materials use thermal en-
one or more processing steps arranged in tandem. ergy. The thermal energy heats water in the tex-
The amount of chemicals applied to the fabric tile material. As the temperature of the water
(add-on) at the padder depends on the concentra- rises, water molecules begin to vaporize and
tion of chemicals in the formulation and the wet escape into the atmosphere around the material.
pickup. Wet pickup is the amount of formulation Mechanisms for heat transfer to textile materials
picked up by the fabric and is usually expressed are classified as follows:
as a percentage on weight of the dry fabric
Indirect: Convection
Wet pickup (%) = Conduction
Irradiation
Weight of formulation picked up 100 Direct: Dielectric
Weight of dry fabric x Microwave
(5.3) Radio Frequency
In conduction heating, heat is transferred from a ture of about 100°C and maintain this tempera-
hot surface to the material to be dried by contact ture for the required processing time. Steam is
between the hot surface and the material being admitted from a boiler. The pressure in the
dried. Both convection drying and conduction steamer should be slightly higher than the pres-
drying often use steam to deliver the energy to sure of the atmosphere outside the steamer to
the point of drying. Radiant drying, or drying by prevent entry of air into the steamer. Boiling
irradiation, uses a source with a high content of water in the bottom of the steamer keeps the
infrared waves. Water molecules absorb infrared steam saturated with moisture. When cold wet
energy causing the water to heat and vaporize. fabric contacts steam, the steam condenses on the
Dielectric heating is classified as direct heating fabric transferring its heat to the fabric. If the
because it is electric energy which vibrates the steam is superheated (not saturated), condensa-
entire water molecule causing molecular friction tion will not occur and the steam may actually
and generating heat inside the wet textile ma- dry the fabric. Drying of the fabric in the steamer
terial. usually adversely affects quality of the material
being processed. Air must be excluded from a
5.2 Steamers steamer since it decreases the transfer of heat to
the wet fabric. Air is excluded by maintaining a
Steamers are commonly used in continuous slight positive pressure in the steamer and by
wet processes to rapidly heat fabric to a tempera- using caution with exhaust fans near the steamer.
5.2
Coating and Laminating
C. G. NAMBOODRI
S. ADANUR
A coated industrial fabric consists of a closely used in coating. A woven fabric can be plain,
woven or knit base fabric that is coated on one or twill or sateen construction (Section 4.3). The
both sides with a man-made or natural elastomer. knitted fabrics can be warp knits or tubular knits
For some applications, such as life rafts and diving finished and slitted. Cut edges are treated with
suits, an interply of polymer may be sandwiched resin to prevent stitch running. The nonwoven
between two fabric layers which may be called a fabrics could be stitch bonded, spunbonded or
laminated product by coating (Figure 5.5). A needlepunched constructions. Tufted fabrics are
simple laminated industrial fabric is a sandwich also back-coated to prevent unraveling of tufts
construction made of a loosely woven or knit fabric and to impart dimensional stability.
(scrim) that is locked between two sheets of ther- The choice of fiber, size of the yam and type
moplastic or rubber elastomer. The open scrim of weave for coated fabrics determine the fabric
fabric allows the outer sheets to bond to each other properties. The yam and fabric construction in-
at the interstices (Figure 5.6). With the lamination fluences the durability of coating. The fiber
process, many layers of fabric and other substrates selection is critical as to the bonding of polymer
can be combined. Coated and laminated fabrics are compound since mechanical adhesion and
used in many industrial applications including ar- chemical bonding vary from fiber to fiber. If the
chitecture and construction, transportation, safety fiber is synthetic, spun yarn construction com-
and protective systems. pared to filament yam gives different mechanical
properties to the coated fabric.
1. COATING
Cotton
A coated fabric is a composite textile material
where the strength characteristics and other Fabrics made of cotton were the traditional
properties are improved by applying a suitably base material used in coating. This trend has
formulated polymer composition. The selection declined due to the availability of synthetics
of fiber and fabric for coating depends on the type which give improved strength characteristics as
of coating and the end-use performance require- compared to cotton. The advantages of cotton
ments. The performance standards are usually fabrics include lower cost, availability and the
set up based on biaxial strengths both tensile and excellent coating adhesion imparting dimen-
tear, abrasion resistance, stiffness, dimensional sional stability to fabric. The disadvantages of
stability, thermal stability, chemical resistance, cotton include low extensibility, poor rot, acid
water repellency and air permeability require- and weather resistance, flex cracking and limited
ments. To meet the above requirements proper shock absorption properties. Cotton has medium
choice of fiber, fabric construction and the poly- abrasion resistance. Extensibility of the fabric
meric coating compounds are needed. can be increased by tubular knit construction.
Size material is normally removed from the cot-
1.1 Fibers and Fabrics for Coating ton fabric prior to coating. Cotton is also blended
with polyester for coated lighter weight fabrics
Woven, knit, tufted and nonwoven fabrics are having improved wear characteristics.
181
182 FABRIC FINISHING AND COATING
Nylon
sional stability. As in the case of nylon the distribution, assuring balanced strength and
polyester filament yarns can be used for coating elongation. These base materials provide good
in the gray stage. For coated lighter weight sheet- tear strength, flexibility, and smooth surfaces for
ings, polyester is often blended with cotton. embossing, with no ''show through'' of weave
Nonwoven polyester coated for stability and pattern. They also provide high thickness-to-
waterproof treated is extensively used in the out- weight ratios at reasonable cost, and can be
door furniture market. calendered, laminated, or electronically heat
sealed to vinyl film. Polyester nonwoven fabrics,
back-coated for stability and coated on face with
Acrylics water and stain repellents, are used for the out-
door furniture market.
Only small usage of acrylic fabrics is found in
the coating market. Acrylic fabrics are used
where outstanding weather resistance properties 1.2 Polymers and Additives in Coating
are required. The mechanical properties of the
modified acrylics limit its application in the coat- The coating polymer or blends of polymers
ing field. Acrylics have low thermal stability and are selected based on the end-use application.
low abrasion resistance. The coating compound contains different in-
gredients apart from the base polymer to impart
the desired properties and performance charac-
Polypropylene teristics. As the need arises, the coating com-
pounds are often modified with addition of
Polypropylene has excellent mechanical newer chemicals to meet the end-use perfor-
properties under normal conditions but has poor mances of coated fabric.
thermal stability. It is used for laminating with The base polymer for coating can be natural
olefin fibers or for olefin melt coating. Poly- or synthetic rubber or rubber-like polymers.
propylene has high stre~s decay and poor coating High polymeric materials such as cellulose ester
adhesion which limits its use. Polypropylene and ethers, polyamides, polyesters, acrylics,
fabric is widely used in the carpet industry re- vinyl chloride, vinylidene chloride, poly-
placingjute backing. Polypropylene fabric tufted urethanes and natural and synthetic elastomers
with nylon or polyester yams producing carpets, and rubbers are used in compounding [5].
is normally back-coated for dimensional The mixing operation of various chemicals to
stability. produce the coating compound is commonly
known as the compounding operation. The com-
pounding can be within a coating plant or can be
Other Fibers bought from a supplier as a compounded
product. The choice of compounding chemicals
Glass, Nomex®, Kevlar® and graphite fibers and fillers are governed by the end product re-
are used in coating where high performance quirements. Besides polymers, resins and fillers,
composites are needed. These fibers possess in- other additives such as fire retardants, thickeners
herent flame retardancy and have merit in certain and coloring agents may be included in coating
applications. Polyester or nylon coated with fire formulations.
retardant compounds limits the use of costly high
performance fibers in coating.
Nonwoven fabrics of stitch bonded, spun- Natural Rubber
bonded or needlepunched constructions are used
as the base fabric for coating and film laminating. While there are many species of plants which
Various fiber combinations and binders are produce rubber-like fluids, natural rubber is nor-
selected, depending upon end-use requirements. mally accepted as being derived from the latex of
Certain nonwoven fabrics have a random fiber the cultivated tree, Hevea brasiliens. Chemi-
184 FABRIC FINISHING AND COATING
name Neoprene. An entire series of neoprenes developed and used where special properties are
(now a generic term) of specific properties is required. Some of these products are:
manufactured. Because of their higher cost than
• polytetrafluoroethylene; CFz=CFz
other natural and synthetic rubbers, their uses are (Teflon® from DuPont)
limited to special applications. Multi-filament
• polytrifluoro-monochloroethylene;
nylon and polyester fabrics are neoprene coated for
CCIF=CFz (Kel F from 3M Co.)
outdoor applications where resistances to weather-
• trifluorochloroethylene and vinylidene
ing, abrasion, and flexing over extended periods of
chloride copolymer (Kel F 3700 and
time are important factors. Colors are limited, with
5500 from 3M Co.)
black and silver commonly used. Neoprene also
• polyfluoropropylene and vinylidene
possesses good resistance to oils, greases, gasoline,
fluoride copolymer (Viton A from
acids, and alkalies. Among the uses for neoprene
DuPont and Kel F 2140 from 3M Co.)
coated fabrics are truck tarpaulins, mine ventilation
tubing, collapsible containers, portable irrigation The Scotchgard® brand of polymers from 3M
dams, protective clothing, air bags, andliferafts for and Teflon® from DuPont are both based on
boats and airplanes. fluorinated rubbers used for carpet and fabric
protective fmishing. Vi ton A is used for coatings
Chlorosulfonated Polyethylene and has exceptionally good heat resistance,
(Hypalon®) capable of withstanding temperatures as high as
600°F. It has outstanding chemical, solvent,
This synthetic rubber, which was developed fuel, and lubricant resistance at elevated tem-
by DuPont under the trade name Hypalon, was peratures.
made by adding chlorosulfonyl groups (-S0 2Cl)
to polyethylene. Available in a wide range of Polyurethane Foam
colors, including translucent forms, Hypalon
coated fabrics have outstanding abrasion and For manufacturing polyurethane foam, the
outdoor weathering resistance properties. They most popular diisocyanate used is TDI or toluene
also resist soiling and can be readily cleaned for diisocyanate. This monomer has two isocyanate
maintenance of a bright, attractive appearance. (- N = C =0) reactive groups and reacts ex-
Fabrics coated with Hypalon are used for tremely rapidly with poly hydroxy compounds or
radomes, protective clothing, truck tarpaulins, polyols commonly known in the trade as
fumigation tents, inflatable warehouses, and polyesters or polyethers to form polyurethanes
convertible automobile and boat tops. [9 -12]. In the presence of water or a blowing
agent, a foam is formed. The polyesters usually
Silicone Rubbers produce flexible foams, and the polyethers
produce rigid foams. The largest market at
The basic structure of silicone polymers is present for foamed polyurethanes is their use as
composed of silicon-oxygen linkages, rather thermal insulators for outerwear. They are
than carbon-carbon linkages. Organic carbon bonded by heat fusion or flame lamination or by
radicals or side groups are also present. Di- using adhesives to fabrics, and have particular
methy I dichlorosilane is the monomer from success when bonded to soft knit goods.
which most silicone rubbers are prepared. Out-
standing properties include high and low Urethane Coating Resins
temperature stability as well as heat resistance.
General Electric, Dow Corning Corporation, Both polyester-type and polyether-type poly-
and Union Carbide are manufacturers of silicone urethane resins have been developed for coating,
rubbers and other silicone polymers. varnishes and paints, where foaming is not in-
volved. Aqueous dispersions of polyurethane
Fluorinated Polymers resins are formulated for coating applications.
Large quantities of resins are coated from sol-
Various fluorine based polymers have been vents. Polyurethane based coatings impart sol-
186 FABRIC FINISHING AND COATING
vent resistance, improved strength, improved position to alter viscosity and other properties.
abrasion resistance, outdoor weathering resis- Hydroxyethyl cellulose is a cellulose ether and
tance and impart flexibility and softness to the carboxymethyl cellulose is an ester type of vis-
coated fabric. They can be formulated with fire cosity modifier commonly used. Viscosity mod-
retardant additives to produce flame retardant ifiers become part of the coating compound and
coated fabrics. are present in the final product.
These are synthetic resins formed by the The amount and type of f1llers used in a coating
polymerization of chemical monomers contain- compound depend on the end product. Fillers are
ing the group -CH=CHz. Polyvinyl acetate, classified as active or inactive fillers. The com-
alcohol, butyral and chloride, and mixtures or mon fillers are inactive and their use can alter
copolymers thereof, are commonly included in physical properties such as tear and tensile
this category. Polyvinyl cyanide, however, is strength and abrasion resistance. The inactive
identified by the separate term ''acrylonitrile:' fillers include, talc, carbon black, kaolin, cal-
Note that for fibers the Federal Trade Commis- cium carbonate, barium sulfate, magnesium car-
sion has assigned specific generic names to the bonate and zinc oxide. Pure silica (SiOz) is
various vinyl types; i.e., vinyon for vinyl considered an active filler whereas calcium sili-
chloride; acrylic for acrylonitrile (vinyl cyanide); cate is a semiactive filler. The inorganic and
and vinal for polyvinyl alcohol. The vinyl resins organic fire retardant additives are also con-
are also known as acrylic resins in industry. sidered as fillers in a compound.
Pyroxylin Pigments
Pyroxylin is a cellulose nitrate coating mate- Both inorganic and organic pigments are used
rial that has declined in its use due to its flam- in coating compounds if a color is needed. A
mability. It can be applied to fabrics in relatively commonly used white pigment is titanium
small amounts, having excellent film forming dioxide. Iron oxide is a typical example of an
characteristics. The use of pyroxylin coated inorganic pigment. There are environmental
fabrics was once popular as book binders in the problems in using chromium and cadmium based
past. However, it is quite flammable and with the inorganic pigments. Organic pigments are based
advent of acrylics and other types of resins, on azo dyes and phthalocyanine dyes. Brilliant
cellulose nitrate declined in importance. colors are obtained with azo pigments and they
are widely used. Generally certain blues and
Starch green colors are based on phthalocyanine dyes
which are metal complexed organic pigments.
The relatively low cost of starch is the chief
advantage of this coating material. Starch has 1.3 Coating Methods
been used in very large volume in the past, but it
is declining steadily in importance. The largest There are several methods and machinery
markets for this type of coated fabric are in the presently available for applying polymeric coat-
bookcloth. Modified starch such as starch ethers ing compounds to textile substrates. The selec-
is used as a viscosity builder in many water based tion of any one procedure is governed largely by
coating systems. the end-use requirements of the coated fabric.
The choice is also influenced by the physical and
Cellulose mechanical properties of coating and the base
fabric, together with the associated processing
Cellulose derivatives such as the cellulose economics.
ethers and esters are often used in coating com- Although a great deal of cloth is coated
5.2 Coating and Laminating 187
without preliminary treatment, for some, pre- pound containing resin, plasticizer, stabilizer,
coating preparation of the fabric is often neces- and pigments is fed to a preblender, where it is
sary. If cotton or cotton/polyester blend sub- blended to a free flowing powder. This powder
strates are used, preparatory treatment includes is then charged to a mixer, in which it is fused
desizing, bleaching, dyeing, heat setting and sur- into a plastic state. The hot plastic is then fed to
face preparations such as a chemical tie coat, to the calender, where the film is formed.
ensure adequate adhesion of the coating to the In the case of calender coating, the hot viscous
base fabric. Filament nylon and polyester fabrics resin is deposited on the two top rolls of the
are ordinarily coated in the gray state for many calender. The resin is picked up by an inter-
outdoor protective covering applications, but in mediate roller that transfers it to the fabric at the
certain critical end uses it may be necessary to pressure nip between the fabric feed roller and
scour and heat set these fabrics before coating. the intermediate roller. Two calender coaters are
Once coated, the fabric is passed through an shown diagrammatically in Figure 5.8.
oven where the excess solvent, if present, is The calender method of coating is adaptable to
evaporated, and the resin is cured. Often a lower heavy vinyl coatings as well as to light coatings
temperature is used for solvent evaporation and as low as four ounces per square yard in the case
resin drying, followed by a higher temperature of a direct fabric calendering operation. Lighter
for accomplishing the cure. Several passes weight films can be formed by this method for
through the coater may be required to build up subsequent laminating to cloth. Nearly all vinyl
the coating to the required thickness. The final coated fabrics for automotive interiors are made
pass through the oven is carried out at a higher in this way.
temperature for curing. Neoprene coated fabrics
may be cured by festooning in a hot air oven, or Flexible Film Laminating
by steaming in an autoclave. It should be noted
that solvent users must have an Environmental Flexible films, such as urethane, polyester and
Protection Agency (EPA) permit that can be ac- vinyl (previously formed on a calender as
quired through the state regulatory group. described above), are combined with fabrics on
The following section describes the principal laminating machines (Figure 5.9). The film is
coating techniques for fabrics. Figure 5. 7 shows first heated to make its surface soft and tacky so
a schematic diagram of a coating range and gives that proper adhesion of film to fabric will result.
location of the coating area and the oven. Fabric and film are then sent through heated
pressure rolls of the machine, and combining
Calendering takes place. Film patterns and surface effects can
be created at this point by use of proper emboss-
In this method, the plastic is calendered di- ing rolls. The resulting combined flexible film
rectly onto the fabric or an unsupported film is laminate is then passed over cooling drums to set
formed that is subsequently laminated to the the film. Sometimes an open mesh fabric such as
cloth in a separate laminating operation. A com- a filament nylon scrim is sandwiched between
~
2
3
fabric in
COOUNG CANS
Knife Coating
onto fairly closely woven fabric. For more deli- FLOATING KNIFE
cate fabrics which should not be stretched during FIGURE 5.10 Knife coating.
the coating operation, the knife-over-blanket
coater should be employed. However, it, too, can
only be used for fairly closely woven base fabrics
due to the coating striking through.
5. 2 Coating and Laminating 189
shape of the knife has developed from various FIGURE 5.11 Various knife shapes [13].
needs in coating. A broader knife edge gives
greater add-on (Figure 5.11).
Both plastisol and organosol formulations may coating viscosity, and the relative speeds of rolls
be applied by knife coating processes. Plastisols and fabric.
are liquid dispersions of finely divided resins in One of the practical limitations of this method
a plasticizer. Stabilizers, pigments, and fillers is the necessity to maintain a proper and constant
may also be present, but plastisols do not contain, fabric tension which will, under certain cir-
nor are they applied from, solvents. An or- cumstances, dictate low coating speeds to insure
ganosol differs from a plastisol in that it contains uniform coating application. Some of these dis-
a non-aqueous volatile solvent. advantages are eliminated in the pan-fed three-
roll reverse-roll coater (Figure 5.12). In this
Roller Coating machine the coating material is picked up from
the trough by the applicator or transfer roll B,
The simplest type of coating device is the roll
coater where a roller, rather than a knife, applies
the coating compound to the fabric (Figure
5 .12). A two-roll reverse-roll coater utilizes a
smaller diameter backup roll and doctor knife to
exert some measure of control upon the thickness COOING
of the applied coating. MATERIAL
During normal operation the large diameter TWO-ROLL REYO:RSE- ROLL (KISS!
applicator roll picks up coating material from the
trough. This picked-up coating material is then
metered according to the gap that exists be-
tween the applicator and backup roll, which
rotates in opposition. The metered coating is
subsequently applied to the substrate fabric by
the applicator roll, which runs in the reverse
direction to that of the fabric. The doctor knife,
running against the backup roll, serves to assist
the metering operation performed by the gap
between the reverse running rolls. The actual
weight of coating material applied depends not
PAN-FED THREE-ROLL REVERSE-ROLL
only upon the reverse-roll spacing, but also on
the nature of the substrate fabric, its speed, the FIGURE 5.12 Roller coating.
190 FABRIC FINISHING AND COATING
metered by the nip between the transfer roll B impregnation of the base fabric is required. A
and the reverse running metering roll C, and typical machine is shown in Figure 5.14. Several
applied to the fabric passing around the rubber lacing-up paths are shown. The actual one
roll A. chosen for any combination of coating and fabric
This coating technique is used extensively for will depend upon the impregnation time and the
the application of lacquer and vinyl coatings to number of pressure nips or reverse-roll contacts
paper, fabric, and nonwoven webs, but is not necessary to meter the coating adequately. If the
suitable for high speed coating due to the lack of coating is to be applied without the application of
adequate fluid control. pressure, a reverse-roll metering action is ex-
Perhaps the best roll coater is the pan-fed four- ecuted at the nip between rolls A and B. Other-
roll reverse-roll coater. This is similar to the three- wise, a pressure nip between rolls B and C may
roll coater described above, but it exerts a greater be employed as an alternative to, or in conjunc-
control over the metering of the coating prior to tion with, the reverse-roll metering between rolls
application to the fabric passing around the rubber A and B. One advantage of this technique is that
roll. Greater control is also exerted over the coating both the face and back of the fabric can be coated
material so that higher coating speeds may be in one pass through the coating machine.
employed in thicknesses from one to twenty mils.
It cannot be used to coat open weave fabrics due to Cast Coating
strike-through onto the rubber roll.
The cast coater combines both the coating and
Nip Coating curing operation into one process as a method of
producing a high gloss coating upon a fabric
Low viscosity coating materials can be speed- web. While the curing operation may not be quite
ily applied to fabrics using interroller pressure complete, it is sufficient to create the exception-
for both application and metering. The three-roll ally smooth coating surface. A cast coater is
squeeze coater, shown in Figure 5 .13, uses a shown in Figure 5.15.
pick-up or fountain roll C to apply the coating to The coating material specially chosen for rapid
the two pressure rolls A and B. As the fabric cure and viscosity is applied to the fabric web just
passes through the nip formed between rolls A prior to contact with the heated casting drum.
and B, the coating is forced into the fabric. Sur- During the time the coated fabric is in contact with
face gloss of the coating can be enhanced by the heated drum, the coating sets, and the coated
using a polishing roll subsequent to coating. fabric can be continuously stripped from the
drum. Coating smoothness is directly related to
Dip Coating the smoothness of the metal casting drum, the
amount of coating applied, and the fabric web
Dip coaters are used when complete saturation roughness. By using this coating technique, rela-
FIGURE 5.13 Three-roll squeeze nip coating. FIGURE 5.14 Dip coater.
5.2 Coating and Laminating 191
COAITD
FAilRIC
end use. Foam coated fabrics are produced for
textile applications by crushed foam coating
method, uncrushed foam coating or by flocked
foam coating techniques. Foam coatings for tick-
ings, drapery, fire retardant foam coatings and
certain upholstery coatings are examples where
crushed foam back-coatings are used. Un-
FABRIC
crushed foam coatings are used for carpets, mats,
WEB filtration fabrics and for upholstery fabrics.
FIGURE 5.15 Cast coater. Flocked foam coatings are used for drapery, tick-
ings and upholstery [ 14- 17].
Typically additives in a back-coating foam
tively open weave fabrics with a high degree of contain latex, filler, foaming agent, auxiliary
stretch may be coated satisfactorily. foaming agents, thickeners and alkali such as
ammonium hydroxide to adjust required pH
Extrusion Coating range.
In this coating method, the latex coating for- Powder coating using thermosetting epoxy
mulation- at a lower viscosity than conventional resins, crosslinkable polyester resins, or acrylic
coating compounds- is sprayed through series of resins are used for coating fabrics, wire, pipes
nozzles uniformly on traveling fabric web. The and for bottle coatings [ 19]. Electrostatic ap-
fabric is then dried and cured as in other coating plication, spray method or screen methods are
methods. The method is widely used for back- commonly used. Powder coating methods can
coating of upholstery fabrics where the fabric also be used for applying the laminating ad-
weights, construction or yarns do not allow con- hesive or thermoplastic resins to fabric surface.
ventional knife or roller coatings. The spray The powder can be applied as a layer or with a
coatings are also used for stabilizing nonwoven
webs.
Foam Coating
gap or in an engraving pattern. Following pow- fabric is required. This method is commonly
der application heat is applied for the coating of used for flexible laminates and allows large rolls
the thermoplastic material and to adhere onto the to be produced on a continuous operation.
fabric.
Rigid laminates are composite products made 2.4 Resins for Laminating
of thin layers or sheets combined by adhesives.
Usually they consist of several layers of fabric, Phenolics
or other fibrous types of materials, cemented or
bonded together with resin, to make rigid plas- The term phenolic resins covers a variety of
tic-like materials of any desired thickness. Both products formed by the chemical reaction of a
thermoplastic and thermosetting resins are used. phenol with an aldehyde. The most commer-
Thermoplastic resins soften and melt under the cially significant phenolic is the one based upon
application of heat and harden upon cooling, the phenol and formaldehyde.
action being reversible. Resins in this category Phenolic resins have been used in the manufac-
include the polystyrenes, acrylics, cellulosics, ture of plastic laminates. However, their use is
polyolefins, vinyls, nylons, polyesters, and declining due to the availability of more environ-
fluorocarbons. Thermosetting resins, when sub- mentally safer acrylic coating resins. The phenolic
jected to heat curing, harden permanently, usu- resins are relatively low in cost, possess good
ally via crosslinking. The action is irreversible. mechanical and electrical properties, and have
Subsequent heating may soften the material, but good heat and moisture resistance, as well as good
it is not possible to restore the resin to its uncured chemical resistance to mild acids and alkalies.
state. Resins in this category include urea for- In the production of high pressure laminates,
maldehyde, melamine formaldehyde, and phe- the uncured resin is dissolved in alcohol to form
nolic aldehydes, alkyds, and epoxies. a varnish. Fabric is passed through the varnish
bath and out through squeeze rolls or over doctor
blades. Then, passing through an oven, the ex-
2.2 Flexible Fabric Laminates cess volatile matter is driven off at a relatively
low temperature, and the resin, partially poly-
Flexible laminating products are produced by merized, is dried on and within the fabric. To
laminating one fabric to another fabric by using make flat sheets, the treated fabric is then cut into
thermoplastic resins or thermoplastic film. required lengths. Several sheets, depending
Flexible fabric laminates could also be laminates upon the desired laminate thickness, are placed
of fabric to films. Films such as vinyl, poly- between polished steel plates in a hydraulic
urethane, or polyester are bonded to fabrics with press. The laminate is cured at a temperature of
heat and pressure. Usually a primer coat on the about 350°F and pressures ranging from 750 to
5. 2 Coating and Laminating 193
2,000 psi. Nonwoven fibrous bases may also be tion with glass fiber fabrics to obtain laminates
molded into reinforced phenolics of various with high temperature resistance and excellent
shapes. electrical properties. Higher in cost than the
phenolics, these laminates resist temperatures up
Melamine Resins to about 550°F, and have higher arc resistance
and lower moisture absorption. Silicone resins
Melamine formaldehyde resins, which are more are available for both high and low pressure
costly than the phenolics, are used for electrical laminating processes, but one deficiency that
insulating laminates because of their good flame they exhibit is their sensitivity to organic sol-
and arc resistance. These resins are essentially vents. Hydrocarbon solvents readily attack
colorless and are predicable in a wide color range, silicone resins.
with excellent lightfastness. Hence, they are useful
in decorative applications. Melamine formal- Polyester Resins
dehyde resin releases free formaldehyde into the
atmosphere. Formaldehyde is considered a cancer Polyester resins have wide applications for
producing agent and the use of melamine resin is low and high pressure laminates, providing good
declining in the laminating field. mechanical and electrical properties. These
resins, with glass fiber reinforcement, are used
Epoxy Resins in the fabrication of many types of products,
from small electrical components to large boat
Epoxy resins, also more costly than the hulls. Glass fiber is used in various forms, in-
phenolics, are generally used with glass and cluding yam, fabric, woven roving, mat, or
carbon fabrics, although they may also be used preforms made from chopped fibers. Laminating
with synthetic yam or fabric reinforcements. pressures are not critical, ranging from contact
They possess a high degree of chemical resis- pressure to about 400 psi. Saturated polyesters
tance, have low moisture absorption, good having hydroxy function can be further extended
dimensional stability, high mechanical strength, with isocyanates and used in film lamination for
and superior electrical properties under high sailcloth and other applications.
humidity conditions. Helmets for football play-
ers and motorcycle riders are often made from Acrylic Resins
epoxy resin laminates of glass fiber fabrics.
Epoxy resins are widely used in other textile Acrylic resins are characterized by excellent
structural composites (Chapter 7 .0). clarity, high impact strength, chemical and
weather resistance, and ease of formability.
Polyurethane Adhesives Acrylic resins are widely used in many types of
fabric lamination. They are used in synthetic
Both solvent based and aqueous dispersions of fiber laminates for special applications, par-
polyurethanes are suitable adhesives for lamina- ticularly in the aircraft field.
tion of textile to textile materials or textiles to
foam products. The laminated products are fast Pressure Sensitive Adhesives
to washing and dry cleaning. The polyurethane
based adhesives are prepared by thickening the Pressure sensitive adhesives and low energy
dispersion and coating by roller or knife ap- cure adhesives have interesting applications. The
plication. When a urethane foam is bonded to room temperature cure function of these ad-
textile materials, low pressure is used for lamina- hesives provides diversified end use. They are
tion. acrylic based resins and copolymers based on
methyl, ethyl and butyl acrylate to obtain
Silicone Resins polymers having lower glass transition tempera-
tures. Low temperature cure polymers have been
Silicone resins are generally used in conjunc- developed in recent years having good adhesion
194 FABRIC FINISHING AND COATING
and solvent resistance. They are used in the Nylon fiber gives exceptional electrical resis-
lamination and bonding of polyurethane foam to tance with high impact strength and is often used
fabrics. for making laminated electrical products.
Polyester has good chemical resistance,
Ethylene Vinyl Acetate Copolymers weather resistance and good abrasion resistance
and its use in laminated products has increased in
These copolymers are gaining a large market recent years.
in the laminating field as they are environmen- Acrylics have special properties, making them
tally safer than phenolics and melamine formal- suitable for many useful laminated products.
dehyde resins. These polymers give good ad- Acrylics possess good resistance to outdoor ex-
hesion for synthetic fiber lamination and are used posure and have excellent acid resistance. The
in the manufacture of laminated furniture up- fabrics are often used as overlays in glass fiber
holstery fabrics. reinforced laminates, produced by low pressure
techniques. The acrylic overlay affords im-
proved resistance to abrasive wear, chemical at-
2.5 Fibers and Fabrics for Laminates tack, and weathering.
Nonwoven fabrics are used for special
Woven, knit and nonwoven fabrics are used in laminates, particularly where smooth machining
producing fabric laminated products depending characteristics are desired in the final laminated
on end-use application and its desired properties. product. These nonwovens or mats are made
The fiber selection for the fabric manufacture with fibers that are randomly distributed so that
also depends on the performance characteristics the mechanical properties are equal in all direc-
required of the end-use product. The following tions within the fabric plane. If a resin is used in
fibers and fabrics are used for high pressure and the manufacture of nonwovens, it must be com-
low pressure lamination process. patible to the laminating process. Nonwoven
Cotton has been used for reinforced high pres- polyester mats are often laminated as backing for
sure laminates requiring good mechanical prop- printed or dyed upholstery fabrics made of cotton
erties such as high impact strength, superior or polyester.
bond strength, and good machining qualities.
However, cotton's share has been declining due
to the synthetics. The cotton fiber at relatively 2.6 Types of Laminates
low cost, has the very desirable combination of
good strength and relatively low extensibility, Textile fabric supported plastic laminates are
thus aiding in the production of dimensionally used in many forms. Some of the most important
stable rigid laminates. Cotton blended with types are described below.
polyester give higher strength and is commonly
used for lightweight base fabric for lamination. Sheet Stock
Cotton and cotton/polyester blended fabrics sup-
plied in gray stage have to be prepared to remove In the manufacture of sheet stock, layers of
size and often scoured and bleached followed by fabric impregnated with the laminating varnish
a thorough wash to remove salts and electrolytes are carefully assembled to form a sheet of the
prior to its use in lamination. required thickness. In some cases, the assembly
Glass fiber is used as a reinforcement for may consist of several different types of impreg-
phenolic laminates for improved heat and electrical nated material to provide the finished product
resistance in combination with high mechanical with the required mechanical or electrical prop-
strength. It has broad application in the low pres- erties. The assembly of impregnated sheets is
sure field in combination with polyester resins, and then placed in the hydraulic press, where it is
where the high pressure lamination techniques are subjected to carefully controlled heat and pres-
used. Epoxy resins are used for laminating glass for sure. The layers fuse together to form a hard,
higher strength and impact resistance. dense, homogeneous sheet.
5. 2 Coating and Laminating 195
Tubes are formed by winding resin impreg- Honeycomb laminates made from resin im-
nated fabric on mandrels, and then rolling them pregnated fabric have a high strength/weight
between heated pressure rolls. The tube assem- ratio. Cotton and glass fiber fabrics are used as
bly is then cured in an oven. Another method is reinforcing materials for this type of laminate,
to mold the tubing under pressure in a hydraulic which has many structural applications.
5.3
References and Review Questions
tion of Vat Dyes, AATCC Monograph No.2, Gohlke, D. 1. and Tanner, J. C., "Gore-Tex®
American Association of Textile Chemists and Waterproof Breathable Laminates;' AATCC
Colorists, Research Triangle Park, NC, 1953. Coated Fabric Update Conference Book of
Carty, P. and M. S. Byrne, The Chemical and Papers, April 1976.
Mechanical Finishing of Textile Materials, Industrial Coatings: Conference Proceedings,
2nd Ed., Newcastle upon Tyne, Polytechnic ASM/ESD Conference, Chicago, November
Products Ltd., 1987. 1992.
Datye, K. V. and A. A. Vaidya, Chemical ' ' Developments in Coating and Laminating;'
Processing of Synthetic Fibers and Blends, Shirley Institute Conference, Publication S41,
John Wiley and Sons, 1984. March 1981.
Lewin, M. and S. B. Sello, eds., Handbook of Coated Fabrics Update, AATCC Conference
Fiber Science and Technology: Volume II- Book of Papers, April 1976.
Functional Finishes, Part A, Marcel Dekker,
Inc., 1983. 2. REVIEW QUESTIONS
Lewin, M. and S. B. Sella, eds., Handbook of
Fiber Science and Technology: J.Vlume II- 1. What are the reasons for heat setting of yarns
Functional Finishes, Part B, Marcel Dekker, and fabrics in industrial textile products?
Inc., 1984. 2. Define the following terms:
Nettles, 1. E., Handbook of Chemical Special- • copper number
ties, John Wiley and Sons, 1983. • pH
• colorfastness
Olson, E. S., Textile ~t Processes, Jill. 1,
• dyeing transition temperature
Noyes Publications, 1983.
3. What kinds of chemicals are used for flame
Peters, R. H., Textile Chemistry, Volume 3, El- retardant finishes? Explain their perfor-
sevier Scientific Publishing Company, 1975. mance.
Trotman, E. R., Dyeing and Chemical Technol- 4. What are the possible application areas of soil
ogy of Textile Fibers, 6th Ed., John Wiley and repellent fabrics?
Sons, 1984. 5. Find out how each test for water repellency is
Weaver, 1. W., ed., Analytical Methods for a conducted. What are the major differences
Textile Laboratory, 3rd Ed., American As- among these tests?
sociation of Textile Chemists and Colorists, 6. What is the difference between coating and
Research Triangle Park, NC, 1984. laminating? Explain.
6.0
ARCHITECTURAL AND
CONSTRUCTION TEXTILES
6.1
Architectural and Construction Textiles
S. ADANUR
2.1 Base Fabrics should not exceed 9 N/tex during warping [2].
For some applications, yams between 220 and
Base fabrics are usually made of synthetic 250 denier may need to be twisted before weav-
fibers and form the carrier layer which provides ing. Twisting is usually not required for 500 or
the necessary strength to the structure. Although higher denier yams. Filling yams over 500
aramid and carbon fibers have excellent proper- denier may need to be twisted when woven on
ties, they are rather expensive to use in these projectile looms (Section 4.4). The warp yam
types of construction extensively. The most may require sizing or twisting if a shuttle loom is
widely used materials are high-tenacity poly- used and the fabric construction is denser than
ester, fiberglass and nylon. Use of synthetic 12 x 12 yarns/inch. Sizing may be necessary
materials allowed lower backing fabric weight when weaving polyester on projectile looms.
compared to conventional canvas fabric made of Reinforcement fabrics can be woven on conven-
natural fibers. tional shuttle, rapier, projectile, air-jet and
Polyester is the most widely used base fabric water-jet machines.
material for its strength, durability, cost and With the availability of low and intermediate
stretch properties. Polyester fabrics are the least shrinkage yams, heat setting is not required.
expensive for longer term applications. Nylon is However, base fabrics made of high-shrink yams
sometimes used for membrane structures. It is need to be heat set before coating in order to
more durable than polyester, but it has higher prevent excessive shrinkage during coating.
cost and more stretch. Glass fabrics resist Scouring base fabric to remove warp size is
stretching after they are tensioned and therefore generally unnecessary for scrim fabrics since the
do not wrinkle or bag. Glass fabrics reflect a high laminates bond to each other and not to the
percentage of the sun's heat and keep the interior fabric. For coated fabrics, scouring may not be
of the structure cool. They do not bum or smoke. needed if the sizing material is compatible with
Woven fabrics made ofPTFE fibers combine en- the coating compounds. For example, greige
vironment-resistant advantages with durability polyester can be satisfactorily coated with vinyls
against flexing and folding. However, these and rubbers.
structures are more expensive. Typical base fabrics for coating have a greige
As in most industrial fabric applications, con- weightof3.3 -5.9 oz/sq. yard (112-198 g/m2).
tinuous filament yams are preferred over staple Since the tightly woven or knit structure does not
yams due to inherent strength and elongation allow the yarns to slip together as well as a scrim
resistance. Yam twist level is selected to be low fabric under tearing load, the higher tensile
to carry higher tensile loads as well as to prevent strength of coated fabric does not necessarily
fiber slippage which may cause early yam rup- yield a higher tear strength. The tear strength of
ture. Filaments with low twist levels can flatten coated fabrics can be increased up to 100% by
during weaving resulting in high cover factor. using a rip-stop construction (a variation of plain
Hydrophobic fiber materials are preferred. weave having two yarns woven as one at regular
Base fabrics can be woven, knit or nonwoven. intervals). However, at the doubled-yam cross-
Woven structures are usually the design of choice over points, the coating may be thinner and
for fabric rigidity and dimensional stability for therefore more susceptible to abrasion. Typical
many applications. Generally simple weave pat- scrim fabrics for laminating have a greige weight
terns such as plain weave and low harness twills of 1.2-3.3 oz/sq. yd (41-112 g/m2). Weft in-
are used. Warp-knit and nonwoven stitchbonded serted warp knit fabrics (Figure 4.52) are
fabrics are also used. suitable for either coating or laminating. Table
Special care should be taken during warping 6. 1 shows typical base fabric and scrim construc-
and weaving of the woven base fabrics. The tions. Weights are for greige fabrics.
tension in the warp sheet should be kept as The width of woven fabrics can be up to 5 m.
uniform as possible since a tight threadline in Depending on the shape and size of the construc-
warping will be visible as a defect in the coated tion, fabric pieces are cut and seamed. The seam
fabric. It is recommended that the yarn tension area is welded by heat and pressure to attain
6. 1 Architectural and Construction Textiles 203
TABLE6.1 Typical Base Fabric and Scrim Constructions {3].
Ends x Picks Weight Warp Yarn Filling Yarn
Fabric (per em) (g/m2) (denier) (denier)
impermeability to air, wind and rain. Special durability. PTFE coated fiberglass is the only
techniques are used to ensure a properly welded material that meets the U.S. model building
seam. codes' defmition of non-combustible materials.
Coated fabrics are usually more expensive
Coating and Laminating than similar laminated fabrics but they offer
higher tensile strength, higher flex resistance,
Coating is made of a plastic material or syn- higher abrasion resistance and longer life. The
thetic rubber. Coating provides waterproofness material and/ or thickness of the coating layers on
and protects the base fabric from sunlight and each side may or may not be the same. For
weathering degradation. Common polymer coat- applications where water and chemical resis-
ings are natural rubber (polyisoprene), sty- tance are the major concern, double coating may
reneutadiene rubber (SBR), nitrile rubber (acry- be used. Laminated fabrics are the most
lonitrile-butadiene copolymers), neoprene economical for general applications. They have
(polychloroprene), butyl rubber (isobutene-
isoprene copolymers), Hypalon® (chlorosul-
phonated polyethylene), polyvinyl chloride
(PVC), polyvinylidene chloride (PVDC),
polytetrafluoroethylene (PTFE), polyurethanes
(PU), silicone rubbers (polysiloxanes),
polyvinyl fluoride (PVF), polyvinylidene
fluoride (PVDF) and fluororubbers [4]. Mostly,
polyvinyl chloride (PVC), polytetrafluoro-
ethylene (PTFE) or silicone coatings with flame-
resistance properties are used. Pigment Conventional coating process
coloration is common. To give the PVC fabric
' ' self-cleaning'' properties and added protec-
tion, a polyurethane topcoating is used.
Polyester fabrics are usually coated or
laminated with PVC films. Laminates usually
consist of vinyl fllms over woven or knitted
polyester or nylon meshes (substrates). In the
Precontraint process, polyester fabric is ten-
sioned before and during the coating process
which is claimed to improve dimensional
PRECONTRAINT system
stability by imparting identical characteristics to
the warp and filling yams (Figure 6.1). Fiber- FIGURE 6.1 The Precontraint coating system (courtesy
glass fabrics are usually coated with PTFE for of Ferrari).
204 ARCHITECTURAL AND CONSTRUCTION TEXTILES
TABL£6.2 Typical Properties of Coated and Laminated Fabrics Made with Trevira® Polyester {3].
Fabric Type
Property Light Duty Light Duty Medium Duty Medium Duty Heavy Duty Heavy Duty
good tear resistance; however they may de- ultraviolet radiation. Therefore, it is important
laminate under repeated flexing or wind-whip- that the coating covers all the interlacing points
ping conditions. in the fabric sufficiently. Figure 6.2 shows the
aging performance of canvas cloth and nylon
2.2 Properties of Coated Fabrics for coated fabrics. Weather resistance tests are time-
Architecture and Construction consuming since they usually require several
years for reliable results. Therefore, rapid tests
Depending on the application area, general can be done on simulating machines. However,
properties required for coated industrial fabrics correlation of accelerated indoor testing with
are high tensile strength, adequate elongation, 15-20 year outdoor testing has not been
high melting point, waterproofness, toughness, demonstrated.
resistance to rot and fungi, resistance to weather- One of the most important properties of coated
ing effects and aging, wet and dry dimensional fabrics for buildings is the residual strength.
stability, resistance of coating to high and low Tensile test results of PVC coated polyester and
temperatures, flame resistance, abrasion and tear nylon 6,6 fabrics, which were subjected to five
resistance, low weight, flexibility, good adhesion
of the backing fibers to coating, and, of course,
low cost. For constructional and architectural "";" '00 J"
~ 90. ~".:~--------;- 3
coated fabrics, resistance to fatigue and time re-
lated fatigue become very important. Table 6.2
shows typical properties of coated and laminated
fabrics made with Trevirafi polyester. Charac-
!~ r~ 40 ~
'',,,, ___ _,
teristics of commercially available air, tent and ~ 3o r
tensile fabric structures are listed in Appendix l. I tr-
20
10 1
Since they are generally exposed to outside ~~,~~~~2~~~·~~3~~~-4~0~oo,-~s~~~·~s~oo~o 1
conditions, aging characteristics are critical for - I I
solar light exposure
(hours] 1/
coated fabrics. Weathering effects cause degra- 3 years 4years4years
and9months ard5mon1hs
dation of both fibrous reinforcement and coating
which, in turn, negatively affect the properties FIGURE 6.2 Aging performance of canvas cloth and
nylon fabrics. Linen canvas cloth, finished, 1-warp direc-
and performance characteristics. Ultraviolet ra-
tion, 1 '-filling direction; nylon fabric (Chemlon), PVC
diation, particularly, degrades the properties of coated, 2-warp direction, 2 '-filling direction; nylon fabric
some synthetic fibers. The life of the coated fab- (Nylon) PVC coated, 3-warp direction, 3 '-filling direction
ric depends on how well the coating blocks the (Elsevier Science [2)).
6.1 Architectural and Construction Textiles 205
BREAKING
LOAD
WARP
WEFT
3. APPLICATIONS OF COATED
FABRICS IN BUILDING STRUCTURES
BREAKING WARP
ELONGATION WEFT Membrane structures can be divided into four
categories: tent, clear-span, air and tensile struc-
TEAR WARP
tures. Although each structure type has specific
STRENGTH wEFT characteristics, there are some structures that
may fall under more than one category. Some
II I I ! I I I 1
manufacturers categorize membrane structures
0 10 '10 30 40 50 60 70 80 90 100"/o
GLASS PES
TEFLON· COATED ~c-co•rEo
2 2"
FABRIC APPEARANCE
3 I
I
.....
TEAR STRENGTH
DIMENSIONAL STABILITY
FLAMMABII.ITV
-- I
I
-....
TRANSLUCENCY
~ I
SEAM STRENGTH I
CLE.ANABIUTY I
MAKING- UP PERFORMANCE
I
FtEXIBIUTY
I
/
FLEXING LIFE /
CHEMICAL RESISTANCE
/
/
HEAT-RESISTANCE
Solar pra1:::ticn for glass roof conserva1ory Oltnos glass dome cover
FIGURE 6.6 Application examples of industrial fabrics in architecture and construction (courtesy of Ferrari).
206
6.1 Architectural and Construction Textiles 207
new tent constructions were developed for build- 3.2 Clear-Span Structures
ing construction, business, exhibitions, enter-
tainment, leisure and recreation. Clear-span structures provide clear space
In pole tents, the fabric is draped or hung rather beneath the fabric, free of poles and other sup-
than tensioned (Figure 6.7). Tension tents include porting elements. They are also known as clear-
various tensile structure characteristics and there- span tents. In a clear-span, the fabric is pulled
fore fall between tents and tensile structures (Fig- taut through channels in the frame's ribs, i.e., no
ure 6.8). Tensile tents have tensioned fabric that poles or masts are used. Well built clear-spans
provides clear span and they do not require guys. are very stable and have been used in many
Pole tents and tensile tents are mass produced. commercial and industrial applications. They are
The most widely used fabrics for tent walls are more permanent than tents and less permanent
polyesters and vinyls. Table 6.3 shows typical than air or tensile structures. Clear-spans can
properties of heavy duty coated tent fabrics. accommodate doors, flooring, insulation, elec-
TABLE 6.3 Typical Properties of a Heavy Duty parabolic in cross section and as an ''X'' when
Tent Fabric (Herculite Products, Inc.). viewed from above. The two main ways to attach
Weight 16 oz/sq yd fabric to anchorages are sleeves and clamps.
Tear strength 150 lb (warp) x 160 lb (filling) Figure 6.10 shows the installation stages of a
Tensile strength 300 lb (warp) X 290 lb (filling) tension structure as a stadium roof. Figures
Low temperature
6.11-6.14 show several tension structures.
resistance -40°F
Hydrostatic burst 450 psi
Flame retardance 0.6 sec, 3.7 inch 3.4 Air Structures
209
FIGURE 6.11 Coated fabric is used to cover high traffic access areas at Jacksonville International Airport, Jacksonville,
Florida (courtesy of Birdair, Inc.).
FIGURE 6.12 Polyester coated fabric was used to replace a worn·out stadium roof in
1993 in Stuttgart, Germany. The membrane structure consists of 35,000 m2 membrane
and 100,000 individual parts which is the largest of its kind in Europe (courtesy of
Hoechst Celanese).
210
FIGURE 6.13 San Diego Convention Center, San Diego, California (cour-
tesy of Birdair, Inc.).
FIGURE 6.14 The roof of Orlando City Hall (Florida) was designed as a soccer ball to commemorate the
1994 World Cup Soccer finals (courtesy of IF AI).
FIGURE 6.15 Schematic of a pressurized air-supported structure (The Textile Institute [1 )).
211
FIGURE 6.16 Pressurized air structure (courtesy of IFAI).
FIGURE 6.17 Inflatable air beam for an air-supported structure (courtesy of Albany International).
212
6.1 Architectural and Construction Textiles 213
The interior of the structure itself is not pres- terior use. Fiberglass based fabrics have been the
surized. Wide diameter supports (up to 42 material of choice for stadium domes (both air
inch) use low air pressure (4 to 10 psi) and and cable supported) and other permanent struc-
narrow-diameter supports (4 to 18 inch) use tures especially in the United States.
high air pressure (30 to 100 psi) [6]. They are
currently used for lightweight, easy-to- 3.5 Designing with Coated Fabrics
transport military structures although civil
applications may have good potential in the The major functional requirements for per-
near future. Polyester and nylon are the manent architectural fabrics are listed in Thble
materials of choice. For high pressures 6.4.
aramid fibers may be needed. The width/ Mainly three types of stresses act on an ar-
height ratio may be a limitation for a single chitectural fabric:
air structure but this limitation can be over-
come by conjoining several modules (1) Stresses due to applied load to tension the
together. fabric
(2) Weight of suspended fabric
There are approximately 150 big fabric struc- (3) Stresses induced by natural forces due to
tures in the world which were built within the last wind, rain and snow
twenty years, including Georgia Dome in Atlan-
ta (cable supported, Figure 1.2), Silver Dome in The calculation of the loads depends on the
Detroit (where Teflon® coated glass fabric was region where the structure will be installed.
used), Bullock's department store in San Mateo, Snow loads push the fabric down while wind
California, Hoosier Dome in Indianapolis (air loads tend to pull the structure upward. Wind can
structure) and the Carrier Dome in Syracuse. affect a fabric structure in two ways: laterally
The Carrier Dome is air supported and made of across the top, or, if the structure is open-sided,
glass fiber coated with a fluoropolymer disper- up from below. Heavier loads necessitate
sion (Figure 6.18). For the large-span areas such stronger anchoring which may require additional
as stadium roofs and airport terminals, tension or larger cables, stronger connecting hardware,
designs are preferred. For example, over and larger foundations or reinforced perimeter
500,000 m2 ofPTFE coated glass fabric was used walls into which to ground the anchors. Properly
in the construction of the Haj Terminal building
for Jeddah International Airport in Saudi Arabia
which was completed in 1982. It is the world's TABLE 6.4 Functional Requirements for
largest tensile structure [7] . The newest tension Permanent Architectural Fabrics (Chemfab).
fabric structure is the terminal at the new Denver Tensile strength 500 lb/inch for air-supported
International Airport which has a coated fabric structures
roof that consists of two layers of Teflon® coated 650 lb/inch for pretensioned
structures
woven fiberglass (Figure 1.10). The fabric is Durability Retain functional integrity for at
designed to allow enough light transmission for least twenty years
plants. The roofis suspended by steel masts and Fire safety Find acceptance within existing
cables, covering an area of 20,000 m2 [8]. building codes
Lighter polyester fabrics (6 to 8 ounces per Energy efficiency Provide adequate day lighting
without artificial illumination
square yard) are used as acoustic and insulated
Provide acceptable thermal gain/
liners. Waterproof, flame retardant tarpaulins loss characteristics
are used in cold weather construction. The fabric Cost Provide life cycle cost competitive
keeps heat in, so construction can continue all to conventional construction
winter, even at 40 degrees below zero (Figure Aesthetics Constitute an exciting structural
alternative to traditional structural
6.19). Heavier polyester materials such as 20 to
options
26 ounce fabrics, are suitable for long-term ex-
FIGURE 6.18 The Carrier Dome, Syracuse, New York (courtesy of John Dowling Photography,
Syracuse).
214
6.1 Architectural and Construction Textiles 215
tensioning systems must be well calculated and attached:' Figure 6.21 shows standard awning
established for long-term, permanent use. and canopy styles. Figure 6.22 shows the main
Tension structure designers use Computer parts of an awning installation. Retractable or
Aided Design (CAD) systems to calculate loads lateral arm awning segment is recently gaining
and determine their effects on the designs before popularity (Figure 6.23). Lateral arm awning
building the structure itself. CAD of fabric struc- systems, which were first introduced in Europe,
tures reduces development time and allows provide easy installation, sun control and good
designers to explore various alternatives and op- looks. Retractable awning systems include a
tions in their work. manual or electric cranking system that allows
General considerations for a tension structure them to be folded up or retracted when not used.
design are as follows [9]: Illuminated (backlit) awnings offer high
visibility in commercial applications. Backlight-
• dimensions of the structure ing is usually achieved by attaching lighting to
• permanent (15 to 20 years) versus the support frame, beneath the fabric cover, as
short-term life structure shown in Figure 6.24. Although any kind of
• type of use (commercial, industrial, lighting may be used for illuminating awnings,
public assembly, roof, skylight, shelter, fluorescent lighting is the most widely used be-
signature, etc.) cause of its low expense, low temperature, high
• free standing versus anchored to a hard durability and a more even distribution of light.
structure Awning and canopy applications are shown in
• budget limitations and considerations Figures 6.25 and 6.26, respectively.
• local requirements regarding fire Fiberoptics are also used in awnings for
resistance, loads and other code-related animation and various color possibilities. The
matters awning industry uses a specially extruded acrylic
fiber that is lightweight, durable and weather
resistant. The fiber is treated with a polymer
4. AWNINGS AND CANOPIES cladding. The light aimed at one end of the fiber
reflects back and forth along the length and
Awnings are widely used in commercial and comes out the other end.
residential buildings for decoration, protection, Umbrellas are primarily used as shade and
or visibility. Canopies, patio covers and porch decorative devices for commercial and residen-
awnings are the leading products in awning busi- tial patios. Recently umbrellas have been made
ness. Fabric awnings and canopies are the most with more high-tech frames and fabrics. For
common types of shading structures. example, retractable umbrellas were used in the
The main difference between an "awning" Mosque of the Prophet in Medina, Saudi Arabia
and a'' canopy'' is that a canopy requires support (Figure 1.14). The 296 m2 screens with a 25 m
in addition to the anchoring that attaches it to a diagonal are the largest ever constructed in the
building. BOCA (Building Officials and Code world. The fabric is Tenara TM specially de-
Administrators International) defmes a fabric veloped by W. L. Gore and Associates, Inc. It is
awning as "an architectural projection that woven from high strength PTFE fibers and has
provides weather protection, identity, and/or good flex life and UV immunity. The operation
decoration and is wholly supported by the build- of the umbrellas is computer controlled at the
ing to which it is attached. An awning is com- press of a button. The shade roof also provides
prised of a lightweight, rigid, or retractable air conditioning. The construction is designed
skeleton structure over which a fabric cover is for wind speeds of up to 155 km/h [10,11].
attached:' A fabric canopy is defined by BOCA ASTM performance specification D 4847
as ''an architectural projection that provides (Standard Specification for Woven Awning and
weather protection, identity, and/or decoration Canopy Fabrics) includes test methods and
and is ground-supported in addition to being specification requirements for awning and
supported by the building to which the canopy is canopy fabrics.
Standard awning. Convex awning.
217
fabric
return
valence
anchoring
framework
FIGURE 6.23 Retractable awning (courtesy of Simu FIGURE 6.24 Illuminated (backlit) awning frame system
U.S. inc.). (courtesy of Eide Industries, Inc.).
218
FIGURE 6.25 Awning (courtesy of IFAI).
219
N
N
0
Description Acrylic-painted Vinyl coated cot- Vinyl coated on Tri-layer fabric; Vinyl coated on Acrylic coated on Woven acrylic Woven,
cotton duck fabric ton duck fabric each side of vinyl outside each side of a each side of a fibers, fluorocar- modacrylic
poly/cotton base layers, woven polyester base polyester base bon finish fibers, fluorocar-
polyester middle bon finish
Typical weight 11 15 13 10-16 11-17 9.5-12.5 9.25 9.25
(oz/sq yd)
Properties Resistant to UV Resistant to UV Resistant to UV Resistant to UV Resistant to UV Resistant to UV Resistant to UV, Resistant to UV,
light, mildew, light, mildew, light, mildew; light, mildew, light, mildew, light, mildew; color degrada- color degrada-
water water water repellent water water, cleanable water repellent tion, water, mil- tion; water repel-
dew lent, resistant
Colors Stripes or solids; Stripes or solids; Solids; same Stripes or solids; Stripes or solids Mostly solids, Stripes or solids; Solid colors and
many colors many colors color both sides primary colors, some stripes many colors tweeds
pastels
Underside Pearlgra~ green, Solid pearl gray Same as top side Linen-like pat- Same as top side Same as top side Same as top side Same as top side
gray with floral tern, solid coor-
print dinating color or
same color as top
Surface Matte finish with Smooth, non- Textured surface Smooth or matte, Smooth, some- Surface is tex- Woven texture Woven texture
linen-like visible glare surface with slight woven or what glossy top tured with cloth surface
texture little or no texture linen-like texture surface appearance
TABLE 6.5 (continued).
Vinyl Coated
Painted Army Vinyl Coated Polyester/ Vinyl Laminated Vinyl Coated Acrylic Coated Solution-Dyed Solution-Dyed
Duck Cotton Cotton Blend Polyester Polyester Polyester Acrylic Modacrylic
*Dimensional stability.
**Some shrinkage in cold weather; some stretch in hot weather.
tDepends on climate and proper care of fabric.
1\)
1\)
.....
222 ARCHITECTURAL AND CONSTRUCTION TEXTILES
TABLE 6.6 Typical Properties of Single-Ply Roof Material (courtesy of Seaman Corp.).
Strain
Hours
FIGURE 6.30 Effect of fiber reinforcement on concrete failure strain (courtesy of Polysilk).
6.1 Architectural and Construction Textiles 225
to support permanent high stress cracked and cement include pavements, decorative clad-
composite, considerable elongations or de- ding, timber substitute, thin shell roofs, internal
flections can take place over time. There- waterproofing of cracked reinforced concrete
fore, these fibers are generally used in tanks, permanent formwork (waffle floor pans,
situations where the matrix is expected to be bridge deck formwork), water tanks, swimming
uncracked, but where transitory overloads pools, low cost and refugee housing, grain silo,
such as handling stresses, impacts or wind pipes and noise barriers.
load is significant. Another concern is that The commercial viability of fiber composites
they generally have large values of Poisson's depends on the costs of the fibers because the
ratio and this combined with lower moduli, matrix is very cheap. Therefore, it is a common
means that if stretched along their axis, they practice to use the cheapest suitable fiber in the
contract sideways much more than the other lowest volume required to fulfill the strength and
fibers. This results in high lateral tensile durability requirements.
stress at the fiber-matrix interface which is
likely to cause a short aligned fiber to debond
and pull out. Woven meshes or networks of 8. TEXTILES FOR ACOUSTIC AND
fibrillated fibers are used to improve the HEAT INSULATION
situation.
(2) Fibers with moduli higher than the cement Textile materials are used in the interior of
matrix. These fibers include glass, carbon buildings for mainly three acoustical purposes:
and Kevlar®. High modulus short fibers may • to improve audibility
require mechanical bonding to avoid pull- • to preserve the natural quality of sound
out. • to prevent transmission of undesired
sound
The elongations at break of textile fibers are
two to three orders of magnitude greater than the Absorbent textile materials such as carpets,
strain at failure of the matrix. Therefore, the textile wall coverings and curtains are used to
matrix would crack long before the fiber strength reduce the reverberation time. Reverberation
is reached. If the modulus of elasticity of the fiber time is defmed as the time a sound takes to die
is less than the cement matrix, due to low fiber away in a building. In an ordinary living room it
volume fraction, the modulus of the composite is is around 0. 5 seconds and in large buildings it can
not greatly different from that of the matrix. be as long as 10 seconds. Complete elimination
The maximum particle size of the matrix is of reverberation is not desired. Too much absorp-
important since it affects the fiber distribution tion could attenuate sound and reduce audibility.
and the quantity of fiber that can be included in There are two types of noise in buildings:
the composite. The average particle size of ce- ''airborne noise'' and'' impact noise.'' Airborne
ment paste before hydration is between 10 to 30 noise is transmitted from the air through open-
microns. Concrete which is intended to be used ings in the building such as open windows and
with fibers should preferably have particles be- doors. Impact noise is transmitted directly
tween 10 mm and 20 mm for uniform fiber through the structure of the building. Textiles
distribution. such as curtains, felts and especially carpets offer
Application areas of fiber reinforced concrete excellent airborne sound absorption properties.
TABLE 6. 7 Acoustical Properties of a Typical Fabric tor Noise Reduction (courtesy of Chemfab).
Frequency (Hz) 124 250 500 1,000 2,000 4,000
Sound absorption (sabins) 43.0 49.7 38.7 50.4 52.1 54.2
Sound absorption coefficient
(sabins/ft2) 0.52 0.65 0.54 0.69 0.69 0.71
Noise reduction coefficient (NRC) = 0.64
226 ARCHITECTURAL AND CONSTRUCTION TEXTILES
FIGURE 6.31 Tyvek® spunbond material for house insulation (courtesy of DuPont).
According to Carpet and Rug Institute of Teflon® fiberglass composite materials are
America, the main factors affecting sound ab- used for noise reduction. The structure is usually
sorption are as follows: porous to facilitate the attenuation of sound
within the fabric. Table 6. 7 shows acoustical
( 1) Cut pile construction provides better absorp-
properties of a typical fabric used for noise con-
tion than loop pile construction (Section
trol.
4.7).
Housewrap materials are used in buildings for
(2) In cut pile constructions, pile height and den- thermal insulation (Figure 6.31). They reduce
sity increase absorption. the flow of air into and out of the house, cutting
(3) In loop pile constructions, pile height is more heating and cooling energy costs. Moisture
important than pile density. vapor is allowed to pass through the wrap
(4) Acoustic performance is independent of the material which reduces damage from inwall con-
pile fiber type. densation.
6.2
References and Review Questions
"U.S. Building Codes Summary: Air, Tent and tion Guidelines;' Fabrics and Architecture,
Tensile Structures;' SpecGuide 1994, Fabrics December 1993.
and Architecture, December 1993. Sudnik, Z. M., "Textiles in Buildings, Part 1-
"U.S. Building Codes Summary: Awnings and Acoustics," Textiles, Vol. 2, No.2, June 1973.
Canopies;' SpecGuide 1994, Fabrics and Ar-
chitecture, December 1993.
Perlstein, S., "New Shades of Umbrellas;' 2. REVIEW QUESTIONS
Fabrics and Architecture, July-August,
1994. 1. Why is coating or laminating necessary for
architecture and construction textiles?
Perlstein, S., "Beam It Up," Fabrics and Ar-
2. What are the advantages of using textiles in
chitecture, May-June 1994.
buildings compared to concrete?
Gorman, J., "Advanced Composites Advanc- 3. Discuss the major properties required for
ing;' Fabrics and Architecture, Septem-
fabrics in buildings.
ber- October 1992.
4. Defme air and tension fabric structures. Ex-
Gorman, J., "That's a Wrap," Fabrics and Ar- plain the major differences between the two.
chitecture, January-February 1992. Find out the names and locations of ten more
Gorman, J., "There's a Fiber in My Concrete," (i.e., not mentioned in this chapter) large air
Fabrics and Architecture, September-Oc- and tensile fabric structures worldwide.
tober 1991. 5. Explain the important fabric and structural
Gurian, M., "Acoustical Fabric Develop- considerations when designing buildings
ments;' Fabrics and Architecture, Winter with industrial textiles.
1990. 6. If you were to choose a fabric construction
Daugherty, H., "Characterization of Architec- type for a large shopping mall roof, would
tural Fabrics;' Fabrics and Architecture, you choose an air or a tension structure?
January- February 1992. Explain your reasons.
7. What are the important test methods for
Warshaw, R. 1., "Designing Single-Ply Roofing
fabrics in architecture and construction? List
Systems;' Fabrics and Architecture, Summer
and explain each (hint: use Appendix 1).
1990.
8. What are the advantages of collapsible fabric
Kerrigan, S. and Warhshaw, R. I., Fabrics and storage vessels for the military?
Architecture, Summer 1989. 9. What kind of fibers are used to reinforce
Mikko, C., "Fighting the Sun;' Fabrics and concrete? Explain their effects.
Architecture, March-April, 1994. 10. Why are textile materials effective in sound
''Awnings and Canopies: Design and Specifica- and heat insulation?
7.0
TEXTILE STRUCTURAL COMPOSITES
7.1
Textile Structural Composites
S. ADANUR
to bind the fibrous materials together and protect formance. The inherent properties of various
them from outside effects. Matrices transport the types of glass fibers are shown in Table 7 .1.
forces and stresses acting on the boundary of the Among the glass fibers, E-glass and S-glass are
composite to the fibers. They also help to the most widely used materials in textile com-
strengthen the composite structure. posites. E-glass is used in electronic boards be-
Application areas of composites are steadily cause of its good electrical properties, dimen-
expanding. They have replaced metals and metal sional stability, moisture resistance and lower
alloys successfully in many applications includ- cost. S-glass has higher tensile strength, high
ing automotives, aerospace, electronics, mili- elastic modulus and better thermal stability but it
tary and recreation. Typical application exam- is also more expensive. Therefore it is used in
ples are military and commercial aircraft parts, advanced composites where cost-performance
rocket and missile components, automotive benefits can be justified.
parts, electronic boards, home appliances, con-
struction and sporting goods. Carbon Fibers
Coefficient of
Tensile Tensile Thermal Liquid
Specific Strength Modulus Expansion, Dielectric Temperature
Gravity (MPa) (GPa) 10-6/K Constant* (OC)
Kevlar®29
(high toughness) 1.44 12 83 3.6 4.0 134-10,000
Kevlar®49
(high modulus) 1.44 12 131 36-4.1 2.8 134-5,000
Kevlar® 149
(ultra-high modulus) 1.47 12 186 3.4 2.0 134-1,000
from environmental effects and handling. The Epoxy resins are ideal for higher temperature
matrix system transfers forces acting on the applications. They offer versatility, broad range
boundaries of composites to the fibers. Matrices of physical properties, mechanical capabilities
also help to strengthen the composite structure. and processing conditions. Depending on man-
The reinforcement material and resin must be ufacturing conditions, epoxy resins can provide
compatible for good penetration and bonding. Both toughness, chemical and solvent resistance,
thermoset and thermoplastic resins are used as flexibility, high strength and hardness, creep and
matrices in textile structural composites. Thble 7.4 fatigue resistance, good fiber adhesion, heat
shows comparison of thermoset and thermoplastic resistance and excellent electrical properties.
resins for commercial aircraft composites. Examples of commercially available resins are
Tactic from Dow Chemical, Araldite from Ciba-
Thermoset Resins Geigy and Epon HPT from Shell Chemical Com-
pany. A curing agent needs to be used with epoxy
The most widely used thermoset resins are resins.
polyester and epoxy. Polyester resins are used in
applications where high temperature is not a Thermoplastic Resins
requirement. The advantages of polyester resins
are low cost, low viscosity for good flow and Thermoplastic materials can be classified as
fiber surface wetting, and low curing tempera- commodity thermoplastics and engineering ther-
tures. The disadvantages are poor strength, poor moplastics. Commodity thermoplastics such as
impact performance and high shrinkage during polyethylene, polypropylene, polyvinyl chloride
the curing process. and polystyrene exhibit very little resistance to
NON· AXIAL
1
MONO· AXIAL BIAXIAL
3
TRIAXIAL "- l
MULTI · AXIAL I
---
1"0 ROVING· YARN
20 lfi! Cf"CPPED
STRAND MAT
I
PRE-IMPREG-
NATION SHEET
a• PLANE
WEAVE
TRIAXIAL
WEAVE 1)·3)
-~
MULTI-AXIAL
WE.WE. KNIT
z
;a ~
-~)
]L'
=
c
'-Ql ' (?
~ .:r.-.s·'~
)EE . y v-"tA,''
cQl
:.Jw X " ( 3-D MULTI-PLY TRIAXIAL 3-0
(MULTI-AXIAL 3·0
WEAVE)
BRAID WEAVE WEAVE 4)-n, 12)•14)
30
~ ~ ~~
z
c
QlQl .
cE .
C1lQl .
o::w oc:. y
X Q<:J LAMINATE HONEY-COMB
TYPE H or I BEAM TYPE
FIGURE 7.2 Classification oftextile reinforcement structures based on axis and dimension [8].
E
'5 knits
..c
~ 1
~----------------------------~
low in-plane shear resistance high
~ multiaxial 0/45/90
cross-machine direction :.0 biaxial bonded WIWK-LI warp
(90 degree) wovens triaxial bonded
triaxial woven
braid-LI warp
braids
multiaxial 45
knits
..c
~~----------------------------~--~
low high
in-plane shear resistance
wovens
biaxial bonded
..c
~ ·-~
0~-------------------------------J
low in-plane shear resistance high
FIGURE 7.3 Relative comparison of the behavior of fabric structures under uniaxial stresses [9].
237
238 TEXTILE STRUCTURAL COMPOSITES
chemically compatible with the reinforcement be grouped as two-dimensional (2-D) and three-
material and should not deteriorate the mechani- dimensional (3-D) structures. In 2-D structures,
cal properties of the interphase between rein- yarns are laid in a plane and the thickness of the
forcement and matrix. fabric is small compared to its in-plane dimen-
sions. Single layer designs include plain, basket,
4.1 Fiber Forms twill and satin weaves which are used in
laminates. Two-dimensional woven fabrics are
Short or chopped fiber reinforced composites generally anisotropic, have poor in-plane shear
are not as strong as the composite structures that resistance and have less modulus than the fiber
allow controlled filament orientation. Con- materials due to existence of crimp and crimp
tinuous fiber reinforced structures with highly interchange. Reducing yarn crimp in the loading
aligned fiber arrangement result in high quality direction or using high modulus yarns improves
and stronger composites. Filament winding is fabric modulus. To increase isotropy, in-plane
used to produce such structures. In filament shear rigidity and other properties in bias or
winding, continuous filaments, fabrics, rovings diagonal direction, triaxially woven fabrics are
or tapes are wound on a rotating mandrel. developed in which three yarn systems interlace
There are two different types of filament wind- at 60° angles as shown in Figure 7.5.
ing: wet and dry. In wet winding, filaments are Unlike 2-D fabrics, in 3-D fabric structures,
fed to the mandrel from a resin bath at a controlled the thickness or Z-direction dimension is consid-
angle. In dry winding, prepregs are used. By erable relative to X andY dimensions. Fibers or
changing the filament tension, which is around yarns are intertwined, interlaced or intermeshed
0.25 to llb per end depending on the size, density in the X (longitudinal), Y (cross), and Z (vertical)
and compaction of the composite structure can be directions. For 3-D structures, there may be an
controlled [11]. The wound preform is then endless number of possibilities for yam spacing
cured. Filament winding is suitable for rocket in a 3-D space. 3-D fabrics are woven on special
engines, pressure vessels, storage tanks, pipes, looms with multiple warp and/or weft layers.
helicopter blades, fuselage and other aerospace Figure 7.6 shows various 3-D woven structures.
parts. There are several winding patterns includ- In polar weave structure, fibers or yarns are
ing helical, circumferential, polar, continuous placed equally in circumferential, radial and
helical, continuous normal axial, continuous axial directions. The fiber volume fraction is
rotating mandrel with wrap and loop wrap. around 50%. Polar weaves are suitable to make
In classical helical winding, a helix angle of up cylindrical walls, cylinders, cones and conver-
to 85° to the axis can be used. In polar or planar gent-divergent sections. To form such a shape,
winding, textile material is wound from one end prepreg yarns are inserted into a mandrel in the
to the other end of the mandrel which rotates radial direction. Circumferential yams are
about its longitudinal axis. In continuous rotating wound in a helix and axial yams are laid parallel
mandrel, fibers and overwrapping are wound on to the mandrel axis. Since the preform lacks the
a mandrel which rotates and travels through the structural integrity, the rest of the yarns are im-
oven. Figure 7.4 shows schematics ofhelical and pregnated with resin and the structure is cured on
circumferential filament winding. the mandrel. Polar weaves can be woven into
near-net shapes. A near-net shape is a structure
4.2 Fabrics that does not require much machining to reach
the final product size and shape. Since fibers are
Woven, braided, knitted, laminated, non- not broken due to machining, net shapes gener-
crimp and nonwoven fabric structures are used ally perform better than machined parts.
to reinforce composites. In orthogonal weave, reinforcement yams are
arranged perpendicular to each other in X, Y and
Woven Fabrics Z directions. No interlacing or crimp exists be-
tween yams. Fiber volume fraction is between
Woven fabrics that are used in composites can 45 and 55%. By arranging the amount of yam in
~
-4~
1\:)
U) FIGURE 7.4 Filament winding patterns (Richardson [11]).
co
240 TEXTILE STRUCTURAL COMPOSITES
each direction, isotropic or anisotropic preforms these structures as woven structures with zero
can be obtained. Except for the components that level of crimp.
are fundamentally Cartesian in nature, orthog- In angle interlock type of structures, warp (or
onal weaves are usually less suitable for net weft) yarns are used to bind several layers of weft
shape manufacturing than the polar weaves. Unit (or warp) yarns together (Figure 7. 7). In place of
cell size can be smaller than polar weaves which warp or weft yarns, an additional third yarn may
results in superior mechanical properties. Since also be used as binder. Stuffer yarns, which are
no yarn interlacing takes place in polar and or- straight, can be used to increase fiber volume
thogonal structures, they are also referred to as fraction and in-plane strength. If the binder yams
"nonwoven 3-D" structures in the composites interlace vertically between fabric layers, the
industry. However, it is more proper to label structure is called orthogonal weave.
Radial
FIGURE 7.6 Schematics of various 3·0 woven fabric structures for composites [12].
7.1 Textile Structural Composites 241
(a)
A prepreg is a textile structure that is impreg-
nated with uncured matrix resin. There are
Ends of
filling yarns
various forms of prepregs such as unidirectional
(weft) Path of typical warp yarn and multi-directional tape prepregs and woven
fabric prepregs. Common fibers that are used for
prepregs are graphite, fiberglass and aramid.
Figure 7.11 shows a schematic of a typical
prepreg machine for unidirectional tape prepreg.
Fibers are wound and collimated as a tape. The
matrix resin is heated to reduce viscosity and
(b) dispersed on the fibers. The prepreg is cal-
FIGURE 7.7 Angle interlock fabric; (a) with and (b)
endered for uniform thickness.
without added stutter yarns [ 12]. Prepregs are suitable for hand and machine
lay-up. Figure 7.12 shows uni- and multi-direc-
tional lay-ups. Increasing the number of oriented
Angle interlock or multi-layer fabrics for flat plies increases the isotropic strength. Four ply
panel reinforcement can be woven on traditional directions, i.e., oo /90° I +45° I -45° orienta-
looms, mostly on shuttle looms. The warp yarns tions, are considered to be sufficient for isotropic
are usually taken directly from a creel. This properties.
allows mixing of different yarns in the warp Woven fabric prepregs are widely used in
direction. Other more complex 3-D fabrics such composite manufacturing. Hot melt or solvent
as polar and orthogonal weaves require special- coating processes are used to prepreg the fabrics.
ized weaving machines. Several weaving ma- The hot melt process is similar to prepregging
chines were developed to weave complex 3-D unidirectional tapes. In solvent coating, fabric is
structures (Figure 7.8).
The most widely used materials in 2-D or 3-D
weaving are carbon/graphite, glass, and aramid.
Any material that can be shaped as a fiber can be
woven into preforms. Woven preforms can be
made of a single type of fiber material or dif-
ferent fiber and yarn materials can be used as a
hybrid structure. Due to the nature of woven
structure geometry and weaving process, when
selecting a fiber for weaving or for any other
textile manufacturing process, fiber brittleness
and bending rigidity need to be considered. For
example, carbon and graphite fibers, which ac-
count for 90% of all 3-D-woven preforms, are
prone to break and fracture during weaving.
Figure 7.9 shows preform and composite
samples made of carbon fibers.
Adanur and Tam developed multi-layer fabric FIGURE 7.8 Schematic of King's 3-D machine [13].
FIGURE 7.9 Woven 3-D preform and composite samples made of
carbon fibers (courtesy of Prof. Mansour H. Mohamed).
FIGURE 7.10 On-loom stitched, four layer fabric structure (Adanur and Tam).
242
7.1 Textile Structural Composites 243
rrrr
To
.r---;;r---::r=-:~-,...-~ prepreg
line
Center pu II packages
immersed in a bath containing 20 to 50% of a
solvent and resin mixture. The fabric is then
FIGURE 7.11 Schematic of a prepreg machine (14). dried. Hot melt prepreg fabrics have less drape-
ability and lower tack, better hot/wet mechanical
properties and they are more expensive. Solvent
coated woven prepregs offer better drape, have
oo~~~~~
oo~~~~~
lower mechanical properties and are less expen-
Oo.<:"':~~~~ sive.
Oo.<:"':~~~~ Most common fabric designs for prepregs are
00 .GG-;iG~"""'~
00"""'-:~~~~
plain, basket, twill, crowfoot (113 harness satin)
oo~~~~~ and 5 and 8 harness satin designs. Increasing the
oo.-=.""""'""""""';., number of harnesses increases the composite
I 0.4
I
Crowfoot satinf-.-
260
11000 filaments/tow) ·v;
"' c.
ll..
"'0
(:J
1.0 100
2 4 6 8 10 2 8 10
Fill yarn spac1ng, picks/em Fill yarn spacing, picks/em
FIGURE 7.13 Effect of fabric construction on composite flexural strength (left) and flexural modulus (data normalized to
100 val% warp fiber) (16).
244 TEXTILE STRUCTURAL COMPOSITES
yarns per inch as well as yarn densities) should TABLE 7.8 Change in the Properties of Hybrid
be selected carefully to meet the required proper- Fabric Composites Depending
on the Mixture Ratio of Fibers [16}.
ties. Too dense fabric structures do not conform
to complex shapes and may not allow resin Ratio of
penetration during consolidation. On the other Aramidto Tensile Tensile
Graphite Modulus Strength Compressive
hand, loose fabrics may not have the strength
Fiber (GPa) (MPa) Strength (MPa)
required in the reinforcing structure due to small
amount of fiber. Tracer yarns (yarns with smaller 100/0 35.8 544 152
denier and different color) are used in woven 50150 48.2 400 227
25175 57.2 434 317
structures to control fiber or ply alignment.
0/100 59.9 434 558
A towpreg is either a single tow or a fiber
strand that is impregnated with matrix resin.
Towpregs are especially suitable for ftlament
winding. They are used in the hard-to-form areas sectional shape such as cones and nozzles as
and joints of structural components. Most shown in Figure 4.59. Braiding allows produc-
towpregs are made by a solvent coating process. tion of near-net shape structures. The yarns can
also be deflected without discontinuity to make
holes or cutouts on the preform.
Hybrid Fabrics
A braided structure can be two- or three-
dimensional. Two-dimensional bias braid struc-
Hybrid fabrics are made of more than one type
ture is obtained with two sets of yarn carriers
of fiber or yarn. By combining different fiber
rotating in opposite directions which is the tradi-
properties in hybrid fabrics, the properties of
tional braiding process (Figure 4.55). By insert-
reinforcing structure can be optimized while
ing additional yarns in the axial direction, triaxial
reducing the cost. Hybrid composites offer new
braided structure is obtained (Figure 4.57). Tri-
possibilities for the designer as shown in Table
axial braids are particularly suitable for com-
7.8.
posites to be used as tension or compression
Graphite, boron, glass and ararnid fibers can
members [17].
be mixed in hybrid woven structures. Table 7.9
3-D braided structures are obtained by inter-
shows impact resistance of hybrid composites.
twining or orthogonal interlacing of multi-yam
systems (Figure 7 .14). In the four-step braiding
Braided Structures method, yarns are intertwined to form a multi-
layer 3-D structure (Figure 7 .15). Some of the
Although braiding is not a major manufactur- braiding yarns traverse the internal layers and
ing process for traditional textiles relative to bind the two exterior layers together. Some sort
weaving and knitting, it is one of the major of a beat-up is needed to push the yarns into the
manufacturing processes for textile composite
preforms. Braiding is done by intertwining yarns
using an over and under sequence (Section 4.6). TABLE 7.9 Impact Resistance of Hybrid Epoxy
Due to several advantages including versatility, Composites [16].
good mechanical properties and low manufactur- Hybrid Composite lzod Impact Strength
ing costs, the interest in braiding has grown for (weight%) Unnotched (J/m)
composite manufacturing in recent years. In Graphite 100% 1,495
comparison to woven structure, braided fabric Graphite 75%, aramid 25% 1,815
structure usually has low shear resistance and Graphite 50%, aramid 50% 2,349
therefore highly deferrable in the axial and radial Aramid 100% 2,562
directions. The reason for this is the lack of Graphite 100% 1,495
beat-up during braid formation. This charac- Graphite 75%, glass 25% 2,349
teristic of braided structure makes it particularly Graphite 50%, glass 50% 2,989
Glass 100% 3,843
suitable to conform to surfaces of varying cross-
FIGURE 7.14 Three-dimensional braiding (courtesy of Prof. A. EI-Shiekh).
245
246 TEXTILE STRUCTURAL COMPOSITES
n n
II"
"Ill
____, 0 0 _r--
- 0 0 0 0 0 0
[ 0 0 0 0 0 0
J
0 0 0 0 0 0
0 0 0 0 0 0
0 0 0 0 0 0
[ ·-.. 0 0 0 0 0 0
--- J
[ 0 0 0 0 0 0
- J
.. p
~
0 0 0 0 0 0
0 0 0 0 0 0
·EJ
E:: -j 0
0
. I
0
' ~
0
0
0
o.r
0 0
~J
fabric structure after each round of braiding. In -----
a two-step system to make 3-D braids, axial ~
yarns and braider yarns are used. The braider FIGURE 7.17 Various net-shape structures that can be
yarns move around axial yarns which are fixed produced by 3-D braiding [18].
parallel to each other. The resultant tubular struc-
ture has good reinforcement in axial direction but
is weak in circumferential direction. The multi-
layer interlock braiding method, which is similar
to two-step braiding, allows greater circum-
ferential reinforcement. In this method, yarns
from adjacent layers are interlocked together.
Figure 7.16 shows two setups for circular and
rectangular braiding in which the carriers move
intermittently in X or Y direction. There are
several research programs to completely auto-
mate the 3-D braiding systems in the United
States. The braiding method is very versatile to
produce various near-net shapes and structures.
It is even possible to produce nuts and bolts with
a braiding system (Figures 7.17 and 7 .18).
Knit Fabrics
FIGURE 7.21 Warp knitted, multi-axial fabric structure, LISA system [21].
piercing through the yam layers. The layers can structures [22]. In non-crimp structures, fibers
be oriented freely within the broad limits (0°, are not subject to the kink stresses inherent in
45°, 90°) as shown in Figure 7.21. Nonwoven woven fabrics, thus their optimum properties are
or non-oriented fibrous layers can be placed on maintained. They have been used successfully in
top and bottom of the structure. Stitching yams a wide variety of applications in the automotive,
secure the orientation of the reinforcing fiber aerospace, construction, corrosive and marine
layers and prevent them from slipping. LIBA industries.
structural composites are generally used in the Combination of fibers can be used within
form of plastic laminates in boat construction, layers or from layer to layer, as engineered for
domes, etc. [21]. A special type of Malimo optimum performance as shown in Figure 7.23.
machine is used to manufacture these structures Reinforcing fibers are continuously placed in
(Figure 7 .22). layers at different orientations to the next accord-
Non-crimp fabrics are a relatively new class ing to the desired properties. The layers are
of textiles. These fabrics offer a reinforcement stitched together in a manner that permits high
form that has the potential to overcome the drapeability and conformance to complex shapes.
deficiencies of woven fabrics without introduc- It is claimed that non-crimp fabrics are
ing any apparent additional property reductions. stronger and more predictable than other types
It is reported that COTECH® non-crimp fabrics of reinforcement structures. Other charac-
offer several advantages over crimped yam teristics include less resin requirements, greater
FIGURE 7.22 Malimo stitch-bonding machine with multi-axial filling insertion [20].
7.1 Textile Structural Composites 249
STITCHING YARN
BUNDLES OF
REINFORCEMENT
45
90
FIGURE 7.23 Schematic of multi-axial non-crimp fabric structure (courtesy of Tech Textiles USA).
TABLE 7.10 Tensile and Flexural Data for Laminates Produced from Quadriaxial
Fabrics at Different Orientations {23}.
251
252 TEXTILE STRUCTURAL COMPOSITES
Autoclave Modification of vacuum and pressure bag; low production; low void content, dense parts,
limited to autoclave size; wet
Blow molding Mainly closed-mold process; multi-layers; short fibers or particulates; high volume; small-
to medium-sized products
Casting (simple) Open-mold process; low production; little control of reinforcement orientation; monomers
or polymers
Compression molding Closed-mold process; preforms available; some control on orientation; dense products
Expanding Mainly closed-mold process; low to high production rates; limited control of reinforcement
orientation; small to large products; monomers or polymers
Extrusion Closed mold process; continuous lengths; multiple layers; continuous long fibers possible;
preforms possible; some control on orientation
Filament winding Mainly open-mold process; low production; control of orientation; wet
Hand lay-up Open-mold process; low production; control of reinforcement orientation; large parts; wet
Injection molding Closed-mold process; short fibers or particulates; little control on reinforcement orienta-
tion; small to medium-sized projects
Laminating (continuous) Mainly closed-mold process; medium to high production; control of reinforcement orienta-
tion; small to large products; continuous; monomers or polymers
Matched-die molding Closed-mold process; low to high production; some control of orientation; preforms;
medium-sized products; monomers or polymers
Mechanical forming Mainly colsed-mold process; medium to high production; preforms; some control of rein-
forcement orientation
Pressure-bag molding Open-mold process; low production; control of reinforcement orientation; preforms; wet
Pulforming Mainly closed-mold process; continuous; some control of reinforcement orientation;
preforms; monomers or polymers
Pultrusion Mainly closed-mold process; continuous; some control of orientation; preforms; monomers
or polymers
Reaction injection molding Closed-mold process; small to medium-sized products; medium production; monomers or
polymers
Rotational casting Open-mold process; low production; little control of reinforcement orientation; small to
large products; powders and wet
Spray-up Open-mold process; low production; little control of reinforcement orientation; preforms;
wet
Thermoforming Mainly open-mold process; preforms; medium to high production; little control of rein-
forcement orientation; mostly short fibers or particulates
Transfer molding Closed-mold process; high production; dense parts; little control of reinforcement orienta-
tion; small to medium products; short fibers or particulates; monomers or polymers
Vacuum-bag molding Open-mold process; low production; control of reinforcement orientation; preforms; wet
253
Reinforcements Gel coat
Hand-brayer-roller
Roving
Resin and
promoter
254
7.1 Textile Structural Composites 255
freezes and is ultimately ejected as the finished laminate are usually covered with a fine poly-
part. The injection molding process permits finer ester fabric which is peeled off after curing. The
part detail and can be easily automated. The part top surface of the lay-up is covered with a porous
and mold can be designed such that near-net release film and "bleeder" or "breather"
shape parts can be manufactured. There is a limit clothes if necessary. The whole assembly is then
to the amount and types of fiber reinforcement covered with a non-porous membrane and placed
that can be included in an injection molded part. in the autoclave as shown in Figure 7.31.
The injection molding process of thermoplastic Autoclave produces high quality and consistent
and thermosets is slightly different. In the ther- products but it is a rather slow process.
moplastic injection molding process, a molten
thermoplastic material is forced through an ori- 5.6 Pultrusion
fice into a cool mold where it solidifies. In ther-
moset injection molding, a reacting material is Continuous reinforcement fibers or rovings of
forced into a warm mold where the material glass, carbon, aramid, etc., are drawn through a
further polymerizes or crosslinks to a solid part resin bath for impregnation and through a heated
[25]. die to produce the desired shape and control the
resin content in a continuous process as shown in
5.5 Autoclave Figure 7.32.
Pultrusion is especially suitable for unidirec-
An autoclave is a large insulated cylindrical tional reinforcement for simple cross-sectional
metal pressure vessel with a door at one or both structures such as circular rods, tubes, channel
ends. In autoclave, which is similar to vacuum- and I-beams. Drawing velocity and the mold
bag and pressure-bag molding, heat and pressure temperature are critical during the process.
are applied on the lay-up from prepreg materials. Polyester and epoxies are commonly used in
Vacuum may be applied in the early stage to pultrusion. The resulting composite has excel-
remove entrapped air. Air can be used for pres- lent mechanical properties due to good fiber
surizing and forced hot air is used for steam alignment and high fiber fraction.
heat-up. Pressure, which is in the range of 345
to 690 MPa, is maintained during heating and 5. 7 Compression Molding
cooling. Typical temperature range is between
room temperature and 350°F. In this method, prepregs or wet impregnated
In autoclave process, the lay-up is built on a textile preforms are placed into an open mold.
mold plate which has the shape of the part to be The mold is closed and heat and pressure are
produced. For a smooth surface, both sides of the applied until the structure is formed and cured.
FAN
HEATERS
PRESSUREi ~ VACUUM
FIGURE 7.31 Schematic of autoclave molding [26].
256 TEXTILE STRUCTURAL COMPOSITES
Product
--L
Impregnating section
tank
FIGURE 7.32 Pultrusion process (Richardson [11)).
The laminate thickness can be controlled by ad- glass, ceramic and graphite textile reinforce-
justing the final distance between press platens. ment structures are suitable for RTM. Woven,
Excess resin is usually allowed to escape. Both stitched, braided, knit and other preforms can be
thermosetting and thermoplastic polymers are consolidated in the RTM process. Typical resin
suitable for compression molding. The textile materials are polyester and epoxy. RfM offers
preforms may be vacuumed before molding to high production rates, more consistent parts, and
eliminate air bubbles in the composite. Compres- material and labor savings.
sion molding is especially suitable for manufac- Comparison of resin transfer and compression
turing flat or slightly curved panels or laminates. molded glass-epoxy composites showed that the
The advantages of compression molding include RTM process gives better product uniformity
low cost, little material waste with close toler- with less void volume [28].
ances, part-to-part uniformity and repro-
ducibility, good control of fiber-to-resin ratios
and void content, and shorter cycle times. The 6. COMPOSITE PROPERTIES
compound can be heavily fllled with little orien- AND TESTING
tation of resin or additives.
6.1 Predicting the Properties of Fiber
5.8 Resin Transfer Molding (RTM) Reinforced Composites-Rule
of Mixtures
Resin transfer molding, also called resin injec-
tion molding, is suitable for manufacturing of As stated earlier, the primary purpose of com-
high fiber volume fraction (up to 70%) com- posites is to obtain properties that are not possible
posite structures. In the RTM process, the resin by any of the constituent materials alone. Figure
system is transferred, at low viscosity and pres- 7. 34 is an excellent example of the synergistic
sure, into the textile preform already placed in effect of textile composites.
the closed mold (Figure 7 .33). The resin system
may consist of resins, curing agents, catalysts,
promoters, inhibitors, etc., which may be pre-
mixed or mixed during the process using an
on-line static mixer. The resin system is then
injected into the mold. The resin is transferred at
a pressure of 20-80 psi and/or with a vacuum
in the range of 26-29 inch Hg. For good filling
and wetting characteristics, viscosity of the resin
should be less than 100 cP at the injection
temperature. After fllling with resin, the mold is FIGURE 7.33 Schematic of RTM process (copyright
sealed and heated for curing. Boron, Kevlar®, 1989 Society of Manufacturing Engineers [27]).
7.1 Textile Structural Composites 257
Principle/charac- Differentialabsorp- Changes in acoustic Uses pulsed Defects in part Mapping of tempera- 3-D imaging of a dif- Changes in elec.
teristic detected tion of penetrating impedance caused ultrasound stress stressed generate ture distribution fusely reflecting ob- cond. caused by
radiation by defects wave stimulation stress waves over the test area ject material variations
Advantages Film provides Can penetrate thick Portable, quantita- Remote and con- Rapid, remote mea- No special surface Readily automated;
record of inspection; materials; can be tive, automated, tinuous surveillance surement; need not preparation or coat- moderate cost
extensive database automated graphic imaging contact part, quan- ing required
titative
Limitations Expensive; depth of Water immersion or Surface contact, sur- Requires application Poor resolution for Vibration-sensitive Limited to elec.
defect not indicated; couplant needed face geometry of stress for defect thick specimens if not coupled cond. materials;
rad. safety detection limited penetration
depth
Defects Detected
Production calcularion
Performance predictions
Qualiry plano
I
I
Analysis
ReVIew
r-
Facilities layour:
tity and rate, capital investment for equipment Direct stress Shear
and technology, reliability and quality. Material t Distortion
Doors X X X X X X X
Rudder X X X X X
Elevator X X X X
Vertical tail X X X X X X
Horiwntal tail X X X X X X X
Aileron X X X
Spoiler X X
Flap X X X X
Wing box X X X
Body X X
decks, hoods, hinges, transiTIIsston support, mid, glass fiber or filament reinforced epoxy
bumpers, seat frames, and wheels. based textile structural composites are used. Fig-
In the defense industry, composites are ideal ure 7.40 shows application areas of composites
materials for lightweight mobile, easily trans- on a Boeing 737-300 commercial airplane in
portable vehicles for tactical shelters, ballistic com- which 3% of the total structural weight is made
bat and logistic applications. Composites are ideal of composites. Carbon reinforced composites in
materials for aircraft and aerospace applications aircrafts can provide up to 30 to 40% structural
where high strength-to-weight ratio is required. weight savings which can be used to carry more
For example, glass fiber composite strength is five fuel or payload for the same takeoff weight.
times higher than that of aluminum. Graphite and In addition to structural body composites,
boron epoxy composite stiffness is five times composites are also used for interior parts such
higher than that of aluminum. Table 7.13 sum- as overhead luggage compartments, sidewalls,
marizes the application areas of composites in ceilings, floors, galleys, lavatories, partitions,
military and aerospace applications. cargo liners, etc. Interior parts are usually made
In aircraft applications, usually carbon, ara- of fiber reinforced epoxy or phenolic resin (for
Tip
Forward fa1ring I
Tip fairings
fan cowl suppon
Thrust reverser/
Fiber strut fairing
li!lm Carbon
m Aramid
~ Carbon·aramid
-TITANIUM
E:J COMPOSITES
CJ OTHER
HORIZONTAL STABILIZER RUOOER
I FULL S P A N ) - - - - ,
WING SKIN I FULL SPAN)
fire resistance, low smoke and toxic gas emis- (Harrier II) aircraft (Figure 7.41). The com-
sions) honeycomb sandwich structures. Impor- posite parts include the wing box, forward
tant properties are impact resistance, stiffness fuselage, horizontal stabilizer, elevators, rudder,
and surface smoothness. Woven, knit, filament- over-wing surfaces, etc. On the F-18 fighter,
wound and braided textile structures are used for 10% of the structural weight and 50% of the
reinforcement. surface area are made of carbon fiber reinforced
In aerospace applications, 40% of the com- composites as shown in Figure 7.42. Other
posites is used for military applications. Carbon military aircrafts that use textile structural com-
fiber reinforced composites constitute 26% of posites include the B-IB bomber, F-14A, F-16,
the structural weight of the U.S. Navy's AV-8B and the Navy's V-22. Approximately 60% of the
1l1i11 Aluminum
~StHI
. . Titanium
c:J Composites
c:::Jo....,
STABILATOR ACCESS COVER
Insulation
Nozzle
Filament-wound caM
FIGURE 7.45 Satellite strut and truss made of graphite-epoxy composites (cour-
tesy of Hercules Aerospace Products Group).
Composites have huge potential for mass- part consistency, lack of well-established manufac-
produced, modular manufactured composite turing techniques and industry-wide specifications.
homes, mobile homes, apartments, hotels and Figure 7.46 shows the increased usage of com-
motels. Other application areas include musical posites in aerospace applications over the years.
instruments, appliance and furniture industries, With the end of the cold war, there are indica-
medical implants such as artificial joints and tions that the composite research in aerospace
organs, electronics, etc. and defense areas is decreasing which leaves the
transportation and construction to be the biggest
9. FUTURE OF TEXTILE potential areas for composite growth. As a result,
STRUCTURAL COMPOSITES due to different and probably less demanding
applications, new low cost composites need to be
Most of the composites in existence today developed. Great potential exists for the utiliza-
were originally developed for aerospace applica- tion of low cost composites in mechanical en-
tions. Detailed information and databases are gineering, civil engineering, structural engin-
available on the performance of these materials eering and other areas such as automotives and
for aerospace applications. Although the results electronics.
have been very successful, the cost factor has In automotives, composite bodies and parts
hindered the wide spread of composites into will help by increasing the fuel efficiency of the
other application areas and industries. Other fac- vehicle due to light weight. By using composites,
tors that hinder the faster growth of composite the number of parts in automobiles can be
usage include capital investment, inspectability, reduced from thousands to hundreds. Although
268 TEXTILE STRUCTURAL COMPOSITES
. - - - - - - - . 10 000
,..
~
i
.
·~
3600
8000 :e
·f"".
.c
...
& 2700
1000
8.E
E 8
0
u
~ "!
"
tl 4000
fi
~"
1800
~
2000
1980 1990
FIGURE 7.46 Usage of composites in aircraft applications within the last twenty-five years (30].
concept models of all-composite automobiles sensing, controlling and actuating. The growing
have been produced by the ''big three'' car use of composites in highly sophisticated systems
manufacturers, at the present time, they are too such as aerospace, may necessitate the develop-
costly for mass production. ment of smart or intelligent composites. This, in
The emphasis on smart or intelligent com- turn, may require new developments in poly-
posites and materials has increased recently. A mers, fibers and other textile structures. Al-
smart or intelligent material may be defined as a though some intelligent materials can be found in
material that possesses intrinsic sensing, control- naturally occurring biosystems, the development
ling and actuating capabilities. A smart or intel- of synthetic intelligent materials is still at the
ligent structure is a system that is capable of conceptual stage.
7.2
References and Review Questions
S. ADANUR
pressure
drop,&>
(psi) increasing
filter
porosity
FIGURE 8.2 Relationship between flow rate and filter pressure drop for
different filter porosities.
8.1 Filtration Textiles 277
particles follow a zig-zag route which in- (e.g., bag, flat) are made from textile materials
creases the chance of being caught by the and are used on drum, disk, plate and frame, belt,
fiber material. vessel and other filters. Detailed discussion of
(4) Electrostatic deposition-Submicron par- filter equipment is out of the scope of this book.
ticles are difficult to capture even with a Therefore, only some examples of filtration
combination of mechanical methods. It is equipment will be given below. The reader may
well known that strong electrostatic forces of refer to the references for in-depth information
fibers attract the particles. Therefore, fibers on filtration equipment.
may be given permanent electrical charges to Liquid filter bags are used in the processing of
attract small or medium sized particles. petroleum derivatives, chemicals, cutting oil,
Charged fibers increase the filtration ef- cleaning fluid, paints, pharmaceuticals, food
ficiency. processing, beverages, cosmetics, semiconduc-
(5) Gravitational forces- Under the influence of tors, etc. Micron rated liquid filters are shown in
gravity, a particle that is sinking, may collide Figures 8.4 and 8.5.
with the fiber and get caught. Figure 8.6 shows the view of a typical vessel
filter for liquid filtration. The 3M company also
Depending on the process of separation, filtra- developed a radial pleated filter element for ves-
tion is generally referred to as particle filtration, sel filters. The radial pleat design fills the entire
microfiltration, ultrafiltration, nanofiltration filter cartridge with pleats that are stacked
and reverse osmosis (hyperfiltration) as shown horizontally. According to the manufacturer,
in Table 8.1. Modern filtration techniques can radial pleat design offers more surface area, bet-
separate the particles as small as 1 Angstrom in ter performance, longer life and less wasted
size. space compared to vertically pleated filter
media.
Rotary drum filters can be vacuum-type
3. FILTRATION EQUIPMENT (rotary drum vacuum filters) or pressure-type
(pressure drum filters). A rotary drum vacuum
Filter equipment and configurations vary and ftlter, which is used for slurry filtration, is a large
can be divided into several groups. The two drum (up to 20 ft in diameter and 20 ft long)
major groups are filters for dry filtration and covered by filtration fabric. The drum rotates
filters for liquid filtration. Depending on the continuously and slowly. The lower part of the
application, different shaped industrial filters drum is dipped in the container containing the
278
8.1 Filtration Textiles 279
belt
fabric
vacuum
vacuum stroke
return stroke
280
FIGURE 8.8 Cylindrical drum filter used in the textile industry to separate coarse particles, fiber and dust
from the air flow (courtesy of LTG).
281
282 FILTRATION TEXTILES
d1aphragm valves
material d1scnarge
through rotarv a~Ciock
dust collection. Collected dust must be removed 4.1 Fibers and Fabrics
from the fabric surface periodically to allow ef-
ficient filtration. This can be done in several The most widely used fiber in dry filter media
ways including pulse jet, reverse air and shaking. is polyester (approximately 70% of all ma-
In older systems, the filter bags in one compart- terials). Other fibers for dry filtration include
ment are shaken while the air flow is diverted to nylon, polypropylene, acrylic, aramids and
another compartment. In new systems, a blast of polytetrafluoroethylene, glass and sulfar (PPS).
compressed air is blown into the bags to shake Table 8.2lists the properties of textile fibers used
them briefly without interrupting the filtration in dry filtration.
process. Dust is collected in a container below Cotton fabrics are used in older shaker type
the bags and removed periodically. Figure 8.9 systems. Woven fiberglass is currently used for the
shows the schematic of a pulse jet baghouse. removal of fly ash in utilities. Microglass blanket
media is used for high ASHRAE (American
Society of Heating, Refrigerating and Air-con-
ditioning Engineers) efficiency, extended surface
4. TEXTILES IN DRY FILTRATION filters in HVAC (Heating, Ventilation and Air Con-
ditioning) applications. Polyester felt fabric is used
Application areas for dry filtration include the for reverse jet or pulse jet systems [9].
mining industry, chemical, iron and steel in- Polyester is the most widely used fiber in gas
dustries, cement, aggregate plants, utilities, the filtration because of its strength, relatively high
primary non-ferrous smelting industry, lime, clay, temperature resistance (up to 150°C) and low
kaolin and ceramic works, feed, grain and food cost (Figure 8.10). The disadvantages of
industries, woodworking and furniture industries, polyester for filtration applications are low resis-
paper-related industries, and textile plants. Filter tance to alkalis, acids and steam. Homopolymer
media is also used in conveying, milling, mixing acrylic is used when chemical conditions and
and shipping of bulk materials [8]. temperatures up to 130°C require a better fabric.
TABLE 8.2 Properties of Textile Fibers for Dry Filtration (copyright 1989 Filter Media Consulting, Inc.).
·All Information is based on data of the dilferent fiber manufactures, verilied and acknowledged.
~IBER ~"'"""'"'
ACRYLIC HOMOPOLYMER
COTTON WOOL POLY AMID POLYPROPYLENE POLYESTER COPOLYMER ACRYLIC AROMA TIC ARAMIO POL YTETRAFLUOAETHYLENE
TRADE NAME NYLON I& HERCULON" DACRON~ ORLON~ DRALON T NOME)("" l'EIJINCONEX4'1 TEFLONJ11: TOYOFLON"
Recommended contmuous 1 BO' F 200' F 200' F 200' F' 270' F 248' F 257' F 400' F 392' F 500' F' 500' F
operat1on temperature
_@_y_heat)
82' c 94' c 94' c 94' c 132' c 120' c 125' c 204' c 200' c 260' c 260' c
--
Water vapor saturated 180' F 190' F 200' F 200' F 200' F' 230' F 260' F 350' F 356' F 500' F' 500' F
condition (moist heat) 82' c 88' c 94' c 94' c 94' c 110' c 125' c 177'C 180' c 260' c 260' c
Maximum (short time) 200' F 230' F 250' F 225' F 300' F 248' F 302' F 465' F 482' F 550' F 550' F
operation temperature
.'t!:Yl~eat
94' c 110' c 121' c 107' c 150' c 120' c 150' c 240' c 250' c 290' c 290' c
Specific density 1.50 1.31 1.14 0.9 1.38 1.16 1.17 1 38 1.37-1.38 2.3 2.3
Resistance to mineral acids Poor Good Poor Excellent Fair+ Good Very Good Fair Fair Excellent Excellent
I--·
Resistance to organic acids Poor Good Poor Excellent Fair Good Excellent Fair+ Fair Excellent Excellent
IResistance to oxidizing agents Fair Fair Fair Good Good Good Good Poor Poor Excellent Excellent
I
j Res1stance to organic solvents Very Good Very Good Very Good Excellent Good Very Good Very Good Very Good Very Good Excellent Excellent I
-~---L---------- !
Comments: '250' F tor ·Not
(continued)
Type 154 Recommended
~
(A)
N
(X)
.f:>.
TABLE 8.2 (continued).
·All information is based on data of the different fiber manufactures, verified and acknowledged.
~~----
EXPANDED
GENERIC NAME POLYETHERIMIDE SULFAR (PPS) POLYKETONE POLY IMIDE GLASS METAL • CERAMIC
FIBER PTFE
TRADE NAME RASTEx• AKZO"" PEl RYTON"!! TEIJIN PPS BAYER PPS zvex• p 84~ FIBERGLA$$ 9 BEKINOX(II; NEXTEL 312• FIBERFAX"
------- .. -
RP.commended continuous 500' F 338' F 375' F 375' F 375' F 460' F 500' F 500' F 1020' F 2100' F 2300' F
oper(]tion temperature
dr Jleat)_ 260' c 170' c 190' c 190' c 190' c 240' c 260' c 260' c 550' c 1150' c 1260" c
Weter vapor •aturated 500' F 338' F 375' F 375" F 460' F 383' F soo• F 1020" F 2100' F 2300° F
n.y.e.'
condition (moist heal) 260' c 170° c 190"C 190' c 240' c 195" c 260' c 550' c 1150' c 1260' c
Self Quenching
Suprorts combustion No No No No No No No No No No
LOI 39-41%
I
~---
8ioloqic.11 r~sistance No No No No No No No No No No
n.y e •
1 (bacteria. rnddew) Effect Elfecl Effect Effect Effect Effect Effect Effect Effect Effect
-----·~~-----
Resistance to alkalies Excellent Good ph<9 Excellent Excellent Excellent Excellent Fair Fair Excellent Good No Effect
------~--~------~---'
Resistance to minerAi acids Excellent Good Excellent Excellent Excellent Very Good Very Good Very Good Good Very Good Very Good 1
--~--- -------~.
ResistAnce to organic acid9 Excellent Excellent Excellent Excellent Excellent Excellent Very Good Very Good Very Good Very Good Excellent !
Re!=iistance to oxidizing agents Excellent Good Fair' Fair Fair" Good Very Good Excellent Excellent Excellent Excellent 1
-----
ncsistar1ce to organic solvents Excellent Good· Excellent Excellent Excellent Excellent Excellent' Very Good Excellent Excellent Excellent
~-------~~-----~--~-
Comments: 'PEl fiber is 'PPS fiber is 'n y.e. 'Soluble only 'INCONEL
dissolved by attacked by Not Yet in strong 601 "'
part i a II y strong Examined polar solvents
chlorinated oxidizing (DMF, DMAC,
hydrocarbons agents. For "Depending DMSO, NMP)
example at on
200' F for 7 Concentration
days.
8.1 Filtration Textiles 285
NOMEX Type 450 felt NOMEX high density felt Without suppon fabnc
(Approx 500 g/m 7 ) (Approx 300 g/nl)
FIGURE 8.12 Electromicroscopic photograph of Tefaire® nonwoven filter fabric (courtesy of DuPont).
inexpensive and can be melt blown. Polyimide lived electrostatic charge. They can be divided
and Gore-Tex® membrane filters are also used in into different fields of manufacturing: electro-
dry filtration. statically charged from a polymer solution, split
Ceramic fibers are suitable for hot gas filtra- fiber corona charged and post media charged
tion around 1,000°C. The major supplier of such materials. Special electret nonwoven fabrics are
fabrics is currently 3M with a material called manufactured in different weight ranges and
Nextel®. There are other high temperature thickness and consequently, different efficien-
ceramic materials being offered by European cies up to 99.9996% according to DOP (DiOctyl
manufacturers [9]. Phthalate liquid) conditions of 0.1 micron at air
For filtration of gases, nonwoven fabrics are flow rates of 5.3 cm/s [12]. Figure 8.14 shows
mainly used. Figure 8.13 shows several filter the comparison of electrostatic capture of par-
products for air filtration. Needlepunched fil- ticles and microfiberglass filters. Electrically
ter fabrics provide good dimensional stability, charged media captures particles such as NaCl
excellent particle retention and freedom from particles throughout its depth, while still permit-
plugging. They are mostly made of polyester, ting air to flow freely through the filter.
homopolymer acrylic, nylon, polypropylene, Microfiberglass filters require a more closed
Nomex®, Ryton®, P84® and PTFE. construction and capture NaCl particles primar-
Melt blown nonwovens are also growing at a ily on the filter surface which results in higher
fast rate. Melt blown and micro fiber nonwovens airflow resistance and greater pressure drops.
are used primarily in the higher efficiency ASH-
RAE and Eurovent classes with efficiencies 4.2 Applications
predominantly between 80-95%. Many melt
blown microfiber nonwovens currently used in Needlepunched filters are used in baghouses
high efficiency ASHRAE/Eurovent filtration are and fabric filters for dust filtration. Nomex®
often electrostatically charged and referred to as (aramid) filter bags are used in hot mixed asphalt
electret nonwovens. An electret is a non-conduc- plants. Thermobonded, molded and melt blown
tive polymeric material that maintains a long- nonwovens are used in industrial and medical
FIGURE 8.13 Various filter products for air filtration (courtesy of 3M Company).
FIGURE 8.14 Electrostatic capture of NaCI particles on fibers (left) versus mechanical capture of NaCI
particles with a microfiberglass filter (courtesy of 3M Company).
287
288 FILTRATION TEXTILES
face masks. High loft glass and polyester filters 0.3 micron particles. The next generation of
are common in ordinary heating and air con- filters is referred to as ULPA (Ultra Low Pene-
ditioning systems in buildings, offices and fac- tration Air filter) with required efficiencies of
tories. Carded rayon, cotton and polyester 99.9995% for particles of 0.1 micron. Such ef-
blends are used in the low-to medium efficiency ficiencies can be obtained normally at the ex-
range. Medium- to high-efficiency microglass pense of relatively high differential pressure.
blanket media is used in critical applications such Seed particles, pollen, fibrous particles, dust,
as pharmaceutical, medical, nuclear, and elec- carbon black, smoke and aerosols in the atmo-
tronic industries. Nonwoven air filters are also spheric air must be filtered for air conditioning
used in automotives, lawn mowers, chain saws systems not to exceed 4 mg/m 3 • The size of these
and portable gas-powered blowers. Other ap- particles may be less than 1 micrometer. Non-
plication areas of nonwoven filters include air- woven filters are ideal for this purpose. For many
intake filters for the protection of industrial years, the HVAC industry has used air filters to
ventilation, blower engines, turbines, pneumatic protect equipment and prevent discoloration of
controls, compressors, silencers and vacuum ceilings and other equipment. Recently, con-
pumps [8]. sumers are becoming aware of the detrimental
In industrial applications such as coal burning, health effects in relation to exposure of airborne
cement manufacture, steel making, etc. large contaminants [13]. Particles in the air that have
amounts of dust are produced which should not human health implications are now given in-
be allowed to escape to the atmosphere. Other creased attention.
particles such as carbon black, fine pigments, HVAC filters are used as part of a forced air
etc., must also be filtered. Fabric filters are very heating and cooling system to reduce indoor con-
suitable for dust collection in baghouse systems. centrations of hazardous airborne particles.
Nonwoven fabrics allow more air flow with the Some particle filters reduce the risk of lung can-
same filtration efficiency. The fabrics are usually cer associated with exposure to condensed to-
made dense with low air permeabilities. Depend- bacco smoke vapors. Microbiological particles
ing on the application conditions, the filters may such as fungi, bacteria and insects are also
become useless in several months due to removed by effective air filtration. Other air-
abrasion, chemical attack or blocking by dust. borne particles have health effects that result
Some conditions may be very harsh including from their composition and substances that are
high gas temperatures, steam, oxides of sulfur, absorbed into their composition [14]. The typical
acid, and alkaline. amounts of dust concentrations in the country-
side and in industrial areas are 0.1 mg/m3 and 5
4.3 Filters in Air Conditioning mg/m3 respectively. A level of 0.2 mg/m3 dust
concentration is considered to be acceptable.
An important area of filter application is in air Therefore, filters in air conditioning units are ex-
conditioning units. The most important reason pected to hold back 90% of the atmospheric dust.
for air filtration is to clean the air. Two applica- Filters for residential air conditioning systems
tions of melt blown nonwovens are HVAC (Heat- are usually made of a thick low-density mat of
ing, Ventilation, and Air Conditioning) and polyester or glass fibers. They are designed to
HEPA (High Efficiency Particulate Air filter) allow high air flow rate and to have good dust
filtration. The HVAC industry requires higher collection capacity. The filter should not build up
standards for air filters because of the importance pressure across its thickness. Sometimes, fibers in
of indoor air quality. The efficiencies of HVAC the mat are covered with a sticky film to help with
systems are regulated through ASHRAE in particle capture. The latest developments include
North America and under the designation an electrostatically charged material from 3M.
Eurovent 4/5 in Europe. Almost all currently Clean air is a must for many applications. In
used HEPA filters worldwide are based on hospital operation rooms, clean air which is free
microglass, wet-laid paper with minimum effi- of harmful bacteria is needed (HEPA filtration).
ciencies according to the DO P test of 99.95% for Bacteria size can range from less than a micron
8.1 Filtration Textiles 289
to 10 microns. A particle free environment is also used to drain water and chemicals from the slur-
critical for clean rooms in microcircuit manufac- ry, are made of polyester mono filaments (Chap-
turing where the distance between parts may be ter 12.0). A small percentage of nylon is also
a few microns apart. For this type of critical used to improve abrasion resistance.
application, usually a second filtration stage is
used. The second filter is usually made of a 5.2 Applications
denser fabric or a glass fiber paper with high
filtration efficiency but low air permeability. As Depending on the particle concentration, liq-
a result, a large filter area is needed which may uid filtration can be divided into two types: low
be obtained by a folded structure. The typical particle concentration and high particle con-
filtration efficiency of the second filter is around centration in which solid concentration is more
99.9% (i.e., dust penetration of0.15). than 10% . Another type of classification for liq-
uid filtration is continuous and discontinuous for
which drum (rotary) filter and plate press are
5. TEXTILES IN LIQUID FILTRATION used respectively.
When the particle concentration is below
5.1 Fibers and Fabrics 10%, the liquid is pumped through a filter fabric
that has small pores. Usually a filter aid is used
Polypropylene fibers are widely used in to prevent the blockage of small pores in the
woven and nonwoven structures in liquid filtra- fabric. The filter aid, which consists of a powder
tion to improve filtration properties because of such as diatomite, forms a porous layer on top of
their resistance to chemical breakdown. Poly- the fabric and increases the solid holding cap-
propylene represents approximately 50% of all acity of the filter and removes undesirable im-
materials in liquid filtration. Polyester in woven purities from the liquid.
and nonwoven structures is used in liquid filtra- In the second type of filtering application,
tion. Viscose rayon fibers are also suitable for such as collection of china clay, particulate
liquid filtration. chemical production, dewatering of sewage, and
Woven fabrics are common in liquid filtration. separation of coal dust, sand and clay, the solid
The most widely used designs include plain, concentration is usually more than 10% which is
basket and satin weave. Warp knit fabrics are called'' slurry:' Rotary vacuum drum filters are
used for relatively coarse filtration. The use of used for some of the slurry filtration applica-
nonwovens in liquid filtration is also increasing. tions. Filter presses are used in discontinuous
Needlepunched, adhesive bonded, impregnated filtration processes. Usually polypropylene
and calendered nonwoven fabrics are used in woven fabric is used for rotary filters and filter
liquid filtration. Needlepunched fabrics are used presses where abrasion is critical.
for plate and frame presses, belt filters and some- For some applications, a woven, stitchbonded
times drum and disk filters. or spunbonded backing may be used. For high
Rayon or polyester needled felts are used in temperature applications, the fibrous web may
micron-rated (between 3 ~-tm and 100 ~-tm) vessel be heat-shrunk. To increase the smoothness of
bags which are used as disposable filter elements the surface, a surface finish may be applied.
in single- and multi-cartridge vessels. Nylon and Smooth surface is necessary for easy removal of
polypropylene felts are also used for this pur- the sludge or cake. Polypropylene fibers offer
pose. Spunbonded filter media is used to filter good chemical resistance, durability, low mois-
and clean industrial fluids and oils extensively ture absorption and a hydrophobic surface which
used in machinery manufacturing plants. Wet- improves the cake removal.
laid nonwovens are used in food filtration espe- In sewage treatment plants, belt filter presses,
cially for dairy products such as milk. Non- drum, plate or belt filters have been used to
wovens are also used in medicine for blood filtra- dewater sewage sludges. Recently, needle-
tion and dialysis [8]. punched fabrics are being used instead of woven
Forming fabrics in papermaking, which are fabrics in these applications. Comparison of
290 FILTRATION TEXTILES
FIGURE 8.15 Filters for oil pumps (courtesy of Fugafil® Saran GmbH & Co.).
woven nylon and needlepunched polypropylene water. Modern milk filtration is done in a con-
ftlters in these applications favored the use of tinuous fashion in automatic ftlter systems. The
nonwovens. ftlter cloth must have good tensile strength.
Petroleum and its products are ftltered using Woven and nonwoven fabrics made of metal
ftlter candles. Filter candles are made into a tube fibers or yams are used for filtration of im-
shape with typical dimensions of250 mm length, purities in melt and spinning of textile fibers.
30 mm inside diameter and 60 mm outside
diameter. Nonwoven ftlter cloth is used for filtra-
tion of oil. For high purity such as aerospace 6. DESIGNING FOR FILTRATION
hydraulics, spunbonded filter cloth made of ex-
tremely fine micron-sized glass, polyester or When designing a textile structure for filtra-
polyvinyl chloride fibers is used. The new sensi- tion applications, several factors should be con-
tive high-performance petrol pumps in injection sidered that include flow velocity, pressure inside
systems set high requirements for the filtration the filtering system, size and concentration of the
characteristics of the petrol ftlter with respect to particles, and the nature and components of the
impurities and air intake. Figure 8.15 shows suspension filtered. When constructing a filter
ftlters used in oil pumps. for a specific application, the fiber must be
Filter products are widely used in the food selected such that it can withstand the harsh
industry. Water cartridge ftlters are used to purify environmental conditions such as temperature,
8.1 Filtration Textiles 291
abrasion, chemical conditions, etc. As in the case large number of air passages, they are particu-
of most industrial applications, use of synthetic larly suitable for filtration applications. The void
fibers is increasing due to several advantages volume (the volume in the fabric that is not
including reduced fabric weight because of the occupied by the fibers) is around 70% for woven
higher strength of man-made fibers, easier han- and knit fabrics and can be as high as 98% for
dling and cloth replacement, easier separation of some nonwovens. Nonwovens offer the pos-
the filter cake from the woven cloth, resistance sibility of disposable filters.
to rot, higher rate of filtration, improved fatigue All air filters change the direction of air flow
resistance, good dimensional stability, high and induce turbulence. This causes an un-
temperature resistance, better abrasion, cor- avoidable pressure drop and loss of energy. The
rosion and chemical resistance. pressure drop causes the compressed air to per-
Filter fabrics used in filter presses are form less work. Excessive pressure drop re-
calendered to obtain a smooth fabric surface quires more work from the fan to give the desired
which improves the removal of filter cakes. flow of air although air flow is not usually
Calendering is done on a machine with electri- changed. Low air flow causes poor heat transfer
cally heated calender rollers. between the coils and the air in an HVAC system.
Natural randomness of the textile structures This causes the compressor to have a higher
increases the probability of the particles being operating pressure and shortens the life of the
caught by the fibers. Therefore, nonwoven system. It also results in increased energy costs
fabrics, in general, provide higher filtration ef- in operating the system [16]. A lower pressure
ficiencies than woven or knit fabric. Woven and drop gives higher air flow and better heat trans-
knit fabrics are considered to have two-dimen- fer. Thus, reduced pressure drop provides more
sional structures while nonwoven fabrics may energy efficiency and overwhelming savings in
give three-dimensional structures with larger power usage. In many cases, more efficient
thickness which increases the distance for the filtration results in a higher pressure drop. Finer
particle to travel. It is also easy to construct filtration, however, does not necessarily cause a
nonwovens in layers. A coarse open fabric decrease in air flow and higher pressure drop. A
removes larger particles. As the fluid progresses balance must be reached between the efficiency
through the filter, the fibers and pores become of heating/ cooling and filtration efficiency.
finer to trap fmer particles.
The advantages of nonwoven filter media over
woven filter media include [3]: 7. TESTING
in gas and dust filtration include permeability, A known amount of ASHRAE Synthetic Dust is
differential pressure, efficiency, strength and then introduced into the airstream through a fun-
chemical resistance. These parameters are all nel at the top of the duct upstream of the filter.
tested, particularly if fabrics are failing [9]. The dust is fed at a controlled rate until a uniform
Efficiency of air filters measures the ability of distribution of particles covers the filter. The
the filter to remove particulate matter from an filter remains in the airstream for five minutes to
airstream. Arrestance is one type of efficiency allow any particles not trapped in the filter media
measurement that determines the amount of par- to pass through. The filter is removed and
ticulate matter that is retained in a filter when weighed to determine the increase in weight due
introduced into the airstream [17]. The ASH- to the added dust. Finally, the percentage of dust
RAE Standard Test Method 52-76 is widely used held (arrestance) is calculated by dividing the
for arrestance measurements. In this method, a difference in weight of the filter before and after
clean filter sample is placed into a wind tunnel. testing by the amount of dust injected.
8.2
References and Review Questions
Dickenson, C., Filters and Filtration Handbook, Morgan, H., "Cost-Effective Clean Room
3rd Edition, Elsevier, 1994. Designs;' Filtration and Separation, January I
Rothwell, E., "Who Needs Better Filter Me- February.
dia;' Filtration and Separation, March/ April Matteson, M. J., and Orr, C., eds., Filtration
1987. Principles and Practices, 2nd Edition, Marcel
Passant, F. H., "Gas Cleaning in the Nuclear Dekker, Inc., 1987.
Industry;' Filtration and Separation, May/
June 1987.
Cherernisinoff, N. P. and Azbel, D. S., Liquid 2. REVIEW QUESTIONS
Filtration, Ann Arbor Science, 1983.
1. Why are textile structures effective in filtra-
Hunter, J. S. III, "Recent Developments in
tion? Explain.
Buoyant Media Liquid Filtration;' Filtration
2. What are the main fabric requirements for dry
and Separation, November/December 1987.
and liquid filtration?
Molter, W. et al., ''Fast, Automated Testing of 3. What are the advantages and disadvantages of
Different Air Filter Media;' Filtration and woven and nonwoven fabric structures for
Separation, January/February 1992. filtration?
Callis, R., ''Practical Application of High 4. Make a table showing application areas of
Temperature Filters;' Filtration and Separa- textile filter media along with fibers and
tion, July/August 1991. fabric types that can be used in each applica-
Versen, R. A., ''Clearing the Air about Fiber- tion.
Glass Air Filters;' Filtration and Separation, 5. What are the major test methods to measure
March/April1994. the efficiency of filters?
9.0
GEOTEXTILES
9.1
Geotextiles
S. ADANUR
Without With
With
FIGURE 9.2 Schematic of railroad bed construction with and without geotextile (courtesy of Hoechst Celanese).
298
TABLE 9.1 Geosynthetics Application Summary [1}.
Application Primary Function Products
Nonwoven Woven
Mass per unit area: a basic identifier typically ranging from 3 oz/yd2 to 16 oz/yd2 •
299
FIGURE 9.3 Woven geotextiles (courtesy of Hoechst Celanese).
300
9.1 Geotextiles 301
finishing. Filaments or short fibers are first ar- [3]. Hot air is either blown through the web on a
ranged into a loose web, then bonded together by conveyor belt or sucked through the web over a
chemical, thermal or mechanical bonding porous drum. In calender bonding, the web is
processes (Section 4.8, Nonwoven Fabrics). drawn between cylinders under heat and pres-
In a chemical bonding process, which is used sure. Calendering gives strong, stable and low
the least, a cementing medium such as glue, latex loft fabrics. Binder materials can be homofil
or resin is added to bind the filaments or short (monocomponent) and heterofil (bicomponent or
fibers together. The impregnated web is then sheath/core spun). The heat bonded nonwoven
cured and/or calendered. fabrics are normally relatively thin.
In the thermal bonding (also called melt or heat Mechanical bonding is done by a needle-
bonding) process, filaments or short fibers are punching process. In this method thousands of
subjected to heat and melted at their crossover barbed needles, attached to a board, are punched
points (Figure 9.4). Thermal bonding can be through the loose web and withdrawn, leaving
achieved with or without additives. If the melting filaments entangled. The needlepunched non-
temperature of the fibers in the web is relatively woven geotextiles are relatively thick (Figure 9.5).
low, they can be easily melted at their crossover Spunbonding, which combines fiber spinning,
points under heat without additives. Alternately, web forming, web bonding and finishing in a
if the melting temperature of the web fibers is continuous process, is widely used to produce
high, bonding additives such as powder and geotextiles from polymers. Spunbonding
granules of fibers can also be used which melt at process may be followed by needlepunching
lower temperatures and bond the web fibers process for some geotextiles.
together. However, this method is rarely used. Special fabrics such as webbings, mats and
The most common fusing methods are through nets are generally coarser than classical geotex-
air or steam heating and calender bonding. In air tiles. Webbings are very coarse woven fabrics
heating, hot air is used to melt the fibers which made of strip-like fibers. A webbing looks like a
produces high loft, low density fabrics in general very coarse slit film woven fabric. Mats are
made of coarse and rather rigid filaments with a Geotextile tests can be two types: index tests
tortuous shape, bonded at their intersections. and performance tests. An index test generally
Some mats look like a very coarse and open does not produce an actual property value but
nonwoven fabric. Nets consist of two sets of provides a value or indicator from which the
coarse, parallel extruded strands (using rotating property of interest can be qualitatively assessed.
spinnerettes) intersecting with a constant angle. Index tests can be used as a means of product
Strands of one setting are connected to strands of comparison and for specifications and quality
the other set by partial melting at the intersec- control evaluation. They are usually rapid and
tions. When designing and manufacturing efficient to perform. Performance tests require
geotextile fabric for a particular civil engin- testing of the geotextile with soil to obtain a direct
eering application, construction considerations assessment of the property of interest. They pro-
need to be evaluated very closely. vide a direct measure of the soil influence on the
particular geotextile property and vice versa.
3. GEOTEXTILE PROPERTIES Performance tests should be done in conjunction
AND TESTING with the site soils under specific design condi-
tions.
Numerous geotextile fabric and fiber proper-
ties are critical for the performance of geotextiles 3.1 Physical Properties
in the field. All the properties of geotextiles fall
under three major categories. The important physical properties of geotex-
tiles are thickness, mass/unit area and flexibility.
• intrinsic properties, such as physical and Specific gravity may become an important
mechanical properties, that are called parameter for some applications involving water
properties of a geotextile in isolation [4]. If the specific gravity of the geotextile is less
• geotextile properties that influence than one, the fabric may float in water. Specific
soil-geotextile interaction gravity of a geotextile fiber is almost equal to the
• endurance properties specific gravity of the base polymer. Specific
9.1 Geotextiles 303
gravities of some geotextile materials are: poly- width strip method) and ASTM D 4632 (grab
propylene = 0.90, polyester = 1.38, nylon = method). Mostly 4" and 8" wide samples are
1.14, polyethylene = 0.92 (Table 17 .2). used for tensile testing (20" wide samples may
The geometry of geotextiles is essentially also be used). Figure 9.7 shows the wide-width
characterized by the fact that the thickness is tensile test of a nonwoven geotextile sample. A
much smaller than the two other dimensions, the wide specimen is especially needed for non-
length and the width. In other words geotextiles wovens because of their necking during testing.
are bidimensional products. Thickness of a In confined tensile tests, the specimen is sur-
geotextile is measured at a specified pressure of rounded by soil to simulate the in situ conditions.
2.0 kPa [5]. Thickness is important for in-plane Figure 9. 8 shows a plot of confined and uncon-
water flow. fined load-elongation curves for a woven and
The mass per unit area (oz/yd2 or g/m 2) char- needlepunched nonwoven geotextile. Confine-
acterizes the quantity of material in the direction ment significantly increased the load values for
perpendicular to the plane of a geotextile [6]. In the nonwoven geotextile.
general, fabric cost and some mechanical Geotextile fabric ends are seamed together for
properties are related to mass per unit area. property continuity either in a shop or in the
Most geotextiles are very flexible in nature field. Various types of seams are used for dif-
with very low bending resistance or stiffness as ferent fabrics. Seaming is usually done by
a result of the mechanical property of the fibers sewing the ends together. Other methods of
used. In stiffness or flex test [7], the geotextile seaming include epoxy, resin, and mechanical
gravitationally bends under its own weight. seaming. Several sewn seam types are shown in
Flexibility of geotextiles enables them to be Figure 9.9.
produced and shipped into rolls and installed Although 100% seam efficiency is desired, it
easily. Functionally, reinforcement may be im- is hardly possible. 90% seam efficiency is con-
portant in reinforcement applications. sidered to be good. Seam efficiency (SE) is
defined as
3.2 Mechanical Properties
SE (%) = (Ts/Tg) X 100 (9.1)
Important mechanical properties of geotex-
tiles are compressibility, tensile strength, seam where 1's is the tensile strength of the seam area
strength, tear, burst, impact and puncture and Tg is the tensile strength of the geotextile
strength. without a seam. Seam efficiency decreases with
Compressibility of woven and thermally increasing fabric strength. In testing of sewn
bonded nonwoven geotextiles is low. Needle-
punched geotextiles have high compressibility.
Compression of a geotextile reduces its transmis-
sivity (in-plane flow) and permittivity (cross-
plane flow) since it changes the pore structure of
the fabric.
Tensile properties are important properties of
geotextiles. Adequate tensile strength is neces-
sary for all types of geotextile functions and
installation. In general, maximum tensile stress,
elongation at break, toughness and modulus
values are reported from tensile tests. Toughness
is the work done per unit volume before fabric
failure which is the area under the stress-strain
curve. Figure 9.6 shows typical load-elongation
curves of woven and nonwoven geotextiles.
Various specimen sizes for tensile testing of FIGURE 9.6 Typical tensile load-elongation diagrams of
geotextiles are indicated in ASTM D 4595 (wide woven and nonwoven geotextiles [8].
FIGURE 9.7 Wide-width tens1le test of a geotextile [9].
304
'prayer' seam
'J' seam
Ssp-1 SSp-2
'buttert1y' seam
SSd-l SSd-2
FIGURE 9.9 Sewn seam types for geotextiles [1 0].
305
306 GEOTEXTILES
·~
eight inch wide seam is gripped in its entire width
with clamps of a tensile testing machine. A lon-
gitudinal (perpendicular) force is applied at a
specified rate of extension until the seam or the
fabric ruptures.
Properties related to the ability of a geotextile
to withstand damage are typically the resistance
to tear and puncture. ASTM D 4533 is used for
n.
Puncture
. .. ..
trapezoidal tear test of geotextiles. The puncture
test is done according to ASTM D 4833. Figure 0
9.10 shows schematics of some of the mechani-
cal tests for geotextiles.
[J
required when soil and geotextile are designed to
move against each other. The shear strength is
governed by the angle of internal friction de-
veloped between soil and geotextile. Two dif-
ferent tests are done to test the friction behavior
of geotextiles: direct shear and pullout tests (Fig- Grab Tensile
ure 9.11).
Indirect shear(ASTM D 5321), the geotextile
is fixed to the bottom half of the shear box which D sample as cut ~ area actually tested
moves against the other half that contains soil FIGURE 9.10 Schematics of some mechanical tests for
under normal stress. Shear forces versus normal geotextiles [1].
forces are plotted from which shear strength
parameters can be obtained. The pullout test is
carried out with the geotextile embedded in the tion coefficients can be generated. ASTM is cur-
soil. This test is usually performed with a normal rently developing a standardized pullout test
stress or surcharge, which represents normal method.
stress in the field, applied above the topsoil layer. Swan [11] studied the effect of geotextile
The horizontal force applied to pull the geotextile geometry on the shear strength parameters of a
out of the soil is recorded as shown in Figure geotextile. He showed that the fabric geometry
9.12. Pullout resistance is calculated by dividing greatly influences the shear strength parameters
the maximum load attained by the test specimen of a geotextile for a given soil type. His study also
width. Plot of pullout resistance versus deforma- showed that the geotextiles having similar
tion at different points along the geotextile can be strength, construction and yarn geometry can
obtained for different applied normal stresses. have different shear strength in a particular soil
From this information, response curve interac- due to difference in geotextile geometry.
pull-out
load
pull-out test
normal pressure
600r
550~
~ 500
.::
::; 450
g
"'2400
~ 350
g
..... 300
§
~ 250
c. 200
150
<>-<> SAND wrrn PEA GRAVEL
100
.,___. MEDIUM SAND
50
0~----~--~--~--~--------~
0.0 1.0 20 3.0 4.0 5.0 6.0 7.0 8.0
FRONT END DISPLACEMENT (INCH)
FIGURE 9.12 Typical pullout load versus displacement
curves for woven geotextiles (Adanur, Mallick and Zhai).
307
308 GEOTEXTILES
The physical interaction is characterized by difficult to obtain a reading of head change ver-
the hydraulic properties of the geotextile. These sus time in the falling head test. In the falling
properties are porosity, percent open area (POA), head test, a column of water is allowed to flow
apparent opening size (AOS), permittivity and through the geotextile. Readings of head changes
transmissivity of a geotextile. Porosity, which is versus time are recorded. The flow rate in this
the ratio of void volume to total volume, indi- test must be slow enough to obtain the accurate
cates the total void volume of the geotextile avail- readings. In the constant head test, a head of 5
able for establishing effective filtration with the em of water is maintained on the geotextile
in situ soil. Pore sizes of some geotextiles may throughout the test. The quantity of flow versus
change under normal load in the field. POA is the time is measured.
ratio of open area to total fabric area which is a Since permittivity may change for some geotex-
valid measurement for woven monofilament tiles under load, a test method for geotextile per-
geotextiles only. Monofilament geotextiles have mittivity under load is being developed by the
a POA range of2-60%. Apparent opening size ASTM. This method provides a means of measur-
or Equivalent Opening Size (EOS) is measured ing the water flow in the normal direction through
for woven and nonwoven geotextiles. To deter- a known cross section of a geotextile sample. The
mine the AOS with ASTM D 4751, a geotextile test is conducted under specified constant hydraulic
sample is placed in a sieve frame. Sized glass head over various applied normal compressive
beads are placed on the surface of the geotextile. stresses. This procedure assumes that Darcy's law
Several sizes of glass beads are used. The sample is valid, which implies saturated conditions and
is tested with the smallest bead first. The geotex- laminar flow. This procedure is normally per-
tile, glass beads and frames are shaken laterally. formed using deaerated water.
The jarring motion causes the beads to pass Filtering efficiency and flow rate of a geotex-
through the sample. The beads remaining on the tile for silt fence applications using site specific
geotextile surface as well as the ones that fall off soil are determined using ASTM D 5141. This
as a result of turning the specimen over and test procedure is useful in determining the spac-
tapping the rims of the sieves are weighed. The ing between silt fences or barriers. It provides a
beads that pass through the sieve are also way to evaluate geotextiles with different soils
weighed. The procedure is repeated using suc- under a variety of conditions that simulate silt
ceedingly larger beads until the weight of the fence or barrier installation. This method may be
beads passing through the sample is 5% or less. used to simulate several storm events on the same
A plot of percent passing versus particle size is geotextile specimen. The test procedure consists
obtained. The AOS of each specimen is the U.S. of placing a geotextile sample across a flume and
sieve number which represents the size of the passing sediment laden water through it. The
beads of which 5% or less pass. The AOS for the time it takes for the water to flow through the
test is determined by averaging the AOS values sample as well as the amount of soil passed by
for five specimens. This test has some limita- the geotextile is recorded. This information is
tions. For example, beads may stick to the used to calculate the amount of soil retained,
geotextile due to the development of static filtering efficiency, and the flow rate. This test
electricity. Bead clumping may also occur. method should be carried out with soil obtained
Permittivity or cross-plane water flow is an from the construction project site.
important index test for filtration. The mech- Transmissivity of a geotextile characterizes
anism by which water moves through the geotex- the flow of water in the plane of the geotextile
tile is characterized by the permittivity of gee- and is generally very small. Transmissivity of a
textile. ASTM test method D 4491 is used to geotextile depends on the cross section of the
determine the water permeability of a geotextile fabric. Woven and nonwoven heat bonded
as the permittivity. The method consists of a geotextiles are relatively thin and as a result have
falling head test and a constant head test. The negligible transmissivity, while transmissivity of
constant head test is used when the flow rate of needlepunched fabrics is slightly higher. ASTM
water through the geotextile is so great that it is D 4 716 covers constant head hydraulic transmis-
9.1 Geotextiles 309
sivity (in-plane flow) of geotextiles and geotex- The resistance to abrasion is determined and is
tile related products. It is used to determine the expressed as a percentage of the breaking load
hydraulic transmissivity of a sample. This is before abrading.
determined by measuring the quantity of water Physicochemical degradation of geotextiles
that passes through a test specimen in a specific can be caused by long term confmement under
time interval under a specific normal stress and sustained load or exposure to the atmospheric
a specific hydraulic gradient. The hydraulic conditions such as ultraviolet ray, moisture, dif-
gradient and the specimen contact surfaces are ferent chemicals (ASTM D 5322), etc. When a
selected to simulate a given set of field geotextile is subjected to a constant long-term
parameters. Measurements are repeated under load, the base polymer in the geotextile suffers
normal stresses ranging from 1.45 psi to a max- from long-term creep deformation. Creep of a
imum specified value. Figure 9.13 shows the geotextile is an important property for reinforce-
schematic of the test. ment application because, as the geotextile un-
dergoes creep deformation, its thickness
3.4 Endurance Properties decreases with time. In tension creep testing of
geotextiles (ASTM D 5262), the geotextile
These properties are related to the resistance sample is maintained at a specific temperature
of a geotextile to progressive deterioration. and humidity. Unless otherwise mentioned, a
Durability of a geotextile depends on the stress temperature of 21 ± 2 o C and relative humidity
exerted by the external media and the base of 50% -70% shall be used. A sustained load is
material used to make the geotextile, which is applied to the sample in one step, and the total
usually polymer. The geotextile can be subjected elongation of the sample is measured as a func-
to two types of external actions, mechanical and tion of time. From this information, the tension
physicochemical (degradation). creep behavior of a geotextile can be measured.
Abrasion is defined as the wearing away of any The creep behavior of geotextiles is greatly in-
part of a material by rubbing against another fluenced by soil confinement conditions.
surface. Abrasion can be caused by large soil Another important performance property of a
particles such as gravel or the failure of soil- geotextile is its long-term drainage capability or
geotextile system. The abrasion resistance test of its resistance to clogging. The soil-geotextile
geotextiles is done using the sliding block system clogging potential is determined using the
method (ASTM D 4886). In this method a sample ASTM D 4716 hydraulic transmissivity test
is mounted on a stationary platform. The sample method or ASTM D 5101 gradient ratio test
is rubbed by an abradent which has specific sur- method. The latter test method requires setting
face characteristics. The abradent is rubbed with up a cylindrical clear plastic permeameter with a
a controlled amount of pressure and abrasive geotextile and soil. Water is passed through this
action on a horizontal axis using uniaxial motion. system with varying differential heads and site-
WATER
RESERVOIR
FIGURE 9.13 Constant head hydraulic transmissivity testing device (copyright ASTM,
reprinted with permission (12]).
310 GEOTEXTILES
specific soils. Measurements of differential total exposure time for each direction. After the
heads and flow rates are taken at different time samples have been exposed, they are subjected
intervals, which are used to determine hydraulic to a strip tensile test. These test results are com-
gradient. pared to the test results for five unexposed con-
Common causes of degradation of geotextiles trol samples to determine the deterioration that
are temperature, chemical, hydrolysis, biologi- has occurred due to ultraviolet exposure. Results
cal, sunlight degradation and polymer aging. are reported as percent strength retained.
Deterioration of geotextiles from exposure to ASTM D 4594 determines the effects of
ultraviolet light and water can be determined temperature on stability of geotextiles. This pro-
according to ASTM D 4355. In this procedure, cedure consists of conditioning geotextile sam-
geotextile specimens for the machine and cross- ples at selected temperatures in an environmental
machine directions are exposed for 0, 150, 300 chamber that is attached to a tensile testing ma-
and 500 hours of ultraviolet exposure in a xenon- chine. The temperatures selected are the tem-
arc device. The exposure consists of 120 minute peratures at which the geotextiles will perform
cycles. The cycles are made up of 102 minutes or are typically exposed in the field. A two inch
of light only, followed by 18 minutes of water strip tensile test is performed on the samples as
spray and light. Five samples are tested for each specified in ASTM D 5035, while the selected
9.1 Geotextiles 311
temperatures are maintained. Control samples (Figure 9.15). Without geotextile, subsoil and
are also tested under standard laboratory test aggregate base intermix and load-bearing
conditions. Tensile strength and percent elonga- capacity are reduced. With geotextile as a
tion properties are recorded at various test separator between subsoil and aggregate base,
temperatures. Strength changes due to the effects load-bearing capacity is maintained.
of temperature are determined. Chemical In almost every application, geotextiles play a
degradation is a major concern since it may separation role. Important geotextile property
potentially cause the failure of the geotextile. requirements for separation are tensile strength,
Table 9.3 summarizes the geotextile test methods puncture, tear, AOS and permittivity. If the
approved by the ASTM. geotextile is locked into position by the material
above and below, it may be subjected to a lateral
4. GEOTEXTILE FUNCTIONS in-plane tensile stress. This tensile stress is
caused by the stones just above the fabric. Table
The main functions of geotextiles are sepa- 9. 5 shows the parameters of influence for separa-
ration, reinforcement, stabilization, filtration, tion function at different stages of construction.
drainage, waterproofing and protection. Table Table 9.6 lists the major geotextile strength re-
9.4 shows geotextile application areas versus quirements for separation.
geotextile functions.
4.2 Reinforcement and
4.1 Separation Function Stabilization Function
Geotextiles are used to separate two dissimilar Geotextiles are high tensile strength materials
materials such as two layers of soil with different and soils, in general, are low tensile strength (but
properties. The purpose of separation is to main- high compression strength) materials. There-
tain or improve the integrity and performance of fore, geotextiles are ideal materials to increase
both materials. Figure 9.14 shows examples of soil quality and thus to increase soil structural
separation function where the geotextile keeps stability. Figures 9.16 and 9. 17 show reinforce-
the soil particles from migrating and mixing with ment applications of geotextiles.
the coarse aggregate. The geotextile ensures that Geotextile increases load-bearing capacity by
the aggregate maintains its load-bearing ability providing tensile mechanism to the soil. This is
With Without
Without
312
TABLE 9.5 Parameters of Influence for Separation Function {2].
Parameters
TABLE 9.6 American Association of State Highway and Transportation Officials (AASHTO) M288
Separation Strength Requirements {13].
313
r--------------------------------------:
I
!
'
Metal Bar
or Pipe
FIGURE 9.16 Reinforcement function of geotextiles: geotextile wall construction steps (courtesy of Hoechst
Celanese).
FIGURE 9.17 Geotextile used to stabilize a steep highway embankment (courtesy of Polyfelt).
314
9.1 Geotextiles 315
Parameters
Slope failure Geotextile tensile strength Hydraulic boundary Creep of the geotextile-soil
Geotextile-soil friction conditions system
Confined strength-elongation In-plane permeability Chemical and decay
resistance
Base failure Tensile strength Hydraulic boundary Chemical and decay
Geotextile-soil friction In-plane permeability resistance
achieved through a bonding mechanism to the that will not clog during the operation period. As
geotextile-soil system. Three different mech- a result, important geotextile properties for
anisms can play a role during a geotextile rein- filtration function are cross-plane permeability
forcement function: membrane-type, shear-type (permittivity), soil retention and compatibility
and anchorage-type. In membrane reinforce- over an indefinitely long period of time. Table
ment, a vertical load is applied to a geotextile on 9.8 shows geotextile requirements for filtration
a deformable soil. In shear reinforcement, a function.
geotextile that is placed on a soil is loaded in the Typical application areas of geotextiles for
normal direction and two materials are sheared filtration are pipe underdrains, drainage for
at their interface, similar to direct shear tests. In retaining walls and erosion control structures as
anchorage reinforcement, a tensile force is ap- shown in Figures 9.18 and 9.19.
plied to the geotextile that is surrounded by soil
on both sides (similar to pullout tests). 4.4 Drainage Function
Geotextile requirements for reinforcement
function are mechanical (shear strength, tensile The drainage function of a geotextile involves
strength), hydraulic and durability (chemical and transmission of liquid in the plane of fabric
decay resistance) as shown in Table 9. 7. without soil loss. Figure 9. 20 shows an earth dam
with geotextile chimney drain. The major dif-
4.3 Filtration Function ference between filtration function and drainage
function is the direction of flow which makes
In filtration function, geotextile acts as a filter in-plane permeability (transmissivity) critical for
by allowing free liquid flow through its plane and the drainage function. Drainage refers to planar
by retaining soil particles on the upstream side. flow as opposed to filtration which refers to flow
Therefore, the geotextile must meet two con- across the geotextile. The soil retention and long-
tradictory demands simultaneously: open struc- term compatibility requirements are similar to
ture for flow of water and tight fabric structure filtration [ 14].
for soil retention. Another important factor is the Table 9.9 shows geotextile requirements for
long-term soil-fabric system flow compatibility drainage function. Fabrics must be relatively
Application Condition Mechanical Filter Stability Hydraulic Filter Stability Long-Term Performance
Upstream Side
Downstream Side
316
9.1 Geotextiles 317
Parameters
thick to provide significant transmissivity. The when impregnated with bitumen or polymeric
only materials of geotextiles with in-plane flow sealing materials. After impregnation, the water
are needlepunched geotextiles. and vapor permeability of the fabric become very
Drainage can be classified as gravity flow and low, in both cross-plane and in-plane flow. For
pressure flow. For gravity drainage, a geotextile the waterproofing function, geotextiles must be
is placed on a slope that creates the necessary homogenous and have affinity for the sealing
driving force for drainage. Typical application material. Fabric shrinkage which may be caused
areas for gravity drainage are chimney drains in by temperature variations should be low. Ade-
dams, pore water dissipaters behind retaining quate elongation is desired to compensate for
walls, and flow interceptors as in fin drains [4]. stresses due to temperature fluctuations. Physi-
In pressure flow, water flows from locations of cal and mechanical requirements of geotextiles
higher pressure to locations of lower pressure for waterproofing function are shown in Table
regardless of the geotextile' s orientation. Ex- 9.10.
amples of pressure drainage are reinforced earth
walls, earth embankments, dams, and beneath 4.6 Protection Function
surcharge fills.
In a variety of structures, geotextiles are used
4.5 Waterproofing Function with geomembranes. Geotextiles can provide
(Moisture Barrier) long-term protection of geomembranes against
mechanical damage, such as perforation and
Geotextiles can act as waterproof materials abrasion, during and after installation. Required
Parameters
318
9.1 Geotextiles 319
Parameters
properties of geotextiles for protection function reported when geotextile was used as a protective
are primarily puncture resistance and abrasion layer underneath the membrane. In this regard,
resistance. They also must be chemically stable the laboratory test estimated that the thickness of
and decay resistant for long-term performance. the geomembrane could be reduced by a factor
Typical application areas are highway tunnels, of at least two when a geotextile is used.
landfills, water and sewage tunnels, railroad and
subway tunnels and reservoirs. Figure 9.21 4. 7 Combined Functions
shows geomembrane protection with geotex-
tiles. First geotextile, then synthetic liner is in- Most of the time, geotextiles must serve more
stalled. than one function (Thble 9.4). For example, in
Table 9.11 shows geotextile requirements for road construction separation, filtration and rein-
protection function. A significant increase in the forcement functions are involved (Figure 9.22).
puncture resistance of the geomembrane was Beneath railroad ballast, the geotextile must
meet the requirements for separation, reinforce- method, which is not practiced much any
ment, filtration, and drainage. In these situa- more, design decision of selecting a geotex-
tions, in addition to the primary function, tile fabric for a particular application is based
additional functions must all be satisfied. Since on the price and availability of geotextile
the required factor of safety for each function fabrics.
must be satisfied, the cumulative factor of safety
(2) Design by specification- This method is
will increase progressively.
common with public agencies. In this
method fabric properties are specified by the
agency for each application category.
5. DESIGNING WITH GEOTEXTILES
Method of specifying geotextiles may vary
from state to state. American Association of
Table 9.12 shows the important criteria and
State Highway and Transportation Officials
principal properties required to evaluate a
(AASHTO) has published manuals for the
geotextile against a specific application. A
specification guidelines. It should be noted
geotextile designer can select a geotextile for a
that these specifications generally list mini-
particular application using one or a combination
mum required fabric properties [15].
of the following methods [4]:
(3) Design by function- In this method, the re-
(1) Design by cost and availability- In this quired numerical value of the geotextile
TABLE 9. 12 Important Criteria and Principal Properties Required for Geotextile Evaluation {14].
Application
Design requirements
Mechanical strength
Tensile strength Wide-width strength X
Thnsile modulus Wide-width modulus X
Seam strength Wide width X
Tension creep Creep * X
Soil-fabric friction Friction angle X
Hydraulic
Flow capacity Permeability X X X X
Transmissivity X
Piping resistance Apparent opening size (AOS) X X X
Clogging resistance Porimetry X
Gradient ratio X
Constructability requirements
Tensile strength Grab strength X X X X
Seam strength Grab strength X X X
Puncture resistance Rod puncture X X X X
Tear resistance Trapezoidal tear X X X X
Longevity (durability)
Abrasion resistance** Reciprocating block abrasion X
UV stabilityt UV resistance X X
Soil compatibilitytt Chemical X X ? X
Biological X X ? X
Wet-dry X X
Freeze-thaw X X
*Compression creep.
**Erosion control applications where armor stone may move.
tExposed fabrics only.
ttWhere required.
9.1 Geotextiles 321
TABLE 9.13 Geotextile Design Chart {2}. are partial safety factors to account factors
(1) Project analysis such as installation damage, creep deforma-
• Problem addressed tion, degradation effects, soil clogging, etc.
• Feasibility of geotextiles (yes/no?) These partial factors of safety values can be
(2) Determination of geotextile primary and secondary obtained by direct experimentation and
functions
measurement. If the calculated safety factor
• Separation
• Filtration is greater than the required FS, then the
• Drainage geotextile is accepted for that particular ap-
• Reinforcement plication. Table 9.13 shows steps for design-
• Cushion ing with geotextiles.
• Waterproofing
(3) Determination of required safety factor: /s,coqurroo
(4) Determination of on-site parameters
• Soil: grain size distribution 6. APPLICATION EXAMPLES
soil strength OF GEOTEXTILES
permeability
• Water: rate of flow Geotextiles play several important roles in
flow conditions
hazardous or sanitary landfills, roads, retaining
• Stress: static
dynamic walls, earth embankments, dams, coastline slope
(5) Calculation of minimum required values: X'"'luired protection, streambed lining, sand and dune
(6) Determination of actual geotextile minimum protection, foundation reinforcement, tem-
values: Xacwa1 porary walls, pipelines, erosion control struc-
• Mechanical: puncture resistance
tures, clay liners, reservoirs and tanks [16-22].
burst strength
tear resistance
There are around eighty specific application
tensile strength areas for geotextiles [2,21]. Figures 9.23-9.25
• Hydraulic: in-plane permeability show some applications of geotextiles. The roles
cross-plane permeability of geotextiles in major applications are explained
effective opening size (EOS) of below.
the geotextile
Filtration geotextiles are used to retain
apparent opening size (AOS)
flow rate erodible soil on slopes and within subsoils for
(7) Calculation of actual safety factor: J,,acruaJ protection against subsurface erosion. Geotex-
(8) Comparison of safety factors: J,,acnw.~ versus tiles retain soil particles in place while allowing
J,,rfX¥Jired seeping groundwater to freely drain, which pre-
vents fine soil particles from clogging drainage
systems. It also prevents the buildup of hydro-
property is calculated for the primary func- static pressures in protected slopes and enhances
tion that the geotextile will serve. Then, a slope stability for erosion control. Thick
factor of safety (FS) is calculated as follows: drainage geotextiles have limited capability of
allowing liquids or gases to flow within the
FS = allowable property/required property fabric's plane. Biodegradation of landfill waste
produces large quantities of carbon dioxide and
where allowable property is a value based on methane. Geotextiles are used as part of the
a laboratory test method that models the field landfill cover system to collect and vent the
conditions and required property is a value gases to prevent random gas migration, buildup
based on a design method that models the and possible explosion. Geotextiles used as silt
field conditions. Allowable property, Pa, is fences and silt curtains remove sediments from
calculated as flowing water. Figure 9.23 shows application of
geotextiles for ftltration.
Pa = P, {1/(fi + ji + j3 + ... )} (9.2) Reinforcing geotextiles provide stability for
water-sensitive structures that can be weakened
where P, is the test property and ji, ji, j3, etc. by forces of water. Mixing forces of water can be
322 GEOTEXTILES
GEOTEXTILE
(PROTECTOR)
SAND
(DRAINAGE LAYER)
GEOMEMBRANE
m COMPACTEDCLAY
LINER
clay liners is extremely low varying from w-s to FIGURE 9.26 Market growth of geotextiles (courtesy of
w- 9 em per second. IF AI).
24. Deatherage, J. D., Beckwith, G. H., and 4. Explain the major manufacturing methods of
Hansen, L. A., ''Restoration of McMicken nonwoven geotextiles.
Dam;' Third International Conference on 5. Define the following properties of geotextiles
Geotextiles, 1986, Vienna, Austria. and explain how they are measured:
• seam strength
2. REVIEW QUESTIONS • percent open area (POA)
• apparent opening size (AOS)
1. List the members of the geosynthetic family • permittivity
and describe each. What are the main dif- • transmissivity
ferences among them? • long-term drainage capability
2. What are the most common fibers and fabric 6. Summarize the geotextile functions. What
designs for geotextiles? Why are they suitable geotextile properties are the most important
for geotextiles? for each function?
3. Explain the pullout test for geotextiles. What 7. Explain the major steps when designing with
is the significance of this test? geotextiles.
10.0
MEDICAL TEXTILES
10.1
Medical Textiles
S. ADANUR
TABLE 10.1 Biomedical Application of Polymeric Materials (reprinted by permission of CRC Press {3]).
Therapy Repair or replacement of injured tissue Prosthesis of bone, joint, tooth, etc.; artificial heart valve;
patch grafting; artificial blood vessel; artificial shunt;
contact lens; intraocular lens; artificial skin
Assist or temporary substitution for Artificial heart and lung, ventricular assist system, artificial
physiological functions of a failed heart, artificial blood, artificial kidney, artificial liver,
organ artificial pancreas, apheresis therapy, biological response
modifier
Disposable articles in daily medical Tubing, catheters, syringe, suture, etc.
treatment
Drug formulation Novel drug delivery systems for Devices for controlled release of drugs, targeting design of
amelioration of pharmacokinetics drugs, pulsatile release devices
Diagnostic ex- New items in clinical laboratory tests Reagents and tools with quick response, high accuracy, and
amination high sensitivity; clinical test for new marker of disease;
cell labeling
Bioengineering New technology in tissue culture in Synthetic substrate or carrier particles for cell culture,
vitro additives for cell fusion, hybrid organ
Separation of blood components Plasma separation, cell separation, removal of virus and
bacteria
2.1 Characteristics of Materials for terials [8], and bulk and surface properties must
Medical Use be suitable for interfacial agreement with host
tissues and fluids [9, 10]. An analysis of struc-
The major requirements for biomedical poly- ture-property relationships of biomedical poly-
mers are non-toxicity (e.g., non-pyrogenicity, mers is provided in Reference [4].
non-allergenic response, non-carcinogenesis), Polyurethanes are widely used in biomedical
the ability to be sterilized (radiation, ethylene applications. Thermoplastic polyurethane elas-
oxide gas, dry heating, autoclave), mechanical tomers are suitable for hemodialysis sets, blood
properties (strength, elasticity, durability), and oxygenation tubing, blood bags, gas therapy
biocompatibility(bioinert, bioactive) [4,5].1fan tubing, heart assist devices, pacemaker lead in-
implanted material in the living body causes sulators, and connectors [11]. Biomer®, a seg-
temperature rise, chronic tissue inflammation, mented polyether polyurethane with long fatigue
allergic reaction, carcinoma or deformity, the life and high tensile strength, was used for blood
material is considered toxic. As biomedical contacting surfaces in artificial heart pumps and
materials may be contaminated with bacteria, left ventricular devices [12]. However, it has
sterilization is important for biomedical poly- recently been discontinued due to its propensity
mers. The sterilization techniques can be physi- to degrade in the body. Ultra-high molecular
cal (dry heat, steam, ionizing radiation) or chem- weight polyethylene is suitable for joint replace-
ical. However, sterility does not guarantee ment while porous high density polyethylene
absence from pyrogenic bacterial products. Non- permits tissue ingrowth. Low density poly-
toxicity is not enough for biocompatibility which ethylene is used for non-load-bearing applica-
includes bioinertness and bioadhesiveness. The tions. Polypropylene is suitable for steam
parameters for biocompatibility tests include sterilization due to a high melting point of
toxicity, thrombogenicity, hemolysis, terato- 170°C. Although polytetrafluoroethylene has
genicity, mutagenicity, carcinogenicity, infection poor load-bearing properties, its derivatives as
behavior and sensitivity [6]. Diffusion properties fiber, expanded, pore sponge, and composites
are critical in controlled drug delivery systems cause minimal tissue reaction [13]. Silicone rub-
and membranes in artificial kidneys [7], optical ber polymer has been used successfully for a
properties are important for contact lens rna- wide range of in vivo (internal) applications. It
10.1 Medical Textiles 331
has thermal and oxidative stability, good medical textiles. Collagen, which is a bio-
flexibility and elasticity, tissue and blood com- degradable material obtained from bovine skin,
patibility and is inert and relatively non-toxic. It is a protein that can be in either fiber or hydrogel
has been used successfully for tubing and shunts, (gelatin) form. Collagen fibers, which are used
mammary augmentation, capping nerve ends, as sutures, are as strong as silk. The hydrogel is
vascular applications, pacer lead insulators, in- formed by crosslinking collagen in 5- 10%
traocular lenses, catheters, plastic and recon- aqueous solution. Calcium alginate fibers, which
structive surgery, replacement of cartilage or are produced from Laminariae seaweed, are ef-
bone, bladders, sphincters, testicles and penile fective in wound healing. It is non-toxic and
struts. Polymethylmethacrylate (PMMA) has biodegradable. Chitin is a polysaccharide ob-
been used for dentures, repair of cranial defects, tained from insect skin, crab and lobster shells.
jaw contour correction, spinal fixation, penile Fibers and fabrics made of chitin are relatively
inserts, testicular implants, and as bone cement. non-thrombogenic, can be absorbed by the body
Polyurethane has been used for aortic patch and have good healing characteristics. Non-
grafts, arterial venous shunts, pacer lead in- woven chitin fabrics are used as artificial skin
sulators and percutaneous devices. Hydrophilic dressings. They adhere well to the body and
polymers (hydrogels) are used for temporary and stimulate new skin formation while promoting
permanent prostheses. Insoluble gel networks healing rate with less pain. Alkali treatment of
can be formed which offer softness and mechani- chitin yields chitosan which can be spun into
cal comfort. End uses include contact lenses, ftlaments and used for slow drug release
breast and other substitutes, bone ingrowth membranes. Research has been done on poly lac-
sponges, drug delivery devices and catheters. tics and polygalactics for sutures and possibly
Polyethylene terephthalate (PET) or polyester is other products.
widely used for fibrous prostheses. It is relatively
inert, flexible and resilient. PET can be sterilized 2.2 Biodegradability and
by all methods. Bioabsorbability
Use of composite or bicomponent materials
such as carbon fiber reinforced polylactic acid Biomedical fibers can also be classified ac-
polymer, hydrogel coatings on various poly- cording to biodegradability. Materials that are
mers, parylene coated polypropylene, metall- absorbed by the body two to three months (or
ized epoxy, sucrose or CMC and bone cements longer) after implantation are considered as
is increasing. biodegradable and include polyamide, some
Textile materials that are used in medical ap- polyurethanes, collagen and alginate. Although
plications include fibers, yarns (monofilament cotton and viscose rayon are biodegradable, they
and multi-ftlament), fabrics (woven, knit, non- are not used as implants. Materials such as
woven) and composites. Depending upon the polyester, polypropylene, polytetrafluoroethyl-
application, the major requirements of medical ene (PTFE) and carbon are not absorbed by the
textiles are absorbency, tenacity, flexibility, soft- body and are considered non-biodegradable.
ness and at times biostability or biodegradability. Biodegradable and bioabsorbable materials are
Medical textile materials can be natural or syn- generally called bioabsorbable materials. They
thetic, biodegradable or non-biodegradable. are decomposed in the body and their decomposi-
Cotton and silk are the most common natural tion products are metabolized and excreted from
materials for medical textiles. These, along with the body. They may also be used to temporarily
regenerated cellulosic fibers (viscose rayon), are replace human organs. Biomedical application of
used extensively in non-implantable materials bioabsorbable polymers are absorbable surgical
and healthcare/hygiene products. Man-made sutures, synthetic skin, adhesives and joints, DDS
materials used in medical textiles include poly- (Drug Delivery Systems) and biohybrid organs as
ester, polyamide, polypropylene, polytetra- shown in Thble 10.2.
fluoroethylene (PTFE), carbon and glass [14]. Bioabsorption of polymeric materials has two
There are several other specialty fibers used in stages: decomposition and absorbtion. During
332 MEDICAL TEXTILES
decomposition, main chain bonds break, mo- to minimize their side effects. Therefore, it is
lecular weight decreases and non-toxic mono- important to know the degradability properties of
meric and oligomeric compounds are produced. materials. Factors that affect degradability in-
Depending upon the polymer, decomposition clude chemical structure, crystallinity, hydro-
may or may not require an enzyme. Polymers de- philic/hydrophobic balance, shape and mor-
composed by the enzyme-specific reaction are phology.
called enzymatically degradable polymers and Enzymatically degradable materials include
those decomposed by non-specific hydrolysis or polypeptides, polysaccharides, polyesters, nu-
oxidation in contact with body fluids are called cleic acids and non-enzymatically degradable
non-enzymatically degradable polymers. By polymers are polyesters, poly(ester-ethers),
definition, only the enzymatically degradable poly(amide-esters). A comprehensive list of en-
polymers are called "biodegradable." In the ab- zymatically and non-enzymatically degradable
sorption stage, the decomposition products are biopolymers is given by Kimura [15].
rendered innocuous by bioprocesses and ex-
creted from the kidney and sudoriferous glands. 2.3 Blood Compatibility
In addition to degradability, the bioabsorbable
materials must satisfy other requirements such as Blood compatibility is necessary in biomedi-
biocompatibility, mechanical and chemical pro- cal materials, especially blood contacting de-
perties, and must also be non-toxic. The degrada- vices, such as artificial hearts and artificial
tion and absorption rate should be compatible vessels as well as blood purification devices and
with the healing rate of biotissues and organs. blood catheters. Blood compatibility implies that
The healing rate is different for various human a material should not cause thrombosis, which is
biotissues: it takes three to ten days for dermal the clotting of blood formed within a blood ves-
tissues, one to two months for internal organs and sel. In addition to thrombosis, materials used in
two to three months for hard tissues and at least long-term applications should not cause altera-
six months for regeneration of large organs. tion of the plasma proteins, destruction of the
Bioabsorbable implant materials should maintain enzymes, depletion of electrolytes, adverse im-
their mechanical properties and functions until mune responses, damage to adjacent tissue, can-
the biotissues are completely cured. After com- cer, toxic and allergic reactions, or destruction
plete healing of biotissues, the implanted ma- of the cellular elements of the blood such as the
terials should be degraded and absorbed quickly red blood cells, white blood cells, and platelets.
10.1 Medical Textiles 333
Although several materials have been used suc- ings of polyamides, polyimides, cellulose ace-
cessfully in conjunction with blood, at present, tate, silicone rubber, and segmented polyether-
there is no polymer that is truly blood com- urethane elastomers have been used for making
patible. composites of carbon. These composites make
The molecular designs of blood compatible carbon more flexible.
polymers are classified in four categories. These Micro fibers in composite form are often blood
are based on the approach for regulation of the compatible. They are able to anchor viable
blood materials interaction and are summarized fibroblastic and pseudo-endothelial cells, thus
in Table 10.3. producing a living surface. This surface is con-
Polyurethanes and polyurethane ureas are sidered blood compatible. Typical microfibers
used for the construction of intraaortic balloons include those made of polyesters, and parylene-
due to favorable reports on their blood com- coated polypropylenes. Other fibers include
patibility and good mechanical properties [ 17]. polytetrafluoroethylene (PTFE) which is used as
Because of their viscoelasticity, polyurethanes artificial arteries and arteriovenous shunts as
have been widely researched by device design- well as a tip material for shunts. Polyethylene is
ers. However, there have been reports of their often used as tubing to carry blood and for in-
lack of long-term stability and their use is very travascular catheters.
limited as permanent implants. Lycra® is a well-
known example of a segmented polyurethane
urea that was developed by DuPont for elastic 3. CLASSIFICATION OF
MEDICAL TEXTILES
fiber applications. It has good physical proper-
ties and good biological performance, but it is
Depending on the application areas, medical
difficult to dissolve, which makes it difficult to
textiles can be classified as follows:
be used in the fabrication of complex medical
devices. More soluble segmented polyurethanes ( 1) Surgical textiles
have been prepared based on methylene and • textiles for implantation (e.g., sutures,
either polypropylene glycol or polytetrameth- vascular grafts, fabrics for heart valves
ylene glycol [18]. and repair, artificial joints, fabrics for
Carbon fibers have good blood compatibility hernial repair, surgical reinforcement
and are appropriate for applications with rigid meshes, fibrous bone plates, etc.)
structures, but they are not suitable for structures • non-implantable textiles (e.g., bandages,
that are thin or that require being flexed. Coat- wound dressings, plasters, etc.)
TABLE 10.3 Blood Compatible Polymers (reprinted by permission of CRC Press [16]).
Synthetic polymer Hydrophobic surface Polytetrafluoroethylene (PTFE)
zero critical surface tension theory Polydimethylsiloxane
Polyethylene
Hydrophilic surface Poly(2-hydroxymethyl methacrylate)
zero interfacial free energy concept Poly(acrylamide)
Heterogenic surface Block-type copolymer
microdornain concept Graft-type copolymer
Molecular cilia mechanism Poly(ethylene glycol)
Negative charge surface Sulfonated polymer
Synthetic polymer + biologically Pseudomembrane formation Expanded PTFE
active polymer Poly(ethylene terephthalate)
Heparinization Heparin releasing polymer
Heparinized polymer
Immobilization of fibrinolysis enzyme
Synthetic polymer + biological Albumin adsorbed surface Polyurethane with alkyl group
molecules biomembrane-like surface formation
334 MEDICAL TEXTILES
(2) Textiles in extracorporeal devices (e.g., ar- (3) Fiber diameter, in general, smaller than the
tificial kidney, liver, lung, etc.) cells for their adherence. Although human
(3) Healthcare and hygiene products (e.g., bed- tissue is capable of encapsulating objects
ding, protective clothing, surgical gowns, much larger than fibers, it can better encap-
cloths, wipes, etc.) sulate the small circular fibers than large
irregular cross-sectional fibers.
(4) Biodegradability or biostability depending
4. TEXTILES FOR IMPLANT AT ION on the application.
(5) Non-toxicity, where fiber polymer or
Although the natural way to replace a defec- fabrication techniques must be non-toxic and
tive body part would be transplantation, this is fibers should be free of contaminants
not always possible due to several reasons in-
cluding availability, performance requirements The implantable material must meet mechani-
etc. Therefore, physicians often have to use an cal requirements for the particular application.
artificial substitute (biomaterials) such as biotex- Biocompatibility requires that the biotextile must
tiles. A foreign or synthetic material or part used interact with the host in a controlled and predict-
to replace a body part is referred to as a pros- able way. In addition to these conditions, the
thesis. Table 10.4 shows major implantable tex- biomaterial must not damage blood cells or cause
tile materials. formation of destructive blood clots. Therefore,
Although it depends on specific application, in it is essential that the structure-property-function
general, the biological requirements for a satis- relationships of implant materials and body or-
factory artificial implant may be stated as follows gans are well understood. For example, the
[1,19]: primary function of hard tissue such as bones and
teeth is load-carrying. On the other hand, col-
(1) A suitable artificial surface for the body cells lagen-rich tissues such as skin, tendon, and car-
to easily adhere to and grow on tilage act as load-bearing elements. Elastic
(2) Porosity, which determines the rate at which tissues, such as blood vessels, ligamentum
tissue will grow and encapsulate the implant; nuchae, and muscles exhibit a large deformation
Implant material should be sufficiently with small cyclic load. Applications of textiles as
porous. implants include abdominal wall, artery, bio-
Sutures
Biodegradable Collagen, polylactide, polyglycolide Monofilament, braided
Non-biodegradable Polyamide, polyester, TetlonGP, polypropylene, Monofilament, braided
polyethylene
Soft tissue implants
Artificial tendon TetlonGP, polyester, polyamide, polyethylene, Woven, braided
silk
Artificial ligament Polyester, carbon Braided
Artificial cartilage Low density polyethylene
Artificial skin Chitin Nonwoven
Eye contact lenses/ Polymethyl methacrylate, silicone, collagen
artificial cornea
Orthopaedic implants
Artificial joint/bones Silicone, polyacetal, polyethylene
Cardiovascular implants
Vascular grafts Polyester, TeflonGP Knitted, woven
Heart valves Polyester Woven, knitted
10.1 Medical Textiles 335
hybrid organs, bone, heart valve and wall, hip (ePTFE), polypropylene, polyester and silk.
joint, ligament, tendon, trachea and vein. They are generally used for closing cutaneous or
oral incisions where the suture can be easily
removed.
4.1 Sutures These absorbable sutures are used to stop inter-
nal bleeding, and are degraded by the body fluids
Sutures are mono- or multi-filament threads after the healing process. Non-absorbable suture
that are used to close wounds, join tissue and tie materials are unresorbed or considered to be un-
off bleeding vessels. In the thirties, silk and linen resorbed in the body for a long period of time.
were used as sutures until the development of Catgut, silk and linen are traditional suture
nylon. BASF then developed a "pseudo-mono- materials. Virgin silk is used for ophthalmic
filament,'' which was a combination monofila- sutures due to its thin size. However, its applica-
ment and multi-filament material. Following tion for other medical areas is limited. The sur-
polyester in the suture market in the late sixties gical suture of silk fibroin is not bioabsorbable.
was polyglycolic and polylactic acid, synthetic Linen and steel have been used in the past but
absorbable suture materials. Dexon® and Vi- have proven less appropriate due to tissue reac-
cry}®, resorbable materials, are presently used in tion and poor handling properties. Recently, ab-
a braided configuration. sorbable surgical suture has been developed
Suture materials can be classified as absorb- from chitin. Its tensile strength is better than that
able and non-absorbable sutures. Absorbable su- of the other absorbable sutures such as Dexon®
tures include collagen (catgut), polyglycolic and catgut. Figure 10.1 shows application of ex-
acid, polyglycolic acid-polylactic acid copoly- panded PTFE monofilament suture.
mer, polydioxanone and polyglycolic acid poly-
carbonate copolymer. Absorbable sutures are Manufacturing Processes
used internally. Non-absorbable sutures are
made of "expanded" polytetrafluoroethylene There are advantages and disadvantages to the
336 MEDICAL TEXTILES
various methods in which suture materials can be flexibility. The twisted suture consists of twisted
manufactured, whether it be a monofilament, a yarns in order to achieve a desired diameter and
braid, a pseudo-monofilament or a twisted strength. The rough surface causes high tissue
strand. It is up to the user to determine the type drag, but has good knotability and security. The
of material and the form that will be the most flexibility is about the same as the braid.
beneficial. Each process is discussed below. Selection of the appropriate suture material is
A monofilament with its smooth surface can likely the decision of the surgeon. The various
only be made from synthetic material by ex- properties have to be considered depending on
trusion. One property of the monofilament is a what the use will be. However, resorbable
minimal tissue drag with low tissue reaction. monofilaments have become popular suture
This is because of the smooth surface. It is also materials.
easy to make or place a knot in the depth of the
body. This advantage is especially critical in in- Test Methods
testine closure. Disadvantages of the monofila-
ment include low knot security and less flex- The tested properties of sutures include knot-
ibility. Typical monofilament materials used are pull tensile strength and diameter, bending stiff-
polyester, polyamide, polypropylene, and poly- ness, surface roughness, knot run-down, and
dioxanone. Polyester has a high knot-pull tensile knot security. Degradation time between thirty to
strength, good flexibility, and low degradation. sixty days is desirable. To measure suture prop-
Polypropylene has excellent tissue drag and erties, exact standardized testing methods and
stability. Polyamides have a similar chemical devices should be developed with the aims of
structure to that of collagen and degrade within specifying needed properties to help the surgeon
the body over a period of time depending on the to choose the right suture for a specific purpose
mass of the implant and the site within the body to minimize operation and healing risk.
it is used. Polydioxanone and polyglycolic acid- The knot-pull tensile test is based on the sur-
polycarbonate copolymer are monofilaments geon's knot and the shape of the clamps that fix
with long resorption time. The tensile strength is the suture at jaws. The methods of measuring
low and the material can be found in the body for diameter are not always accurate, so exception-
about 180 days. ally strong sutures are often used to be safe in
Various yarns of different multi-filament fi- regard to yarn strength. Bending stiffness deter-
bers can be braided together to form a suture mines how easily a suture is handled. A slack
material. There are anywhere from eight to six- suture is easier to knot and is more secure. A
teen yarns in a braided material for this purpose. stiffness tester presses a yarn loop onto measur-
Obviously, due to the manufacturing method, the ing bolts of a precision scale by the circling
braid is rougher on the surface, which causes movement of the clamp that fixes the suture ends.
tissue drag to be high. A lubricant can coat the This determines bending stiffness.
braided suture material to lower the tissue drag A rough suture can cause damage to biological
and allow better knotability. Braids are also tissue and can damage a surgeon's operating
flexible and easy to handle, which are also gloves. However, a rough surface allows for
beneficial properties of sutures. Polyesters, better knot stability and security due to the fric-
polyamides, and silks are commonly used for tion between the surfaces. The Hommel rough-
braids. The synthetic resorbable materials, poly- ness tester has a light-weighted, rounded mea-
glycolic acid and the poly glycolic acid-polylactic suring tip that runs along the moving thread, the
copolymer are resorbed in the body within yarn causes an up and down motion of the tip
twenty to twenty-eight days [20]. which is recorded on-line with a plotter.
The pseudo-monofilament has a core of Knot run-down, knot security and knot snug-
several twisted materials coated with an ex- ging -down are important parameters that depend
trusion of the same material as the core. Because on suture stiffness, surface roughness, and coat-
of its low coefficient of friction, it has low tissue ing material. Knot security means whether the
drag, good knotability, low knot security, and fair knot stays under steady tension in its determined
10.1 Medical Textiles 337
place. When a slack or smooth suture is used licity and hydrophobicity, roughness of surface,
there is less force to form the knot, and the microheterogeneity and material flexibility.
tension on the biological tissue is small. Table There is an inverse relationship between the per-
10.5 shows knot-pull tensile strength of some centage of initial cell attachment and the relative
sutures. rate of cell growth. As the affmity of the cell to
the material increases, the cell growth decreases.
Bacteria on the Degradation of It was reported that cell attachment and growth
Absorbable Sutures are promoted on the positively charged substrate
and are restrained on the negatively charged sub-
Bacteria in surgical wounds can cause difficul- strate [22,23]. Hydrophilic material surfaces
ties in the healing process. Complications can be promote cell attachment. As the surface rough-
especially critical with absorbable sutures that ness increases, cell attachment increases, but cell
degrade by bacteria or bacterial enzymes. growth decreases. For the cell attachment and
Testing was performed by Elser et al. on growth on the material surface, a hard footing in
Dexon® and Maxon® suture material for bac- molecular order is needed for the cells to anchor
terial effects [21]. Dexon® is a coated and non- to the surface.
stained braided, absorbable multi-filament made Soft tissue compatible biological polymers are
from polyglycolic acid. Maxon® is an absorbable collagen, silk protein, cellulose, chitin and
monofilament made from polyglycolate. The in- chitosan. Collagen, which is a main component
cubation liquid for the test was a bacterial of soft tissue in the human organism, is a protein
suspension based on nutrient broth inoculated which forms connective tissue in vivo. There-
with Staphylococcus aureus ATCC 6538P fore, artificial implants with collagen modified
(1 06/ml). The results were that both Dexon® and surfaces easily adhere to soft tissue. Collagen is
Maxon® degradation was accelerated signifi- also used to make artificial skin dressing which
cantly due to the presence of the bacteria. With has a similar constitution to the living skin and is
Dexon®, 50% degradation occurred within 10 regarded as a living skin-equivalent hybrid skin
days in sterile broth and within 8 days in the [24]. Silk protein is madeoftwotypes of protein,
presence of bacteria. Maxon®' s degradation was silk fibroin and silk sericin. Important charac-
50% within 24 days in sterile broth and 22 days teristics of cellulose include chemical stability,
in the presence of bacteria. hydrophilicity, good mechanical properties and
chemical functionality.
4.2 Soft Tissue Implants Soft tissue compatible artificial materials in-
clude silicone rubber, polyurethane, hydrogels
Biomedical materials are used in applications and carbon fiber. Silicone rubber is a cross-
such as soft tissue compatible artificial pros- linked polymer of poly(dimethyl siloxane).lthas
theses, artificial skin patches, artificial tendon, been used in artificial breasts, ears and noses
and artificial corneas. Important properties that [25]. Hydrogels are insoluble water-containing
affect cell attachment and tissue growth are materials. They are made by introduction of
chemical structure, electric charge, hydrophi- either crosslinks, hydrophobic groups, or crys-
TABLE 10.5 Knot-Pull Tensile Strength of Various Sutures (courtesy of W. L. Gore and Assoc.).
Knot-Pull Tensile Strength (kg)
FIGURE 10.4 Cross-sectional view of Gore-Tex"' soft tissue patch and its use in vetral hernia repair (courtesy ol W. l.
Gore and Assoc.).
340 MEDICAL TEXTILES
TABLE 10.7 Mechanical Properties of Hard Tissue Materials (with permission from CRC Press [27]).
Tensile Tensile Compressive Bending
Strength (MPa) Modulus (GPa) Strength (MPa) Strength (MPa)
Teflon® is used around the implant to promote widely used fibers are polyester and expanded
tissue growth. PTFE. Polyester vascular grafts can be woven,
knit or extruded. Expanded polytetrafluoro-
4.4 Vascular Implants ethy lene grafts are rendered porous by expand-
ing sintered particles of Teflon®. Straight or
Artificial veins or arteries are used to replace bifurcated grafts are produced with warp knitting
segments of the natural cardiovascular system or weaving. The structure in warp knit grafts is
that are blocked or weakened. A typical example reverse lock knit and full tricot. Tubular woven
is to replace a section of the aorta where an grafts are made on narrow label looms. Mostly
aneurism has occurred. Another example is the plain weave is used with yams between 50-150
arteries in the legs of diabetic patients that have denier. In some woven vascular grafts, a leno
a tendency to be blocked. Grafts are inserted to weave is used for every few ends to minimize
bypass the blockages and restore circulation. unravelling and fraying. Heat setting creates a
Grafts usually have a tube shape. The most crimped structure and improves the handling
characteristics of polyester vascular grafts.
High density polyethylene
The most important property of a graft is its
porosity. Woven graft structures are typically less
porous than knitted structures which diminishes
blood leakage through the interstices but at the
same time can hinder the tissue growth. Knitted
Artificial Bone
vascular grafts are more porous which allows
Charnley type tissue growth but leakage may be a concern.
Stainless steel Typical water permeabilities of woven grafts are
cr-co-Mo alloy
Tlalloy 50-500 cc/cm2/min and of knitted grafts are
1,000-2,000 cc/cm2/min [28]. In order to fill
the interstices of the graft and prevent leakage,
knitted and woven grafts with internal and/or
external velour surfaces have been developed
(Figures 10.6 and 10. 7). Most knitted and woven
grafts are preclotted prior to transplantation.
Blood is intentionally soaked into the textile wall
FIGURE 10.5 Replacement of artificial bone with bone allowing clot formation to occur. The proclotting
cement (reprinted by permission of CRC Press (27]). steps reduce or eliminate blood loss through the
10.1 Medical Textiles 341
FIGURE 10.6 Outer surface of plain weave, double velour graft (courtesy of Meadox Medical, Inc.).
textile wall once the graft is implanted. Pre- Figure 10.9 shows various expanded PTFE
sealed prostheses (also called composite grafts) grafts. In addition to porosity, good handling and
are impregnated with collagen (e.g., Hema- suturing characteristics, satisfactory healing
shield® grafts and fabrics from Meadox Medical) (rapid tissue growth), mechanical and chemical
or gelatin first to seal pores (Figure 10.8). Ap- stability (good tensile strength and resistance to
proximately two weeks (gelatin) to three months deterioration) are the major requirements of vas-
(collagen) after implantation, the seal degrades cular grafts. Since vascular grafts are subjected
allowing tissue ingrowth. Polyester fabrics are to static pressure and repeated stress of pulsation
used as suture cuffs on artificial heart valves to in application, they should have good dilation
allow suturing the valve to the surrounding tis- and creep resistance. Application examples of
sue. The fabric also helps secure the valve with vascular grafts are shown in Figure 10.10.
the tissue growth. Crimp in grafts is for handling and length
FIGURE 10.7 Inner surface of full tricot knit, double velour (courtesy of Meadox Medical, Inc.).
FIGURE 10.8 Inner surface of full tricot knit. double velour, collagen impreg·
nated graft (courtesy of Meadox Medical, Inc.).
342
10.1 Medical Textiles 343
sizing. Crimped geometry improves the graft's crimped structure, all the grafts showed high
bending ability without kinking. Crimp is longitudinal distensibility, knit grafts being the
removed at implantation by the surgeon. The highest. Composite graft structures, which are
elasticity of the graft depends on the elastic obtained by impregnation with biodegradable
modulus of the material, its thickness and radius. compounds, resulted in stiffer structures with
To determine the circumferential deformation less elasticity. Externally supported grafts ex-
under internal pressure (dilatability), a para- hibited good dimensional stability.
meter called'' compliance'' is used. Compliance Figure 10.11 shows a different type of vas-
is the percent change in the external diameter per cular graft structure before and after implanta-
unit change in pressure assuming a constant ves- tion. The wall of the graft is composed of
sel length and neglecting wall thickness varia- 1,400-1,600 layers of 8-12 micron diameter
tion. It was reported that knit grafts showed more fibers.
compliance than woven grafts, and warp knit Vascular grafts have been successfully im-
graft dilated less than the weft knit graft as inter- planted in individuals during the last thirty years
nal pressure was increased [29]. Due to their [30]. The manufacturers of vascular grafts in the
344 MEDICAL TEXTILES
Wound dressings are used for many purposes FIGURE 10.12 Wound dressing (courtesy of Johnson
including protection against infection, absorp- & Johnson).
tion and exudation of blood and excess fluids,
healing and application of medication (Figure
10.12). Ideally, surgical dressings should be soft, which is hydrophilic, permeable to oxygen, im-
pliable, pad the wound to protect from further permeable to bacteria, and helps with the forma-
injury, be easily applied and removed, be sterile, tion of new tissue [29].
lint-free and non-toxic. Wound care products are Gauze and paraffin-coated gauze are the most
usually made of three layers: wound contact common dressings used. Most gauze is made
layer, absorbent layer and base material. Wound from cotton in the form of a loose plain weave.
dressing should not adhere to the wound allowing The typical yarn densities per inch are 12- 19 for
easy removal without disturbing new tissue warp and 8-15 for filling (Figure 10.13). 44's
growth. The middle layer absorbs blood or liq- cotton count of warp yarns and 54's weft carded
uids while providing a cushioning effect to yams are common sizes for gauze manufactur-
protect the wound. The base material is coated ing. Gauze is used mostly as a dressing for direct
with an acrylic adhesive to hold the dressing in wounds, but it is also used in internal pads and
place. The tightly woven cloths provide a general swabbing applications.
smoother dressing pad and probably absorb more Perhaps the most difficult property to achieve
quickly, but looser structure will give more bulk is dressing removal because when a gauze is
for greater protection. placed in contact to the wound the exudate, the
The collagen, alginate and chitin fibers are discharge from a wound, adheres to the fibers of
proven to be effective in healing of wounds. The the dressing. Bums and skin graft sites must have
interaction between the alginate fibers and exud- their dressings changed frequently. When the
ing liquids creates a sodium calcium alginate gel dressing is removed, it is not only painful, but it
~:mndcare
Absorbent pad Cotton, viscose Nonwoven
Wound contact layer Silk, polyamide, viscose, polyethylene Knit, woven, nonwoven
Base material Viscose, plastic film Nonwoven, woven
Bandages
Simple inelastic/elastic Cotton, viscose, polyamide, elastomeric yarns Woven, knit, nonwoven
Light support Cotton, viscose, elastomeric yarns Woven, knit, nonwoven
Compression Cotton, polyamide, elastomeric yarns Woven, knit
Orthopaedic Cotton, viscose, polyester, polypropylene, polyurethane Woven, nonwoven
foam
Plasters Viscose, plastic film, cotton, polyester, glass, polypropylene Knit, woven, nonwoven
Gauzes Cotton, viscose Woven, nonwoven
Lint Cotton Woven
Wadding Viscose, cotton linters, wood pulp Nonwoven
346 MEDICAL TEXTILES
compression they provide, compression ban- hemodialysis (dialysis, membrane pore size 1-8
dages are classified as light, moderate, high and nm), hemofiltration (ftltration, membrane pore
extra-high compression bandages. They can be size 3-60 nm), plasma exchange (ftltration,
woven, warp or weft knitted with cotton and porous membrane pore size 0.2-0.6 microm-
elastomeric yarns. eter) and hemoadsorption. Hemodialysis ac-
Nonwoven orthopaedic cushion bandages are counts for more than 90% of the blood
used under plaster casts and compression purification treatment in the world which
bandages for padding and comfort. They are corresponds to 30 million treatments per year
made of polyester or polypropylene, with blends keeping 300,000 patients alive. Hemodialysis in-
of natural and other synthetic fibers. Poly- cludes removal of metabolic substances, adjust-
urethane foam may also be used. Light needle- ment of electrolytes and pH and removal of
punching gives bulk and loft to the structure for excess water by ultrafiltration and dialysis.
greater cushion effect. During the process, blood contacts with dialysate
through a membrane (Figure 10.14).
The materials used in dialysis membranes are
6. TEXTILES FOR EXTRACORPOREAL regenerated cellulose, cellulose triacetate, acryl-
(BIOMEDICAL) DEVICES onitrile copolymer, poly(methyl methacrylate),
ethylene-vinyl alcohol copolymer, polysulfone
Textile materials are used in mechanical or- and polyamide which can be grouped as cellulose
gans such as artificial kidney (hemodialysis and synthetic polymer systems. Eighty percent
units), artificial liver and mechanical lung (blood of the dialyzers use cellulose materials which
oxygenator) for blood purification (Table 10.9). have excellent permeability for low molecular
In the artificial kidney, blood is circulated substances. Pore sizes of membranes vary be-
through a membrane that retains unwanted waste tween 1-3 nm for conventional membranes and
material. The membrane may be a flat sheet or a 4-8 nm for large pore membranes. Today, high
bundle of hollow regenerated cellulose fibers in efficient hollow fibers have replaced coil or
the form of cellophane. Multi-layer fabrics, laminate in dialyzer devices. The cross section
made of several layers of needlepunched fabrics of a hollow fiber-type dialyzer is shown in Figure
with different densities are also used in artificial 10.15, which consists of4,000 to 20,000 hollow
kidneys. ftlaments having an external diameter of 200 to
Blood purification is an effective therapy for 300 micrometers. Blood flows inside of the
incurables such as end-stage renal failure. It is fibers and the dialysate flows outside of the
used to correct the abnormality of blood quality fibers. Almost the same materials are used for
and quantity in treating sickness. Principles of hemofiltration.
blood purification therapies are dialysis, filtra- Mechanical lungs use microporous mem-
tion and adsorption. Separation membranes and branes that provide high permeability for gas
adsorbents are used in blood purification flow and low permeability for liquid flow which
devices. The membrane separation depends on is similar to the natural lung where oxygen and
membrane pore size. Purification methods are blood come into contact. In these devices,
Artificial kidney Hollow viscose Remove waste products from patient's blood
Hollow polyester
Artificial liver Hollow viscose Separate and dispose patient's plasma, and supply fresh plasma
Mechanical lung Hollow polypropylene Remove carbon dioxide from patient's blood and supply fresh
Hollow silicone oxygen
Silicone membrane
348 MEDICAL TEXTILES
Surgical clothing
Gowns Cotton, polyester, polypropylene Nonwoven, woven
Caps Viscose Nonwoven
Masks Viscose, polyester, glass Nonwoven
Surgical covers
Drapes Polyester, polyethylene Nonwoven, woven
Cloths Polyester, polyethylene Nonwoven, woven
Bedding
Blankets Cotton, polyester Woven, knitted
Sheets Cotton Woven
Pilowcases Cotton Woven
Clothing
Uniforms Cotton, polyester Woven
Protective clothing Polyester, polypropylene Nowoven
Incontinence diaper/stock
Coverstock Polyester, polypropylene Nonwoven
Absorbent layer Wood fluff, superabsorbents Nonwoven
Outer layer Polyethylene Nonwoven
Cloths/wipes Viscose Nonwoven
Surgical hosiery Polyamide, polyester, elastomeric yarns, cotton Knit
According to this definition, there are two Protective Clothing Materials to Synthetic
basic requirements for a protective textile gar- Blood- In this test method synthetic blood
ment: it should prevent infectious materials from with a surface tension of 40 dynes/em (which
passing through the skin and it should last long is the surface tension of human blood) is
enough. used. The fabric specimen is wetted with the
Recently, two hydrostatic test methods have synthetic blood for five minutes; then it is
been adopted by the ASTM as emergency stan- kept in a pressurized cell at two psi for one
dards: minute. With no pressure, the penetration of
blood to the downstream side is visually ob-
(1) ES-21-1992 Test Method for Resistance of served for the next fifty-four minutes.
FIGURE 10.16 Various textile products to protect healthcare professionals (courtesy of Fiberweb North America,
Inc.).
350 MEDICAL TEXTILES
(2) ES-22-1992 Test Method for Resistance of of moisture vapor. Two types of materials are
Protective Clothing Materials to Penetration used to satisfy these contradicting demands [38]:
by Blood-Borne Pathogens Using Viral Pen-
etration as a Test System. (1) Monolithic membranes- They are made of
polyurethane, polyether/polyester or other
National Fire Protection Association (NFPA) copolymers. They have solid layer(s) to pro-
issued a standard in August 1992 addressing vide protection. These ftlm membranes con-
biological protection: NFPA 1999 Standard on tain polymers that are made of "hard" and
Protective Clothing for Emergency Medical ''soft'' segments in the molecular chain. Due
Operations. to structural differences between these seg-
Protective apparel in the medical field should ments, there is a thermodynamic intolerance
be affordable, breathable, comfortable, de- between them that causes a separation at their
pendable, and effective. According to OSHA, interfaces. Semipermeability takes place at
''Fluid-resistant clothing shall be worn if there is these points of microseparation. The
a potential for splashing or spraying of blood or phenomenon is driven by the difference in
other potentially infectious materials" and relative humidity between the surface of the
"Fluid-proof clothing shall be worn if there is a skin and the air.
potential for clothing becoming soaked with (2) Microporous membranes- Microporous
blood or other potentially infectious materials" membranes provide comfort by allowing
[36,37]. body perspiration to be transmitted from the
The impact of AIDS (Acquired Immune skin surface to the air through a fabric. When
Deficiency Syndrome) and other contagious dis- humidity on the surface of the skin is greater
eases have made hospitals very cautious about than the atmosphere, moisture can pass
protective fabrics. The medical profession was through the pores of a microporous mem-
once concerned mainly with protecting patients brane by gaseous diffusion and convection.
from germs, now they must protect themselves. The dimensions of the pore are about
These precautions have caused an increase in 0.1-0.2 micron which excludes liquid
demand for medical products ranging from water compared to water vapor which has
gloves and face masks to complete gowns. been estimated to be 0.0004 micron.
Manufacturers are also responding to higher
demands of protection by producing products Equipment used in an operating room is usu-
with increased barrier levels. Industry is also ally Class I Medical Device. Therefore, in order
having to consider the environmentally con- to show commitment to standards and quality,
scious population when deciding between recy- some textile companies that produce medical
cling potentially contaminated products or dis- textiles register as Medical Device Manufac-
posing of the products in landfills. turers [39].
In the United States, fabric based products Needlesticks and sharp objects are the main
used by medical personnel in patient care are causes for infection of medical professionals by
considered medical devices. Therefore, their HIV. Current focus is on development of protec-
manufacture and sale is regulated by the Federal tive materials that will prevent penetration of
Drug Administration (FDA). Some of the test needles and sharp objects. Proper sealing of
methods to determine antimicrobial properties of seam areas is critical.
medical textiles are as follows: Healthcare garments can be woven, knit or
• fungal tests: ASTM 6-21 and AATCC 30 nonwoven. Vinyl garments are also used.
Parts III and N Healthcare garments could be washable (and
• bacterial test methods: AATCC 147, therefore recyclable) or disposable.
AATCC 100 Woven cotton fabrics are traditionally used in
some surgical gowns because cotton does not
The protective material has to be waterproof produce static electrical charges that can build up
but breathable, i.e., it must allow transmission and produce electric sparks. However, it may
10.1 Medical Textiles 351
release particles from the surgeon and also sources of contamination and are composed of
generate high levels of dust (lint) which is the nonwoven fabrics and polyethylene films. Non-
source of contamination. Bar-Bae® Plus is a wovens are known for their disposability, but
patented, piled, 50150 polyester/combed cotton their performance has proven to be better for
blended and tightly woven into fabric. It has a protecting medical professionals from infectious
durable, moisture resistant and static control liquids. One way the nonwovens industry is
finish. It breathes and has proven to be comfort- marketing itself is by using the term'' single use''
able to wear. Other properties include abrasion instead of'' disposable'' products. Money is the
resistance, good tensile strength, fast drying, and largest problem because many hospitals have
reusability. ASEPR Surgical and Precautionary much capital invested in laundry facilities, which
Apparel is made up of high construction con- does not allow for disposables.
tinuous filament polyester fabrics. This product Surgical drapes are used in the operating room
has been very successful where high bacteria to cover patients and cover cloths are used to
filtration is required. It is also moisture resistant, cover the area around the patient. The choice of
lightweight, comfortable, and reusable. material is nonwovens which are used as backing
Gore-Tex® is a two layer laminated fabric material on one or both sides of a film. While the
produced by W. L. Gore & Associates as a barrier film is impermeable to bacteria, nonwoven back-
material. It is reported that it keeps water and ing is highly absorbent to both body perspiration
bacteria-proof properties even after fifty laundry and secretions from the wound. Hydrophobic fin-
autoclave cycles. Other properties reported include ishes may also be used as a bacteria barrier. Back
good moisture, vapor transmission, light weight to back laminated loop-raised warp knitted poly-
and softness. Gore-Lite® is a coating material ester fabrics, containing a microporous PTFE
similar to Gore-Tex film. It is used in nonwovens film in the middle, provide permeability and
for medical and surgical purposes. This coating comfort as well as resistance to microbiological
makes the fabric breathable yet liquid-proof. The contaminants.
coating has been used on spun laced, wood Surgical masks are made of three layers: a
pulp/polyester with various reinforcements, woven middle layer of extra fine glass fibers or synthetic
polyester fabric, and Gore-Thx barrier fabric. microfibers covered on both sides by acrylic
A high performance aery lie fiber, Courtek M, bonded parallel-laid or wet-laid nonwoven. The
can prevent the buildup of bacteria in cloth and performance requirements for surgical face-
medical equipment. Developed by Courtaulds, masks are high bacterial filtration capacity, high
the fiber contains a combination of antimicrobial air permeability, lightweight and non-allergenic.
compounds, based on metallic salts. The com- Nonwoven disposable surgical caps are made of
pounds are bound into the fiber matrix [40]. This cellulosic fibers with the parallel-laid or spun-
makes them more effective because they are not laid process. Hydroentanglement is gaining pop-
harmed by wear or washing. An aseptic chlo- ularity in producing operating room disposable
rofiber developed by Rhovyl is designed to fight products and garments.
against the proliferation of microorganisms The general requirements for surgical drapes
where hygiene is a concern. It contains the Mer- and gowns include liquid repellency and bac-
curobutol compound, an antiseptic well known terial barrier properties, aesthetics (including
in the medical world. This compound is trapped conformability, tactile softness, comfort),
within the basic polymer molecule during the strength, fiber tie-down properties (lint propen-
manufacturing process. It is able to remain unaf- sity and abrasion resistance), flame resistance,
fected through repeated washings. Tests on static safety and toxicity. For surgical drapes,
various bacteria revealed a rate of reduction stiffness is very critical because barrier perfor-
greater than 90% in the development of bacteria mance may be affected by conformability to
on aseptic chlorofiber compared to traditional patient or equipment. For gowns, comfort and
chlorofiber. This fiber is also anallergenic and stiffness may affect perspiration and movement.
non-toxic, as well as comfortable. Strength requirements include tensile, tear, burst
Nonwoven surgical gowns are used to prevent and puncture resistance. Linting is not wanted
352 MEDICAL TEXTILES
because particles from gown or drape may com- 7.2 Other Medical Textiles
plicate the wound healing process. Good abrasion
resistance is a necessity for the safety of barrier Other textile products used in hospitals in-
materials. Flame resistance is needed especially clude bedding, clothing, shoe covers, mattress
for laser applications and oxygen administration. covers, incontinence products, cloths and wipes.
The Consumer Product Safety Commission Cotton leno woven blankets have replaced tradi-
(CPSC) requires 3.5 seconds bum time on CS- tional woollen blankets in order to reduce the risk
191-53 for gowns, head coverings and surgical of cross-infection. Nurse's apparel is made of
drapes. For static discharge propensity, the Na- conventional fabrics since no specific require-
tional Fire Protection Association requires non- ment is needed other than comfort and durability.
cellulosic fabrics to be incapable of discharging a In isolation wards and intense care units, com-
spark with sufficient energy to ignite flammable posite fabrics are used for protective clothing.
anesthetic gases. Test methods to measure surface These fabrics consist of tissue reinforced with a
resistivity or static discharge are used. Non-toxicity polyester or polypropylene spun-laid web.
is needed to prevent skin irritation; allergic reac- Incontinence textile products can be either
tion; tissue or cell damage; and carcinogenic, diapers or bedding sheets (Figure 10.17). The
mutagenic or tetragenic reactions [41]. disposable diapers have three layers: inner
Nonwoven medical textile products are covering layer (coverstock), an absorbent layer
manufactured using various processes including and an outer layer. The inner covering layer
wet and dry forming, spunbonding, spun lacing consists of a hydrophilic finish treated polyester
and melt blowing. web or a spun-laid polypropylene nonwoven.
Laboratory tests for healthcare garments in- Tissue paper or nonwoven bonded fabrics are
clude water repellency, launderability (if recy- used in cloths and wipes which usually have an
clable), burst strength and tear strength. The antiseptic finish. Cloths and wipes are used to
guidelines for operating room materials have clean wounds prior to wound dressing or to treat
been defined by several institutions including the rashes and bums. Surgical hosiery materials pos-
Centers for Disease Control (CDC), Association sess compression characteristics and are used for
of Operating Room Nurses (AORN), and the various applications including support to the
American College of Surgeons' Committee on limb, treatment of venous disorders, protection
Operating Room Environment [42,43]. in physical activities, etc.
10.2
References and Review Questions
Standards for Draping and Gowning Ma- 4. Why is blood compatibility important for
terials;' in AORN Standards of Practice, medical textiles?
1982. 5. What are the major requirements of textiles
43. ''American College of Surgeons Committee for implantation? Explain.
on Control of Surgical Infections;' Manual 6. What is an extracorporeal device? How are
on Control ofInfection in Surgical Patients, textiles used in these devices?
J. B. Lippincott Co., 1976. 7. What properties are important for sutures?
What kinds of test methods are used for
sutures?
8. What are the differences between artificial
2. REVIEW QUESTIONS tendons and ligaments?
9. What types of mechanical properties are im-
1. Why are textile materials, in general, suit- portant for hard tissue implants? Why?
able for medical applications? 10. What types of fabric structures are used for
2. Define biocompatibility. What are the re- vascular implants? Explain their properties.
quirements for biocompatibility? 11. What is the structure of fibers used in ex-
3. What are biodegradability and bioabsorb- tracorporeal devices?
ability? Explain the major characteristics of 12. Explain how monolithic and microporous
these types of materials. membranes work.
11.0
MILITARY AND DEFENSE TEXTILES
11.1
Military and Defense Textiles
S. ADANUR
360
11.1 Military and Defense Textiles 361
TABLE 11.2 Integrated Protection Offered by the New, Improved Battle-Dress Uniform Fabrics [5].
Nomex®, Kevlar®, Cotton, Kevlar®,
Fabric Characteristics Nylon, Cotton P-140 Nylon, P-140
Flame resistance N y y
Liquid chemical agent resistance y N y
Electrostatic resistance N y y
Day/night camouflage y y y
Durability y y Y+
Weight (oz/yd2) 7.0 5.5 6.5
Cost ($/linear yd) 4.00 20.00 11.00 (estimate)
Y: yes, N: no.
11.1 Military and Defense Textiles 363
Cl
12
Aramid
structure causes creep and stress relaxation to be ultra-high molecular weight polyethylene, is
low [18]. produced using a gel-spinning process. Parallel
Spectra® fibers are produced using a patented orientation of the molecules and high crystal-
gel-spinning process. Spectra® has very high ten- linity give the fiber ultra-high strength.
sile strength and good chemical resistance. Dyneema® SK60 is used for general applications
Spectra® 1000 has higher strength and modulus and Dyneema® SK66 is used in fabrics for ballis-
than Spectra® 900. Spectra® Shield is a com- tic applications. In UD66, which is a relatively
posite armor structure made of nonwoven ballis- new construction, the yarns are laid unidirection-
tic armor material in which two layers of ally, cross-plied and impregnated with a matrix.
unidirectional fibers are impregnated and bound Tekmilon® is a high modulus, high strength, high
together with a polymeric resin in perpendicular molecular weight polyethylene fiber with low
directions. Multiple layers of Spectra® Shield weight, and good water, abrasion and chemical
can be pressed together to the desired thickness resistance. Its properties are similar to Spectra®
and weight for different ballistic requirements. It and Dyneema® [18].
can be made flexible, thin and lightweight. Vectran® from Hoechst Celanese is a ther-
Spectra® Shield provides good protection against moplastic monofilament made of liquid crystal
high-velocity rounds, multiple hits and shots polymer. Its properties include high strength and
fired at an angle. Vests made of flexible com- rigidity, low moisture absorption, negative coef-
posites are being used more and more because ficient of thermal expansion and good chemical
they offer many advantages over woven fabrics. resistance. It is reported to be five times stronger
Flexible composite body armor weighs around 3 than steel and ten times stronger than aluminum
to 4lbs compared to 5 to 6lbs of traditional ny Ion [18].
vests. Their ballistic performance is also better. The use of hybrid structures is increasing in
In addition to intercepting the projectile, com- ballistic protection systems (Figure 11. 8).
posite armors may also minimize blunt trauma Aramid fabrics blended with ultra-high
which is the punching effect on the body caused molecular weight polyethylene unidirectional
by the arrested projectile. A ballistic vest also cross-plied nonwoven material which is impreg-
provides a measure of protection against vehicle nated with matrix offers the flexibility and com-
accidents and other impact injuries. fort of fabric and the high performance of
Dyneema® fiber from DSM, which is made of composite nonwoven material.
FIGURE 11.8 Ballistic panel configurations; all Kevlar® 129, all Spectra® Shield and hybrid (Spectra
Shield and Kevlar) package (courtesy of IF AI).
366 MILITARY AND DEFENSE TEXTILES
*Available scoured (Class I) or scoured and treated for water repellency (Class 2) for use in fragment· or bullet-resistant vests.
**Available scoured (Class I) for use in helmets or scoured and treated for water repellency (Class 2) or use in fragment-resistant vests.
tAvailable with adhesion modified treatment (Class 3) for use in helmets.
11.1 Military and Defense Textiles 367
Ballistic Helmets
FIGURE 11.12 The old M-1 steel helmet (left) compared with the U.S. current
Personnel Armor System for Ground Troops (PASGT) Kevlar® helmet (right). Both
helmets are the same weight, but the PASGT helmet provides substantially in-
creased protection (courtesy of U.S. Army Natick Research, Development and
Engineering Center).
(projectile or bullet type, caliber, impact shirt in civilian life, but the reverse is true for the
velocity), final weight of the uniform, wearer majority of the military [19].
comfort and ease of movement. Each fiber and It is important to note that an armor which is
fabric type has unique ballistic properties. effective against a projectile at a certain impact
Depending on the specific threat to be addressed, speed may not be effective against the same
composite ballistic material can improve the per- projectile if the impact speed is increased. The
formance of the protective system. Coated bal- National Institute of Justice (NIJ) Standard-
listic fabrics may also be used. Some man- 0101.03, which was issued by the National
ufacturers use a non-ballistic layer to increase Bureau of Standards' Law Enforcement Stan-
blunt-trauma protection. There are different dards Laboratory in 1987, identifies six formal
ways of assembling ballistic panels into a single armor classification types and a special armor
unit such as bias stitching around the edge of the type: Type I, IIA, II, IliA, III, IV and Special
panel, tack-stitching at several locations, biaxial Type Armor. Each armor type provides either
stitching, or quilting the entire panel. Ballistic multiple-hit or single-hit ballistic protection
protective clothing is generally worn beneath the against a specified bullet at a specified velocity.
700
35
600
400
25
300
200 20
Steel Current Reduced Weight Future
1941 1978 1992 1998
-Ballistic Limit [ft"tt!l Weight
(m/sec) (oz/112)
10 MIL,.,.
Vlaor
Cooling Sv-tem
Ice Pouch
Glovoa ---11.
Inner.
Outer.
a.....-
M.,orial:
Challonvo '"5100
thermal radiation and flame resistance. Non- higher yam strength and ease of decontamina-
melting, non-flammable textiles with good resis- tion. Nuclear protective clothing are decontam-
tance to intense thermal spikes even for short inated at special protective clothing laundries.
periods of time are used for this purpose [23]. Recently, new and better nuclear protective
It is well known that for a material exposed to fabrics have been developed including ny-
radiation of a particular wavelength, the total of lon/polyester and nylon/carbon blends. Fabric
the relative proportional values of absorption, construction of 99/1 nylon/carbon fabric offers
transmittance and reflectance is one. To protect improved barrier properties, reduced heat stress,
against high-intensity thermal radiation, absorp- reduced linting, better contamination resistance
tion and transmittance should be low and reflec- and easier decontamination [24].
tance should be high. Fabrics would be ideal for
this purpose, but they might create a problem for 2.4 Environmental Protection
camouflage in certain areas.
From the 1940s to the 1980s, all nuclear The U.S. Army requires different uniforms for
protective fabrics were made of 100% cotton use in five basic climates: hot-wet, hot-dry,
twill or sateen. However, cotton has some temperate, cold-wet, and cold-dry. In hot-wet,
shortcomings for nuclear protection which in- hot-dry and temperate environments battle-dress
clude irregular surface (not desirable for decon- uniforms are worn that are made from a blend of
tamination) and high linting, which reduces the 50% cotton, 49% high tenacity nylon, and 1%
protection. The second generation of nuclear static dissipative fiber. The balance of durability
protective fabrics utilized a 65/35 polyester/cot- and comfort are critical performance factors.
ton blend which accounts for 80% of all nuclear The temperate battle-dress uniform is made from
protective wear in the U.S. Poly/cotton fabric has a 7 ounce per square yard twill fabric. The hot
a longer life than all-cotton fabrics because of weather and desert battle-dress uniforms are
372 MILITARY AND DEFENSE TEXTILES
made from a 6 ounce per square yard ripstop lency for the life of the garment. Since the fabrics
poplin fabric. Woodland camouflage patterns will also repel perspiration they are used in gar-
consisting of the four colors of light and dark ments that are not worn next to the skin such as
green, brown and black, are applied using roller caps, hoods, cold weather field coats and trou-
screen printing [25]. The three color desert pat- sers.
tern consisting of light tan, light brown and light Smooth fabric surfaces are good for snow-
khaki are applied using the same technique. The shedding. Continuous filament nylon or poly-
sewing threads are cotton, rayon or polyester ester fabrics give smooth fabric surfaces. Silicon
with a polyester core. For flame resistance, plain treatment also reduces snow or ice adhesion.
and oxford weave aramid cloth is specified. The
aramid fiber blend consists of92% meta-aramid,
2.5 Surveillance and Camouflage
5% para-aramid and 3% static dissipative fiber.
The fabrics are woodland or desert camouflage
Textiles for military uniforms, individual
printed. Research is continuing for improved
equipment and tents must reduce visibility to
flame-resistant fabrics for military use.
sensor threats such as image intensifiers, radar,
Protection from extremely cold weather is
thermal imagers, and multi-spectral sensors.
another aspect of military clothing. The U.S.
Textile materials used in military applications
Army Natick Research, Development and En-
must provide protection against infrared image
gineering Center developed the Extended Cold
detection by blending in with the terrain. The
Weather Clothing System (ECWCS) for this pur-
traditional camouflage colors against a subtropi-
pose. It is made of synthetic fibers which
cal background are black, brown and green (Fig-
transport the moisture away from the body. The
ure 11.17). In deserts, the camouflage colors
system, which provides insulation, waterproof-
become different tones of brown. In snowy
ness and moisture vapor permeability, consists
areas, the obvious choice for camouflage is a
of polypropylene underwear, cold weather trou-
white color garment which may be a light over-
sers, field jacket and trouser made with a semi-
garment [26].
permeable film laminated fabric. This system
provides warmth and dryness without excess
weight. This system performs well at -25°F. By 2.6 Other Textile Materials for
adding a polyester fiber pile shirt and bib over- Individual Equipment
alls, the range can be extended to -60°F [19].
Protection against liquid water penetration is Special high altitude flight suits are used by the
achieved by polymer coating fabrics using rub- pilots in the U.S. Air Force. The flight jackets
ber, PVC, neoprene, acrylics, or polyurethanes. are generally made of Nomex~ IliA. The fabric
Waterproof fabrics may allow moisture-vapor is designed to protect the body against pressure
permeability even though it may be a small fluctuations. It also provides extra fire protec-
amount, e.g., up to 200 g/m2 per 24 hr for a tion.
lightweight polyurethane coated nylon fabric. Antifragmentation trousers made of Kevlar®
For an effective moisture-vapor permeable are effective against low velocity fragments and
clothing a minimum of 2,000-2,500 g/m2 per blasts. Parachutist's rough terrain suits made of
24 hour permeability is required [1]. Kevlar® offer increased puncture protection
Although fabrics treated with water-repellent from branches. Inclusion ofKevlar® in parachute
finishes can withstand light showers, they are not fabrics also increases flame resistance, tear
waterproof. The U.S. Army treats various tightly strength and cut resistance. Ballistic blankets
woven nylon and cotton blend fabrics with a increase fragmentation resistance for ordnance
fluorocarbon-based water and oil repellent and cargo. Gloves made of Kevlar® increase
finish. The combination of the dense fabric con- flame resistance and provide improved cut and
struction and durable fluorocarbon treatment wear resistance for working with razor wire.
results in an air and moisture vapor permeable Safety and protective fabrics for non-military
fabric that provides durable water and oil repel- applications are covered in Chapter 13.0.
11.1 Military and Defense Textiles 373
Textile structural composites (Chapter 7 .0) are FIGURE 11.19 Air·drop equipment (courtesy of High·
widely used in military equipment and hardware. land Industries).
FIGURE 11.20 A command post area camouflaged with textiles (courtesy of U.S. Army).
FIGURE 11.21 Filament winding of graphite fibers for lightweight, high strength racket motor case
for the small ICBM mobile missile (courtesy of the U.S. Department of Defense).
375
376 MILITARY AND DEFENSE TEXTILES
hardware including fighter planes and armored 2. 5 times and inspection interval five times com-
vehicles. Boron, silicon carbide and aluminum pared to aluminum patches. Boron-epoxy patch-
oxide fibers are also being used. A boron/epoxy ing is also easier to do in less time than metal
skin on the F-14 fighter plane is 20% lighter than patching. Boron-epoxy reinforcements have
titanium which reduces plane weight by several been used for the U.S.' s C -141 fleet for many
hundred pounds. On the F-18 fighter, 10% of the years [29].
structural weight and 50% of the surface area are
made of carbon reinforced composites (Figure
11.22). 4. OTHER APPLICATIONS
In naval applications, composite propellers
are used for the Mark 46 torpedo in the U.S. Fiber-optic systems are finding more and
Navy. Composite propellers performed better more usage in military applications including
than forged aluminum and decreased the produc- guidance systems for aircraft, missiles, and
tion costs by 55%. Other advantages offered by remotely piloted vehicles. They are also used
the composite propellers are weight reduction, under water to detect the enemy submarines [30].
chemical inertness and acoustic properties such Smart textile materials offer good potential for
as transparency to electronic detection. Com- use in military applications (Chapter 24.0). New
pression molding technique is used to manufac- polymers and composites that can detect and
ture the composite propellers [28]. respond to environmental stimuli (temperature,
Due to cabin pressurization cycles, cracks light, humidity) can be used to reduce heat build-
may develop around fasteners and windows in up and stress. Textile materials that will change
older aircrafts. Boron-epoxy composites are their color or properties as the background
used to patch cracks in aircrafts. It was reported changes can provide good dynamic camouflage.
that boron-epoxy patches increase the fatigue life Research in these areas is continuing.
11.2
References and Review Questions
Armor Selection;' Safety and Protective Retardant Fabric for the Armed Forces,"
Fabrics, Industrial Fabrics Association In- American Dyestuff Reporter, February,
ternational (IFAI), May 1993. 1987.
21. Truong, J. Q., "Semipermeable Materials, 28. Pegg, R, and Reyes, H., "Advanced Com-
Fact Sheet," U.S. Army Natick Research, posites: Now They've Joined the Navy;•
Development and Engineering Center. Design News, September 8, 1986.
22. Stull, J. et al., "Hydrogen Fluoride Ex- 29. Lynch, T. P., "Composite Patches Rein-
posure Testing of the U.S. Coast Guard's forced Aircraft Structures;' Design News,
Totally Encapsulated Chemical Response April22, 1991.
Suit;' in Performance of Protective Cloth- 30. Robinson, G. M., "Fiber Wins over the
ing: Second Symposium, ASTM STP 989, Military," Design News, April22, 1991.
S. Z. Mansdorf, R. Sager, and A. P. Niel-
sen, eds., American Society for Testing and
Materials, Philadelphia, 1988.
23. Seidel, L. E., "Defense Needs Offer Textile 2. REVIEW QUESTIONS
Opportunities;' Textile Industries, Novem-
ber 1983. 1. What are the major requirements for mili-
tary/defense textiles for soldier protection?
24. Bugge, G., "Cleaning Nuclear Protective
2. What are the typical materials used in battle-
Wear;' Safety and Protective Fabrics, May
dress uniforms?
1994.
3. Explain the principle of ballistic protection
25. Military Specification, MIL-C-44031D, using textiles.
U.S. Army Natick Research, Development 4. What is blunt-trauma effect? How could it be
and Engineering Center, August 22, 1989. reduced?
26. Military Specification, MIL-C-83429B, 5. What are the requirements for camouflage
U.S. Army Natick, 26 September 1990. fabrics for different climate and landscape
27. Weil, E. D., "Recent Progress in Flame conditions?
12.0
PAPER MACHINE CLOTHING
12.1
Paper Machine Clothing
S. ADANUR
fORMING
PRESS
382
Pickup
Felt Second
Press Felt
/
Wire
Bottom
Felt
FIGURE 12.3 Longitudinal cross section of a typical Fourdrinier paper machine (Albany International (2]).
paper web
forming fabric
water filtration
to press
sheet fonnation
zone
383
384 PAPER MACHINE CLOTHING
top headbox
___fJ top fabric
~ --+
decreasing. There are various machine elements There are different types of pressing mech-
to improve and control the drainage and forma- anisms (suction press, grooved roll transverse
tion which are outside of the scope of this book press, blind-drilled press, fabric press, shrink
[4-7]. sleeve press, double-felted and double-vented
nip press, extended nip press, impulse drying
2.2 Press Section and press drying) and press configurations
(straight-through press, transfer press, twinver
The function of pressing is to continue the press and no-draw press) [2,5,6].
water removal process which started in the form-
ing section, consolidate the sheet, give texture to 2.3 Dryer Section
the sheet surface, support and transfer the sheet.
The fabrics in this section are called press fabrics After pressing, the residual water in the sheet
or press felts. Although it depends on sheet grade is removed by evaporation (mass transfer) in the
and paper machine, typical sheet consistency at dryer section by using steam (heat transfer). The
the end of press section is 40% fiber and 60% fabrics in this section are called dryer fabrics or
water. At the end of the press section, sheet is dryer felts. The consistency after this section is
transferred to the dryer section. on the order of 95% fiber and 5% water which is
During pressing, the sheet is compressed be- the typical consistency of regular paper. The
tween one or two felts and two rolls in the press sheet is then wound on a roll.
nip to squeeze water from inside the web and out The drying zone can be considered as a'' black
of the felt fibers. Figure 12.7 shows this process box'' into which wet paper, steam and air enter.
in a plain press nip. Increased compression in- The dried paper, the moist and heat-laden air, and
creases water removal [8- 10]. the condensate leave the box [2]. Figure 12.8
~I lngomg
Nip
I
Mrd-Nrp
Outgoing
Nip
'
Top Press Roll
3. FORMING FABRICS
fahric
dryer
single fabric. double tiet single fabric, single tier double fabric. double tier
FIGURE 12.9 Configuration of dryer fabric with respect to cylinders and sheet.
386 PAPER MACHINE CLOTHING
layer fabrics were introduced. Today almost all fabric design: single layer, two layer and three
of the forming fabrics are made with high layer.
molecular weight and high modulus monofila-
ment polyester. For wear resistance, alternating Single Layer Forming Fabrics
nylon yarns are used in the bottom layer of multi-
layer fabrics. However, nylon is not dimen- Figure 12.10 shows schematics of single layer
sionally stable under wet conditions which limits forming fabric designs. There is one layer of warp
its use in forming fabrics. With the increase of and one layer of weft yarns. In practice, single
alkaline paper making, more and more nylon layer fabrics are woven with two to eight har-
yarns are being used along with polyester. nesses. Figure 12.11 shows a photomicrograph of
Polyester has good stress-strain properties and it a five harness single layer forming fabric.
is resistant to acid, but is subject to hydrolysis
under alkaline conditions. Two Layer Forming Fabrics
Today, with the use of recycled fibers, con-
taminants in the pulp such as pitch, wax, latex, Two layer designs have one layer of warp
etc., may create problems during paper manu- yarns and two layers of filling yarns. There are
facturing. Therefore yarns with contaminant two variations of two layer fabrics: standard two
resistance properties are in high demand. There layer and two layer extra designs. Figure 12.12
are several ways to achieve contaminant resis- shows a schematic of a standard two layer design
tance such as yarn coating, by adding contaminant and Figure 12.13 shows a photomicrograph of a
resistant additives to the polymer and fabric coat- standard two layer fabric. In this design, the ratio
ing. Fabric coating also improves stability. of the number of top weft yarns to bottom filling
Generally, fluorocarbon based coatings are used. yarns is 1 to 1. The second type of two layer
forming fabric is called ''two layer extra'' in
3.2 Fabric Designs and Structures which the ratio of the top filling yarns to bottom
filling yarns is 2:1 (in paper machine fabrics
There are basically three types of forming industry, a filling yarn is often called a'' shute'' ).
3 harness ('shed'), I /2
4 harness, 2/2
4 harness, 1/3
5 harness, 1/4
bottom filling
387
388 PAPER MACHINE CLOTHING
FIGURE 12.13 Photomicrograph of a standard two layer fabric (courtesy of Asten Forming Fabrics, Inc.).
The warp strand profile of a seven harness two Three Layer Forming Fabrics
layer extra design is shown in Figure 12.14. Two
layer extra design provides higher fiber support These fabrics have two separate fabric layers
compared to standard two layer designs. There- (top and bottom) connected with a binder strand
fore, their main application area is in the fine (stitch). As a result, there are two sets of warp
paper market. Figure 12.15 shows the photo- yams and two sets of filling yams as shown in
micrograph of a two layer extra design. Figure 12.16. In general, the top layer is finer
The advantages of two layer fabrics include than the bottom layer. Advantages of three layer
improved stability, resistance to wear and dam- designs are better formation and sheet quality
age, improved sheet formation, greater water due to the fine top layer, improved retention of
drainage capacity, more uniform wood fiber dis- fines and fillers, increased stability, improved
tribution, higher wood fiber support, less two- wear resistance due to the coarser bottom layer,
sidedness in the sheet and improved retention of and increased drainage rate, drainage capacity,
fines and fillers. fiber support and sheet smoothness.
bottom filling
Figure 12.17 shows a photomicrograph of a Section warping is the general type of warping
typical three layer design. The stitch strand is for forming fabrics. Only shuttle looms are used
usually finer than the other yams. Therefore, it for forming fabric manufacturing. Their con-
is well protected against wear due to paper struction is very heavy due to the high forces
machine elements. involved, especially during beat-up. Today,
The forming fabric designer can select and looms are manufactured at widths well over 500
control yarn materials, warp and beat count, inches. For three layer fabrics, two separate
weave pattern, number of harnesses and yarn warp beams are used. There are two types of
diameters in order to achieve the desired fabric weaving forming fabrics- flat weaving and end-
properties. These variables have effects on less weaving. In flat weaving, warp yarns on the
several fabric properties (air permeability, fabric loom become machine direction yarns on the
stability, fabric modulus, open area, fabric paper machine. In endless weaving, filling yarns
caliper) and paper machine operations (drainage, on the loom become machine direction yarns on
formation, fiber retention, sheet release, wire the paper machine.
mark, fabric cleaning and life).
Preliminary Heat Setting
3.3 Manufacturing of Forming Fabrics
After weaving, forming fabrics are heat set at
Design and manufacturing of forming fabrics high temperatures and under tension in warp and
require careful engineering. Manufacturing equip- filling directions. The maximum heat set tern-
FIGURE 12.17 Photomicrograph of a three layer fabric (courtesy of Asten Forming Fabrics, Inc.).
perature depends on the fabric material, however less fabrics since they are woven as an endless
it is usually around 475°F for standard polyester belt on the loom.
fabrics. The purpose of heat setting is to relieve
the internal stresses in the fabric after weaving in Final Heat Setting and Finishing
order to have a stable fabric structure. Fabric
modulus is drastically increased by heat setting. After seaming, the fabric is given a final heat
Fabric structure becomes more stable after heat set to relieve the stresses in the seaming area. The
setting due to crimp interchange. Warp crimp final heat setting temperature is lower than the
decreases and weft crimp increases during heat preliminary heat setting temperature in order not
setting (Figure 12.18). to alter the properties of the fabric that were set
during preliminary heat set. After final heat set-
Seaming ting, fabric edges are trimmed to the paper
machine width. An adhesive is applied on the Especially with the increased use of recycled
edges to prevent yam unraveling during opera- fibers, that are generally shorter, fiber support
tion. capability of forming fabrics has become more
Forming fabrics that will be used for finer important. A statistical model was developed by
paper grades are sometimes sanded with an Beran to calculate the fiber support of various
abrasive roll. Sanding removes the acute knuckle forming fabrics [12]. In its simple form, the fiber
points on the fabric and provides a smoother support index is calculated as follows:
surface.
FSI = 2/3 [a · W + 2 · b · S] (12.I)
3.4 Physical Properties of
where
Forming Fabrics
a = support factor for warp yarns
Some physical properties of forming fabrics b = support factor for weft yams on sheet
are crucial to its successful performance on paper side
machine. W = number of warp yarns per inch
S = number of filling yarns per inch
Mesh and Beat Count a = (number of weft yarns under warp
knuckle +I)/number of harnesses
Mesh is the number of warp yams per inch and b = (number of warp yarns under filling
beat is the number of filling yams per inch. These knuckle +I)/number of harnesses
numbers are usually used to distinguish forming
fabrics and they affect the other fabric proper- Drainage Index
ties. Lower mesh and beat numbers usually mean
a coarser fabric. Drainage index is a tool for rating fabrics
based on relative drainage rates. Drainage index
Air Permeability was developed by Johnson [13] and is given by
the following formula:
This is one of the most important fabric
properties. Air permeability is the measurement DI = (b · S · P)/I,OOO (I2.2)
of air flow through the fabric at a pressure dif-
ference of0.5 inch of water. It is measured as the where
air volume (cubic feet) passing through a unit b = support factor from weft strands
area (square feet) of fabric per minute (cfm). S = number of ftlling yarns per inch
P = air permeability (cfm)
Modulus b = (number of strands under filling knuckle
+I)/number of harnesses
Modulus is another important property of
forming fabrics. With the increasing speeds of Fabrics with higher DI values have higher
paper machines, tension on fabrics has increased drainage rates.
significantly. In order to prevent excess stretch-
ing of fabric beyond the take-up limit of the Caliper (Fabric Thickness)
machine under high tension, fabrics should have
enough resistance to stretching in the machine Low caliper is usually preferred especially in
direction. In practice, modulus is expressed in multi-layer fabrics since it reduces the water
terms of load per lineal unit length across the carry-back and increases drainage.
fabric width.
Open Area
Fiber Support Index
Open area in a fabric is an indication for
Fiber support is critical in sheet formation. straight-through drainage. Some two layer de-
392 PAPER MACHINE CLOTHING
signs do not have any open area at all. In these (1) Paper properties
designs, warp coverage is usually more than • grade (tissue, fine paper, newsprint,
100%, therefore, water drainage path is not kraft, nonwovens)
straight. The open area of a fabric is calculated • type of furnish and recycled fiber
as follows: content
• paper weight
Open Area (%) • wire mark considerations
• formation type
= [1 - (warp count)( warp diameter)]
(2) Paper machine parameters
X [1 - (weft count)(weft diameter)] • machine type
• machine length and width
X 100 (12.3) • speed
• type of pickup
Void Volume • paper machine elements (rolls, foils,
vacuum elements)
Void volume is the volume that is not occupied • operating tension
by yarns in fabric volume. Void volume affects
drainage of forming fabric. As the void volume The drainage path of forming fabric is very
increases, drainage also increases. important. Figure 12.19 shows drainage paths of
single layer and multi-layer fabrics. In single
3.5 Applications of Forming Fabrics layers, there is straight-through drainage. In
multi-layer fabrics, there may be straight-through
Selection of Forming Fabric Design drainage and angular drainage at the same time.
Drainage path determines the orientation of fibers
Different paper grades require different form- in the sheet which in turn affects the physical
ing fabric designs. When selecting a fabric properties of sheet such as tensile strength ratio
design for a specific application, the following and bulk. Figure 12.20 shows filling yarn profiles
paper and paper machine parameters need to be of various forming fabric designs.
considered: Fabric surface topography also plays an im-
single layer
two layer
~
(.,)
394 PAPER MACHINE CLOTHING
portant role. Figure 12.21 shows the paper side while. The contaminants can be organic
surfaces of typical single layer, two layer, two (pitch, size, starch, defoamers, ink, wax,
layer extra and three layer forming fabrics. latex), inorganic (calcium carbonate, cal-
Hole size and shape determine wood fiber cium sulfate, calcium silicate, talc, titanium
bridging between the yams. They also affect dioxide, clay) or biological (aerobic, an-
fiber orientation. For a given warp count, hole aerobic, fungi, algae). Several shower
size can be altered by changing the number of methods are used in order to keep fabrics
weft yams per unit length. clean.
Running attitude of forming fabrics are dic-
tated by the paper grade and wood fiber types. Edge unraveling and ridges/creases also cre-
Running fabrics with long filling knuckles up or ate problems on paper machine. Paper machine
down affects the paper properties and fabric run- misalignment, guide malfunction, and roll
ning conditions (Figure 12.22). There are two damage are among the causes for ridges and
fabric running attitudes: creases. Proper alignment and maintenance of
paper machine reduce the risk of ridges and
(1) Long filling knuckle up (to the sheet side) has creases.
the following effects
• better sheet formation
• easier fabric cleaning 4. PRESS FELTS
• reduced load
• better fiber bridging Until the mid-1940s, wool was the choice of
• good sheet release material for press felts. Introduction of staple
• better drainage synthetic fibers drastically improved the strength
• less fiber bleeding and life of the felt. In the early 1960s, needle-
(2) Long fllling knuckle down (to the machine punched felts were developed with improved
side) has the following effects drainage, finish and life. Later, inclusion of a
• poorer sheet formation due to less fiber base fabric inside the needled felt allowed in-
bridging creased press loading since it provided greater
• difficulty in cleaning incompressible void volume and improved the
• higher load due to larger wear surfaces water handling capacity of the felt. The resulting
• poor release fabric was the batt-on-mesh felt that was much
stronger, easier to clean, and had longer life.
3.6 Forming Fabric Operating Problems The main functions of a press fabric are water
removal from the sheet, sheet support and
Common problems affecting life and perfor- transportation, providing uniform pressure dis-
mance of forming fabrics can be summarized as tribution, and imparting proper surface finish to
follows: the sheet. The felt should provide proper cushion
for the sheet to resist crushing, shadow marking
(1) Stretch-Fabrics with low modulus may
and groove marking. Other functions include
stretch too much under high operating ten- transferring the sheet from one position to
sions on paper machine. Proper use of high another in the case of closed draws, driving the
modulus warp material and heat setting tech- undriven felt rolls and cylinder formers. The
niques can reduce fabric stretch during
amount of water that the felt can absorb and the
operation. water flow resistance are affected by the void
(2) Fabric wear- The main causes for fabric volume (volume that is not occupied by fibers or
wear are slippage, fillers in slurry, high yarns) in the fabric. Low flow resistance and
vacuum, abrasive roll surfaces, and flatbox ability to maintain void volume under load are
cover materials. important during operation. Important felt
(3) Contamination- Various contaminants may properties include strength, adequate void vol-
fill the fabric and make it useless after a ume, required permeability, low compressibility,
(a)
(b)
FIGURE 12.21 Forming fabric surfaces: (a) single layer, (b) two layer (courtesy of Tamfelt, Inc.).
395
(c)
(d)
FIGURE 12.21 (continued) Forming fabric surfaces: (c) two layer extra, (d) three layer fabncs
(courtesy of Tamfelt, Inc.).
396
12.1 Paper Machine Clothing 397
filling
fiiiing
Baseless Felt
Air Permeability
Void Volume
FIGURE 12.28 Pin seamed press fabric (courtesy of
Albany International) Void volume is the volume that is not occupied
by the yarns or fibers in the fabric. It is an
indication of the amount of water that felt can
proves start-up characteristics, abrasion, bac- absorb.
terial and chemical resistance, compaction resis-
tance, and contaminant resistance. Singeing is Flow Resistance
done to remove loose fibers and properly prepare
the surface. Properly designed felt should provide adequate
drainage and filtration of water and therefore
4.3 Properties of Press Fabrics should have minimum resistance to flow. Resis-
tance to water flow in the felt is measured in three
Based on their structures (number and dimen- directions using water permeability testers-
sions of base yarns, size of batt fibers, smoothness machine direction, cross-machine direction and
of the surface finish), press felts are classified as vertical direction. Low flow resistance indicates
superfine, fine, medium and coarse. The important higher water acceptance capacity of the felt.
properties of press felts are given below.
Compressibility and Resiliency
Felt Mass and Thickness
Compressibility is a measure of compactness
Felt mass is defined as the fabric weight per under load and resiliency is a measure of
unit area. Press felt should have a uniform mass rebounding capability of the felt after compac-
distribution across the width. Uneven mass or tion. Compaction resistance is a desired property
thickness (caliper) may cause press bounce or in press felts. A compaction resistant fabric can
vibration. Thickness is important for felt wear be either incompressible or compressible but
and compaction characteristics that influence resilient.
void volume and drainage of the felt. The rate of
thickness change during the operation depends Uniformity of Pressure Distribution
on the felt design. The thickness decreases quite
rapidly during the early days of the operation. Pressure from the rolls should be transferred
After a certain thickness loss, the fabric has to be to the sheet uniformly by the felt in order to
removed from the machine. prevent uneven sheet moisture profiles. Press
felts with fine base fabrics and fine batt fibers
Batt-to-Base Ratio provide more uniform pressure distribution. Too
coarse base yarns, improper weave design or
Batt-to-base ratio is defined as the mass of the insufficient batt may also cause sheet marking.
402 PAPER MACHINE CLOTHING
ture and moist conditions in an autoclave for a FIGURE 12.29 Hydrolysis resistance of materials
certain period of time. (CPPA [16)).
12.1 Paper Machine Clothing 403
which case the fabric becomes 100% monofila- struct spiral fabrics. Spiral fabrics have air per-
ment, or spun yam. Therefore, there are mainly meabilities in the range of 100-1 ,000 cfm. Per-
three variations of monofilament dryer fabrics: meability can be altered by inserting yarns in the
• monofilament weave cross-machine direction. This type of fabric is
resistant to stretching, bowing and narrowing.
• monofilament weave with monofilament
stuffer for low air permeability Spiral fabric is especially suitable for brown
• monofilament weave with spun stuffer paper applications.
404
FIGURE 12.31 Spiral fabric (courtesy of Asten Dryer Fabrics, Inc.).
405
406 PAPER MACHINE CLOTHING
yarns and creating a fringe. Then, a precoiled ment fabrics. In the joined spiral seam, which is
synthetic spiral is slipped into the fringe area, the for monofilament fabrics, a spiral with loops is
fabric is folded over and sewn [ 16]. The spiral used as well. However, instead of sewing, the
loops engage a similar spiral on the other end of area next to the spiral is woven into the fabric,
the fabric. The sewing thread should be buried in thus the spiral is anchored into the fabric (Figure
the fabric to avoid abrasion and seam failure. 12.33). The woven seam area is around 40-60
This seam style is used for mono- and multi-fila- mm in the warp direction. In a pin seam, all the
FIGURE 12.33 Spiral coil seam in monofilament fabric; the spiral yarn is PEEK
(courtesy of Asten Dryer Fabrics, Inc.).
12.1 Paper Machine Clothing 407
FIGURE 12.34 Pin seam in monofilament dryer fabric. The larger white area is a
sheet of paper placed for contrast. The joining wire is hidden, but is located between
the two white areas (courtesy of Asten Dryer Fabrics, Inc.).
warp yarns are woven back into the fabric but reached the 1.5-2.5 kN/m range which should
only some warp yarns participate in loop forma- be a fabric design factor especially in the seam
tion. Then, the loops on each end are connected area.
by a pin in the weft direction. The pin seam is
used for monofilament fabrics only (Figure 6. CURRENT AND FUTURE TRENDS IN
12.34). PAPER MACHINE CLOTHING
Monofilament dryer fabrics may be sanded to
obtain a smoother surface especially for the finer Paper machine clothing design, properties and
paper grades. applications have tremendous effects on paper
properties and papermaking process. Proper
5.3 Application of Dryer Fabrics paper machine clothing improves product qual-
ity, increases productivity, decreases paper ma-
The factors that affect dryer fabric selection chine downtime and increases the bottom line.
are paper grade, cylinder temperature and air Advances in raw materials and paper machine
moisture, operating life and economic considera- clothing design usually follow the advances in
tions, paper machine speed, pocket ventilation, paper machine design, paper making processes,
fabric drying equipment, operation tension, and paper grades and properties very closely. As a
dryer section configuration. Dryer fabric design result, a more ''engineered'' fabric is demanded.
should not mark the sheet.
Since monofilament fabrics are resistant to 6.1 Trends in Papermaking
filling and can be cleaned more easily, they are
suitable for recycled paper manufacturing. • increased recycling: In 1991, over 35%
Teflon® content monofilaments are used in the of all paper consumed in the United
construction of fabrics used with recycled pulp. States was recovered for recycling. In
Open-mesh multi-filament and monofilament 1993, the percentage reached 40%.
fabrics provide better moisture profile of the web • easy fabric installation, less downtime,
across the machine width. With the increased better runnability and improved fabric
machine speeds, fabric operating tension has efficiency
408 PAPER MACHINE CLOTHING
ing a forming fabric design for a particular 10. Defme hydrolysis resistance. Which fibers
application? are the best for hydrolysis resistance?
8. Explain the major press felt structures. 11. Explain how a pin seam is formed using a
9. What are the important properties of press schematic.
felts?
13.0
SAFETY AND PROTECTIVE TEXTILES
13.1
Safety and Protective Textiles
S.ADANUR
Kevlar PAN/carbon
blends PBI
*Rayon Glass Nomex PTFE Polyacxylate
Kevlar Phenolic Polyimide
*Nylon Silica Melamine
*Modacxylics PPS
*Polyester Ceramic
used for insulation and retain some strength are given in Thble 13.3. Table 13.4 shows the
above 2,000°F, they generally lose their textile application areas of some high performance-high
characteristics at that temperature range [3,4]. temperature fibers.
Table 13 .2 lists the major high temperature Thermal resistance is the ability of the fiber to
materials along with their manufacturers. hnpor- remain relatively unchanged when exposed to
tant properties of some high temperature fibers radiant, conductive and convective heat. If heat
Note: This is not an exhaustive list. Others are being developed; © 1995, Industrial Textile Associates, Greer, SC 29650.
TABLE 13.3 Properties of Selected High Temperature Fibers (courtesy of Industrial Textile Associates).
Fiber
Aramid3
M =meta PAN/ Novoloid Polyamide
Properties P =para Carbon Glass Melamine PBI (Phenolic) PPS Polyacrylate PTFE Polyimide Imide
Fiber Properties
Tenacity-dry g/d 4.0-5.3M 24 15.3 1.8 2.6-3.0 1.3-2.4 3.5 1.3-1.7 0.9-2.0 3.7 3.4
21-27 p
Tensile-000 psi 90M 31 500 30 50 20-30 61 25-33 40-50 67 75-80
400P
Elongation at break % 22-32M 19 4.8 12 25-30 30-60 40 20-30 19-140 19-21 16-21
2.5-4.0 p
Moisture regain % 6.5M 9 <0.10 5 15 6-7.3 0.6 12 0 3 4-4.5
4.0P
Specific gravity 1.38M 1.4 2.5 1.44 1.43 1.27 1.37 1.5 2.1 1.41 1.34
1.44P
Avg. toughness-g/d 0.30M N/A 0.37 NIA 0.4 N/A NIA N/A 0.15 N/A NIA
0.85P
Abrasion resistance GoodM Poor Poor Fair Good Poor Good Fair Good Good Good
PoorP
Resilience Excel Poor Poor Fair Excel Fair Good Good Poor Fair N/A
- - - ---····---
(continued)
.J:>.
......
-...J
....
.!)o.
00
Aramid 3
M =meta PAN/ Novoloid Polyamide
Properties P =para Carbon Glass Melamine PBI (Phenolic) PPS Polyacrylate PTFE Polyimide imide
Chemical Resistance
Solvents Excel M Good Excel Excel Excel Excel Excel Good Excel Excel Excel
GoodP
Acids dilute: GoodM Good Excel Good Excel Excel Excel Excel Excel Excel Good
concentrated: FairP Poor Excel Poor Excel Poor 1 Good Excel Excel Excel F-Good
Alkalies dilute: GoodM Good Fair Excel Excel Excel Excel Excel Excel Poor Good
concentrated: GoodP Good Fair Excel Good Excel Excel Excel Excel Poor Good
Ultraviolet (UV) Poor Good Excel Good Good Excel Excel Excel Excel Good Good
Thermal Properties
Relative Cost
1 =Low 4 =High 3 3 2 2 4 2 3 3 4
- 3 3
---- -- - - - -
1Nitricand sulfuric.
2Auto ignition@ 450°C and 100% 0 2.
3M-meta-aramid (as Nomex); P-para-aramid (as Kevlar).
Source: Producers literature and ITA database. © 1995- ITA, Greer, SC.
TABLE 13.4 Typical Applications of High Temperature Fibers (courtesy of Industrial Textile Associates).
Market Desired Properties Fibers Used
Construction
Hi-temp pipe wrap Tensile, thermal, hydrolytic properties Aramids, glass
Inflatable roofs Hi-strength, fire resist., low creep Glass
Coated Fabrics
Hi-temp silicone and similar Strength, fatigue resist., low creep Aramids, glass, PBI, others
coatings, seals, diaphragms,
inflatables
Filtration
Hot air/gas and corrosive liquids Hi-temp and chemical resistance Ararnids, PPS (sulfar), glass
retention of properties polyimide, other
Friction Products/Packing, Seals, Gaskets
Brake linings, clutch facings Modulus, thermal stability, non-toxic, Aramids, polyacrylate, carbon glass,
low wear phenolic
Gaskets, packing, seals Compressibility, thermochemical PTFE, PBI, polyimide, phenolic
resistant, recovery, sealability
Protective Clothing
Garments Thermal, absorption, dyeable, good Aramids, PBI, polyimides, PAN,
textile properties others
Gloves/aprons/sleeves Thermal, abrasion and cut resistance Aramids, glass
Reinforcement, Plastic, Advanced Composites
Aerospace, interior Strength, low density, thermal Aramid, carbon
Aerospace, structural +compression, vibration Carbon, quartz, glass, aramid
dampening hi-temp, ablative,
electrical prop.
Automotive, structural Tensile, compression and flexural prop. Carbon, glass
Reinforcement/Rubber
Belts/mechanical Strength, stiffness, hydrolytic stability, Aramid, other
temperature resistance
Tires-radial/hoses Strength, stiffness, adhesion, low Aramid, other
fatigue, oxidation resist, thermal
Ropes/Cordage
Rescue/fire resistant/escape Strength, thermal, low elongation Aramid, other
chutes/slides/slings compressed storage properties
Miscellaneous Industrial
Hi-temp fire blankets, welding and Thermal resistance, extreme hi-temp, Aramid, glass, PBI
fire barriers reasonable cost Leached glass
Sewing threads Strength, weatherability, thermal Aramid, PTFE
+ extreme hi-temp Leached glass, quartz, ceramic
Fire block seating Thermal, low toxicity, light weight Aramid, polyimide
Wire insulation Thermal, electrical, strength PPS, PEEK, aramid, glass
419
420 SAFETY AND PROTECTIVE TEXTILES
3. FLAME RESISTANT
PROTECTIVE CLOTHING
Aramid (meta) Nomex DuPont 6.5 4.0-5.3 Fiber forming substance is a long chain synthetic
polyamide. Excellent durability and chemical
resistance. Relatively poor colorfastness to
laundering and light exposure.
Kermel Rhone-Poulenc (France) 3.4 4.0-4.5
(para) Kevlar DuPont 4.3 21-27 Blended with Nomex for strength. Difficult to
Twaron Akzo (Holland) 4.0 22.6 dye. Excellent strength and abrasion resistance.
Sensitive to bleach, light, and strong mineral
acids.
Modacrylic SEF Monsanto 2.5 1.7-2.6 Fiber forming substance is a long chain synthetic
Kanecaron Kaneka (Japan) polymer containing acrylonitrile units. Excellent
chemical and abrasion resistance. High thermal
shrinkage.
PBI pbi Hoechst Celanese 15.0 2.8 Polymer is a sulfonated poly(2,2-m-phenylene-
5,5-1iibenzimidazole). Will not ignite, does not
melt. Excellent chemical resistance. Dyeable in
dark shades only.
Polyimide P84 Lenzing (Austria) 3.0 3.7 Fiber forming substance is a long chain synthetic
polyimide. High thermal shrinkage. Thermal
properties inferior to Nomex.
FR Viscose PFRRayon Lenzing (Austria) 11.5 2.6-3.0 Man-made cellulosic, properties similar to cotton.
FRCotton FRCotton Natural fiber 8.0 2.4-2.9 Flame resistant treated in fabric form. Poor
resistance to acids. Abrasion resistance on! y fair.
Relatively poor colorfastness to laundering and
light exposure. Wear properties similar to un-
treated cotton.
Vinal VinexFR9B Westex 3.0 3.0 Fiber composed of viny I alcohol units with acetal
crosslinks. Sheds aluminum splash, but very
sensitive to shrinkage from wet and dry heat.
FR Polyester Trevira FR polyester Hoechst Celanese 0.4 4.5 Polyester with proprietary organic phosphorus
compound incorporated into the polymer chain.
Properties similar to regular polyester except for
inherent flame resistance. Melt point 9°C lower
than regular polyester.
13.1 Safety and Protective Textiles 423
a single type of fiber (e.g., 100% SEF Moda- (1) A precondensate of tetrakis (hydroxy-
crylic) or from blends of two or more fibers methyl) phosphonium chloride (THPC)
(e.g., DuPont's Nomex® IliA which is made of reacted with urea and cured with gaseous
Kevlar®, Nomex® and carbon). Blending of ammonia to form a polymeric molecule,
fibers is a common practice in industry to op- e.g., Proban from Albright and Wilson
timize the desired flame resistance and other (2) A heat cured dialkylphosphonarnide, e.g.,
properties, including cost. By mixing natural Pyrovatex CP from Ciba Geigy
fibers such as cotton and wool with synthetic
fibers, fabrics with high comfort and good aes- Depending on the treatment, flame retardant
thetic properties can be engineered to meet the finishes for cotton may be temporary or per-
specific thermal requirements. However, cau- manent. While FR treated cotton is suitable for
tion should be exercised when mixing FR fibers foundries, flame cutting, welding, chemical en-
that may react differently to flame. Future FR vironments, oil, gas and petrochemicals, it is not
garments will withstand longer exposure times in recommended for protection against molten
hazardous conditions, reduce the potential for white metals such as aluminum (molten metals
body bums, and enhance the ergonomical aspect will stick to the fabric) and in critical static con-
for better job efficiency. trol operations. Although cotton is resistant to
alkalis, many acids will completely destroy FR
and non-FR cotton. Chlorine bleach destroys the
3.1 Flame Resistant Fibers and Fabrics flame retardant polymer in treated cotton fabric.
Starches and fabric softeners should also be
Treated cotton is widely used in apparel for avoided. Life expectancy of the FR cotton is
flame resistance. The most commonly used syn- similar to 100% cotton.
thetic flame resistant fibers include aramids, PBI FR-8 cotton fabric is treated with a non-phos-
and PFR rayon. SEF acrylic is used in some phorus flame resistant finish. It is exclusively
chemical resistance requirements and in intended for protection against aluminum splash.
children's sleepwear. Table 13.5 shows the com- A system of antimony oxide and bromide com-
mercially available flame resistant fibers for pounds is bound to the fiber by a special latex
work apparel fabrics. Many blending combina- binder. The disadvantages include stiffness, little
tions are possible using fibers in the table. Brief moisture absorbency, and short treatment life.
descriptions of flame resistant fibers and fabrics Fabric weight is an important parameter for
are given below. For more detailed information thermal insulation with FR cotton materials. It
the reader may refer to Reference [1]. Table 13.6 was reported that increasing fabric weight in-
shows the FR fabric consumption in the United creased protection time as shown in Figure 13 .4.
States. Twenty-eight FR cotton fabrics of weights rang-
ing from 4.5 oz/sq. yd to 13.5 oz/sq. yd were
Flame Resistant (FR) Cotton exposed to a mixture of convective and radiant
energy from a thermal source of2.0 callcm2 sec.
Various flame resistant treatments have been It should be noted that the fabric itself, not the
applied to cotton goods over the years. The two flame retardant treatment provides the insulative
most widely used treatments for cotton today are: protection.
TABLE 13.6 Estimated Consumption of FR Fabrics in the United States (millions of square yards [8]).
Fabric Type 1985 1987 1990 1991 1996
Ij: s 0
0
strength. Nomex® IliA, which consists of 93%
00
0 Nomex®, 5% Kevlar and 2% carbon core nylon,
z 0
0 was developed to improve static electricity
~Ill 5
0
0
properties. Nomex® ill and IliA are extremely
i
0
0 durable.
~0 Nomex® Delta A is designed to reduce the risk
4 0
0 of explosions sparked by static electricity
0 prevalent in the petroleum and chemical in-
3+---~--r-~--~--~--~--~~ dustries. Nomex® Delta Tis suitable for protec-
3.0 4.5 6.0 7.5 9.0 10.5 12.0 13.5 15.0
tion from flash fires or other sources of intense
FABRIC WEIGHT OZ/YD'
heat for extended periods of time. Nomex® Delta
FIGURE 13.4 Protection time versus Iabrie weight tor FA
cotton fabrics [9). FF incorporates fine fibers for hot gas filtration
applications.
7.0 2.2 2.1 2.2 2.2 2.5 2.5 2.7 2.7 3.0 3.4
9.0 2.6 2.3 2.5 2.6 2.6 2.5 2.5 2.3 2.0 2.8
However, it is not recommended against molten molten materials, welding or in critical static
substances or welding exposure. SEF offers control operations is not recommended. Ker-
good colorfastness to laundering. It is resistant to mel® is solution dyed, i.e., dyed in fiber form. It
most acids, weak alkalis, bleaches and most sol- is resistant to most acids and alkalis.
vents. Since SEF garments shrink considerably
over l40°F, their use in FR clothing has been Fire Wear®
declining.
FireWear® is an inherently flame resistant yam
F/amex //® which is a blend of 55% FFR-acrylic (Fibrous
Flame Retardant Fiber) and 45% combed cotton
Flamex fii~D, a treated fabric, is a 70/30 cot- produced by Springs Protective Fabrics. It may
ton/polyester blend produced by Galey & Lord be used in knitted fabrics (T-shirts, polo shirts,
Inc. It is dyeable in various colors with good sweatshirts, protective hoods) and in woven
colorfastness to laundering, which makes it fabrics (shirts, pants, etc.). FinWear® is dyeable
suitable for professional fire fighters and utilities in fabric form. Application areas include petro-
personnel. Its use is not recommended against chemicals, utilities, and fire fighter uniforms. It
molten substances and welding. Flamex HIP is offers excellent thermal stability.
sensitive to chlorine bleach. Flamex®, which Upon exposure to flames, certain molecular
was an earlier version, had 50/50 cotton/poly- components of the FFR fiber emit a non-combus-
ester ratio. tible gas-released through the tiny pores in the
fiber-that smothers the fire similar to a fire
PBI (Polybenzimidazole) extinguisher. These gases shut off the oxygen
feeding the flames, thereby stopping further
PBI from Hoechst Celanese, is an inherently burning. Figure 13.5 showsFFRfibersandFire-
flame resistant fiber. First used in manned Wear® woven and knit fabrics before and after
spacecraft applications, PBI is mostly used for exposure to flames.
military and aerospace applications as well as
professional fire fighters. PBI, which has a Trinex®
natural color of gold, can be dyed in dark colors.
It has good resistance to most acids, alkalis and Trinex® (Westex, Inc.) is a blend of mod-
solvents, however, chlorine bleach reduces acrylic, polyester and rayon. The ratio is
PBI' s strength. PBI is thermally very stable and 40/30/30 for pants fabric and 50/30/20 for shirt
retains fiber integrity after flame exposure. Gar- fabrics, respectively. It is inherently flame resis-
ment life is claimed to be compatible with tant. Trinex® is used for fire fighter and utility
Nomex®. Kombat 450, which is a blend of 60/40 worker uniforms, and airline flight personnel. It
Kevlar/PBI fabric produced by Southern Mills, is not recommended for molten materials, weld-
is suitable for career apparel applications. PBI is ing operations, or in critical static control opera-
used in high temperature industrial gloves, tions. Other properties include relatively poor
foundry applications, firemen's protective ap- thermal stability, good resistance to chemicals,
parel and as an aircraft seat fire blocker. aging, sunlight and abrasion.
Kerme/® P84
FFR'" Fibers
Woven FireWear®
Knitted FireWear"'
FIGURE 13.5 FFR fibers and FireWear® fabrics before and after exposure to flames (courtesy
of Springs Protective Fabrics).
is solution dyed. It offers good resistance to aluminized and rubberized fabrics. Kynol® is a
organic solvents, acids and bleach. P84' s ther- non-melting and non-shrinking organic fiber
mal stability is low. which offers light weight and soft hand. The
practical temperature limits for long-term ap-
Kyno/® plication are 150°C in airand200-250°C in the
absence of oxygen [11].
Kynol®, which is produced by Gun Ei Chemi-
cal in Japan and distributed by American Kynol, Aflammit®
Inc., is an inherently flame (and chemical) resis-
tant novoloid fiber and can be made in fiber, Aflammit® is a group of FR products de-
yarn, fabric and felt forms. It can also be used in veloped by Thor Chemicals that is durable to
13.1 Safety and Protective Textiles 427
All wearing apparel sold in the United States TABLE 13.8 Typical Vertical Flame Test
must be made of fabrics in Class 1 or 2. Results Using FTM 5903A (DuPont {13}).
The most widely used test methods to evaluate Char Length After-Flame
the performance of thermal protective fabrics are (inch) (seconds)
as follows: Flame Resistant Fabrics
Aramid (6 oz/yd2) 3 0
(1) The vertical flame resistance test, Method FR cotton (10 oz/yd2) 3 0
5903.1 of Federal Test Standard 191A, Non-Flame Resistant Fabrics
which is sponsored by the General Services 100% Cotton 12 36
65/35 Polyester/cotton
Administration (GSA), Office of Federal
blend 12 48
Supply Services. In this method, a twelve
inch long fabric, which is suspended verti-
cally, is subjected to a controlled flame on the
cut edge. After twelve seconds, the flame is maximum of 2.0 seconds after-flame and
removed and three characteristics are re- five inches char length for fire fighter
ported (Figure 13.6): uniforms. Heat resistance of thread materials
• afterflame: the time (in seconds) that is commonly measured using Federal Test
visible flame remains on the fabric Method 191A, 1534.
• afterglow: the time (in seconds) that (2) ASTM Standard Test Method for Thermal
glow remains on the fabric Protective Performance (TPP) of Materials
• char length: fabric length that is for Clothing by Open-Flame Method, D
destroyed by the flame (inches) 4108. This test method is used to rate textile
Five samples are tested in each direction materials for thermal resistance and insula-
(warp and filling) of the fabric and the tion when exposed to a convective heat flux.
average of each group is reported. It should It is suitable for testing of woven, knit, non-
be noted that Method 5903.1 is only a test woven fabrics and batting materials. The
method and it does not establish require- material is exposed to heat from a standard
ments. Table 13.8 shows typical vertical flame on one face. The amount of heat en-
flame test results using this method. Some ergy, which would be expected to cause a
manufacturers and professional agencies second degree burn on human tissue in con-
have established more specific standards. tact with or close to the opposite face, is
For example, California. OSHA specifies a measured. ASTM D 4108 specifies two
methods for TPP testing: one for single layer
fabrics (such as those used in the shirts, pants
and coveralls worn by industrial workers)
and one for multi-layer fabrics (such as those
used in three layer firefighter turnout coats).
During single layer fabric testing, 0.25 inch
spacer is placed between the fabric sample
and the heat sensor. In multi-layer fabric
testing, the fabric sample and the heat sensor
is in intimate contact, without the spacer.
Other ASTM standards related to flame
resistance clothing include:
• D 1230, Test Method for Flammability
of Apparel Textiles
• F 1358, Test Method for the Effects of
Flame Impingement on Protective
FIGURE 13.6 Vertical flame test of FR cotton (courtesy Clothing Materials Not Designated for
of American Kynol, Inc.). Primary Flame Resistance
13.1 Safety and Protective Textiles 429
• F 1449, Guide for Care and Finally, it should be noted that extreme care
Maintenance of Flame Resistance and should be taken when conducting the tests. The
Thermal Protective Clothing test results may vary slightly from laboratory to
• Method for Thermal Protective laboratory although the same standard test
Performance of Materials for Clothing method is used as shown in Table 13.10. One
by Convective and Radiant Heat reason for this variation may be the fact that
Method (New Standard) every flame or fire is different.
• Test Method for Thermal Protective
Performance of Materials for Clothing
by Radiant Heat Method (New 3.3 Performance of FR Textiles
Standard)
(3) The National Fire Protection Association Baitinger and Konopasek examined a variety
(NFPA) has issued several standards on fire of FR cotton fabrics for thermal protective per-
fighter protective clothing. formance [15]. Fabrics were subject to convec-
• NFPA 701, Fire Tests for Flame tive and radiant exposure (ASTM D 4108). The
Resistant Textiles and Films results are shown in Table 13.11.
• NFPA 702 (for clothing except hats, Barker et al. measured the ability ofFR fabrics
gloves, footwear and interlinings) to block heat transfer when in contact with a hot
• NFPA 1971, Standard on Protective surface [16]. They found that protection time
Clothing for Structural Fire Fighting drops off exponentially with surface tempera-
• NFPA 1973, Standard on Gloves for ture. Applied pressure increased the contact be-
Structural Fire Fighting tween the fabric and hot surface and decreased
• NFPA 1975, Standard on Protective the effective thickness of compressible fabrics
Clothing for Station Work Uniforms. resulting in increased heat transfer rate. Figure
In this standard, two new 13.7 shows their results. Table 13.12 shows
requirements are established: tolerance time of tested fabrics at different sur-
garments must not melt or drip when face temperatures.
exposed in a forced air oven at 500°F Thermal comfort of the protective garment is
for five minutes; and garments must very important for the wearer. At high outside
be approved by a third party temperature and humidity, the evaporation of
organization. sweat becomes a factor. Therefore, to improve
• NFPA 1976, Standard on Protective comfort, water vapor permeability of protective
Clothing for Proximity Fire Fighting clothing must be high.
• NFPA 1977, Standard on Protective Special attention should be given to sewing
Clothing and Equipment for Wildlands thread when manufacturing flame resistant gar-
Fire Fighting ments. Sewing thread failure can lead to
In 1992, NFPA issued NFPA 1999, Stan- downfall of the entire protective system. Table
dard on Protective Clothing for Emergency 13.13 shows properties of the some sewing
Medical Operations which includes design, threads for high temperature applications.
performance and labeling requirements for Some companies and research institutions
emergency medical protective gloves, gar- developed instrumented mannequin testing pro-
ments and facewear. cedures to predict the relative protective perfor-
mance of actual garments in a flash fire. Figure
Table 13.9 summarizes flammability test 13.8 shows a schematic of such a system. These
methods for various applications. tests use a controlled laboratory simulation of a
In Europe, the European Standardization flash fire exposure on a life-size mannequin to
Committee (CEN) is responsible for standard predict estimated bum injury (Figure 13.9).
development. CEN standards specific to protec- Variables include fabric type, fabric weight, gar-
tive clothing are developed by Technical Com- ment style, use of undergarments, heat flux and
mittee (TC) 162 [14]. exposure time.
.j:>.
c.l
0
TABLE 13.9 Major Characteristics of Various Fabric Flammability Test Methods (courtesy of U.S. Testing Co. Inc.).
1a CPSC Flammability cs 191-53 Fabrics 2x6 5 original 45° Butane burner Oven-dry 112 Time of flame spread, ease of
of Clothing 16 CFR 1610.4 Apparel 5DC&W hr@ 221°F ignition, flame intensity
Textiles
1b ASTM Flammability ASTMD 1230 Fabrics 2X6 5 original 45° Butane burner Oven-dry 112 Time of flame spread, ease of
of Clothing Apparel 5DC&W hr@ 221°F ignition
Textiles
2 CPSC Children's FF 3-71/5-74 Sleepwear 3.5 X 10 10 fabrics Vertical Methane Oven-dry 112 Char length
Sleep wear 16 CFR 1615.4 sizes 0-6X 15 seams burner hr@ 221°F
16 CFR 1616.4 sizes 7-14
3 GSA Flame FTMS 191 Fabrics 2.75 X 12 5W,5F Vertical Methane 70°F, 65% RH After-flame, afterglow, char
Resistance of Method 5903.1 burner length
Clothing,
Vertical
4 GSA Flame FTMS 191 Fabrics 2.75 X 12 5W,5F Vertical Butane burner 70°F, 65% RH After-flame and % consumed
Resistance of Method 5905.1
Clothing,
Vertical
5 GSA Burning Rate FTMS 191 Fabrics 2X6 5 45° Butane burner Oven-dry 112 Ease of ignition, rate of burning
of Cloth, 45° Method5908 hr@ 221°F
Angle
6 GSA Burning Rate FTMS 191 Fabrics 1 X6 3W,3F 30° Match 4hrs@ 140°F Rate of burning
of Cloth, 30° Method5910
Angle
7a CPSC Mattresses FF-4-72 Mattress and Finished item 6 surfaces Horizontal Cigarette 48 hrs@ Char length and ignition
16 CFR 1632.4 mattress pads 65-80°F and
16 CFR 1632.6 ticking 20 X 20 6 surfaces 55% RHmax.
7b State of CA Mattresses Tech Bulletin Mattress and Finished item 6 surfaces Horizontal Cigarette 48 hrs@ Char length and ignition
Bureau of 106 mattress pads 65-80°F and
Home ticking 20 X 20 6 surfaces 55% RHmax.
Furnishings
TABLE 13.9 (continued).
Name of Procedure Specimen Size No. of Angle of Ignition
Sponsor Test I.D. No. Sample (inches) Specimen Specimen Source Conditioning Properties Measured
7c StateofCA Mattresses Tech Bulletin Mattress N/A I Horizontal Propane burner 70°F, 50% RH Heat release, weight loss,
Bureau of 121, 129 smoke density
Home
Furnishings
Sa NFPA Fire Tests for NFPA 701, Fabrics and Installed: Vertical Burner Oven-dry I hr After-flame, afterglow, char
Flame large scale films (I) in sheets SW,SF @ l40°F length
Resistant 5 X 84
Textiles and (2) in folds 2W,2F
Films 25 X 84
8b NFPA Fire Tests for NFPA 701, Fabrics and 3.5 X 10 SW,SF Vertical Natural gas I hr@ 140°F After-flame, flaming residues,
Flame small scale films char length
Resistant
Textiles and
Films
8c NFPA Fire Tests for NFPA 701 Fabrics 3.5 X 10 SW,SF Vertical Natural I hr@ 140°F Weight loss
Flame curtain and
Resistant drapery under
Textiles and 3.0 oz/sq yd
Films
9 City of Fabric BFDIX-1 Treated fabrics 4 X 12 3L, 3W Vertical Propane Ambient After-flame, afterglow, char
Boston Classification 45° torch length
10 City of Board of STDs. Calender No. Fabrics 2 X 12.5 3L, 3W Vertical Burner Ambient After-flame, afterglow
New York Appeals Bylaw 294-40-SR
!Ia State ofCA Fire Code Par. 1237 .I, Fabrics 2.5 X 12.5 3W, 3F Vertical Burner I hr@ 140°F After-flame, char length
Title 19 small scale
lib State of Fire Code Par. 1237.3, Fabrics 5 X 84 3W, 3F Vertical Burner I hr@ 140°F After-flame, char length
CAFire Title 19 large scale
Marshal's
Office
12a CPSC Surface FF 1-70/FF Carpets and 9X9 8 Horizontal Methanamine Oven-dry 2 hrs Area of flame spread (greatest
Flammability 2-70 rugs 24 sq. ft. burning tablet @ 221 °F diameter)
of Carpets and 16 CFR 1630.4
Rugs 16 CFR 1631.4
.j:lo.
U) (continued)
......
_.::..
CtJ
I\)
TABLE 13.9 (continued).
Name of Procedure Specimen Size No. of Angle of Ignition
Sponsor Test J.D. No. Sample (inches) Specimens Specimen Source Conditioning Properties Measured
12b ASTM Surface ASTM 02859 Carpets and 9X9 8 Horizontal Methenamine Oven-dry 2 hrs Area of flame spread (greatest
Flammability rugs burning tablet @ 221 °F diameter)
of Carpets and
Rugs
13a State of Upholstery Tech Bulletin Fabrics and
CABureau Materials 117 filling materials
of Home Specimens and procedures vary with materials
Furnishings
13b UFAC Upholstery UFAC-1990 Fabrics and Char length
Materials Specimens and procedures vary with materials
filling materials
13c NFPA Upholstery NFPA-260 Fabrics and Char length
Materials filling materials Specimens and procedures vary with materials
l3d BIFMA Upholstery BIFMA Fabrics and Char length
Specimens and procedures vary with materials
Materials filling materials
l3e Brit Stnds Upholstery BS 5852 Fabrics and Char length, weight loss
Specimens and procedures vary with materials
Materials filling materials
l3f NFPA Upholstered NFPA261 Component Varies with 1 Horizontal Cigarette 48 hrs@ Char length
Furniture or materials procedure 73°F, 50% RH
Mock-ups
l3g State of Upholstered Tech Bulletin Complete N/A 3 Horizontal Cigarette 65-80°F, Char length
CABureau Furniture 116 upholstered 55%RH
of Home
Furnishings
l3h State of Seating Tech Bulletin Complete N/A 1 N/A Propane burner 70°F, 50% RH Heat release, weight loss,
CABureau Furniture 133 upholstered smoke density
of Home
Furnishings
14a NFPA Protective NFPA 1971 Component 2.75 X 12 5W,5F Vertical Bunsen burner 70°F, 65% RH After-flame, afterglow, flaming
Clothing materials drips, char length
14b NFPA Station Work NFPA 1975 Fabrics 2.75 X 12 5W,5F Vertical Bunsen burner 70°F, 65% RH Melt and drip, after-flame, char
Uniforms length
TABLE 13.9 (continued).
Name of Procedure Specimen Size No. of Angle of Ignition
Sponsor Test 1.0. No. Sample (inches) Specimens Specimen Source Conditioning Properties Measured
15a Federal FAA FAR. 25.853 Compartment 4 X 14 3L,3W Horizontal Burner 70°F, 50% RH Time of flame spread
Aviation Regulations AppendixF, materials
Authority for Pt. 1
Compartment
Interiors
15b Federal FAA FAR. 25.853 Compartment 2.75 X 12 3L,3W Vertical Burner 70°F, 50% RH After-flame, bum length,
Aviation Regulations AppendixF, materials flaming drips
Authority for Pt. 1
Compartment
Interiors
15c Port Upholstery of Same as FAA Fabrics 2.75 X 12 3W,3F Vertical Methane 70°F, 50% RH After-flame, char length, flam-
Authority Seating 25.853 ing drips
of NY and
NJ
16 Dept. of Flanunability FMVSS302 Interior 4 X 14 3L,3W Horizontal Burner 70°F, 50% RH Flame spread
Transpor- of Interior materials
tation and Materials of
State ofCA Cars, Trucks,
Multipurpose
Passenger
Vehicle Buses
17 Fed. Test Mackey FTMS 191 Cloth, related 2 X 12 2min. N/A NIA 4hrs@ 60°C Tendency of material to
Method Method5920 materials minimum undergo self-heating at
STD. moderate temp.
(continued)
t;
c.l
.1:>-
Ul
.1:>-
!Sa Canvas Camping CPAI-84 Tenting Floors 9 x 9 8 Horizontal Pill burner 70°F, 65% RH Area of flame spread,
Products Tentage ASTM 04372 materials Walls 2.75 x 8W,8F Vertical Leached & after-flame, char length
Assoc. Int' I 12 weathered
18b NY State Tents Dept. of Labor Fabrics 2.75 X 12 5W,5F Vertical Bunsen burner 70°F, 65% RH After-flame, char length
Bd. STDS.
and Appeals
Code 36, Sec.
3.8C
19 Canvas Sleeping Bags CPAI-75 Sleeping bags Entire bag 5 original Horizontal Bunsen burner 70°F, 65% RH Burning rate
Products 5laundered
Assoc. Int'l
20 ASTM Blankets ASTM 04151 Fabric 2.75 X 2.75 5 face Horizontal Butane burner Oven-dry l/2 Pass/fail
5back hr@ 220°F
21 ASTM Apparel ASTMD3659 Fabric 6 X 15 5W Vertical Fan burner Oven-dry l/2 4 burn time, weight loss
Fabrics hr@ 220°F
Semi-Resistant
22 U.S. Modified 5100-IA Fire tent 10 X 4.5 to I min. 45° Radiant panel Ambient Inhalation toxicity
Forestry USTC- laminate 10 X 36
Depart. Comparative
Inhalation
TABLE 13.10 TPP Tests of Single Layer Fabrics (courtesy of DuPont).
TPPValue
TABLE 13.11 Protection Times for FR Cotton Fabrics Exposed to Radiant and Convective Heat
(copyright ASTM {15}).
Protection Time, s
435
TABLE 13. 12 Insulation of FR Fabrics in Surface Contact (copyright ASTM {16]).
Tolerance Time, • s, at Surface Temperature, oc
Fabric Composition 100 150 200 300 375
*Tolerance time: time to second degree bum injury predicted using the Stoll criterion.
436
FIGURE 13.7 Effect of plate temperature and fabnc thickness on insulation time (copyright
ASTM [16]).
mannequin
propane measuring
~50cm~ instrument
FIGURE 13.8 Schematic of a typical mannequin test setup
(courtesy of Teijin Limited).
437
~
w
CD
FIGURE 13.9 Mannequin test results of protective garments made of 100% meta-aramid fabric (top row) and polyester/cotton fabric (bottom row) (courtesy of Teijin Limited).
13.1 Safety and Protective Textiles 439
Ensemble Description Area of Application Weight (gfm2) Thickness (mm) TPP Rating
440
TABLE 13.14 (continued).
Ensemble Description Area of Application Weight (g/m2) Thickness (mm) TPP Rating
OS: outer shell, VB: vapor (moisture) barrier, TL: thermal liner.
Total thickness may exceed the sum of parts because of air entrapment between layers.
Each TPP rating is an average of three separate tests. A minimum TPP rating of 35.0 is being considered as a standard for coats or pants.
441
FIGURE 13.11 Fire entry suit. This suit is designed for FIGURE 13.12 Kiln entry suit for worker who must func-
short duration entry into total flame engulfment or fur- tion in kiln or other extreme heat situations that do not
nace. It consists of separate coat and pants constructed involve total flame, but require high quality heat protec-
from multiple layers of glass insulation, aluminized glass, tion. It is made of multiple layers of glass and an extra
and non-aluminized glass surface (courtesy of Fyrepel layer of aluminized glass between the wearer and heat or
Products). non-ferrous splash (courtesy of Fyrepel Products).
442
13.1 Safety and Protective Textiles 443
4. CHEMICAL PROTECTIVE
CLOTHING (CPC)
(4) Level Dis the normal work clothing to keep Particulate Protective Textiles
off dirt, grease, limited spill protection, etc.,
and is not considered protective clothing by Examples of materials for particulate protec-
emergency-response personnel. tion are spunbonded olefins (e.g., Tyvek®),
hydroentangled spun lace (e.g., Sontara®), cel-
Chemical protective clothing may be cate- lulosic materials (e.g., Kaycel®) and spunbond-
gorized as encapsulating and non-encapsulating. meltblown-spunbond composites (e.g., Kleen-
Encapsulating ensemble covers the whole body guard®).
including the respiratory protection equipment. Tyvek® is a spunbonded polyethylene material
The non-encapsulating system is assembled from made by DuPont. It has high strength, low per-
separate components and the respiratory ap- meability and meets the federal flammability re-
paratus may be worn outside the suit. Encap- quirements. Tyvek® is formed by a continuous
sulating garments usually provide better process from very fine 0.5-10 micrometer
chemical protection. All Level A and Level B fibers. These non-directional fibers are first spun
protective clothing is encapsulating. Non-encap- and then bonded together by heat and pressure,
sulating systems usually apply to Level B or without binders or fillers. Figure 13.15 shows
below. the fiber structure of Tyvek®.
Tyvek® is suitable for cutting and sewing.
However, garments made of Tyvek® may cause
4.1 Chemical Protective Materials heat stress. Perforated Tyvek® allows through
air flow due to tiny air holes opened in the struc-
In general, porous fabrics are used for particu- ture. Usually antistatic treatment is applied on
late protection and coated/laminated fabrics are the surface of Tyvek®, which is opaque.
used for liquid and gas protection. Table 13.15 Kaycel® of Kimberly-Clark is made of cel-
gives some of the currently used materials for lulosic fabric reinforced with a plastic scrim.
chemical protection. Hydraspun FR®, produced by Dexter Corpora-
TABLE 13. 17 ASTM F 1001 Recommended Chemicals to Evaluate Protective Clothing Materials
(Texas Research Institute {21]).
Liquids Gases
447
448 SAFETY AND PROTECTIVE TEXTILES
Ch
0.1% Natural rubber latex 0.46 >8.0 ND
Neoprene 0.41 >8.0 ND
0.002% PE Tyvek 0.15 >8.0 ND
HCN (liquid) 100% PVC 0.79 0.5 2.9
Butyl 0.38 1.0 0.15
PE Tyvek 0.15 1.0 1.1
CHzO
37% Natural latex 0.15 0.1 33.3
Nitrile 0.28 >6.0 ND
under Conditions of Continuous Contact. This Evaluating the Comfort, Fit, Function,
method quantifies three parameters: the normal- and Integrity of Chemical Protective Suit
ized breakthrough time, the permeation time and Ensembles
the cumulative amount of chemical that has per- • F 1291 Test Method for Measuring the
meated at any time. In this method, the outside Thermal Insulation of Clothing Using a
surface of the protective clothing is exposed to a Heated Mannequin
challenging chemical. The inside surface is kept • F 1194 Guide for Documenting the
in contact with a collection medium that is Results of Chemical Permeation Testing
monitored for the chemical content [25]. ASTM on Protective Clothing Materials
developed other test methods related to chemical • F 1296 Guide for Evaluating Chemical
protective clothing that include: Protective Clothing
• F 1301 Practice for Labeling Chemical
• F 903 Test Method for Resistance of Protective Clothing
Protective Clothing Materials to • F 1359 Practice for Determining the
Penetration by Liquids Liquid-Tight Integrity of Chemical
• F 0955 Test Method for Evaluating Heat Protective Suits or Ensembles under
Transfer through Materials for Protective Static Conditions
Clothing upon Contact with Molten • F 1383 Test Method for Resistance of
Substances Protective Clothing Materials to
• F 1001 Guide for Selection of Chemicals Permeation by Liquids or Gases under
to Evaluate Protective Clothing Meterials Conditions of Intermittent Contact
• F 1002 Performance Specification for • F 1407 Test Method for Resistance of
Protective Clothing for Use by Workers Chemical Protective Clothing Materials
Exposed to Specific Molten Substances to Liquid Permeation-Permeation Cup
and Related Thermal Hazards Method
• F 1052 Practice for Pressure Testing of • F 1461 Practice for a Chemical
Gas Tight Totally Encapsulating Protective Clothing Program
Chemical Protective Suits • F 1494 Terminology Relating to
• F 1060 Test Method for Thermal Protective Clothing
Protective Performance of Materials for • Test Methods for Measuring the
Protective Clothing for Hot Surface Performance Characteristics of Exhaust
Contact Valves Used in Chemical Protective Suits
• F 1154 Practices for Qualitatively (New Standard)
13.1 Safety and Protective Textiles 449
• Practice for Determining the Resistance Goldman identified six parameters that should
of Chemical Protective Coveralls, Suite be taken into account in predicting the heat stress
or Ensembles to Inward Leakage to of the garments: air temperature, ambient air
Liquids under Dynamic Conditions (New motion, ambient vapor pressure, mean radiant
Standard) heat temperature, task work load and the type of
• Practice for Evaluating Resistance of clothing worn by the worker [27]. These pa-
Protective Clothing Materials to rameters affect the body temperature, heart rate
Permeation by Liquid Chemical Warfare and skin dampness which are important for com-
Agent (New Standard) fort and health.
party certification is becoming important for this ways: increasing fabric weight, using inherently
purpose. cut resistant materials and using composite
Hazardous material response, toxic waste yarns. Heavier fabrics provide better cut resis-
dump cleanup and manufacture of some chemi- tance, however increased weight may adversely
cals require complete encapsulation of workers. affect the user performance. Materials such as
A typical totally encapsulating chemical protec- extended chain polyethylene and para-aramid
tive (TECP) suit is made up of several com- offer high inherent cut resistance. By wrapping
ponents: self-contained breathing apparatus, cut resistant fibers around steel or fiberglass
lens, suit closure, vent valves, suit membranes, yarns, composite yarns with excellent cut resis-
seams, gloves and boots. tance can be obtained [30].
Factors to consider when selecting a protec-
tive garment include type of application, level of
protection and type of chemicals, productivity, 5.1 Gloves
cost, acceptance and durability (decontamina-
tion versus reuse). Different garments provide Glove selection must be done according to the
different degrees of protection, have different end-use requirements. The requirements for a
sealing properties, etc. Their selection also surgeon's glove and sheet metal worker's glove
depends on whether respiratory equipment is are different. Gloves should be comfortable and
used or not. The goal is to provide just the right should not hinder the wearer's manual dexterity
amount of protection in order to minimize cost in performing his or her job. Gloves made of
and maximize production by acceptability. continuous filament yarns like nylon and
polyester are suitable for clean rooms and paint
shops since they are lint-free.
5. MECHANICAL PROTECTION Standard work gloves made of cotton or
leather provide little cut resistance. A 14-ounce
Industrial textiles are used to protect the para-ararnid glove provides more cut resistance
wearer from mechanical hazards which include than a 30-ounce cotton glove [31]. Gloves made
cut, tear, puncture, splash, impact and abrasion. of composite yarns combining para-aramid or
Textiles for mechanical protection can be extended-chain polyethylene with steel wire or
manufactured from high strength textile fibers fiberglass provide excellent cut protection. They
used alone or with metallic fibers (see section on provide better dexterity and comfort with the
Metallized Fabrics). protection levels of metal mesh gloves.
According to the U.S. Labor Department, Gloves with puncture resistance are needed
each year more than one million workers suffer when dealing with small, pointed objects. For
job related injuries, 25% are to the hands and this type of application, the glove construction
arms [29]. Cut resistant textiles are used for becomes very important. Loosely knit gloves are
many applications including food preparation, not suitable for puncture resistance. Tightly
construction, forest services, utility works, woven fabrics made of strong fibers increase
metal works and tree trimming among others. puncture protection. Leather also provides punc-
The use of protective gloves, aprons, sleeves and ture resistance because of its dense, tough sur-
chaps reduce the number of injuries, the severity face. Nonwovens made of metallic and high
of the injury and lost time as well as insurance strength textile fibers provide excellent puncture
and legal costs. resistance. After forming, the web is highly con-
The types of materials used in mechanical solidated and coated. The resulting fabric is
and physical protective clothing include para- suitable for puncture resistant gloves, protective
aramids, high density polyethylene (HDPE), vests and outdoor apparel.
ny Ion/cotton blends in woven and knit configura- For protection against abrasion, glove thick-
tions, as well as specialized fabrics with metal ness becomes important. Leather gloves provide
yarns. the best abrasion resistance followed by synthetic
Cut resistance can be achieved in several fibers.
13.1 Safety and Protective Textiles 451
5.2 Chain Saw Clothing FIGURE 13.18 Chain saw chaps provide effective cut
and slash protection (courtesy of DuPont).
To protect the workers in these situations, rubber injury was negligible. They concluded that more
gloves, dielectric hard hats and boots, sleeve protection is obtained by using two or more
protectors, conductive Faraday Cage garments, fabric layers (Table 13.20).
rubber blankets, non-conductive hot sticks, and Figure 13.19 shows the response of shirts
live line buckets are used. made from 100% ordinary cotton, Nomex® Ill
In January 1994, OSHA issued a new stan- and FR treated cotton to electric arc blast. The
dard, 29 CFR Part 1910, addressing the work shirts were exposed to an average arc energy of
practices to be followed during the operation and 96 cal/cm2 for 116 seconds.
maintenance of electric power generation, trans- Radiation from electromagnetic fields (EMF)
mission and distribution facilities. In the same generated by power lines is another public con-
document, the electrical protective equipment cern. There have been mixed reports about the
requirements contained in the electric power relation between exposure to electromagnetic
generation standard are also revised [34]. fields and health hazards like leukemia and brain
Conductive protective clothing is necessary cancer. It is suggested that the ''Live Line''
for people who work in the vicinity of very technology could be readily adapted for protec-
high-voltage electrical equipment. In addition to tion against EMF radiation with slight modifica-
conductivity, these garments must be flame resis- tions [29].
tant, wear resistant and comfortable. Humans InAprill994, ASTM issuedF 1506, Standard
are sensitive to electrical energy because of their Performance Specification for Use by Electrical
sophisticated nervous system. Conductive pro- Workers Exposed to Momentary Electric Arc
tective materials are made by closely weaving and Related Thermal Hazards [37].
metal and natural or synthetic fibers. These gar-
ments (called "Live Line" garments) were in- 6.2 Electrostatic Protection
troduced in the early 1970s and are still in use
today. A typical protective fabric is woven from Static electricity is an electrical charge at rest
spun yams containing a mixture of fire retardant that is generated by the transfer of electrons. The
textile fibers and stainless steel fibers (8- 12 transfer of these electrons between objects with
micron diameters). It was proved that "Faraday different electrostatic potentials or to the ground
suits" made of fabrics with 25% stainless steel can cause electrostatic discharge. The human
fiber/75% wool blend or 25% stainless steel body, which can be considered a capacitor, may
fiber/75% aramid fiber can be effective at volt- get electrostatically charged. The body transfers
ages up to 400 kV [35]. It should be emphasized its charge to a metallic object upon contact, thus
that the garment protects the wearer from the creating an electrostatic discharge. This dis-
effects of electromagnetic field generated by charge can damage an electronic part, cause an
high voltage in the vicinity of the power line, i.e., explosion in a hazardous atmosphere, cause a
the garment cannot protect the individual if there computer glitch through signal misinterpretation
is direct contact with the high voltage line. and can cause an involuntary reflex leading to
King et al. measured the thermal protective injury. Antistatic garments and materials are also
performance of single layer and multi-layer critical for the space programs [29,38].
fabrics exposed to electrical flashovers [36]. The generation of static electricity caused by
They exposed fabric specimens to a 12 s (720 rubbing two materials together is called the
cycle) arc at a distance of 57 mm from the triboelectric (static) effect. As a result of the
electrodes which created an incident energy flux triboelectric effect, materials can be ranked in
density of 211 kW/m2 • Table 13.19 shows the order of positive to negative charging, which is
results of some of the single layer fabrics they called triboelectric series as shown in Table
tested. All of the fabrics were flame resistant. 13 .21. When any two substances in the list con-
They showed that those parts of the body covered tact each other and are separated, the material
by only one fabric layer were exposed to the highest on the list gains a positive charge.
highest risk of bum injury, whereas for those Table 13.22 shows typical voltage generation
covered with six or more layers, the risk of bum during daily life. Since electric parts can be
TABLE 13. 19 The Thermal Protective Performance (TPP) of Single Layer Fabrics (copyright ASTM {36]).
Cotton Shirting 2/1 twill Proban~ 0.51 177 34.1 2.4 0.46
Cotton Drill 3/1 twill Proban 0.65 288 32.7 4.7 0.92
Cotton Satin 4/1 satin THPOH-NHJ 0.73 328 52.6 4.7 0.83
Cotton Denim 3/1 twill Proban 0.81 348 28.9 4.7 0.89
Cotton Brushed 4/1 twill Proban 1.12 414 89.3 5.5 1.26
Cotton Satin 4/1 satin P44 0.66 429 87.2 4.4 0.95
Cotton Denim 3/1 twill Proban 0.93 491 84.1 5.6 1.12
15/85 P/C Denim 211 twill Proban 0.75 361 28.2 4.1 0.84
15/85 PIC Denim 2/1 twill P44 0.66 453 31.2 5.2 1.29
Wool Suiting 2/2 twill FR 0.68 262 14.3 4.6 0.95
60/40wooll
Cordelan~ Serge 2/2 twill 0.61 243 55.2 3.9 0.97
60/40 Cordelan~/
wool Suiting 2/2 twill 0.60 274 23.0 4.4 0.98
Aramid Nomex~m 1/1 plain 0.58 178 87.9 4.1 0.72
50/50 Kevlar~/Nomex aramid 1/1 plain 0.64 250 83.7 4.1 0.77
Aramid Nomexm 1/1 plain 0.89 293 88.3 4.7 0.90
Aramid (reclaimed) Needlepunched 3.65 353 26.7 6.1 1.41
felt
Aramid Norfab~ 1/1 plain 2.45 747 77.2 9.4 1.77
Glass 1/1 plain 0.28 205 92.1 4.5 0.77
Glass 1/1 plain 1.53 646 68.0 4.9 0.84
Glass and A1 foil 111 plain 1.42 677 95.9 15.7 2.80
Novoloid Kynol~ Needlepunched 2.50 157 49.2 3.8 0.69
felt
Novoloid Kynol 1/1 plain 0.39 163 46.7 2.4 0.45
Novoloid/aramid Kynol 1/1 plain 0.54 201 46.6 2.4 0.44
Novoloid/glass Kynol 1/1 plain 2.11 561 52.4 5.1 1.07
Polybenzimidazole PBI 2/1 twill 0.95 308 27.5 4.1 0.59
Oxidized acrylic Pyron® 2/1 twill 1.28 419 14.3 3.9 0.73
Modacrylic SEf® 2/1 twill 0.52 217 24.7 2.3 0.43
~
01
~
.j:o.
01
.j:o.
TABLE 13.20 The TPP Ratings of Two Layer Assemblies (copyright ASTM [36]).
15/85 Polyester/
FR cotton 361 0.84 FR Cotton 177 0.46 538 6.7 1.67
15/85 Polyester/
FRcotton 361 0.84 Aramid 178 0.72 539 7.3 1.81
15/85 Polyester/
FRcotton 361 0.84 Novoloid 163 0.45 524 7.2 1.56
FRWool 262 0.95 FR Cotton 177 0.46 439 7.6 1.55
FR Wool 262 0.95 Aramid 178 0.72 440 6.3 1.31
FR Wool 262 0.95 Novoloid 163 0.45 425 6.3 1.31
Aramid 293 0.90 FRCotton 177 0.46 470 11.8 2.19
Aramid 293 0.90 Aramid 178 0.72 471 6.5 0.97
Ararnid 293 0.90 Novoloid 163 0.45 456 7.3 0.98
PBI 308 0.59 FR Cotton 177 0.46 485 8.1 1.20
PBI 308 0.59 Aramid 178 0.72 486 10.3 1.47
PBI 308 0.59 Novoloid 163 0.45 471 8.5 1.32
Before Arc Blast NOMEX"III
FIGURE 13.19 Response of shirts made of different fabrics to an electric arc blast. Ordinary 100% cotton shirt 1s shown
before, during and after arc blast. Nomex® Ill and FR treated cotton shirts arc blast are shown on the right (courtesy of
DuPont).
455
456 SAFETY AND PROTECTIVE TEXTILES
TABLE 13.21 Triboe/ectric Series [29}. introduced in the medical market in the late
Positive ( +) Acetate 1960s. They were later adapted to electronics
Glass manufacturing in clean rooms and other areas
Human hair including emergency chemical response and
Nylon cleanup, fuel or ordnance handling operations
Wool
and general chemical process industry.
Fur
Aluminum In the late 1960s, NASA developed a method
Polyester to test the static charge generation and discharge
Paper rates on flat plastic and textile materials. Re-
Cotton cently, an ASTM F-23 committee has developed
Wood a new standard for evaluating triboelectric
Steel
charge generation on protective clothing
Acetate fiber
Nickel, copper, steel materials [Draft ASTM F 23.20.05, Resistance
Brass-stainless steel of Protective Clothing Materials to Triboelectric
Rubber (Static) Charge Generation]. This method mea-
Acrylic sures the maximum charge accepted and rate of
Polystyrene foam
discharge for static produced on materials by
Polyurethane foam
Saran
rubbing friction. Measurement of material sur-
Polyethylene face resistivity and electrostatic decay has been
Polypropylene by the common test methods used to evaluate
PVC (vinyl) material static electric hazards. AATCC Test
Negative (-) Teflon Method 76 is used to measure surface resistivity.
Federal Test Method Standards (FTMS) 191A,
5931 and 10 IB, 4046 provide methods to
damaged by electrostatic discharge voltages of measure electrostatic decay of fabrics and plas-
100 volts or less, static control is extremely tics. Table 13.23 shows the ranking of some
important for the electronics industry. chemical protective clothing materials in the
Using textile fabrics made of intimately market for triboelectric charge.
blended metal and textile fibers is an effective
way to control static buildup. Garments made of
these fabrics dissipate the static generated by the 7. CLEAN ROOM TEXTILES
wearer before it reaches dangerous levels. Con-
tinuous multi-filament metal fibers can also be Clean room (anticontarninant) textiles protect
woven into fabrics at intervals to control static. the environment from the wearer. The human
High concentration spun yarns are also used for body sheds one billion skin cells every day. The
this purpose. body and its clothing also carry a good amount
Metal fiber content is usually varied between of dust, ions, hair, textile lint, cosmetics, per-
1% to 5% depending on the hazard level of fume, and tobacco smoke, all of which are in-
application. A typical antistatic garment is a compatible with high-tech production methods
blend of 65% polyester/32.5% cotton/2.5% [39]. Clean room items are used in clean rooms
stainless steel fabric. Antistatic garments were to keep the atmosphere clean and prevent con-
65-95% 10-20%
Action Relative Humidity Relative Humidity
Wovens Laminates
Nonwoven
High- PTFE
Industry Herringbone Taffeta Twill Density Spunbonded Polyolefin Urethane
Integrated circuit X X X X
Disk drive X X X X
Pharmaceutical X X X X X
Aerospace X X
Electronic assembly X X
Optics X X X X
Food X X X X
Automotive X
its proxumty. The radiant energy absorbed by been the fabric of choice for nuclear protective
tissue from a distance will cause damage even if wear. Poly/cotton fabrics represent 80% of all
the radioactive dirt does not touch the human nuclear protective wear in the United States.
tissue. The techniques used for protection from More recently other synthetic fabrics have been
gamma and some beta radiation-emitting radio- introduced to the nuclear protective wear
active materials are contamination control, time, market. One example is 99% nylon/1% carbon
distance and shielding. Shielding is done by plac- fabric which offers better performance over
ing a dense (heavy) radiation barrier such as lead poly/cotton fabrics.
between the radioactive dirt and the worker [41]. There are no regulatory requirements for
Nuclear protective wear fabrics are made of specifications of radiation protection clothing.
cotton, polyester/cotton or nylon/polyester [42]. Each institution is responsible for protecting
Until the 1980s twill or sateen cotton fabrics their employees. As an example, Table 13.25
were the main material for all nuclear protective lists the types of protective garments used at
wear. Recently, polyester/cotton (65/35) has Duke Power Co.'s (Charlotte, NC) nuclear sta-
TABLE 13.25 Typical Examples of Clothing for Radiation Protection (Duke Power Co. [43]).
Drylete<~> Hind Combines hydrofil nylon and Skiwear, running and cycling apparel
hydrophobic polyester to push mois-
ture away from the body and then pull
it through fabric for quick drying
Gore-Tex<~> W. L. Gore The original waterproof/breathable Outerwear, gloves, hat, footwear, run-
laminated fabric with pores large ning and cycling apparel
enough for water to escape, small
enough to block rain
Hydrofil® Allied A new super-absorbent hydrophilic Linings, long underwear, cycling ap-
(water-loving) nylon that sucks mois- pare!
ture away from skin
Silmond® Teijin A durable water repellent and wind- Outerwear
proof fabric made from polyester
microfibers
Supplex® DuPont A strong, quick drying nylon fabric, Outerwear, skiwear, running and cy-
in smooth or textured weaves, that cling apparel
feels like cotton
Synera<~> Amoco A strong, lightweight polypropylene Long underwear, jacket linings
fabric that transports moisture
away from skin
ThcteJ<I> DuPont Extremely soft, quick drying nylon Outerwear, skiwear, running and cy-
in smooth or textured versions cling apparel
Thermo lite® DuPont An insulation made of polyester Skiwear, climbing apparel
fibers that have been coated to
make them slippery and more
drapeable.
Thermo loft® DuPont A semithick insulation that contains Skiwear, outdoor apparel
hollow polyester fibers that trap
warm air
Thinsulate® 3M Thin insulation made of polyester Skiwear, gloves, footwear
and polypropylene fibers
Thintech® 3M A waterproof/breathable laminated Skiwear, outerwear
fabric that is highly resistant to
contamination by determination
by detergents or perspiration
tions. Protective garments for radiation include and hair from contamination. Cotton and dis-
coveralls, head covers and hoods, gloves, shoe posable hoods are used. Gloves can be rubber or
covers, rain suits, lab coats, modesty tops and cotton. Rubber shoe covers are worn over dis-
gym shorts. Respiratory protection equipment posable shoe covers. Plastic rain suits are used
may be necessary when contamination levels when water may be involved. They are also used
(loose) are greater than 25,000 disintegrations in highly contaminated areas to provide maxi-
per minute (dpm)/100 cm2 for heavy work and mum protection from contamination. Lab coats
100,000 dpm/cm2 for light work. are used where the chance of contamination is
Coveralls provide general protection for the low. Modesty tops and gym shorts are worn
whole body, including the arms, legs and torso. under protective clothing [43].
Cotton coveralls are used for normal to heavy Non-ionizing radiation hazards may be en-
work conditions. Disposable coveralls may be countered around microwave relay towers, high-
worn over personal clothing for low-level con- voltage transmission lines (see the section on
tamination. Hoods are worn to protect the head Electrical Protective Clothing), and even among
13.1 Safety and Protective Textiles 461
those who work around computers and radiating The figure of the duck down shows a branch
electronic equipment. Metallized materials that that comes from waterfowl down quill. The
provide dissipation of radio frequency and larger branch fibers give loft and compressional
electromagnetic radiation are being used for non- resistance while the smaller fibrils exemplify
ionizing radiation protection. many micro-spaces of trapped air that give the
down its insulating abilities. The figure of the
9. THERMAL INSULATION Primaloft® fibers and air spaces shows how it is
(PROTECTION FROM COLD) very similar to that of the duck down in terms of
size, number and distribution. Dead air space is
Table 13.26 lists some of the insulation an effective insulator; more important than the
materials on today' s market. The list includes the fiber material itself. Its unique characteristics
product name, the manufacturer of the product, result in giving similar control of convective and
different characteristics of the fiber and the radiant heat transfer, overall insulating perfor-
product's end uses. mance that is just as good or maybe even better
One new advancement in fiber technology in- than that of down and other synthetic insulators.
volves the invention of a unique, patented ther- Primaloft' s microscopic air pockets help it to
mal insulation of a fine bonded polyester called resist the passage of water while allowing body
Primaloft®, manufactured by Albany Interna- moisture, in the form of water vapor, to escape.
tional. Primaloft has been proven to be superior There are millions of these tiny air pockets that
to fme goose down. It is used for insulating such cause the Primaloft® to entrap heat and minimize
things as sleeping bags and snow skiing clothes convective and radiant heat transfer. Its smaller
because it is lightweight, durable and maintains fibers help to create a soft hand, exceptional
its insulating properties even when wet. Pri- drape and great compressibility.
maloft® carries no more than 20% of its own Albany International has shown with a Tooth-
weight in moisture. This is minute when com- pick Theory that there can be a perfect balance
pared to 108%-1,000% for synthetics. Prima- between density and loft (Figure 13.22). The
loft's insulating value when wet is also better Toothpick Theory consists of imagining heat
than that of goose down. Figure 13.21 shows the traveling around one pencil to escape. The heat
comparison of several insulation material dia- would have to travel from distance A to B, but
meters. would have an easy path to travel between these
FIGURE 13.21 SEM of various insulation materials: duck down (left), Primaloft® (center), and synthetic insulation
(courtesy of Albany International).
462 SAFETY AND PROTECTIVE TEXTILES
........
••••••••
••••••••
I I
Toothpicks c A Pencil
sonal safety products. Fabrics are covered with
reflective microprism sheeting for high visibility
personal safety items. These items are used by
pedestrians, highway workers, cyclists, joggers,
t t t t Dst
a = a a =
hikers, police, firemen and other professionals.
State Departments of Transportation, the Oc-
cupational Safety and Health Administration
FIGURE 13.22 Toothpick theory (Albany International). (OSHA) and the National Fire Protection As-
sociation (NFPA) require the use of reflective
material on workers' garments. Airlines, law
two points. Then imagine the heat having to enforcement and emergency medical services
travel through 15-20 toothpicks from distance also use reflective materials.
C to D. It is more effective for an insulator that In a recent development, 3M's Scotchlite®
the heat travel the shorter distance through reflective transfer film was micro-slitted to form
15-20 times more fibers. narrow retro-reflective yams. These yams can
Insulation textiles for military applications are be woven, knit or braided into fabrics. 3M's
explained in Chapter 11.0, Military and Defense Scotchlite® 8710 retro-reflective transfer film
Textiles. has 50,000 tiny, highly reflective glass beads per
square inch. These glass beads, due to their
round shape, reflect light back to its source [47].
10. HIGH VISIBILITY TEXTILES Photoluminescent or phosphorescent mate-
rials have the ability to absorb daylight or ar-
Studies have shown that reduced visibility tificial light, store its energy and emit a
contributes to fatal pedestrian accidents. It was green-yellow glow in darkness. High quality
reported that night time vehicles strike and kill photoluminescent safety fabrics remain visible to
more than 4,000 pedestrians and injure more darkness-adapted eyes for up to six hours [48].
than 30,000 pedestrians annually in the United Zinc-sulfide crystals, which are non-radioactive
States [45]. It is believed that high visibility and non-toxic pigments, provide the visibility in
materials (HVM) assist in avoiding worker and dark. They may be recharged repeatedly when
pedestrian deaths or serious injuries. According exposed to light for a few minutes. Photo-
to the National Safety Council, the work-related luminescent fabric-backed vinyl can be sewn on
deaths have declined more than 40% during the uniforms, protective apparel, back supports, etc.
past ten years, from 12 to 7 per 100,000 workers. They are ideal for emergency exits and escape
The use of HVM has at least doubled during the routes (Figure 13.23).
same period [46]. In some applications, a combination of the
Dark clothes reduce and white clothes in- three methods are used for optimum safety
crease visibility at night. For safety purposes, it during the day and night.
is necessary to increase visual contrast. The ASTM Subcommittee E-12.08, High
primary technique to increase conspicuity is Visibility Materials for Pedestrian Safety, is
through the use of high visibility materials. working to develop standards for both manufac-
There are three major types of high visibility turing and grading materials.
products:
• reflective materials (they shine when
struck by light) 11. METALLIZED FABRICS
• photoluminescent materials (give yellow
light in dark) As it has been mentioned throughout the chap-
• fluorescent materials (i.e., red-orange is ter, metallized products are used in industrial,
visible during the day) specialty and protective clothing applications.
There are various ways to combine metals with
Textile substrates are used in reflective per- textile materials for specific applications.
13.1 Safety and Protective Textiles 463
11.2 Blending
Bundle Drawing
000 protects astronauts from the harsh environment
of space outside the Space Shuttle' s crew cabin.
The EMU includes many individual components
that, when assembled, form a single space suit
Shaving ""'-../ (Figure 13. 26).
When fully assembled, the EMU becomes a
Shearing
tJ complete short-term, "soft" spacecraft for one
person. It provides pressure, thermal, and
Melt Spun
0 micrometeoroid protection, oxygen, cooling
water, drinking water, food, waste collection
(including carbon dioxide removal), electrical
Melt Extraction
0 c:::J power and communications. Space suits for
space shuttle missions are pressurized at 4.3
pounds per square inch (psi). On earth, the suit
FIGURE 13.25 Typical metal fiber cross sections [49]. and all its parts weigh about 112 kilograms. In
13.1 Safety and Protective Textiles 465
orbit, they have no weight at all, but do retain Protection of the astronaut from micro-
their mass, which astronauts feel as a resistance meteoroid penetration is one of the unique
to a change in motion. functions of the space suit. The average
There are several layers of the space suit. micrometeoroid has a density of 0.5 g/cm3
Table 13.27 lists the shuttle space suit assembly and a speedof20 km/s.
materials and functions. Figure 13.27 shows the
(2) Super insulation layers (aluminized PET,
upper parts of the space suit.
such as Mylar® from DuPont and Hos-
taphan® from Hoechst)- The next five layers
(1) Micrometeoroid/tear protection layer- This
of the Thermal Micrometeoroid Garment
is the outermost layer of the space suit. It
provide the astronaut with thermal protec-
comprises the outer layer of the Thermal
tion. The material in these layers is
Micrometeoroid Garment. This layer is of
aluminized Mylar® film, which is reinforced
Ortho Fabric®, a blend of woven Nomex®
with PET scrim.
and Teflon® with Kevlar® rip stops (a rip stop
The space suit protects the astronaut from
is a fabric design in which strong yams or
extreme outside temperatures ranging from
fibers are placed to prevent tear growth). It
-180°F to 235°F. Inside the SSA, the
protects subsequent layers of the space suit,
temperature may range from 50°F to ll0°F.
namely, the pressure restraint layer and the
pressure bladder, from abrasions and tears. (3) Second micrometeoroid layer (Neoprene®)
466 SAFETY AND PROTECTIVE TEXTILES
TABLE 13.27 Shuttle EMU Space Suit Assembly Materials and Application Functions
(courtesy of NASA).
Ortho fabric (woven Abrasion and tear protec- Thermal control Micrometeoroid protection
Nomex and Teflon with tion for pressure restraint as part of Thermal
Kevlar rip stop) and bladder Micrometeoroid Garment
Aluminized Mylar film Thermal insulation Micrometeoroid protection
reinforced with Dacron as part of Thermal
scrim Micrometeoroid Garment
Neoprene coated nylon Micrometeoroid barrier Inner-liner for
cloth layer Micrometeoroid Garment
Fiberglas 8 ply layup Pressure/load structure for Life support and display Helmet, arm, and lower
hard upper torso module attachment struc- torso attachment
assembly ture and fluids and gas structure
connections
Dacron cloth Pressure restrain/load struc- Single axis joint flexure for
ture for arms, gloves, elbow, wrist, finger,
and lower torso assembly waist, knee, and ankle
mobility
Polyurethane-coated nylon Pressure bladder for arms
cloth and lower torso assembly
Dipped polyurethane film Pressure bladder for gloves
Multi-filament stretch Attachment restraint for Attachment restraint for bio- Attachment restraint for
nylon coolant tubing and ven- medical instrumentation body comfort interlining
tilation gas ducting and radiation dosimeters
Ethylene vinyl acetate Water coolant distribution
tubing for body thermal control
Nylon chiffon Body comfort lining
-As the inner lining for the Thermal vinyl acetate tubing, through which water is
Micrometeoroid Garment, this layer is the circulated to control the temperature.
final barrier of micrometeoroid protection. (7) Body comfort lining (nylon chiffon)- This is
The material is Neoprene® coated nylon cloth. the first layer of fabric touching the
(4) Pressure restraint layer (PET)- This layer is astronaut' s skin. It is made of ny Ion chiffon,
composed of synthetic fabric placed over the a lightweight material, to be as comfortable
pressure bladder fabric to give it additional as possible. It is positioned between the
support and shape. astronaut and the liquid cooling and ventila-
(5) Pressure bladder (polyurethane coated tion garment.
Nylar®)- Pressure bladders are much like (8) Pressure restraint system- The materials
today' s tubeless tires, composed of rubber used for the EMU pressure restraint system
(urethane) to seal in the air pressure and are a composite of items. Airtight linings
nylon to restrain expansion. For the bladder with comfort fabrics are a significant part,
in the space suit, nylon is dipped in but the space suit must also be flexible and
polyurethane a minimum of six times to cre- retain its shape as well as inside pressure.
ate an impermeable barrier between the pres- (9) Gloves- The restraint layer of the EMU
sure of the pure oxygen inside the space suit glove is placed over the bladder (Figure
and the vacuum of space on the outside. 13.28). The bladder is formed when a
(6) Liquid cooling and ventilation garment ceramic cast of a hand is dipped seven or
(ethylene vinyl acetate tubing)- This gar- eight times into a vat containing urethane.
ment covers the astronaut's upper and lower Then the hand-shaped bladder is stripped
body. The garment itself contains ethylene from the ceramic cast and inflated to check
Primary llle Support System Cover
,/~-~
~
~ --
- L~~{ I
- - \ "''""~Tmo .
\
~~~
Glove
-------
~
\
~
Displays and
Control Module
/ \ '
~
/
~
_/
Waisl Bearing
for defects and leaks. The gloves have fin- posure functions in an emergency situation in
gertips of silicone rubber that permit some which the crew must parachute from the orbiter.
degree of sensitivity in handling tools and The suit has inflatable bladders that fill with
other objects. Metal rings in the gloves snap oxygen from the orbiter. These bladders fill auto-
into rings in the sleeves of the upper torso. matically at reduced cabin pressure. They also
The rings in the gloves contain bearings to can be inflated manually during entry to prevent
permit rotation for added mobility in the the crew member from blacking out. Without the
hand area. suit pressing on the abdomen and legs, the blood
would pool in the lower part of the body and The AX-5, a hard, all-metal suit, is being
cause a person to blackout as the space craft developed by the NASA Ames Research Center
returns from microgravity to the Earth's gravity. (ARC) in California. Both suits are being
designed to operate at a pressure of 8.3 psi.
12.4 Textiles for Space Station Specially designed static-free fabrics will be
used in the space station. They have been used
The next generation of space suits is being for the space shuttle program. Figure 13.29
designed for the space station program. The shows static-free woven coated fabric liner for
Mark III suit, a combination of soft and hard the space shuttle' s cargo bay. The liner was in
elements, is being developed at the NASA Lyn- service on Discovery's Hubble Space Telescope
don B. Johnson Space Center (JSC) in Houston. mission.
13.2
References and Review Questions
19. Veghte, J. H., "Functional Integration of 31. Rivet, E. and Blocker, R., ''Factors Affect-
Fire Fighters' Protective Clothing;' in Per- ing Glove Selection;' Safety and Protective
formance ofProtective Clothing, ASTM STP Fabrics, September 1992.
900, R. L. Barker and G. C. Coletta, eds., 32. Turner, R., "PPE for Europe: A Guide on
American Society for Testing and Materials, How to Succeed;' Safety and Protective
Philadelphia, 1986. Fabrics, May 1994.
20. Schroll, R. C., "Emergency-ResponseCPC 33. Jagielski, K., "Market Report: Cut and
Is Last Line of Defense;' Safety and Protec- Slash Protection;' Safety and Protective
tive Fabrics, May 1993. Fabrics, February 1994.
21. Stull, J. 0., "Suitable Suits;' Industrial 34. Federal Registrar, Rules and Regulations,
Fabric Report Review, September 1988.
Vol. 59, No. 125, June 30, 1994.
22. Smith, W. C., "The Protective Clothing
35. Davies, J., "Conductive Clothing and
Market;' Industrial Fabric Products Re-
Materials;' in Performance of Protective
view, September 1988.
Clothing: Second Symposium, ASTM STP
23. Goldstein, L., "Limited Use Protective 989, S. Z. Mansdorf, R. Sager, and A. P.
Clothing;' in Protective Clothing: An In- Nielsen, eds., American Society for Thsting
dustry Perspective, 77th Annual !FA/ Con- and Materials, Philadelphia, 1988.
vention, Orlando, October 1989.
36. King, M. W., "Thermal Protective Perfor-
24. Henry, W. N. III, "How Protective Is mance of Single-Layer and Multiple-Layer
Protective Clothing?" in R.L. Barker and Fabrics Exposed to Electrical Flashovers;'
G. C. Coletta, eds., Performance ofProtec- in Performance of Protective Clothing:
tive Clothing, ASTM STP 900, 1986, p. 57. Second Symposium, ASTM STP 989, S. Z.
25. Winter, J. E., ''Protective Clothing Permea- Mansdorf, R. Sager, and A. P. Nielsen, eds.,
tion Testing: Calculations and Presentation American Society for Testing and Materials,
of Data," in R. L. Barker and G. C. Coletta, Philadelphia, 1988.
eds., Performance of Protective Clothing, 37. Baitinger, W. F., "PC Issues Are Hot in the
ASTM STP 900, 1986. Electrical Utility Business;' Safety and
26. Smith, W. C., "Thermal Resistance in Protective Fabrics, January/February 1995.
Limited Use Garments," in Protective
38. Stull, J., "Measuring Static Charge Genera-
Clothing: An Industry Perspective, 77th An- tion on PC Materials;' Safety and Protective
nual /FA/ Convention, Orlando, October Fabrics, August 1994.
1989.
39. Ravnitzky, M., "Toward Cleaner Clean
27. Goldman, R. F., "Heat Stress in Industrial
Rooms;' Safety and Protective Fabrics,
Protective Encapsulating Garments;' in
March 1993.
Protecting Personnel at Hazardous Ubste
Sites, Butterworth, Stoneham, MA, 1985. 40. Spector, R., "A Study in Cleanroom
Fabrics;' Safety & Protective Fabrics, Au-
28. Honnigford, L., "Safety and Protective
gust 1994.
Clothing, Limited-Use Sees Growth;' in
Protective Clothing: An Industry Perspec- 41. Hardy, B., " Protection Methods Reduce
tive, 77th Annual !FA/ Convention, Orlando, Contamination;' Safety and Protective
October 1989. Fabrics, November 1993.
29. Toon, J. J., "Metal Fiber Fabrics for 42. Bugge, G., "Cleaning Nuclear Protective
Mechanical, Electromagnetic and Electro- Wear;' Safety and Protective Fabrics, IFAI,
static Protection;' Textile Technology Forum May 1994.
'94, IFAI, Indianapolis, IN. 43. Courtney, G. L., "Protective Clothing
30. Phillips, C. and Bledsoe, E.,' 'An Update in Specification for Radiation-Contaminated
Cut-Resistance Technology;' Safety and Environments;' Safety . and Protective
Protective Textiles, May 1993. Fabrics, March 1993.
472 SAFETY AND PROTECTIVE TEXTILES
44. Walzer, E., "Dressed for Chill;' Health, 5. What are the two ways to achieve flame
November 1990. resistance in textile materials? Explain. Dis-
45. DeMaio,J., "SeeandBeSeen;' Safetyand cuss the advantages and disadvantages of
Protective Fabrics, September 1992. both methods.
46. Lesley, G., "Correlating HVM Usage with 6. Which is more critical for fire resistance:
Worker Accidents;' Safety and Protective fiber material or fabric structure? Why?
Fabrics, August 1994. 7. List the major tests for flame resistance.
Explain three of them.
47. Textile Protection, America's Textile Inter-
8. Explain the structure of the fire fighter suit?
national, January 1995.
What type of fiber materials are used?
48. Batzke, M., "See, and Be Seen, in the 9. What is the purpose of chemical protective
Dark;' Safety and Protective Fabrics, IFAI, clothing? What are the differences between
May 1994. flame resistant clothing and chemical pro-
49. Toon, J. J., "An Overview of Metal Fiber tective clothing?
Production;' Safety and Protective Fabrics, 10. What are the types of chemical protection?
August 1994. Explain the textile material requirements for
50. Spacesuit Guidebook, NASA, July 1991. each.
51. Spacesuit Wall Chart, NASA, January 1990. 11. How does the cut resistant clothing work?
52. Gomes, C. A., "Protected in Space;' Safety Explain the ways to achieve cut resistance.
and Protective Fabrics, September 1992. 12. What are the requirements for electromag-
netic and electrostatic protection? Explain
53. ''Wardrobe for Space: From Shuttles to Sta-
the textile materials used for each type of
tions;' Safety and Protective Textiles, March
protection.
1993.
13. Define a clean room textile. What kinds of
fabrics are used for clean rooms?
2. REVIEW QUESTIONS 14. What are the characteristics of textile
materials for radiation protection?
1. Summarize the application areas for safety 15. What is the most important factor for protec-
and protective textiles. State the major re- tion from cold? Explain the Toothpick
quirements for each application area. Theory.
2. Define high temperature textiles. What are 16. What is the significance of high visibility
the major requirements for high temperature textiles? How is high visibility achieved?
textile materials? 17. List the application areas of metallized
3. What is the significance of limiting oxygen fabrics. Explain the major methods to pro-
index (LOI)? duce metallized fabrics.
4. What are the factors to consider when select- 18. Explain the major characteristics of a space
ing a high temperature fiber for a specific suit.
application?
14.0
SPORTS AND RECREATION TEXTILES
14.1
Sports and Recreation Textiles
S. ADANUR
4. BASEBALL This is why the aluminum bat has cut into the
wooden bat market. But the aluminum bat is not
Baseball, though an extremely traditional the preferred bat of baseball players. They
sport, has not escaped the invasion of high tech- choose wooden bats over aluminum bats because
nology. It, along with many other sports, has had they are not cold to the hand, have a more natural
the privilege of experiencing today' s innovative feel and make the sound people are used to hear-
and advanced scientific inventions. The technol- ing when a baseball is hit.
ogy in baseball involves the ever-important Engineers have worked to develop a com-
baseball bat. posite baseball bat that delivers the look, feel,
White ash has been the overriding choice of sound and performance of traditional hardwood
bat manufacturers for decades because of its high bats with the durability of metal bats. Two im-
impact resistance and strength-to-weight ratio. portant types of composites have been de-
However, the decline in quality and availability veloped- the graphite composite bat and the
of ash in northeastern forests has led the bat wood composite bat. The graphite composite bat
manufacturers to look elsewhere for more use- is made on automated filament winding ma-
ful, quality products from which to develop bats. chines. These machines precisely position strong
Three season (20°F) 5'11" 6'6" 61" 44" llblloz lib 12 oz 21b 13 oz 21b 14 oz
Winter (-5 °F) 5'11" 6'6" 61" 44" 2lb 7 oz 2lb 9 oz 3lb 12 oz 3lb 15 oz
Expedition (- 30°F) 5' 11" 6'6" 63" 46" 3lb 9 oz 31blloz 41b 14oz Sib Ooz
480 SPORTS AND RECREATION TEXTILES
graphite and glass fibers that are subsequently resin bonded matrix of woven ceramic, graphite
bonded together with epoxy resin to create a and boron fibers together with fiberglass and
hollow bat structure. Kevlar®. The way composites are constructed
The wood composite bat is made of a high allows them to be more important in the racket's
strength inner core fabricated from resin impreg- performance than any one material such as wood
nated synthetic fibers and yarns, integrated with or aluminum. Fibers crosslink with the resin
an ashwood outer surface. The wood composite when bonded together to form the racket's
bat has performed remarkably like a traditional durable frame. The various composite materials
hardwood bat but is far less likely to break than are pressed into a resin film and then heated. As
a solid wooden bat. One of the latest versions of this mix warms up, the different fibers begin to
this bat was tested and it withstood more than crosslink making them stronger than any pre-
3,000 hits with no drop in performance. Some of vious material used for this application. These
the bats even lasted for thousands of hits. rigid materials produce both the lowest weight
Bat design requires extensive testing on the and high strength while simultaneously reducing
field and in the laboratory. An engineer must look the vibrations of the racket.
at several different aspects of the dynamics of the Graphite is the current top choice material that
bat, such as the weight distribution, the place- combines both lightweight and durability in-
ment of center of percussion, the cosmetics, the creasing both power and control of the racket.
handle size, the baseball organization rule con- The drawback to graphite is simply the cost of
straints, the sound of the bat and the impact of the material. Slazenger' s first graphite racket
the ball on the bat. The bats are subjected to arrived in 1976, made in a German factory that
numerous trials and repeated impacts along their normally produced graphite composite skis.
lengths in order to confirm structural integrity, to Graphite fiber rackets are up to five times
find the bat's bending frequencies and to develop stronger than aluminum ones and thirty times
data regarding the behavior of balls as they stronger than the traditional wooden racket.
rebound off the bat. Other space aged fibers such as Twaron®, and
The new and exciting technology within the boron are combined with high performance car-
sport of baseball is promising to the textile in- bon producing an excellent racket; again the cost
dustry. There are still many challenges facing the is high especially for the recreational player.
engineer in the area of the composite-style bats Boron fiber composites are six times stiffer than
and they are making innovative discoveries steel and five times stronger than aluminum.
every day. High performance industrial textiles allow
special features to be molded into the equipment
5. TENNIS rather than being added later, and this cuts the
price of production while maintaining the re-
Today, tennis rackets are going through some liability of composites. In the highly competitive
remarkable changes in the design of the racket. tennis racket industry, manufacturers are con-
Recently, sporting goods manufacturers began stantly searching for better, stronger and more
combining computer aided design techniques durable fibers to mold into a new and improved
with breakthroughs involving materials, racket racket.
shapes and control of string tension. However, Tennis balls are made of woven and needled
the most significant of these changes is material tennis felts. Slit film fabrics are used for wind
selection. Yamaha International put the first com- break screening for outdoor courts. Tennis net is
posite fiberglass tennis racket on the market in made of very durable polyethylene monofila-
1974. Since then there has been tremendous ment fibers.
growth in the use of many different textile com-
posites in racket design. In fact, manufacturers 6. FOOTBALL
combined fiberglass with other fibers- graphite
and ceramics-in an attempt to increase the Manufacturers of footballs realized that there
strength and durability of the rackets. was a problem with catching the traditional
These improvements led to the use of a new "pigskin" ball during cold weather. For that
14.1 Sports and Recreation Textiles 481
Not wanting to use steel, manufacturers of these impregnated composite attaches to the frame in
"in-line" skates used. a glass reinforced ther- front of the seat. This in turn compresses to
moplastic resin. This resin met both the very absorb the shock when the front wheel of the
rigid requirements for impact strength and stiff- bicycle hits a bump. The elastic properties of the
ness. composite enable the frame to elongate and
The in-line skate frame experiences par- shorten, while the coil spring compresses and
ticularly high stresses because of the way it is extends. An epoxy impregnated continuous flla-
designed. Unlike conventional skates, which dis- ment glass fiber composite forms the inside of the
tribute the force of the person equally among four system. The composite attached to the frame of
wheels, the in-line skates have concentration of the bicycle acts as a spring to permit frame elon-
stresses on centered wheels. This is a consider- gation and energy storage. This energy storage
able amount of stress to contend with. Rol- means the cyclist can exert less power and
lerblade engineers originally used steel for this receive better benefits. In fact, all the energy put
application. The steel provided large flexural into the bicycle is returned.
and tensile capabilities along with the needed High performance composite materials which
impact resistance. The drawback to using steel is have both flexural strength and fatigue resistance
obviously the weight. Switching to the composite increase the durability of bikes. These com-
thermoplastic resin reduced the weight of each posites are now used widely in mountain bikes
skate 50%. and racing bikes.
The composite also helped to simplify the
skate's assembly. By reducing the number of
bolts and washers, the manufacturers were able 10. MARINE PRODUCTS
to produce the rollerblades faster. Since com-
posite material can form a more complex struc- Textile materials are used in various marine
ture than the steel, the reduction of pieces can products for function and fashion purposes in-
take place. cluding mooring covers, boat tops, shading, sail
Along with these improvements over the steel covers, etc. Table 14.2 lists major properties of
version of the skate, chemical resistance and textile marine products. Figures 14.10 and 14.11
abrasion resistance have increased. Composites show typical uses of textile materials in marine
also lend themselves well to acquiring bright applications. Table 14.3 shows typical specifica-
colors that steel could not produce. tions of an awning marine fabric.
Structural cores of skateboards are made with Industrial textiles made their way into the sail-
layers of reinforcement fabrics impregnated with boat industry a long time ago. The requirements
resins. The resulting board is strong, yet for these textiles include low stretch, high
lightweight. strength failure along with good resistance to
weather, aging and chemicals. Of course, the
material must be waterproof as well.
9. BIKES Four types of sailcloth account for more than
ninety percent of the textiles manufactured for
Bicycling enthusiasts believe that bike frames sailcloth in the United States [4].
should be as rigid as possible to prevent the loss
of energy and unstable steering. Going com- (1) Woven polyester fabric- Has low stretch
pletely against this theory, bicycles have been achieved with elimination of crimp; high
produced consisting of completely ''elastic'' tenacity and high initial modulus yams are
material. The flexible frame allows for the ab- used with a plain weave
sorption of the shocks of a mountain bike. (2) Woven nylon fabric-Main properties are
A cable and spring system replaces the frame's lightweight, limited porosity, good breaking
down tube. The cable connects the top of the and tear resistance using a plain weave and
frame and a conventional coil spring to the bot- can be coated to control porosity
tom. A separate spring made of an epoxy resin (3) Laminates with oriented polyester fllm
TABLE 14.2 Major Characteristics of Marine Products (courtesy of
Marine Fabricators Association, /FA/).
Product Advantages Disadvantages
483
~
(X)
~
r - -_----
---~------
f:~:ETJ2¥tr5
~
Aft Deck Bow Seat
Enclosure Cover
Aft California Dodger
Tee Top
Curtains Side Curtains
·'"";
\=
::> ::::::::::~
BY
Traditional Dodger I Sunshade
Drop Curtain
Cockpit Cover
I I
I :
I
1 -"'
l"j\ Sail Cover\ _
-rJ
~<== ~~~:=;;>
b-
?
= - ~ = -~
\;-,~,~= . Ccc~ ~ c:__ -
Cover
California Dodger I Bimini I Enclosure
Camper Enclosure
Travel Cover
r ll~l I \
~~-~--------------
~ ____ ~7 - ...
~1
,..._- ~. __ B. imini Top Mooring Cover Cover_- i_'"",_.,._,""~ Capratl
,(r"'.=t'<f:~""~~}~~~- ,,_ "'- Covers
~. :(~:r~.,~til~ ~-cf'::>
c:::~~/
Rigid
Support-- •. -~ ~;1, ~:~ -":.>-
~~- ~~-o-c-~~~~!ir~·-='c
Pedestal Hatch Windlass
Cover Cover Cover
FIGURE 14.10 Schematics of typical uses of marine fabrics (courtesy of Marine Fabricators Association, IFAI).
14.1 Sports and Recreation Textiles 485
FIGURE 14.11 Application of textiles in boats (courtesy of March em Coated Fabrics, Inc.).
(4) Exotics such as carbon fiber and layered is also applied to sailcloth for high performance
composites-The common characteristic of quality for yacht sails.
these fibers is the relatively high cost. Coated fabrics are used in inflatable boats and
other marine applications (Figure 14.12).
Spectra®, a high performance polyethylene
fiber from AlliedSignal, is widely used in sail- Diving Suit
cloth due to its high strength and low creep under
constant use. It is also suitable in rope and cord- A typical scuba diving suit is made of
age uses. Spectra® has good abrasion and fatigue laminated elastic products. The composite is
resistance. Carbon fibers are used in high perfor- made up of two stretch fabrics each adhesively
mance sailboats such as the Stars and Stripes laminated to both sides of a urethane film. The
which won the America's Cup in 1988. Kevlar fabrics are composed of nylon and spandex and
FIGURE 14.12 Inflatable boats for leisure purposes (courtesy of Reeves International).
486 SPORTS AND RECREATION TEXTILES
the adhesive utilizes a dot matrix to allow for as such as concrete. If used outdoors, the founda-
much elasticity as possible. The product is tion should provide water drainage. Artificial
waterproof and breathable since it passes mois- playing surfaces can be permanent or roll-unroll
ture vapor. type to accommodate different sports.
Artificial fabrics with felt-like surfaces consist
of a dense nonwoven top layer and a shock ab-
11. TEXTILES IN SPORTS SURFACES sorbing base as shown in Figure 14.14. The felt
is usually made of densely needlepunched syn-
Artificial sports surfaces were developed to thetic fibers such as polypropylene. The fibers
replace natural grass which is expensive to estab- are fusion-welded to prevent fiber loss. In some
lish and maintain. Compared to natural grass, applications, dense acrylic fibers are needled
textiles offer the advantages of uniformity, all- into a woven polypropylene base fabric which is
weather playing surfaces and constant perfor- laid on a polyester or polyamide fiber needled
mance with little deterioration [5]. polypropylene base fabric.
Basically two types of textile products have Sometimes, soil under the natural grass is rein-
been developed to replace natural grass: textile forced by a synthetic fiber web. This can be done
pile" carpet" (artificial grass) and felt-like tex- in two ways: (1) natural grass turf is rolled back
tile structures. Pile carpet-type surface was and a fibrous web is placed under it (2) the web is
developed first. In the early 1960s, Monsanto laid under the soil and the soil is seeded. The
produced AstroTurf artificial playing surface. fibrous web is flexible, rot-resistant and porous
The pile fibers, which are tape-like fibers made which allows grass roots to develop within and
of nylon 6,6 for wear resistance, are knitted into through the web. The fibrous web stabilizes the
a tough backing fabric as shown in Figure 14.13. soil, prevents grass from being uprooted during
The base fabric, which is generally made of play, reduces surface damage and improves
polyester tire cord yarns with high strength, is natural grass growth and turf recovery.
laid on a foam underpad that provides cushioning The major requirements of artificial playing
and provides safety against hard falls. The pile surfaces are durability, wear resistance, resis-
fibers are crimped to improve resiliency and tance to damage, stain resistance and clean-
increase density for uniform and consistent ability. For outside use, the fibers must be
bouncing of the ball. The whole assembly of resistant to photochemical degradation, and
carpet and cushion is placed on a firm foundation biodegradation (resistance to fungi and insects).
drainage
FIGURE 14.17 Hot-air balloon (courtesy of Queen Light Electronic Ind., Ltd.).
488
FIGURE 14.18 The Crocky.Woc water slide (courtesy of FIGURE 14.19 Educational Softplay materials (courtesy
Airspace USA, Inc.). of Airspace USA, Inc.).
489
490 SPORTS AND RECREATION TEXTILES
propagation of fabric tear. The fabric is coated products produced by various companies. For
with a thin layer of polyurethane to reduce example, DuPont developed the Cordura® fam-
porosity. A typical balloon is made of around 100 ily of fibers in the mid-1970s which are suitable
panels, totaling 1,500 m2 of fabric (Figure for a variety of applications. Cordura® is an air-
14.17). The lift of the balloon is provided by textured, high tenacity nylon fiber. It can be
heating the air inside the balloon with propane blended with Supplex® nylon, Taslan® air-jet tex-
burners. tured yarn, Lycra® spandex or Antron® nylon
which results in high durability and/or quiet
movement. Applications of Cordura® blends in-
13. FABRICS FOR CHILDREN'S FUN
clude apparel, backpacks, boots, camera bags,
AND PLAY
golf bags, handbags, horse blankets, hunting ap-
parel, hunting gear, indoor/outdoor furniture,
Coated and laminated fabrics are used in a
soft-sided luggage, protective covers, shoes, ski
variety of applications for children's fun and
covers, boot bags, sport-bags, totes, duffles, up-
play. Figures 14.18, 14.19 and 14.20 show some
holstery, video and computer bags and wallets
examples.
(Figure 14.21). Recently, DuPont introduced
Cordura® Plus for the leisure fabric market. It in-
14. OTHER FIBERS AND FABRICS creased the performance for soft luggage, back-
packs, camera bags and other leisure applica-
There are several other fabrics for leisure tions.
14.2
References and Review Questions
491
15.0
TRANSPORTATION TEXTILES
15.1
Transportation Textiles
S. ADANUR
3 2 17 18 19
4----------~~47~~
5----------------~ i----~~~~--------20
6 -------,,......-..,=----:
7------r
8
iI
24 28 9 10 11 27 26 16 1315 14
FIGURE 15.1 Application of textiles in cars [3]: 1. saloon roof. 2. sunroof, 3. backing material for interior roof, 4. pad·
ding for sunvisors, 5. covering material for sunvisors, 6. carburetor filters, 7. battery separators, 8. belts and hoses, 9.
door trim, 10. airbags, 11. covering for seat belt anchorage, 12. seat belt, 13. boot trunk liners, 14. boot floor covering,
15. silencer (muffler) wraps, 16. tire reinforcement, 17. inside roof lining, 18. bodywork parts, 19. window frames, 20.
covering for molded seats, 21. upholstery, 22. insulation and sound-proofing, 23. decorative fabric, 24. filters, 25.
molded fuel tanks, 26. polyurethane coated backing, 27. carpeting, 28. backing for tufted carpeting.
Other advantages are better ride at high For example, in 1993, radial passenger tire
speed, better cornering, improved wear re- production totaled 193 million units in the
sistance and road-holding ability. Glass United States and other constructions were
fiber, aramid and steel are used in the belt, 5 million units. Light truck tire produc-
but steel became the dominant material by tion for 1993 was 24 million radials and 4
1990. Radial tires were developed after di- million other constructions. Medium and
agonal and belted bias tires and have taken heavy duty radial truck tires are mainly
over the passenger and truck tire markets. steel carcass and belt. The 1993 production
TABLE 15.1 Fiber Product and Formation/Bonding Methods for Automotive Applications
(Chrysler Motor Corp. {2]).
of these radials was 10 million units com- of textile materials are woven cord fabrics made
pared to less than 2 million units of bias of cords and light filling yarns.
construction. A cord is produced by plying several twisted
filament yarns together. The twist direction of
Table 15.2 lists the angles between the cord each constituent yarn and the cord are opposite.
yarns and tire circumferential centerline for all The three major systems used to form tire cord
three designs. In all tire designs, carcass plies are ring twisting, direct cabling and two-for-one
made of textile materials or steel give the tire its twisting. The twist level is usually high (10
strength. Polyester is the predominant yarn used twists per inch). The cord yarns are then woven
in the United States today as the carcass rein- as the warp of the cord fabrics with a low filling
forcement for radial passenger cars and light count of one to two picks per inch. "Combs" or
trucks. A small percentage of rayon is also used. "thread bars" are used to aid in warp spacing
(ends per inch) uniformity. Usually rapier, air-
2.1 Manufacturing jet and shuttle looms are used for cord fabric
weaving. Filling yarns are very fine compared
Figure 15.4 shows the schematic of the major to warp cords. The major function of the filling
steps in tire manufacturing. Carcass plies made yarn is to maintain the warp spacing during han-
I
Wall
paHern
bracing layers
FIGURE 15.3 Major tire designs. Top: diagonal tire (four-ply construction), tubed. Middle: belted bias tire (two-ply con-
struction). tubeless. Bottom: radial tire (two-ply construction). tubeless (4].
498
15.1 Transportation Textiles 499
~ ~.
GREEN TIRE TIRE
BUILDING m
GUM-INSERT SPLICING BIAS·
CUTTING
CALENDERING
dling of the fabric. The filling yams do not con- yarns are used. Radial tire designs in particular
tribute to the performance of the ply and there- need the elimination of the filling influence. Ex-
fore the tire. Relatively fine filling yams are tensible filling yams consist of a core (undrawn
used to avoid misalignment of the warp cords nylon or polyester filament with up to 200%
during treating and calendering with rubber. elongation) and a cotton sheath. The superex-
The cord fabric is treated with adhesives and tensible core ensures a uniform partition of
calender coated with rubber to a thickness of warp ends as the tire is shaped, and the sheath
approximately 1 mm [4]. Treating the cord also provides sufficient rigidity to enable the fabric
heat sets for physical properties. Once the warp to be processed through treating and calender-
yams are firmly placed in the rubber com- ing, but then breaks during shaping of the tire.
pound, the need for filling yarns ceases, and in Steel cords and some treated textile warp cords
subsequent stages of tire manufacturing the cord are fed directly from a creel through the rubber
spacing changes as the tire is shaped. In fact, calender, thus eliminating the need for filling
the very existence of filling yams may adversely yams. Thble 15.3 shows the properties of poly-
affect the uniform distribution of the tire forces ester tire yarns.
and cord geometry. To avoid this, either the fill- Rayon or polyester cords and steel belts are
ing yarns are broken, or highly extensible filling extensively used in radial passenger tires. Vis-
TABLE 15.3 Typical Physical Properties of High Tenacity Polyester Tire Yarns
(courtesy of Hoechst Celanese).
cose rayon is suitable for both the body and the bead area of the tire where it makes contact with
belt. In bias car and truck tires nylon cord is the the wheel rim. The fabric aids in maintaining
choice of material. Nylon cord is used in radial the desired shape of the bead area as the tire is
truck tires with a steel cord belt. Polyester and cured, and protects the tire during mounting
glass cords are traditionally used in bias and and dismounting on the rim. The chafer also
semiradial car tires, with polyester cord in the resists abrasion and degradation of the bead
body, and glass cord in the belt of the tire. How- area during the life of the tire.
ever, by the late 1980s, fiberglass had essen- Historically cotton and rayon were the fibers
tially disappeared from the tire industry. used in chafers, but in the 1970s nylon became
Various adhesive and heat treatments are ap- the dominant fiber. Both monofilament and
plied to synthetic cord fabrics to optimize adhe- multi-filament yarns are used. In all cases the
sion and performance. The adhesive is typically fabrics are adhesive treated (RFL) both for
an aqueous solution of resin and latex called adhesion to the rubber and to impregnate the
RFL. Steel wire is brass coated which increases fiber bundles (yarns) so that the pressurized air
its adhesion to rubber. Thermoplastic cord fab- in the tire cannot wick along the filaments and
rics made of nylon and polyester are subjected escape to the outside or into the sidewall of the
to heat setting under controlled time, load and tire. The former causes a flat tire and the latter
temperature to improve properties and dimen- leads to tire failure.
sional stability.
Fatigue resistance of cord fabric materials is 2.3 Bead Wrap
critical in tire applications. Nylon fibers have
the highest resistance to dynamic stresses fol- The bead wire bundles are generally wrapped
lowed by polyester and viscose rayon [5]. with treated nylon cords, or woven or warp
The use of steel, polyester and aramid fibers knitted nylon fabrics to maintain the integrity of
in tires is increasing at the expense of nylon and the wire bundle during cure. These fabrics are
rayon, particularly in passenger tires. Com- treated for adhesion and tack to uncured rubber,
pared to steel belts, the disadvantage of textile and are slit to width by the textile supplier for
belts are poorer self centering (more difficult direct application at the tire building machine.
steering), shorter life due to higher internal Standard test methods for tire cords and tire
abrasion, and lower uniformity due to greater cord fabrics are given in ASTM D 885, Stan-
tire growth. dard Methods of Testing Tire Cords, Tire Cord
In the 1980s, the high performance, high Fabrics, and Industrial Filament Yarns Made
speed radial tire was developed for high speed from Man-Made Organic Base Fabrics (stan-
sports cars and performance luxury touring dard units) and in ASTM D 885 M (metric
cars. They utilize a shoulder guard or cap ply of units).
cord fabric wound over the shoulders of the
steel belts or over the entire belt. Most fre-
quently these are nylon cord fabric, but other 3. AIRBAGS
fibers including aramid have been used. The
cords are placed in the rolling direction of the An airbag is an automatic safety restraint
tire, and act as a compressing force to resist the system that has gained significant importance
centrifugal force of the steel belt as the tire per- within the last decade. Airbags are built into the
forms at high speed and high rpm. steering wheel and instrument panel. They are
Some smaller volume, but important textile not alternative but supplemental to seat belts
contributions are made to tire building and tire because airbags provide protection only against
performance in the bead area. head-on collisions while seat belts provide pro-
tection regardless of the crash direction (Figure
2.2 Chafer 15.5).
Airbags are made to inflate from collisions
Square woven (but bias cut and applied) that occur within a 60% arc in front of the vehi-
chafer fabrics are built into the surface of the cle, and with collisons equivalent to about 12
15.1 Transportation Textiles 501
miles per hour into a fixed wall. Upon crash, from impact. The airbag then deflates 0.12 sec-
sensors set off an igniter in the center of the air- ond after absorbing the forward force. The en-
bag inflator. Sodium azide pellets in the inflator tire event, from initial impact to full deploy-
ignite and release gases that primarily consist of ment, takes about 55 milliseconds-about half
nitrogen. The gas then passes through a filter, the time to blink an eye [6].
which removes ash or any particles, into the Data show that more than half of all severe in-
bag, causing it to inflate (Figure 15.6). juries and deaths in automotive accidents are
Figure 15.7 shows the operation sequence of the result of frontal collisions. The proven effec-
an airbag. Since almost all collisions occur tiveness to prevent death and decrease certain
within 0.125 second, the airbag is designed to types of injuries in accidents has made airbags
inflate in less than 0.04 second or 40 millisec- almost a standard item in vehicles by legislative
onds (ms). In a collision, the airbag begins to mandates. A recent study by the Insurance Insti-
fill within 0.03 second. By 0.06 second, the air- tute showed that airbags are much more effec-
bag is fully inflated and cushions the occupant tive than seat belts alone for safety. Compared
20
15
"'
....
~
u
c: 10
a:E
5
0
Western Asia North Others
Europe Pacific America
Ill Car Production • With Air Bag I
FIGURE 15.8 The 1992 world car production with airbags (Automotive News [8]).
to seat belts alone, airbags have reduced death Signal, Akzo and Toray are the major fiber sup-
by 28%, serious injury by 29% and hospitaliza- pliers of airbags. Table 15.4 shows physical
tion by 24%. properties of Nylon 6,6 airbag fibers. PET,
The first airbags were introduced in the early which has good dimensional stability even at
1970s by General Motors but were not readily humid environmental conditions and good com-
accepted by the consumer. The market for air- paction, is beginning to be used in certain ap-
bags was assured in the United States when the plications as airbag material.
Department of Transportation (Dar) imple- Driver and passenger side bags differ slightly
mented the Federal Motor Vehicle Safety Stan- in their properties as shown in Table 15.5.
dard (FMVSS) 208 in 1984 [7]. Because of this Passenger side fabrics have different properties
law, the United States leads the commercializa- and are uncoated because the gas that inflates
tion of the airbag as shown in Figure 15.8. the airbag is dispersed over a larger area.
Fabrics must be free of knots, splices, spots and
3.1 Materials and Properties of Airbags broken ends.
TABLE 15.5 Typical Characteristics of Driver stability, low air permeability and low cost.
and Passenger Side Fabrics Used Table 15.6 shows typical fabric properties of an
in Airbags (courtesy of AlliedSignal).
840 denier nylon airbag fabric. Coating com-
Driver Side Passenger Side panies in the United States include Reeves,
Takata/Highland, Milliken, Alpha and Bradford.
25 X 25 plain weave 25 x 25 rip stop
840 denier Nylon 6,6 840 denier Nylon 6,6
Cutting and sewing of airbag fabrics demand
Scoured, heat set, coated Scoured, heat set careful attention. Dimensional tolerances are
46 X 46 plain weave 41 X 41 plain weave
very small. Sewing thread fiber type, weight,
420 denier Nylon 6,6 630 denier Nylon 6,6 construction and coating need to be selected
Scoured, heat set, coated Scoured, heat set properly. Nylon 6,6, Polyester and Kevlar®
49 X 49 plain weave aramid fibers are used for sewing threads. Sew-
420 denier Nylon 6,6 ing patterns and stitch types are critical to the
Scoured, heat set performance of the airbags.
An airbag module consists of airbag, inflator,
mounting hardware and molded cover. Crash
by Milliken, JPS Automotive, Takata/Highland sensors and diagnostics are used as part of the
Industries, Clark-Schwebel, and Stern & Stern. system. Major module manufacturers are lo-
Reeves International of Italy is a major manu- cated in the United States (American Bag Co.
facturer in the world. Figure 15.9 shows a typi- division of Milliken, Reeves, AlliedSignal
cal dense woven fabric for airbags. Safety Restraints, Takata/Highland Industries,
After weaving, the driver side airbag fabric is Morton International, TRW Inc., GM-Inland
coated with black neoprene rubber or silicon Fisher Guide, Breed), Europe (Electrolux
rubber. Major requirements for coating are good Autoliv, TWR Repa) and Japan (Takata Indus-
adhesion, antiblocking, long term flexibility, re- tries). The module manufacturing companies
sistance to cyclic temperature change (from are responsible for designing, testing, con-
-40°F to 250°F), ozone resistance, long term structing, certifying and supplying the car man-
warp
weft
both sides of the belt provide the necessary • Dynamic Test Procedure, TYpe 1 and
strength in the loading direction. This configu- TYpe 2 Seat Belt Assemblies, SAE 1117
ration also provides a lightweight, slim and • Seat Belt Assembly Webbing Abrasion
flexible fabric with a smooth surface that is Test Procedure, SAE 1339 MAR86
comfortable to wear and easy to use. The woven
fabric is shrunk during finishing to improve the
energy-absorption properties. As a result of the 5. AUTOMOTIVE INTERIOR TRIM
shrinkage, the weight would increase typically
from 50 g/m to 60 g/m. Proper dyestuff should Various woven and nonwoven fabrics are used
be used to provide fastness to light, rubbing and for seat facing, seat bolsters, headliners, doors
perspiration. No dye should be transferred from and side panels. Fabrics provide comfort and
the seat belt to garment by rubbing even in wet better appearance in car interiors while still
conditions. meeting the performance and consistency re-
A properly designed seat belt should provide quirements. Automotive interiors have an in-
non-recoverable extension or stretch during the fluence on new car buyers.
collision to reduce the deceleration forces on Each application requires different fabric
the body (elastic stretch is not wanted since it properties. The overall main trends in automo-
may cause whiplash damage). A typical seat tive industry's fabric requirements are:
belt should allow the passenger to move forward
around 12 inches during an accident by con- • softness, luxury, hand and aesthetics
trolled extension of the belt. The extension and • patterning, design flexibility
reduced recovery from stretch properties are • dyeability
given to seat belts by controlled heat relaxation • "moldable" fabrics
during finishing. Since the stretch on the belt is • stretch 5-200%
not recovered, seat belts need to be replaced The Society of Automotive Engineers has
after a major accident. Otherwise, a seat belt developed the following test methods and stan-
should last as long as the life of the car. dards for general automotive textile characteris-
In a serious accident, a well-designed seat tics and interior trim materials. The SAE inte-
belt provides a deceleration of 20 g (g is gravita- rior trim and textile standards were developed
tional acceleration) or more, which means that through the IFAI Transportation Division before
there is a considerable amount of force exerted they were published as SAE standards.
on the body by the seat belt. Although this force
may cause some damage to the body, this dam- • Felts, Wool and Part Wool, SAE 1314
age is far less compared to the damage (i.e., MAY81
death or serious injury) without a seat belt. • Test Method for Measuring Thickness of
The Society of Automotive Engineers has de- Automotive Textiles and Plastics, SAE
veloped the following standards for seat belts: J882 FEB85
• Test Method for Determining
• Seat Belt Assembly Webbing Abrasion Dimensional Stability of Automotive
Performance Requirements, SAE 1114 Textile Materials, SAE J883 FEB86
MAR86 • Test Method for Wicking of Automotive
508 TRANSPORTATION TEXTILES
Fabrics and Fibrous Materials, SAE 1913 Materials- Horizontal Test Method,
FEB85 SAE 1369 1UN89
• Test Method for Determining Resistance
to Abrasion of Automotive Bodycloth, 5.1 Seat Fabrics
Vinyl and Leather and the Snagging of
Automotive Bodycloth, SAE 1948 Textile fabrics and leather have replaced PVC
FEB86 for car seats. However, vinyl is still used with
• Test Method for Determining Resistance either a polyester/cotton knit or a polyester non-
to Abrasion; Beading; and Fiber Loss of woven substrate as trim on the back and in the
Automotive Carpet Materials, SAE skirt (boxing) of the seat. Major seating fabric
11530 1UN85 structures are:
• Method of Testing Resistance to
• flat woven fabrics
Scuffing of Trim Materials, SAE 1365
• pile woven fabrics
FEB85
• warp knits
• Test Method for Measuring Weight of
• circular knits
Organic Trim Materials, SAE 1860
• double needle bar raschel
1AN85
• Test Method for Determining Blocking The use of flat woven fabrics is decreasing
Resistance and Associated while the use of all-pile fabrics is increasing.
Characteristics of Automotive Trim The dominant fiber used in car interiors is
Materials, SAE 1912a polyester. Nylon was used in early seat fabrics.
• Hot Odor Test for Insulation Materials, Polypropylene is used successfully in accent
SAE 11351 APR87 colors and some bolster fabrics. Major yarn
• Accelerated Exposure of Automotive structures are flat continuous filament, false
Interior Trinf Components Using a twist, air-jet textured and knit-de-knit. Regular-
Controlled Irradiance Water Xenon-Arc ity of texture is critical. The main requirements
Apparatus, SAE 11885 MAR92 of seat facing fabrics are soft handle, design
• Accelerated Exposure of Automotive color and pattern, piece dyeability and mold-
Interior Trim Components Using a ability via stretch (Figure 15.11).
Controlled Irradiance Air-Cooled Seat fabrics can be yarn dyed (for spun or tex-
Xenon-Arc Apparatus, SAE 12212 tured yarns) or piece dyed. Figure 15.12 shows
MAR93 the major process steps for both methods. Very
• Accelerated Exposure of Automotive little solution dye is used for woven fabrics.
Interior Trim Materials Using an Color and shade reproducibility are critical
Outdoor Under Glass Variable Angle for seat fabrics which require computer control
Controlled Temperature Apparatus, SAE on dyeing machines. Setting of thermoplastic
12229 FEB93 fibers is usually necessary. Finishes such as
• Accelerated Exposure of Automotive lubricants and antistats are usually applied to
Interior Trim Materials Using Outdoor seat fabrics. After finishing, the fabric is lami-
Under Glass Controlled Sun-Tracking nated. Flame lamination, which is widely used,
Temperature and Humidity Apparatus, produces a trilaminate of face fabric, polyure-
SAE 12230 FEB93 thane foam and lining. The foam lining has a
• Test Method for Determining Window thickness of 2-10 mm. Testing of seating fabrics
Fogging Resistance of Interior Trim includes heat stability, light degradation and
Materials, SAE 1Z75 FEB85 pile distortion. Ovens with temperature and hu-
• Non-metallic Trim Materials-Test midity control are used for the tests. Fogging
Method for Determining the Staining tests are also performed for safety concerns.
Resistance to Hydrogen Sulfide Gas, Recently, Inland Fisher Guide (IFG), a com-
SAE 1322 DEC85 ponents division of General Motors, has devel-
• Flammability of Polymeric Interior oped a new technology for a seamless seat
FIGURE 15.11 Seat fabrics (courtesy of Stork).
509
51 0 TRANSPORTATION TEXTILES
6.1 Convertibles
nomical. More recently, solution dyed acrylics pinpoint texture. The finish in Europe has a
and acrylic polyester blends are being used as rougher animal leather grain.
the outer fabric combined with another plain
drill or jacquard lining fabric to produce the soft
convertible topping fabric. These lining fabrics 6.2 Vinyl Roof Treatments
may be cotton, polyester, or nylon or a blend of
a combination. The "Landau" roof originated as an option in
The soft topping for sport utility vehicles is a 1964 on luxury cars to give the vehicle an ex-
vinyl coated heavy-duty polyester-cotton sateen. pensive leather look (Figure 15.18). The sub-
Another variation is a low count square weave strate under the vinyl is a nonwoven needle-
polyester scrim coated with vinyl on both sides. punched polyester backing. With the use of a
The vinyl top in the United States has tradition- foam pad underneath, this enabled the top to
ally been the symmetrical small diamond or assume a luxurious padded look and feel. Use
of roof treatments is all but over on current pro- Color Match to Master Specimen for
duction. A small but profitable aftermarket Fabrics, Vinyls, Coated Fiberboards and
restyling market remains. Other Automotive Trim Materials, SAE
1361 MAR85
• Method of Testing Resistance to
6.3 Other Automotive Exterior Fabrics Crocking of Organic Trim Materials,
SAE 1861
Other exterior fabrics include sports car front • Instrumental Color Difference
end covers, truck covers, rear window curtains Measurement for Exterior Finishes,
for hatchbacks, binding fabrics and tire covers. Textiles and Colored Trim, SAE 11545
Front end covers are used to protect the body 1UN86
finish from gravel and insects. These fabrics are • Retroreflective Materials for Vehicle
made of vinyl on nonwoven polyester or ex- Conspicuity, SAE 11987 MAR91
panded vinyl or polyester knit. The light utility
truck cover is used to protect the cargo. The
backing fabric is a weft inserted loop sheeting 7. TRUCK AND CAR COVERS
or a conventional sheeting made of polyester.
Although the rear window curtains for hatch- Cars with low drag coefficients are more fuel
backs are used inside the vehicle, they are posi- efficient. Textile fabrics (tarpaulins) are used as
tioned directly beneath the rear window glass truck covers to reduce the drag and therefore
and subject to magnified ultraviolet rays. Bind- improve truck aerodynamics as shown in Figure
ing fabrics are used to cover either a raw edge or 15.19. The small arrows indicate turbulence,
provide a bridge to fill in a narrow gap. Vinyl giving rise to drag. This is especially effective
coated polyester/cotton binder fabrics are used for trucks that carry open cargoes. It was shown
for vinyl products. For the soft acrylic tops, a that when properly tied down, tarpaulins give
matching acrylic duck is used with or without a fuel savings of up to 7% [15]. Tarpaulins are
light vinyl or adhesive back-coating. A variety coated fabrics made of high strength polyester
of fabrics are used as tire covers ranging from and nylon fibers. Thrpaulins are also excellent
heavy cotton knitted fabrics to nonwoven 6-10 means to protect cargoes against the weather.
oz polyesters coated with vinyl. They prevent cargo debris from flying. Tarpau-
The following standards have been developed lins are a legal requirement in some states for
by the Society of Automotive Engineers for ex- certain types of cargo.
terior trim: The Industrial Fabrics Association Interna-
tional (IFAI) estimated that in 1991, 15 million
• Accelerated Exposure of Automotive square meters of fabric was consumed in the
Exterior Materials Using a Controlled truck cover market. Replacement covers are es-
Irradiance Water-Cooled Xenon-Arc timated to have 80-85% of the market, of which
Apparatus, SAE 11960 1UN86 30% are open tops, and 70% are load covers.
• Accelerated Exposure of Automotive This translates into roughly 350,000 average-
Exterior Materials Using a Solar sized truck covers. There are several types of
Fresnel-Reflective Apparatus, SAE 11961 truck covers as shown in Figure 15.20. Soft side
DEC88 trailers and open-top trailer covers such as the
• Outdoor Weathering of Exterior one shown in Figure 15.21 remain more popular
Materials, SAE 11976 1UN89 in Europe than in North America [16].
• Accelerated Exposure of Automotive Textile fabric covers are used to protect cars
Exterior Materials Using a Fluorescent from sun, rain, hail, snow and other harsh en-
UV and Condensation Apparatus, SAE vironmental effects (Figure 15.22). All-season
12020 1UN89 car covers are made of polyester and impact-
• Test Method for Determining Visual absorbing padding.
FIGURE 15.19 Typical air flows over trucks (a) without. and (b) with, tarpaulins [15).
514
15.1 Transportation Textiles 515
FIGURE 15.23 Belts and hoses used in cars (courtesy The Federal Aviation Administration (FAA)
of Amoco Chemical Co.). has stringent rulings concerning the flammabil-
ity requirements for aircraft seat cushions. In
order to comply with their specifications, the
radiator hose is towards aramids. They should materials have to withstand burning and also not
be resistant to vibration, oils and other solvents. give off any toxic fumes. In the past, polyure-
The required properties of textile reinforcing thane foam alone was inserted into the aircraft
materials for hoses and belts are strength, flex- seat cushions. When burned, these cushions re-
ibility, temperature resistance and strong adhe- leased dense amounts of toxic fumes, causing
sion to elastomers. airplane passengers to suffocate.
Recently, high temperature thermal barrier In airplane upholstery, a type of structure
materials such as fiberglass, ceramic and silica known as blocking layers is used to help pass
fibers, aramids, molded mineral fibers, metal- flame resistance regulations. These layers of
lized fabrics and silicone rubber coated fabrics fabric consist of aluminized Zirpro wool and
are being used in modem cars for insulation of glass fiber or a blend of chemically treated wool
hydraulic, fuel, air-conditioning wires, engine and flame retardant synthetic fibers. Zirpro
mounts, wiring harnesses, exhaust gas recir- wool is a chemically treated flame resistant
culating tubes and electronic components. wool that has recently been developed. Seat
Drive belts require similar requirements in covers with one of these kinds of layers help in-
textile reinforcement materials. V-belts are used crease the chances of surviving a postcrash fire.
to drive the alternator and water pump. With the The aluminized wool fire blocking layers are
inclusion of stronger and lighter textile rein- placed next to the foam filler in the seat cush-
forcements, toothed belts for timing drives have ion. The glass fiber is placed on the other side
replaced chain drives completely. Due to its in- of the wool to give extra protection from fire.
extensibility, polyester is the main reinforce- When this type of procedure is used, fire safety
ment material for toothed belts. dramatically increases. However, these layers
Textile reinforced belts offer low noise, low proved to be rather inflexible so for that reason
cost and light weight. Since the textile belts are they were better suited for critical locations
more flexible than chains, smaller pulleys can such as flight attendant and pilot seats. The
be used for power transmission which allow other type of fire blocking layer (consisting of
compact designs. Another advantage of a textile chemically treated wool and man-made fibers)
reinforced belt is that it does not require lubri- are more flexible and therefore are used for pas-
cation. Belts and hoses for industrial applica- senger seating.
tions are covered in Chapter 16.0. A new fabric, known as Firotex® has been de-
15.1 Transportation Textiles 517
veloped which is placed around the cushions as aerospace industry. Protective garments must
an inner cover. The Firotex® fubric is made of be worn when working in aerospace industry
viscose rayon with a reinforced aramid inside to clean rooms. These rooms are where flight
give needed abrasion resistance. The fabric can hardware is processed and they differ from the
withstand burning with kerosene for up to two usual clean-room environment. The fucilities at
minutes. Kennedy Space Center for example, are large
Wool is another flame resistant material that environmentally controlled high bays and are
is often used in aircraft furnishings. Due to the similar to airplane hangars. As air enters these
chemical and morphological structure of the facilities, it is filtered and monitored for air-
fiber, the wool has a high nitrogen and moisture borne particulate, particulate fallout, and hydro-
content. Therefore the wool will not usually carbons. In order to maintain this level of clean-
support a flame or be susceptible to burning. If liness, workers must wear protective clothing.
the wool does bum, it does not melt away. In- Garments are sometimes changed on a daily
stead, it leaves a foam-like ash which has good basis. The garments are made to be launder-
insulating properties and can be handled right able, flexible, and comfortable. This will allow
after burning. This ash can also be easily re- for longer life of the garment, thus resulting in
moved so that major clean-ups are not required a higher cost effectiveness. These garments are
if part of the aircraft is burned. Wool does not made to meet several conditions. They are made
shrink when burned so it will not leave any to be flame resistant, and have to withstand
areas exposed to the fire. Wool is often used exposure to hazardous wastes. The compo-
because it has a good appearance, and is easily nents that make up the garments are 99% con-
maintained. Planes have curtains, carpets, up- tinuous filament polyester material with 1%
holstery, and blankets made from wool. Wool raised grid carbon/polyester filament yarn.
fubrics usually undergo a flame resistant treat- Nomex material is used in some of the garments
ment. that require extreme resistance to hazardous
For carpeting used in airplanes, one flamma- materials.
bility specification is known as the National Another important factor to consider in aero-
Bureau of Standards radiant panel test. This test space is the space requirements. Workers have
is considered to be more reliable for carpets to be able to crawl and climb into various
than the vertical test. In this test, the carpet is spaces. They also had to be very careful when
positioned horizontally under an angled radiant working with orbiters since certain areas of the
panel with a small igniting flame located at the orbiter could not be stepped on. For this reason,
hottest area closest to the radiant panel. To be garments with snaps, buckles, and belts are not
able to pass this test, a flame resistant latex must used. Instead, the garment is made to be zipped
be applied to the carpet backings to keep it from up diose to the wearer's body. This type of de-
burning. Cellulose fibers may also be used in sign makes it much easier to move around when
this backing. wearing these garments.
Other areas of the plane that require the use of Textiles have also been used as actual compo-
textiles include seat belts and shoulder har- nents of the space shuttle. The thermal protec-
nesses. These fabrics undergo tests in both the tive system is aided by the placement of outer
warp and the weft direction. Samples are taken ceramic tiles and Nomex®-strain isolation pads.
at random from the item as it is installed in the Composites have been used in forgings and cast-
aircraft. If this is not possible, simulated sam- ings of the shuttle. These composites are light-
ples are constructed for testing purposes. The weight and provide for easier handling of the
main test used for these fabrics is known as a area into which they are installed (Chapter 7.0).
horizontal test. This test uses a fabric length of In a rather unique application, polychloro-
6 em. All materials are tested as closely as pos- prene-coated 2-ply nylon, one-ply biased fabric
sible to the form in which they are used in the is used for emergency slides (FAA slides) in
airplane. airplanes (Figure 15.24). Critical properties
Protective clothing plays a major role in the of these fabrics are weight, breaking strength,
518 TRANSPORTATION TEXTILES
FIGURE 15.24 Airplane evacuation slide made of coated fabric (courtesy of Reeves).
tearing strength, flame resistance and air reten- brakes and railroad brake shoes require less
tion. than 5% short fibers of Kevlar® by weight as the
reinforcement material. Sheet gasketing can be
reinforced with less than 6% Kevlar® pulp by
10. TEXTILES AS STRUCTURAL weight combined with other fibers, fillers and
ELEMENTS IN TRANSPORT VEHICLES rubber binders. Figure 15.25 shows various au-
tomotive parts that include Kevlar® as the rein-
The use of textile structural composites forcement material.
(Chapter 7.0) is increasing in manufacturing of
transport vehicles including automotives, trucks Automotive Polymer Composites
and aircrafts. In commercial aircrafts, compos-
ite materials provide long-term fuel and chemi- Automobiles account for approximately two-
cal resistance. Honeycomb composite structures thirds of the gasoline consumption and one-
made of Nomex® and impregnated with phe- third of total energy use in the United States.
nolic resin are used for aircraft flooring due to Approximately 75% of a vehicle's fuel con-
their low density, light weight and chemical and sumption is directly related to weight-related
fire resistance. In automotives, many body com- factors, the other 25% is related to air drag. A
ponents are made of textile reinforced compos- small weight reduction of current vehicles
ites. In shipbuilding, graphite composite can would result in tremendous gasoline savings as
reduce structural weight to increase payload well as reduction in C02 emissions [18] . Auto
capability, and improve ship stability. Boron re- companies have made an effort to reduce the
inforced aluminum was used in the space shuttle weight of vehicles over the past twenty years.
which saved around 300 lb of weight in the shut- The average weight of a vehicle has been re-
tle's cargo structure compared to conventional duced nearly 25% while doubling fuel economy
metals [17]. without sacrifiqing other desirable performance
Textile fibers can be used in clutch and brake features.
parts replacing asbestos. These parts require Polymeric materials are expected to replace
good abrasion and high temperature resistance. steel in many automotive .application areas.
Clutch facings are reinforced with 20% by Steel is heavy and subject to corrosion. Polymer
weight Kevlar® short fibers, combined with in- composites are lighter, more flexible and can
organic fillers and binder. Properly constructed offer better dent resistance. Examples of substi-
disc brake pads, drum brake shoes, truck block tuting metals with polymer products include
15.1 Transponation Textiles 519
FIGURE 15.25 Various automotive parts reinforced with Kevlar® aramid chopped
fibers and pulp (courtesy of DuPont).
plastic bumpers, front and rear ends, radiator Polyurea resins processed by reaction injec-
tanks, fenders, wheel covers and door handles tion molding (RIM) are the current front run-
(Figure 15.26). Table 15.8 shows the major ners in fender applications. These resins have
areas for plastic and polymer composite body been used on the Chevrolet Camara four-seat
panels. It is estimated that polymeric materi- sport coupe. Sheet molding compound (SMC)
als accounted for 12 % of the body weight in is the leading material for hoods. SMC is a
1990. composite of thermoset polyester modified with
Interior parts
Trim ABS, ABS alloys, modified PBT, acetal
Instrument panel RIM polyurethane (PU), RIM polyurea
Instrument panel skin ABS/PVC alloy, PPO
Console ABS
Functional interior parts
Radiator header tanks Nylon
Brake reservoirs Nylon, acetal
Electrical distributor caps PBT, PPO blends
Fuel tanks Acetal, nylon, modified PET, PBT
Gears Acetal, nylon
Seat backs PPO
Seat cushions PU
Engine fans and shrouds Nylon
Air cleaner housing Nylon
Exterior parts
Bumper fascia RIM-PU, RIM-Polyurea, SRIM-PU, PPs,
toughened PPs, fiber reinforced PPs, and
other thermoplastic polyolefins (TPOs),
PC/PBT Alloys, thermoplastic elastomers
Body panels SMC, BMC, PET/PBT blends, TPOs, nylon,
nylon/PPO blends
Exterior trim PPO/HIPS blend, PC, PC/PET blend,
PC/PBT blend
Hood SMC
Functional exterior parts
Headlamp assemblies Nylon, PC, modified polyesters
Wheel hubs, covers Nylon, PC, modified polyesters
Mirror housing Nylon
RIM = reaction injection molding, PPO = polyphenylene oxide, ABS = acrylonitrile-butadiene-styrene, SMC = sheet molding compound,
PC = polycarbonate, PVC = polyvinylchloride, PET = polyethyleneterephthalate, PP = polypropylene, PBT = polybutylene !ere-
phthalate.
520
15.1 Tmnsportation Textiles 521
fillers like calcium carbonate and reinforced case of emergency, a small canister of com-
with chopped glass fibers. The roof, doors, pressed carbon dioxide, which is at - 78 o C, is
hatch, and spoiler of Camaro sport coupe and used to inflate the life raft in a few seconds. To
those of the fourth-generation Pontiac Firebird prevent flex cracking due to cold gas during in-
are made of chopped glass/polyester SMC. flation and unfolding the raft, polymer coatings
The material cost of SMC is very attractive to with good low-temperature flexibility are used.
automakers. SMCs have found applications in Civilian rafts are generally made of woven
specialty roofs for light-duty vehicles such as nylon fabrics and coated on both sides with
the Ford Blazer and Jeep Wranglers. SMC lift natural rubber or natural rubber/SBR (styrene-
gates are utilized on Jeep Cherokees and Ford butadiene rubber) blend. The coating contains
Broncos. SMC is being incorporated in side pan- daylight fluoresecent pigments for maximum
els on the box of GM support trucks. visibility. Naval life rafts are usually made of
The Society of Automotive Engineers has de- nylon laminates with an interply of butyl rubber
veloped the following standards for structural which is less permeable to carbon dioxide than
polymeric materials: natural rubber providing longer use [19]. Lei-
sure boats are inflated to a pressure of 15-25
• Test Method for Determining Cold kPa by compressed air rather than carbon diox-
Cracking of Flexible Plastic Materials, ide.
SAE J323 Instead of strengthened fabric floors, naval
• Test Method of Stretch and Set of and coast guard vessels have a rigid hull en-
Textiles and Plastics, SAE J855 MAR87 circled with buoyancy tubes (Figure 15.27).
• Chemical Stress Resistance of Polymers, These amphibious craft are suspended above the
SAE 12016 JUN89 surface of water by a cushion of air that is gen-
erated by fans and airscrews. The coated-fabric
"skirt" is fitted around the hull and contains the
air cushion. The fabric is inflated to a pressure
11. INFLATABLE PRODUCTS USED around 3 kPa. Heavy polyester or nylon fabrics
IN TRANSPORTATION coated with thick layers of Neoprene, Hypalon,
or polyurethanes are used. Similar coated fab-
Coated fabrics are used in inflatable life- rics are also used to surround and contain oil
saving aids such as life jackets, rafts and aircraft slicks, for marker buoys and in flotation equip-
emergency chutes. Modern life rafts, which are ment for offshore oil and construction indus-
generally designed for 1-30 people, have multi- tries. Buoyancy bags are used for supporting
ple buoyancy tubes to keep the raft afloat even if pipelines and platform sections. Deflated bags
a tube is punctured. Usually canopies are also can be attached to sunken objects and then in-
included to protect against severe weather. In flated to raise them to the surface.
15.2
References and Review Questions
6. Why is testing especially important in air- 8. What are the general requirements for au-
bag manufacturing? List the major tests for tomotive interior trim? Explain.
airbags. 9. Why are truck covers used? What are the
7. Explain the structure of seat belts. What materials?
are the major requirements for seat belts? 10. Discuss the use of textiles in aircrafts.
16.0
GENERAL INDUSTRIAL TEXTILES
16.1
General Industrial Textiles
S. ADANUR
528
16.1 Genera/Industrial Textiles 529
.Jl::rl:ri 30 20 10 50 25 10 - - 30
~~ 10 5 5 10 5 5 - 20 5
~ 20 10 5 20 10 5 30 20 5
C>\7 10 5 5 20 10 5 - 20 10
-~ + + + A A B - - ~
-~ + ++ ++ B B B - ~
~
Q\ + ++ ++ A B B ~ ~ ~
Cft + ++ ++ (A, BI+S - ~ ~
symbols
+ protective gloves with short term resistance
++ protective gloves with long term resistance
A protective suits e.g. cotton coverall
B protective suits (permeability < 5 %1
e.g. Goretex, Propylen·Kimberly.Ciai'X, Tyvek
S apron of good resistance
penetration of aerosol sprays. The results were The USDA, EPA and NIOSH (National Insti-
recorded as pass or fail. The presence of any tute for Occupational Safety and Health) recom-
methylene blue dye on the fabric backing was mend the use of protective apparel during han-
considered as "fail!' They concluded that the dling and application of most pesticides [8].
presence of fluorocarbon finish increased the The information about the proper personal pro-
resistance to aerosol penetration. In another tective equipment for the safe use of pesticides
study, it was found that water-repellent and soil- is included in the Federal Insecticide, Fungi-
release finishes increase the fabric effectiveness cide, and Rodenticide Act (FIFRA) and the
for protection [7] . Code of Federal Regulations, Title 40, Section
FIGURE 16 ·5 Typ1cal
. (copyright ·
ASTMprotective
garment and hood design for pesticide pro-
tectlon [2)).
531
532 GENERAL INDUSTRIAL TEXTILES
162.10, Labeling Requirements of Pesticide paper are used as insulation in motors and gen-
Products issued by the Office of Pesticide Pro- erators. Nomex® paper is used in slot liners,
grams (OPP) of the EPA. phase insulation, wedges, coil insulation and
high voltage insulation (Figure 16.6).
Thermount® from DuPont is a nonwoven
2. TEXTILES IN ELECTRONICS aramid reinforcement material for printed wir-
ing boards. It is suitable for high-density inter-
Kevlar® aramid can be used as a high density, connects such as fine-pitch surface mount,
leadless electronic chip carrier. The carrier can direct-chip attach, or in multi-chip modules.
be made of a printed copper surface and lami- Thermount® provides a low coefficient of in-
nated with a woven Kevlar® structure which plane thermal expansion (CTE), which reduces
allows placement of more electrical connections strain on solder joints during thermal cycling
in less space and restrains copper and epoxy and a low dielectric constant, which allows
thermal expansion. Kevlar® is also more resis- faster signal speeds and good dimensional sta-
tant to vibration and failure, which makes the bility for improved registration yields.
chip very suitable for military missiles and air- PTFE composites are utilized in low loss, low
craft [9]. dielectric constant, printed circuit boards for
Nextel alumina-boria-silica ceramic fibers microwave applications as shown in Figure 16.7.
developed by 3M are used in electrical equip- Textiles are used as planar antenna covers as
ment, thermocoupling devices and wire insula- shown in Figure 16.8. The permanent hydro-
tion. N-312 can withstand up to l,205°C and phobic surface of the modified PTFE composite
N-440 can withstand up to 1,370°C. These provides a durable, weather resistant construc-
fibers can be woven into a fabric. tion.
Polyester ftlm laminates and Nomex® aramid Kevlar® aramid is used in fiberoptic cables,
533
534 GENERAL INDUSTRIAL TEXTILES
can be woven or knitted. They are coated or and power transmission belts. Tires are ex-
treated for durability, smoothness and printabil- plained in Chapter 15.0, Transportation Textiles.
ity. Polyester and nylon fabrics are widely used Uses of textile materials in other rubber prod-
for flags. Spunbonded polyolefin fabrics offer ucts are discussed in this section.
the look and feel of paper and they are used for Major fibers used in the rubber industry are
short-term banners. Unsupported films, such as cotton, viscose rayon, nylon, polyester, glass
polyethylene or vinyl sheeting are light and in- and aramids. The major fiber properties re-
expensive plastics without any fabric reinforce- quired in rubber reinforcement are:
ment. Canvas and drill cloth are made of natural
• high tenacity and modulus
fibers (all the others are made of synthetics).
• good dimensional stability
They are less expensive but also less UV-
• moisture resistance
resistant and tough. Table 16.1 lists the major
• resistance to high temperatures
properties of banner and flag fabrics.
• fatigue resistance
• good bonding with adhesives and rubber
4. TEXTILE REINFORCED PRODUCTS
4.1 Transport Conveyors
The rubber industry uses textile yarns and
fabrics extensively for reinforcement. The ma- Transport conveyors are used in mineral
jor rubber product items in which textiles are works and transportation, material handling
used as reinforcement are tires, conveyor belts, systems and for passenger transportation at air-
FIGURE 16.10 Flags combine two unique properties of textiles: flexibility and strength (courtesy of Wellington Sears
Company).
01
eN
0) TABLE 16.1 Major Properties of Banner and Flag Fabrics (courtesy of /FA/).
PVC, Mesh,
Laminates Cotton,
Nylon Polyester Coated Nylon Polyester/Cotton Acrylic, Modacrylic Polyolefin
Description Indoor/outdoor woven Spun, woven or knit Indoor/outdoor Woven, all-natural Acrylic fibers dyed in Spunbonded polyolefin
material, 200--400 polyester fibers, used materials, includes ex- fabrics and poly- the formulation stage, fibers create a light-
denier most common, for indoor/outdoor truded woven, !ami- ester cotton giving woven material weight, weatherable
coatings/finishes applications. Finishes nated, and coated blends, including colorfastness. Mod- material similar in
available are for texture, per- materials bunting, canvas, acrylic inherently fire- touch to wax paper.
formance characteris- drill cloth, and resistant Typical usage: short-
tics ducks term indoors, out-
doors
Weight/sq yd 3-6 oz 4-12 oz 10-18 oz most common 8-18 oz 8-10 oz 3-5 oz
Colors Wide range Wide range Wide range Limited in natural Wide range Limited
state, some come
dyed
Graphic Applique, screenprint Applique, screenprint Screenprint ink, Screenprint ink, Screenprint ink, appli- Screenprint ink, hand
versatility solvent, screenprint ink, dye process, sub- pressure-sensitive vinyl, dye, applique, que, heat transfer paint
ink, acid dye, Iimation print heat transfer film, hand hand paint film, heat-sealed in-
pressure-sensitive paint set, hand paint
viny I on coated
materials
Transparency Transparent light No Opaque (some blocked No White is translucent Translucent
colors, translucent with ink
dark colors
Maintenance Yes, consult Yes, consult- Easily cleaned, consult Consult Yes N/A
manufacturer manufacturer manufacturer manufacturer
Life expectancy 6 mo average, some 6-12 mo 1 yr 6 mo 1 yr 2 wks outdoors
treated for UV resis-
tance
Fire-resistance Yes, treatable Some are FR Many are; consult Some are; con- Yes No
(from manufacturer manufacturer verted by manu-
or treatable) facturer
UV resistance Yes Yes Yes Some are Yes No
16.1 General Industrial Textiles 537
ports, shopping centers, etc. (Figure 16.11). Tex- High modulus materials, such as aramid and
tile or steel cords are used to reinforce rubber or polyester, are required in the longitudinal
plastic in conveyor belts and to provide longi- (warp) direction for long-haul high tensile belt-
tudinal strength. In return, rubber or plastic ing. Aramid fibers are as strong as steel and
covering protects textile materials from damage, they are non-corroding, fire resistant with a low
moisture, etc. Depending on the application thermal conductivity [2 ,3].
area, the major property requirements of con- Simple fabric designs such as plain or basket
veyor belts are high strength and flexibility; low weave are widely used in conveyor belts. Spe-
stretch in service; abrasion, impact and tearing
resistance; temperature and fire resistance; long
life; resistance to moisture, oils, and chemicals.
Good adhesion of the reinforcing plies is essen-
tial.
A number of rubberized textile reinforcement
plies are laminated, consolidated and vulcan-
ized in special presses and curing machines to
form conveyor belts (Figure 16.12). Usually
three to six plies are used for reinforcement. In-
creasing the number of plies unnecessarily re-
duces the ratio of total ply strength to belt
strength. The main textile reinforcement fibers
are rayon, polyester, nylon and aramid. Cotton FIGURE 16.12 Schematic of multi-ply fabric reinforced
is used for relatively low strength requirements. conveyor belts.
538 GENERAL INDUSTRIAL TEXTILES
cial weaves may be used to improve physical The fabrics are coated with rubber. The number
characteristics such as stretch, edge wear and of plies is usually between three and ten. Single-
tear. Two- or three-layer solid or hybrid fabrics ply or compound weave fabrics are also com-
provide dimensional stability. Blending dif- mon. The requirements for flat driving belts are
ferent fibers in fabrics offers many advantages similar to conveyor belts. Rayon, polyester,
including improved adhesion, strength, impact glass and ararnid cord materials are used in end-
resistance, fatigue resistance, stretch resistance, less V-belts which may have trapezoidal or
temperature and chemical resistance. Typical wedge shape.
fiber combinations include ararnid or polyester Textile reinforcement in the form of a cord
warp and nylon weft, nylon warp and weft. For fabric or yams is placed at the neutral axis or
bulk and adhesion, cotton and synthetic staple center of the V-belt in between two layers of
fibers are added. Fabrics are dried to avoid rubber. Then the whole structure is covered by
blowing of the laminate during the vulcaniza- fabric. Raw edge V-belts do not have the outside
tion. Fabric is passed over a multiple steam- protective jacket and therefore the tension
heated drum drier or hot plate. Next, frictioning members are exposed. These belts are suitable
is done while the fabric is still hot. Frictioning for smaller diameter pulleys. The trend in driv-
is a coating process in which the large differ- ing belts is towards higher power transmission
ence between the fabric and the rubber sheet at and smaller pulley diameters which results in
the nip of the calender forces the rubber into the steadily growing use of polyester fibers in
fabric weave. In calendering, both sides of the V-belt manufacturing. In compact cars, this
full width fabric are coated simultaneously. trend is very obvious. Besides, the diminished
Then, fabrics are cut to the width desired. The motor space is responsible for higher heat
cut widths are passed through a doubling ma- stresses to which V-belts are also exposed.
chine to adhere the layers together until the By joining several belts together, multi-V and
desired number of plies is obtained. Vulcaniza- poly-V belts are made. The major fiber require-
tion is carried out in a press or continuous drum ments for V-belts are high strength and dimen-
curing machine. To make the belt endless, the sional stability, resistance to impact and
ends of the belt are brought together either by periodic bending stresses, resistance to high
mechanical fastening or splicing. Splicing is temperature and chemicals and good adhesion
done by vulcanizing the belt ends together. Fire to rubber.
resistance requirements for passenger and pack- Positive drive belts or toothed belts are used
age carrying belts are increasing. PVC belting is in applications where no-slip precision drive
used for fire resistance. and timing are required. Since these belts
Belts are identified according to reinforce- should have very low stretch, steel, glass or
ment fiber type: "E" indicates polyester, and "P" ararnid cords are used. The teeth are molded
indicates nylon. "EE" designates a belt with with the belt and covered by tough nylon fabric
polyester warp and weft, and "PP" indicates a for abrasion resistance.
nylon warp and weft belt. A belt with polyester
warp and nylon weft is designated as "EP." 4.3 Hoses
outer polymer
sheath
fabric
reinforcement
Braided Hose
FIGURE 16.15 Types of hose constructions (courtesy
of Hoechst Celanese).
product quality, production technique and type 6. FABRICS TO CONTROL OIL SPILLS
of rubber. The basic fiber requirements for rub-
ber products are strength, dimensional stability, Oil spills are dangerous and not uncommon.
and good adhesion to rubber. The Oil Pollution Act of 1990 (OPA '90), which
Figure 16.18 shows abrasive products in which was formed as a direct result of the 1989 Exxon
fabrics are used for structural integrity. Valdez oil spill in Alaska, requires facilities that
handle oil products near lakes, rivers, oceans or
other waterways to maintain oil spill contain-
5. TRANSPORT BAGS AND SHEETS ment and cleanup capabilities [12].
Oil booms set out on the water contain dam-
Large bags made of coated textile fabrics are aging spillage (Figure 16.20). Most oil booms
very convenient to transport loose materials of are made of PVC coated polyester, PVC coated
one ton or more (Figure 16.19). The coated nylon or urethane coated polyester. Sections of
fabric is made of a woven nylon or polyester some booms are constructed from chloroprene
backing coated on both sides with PVC. The coated fabric or nitrite rubber coated fabric.
coating provides a waterproof and airtight struc- Polyurethane coated aramid fabrics are used to
ture. Huge transport bags are widely used in control oil spills in seas.
civil engineering, agriculture, and the food in- Rapid deployment booms are usually made of
dustry. lightweight 12 to 18 ounce PVC coated poly-
Coated textile fabrics are also used as trans- ester. The weight can be up to 100 to 110 ounces
port handling sheets. Due to their strength, they for conveyor belting materials for open-ocean
can handle various products such as hay, bricks, barriers.
prefabs, etc. The fabrics must be oil, water and abrasion
542 GENERAL INDUSTRIAL TEXTILES
Boom Types
7. CANVAS COVERS
AND TARPAULINS
Nominal Nominal
Diameter Circumference Average Linear Tensile Strength
Fiber (inch) (inch) Density (lb/1 00) (lb min, new)
are FDA (Food and Drug Administration) ap- Home and office furnishing textiles form a
proved. bridge between consumer (traditional) textiles
Important general properties of canvas and and industrial textiles. In many ways, they have
tarpaulins are strength, tear resistance, puncture the characteristics of both technical textiles and
resistance, weather resistance, flexibility and traditional textiles. For example, functions of
durability. Flame resistance or UV resistance carpets in homes and offices include heat in-
treatments may be applied. Due to synthetic sulation and sound deadening. Tufted and non-
materials used, tarpaulins are usually lighter woven mats are used in homes and offices for
and stronger than canvas covers. abrasion resistance to protect the original floor
where the traffic is high (Figure 16.22).
Awnings are used internally in offices and
8. ROPES AND NETS homes for aesthetic purposes (Figure 16.23).
Wall coverings and partition panel fabrics in
Natural and synthetic fibers are used in homes or offices are used for insulation, privacy
ropes for various purposes. The main natural and aesthetics (Figure 6.24). Ceiling tiles made
fibers are sisal and manila. Synthetic materi- of fabrics provide sound absorption and decora-
als include polyester, polypropylene, polyester/ tion. Drapery and upholstery fabrics in homes
polypropylene composite, nylon and ararnid. and offices play an important role in creating a
Strength, elongation, weight and abrasion char- warm leisure or friendly business environment
acteristics of ropes are important. Kevlar® ara- (Figures 6.25 and 6.26). Figure 16.27 shows a
rnid is used in deep-sea work-system cables and tablecloth that may have been coated for leak-
balloon tethers. Thble 16.2 shows the Cordage In- proofness.
stitute Rope Specifications. Fishing nets and In addition to functional requirements, the
lines are made of nylon fibers (Figure 16.21). aesthetic criteria, i.e., color, texture and ap-
pearance, are of primary importance to the user
in home and furnishings. This is one of the dif-
9. HOME AND OFFICE FURNISHINGS ferences between a typical industrial textile and
a home furnishing textile. Functional require-
The home and office furnishing market is an ments now include flame resistance in many
important part of the textile industry. Home fur- home and office applications.
nishing textiles include carpets and rugs, drap- With the change in lifestyle and behavior of
eries and curtains, upholstery, blankets, bed- consumers, more exact or tailored requirements
spreads, sheets, pillowcases and tablecloths. are demanded from furnishing textiles. There-
FIGURE 16.21 Fishing net made of nylon (courtesy of
AlliedSignal).
544
FIGURE 16.23 Internal awning (courtesy of Wellington Sears Company).
545
FIGURE 16.25 Home furnishings (courtesy of Wellington Sears Company).
546
FIGURE 16.27 Tablecloth (courtesy of Wellington Sears Company).
547
FIGURE 16.29 Three-dimensional fabric structure for athletic shoes (courtesy of Synthetic Industries).
548
16.1 General Industrial Textiles 549
fore, many times the physical properties of each mesh is 18 X 16 with colors of usually char-
product are custom tailored which is character- coal, silvery gray and bronze.
istic of technical textiles. As a result, design, Another common application area of textiles
manufacturing and testing of home and office is footwear. Structural components such as box
furnishings are getting more sophisticated. toes, counters, midsoles, insoles, doublers, heel
tucks and linings are made of textiles (Figure
16.28). Three-dimensional fubrics are used in
10. MISCELLANEOUS APPLICATIONS athletic shoes. Figure 16.29 shows a spring coil
fubric for high performance athletic shoes.
Woven glass fubrics, which are coated with a Substrates are used for coated fabrics for seat-
protective vinyl, are used for window and door ing materials, footwear upper materials, vertical
insect screening. The fabric is non-combustible blinds and car wash fabrics. Luggage is another
and does not rust, corrode or stain. The typical application area of textiles (Figure 16.30).
16.2
References and Review Questions
S. ADANUR
The major properties of textile fibers that have dices which are parallel with, and transverse to,
important industrial textile usage are included the fiber axis. The difference is called the "bire-
in this chapter. There are many synthetic fibers fringence." For all fibers except Saran® the par-
of the same generic class, manufactured by dif- allel index n, is greater than the transverse in-
ferent companies. For those fibers which are dex nw. and so the birefringence is always
reasonably well known or widely used, proper- positive. Refractive indices are useful for identi-
ties are listed generically and by trade names. fying fibers and, in research, indicating the
Fibers with lesser known trade names are nature of molecular order in experimental
grouped under their proper generic class, with fibers. While refractive index may influence
ranges of values being given wherever possible. fiber luster, the effect of fiber crimp and the
The continual introduction of new man-made state of aggregation of fibers in yarns and yarns
fibers makes it a genuinely impossible task to in fabrics are of far greater significance in ob-
present a tabulation which will remain up-to- taining or preventing fabric luster. Except as it
date for any reasonable length of time. Fiber is a measure of molecular order, which in turn
names, types, and properties are constantly may influence the tensile and elastic properties
changing. Therefore, caution should be exer- of fibers, refractive index is of no special signif-
cised in using the numerical data presented in icance in the industrial textile picture. Table 17.1
the following tables. This chapter also discusses lists refractive indices and birefringences of
the significance of fiber properties as they in- natural and man-made fibers.
fluence the performance characteristics of yarns
and fabrics.
Appendix 4 lists the characteristics, industrial 2. DENSITY (SPECIFIC GRAVITY)
uses and manufacturers of generic man-made fi- OF FIBERS
bers and trade names. Figure 17.1 shows longi-
tudinal and cross-sectional photographs of Table 17.2 lists densities of fibers. Density is
selected industrial fibers. defined as the ratio of a substance's unit volume
weight to that of water at 4 °C.
1. REFRACTIVE INDEX
3. FIBER FINENESS AND DIAMETERS
The refractive index (n) of a substance is
defined as the ratio of the velocity of light in a Table 17.3 lists fiber diameters (~tm) based on
vacuum to the velocity of light through the fllament deniers for selected fibers.
substance. Because of the molecular orientation
within fibers, the speed of light along the fiber
axis is usually different from that transverse to 4. FIBER STRENGTH AND TENACITY
the fiber axis. The greater the amount of orien-
tation and degree of crystallinity, the greater While it might be desirable to catalog the ab-
will be the difference between the refractive in- solute breaking strengths of individual fibers,
555
Name Photomicrographs
Asterisk denotes Cross section, 500X
trademark Longitudinal, 250X
Polyester
*A.C.E.
*Com pet
Allied
• Dacron
Du Pont
*Fortrel
Wellman
4DG
Eastman
*Tairilin
Nan Ya Plastics Corp.,
America
*Trevira
Hoechst Celanese
FIGURE 17.1 Photomicrographs of man-made fibers (courtesy of McLean Hunter Publishing Co.).
556
Name Photomicrographs
Asterisk denotes Cross section, 500X
trademark Longitudinal, 250X
Carbon
*Thorne I
Amoco
Nylon
Nylon 6
Nylon 6,6
Lyocell
* Tencel
Courtaulds
Rayon
*Fibro
Courtaulds
Cuprammonium
FIGURE 17.1 (continued) Photomicrographs of man·made fibers (courtesy of Mclean Hunter Publishing Co.).
557
Name Photomicrographs
Asterisk denotes Cross section, SOOX
trademark Longitudinal, 250X
Rayon
Norlh American
Rayon Corp.
*Saran
Pittsfield Weaving
Acetate
Acetate
Sulfar
*Ryton
Amoco
(Licensed by Phillips)
Acrylic
* Acrilan
Monsanto
*Creslan
*MicroSupreme
Cytec
FIGURE 17.1 (continued) Photomicrographs of man-made fibers (courtesy of Mclean Hunter Publishing Co.).
558
Name Photomicrographs
Asterisk denotes- Cross section, 500X
trademark Longitudinal, 250X
Modacrylic
* SEF
Monsanto
Olefin
Polyethylene
Hercules
* Herculon
Hercules
*Marvess
*Alpha
Amoco
*Essera,
*Marquesa Lana,
*Patlon Ill
Amoco
*Spectra 900
*Spectra 1000
Allied
FIGURE 17.1 (continued) Photomicrographs of man-made fibers (courtesy of Mclean Hunter Publishing Co.).
559
Name Photomicrographs
Asterisk denotes- Cross section, 500X
trademark Lonqitudinal, 250X
*Fibrilon
Synthetic Industries
Spandex
*Giospan/
Cleerspan, S-85
Globe
• Lycra
DuPont
Glass
Glass
Aramid
• Kevlar
DuPont
FIGURE 17.1 (continued) Photomicrographs of man·made fibers (courtesy of Mclean Hunter Publishing Co.).
560
Name Photomicrographs
Asterisk denotes Cross section, SOOX
trademark Longitudinal, 250X
* Nomex
DuPont
Fluorocarbon
* Gore-Tex
W. L. Gore
* Teflon
DuPont
Polybenzimidazole
PBI
Hoechst Celanese
FIGURE 17.1 (continued) Photomicrographs of man-made fibers (courtesy of Mclean Hunter Publishing Co.).
561
TABLE 17.1 Refractive Indices and Birefringences of Fibers ([1}, Fiber Manufacturers' Data).
Refractive Index
Birefringence
Fiber Parallel (n,) Transverse (nw) (n, - nw)
562
17.1 Fiber Properties and Technology 563
TABLE 17. 2 Density of Fibers [1, 2]. fiber's strength may be meaningless until it is
related to its cross-sectional area or its linear
Density
Fiber (mg/mm 3) density, i.e., weight per unit length. As is the
custom with all engineering materials, fiber
Polyester breaking strengths can be listed on a pounds per
ACE® 1.38
Compet®
square inch (psi) basis. More commonly, how-
1.38
Dacron® 1.34-1.39 ever, the textile trade uses the term "tenacity" to
FortreJ® 1.38 describe strength on a grams per denier (gpd)
Tairilin® 1.38 basis. This is because it is easier to determine a
Trevira® 1.38 fiber's or yarn's weight per length than its weight
Thorne!® carbon
per cross-sectional area, because yarn weight is
High strength 1.77
High modulus 1.77 an important textile physical and economic fac-
Ultra-high modulus 1.96 tor. Since denier is based upon weight per unit
Nylon 6 1.14 length, it is obvious that tenacity is influenced
Nylon 6,6 1.13-1.14 by the specific gravity of the fiber, while
TenceJ® lyocell 1.56
strength per unit area is not. The relationship
Viscose rayon 1.52
Cuprammonium rayon 1.53 between these properties is:
Saran 1.62-1.75
Acetate 1.32 tensile strength (lb per sq. in. or psi)
Ryton® sulfar 1.37
Acrylic 1.17
Modacrylic 1.35
= 12,800 X tenacity (grams per denier or gpd)
Nytril 1.20
Polyethylene, low density 0.92 x specific gravity (17 .1)
Polyethylene, high density 0.95
Polypropylene 0.90 In Table 17.4 tensile strengths are listed in psi
Spectra® olefin 0.97 and grams per denier for various fibers. The
Lycra® spandex 1.2
E-glass, single filament 2.54-2.69 relationship between tex and denier is:
S-glass, single filament 2.48-2.49
Glass, multifilament 2.5 denier
Aramid tex (17.2)
9
Kevlar® 1.44
Nomex® 1.38
Fluorocarbon Textile fibers are relatively light, therefore
Gore-Tex® 0.8-2.2 they can be highly efficient on a strength-to-
Teflon® 2.1 weight ratio basis. High tenacity nylon, for ex-
Polybenzimidazole 1.43 ample, with a specific gravity of 1.14 may have
Asbestos 2.1-2.8
a tenacity of 9 grams per denier (81 grams per
Flax 1.54
Cotton 1.54 tex) as compared with a high strength steel
Novoloid 1.28 (500,000 psi) or about 3.5 gpd. On a cross-
Polycarbonate 1.21 sectional area basis, high tenacity nylon has a
Silk 1.35 strength exceeding 100,000 psi.
Vinyon (PVC) 1.40
While textile fibers may have high tenacities,
Wool 1.31
often the corresponding strength of the textile
fabric is disproportionately lowered, due to the
inefficient translation of fiber strength into yarn
cross-sectional shapes and areas of fibers can strength and yarn strength into fabric strength.
vary widely. When subjected to a tensile force, This is particularly true with staple fibers.
the total strength of a fiber is dependent upon Because of non-uniform fiber lengths, interfiber
both its intrinsic ability to remain intact and slippage, random fiber orientation within the
upon its dimensions. The absolute value of a yarn, and the helical path of fibers due to yarn
564 FIBER PROPERTIES AND TECHNOLOGY
twist, only a part of the theoretically available ure. As a general rule it can be stated that an in-
strength, based upon the number of fibers in the verse relationship exists between fiber strength
yarn cross section, will actually result in the and elongation. For natural cellulosic fibers,
yarn. linen and ramie are stronger but have lower
Cotton has a tenacity of about 3.0 to 4.9 gpd elongations than cotton; the animal fibers are
(Zl to 44 gpt). Because it exists only as staple, much weaker but have greater elongations than
its fiber strength is not completely convertible the cellulosics. Glass fibers are very strong but
into equivalent yarn strength, the efficiency of very brittle, i.e., they have low elongations. In
the conversion being on the order of magnitude the manufacture of man-made fibers, for a par-
of 50%. Thus, cotton yarns usually have tenac- ticular generic type, a range of inverse strength-
ities not in excess of about 3 gpd (T/ gpt). The elongation values is normally obtainable. Thus
competitive advantages of multi-filament high nylon can be made with a tenacity of 9 gpd (81
tenacity rayon, nylon, or other synthetic yarns gpt), an elongation of 12% or 5 gpd (45 gpt) and
become obvious. an elongation of 30% .
It should be apparent that strength per se is
not the only criterion by which the performance
of textiles should be judged. Textile yarns and 6. FIBER LOAD-ELONGATION
fabrics are normally used because they have DIAGRAMS
flexibility and moderate strength, coupled with
the ability to deform or strain under load, Figure 17.2 shows fiber tenacity (gpd) versus
thereby absorbing energy, and the ability to percent elongation diagrams. Often such dia-
recover or retract when the load is removed. grams are popularly but somewhat erroneously
Many other chemical and physical properties called "stress-strain" curves. Actually the tenac-
will influence the ultimate selection of the fiber ity scale should be converted to a pounds per
and the yarn and fabric into which it is con- square inch (psi) scale in order to produce a true
verted. stress versus strain diagram. A variety of fibers
with a wide range of tenacity-elongation dia-
grams is available. The selection of a fiber for a
5. FIBER BREAKING ELONGATION particular purpose, of course, is dependent
upon many property requirements. The shape of
Table 17.5 lists breaking elongations or strains a fiber's load-elongation diagram, initially and
which fibers can undergo up to the point of fail- after the fiber has been cyclically loaded and
TABLE 17.4 Tensile Properties of Fibers [2}.
Breaking Tenacity (gpd)
Tensile Strength
Fiber Standard Wet (psi)
Polyester
A.C.E® and Compet®
Filament- HT 8.3-9.0 9.0 135,000-160,000
Dacron®
Staple and tow 2.4-7.0 2.4-7.0 39,000-106,000
POF 2.0-2.5 2.0-2.5 33,000-42,000
Filament- RT 2.8-5.6 2.8-5.6 50,000-99,000
Filament-HT 6.8-9.5 6.8-9.5 106,000-168,000
FortreJ®
Staple series 400-RT 4.8-6.0 4.8-6.0 85,000
Staple series 300-HT 6.0-6.8 6.0-6.8 102,000
PO filament 2.0-2.5 2.0-2.5 80,000-88,000
Tairilin®
POY 2.0-3.0 2.0-3.0 33,000-42,000
Staple 4.5-7.0 4.5-7.0 80,000-102,000
Trevira®
Staple 3.5-6.0 3.5-6.0 41,000-105,000
POF 2.0-2.5 2.0-2.5 33,000-42,000
Filament- HT 7.2-8.2 7.2-8.2 118,000-140,000
Thorne!® carbon
High strength 24.1 24.1 550,000
High modulus 21.3 21.3 500,000
Ultra-high modulus 10.8 10.8 270,000
Nylon
Nylon 6
Staple 3.5-7.2 62,000-98,000
Monofil. and filament-RT 4.0--7.2 3.7-6.2 73,000-100,000
BCF-RT 2.0-4.0 1.7-3.6
Filament-HT 6.5-9.0 5.8-8.2 102,000-125,000
Nylon 6,6
Staple and tow 2.9-7.2 2.5-6.1
Monofil. and filament-RT 2.3-6.0 2.0-5.5 40,000-106,000
Filament- HT 5.9-9.8 5.1-8.0 86,000-134,000
TenceJ® lyocell-HT 4.8-5.0 3.8-4.2
Rayon
Fibro®
RT- Multi-lobed 2.3 1.1
IT -0.9 den or 0.25 in and up 3.0 1.5
Cuprarnmonium, filament 1.95-2.0 0.95-1.1
Rayon
Filament- RT 1.9-2.3 1.0-1.4
Filament-HT 4.9-5.3 2.8-3.2
Saran®, monofilament 1.2-2.2 1.2-2.2 15,000-27,000
Acetate, filament and staple 1.2-1.4 0.8-1.0 20,000-24,000
Ryton® sulfar, staple 3.0-3.5 3.0-3.5 35,000-40,000
Acrylic
Acrilan®, staple and tow 2.2-2.3 1.8-2.4 30,000-40,000
Creslan®, staple and tow 2.0--3.0 1.6-2.7 30,000-45,000
MicroSupreme, staple 2.0-3.0 1.6-2.7 30,000-45,000
SEf® modacrylic, staple 1. 7-2.6 1.5-2.4 29,000-45,000
(continued)
565
TABLE 17.4 (continued).
Breaking Tenacity (gpd)
Tensile Strength
Fiber Standard Wet (psi)
Olefin
Polyethylene
Monofilament, low density 1.0-3.0 1.0-3.0 11 ,000-35,000
Monofilament, high density 3.5-7.0 3.5-7.0 30,000-85 '000
HerculonG~>
Staple 3.5-4.5 3.5-4.5 41 '000-52 '000
Buff filament 3.0-4.0 3.0-4.0 35,000-47,000
Marvess® and Alpha®
Staple and tow 2.0-5.0 2.0-5.0 60 '000-1 00 '000
Multifilament 2.5-5.5 2.5-5.5 20' 000-50 '000
Essera®, Marquesa Lana®, Pation® III
BCF 2.5-3.5 2.5-3.5 30 '000-40 '000
Staple 2.5-4.0 2.5-4.0 30,000-45,000
SpectraG~> 900 30 30 375 '000 '000
SpectraG~> 1000 35 35 425 '000 '000
Fibrilon®
Staple 2.5-5.5 2.5-5.5 12,000-60,000
Fibrillated 3.5-5.0 2.5-5.0 40,000-60,000
Multifilament- RT 2.5-5.5 2.5-5.5 20,000-50,000
Spandex
Glospan®fCleerspan, S-85, multifilament 0.7 11,000
Lycra®
Type 126, 127 1.0 11 '000-14' 000
Type 128 0.8
Glass
Single filament- E-glass 15.3 15.3 450' 000-5 50' 000
Single filament-S-glass 19.9 19.9 650,000-700,000
Multiftlament 9.6 6.7 313,000
Ararnid
Kevlar®
Kevlar 29/Kevlar 49 23 21.7 425,000
Kevlar 149 18 340,000
Kevlar 68 24.0 425,000
Kevlar HT (129) 26.5 490,000
Nomex®, staple and filament 4.0-5.3 3.0-4.1 90,000
Fluorocarbon
Gore-Tex® 3.0-4.0 3.0-4.0 85 '000-115 '000
Teflon®
TFE multifil., staple, tow, flock 0.9-2.0 0.9-2.0 40 '000-50' 000
FEP, PFA monofilament 0.5-0.7 0.5-{).7 14 '000-20 '000
PBI, staple 2.6-3.0 2.1-2.5 50,000
Asbestos 2.5-3.1 80 '000-300' 000
Cotton 3.0-4.9 3.3-5.39 59,500-97,000
Silk 2.4-5.1 1.75-4.01 38,500-88,000
Wool 1.0-1.7 0.85-1.44 16,500-28,000
Steel 3.5 3.5 512,500
HT: high tenacity.
POF: partially oriented filament.
POY: partially oriented yam.
RT: regular tenacity.
IT: intermediate tenacity.
566
TABLE 17.5 Breaking Elongation, Elastic Recovery, Stiffness and Toughness of Fibers [2].
Breaking
Elongation (%) Average Average
Stiffness Toughness
Fiber Standard Wet Elastic Recovery(%) (gpd) (gpd)
Polyester
A.C.E.<t and Compet®
Filament- HT 13-22 13-15 77 at 5%; 75 at 10% 55-56 0.7-0.9
Dacron<t
Staple and tow 12-55 12-55 82 at 3% 12-17 0.2-l.l
POF 120-150 120-150 1.3-1.8
Filament-RT 24-42 24-42 76 at 3% 10-30 0.4-l.l
Filament- HT 12-25 12-25 88 at 3% 30 0.5-0.7
Fortrel®
Staple series 400-RT 44-55 44-55 1.3-1.8
Staple series 300-HT 24 24
PO filament 120-150 120-150
Tairi!in®
POY 120-170 120-170 1.3-1.8
Staple 28-6 28-55 88 at 3% 10-30 0.3-1.5
Trevira<t
Staple 18-60 18-60 67-86 at 2% 7-31 0.28-1.50
57-74% at 5%
POF 130-145 130-145 1.3-1.8
Filament- HT 10-20 10-20 99 at 1% 54-77 0.35-0.55
Thorne(® carbon
High strength 1.6 1.6 100 1,500
High modulus 1.0 1.0 100 2,300
Ultra-high modulus 0.38 0.38 100 3,000
Nylon
Nylon 6
Staple 30-90 42-100 100 at 2% 17-20 0.64-0.78
Monofil. and filament-RT 17-45 20-47 98-100 at 1-10% 18-23 0.67-0.90
BCF-RT 30-50 30-60
Filament-HT 16-20 19-33 99-100 at 2-8% 29-48 0.75-0.84
Nylon 6,6
Staple and tow 16-75 18-78 82 at 3% 10-45 0.58-1.37
Monofil & fllament-RT 25-65 30-70 88 at 3% 5-24 0.8-1.25
Filament-HT 15-28 18-32 89 at 3% 21-58 0.8-1.28
Tence1® 1yocell- HT 14-16 16-18 30 0.34
Rayon
Fibro®
RT- Multi-lobed 18-22
IT -0.9 den or 0.25 in and up 18-22
Cupranunonium, filament 8-14 24-28
Rayon
Filament-RT 20-25 24-29
Filament- HT 11-14 13-16
Saran®, monofilament 15-25 15-25 95 at 5-10% 5-10 0.165-0.265
Acetate, filament and staple 25-45 35-50 48-65 at 4% 3.5-5.5 0.17-0.30
Ryton® sulfar, staple 35-45 100 at 2%; 86 at 10% 10-20
Acrylic
Acrilan<t, staple and tow 40-55 40-60 99 at 2%; 89 at 5% 5-7 0.4-0.5
Creslan®, staple and tow 35-45 41-50 6-8 0.62
MicroSupreme, staple 30-40 30-40 6-8 0.62
SEf® modacrylic, staple 45-60 45-65 100 at 1 %; 95 at 10% 3.8 0.5
(continued)
567
TABLE 17.5 (continued).
Breaking
Elongation (%) Average Average
Stiffness Toughness
Fiber Standard Wet Elastic Recovery(%) (gpd) (gpd)
Olefin
Polyethylene
Monofilament, low density 20-80 20-80 Up to 95 at 5% 2-12 0.3
88 at 10%
Monofilament, high density 10-45 10-45 Up to 100 at 1-10% 20-50
Herculon~
Staple 70-100 70-100 96 at 5%; 90 at 10% 20-30 1-3
Buff filament 80-100 80-100 96a at 5%; 90 at 10% 20-30 1-3
Marvess~ and Alpha~
Staple and tow 60-100 80-98 90-93 at 5%; 83 at 10% 3-10 1.5-4
Multifilament 20-50 85-99 92-96 at 5%; 87 at 10% 12-25 0.75-3.00
Essera~, Marquesa Lana~, Pation~ III
BCF 40-60 40-60 90 at 5%; 65-90 at 10% 5-10 0.9-1.05
Staple 30-450 30-450
Spectra~ 900 3.6 3.6 1,400
Spectra® 1000 2.7 2.7 2,000
Fibrilon®
Staple 30-150 30-150 93 at 5%; 85 at 10%
Fibrillated 14-18 14-18 85 at 5%; 75 at 10%
Multifilament- RT 30-100 30-100 95 at 5%; 85 at 10% 12-25 0.75-3.00
Spandex
Glospan®/Cleerspan, S-85, multifilament 600-700 99% at 50% (S-7) 0.17 (S-7)
98% at 200% (S-5) 0.05 (S-5)
Lycra®
Type 126, 127 400-625 97 at 50% 0.13-0.20 2.00
Type 128 800 99 at 200%
Glass
Single filament- E-glass 4.8 4.8 100 320 0.37
Single filament-S-glass 5.3-5.7 5.3-5.7 100 380 0.53
Multifilament 3.1 2.2 100 310 0.15
Aramid
Kevlar®
Kevlar, Kevlar 29/Kevlar 49 4.0/2.5 4.0/2.5 100 at 1%, 2%, 3% 500/900
Kevlar 149 1.5 100 at 1% 1,110
Kevlar 68 3.0 100at1%,2% 780
Kevlar HT (129) 3.3 100 at I%, 2% 755
Nomex®, staple and filament 22-32 20-30 70-120
Fluorocarbon
Gore-Tex® 5-20 5-20
Teflon®
TFE multifil., staple, tow, flock 19-140 19-140 1.0-13.0 0.15
FEP, PFA monofilament 40-62 40-62 7.0 0.10-0.12
PBI, staple 25-30 26-32 9-12 0.40
Cotton 3-7 74 at 2%; 45 at 5% 60-70 0.15
Silk 10-25 92 at 2%; 51 at 10% 60-116 0.4-0.8
Wool 25-35 25-50 99 at 25%; 63 at 20% 4.5 0.35
HT: high tenacity.
POF: partially oriented filament.
POY: partially oriented yarn.
RT: regular tenacity.
IT: intermediate tenacity.
568
9 8
ua.
:0
a. !::!' 6
6
~ ~
?: u
u "'c:
Ill
4
"'c: f-
~ 3
2
5 10 15 20 25 10 20 30 40 50 60
Elongatton (%) Elongalton (%)
6
"0
a.
0'1 4
40 1.0 1.5
Elongat10n ('Yo) Elongalton (%)
Trevira* Thornel*
Polyester Carbon
5 3
4 2.5
0 2 Regular
0 3 H1gh tenacity a.
a. ~
2'
?:
~ u
u 2
"'
c "'c
I])
~ 1-
5 10 15 20 25
5 10 15 20 25
Elongat1on (%) Elongat1on (%)
Fibro* Cuprammonium
Rayon
FIGURE 17.2 Typical tenacity versus elongation diagrams of fibers (courtesy of Mclean Hunter Publishing Co.).
569
4 3
3
2.
'0
a.
ua.
!!J 2 ~ 1.5
~ ~
u
ro
u
ro
c: c:
~
Ql
t- 5
10 20 30 40
Elongalton {%) Elongalton I'Vo)
Ryton* Acrilan*
Sulfar Acrylic
7
6
4 5 Ftlarnent (420-den)
ua. u
a.
~ ~ 4
Staple
?: ?'
u .2 u
ro
3
ro c:
c:
Ql
t-
Ql
t-
2
70
Elongalton !'*•) Elongatton ('lin)
Polyethylene Herculon*
Olefin
~ ~t
8
S-7 S-5
Staple .6
ua.
-~ Fibrillated
~ 4
~ 3 ?'
u
8.
VI
2 ro
c:
Ql .2
t-
E
~
(!)
Fibrilon* Glospan*
Olefin Spandex
FIGURE 17.2 (continued) Typical tenacity versus elongation diagrams of fibers (courtesy of Mclean Hunter Publish-
ing Co.).
570
~:f
8
150.000%/rTllrl
6 f"'HT
'0
a.
£' 4
~ I~
i=" >3 I ~--- RT
u
<'0
c:: G2 I
....C1i 2 <
ffi1
....
4 8 12 14 16 18 00 5 10 15 20 25 30
ELONGATION %
Elongation ('l•bJ
Nomex* Gore-Tex*
Aramid Fluorocarbon
8 High tenac1ty 8
H1gh- tenac1ty staple
6 6
~
Cl.
S!! 4
?:
4
u
<'0
c::
(j)
.... 2 2
20 30 40 50 10 20 30 40 50
Elongal•on (%1 Elongation (%)
571
25 6
Flat
5
ua. 4
~
?: 3
u
"'c:
<I>
2
I-
Saran Rayon
4 4
3
:0 3
ua. a..
~
~
2 .~ 2
?: u
u
"'
c: "'
c:
11)
I-
~
10 20 30 40 50 10 20 30
Elongatton (%)
Elongation(%)
Creslan* Acrylic
Acrylic
7
5 Marquesa Lana
6 Amoco XXV
5 4
ua. 4 u
a.
~ Ol
?: 3
u u 2
"'c:
<I> 2 "'c:
I- ~
10 20 30 40 50 60 70 10 20 30 40 50
Elongation (%) Elongation (%)
572
5 Conditioned 1.6
4 1.2
'0
a. 3 Wet &
g) ~ .8
~ ~
u 2 u
"'t:
..._
C1> "'c:
Ql
..._ .4
1
5 10 15 20 25 5
Elongat1on (%) Elongat1on (%)
3 40
'0
a. '0 30
g) a.
2 g)
~
u £20
u
co co
t: t:
..._C1>
~ 10
10 20 30 40 50 60 1 2 3 4 5
Elongalion (%) Elongation (o/o)
.8 15
'0 .6 '0
a. a.
£' £' 10
>.
~
u .4 u
co
co t:
t:
~ ~ 5
400 600 2 3 4 5 6
Elongation ('llo) Elongat1on (%)
Lycra* Glass
Spandex
FIGURE 17.2 (continued) Typical tenacity versus elongation diagrams of fibers (courtesy of McLean Hunter Publish-
ing Co.).
573
16
12
-o0.
~ 8
~
u
"'c:
Q) .4
1-
10 20 30 40 50 60
Elongation ("lu)
Teflon*
Fluorocarbon
20 22
18
15
-o0. ~ 14
0.
£l 10 ~
10
~ ~
u u
c:
<1) <1)
c: 6
~ 5 QJ
....
2
2 3 4 5 6 5 10 15 20
Elongat1on (%) Elongation (%)
Glass Kevlar*
Aramid
16
1.2
-o0. 4
£l .8
~ 3
u
"'c:
Q) 2
1-
10 20 30 40 50 60 5 10 15 20 25
Elongat1on ("lo) Elongat1on 1"'"1
Teflon* PBI
Fluorocarbon Polybenzimidazole
FIGURE 17.2 (continued) Typical tenacity versus elongation diagrams of fibers (courtesy of McLean Hunter Publish-
ing Co.).
574
17.1 Fiber Properties and Technology 575
unloaded at loads below rupture, is important in that during selected periods of progressive load-
terms of the fiber's influence on such fabric ing, they may function in a perfectly "elastic" or
properties as breaking and tear strength, energy "spring-like" manner. During other periods of
absorption, dimensional stability, and abrasion loading a "viscous flow" or creep type of defor-
resistance. mation occurs. These two mechanisms most
often act in varying contributory amounts at the
same time and thus produce a viscoelastic type
7. VISCOELASTICITY of stress-strain response.
The above description pertains to the applica-
Examination of fiber load-elongation dia- tion of a tensional force in one time loading to
grams shows that they are normally "non- rupture. If a specimen is strained (elongated) to
Hookean;' i.e., they do not obey Hooke's law a value below rupture and the strain producing
which states that the strain (elongation) is lin- force is then removed, a strain recovery will
early proportional to the applied stress (load). usually take place. Repeated load applications
Figure 17.3 for a typical polyester, for example, and removals produce strains and recoveries
shows an original region OA which is approx- which are dependent upon the material's vis-
imately linear. Point A is called the "propor- coelastic properties. The phenomenon becomes
tional limit." Beyond this point, region AB devel- complex, giving rise to hysteresis [Figure
ops where additional incremental loads produce 17.10(b)] . The elongation recovery or "repeated
proportionately larger increases in elongation, stress" characteristics of fibers is discussed later
due to the propensity of the fiber to "creep," or in the chapter. They are of great significance
slowly elongate under load. A slope change because they influence such properties as fabric
occurs at point B, followed by a stiffening re- dimensional stability, wrinkle resistance, abra-
gion BC where additional loads beyond B cause sion resistance, and energy absorption.
smaller changes in elongation. Finally there is a
second flow region CD.
Textile fibers and other high polymers such as 8. ELASTIC MODULUS
rubbers, elastomers, films, and plastics which
exhibit such varying "stress-strain" properties The ratio of stress to strain is called the
are stated to be "viscoelastic." The molecular "modulus" of a material. High modulus mate-
and structural nature of these materials is such rials are stiff; they show small elongation under
5 10 15 20 25 30
"Ye STRAIN
load. Low modulus materials are extensible; it is properly defined. ASTM also lists the fol-
they show high elongation under load. "Young's lowing moduli definitions for textile materials:
modulus" is defined by ASTM as the ratio of
• initial modulus: the slope of the initial
change in stress to change in strain within the
straight-line portion of the stress-strain
elastic limit of the material. The ratio is
curve
calculated from the stress, expressed in force
• chord modulus: the ratio of the change
per unit cross-sectional area, and the strain, ex-
in stress to the change in strain between
pressed as a fraction of the original length.
two specified points in the stress-strain
Young's modulus is of great value to the en-
curve
gineers utilizing wood, structural steel, and
concrete since these materials are used below
their elastic limits, and small deformations 8.1 Determination of Initial Modulus
under load can be calculated with a reasonable
degree of precision. The textile engineer and In the case of a fiber exhibiting a region that
technologist also make use of this ratio, but obeys Hooke's law (i.e., has a linear region), a
because load-elongation diagrams of textiles are continuation of the linear region of the curve is
not usually linear over their entire use range, constructed as shown in Figure 17.4. The inter-
the "tensile modulus" of a fiber is not a constant section point B is the zero-strain point from
and should be used only under conditions where which strain is measured. The initial modulus is
/o
/
/
/
/
F
/
/
h
/
/
V'1 /
....,
V'1
...
a: /
V'1 /
/
/
/
/
/
/
TANGENT POINT V
v
A 8 STRAIN
FIGURE 17.4 Construction of initial modulus for materials with Hookean region [4].
17.1 Fiber Properties and Technology 577
I
I K'
I
/
/
/
I
/
/
I
FIGURE 17.5 Construction of initial modulus for materials with no Hookean region [4].
determined by dividing the stress at any point is constructed through the zero-stress axis, such
along the line BD by the strain at the same point as zero strain point A 11 and a second point, such
(measured from point B). Point C, the point as 10% strain, point M 11 (Fi~ure 17.6). The
where line BD first touches the stress-strain chord modulus is determined by dividing the
curve is the tangent point. stress at any point along line A "M 11 (or its ex-
In the case of a fiber that does not exhibit any tension) by the strain at the same point.
linear region (Figure 17.5), a tangent K 'B' is Figure 17.6 also represents a straight line con-
constructed to the maximum slope. Point B' is structed through any two specified points, point
the zero point from which strain is measured. Q II and point R 11 , other than zero and 10%
Point C' , the point where line K 'B' first strain. In this case, the line extends through the
touches the stress-strain curve, is the tangent zero stress axis at point B 11 • This intersection is
point. The initial modulus is determined by the zero strain point from which strain is
dividing the stress at any point along line B' K' measured. The chord modulus can be deter-
by the strain at the same point (measured from mined by dividing the stress at any point along
point B'). line Q 11R 11 (or its extension) by the strain at the
same point (measured from point B 11) .
8.2 Determination of Chord Modulus The modulus is also called the "stiffness" of
the material since the higher the modulus the
In a typical stress-strain curve, a straight line greater the resistance to deformation.
578 FIBER PROPERTIES AND TECHNOLOGY
V"'
V"'
.....
....a:
V"'
Since engineering stress is given in pounds Spectra® olefin, and Kevlar® ararnid fibers have
per square inch, modulus units for engineering moduli far above the range of other textile
materials normally are reported as psi per unit fibers. This is why these high modulus fibers,
strain, or simply psi. Again, because conve- yams, or fabrics are used in plastic laminates
nient textile nomenclature uses the denier where minimum distortion under load is re-
system, Young's moduli of fibers are reported as quired. However, because of their high modulus
grams per denier per unit strain, i.e., the hypo- and inability to deform under load (i.e., brittle-
thetical tenacity required to strain the filament ness), excessively high stress concentrations
100% , presuming strain extended at a rate equal may be induced in these fibers, and they may
to that of the initial slope of the stress-strain fail. In other low modulus fibers, the high
curve. The modulus (stiffness) is usually re- strains resulting from the application of the non-
ported simply as "grams per denier:' Moduli of uniform loads reduce the stress concentration,
major textile fibers are given in Table 17.5. Ex- and the fiber can remain intact. This, among
tensible fibers such as wool, acetate and acrylic other reasons, is why high modulus fibers have
have low textile moduli. Nylon and polyester not found wide use in textile fabrics where
can be drawn to varying degrees so that their repeated flexing and abrasion, both being ex-
moduli may have varying ranges (on the aver- amples of non-uniform loading, are required. In
age, polyester slightly higher than nylon). Glass uses where deformations are necessary, particu-
at 300 has a high modulus. However, carbon, larly under impact conditions, low modulus rna-
17.1 Fiber Properties and Technology 579
terials are advantageous, for the material will belts, bagging, webbings, tents, awnings, and a
then extend rather than permit the buildup of an wide array of industrial uses where a combina-
excessive force. tion of lightness, strength, and toughness is re-
quired. Such end items usually are used many
times, and therefore a further requirement is
9. TOUGHNESS OR that they can repeatedly deform and absorb en-
ENERGY ABSORPTION ergy under load, and retract when the load is
removed.
The load-elongation diagram is a measure of
work done or energy absorbed by the filament.
This property is also called "toughness." Units 10. ELONGATION-RECOVERY
normally are grams per denier (or tex). Table PROPERTIES
17.5 lists energy absorption capacities of the
various fibers. If a vertically suspended textile fiber is dead-
Figure 17.7 shows that equal areas (i.e., ener- loaded with a weight equal, for example, to
gies) under a load-elongation diagram can be about half of its breaking load, the fiber will im-
obtained via many different paths. For example, mediately elongate a fixed amount (Figure 17.8,
the area bounded by OBC is equal to OB 'C' ; part A). This elongation from 0 to 1 is called the
but for Case I it is obtained via high strength "instantaneous elastic deflection" (lED). If the
and low elongation, while for Case IT the weight is then left hanging on the fiber for many
strength is lower but the elongation is higher. minutes or hours, the fiber will continue to
Except in those cases where energy must be elongate or "creep" at a slow rate from 1 to 2
absorbed with a minimum amount of deforma- (part B). If the weight is then removed, the fiber
tion or elongation in the specimen, in order that will immediately and instantaneously recover or
the material maintain its dimensional stability, a spring back by an amount approximately equal
combination of load bearing and elongation to the original lED. The recovery (from 2 to 3,
capacities is usually desirable. For example, part C) is called the "instantaneous elastic
glass is strong but its elongation is too low to be recovery" (IER). If the weight is then kept off,
a good energy absorber. Wool is weak but is the fiber will tend to "creep back" and return to
quite extensible, and so can absorb significant its original length. The amount which it re-
amounts of energy. However, because its load covers (3 to 4, part D) is called "primary creep"
supporting capability is low and because the or "creep recovery." The amount by which it
wool yarn, cord or fabric would become highly fails to return to its original length (4 to 0), is
distorted, normally it is not used for industrial called "secondary creep" or "permanent set."
purposes. Cotton, high tenacity rayon, and es- Diagrammatically, the elongation versus time
pecially polyester and nylon are tough, and curve is depicted in Figure 17. 9.
hence have been widely used in ropes, conveyor The instantaneous elastic deflection obeys
Hooke's law, which states that the strain (elon-
gation) is linearly proportional to the applied
stress. Thus, if progressively increasing weights
are hung on the fiber, the resulting lED's will be
0
proportional to the applied loads and a linear
~ load-lED diagram results. The creep portion of
g the elongation is the viscous effect referred to
earlier. While, in practice, textiles may be dead
c loaded under a constant force, more often they
are subjected to a heterogeneous combination of
ELONGATION
repeated below-rupture stresses and strains.
FIGURE 17.7 Energy absorption diagram. When a specimen is progressively loaded to a
A B c D
r-- --,
: -w :
0 L---r--_. 0
I
I
I }
r------,
: -w :
I
r--.lt---, D '---x--.J
l +W : •I
--.,
L------.J I
: Tl ,----
: -w :
}3 GJ
11
:
r---'1:--.,
+W ...l
l.. ______
REEP
2
~---:---'
GJ
1 IER
2
3
B
z
0
Ei
~ I
IER
z
g TOTAL : C
w CREEP 11
II
II
-------------.JI•
I
TIME
FIGURE 17.9 Elongation as a function of time under constant load and load removal.
580
17.1 Fiber Propenies and Technology 581
I
, I I
I
0 ,/ 0 I
, I
9 , , "' 9 fl I
I
I
level below its rupture point, and then the load most important properties which textile fabrics
is progressively removed, one of the three types must have. Several pertinent examples are cited.
of load-elongation-recovery diagrams shown in
Figure 17.10 will result. (1) Ability to absorb energy repeatedly- In
Figure 17.10(a) depicts a truly Hookean ma- order to be repeatedly useful, pump dia-
terial where the strain (elongation) is propor- phragms, aircraft arrestation cables, con-
tional to the applied stress (load) over the entire veyor belts, tire cords, fire hoses, crane
curve. Only instantaneous elastic deflection and slings, and the like must be capable of
recovery exist, thus producing a straight line for retracting absorbing energy. This is ac-
both loading and unloading, the two lines being complished by the materials' elongation
superimposed at all points. Such a condition under load. If a fabric is to be used more
represents "perfect elasticity." than once, it must be capable of retracting
Figure 17.10(b) represents a condition where to its original dimension after use in order
the strain is not proportional to the load, thus that it again will have the ability to absorb
creep causes additional elongation. However, an equal amount of energy on second or
all the creep is primary, and upon load removal, subsequent uses. If most of the elongation
complete recovery takes place, but via a path is non-recoverable secondary creep, the en-
different from the loading curve, thus producing ergy absorption capacity on a subsequent
a "hysteresis" area. The primary creep recovery, use will be significantly reduced to the
while complete, is delayed and requires a longer point where failure may result.
recovery than the original loading time to be (2) Ability to maintain dimensional stability-
completed. Such a condition represents "com- A tarpaulin, truck cover, auto seat cover, or
plete elasticity." Figure 17.10(c) also represents a tent may be subjected to deforming forces
condition where the strain is not proportional to resulting from handling, or wind and
the load, thus creep causes additional elonga- weather. Its ability to deform or "roll with
tion. Here, however, secondary as well as pri- the punch" on load application, and return
mary creep exists. Upon load removal recovery to its original dimension on load removal is
is incomplete, and a "permanent set" repre- necessary if the fabric is to be capable of
sented by 0-X results. Such a condition repre- absorbing stresses and strains repeatedly
sents "imperfect (and incomplete) elasticity." without becoming distorted and out-of-
shape. In the case of conveyor belts, while
Significance of Elongation- high modulus-low elongation fabrics are
Recovery Properties usually demanded to keep "stretch" to a
minimum, nevertheless the ability of the
The abilities to deform upon load application material to "give" slightly under load and
and recover upon load removal are two of the recover upon load removal is a prerequisite.
582 FIBER PROPERTIES AND TECHNOLOGY
(3) Wrinkle resistance-When fabrics are subjected. These are simple compression, shear,
creased, yams and fibers are bent in a man- torsion, and bending (Figure 17.11).
ner such that some portions are in compres- One of the outstanding attributes which a tex-
sion, and others are in tension. Creases tile fiber must have is flexibility. In fact, this re-
which develop will be removable as a func- quirement probably should be included as an in-
tion of the ability of the fibers to recover tegral part of the definition of a textile fiber. The
from the imposed strains. ability of the fiber repeatedly to bend and re-
(4) Abrasion resistance-As will be discussed cover without failure is vital for most fabric
later in the chapter, a fabric's abrasion re- uses. The stiffness of a textile fiber or any struc-
sistance is governed in part by the capacity tural beam, is directly proportional to its elastic
of its fibers to absorb energy repeatedly at modulus, and to the fourth power of its di-
stresses below rupture. The fibers must be ameter. The modulus is governed by the intrin-
able to deform under the force produced by sic nature of the fiber substance, i.e., the ar-
the abrasive action and to recover when the rangement of atoms in the molecule, the amount
force is removed. Then, upon a subsequent of crystallinity, and the molecular orientation.
abrasion stroke, the fibers again can deform Organic fibers, in general, have stiffness
and absorb energy without failure. moduli in the range of 10 to 200 grams per
denier (Table 17.5). Rubbery or elastomeric
Table 17.5 shows the percent recovery of materials have moduli of about 0.1 to 0.5 gpd.
fibers which have been strained by varying Glass, metals, and ceramics are in the range of
amounts. After being strained 2%, staple Nylon 250 to 350. Conventional organic fibers have
6, upon load removal, will recover to its original sufficient flexibility for most textile uses when
unstrained dimension. The Nylon 6 is thus said their diameters are in the 10 to 70 micron range.
to recover 100% from the 2% strain. After 3% In order for glass, ceramic, and metallic fibers
strain, regular tenacity Nylon 6,6 recovers 88%. to enjoy equal flexibility, they must be of even
This recovery capability, coupled with its high smaller diameter because of their higher
energy absorption permits it to repeatedly ab- moduli. Furthermore, the stiffness increases in
sorb large quantities of energy, thus accounting direct proportion to the fourth power of the di-
for nylon's excellent abrasion resistance. ameter, and so it becomes obvious that high
modulus fibers must be drawn to very fine di-
ameters if they are to be sufficiently flexible to
11. RATE OF RECOVERY PROPERTIES perform as textiles. Furthermore, the specific
gravities of glass, ceramics, and metals are con-
The more quickly and completely a fiber re- siderably higher than the organic polymers.
covers from an imposed strain, the more nearly Therefore, inorganic fiber diameters must be
perfectly elastic it is. The ratio of the instan- small, not only to attain flexibility, but also to
taneous elastic deflection to the total deflection reduce fiber weight.
may be used as a criterion of elasticity. The inte- In simple compression, forces act in opposi-
grated closeness from a theoretical graph of tion to the direction they assume for tension. In
perfect elasticity versus elongation is also used the case of textiles, unless the fiber, yarn, or
as a criterion under the term "elasticity index." fabric is very short; true and complete compres-
sion does not exist, for the fiber will buckle and
bending will result. This produces tension on
the outside portion of the fiber and compression
12. BENDING, COMPRESSION, on the inside. Similarly, torsion and shear
SHEAR, AND TORSION STRAINS forces are negligible in flexible textile fibers,
since the initial development of such forces pro-
In addition to tensile forces and strains, there duces strains in the material of such a magni-
are four other types of deformations to which tude that the forces immediately become ten-
engineering materials including textiles, may be sional.
r -- --, F
1
r ----------- -,
I
I
I
I
I
I I
I 1
I I
' ·l '
'---~--~
L-------------- J
F
r
F
- - - ORIGINAL ORIGINAL
------ AFTER EXTENSION AFTER COMPRESSION
F • EXTENSION FORCE
F • COMPRESSION FORCE
TENSION COMPRESSION
---------------
-----------------
- - - ORIGINAL
------ AFT£R BENDING
M • BENDING FORCE
BENDING
.
---·----
F
I
I
'I I
\
I
I M
I
I
E ,
ORIGINAL ORIGINAL
------ - AFTER SHEARING AFTER TORSION
F • SHEARING FORCE M • TORSIONAL FORCE
SHEAR TORSION
583
584 FIBER PROPERTIES AND TECHNOLOGY
13. LOOP STRENGTH The greater the rupture elongation, the greater
is the ability of the fiber to bend without failing.
Table 17.6 lists fiber loop and knot strengths. High modulus fibers have low loop strength
The loop strength test consists of looping one efficiences and weak, extensible fibers have
length of a fiber through another loop as shown higher efficiencies. Remember, however, that a
in Figure 17.12, and elongating the loops until less efficient, but originally stronger, fiber may
rupture occurs. As the rupture elongation in- have a higher absolute loop strength than a more
creases, the loop strength efficiency also in- efficient weaker fiber. Cotton has a remarkably
creases. The reason being that in low elongation high loop strength accompanying its nominal
brittle fibers, high stresses are quickly built up elongation. Aramids, nylon and polyester being
and tensile failure occurs. High elongation fibers tough, strong fibers, exhibit high absolute loop
can extend rather than fail, and a more efficient strength.
break ultimately results. When a fiber is bent
around itself, a tension strain develops on the 14. KNOT STRENGTH
outside and a compression strain on the inside.
Knot strengths of several fibers are listed in
Table 17.6. The knot test consists of making a
simple overhand loop (Figure 17.13) and then
f subjecting the specimen to a tensile pull. The
general efficiencies (i.e., the ratio of knot to
JAW 3XI" tensile strength) of knot strengths are about the
same as for loop strengths, and for the same
reasons.
Loop and knot strengths of yarns and cords
are functions of the intrinsic fiber properties
and the geometry of the yarn or cord structure.
The actual formation of a knot can cause se-
lected fibers, depending upon their position
within the yarn, cord, or rope, to be bent into a
configuration so that the resulting strain exceeds
the fiber's rupture elongation, and therefore
some fiber breakage occurs. Other fibers in the
knot are not so strained, and so complete failure
of all fibers is avoided. The higher its rupture
elongation the greater is the opportunity for the
fiber to be strained without failure. After a knot
is formed in a yarn and it is then subjected to a
loading force, the necking down or compacting
of the knot into a smaller, denser structure can
also produce excessive strains in certain fibers,
depending upon their position. All of the fibers
within the knot are not subjected to the same
amount of strain. This maldistribution of
stresses and strains among the fibers causes
some to fail prematurely. The load they were
carrying then is transferred to the remaining in-
tact fibers. However, this added load may then
exceed the capacity of the adjacent fibers and
they, too, fail. Thus, the failure proceeds from
FIGURE 17.12 Loop strength test. fiber to fiber and the entire cord or rope fails.
TABLE 17.6 Fiber Loop and Knot Strengths {2].
Fiber Loop Strength (gpd) Knot Strength (gpd)
Polyester
A.C.E® and Compet®, filament-HT 6.0-7.0 5.0-6.0
Dacron®
Staple and tow 2.1-6.4 2.1-6.4
Filament- RT 2.5-5.2
Filament- HT 5.6-5.8
FortreJ®
Staple series 400-RT 4.4-5.6
Staple series 300-HT 5.6-6.0
Tairilin®, staple 2.0-5.6
Trevira®
Staple 1.2-5.6 2.0-5.6
Filament- HT 4.4-6.7 4.0-6.3
Nylon
Nylon 6
Monofil. and filament-RT 3.8-5.6 3.8-5.5
BCF-RT 2.0-3.0 2.0-3.0
Filament-HT 5.1-10.1 4.8-6.7
Nylon 6,6
Staple and tow 3.7-5.9 3.7-5.9
Monofil. and filament-RT 2.0-5.1 2.0-5.1
Filament-HT 5.0-7.6 5.0-7.6
TenceJ® lyocell- HT 2.2-2.6 2.1-2.3
Cuprammonium rayon, filament 2.15-2.25
Saran®, monofilament 0.7-1.1 1.0-1.7
Acetate, filament and staple 1.0-1.2 1.0-1.2
Acrylic
Acrilan® 1.9-2.6
Creslan®, staple and tow 1.9-2.3
MicroSupreme, staple 2.5-3.0
SEF® modacrylic, staple 1.6-2.5
Olefin
Polyethylene
Monofilament, low density 1.0-2.5
Monofilament, high density 2.5-4.0 2.5-4.5
Herculon®
Staple 3.0-4.0
Bulk filament 2.5-3.5
Glass, multifilament 4.0 0.9
Aramid
Kevlar®
Kevlar 29/Kevlar 49 10.5 7.6
Nomex®, staple and filament 4.0-5.0
Fluorocarbon
Gore-Tex® 2.5-3.3 2.5-3.3
Teflon® TFE multifil., staple, tow, flock 0.8-1.4 0.8-1.4
Cotton, mercerized 2.5
585
586 FIBER PROPERTIES AND TECHNOLOGY
15. FRICTION
F
p,=- (17 .3)
N
where
p, = coefficient of friction
F = frictional force
FIGURE 17.13 Simple knot test.
N = normal force
-
employed in a much broader sense and encom-
passes all of the interacting factors which may
cause fabrics to fail; for example, rubbing, flex-
FIGURE 17.14 Frictional forces between two sliding ing, snagging, impacting, stretching, twisting,
surfaces. and exposure to chemicals, wind, sunlight,
weather, wetting, drying, heating, and the like.
Much time and effort have been expended;
scale structure of wool and other fur fibers is the technical literature is replete with articles,
considered to act as a ratchet which allows mo- and the industry is constantly faced with the
tion in one direction, but resists it in the other, problems of predicting the abrasion and wear
thus producing DFE (Figure 17.15). resistance of new fibers and fabrics. The prob-
lems are complex. They include the selection of
16. ABRASION AND laboratory abrasion test methods and specifica-
WEAR RESISTANCE tions, determination of the intrinsic abrasion re-
sistance of new candidate fibers, the influence
It is necessary to define these two terms at the of yam and fabric geometry, and the degree to
outset. Textile technologists generally agree that which laboratory abrasion and other physical
1. 2. 3. 4. 5. 6. 7.
FIGURE 17.15 Surface of various fibers: 1. wool, 2. cashmere, 3. mohair, 4. camel, 5. mink, 6. cotton, 7. rayon (cour-
tesy of Albany International).
588 FIBER PROPERTIES AND TECHNOLOGY
tests correlate with service performance. It is sharp abradant of small particle size
beyond the scope of this book to discuss in great relative to the fiber diameter-This action
detail and review the work of the many people would be typified by rubbing the fabric with
who have engaged in research in this important a fine piece of emery cloth, and is repre-
area of textile technology. However, the follow- sentative of the way many laboratory abra-
ing sections discuss the concepts which various sion testers abrade fabrics.
investigators have proposed with respect to the (3) Fiber rupture or slippage caused by rubbing
intrinsic abrasion resistance of textile fibers and the fiber with an abradant where the parti-
other materials. The influence of yarn and cle size is large compared with the fiber di-
fabric structure on abrasion resistance and a ameter-The fiber is then caught and
description of laboratory abrasion testers is plucked like a violin string. The fiber may
given in Chapter 19.0, Fabric Properties and be broken, or partially or completely pulled
Technology. away from its neighbors in the yarn and
The criteria selected to judge abrasion or fabric, thus producing a disrupted ap-
wear resistance must be based upon the fabric's pearance.
function. For example, for a tarpaulin, mainte-
In addition to fiber degradation or attrition,
nance of breaking and tear strength is required.
these mechanisms particularly the third, can
Changes in fabric thickness, weight, water
significantly alter the positions of the yarns in
permeability, electrical resistivity, surface luster,
the fabric, cause the fabric to distort, and other-
color, air permeability, the initial appearance of
wise change the fabric structure. Backer also
broken threads, or formation of a hole, are other
pointed out that transverse rubbing action
criteria that are used or have been considered.
across a fiber can produce tension within the
Probably the three most widely used laboratory
fiber.
criteria are:
Hamburger [6] examined the influence of the
(1) Direct visual comparison of fabric ap- tensional repeated stress properties of fibers on
pearance against a known standard, after abrasion resistance. He states that abrasion is a
both the test sample and the standard have repeated stress application caused by the
been abraded for a selected number of cyclical application and removal of stresses of a
cycles low order of magnitude. For the fiber to be
(2) Determination of the number of abrasion abrasion resistant, it must be capable of repeat-
cycles required to form a hole or for the edly absorbing the energy imparted to it by the
fabric to fail abrasive action. Therefore, it must have the
(3) Determination of the strength loss caused ability to elongate under load application, and
by a selected number of abrasion cycles or, recover to its original dimension upon load re-
more properly, a graph of abrasion cycles moval. This ability to deform and recover com-
versus strength loss pletely is governed by the relationship between
instantaneous elastic deflection, primary creep,
and secondary creep. Since secondary creep is
Abrasion Mechanisms removed during the first (or second or few)
loading (abrasion) cycles, the energy repre-
Backer [5] proposed three mechanisms which sented by secondary creep contributes little to
may develop during the abrasion of a textile abrasion resistance. Hamburger proposes that
fiber: intrinsic abrasion resistance is correlative with
( 1) Smooth frictional wear such as occurs the energy absorption of "mechanically condi-
when two smooth metal surfaces are rubbed tioned" fibers free of secondary creep. He lists
together-This kind of abrasion would be five fiber properties requisite for high abrasion
typified by sliding a fabric over a polished resistance:
wooden table. • low elastic modulus
(2) Surface cutting or grinding of the fiber by a • large immediate elastic deflection
17.1 Fiber Properties and Technology 589
• high ratio of primary to secondary creep 20r---------------------,
• high magnitude of primary creep
• high rate of primary creep
::!
0
Hamburger determined an "energy coeffi- z
cient" which is a measure of the fiber's resid- c0
ual energy absorption after secondary creep \II
a::
has been removed, and a "durability coeffi- wiO
It:
cient" which is a laboratory measure of the
rate of loss of fiber strength with abrasion ~
!!
cycles. A linear correlation between these two 0
z
factors appears to exist, and demonstrates that
apparently abrasion resistance is dependent
upon the repeated capacity of the fiber to absorb
energy. 60 80 100
Susich [7] observed that staple yarns were HUMIDITY Ofo
always more severely abraded than correspond-
ing multifilament yarns. He stated that although FIGURE 17.16 Relative humidity versus percent mois·
high elastic energy of fibers is the main factor ture regain of cotton fiber.
necessary to prevent inherent abrasion damage,
yarn extensibility, surface, and friction must
also be taken into account.
hygroscopic; that is, they have the ability to ab-
In a general assessment of fiber abrasion re-
sorb water in the form of vapor or liquid. Hy-
sistance, it appears reasonable to state that types
groscopic material will absorb moisture from,
6,6 and 6 nylon are most outstanding in their
or release moisture to, the surrounding air until
abrasion resistance. Polyester fiber is often
an equilibrium moisture content is attained.
considered as second only to nylon. Cotton has
Figure 17.16 shows a plot for cotton of percent
good abrasion resistance, and probably follows
moisture regain, defined below, as a function of
behind nylon and polyester. Since cotton is
progressively increasing relative humidity. If a
stronger when wet than dry, this is an added
dry fiber is brought to equilibrium in an in-
advantage which most other fibers do not have.
creasingly humid atmosphere the water content
Its wet strength and toughness give cotton ex-
at any relative humidity will be less than that
cellent wet as well as dry abrasion resistance, which would result from bringing the fiber to
and explains why cotton fabrics are still used
equilibrium from a wet condition. Thus, Figure
in industrial applications. Wool, because of
17.16 shows moisture absorption and desorption
its high elongation and recovery properties,
curves which superimpose only at the 0 and
has remarkably good abrasion resistance. The
100% rh values, an area of hysteresis resulting
acrylic fibers, viscose, acetate and regen-
when fabrics are conditioned from the dry ver-
erated protein fibers probably follow about
sus the wet side. The moisture content of a tex-
in that order. Polyvinyl alcohol, polypropyl-
tile material will influence its weight, its gen-
ene, and polyethylene all appear to be in the
eral dimensions, and many of its physical
range approaching nylon for abrasion resis-
properties.
tance.
The amount of moisture is usually determined
by weighing a specimen on a balance of proper
sensitivity, bone drying in an oven at about
17. MOISTURE ABSORPTION 220 oF and reweighing the bone dry specimen
PROPERTIES (Chapter 20.0, Textile Testing).
Percent moisture content is defined as the
All of the natural fibers, as well as the re- weight of water calculated as a percentage of the
generated cellulosic and protein fibers, are original weight of sample:
590 FIBER PROPERTIES AND TECHNOLOGY
17.2 Commercial Moisture Regains Table 17.9 lists the swelling properties of
for Fibers fibers when immersed in water. Upon wetting,
most hygroscope textile fibers exhibit a slight
Depending upon conditions of harvesting or increase in length and a considerable increase in
manufacturing, hygroscope fibers can vary diameter and cross-sectional area. The in-
widely in moisture regain with a concomitant fluence of all of these interacting effects on
variation in true fiber weight. Therefore, for fabric air and liquid permeability and on shrink-
economic reasons the purchase or sale of cot- age are discussed in Chapter 19.0, Fabric Prop-
ton, wool, rayon, etc. must be based upon a erties and Technology on "Cover Factor;'
standard amount of moisture. The normal prac- "Fabric Density and Packing Factor," ':Air
tice is for a laboratory, often an independent or- Permeability," and "Water Repellency:' Since
ganization agreeable to both buyer and seller, to hygroscopic fibers themselves do not shorten
measure the average moisture regain of the en- upon wetting, fabric shrinkage must be caused
tire fiber lot. The actual weight of the lot is then by other mechanisms.
TABLE 17.7 Moisture Regain of Fibers (2].
Moisture Regain(%)
Polyester
A.C.E® and Compet®
Filament- HT 0.4
Dacron®
Staple and tow 0.4
POF
Filament-RT 0.4
Filament- HT 0.4
Tairilin®, staple 0.4 0.6
Trevira®
Staple 0.4 0.6
POF 0.4 0.6
Filament-HT 0.4 0.6
Nylon
Nylon 6
Staple 2.8-5.0 3.5-8.5
Monofil. and filament-RT 2.5-5.0 3.5-8.5
Filament-HT 2.8-5.0 3.5-8.5
Nylon 6,6
Staple and tow 4.0-4.5 6.1-8.0
Monofil. and filament-RT 4.0-4.5 6.1-8.0
Filament-HT 4.0-4.5 6.1-8.0
Tencel® lyocell- HT 11.5
Rayon
Fibro®
RT- Multi-lobed 11 27
IT -0.9 den or 0.25 in and up 11 27
Cuprammonium, filament 11
Rayon
Filament-RT 11
Filament- HT 11
Saran®, monofilament 0 N/A
Acetate, filament and staple 6.3-6.5 14
Ryton® sulfar, staple 0.6
Acrylic
Acrilan®, staple and tow 1.5 3.5
Creslan®, staple and tow 1.0-1.5 2.0-2.5
MicroSupreme, staple 1.0-1.5 2.0-2.5
SEf® modacrylic, staple 2.5
(continued)
591
TABLE 17.7 (continued).
Moisture Regain (%)
Olefin
Polyethylene
Monofilament, low density Negligible Negligible
Monofilament, high density Negligible Negligible
Herculon®
Staple 0.01
Bulk filament 0.01
Marvess® and Alpha®
Staple and tow -0.1
Multifilament -0.1
Essera®, Marquesa Lana®, Pation® III
BCF 0.01-0.1
Staple 0.01-0.1
Spectra® 900 Negligible Negligible
Spectra® 1000 Negligible Negligible
Fibrilon®
Staple 0.01 0.01
Spandex
Glospan®/Cleerspan, S-85, multifilament Less than 1
Lycra®
Type 126, 127 1.3
Glass
Single filament- E-glass None Up to 0.3
Single filament-S-glass None Up to 0.3
Multifilament None Up to 0.3
Ararnid
Kevlar4D
Kevlar 29/Kevlar 49 4.3 6.516.0
Kevlar 149 1.2 2.3
Kevlar 68 4.3
Kevlar HT (129) 4.3
Nomex,., staple and filament 4.5 7.5
Fluorocarbon
Gore-Tex® 0 0
Teflon®
TFE multifil., staple, tow, flock 0 0
FEP, PFA monofilament 0 0
PBI, staple 15 20
Asbestos 1.0 3.0
Cotton 8.5 15
Silk 11 25
Wool 16 29
592
17.1 Fiber Properties and Technology 593
TABLE 17.8 Commercial Moisture Regain are 75 to 90% of dry strengths. Regenerated cel-
Values of Fibers {8]. lulose fibers such as viscose and cuprammo-
Moisture nium rayons have wet strengths in the order of
Fiber Regain (%) 45 to 60% of dry. The wet strengths of high
modulus rayons range from 60 to 75% of dry.
Acetate (secondary) 6.5
The modified cellulosics, such as acetate, also
Acrylic 1.5
Aramid, for have wet strengths which are 60 to 80% of
Plastic reinforcement 3.5 dry. Because many of the hydrophilic (water ab-
Filtration fabrics and safety apparel 4.5 sorbing) hydroxyl groups in these fibers have
Reinforcement of rubber goods 7. 0 been replaced by more hydrophobic (water re-
Azlon 10.0
Cotton
sisting) acetate groups, the tendency for such
Natural cotton yarn 7.0 fibers to absorb water is less, and so they are
Dyed cotton yarn 8.0 somewhat less sensitive to strength losses when
Mercerized cotton yam 8.5 wet.
Flax (raw) 12.0 As a general rule it can be stated that, for
Fluorocarbon 0.0
man-made fibers, the lower their moisture re-
Glass 0.0
Hemp 12.0 gains and liquid water absorption capacity, the
Jute 13.75 less sensitive they are to wet strength losses.
Linen 8.75 Thus nylon 6,6, with a moisture regain of 4.5%
Metallic 0.0 (Table 17.7), has a wet strength of about 85-
Modacrylic
90% of dry, while Dacron® polyester, with are-
Class I 0.4
Class II 2.0 gain of 0.4% has a wet strength just about equal
Class III 3.0 to its dry strength. While the general rule is
Nylon (polyamide) 4.5 valid, care should be exercised in its employ-
Olefin 0.0 ment, for the nature of the polymer also in-
Polyester 0.4
Ramie
fluences the strength loss upon wetting.
Raw 7.6
Scoured 7.8 Wet Yarn Strengths
Rayon (regenerated cellulose) Il.O
Rubber 0.0 Because cotton has higher strength when wet
Saran 0.0
than dry, it follows that yarns made from cotton
Silk Il.O
Spandex 1.3 will also be stronger at higher moisture regains
Triacetate (primary) 3.5 as well as when wet. This is in fact the case, the
Vinal 4.5 increase for wet yarns being on the order of 25
Vinyon 0.0 percent. In addition to the intrinsic wet fiber
Wools (all forms) 13.6
strength increase, wet cotton fibers swell
radially, thus causing a denser packing of fiber
against fiber. The total frictional force increase
19. WET FIBER STRENGTHS reduces fiber slippage and so a stronger yarn
results. For natural animal, regenerated cellu-
Table 17.4 lists wet and dry fiber tenacities. losic and synthetic fibers, generally the ratio of
Natural cellulosic fibers such as cotton, are 10 wet-to-dry yarn strengths is about the same as
to 15% stronger when wet than when "dry" their respective wet-to-dry fiber strengths.
under standard conditions. This is of obvious
advantage in end uses where fabrics are apt to
become wet. 20. WET FIBER
The natural cellulosics are the only fibers BREAKING ELONGATIONS
presently known whose wet strengths exceed
dry strengths. The natural animal fibers, in- Table 17.5 lists wet rupture elongations. As a
cluding silk and wool, have wet strengths which general rule, for both the natural and re-
594 FIBER PROPERTIES AND TECHNOLOGY
Glass 0
Nylon 6,6 high tenacity 1.2 1.9-2.6 1.6-3.2
Polyethylene, low density 0
Dacron polyester, regular 0.1 0.3 0.6
Lycra spandex Approx. 1.0 Approx. 1.0
Viscose rayon, regular 3-5 25-52 50-113
Viscose rayon, high tenacity 50
Cupramrnonium rayon 4 32-53 56-62
Acrilan acrylic Approx. 5
Orion acrylic 0.2 2.4 4.8
Acetate 0.14 9-14
Cotton, raw 1.2 14-30 40-42
Cotton, mercerized 0.1 17 24-46
Flax 47
Jute 0.37 20 40
Ramie 37 (bleached)
Silk 1.7 16-20 19
Wool 1.2 16 25
generated hydrophilic fibers, the water absorbed greater elongation resulting from the plasticity
may be considered as a plasticizer. The fiber's of wet fibers can either by recoverable or non-
modulus is reduced and the total elongation-to- recoverable. For natural fibers the wet recovery
rupture increases. The increase for the natural properties often equal or surpass the dry prop-
cellulosic fibers, e.g., cotton, is small. erties, having high instantaneous elastic recov-
The regenerated cellulosic fibers normally ery, high primary creep recovery, and low per-
have appreciably greater wet elongations than manent set. The regenerated hygroscopic fibers
dry. Usually the greater their wet strength loss, usually have poorer recovery properties. The
the greater will be their rupture-elongation hydrophobic synthetic fibers, being insensitive
gain. For example, the high modulus rayons to water, show little or no change.
have higher wet strength than do the regular
rayons, their wet elongations are concomitantly
lower, and therefore they have better wet dimen- 22. THERMAL PROPERTIES OF FIBERS
sional stability. The synthetic fibers are more
hydrophobic and are therefore less sensitive to The influence of heat on the properties of
water. Thus there is little difference in the wet fibers is of paramount importance with respect
and dry strength-elongation properties of the to textile processing as well as use. All of the
acrylics, the polyesters, the polyolefins, and the natural fibers and the regenerated cellulosic and
like. Nylon, being somewhat hydrophilic, is protein fibers are non-thermoplastic. They do
proportionately sensitive to water. not soften with heat, but instead char and
decompose. Most synthetic fibers and the modi-
fied cellulosics such as acetate, are ther-
21. EFFECT OF RELATIVE moplastic and have specific melting points.
HUMIDITY ON TENACITY- Thermoplasticity in a fiber can be advanta-
ELONGATION DIAGRAMS geous or disadvantageous, depending upon
processing or requirements. Because of their
For all fibers except cotton, tenacities and cross-linked molecular structure, cotton and
moduli are lower and elongations are higher wool are essentially temperature insensitive and
as relative humidity increases. Obviously the so do not soften in the 200-300°F range, nor
17.1 Fiber Properties and Technology 595
stiffen at temperatures below freezing. Thus heat set the fabric in order to stabilize it and to
they can be ironed with relative safety, and do remove wrinkles and distortions.
not significantly shrink, stretch, or lose strength Table 13.2 (Chapter 13.0) lists the commer-
at elevated temperatures. For processing or end cially available high temperature fibers and
uses where plasticity is necessary, water and/or Table 13.3 gives their properties.
steam are used rather than heat as the plasticiz-
ing means.
The thermoplastic fibers are temperature sen- 23. EFFECT OF HEAT ON THE TENSILE
sitive. As temperature increases, strength nor- PROPERTIES OF FIBERS
mally is lowered, rupture elongation may in-
crease, and the tensional modulus thus is Two subjects must clearly be separated for the
reduced. Unless the fiber is permanently influence of heat upon fiber properties:
damaged by heat, the effect often is reversible. (1) Tensile properties of fibers tested at ele-
As the fiber cools it may reassume its original vated temperatures
properties. However, the heat exposure may
(2) Tensile properties of fibers tested at room
produce a permanent thermal shrinkage with an
temperature after exposure to elevated tem-
accompanying increase in rupture elongation
peratures for selected time periods
and a decrease in both strength and tenacity.
This shrinkage is removable only by restretch- The former indicates the capability of the
ing the fiber at an elevated temperature. Ther- fiber to perform at the required elevated temper-
moplasticity is an attribute when it is desired to ature. The latter is often used as a criterion of
heatset the fibers within the yarn and fabric, heat degradation resistance.
i.e., to make them conform permanently to the Fabric degradation by heat normally is a
position and form into which they are placed, or function of temperature, time, relative humid-
where the fabric itself must then be molded or ity, and air circulation. Since many heat
reshaped. Thermoplasticity is a disadvantage degradation processes involve oxidation, the
when a fabric becomes excessively limp or greater the air circulation the greater will be the
tacky or shrinks or distorts at high tempera- amount of oxygen which comes in intimate con-
tures, or becomes stiff and brittle at low temper- tact with the fiber, and the more rapid will be
atures. the degradation. Of course, for those fibers
Heat may influence the properties and func- which are insensitive to oxygen, this factor is of
tions of textiles in many ways. Important criteria no consequence.
to consider are (1) softening, melting, or decom- For those industrial textile uses where the
position temperatures; (2) tendency of the fiber item will be subjected to a tension at an elevated
and fabric to shrink when heat-relaxed, or temperature, it is important that the fiber does
stretch when heated and tensioned; (3) ability of not become soft and extensible at that tempera-
the fabric to be heat set; (4) ability of the fabric ture. Glass is generally used for heat insulation
to function properly at elevated temperatures in and heat resisting applications. While it does
one time or in repeated use; and (5) ability of not begin to lose strength until 600°F, its abra-
the fabric to function properly at room tempera- sion resistance is poor, and it cannot be used
ture (or some other lower temperature) after ex- where prolonged flexing or rubbing is required.
posure at high temperature for a given period of Protective silicone finishes improve the abra-
time. sion resistance of glass fabrics, making them
Table 17.10 shows the effect of heat on fiber useful in certain applications, for example, high
properties of various fibers. Normally for a tex- temperature resisting gas filtration fume bags.
tile fiber to be industrially useful it should not Nylon is strong and tough, but it degrades
become tacky or soften below about 300°F. rather quickly at elevated temperatures in the
Upper temperature limits depend upon end-use presence of air, and this limits its high tempera-
requirements, and upon the ability of the finish- ture use. For example, when exposed at 350°F
ing plant to provide a temperature which can for 6 hours, 210 denier type 6,6 nylon yarn loses
TABLE 17.10 Effect of Heat on Fiber Properties {2].
Fiber Effect of Heat
Polyester
A.C.E11 Softens at 464°F. Melts at soo•F.
Competil Melts at 488°F.
Dacron11 Sticks at 440 to 445°F. Melts at 482°F.
Fortrel11 Melts at 478 to 490°F.
Tairilin® Sticks at 440-450°F. Melts at 485-495°F.
Trevira® Softens at 445 to 465°F. Melts at 495°F.
Thomel11 carbon Does not melt. Oxidizes very slowly in air at temperatures above 600°F.
Nylon
Nylon 6 Melts at 419 to 430°F. Slight discoloration at 300°F when held for 5 hr. Decom-
poses at 600 to 730°F.
Nylon 6,6 Sticks at 445°F. Melts at 480 to 500°F. Yellows slightly at 300°F when held for
5 hr.
Tencel11 lyocell Does not melt. Loses strength at about 300°F and begins to decompose at about
350°F under extended periods of exposure.
Rayon
Fibro® Does not melt. Loses strength at 300°F and decomposes at 350 to 464 under ex-
tended periods of exposure.
Cuprammonium Does not soften, stick or melt. Decomposes at 350°F under extended exposure.
Rayon Does not melt. Loses strength at 300°F and begins to decompose at about 325°F.
Saran
Saran11 Melts at 240-280°F; will not support combustion; self extinguishing.
Acetate Sticks at 350 to 375°F. Softens at 400 to 445°F. Melts at 500°F.
Sulfar
Ryton® Outstanding resistance to heat (melts at 285°C}. Excellent resistance to aerial ox-
idation, most chemicals. Retains 70% + original strength to 400°F for 5,000 hr.
Acrylic
Acrilan® Does not melt.
Creslan® Sticks at 420 to 450°F. Safe ironing at 300°F.
MicroSupreme Does not melt.
SEF11 modacrylic Does not melt. Boiling water shrinkage equals 1%. Excellent resistance to shrink-
age in dry heat. At 390°F, 5% shrinkage.
Olefin
Polyethylene Low density softens at 225 to 230°F, melts at 230 to 250°F. High density softens
at 240-260°F, melts at 225 to 280°F. Low density shrinks 5-8% at 165°F,
50-60% at 212°F. High density shrinks 3-5% at 165°F, 8-12% at 212•F.
Herculon® Softens at 285 to 330°F. Melts at 320 to 350°F. Decomposes at 550°F. Zero to
5% shrinkage at 212•F; 5 to 12% at 265°F.
Marvess® and Alpha<~ Fiber softens at 300-320°F. Melts at 320-340°F. Decomposes at 550•F.
Essera®, Marquesa Softens at 285-340°F. Melts at 325-340°F. 0-5% shrinkage at 212°F. 5-12%
Lana®, and Pation® III shrinkage at 265 • F.
Spectra® Melts about 300•F.
Fibrilon® Fiber softens at 290-310°F, melts at 320°F, and decomposes at 550°F.
596
17.1 Fiber Propenies and Technology 597
Spandex
Glospan~/Cleerspan, S-85 Good dimensional stability. Sticks at 420°F.
Lycra~ Good dimensional stability. Can be heat set. Sticks at 347-392°F. Melts at 446°F.
Glass None bum. At 650°F, E holds 75% tensile strength; S 80%; multifilament 50%.
E softens at 1,350 to 1,611 °F; melts at 2,050 to 2,160°F. S softens at 1,560 to
1,778°F; melts at 2,720°F.
Aramid
Kevla~ Difficult to ignite. Does not propagate flame. Does not melt. Decomposes at about
900oF.
Nomex~ Does not melt. Decomposes at 700°F.
Fluorocarbon
Gore-Tex® Extremely heat resistant. Can be safely used from -350°F to +550°F. Melts at
620°F.
Teflon®
TFE Extremely heat resistant. Safely used at -350°F to +550°F. Melts at 620°F.
FEP,PFA Extremely heat resistant. Continuous use temperature: FEP, 400°F, PFA 500°F.
PBI Will not ignite. Does not melt. Decomposes in air at 860°F. Retains fiber integrity
and suppleness upon flame exposure. High char yield.
Asbestos Weight loss 0.5 to I% after exposure at 1 ,400°F for 2 hours. Stable up to
J,490°F.
Cotton Yellows at 250°F, decomposes at 300°F.
Silk Decomposes at 300°F. Rapid disintegration above 340°F.
Wool Decomposes at 275°F, chars at 570°F.
54% of its original strength. Dacron® polyester • flammable textile: "any combustible
has better heat aging resistance, losing only 8% textile that burns with a flame"
when exposed under the same conditions. • heat resistance: "the extent to which a
material retains useful properties as
measured during exposure of the
24. FIBER FLAMMABILITY material to a specified temperature and
environment for a specified time"
Several terms related to the burning behavior • inherent flame-resistance: "flame
of textiles are defined by the ASTM as follows resistance that derives from an essential
[9]: characteristic of the fiber from which
the textile is made"
• combustible textiles: "a textile that will
• non-combustible textile: "a textile that
ignite and burn or that will give off
will neither ignite nor give off vapors
vapors that will ignite and burn when
that will ignite when subjected to
subjected to external sources of ignition"
external sources of ignition"
• flame resistance: "the property of a
• non-flammable textile: "any combustible
material whereby flaming combustion is
textile that burns without a flame"
prevented, terminated, or inhibited
following application of a flaming or Cotton and other cellulosics, as well as cellu-
nonflaming source of ignition, with or lose acetate, will ignite readily and are not self-
without subsequent removal of the extinguishing. Once they are ignited, they will
ignition source" continue to burn, even when the igniting flame
• flammability: "those characteristics of a is removed. Silk, wool, and all the other animal
material that pertain to its relative ease fibers will burn, but are self-extinguishing.
of ignition and relative ability to sustain Synthetic organic fibers have varying degrees of
combustion" flammability depending upon their composi-
598 FIBER PROPERTIES AND TECHNOLOGY
tions. Nylon 6,6 is stated to be moderately diffi- Agency. In 1973, responsibility for both issuing
cult to ignite and self-extinguishing. Glass does and enforcing flammability regulations was
not burn. Carbon does not melt but oxidizes transferred from the Commerce Department to
very slowly in air at temperatures above 600°F. the Agency.
Kevlar® aramid is difficult to ignite, does not The flammability standard described in the
propagate flame and does not melt. It decom- Act states, ')\ny fabric or article of wearing
poses at about 900°F. Nomex® aramid does not apparel shall be deemed so highly flammable
melt and decomposes at 700°F. Gore-Tex® and within the mean . . . of this Act as to be danger-
Teflon® are extremely heat resistant. They can ous when worn by individuals if such fabric or
be safely used from - 350°F to + 550°F. PBI any uncovered or exposed part of such article of
will not ignite nor melt but decomposes in air at wearing apparel exhibits rapid and intense burn-
860°F. It retains fiber integrity and suppleness ing when tested under the conditions and in
upon flame exposure. the manner prescribed in . . . 'Flammability
Because burning is an oxidation process, for of Clothing Textiles, Commercial Standard
those fibers which will burn, the type of yarns 191-53.' " This standard specified the methods
and fabrics into which they are manufactured for testing fabric flammability and classifies
will directly influence the burning rate. Dense, fabrics as follows.
heavy fabrics will not burn as readily as will
lofty, open, thin, or brushed pile fabrics. For Class 1. Normal Flammability
these latter types, the oxygen in the air can sur-
round each fiber and accelerate the burning These textiles are generally accepted by the
rate. Here, if the fibers are combustible and trade as having no unusual burning character.
finely dispersed, a rapid flash burning can de-
velop. In addition to the intrinsic flammability • textiles that do not have a raised fiber
of the fiber, and the textile into which it is surface, but have a time of flame spread
manufactured, precaution must be taken to in- in the test of 3.5 seconds or more
sure that a fabric finish or coating applied to im- • textiles having a raised fiber surface that
part a certain property do not produce a have a time of flame spread in the test
dangerously flammable fabric. of more than 7 seconds or that burn
with a surface flash (time of flame
24.1 Flammable Fabrics Act spread less than 7 seconds) provided the
intensity of the flame is insufficient to
In 1953, the U.S. Congress passed the Flam- ignite or fuse the base fabric
mable Fabrics Act to ban easily ignitable fabrics
and wearing apparel from the market. The Act Class 2. Intermediate Flammability
stated that "no article of wearing apparel or
fabric subject to the Act and Regulations shall These textiles are recognized by the trade as
be marketed or handled if such article or fabric, having flammability characteristics between
when tested according to the procedures pre- normal and intense burning. Textiles having a
scribed . . . is so highly flammable as to be raised fiber surface that have a time of flame
dangerous when worn by 'individuals.' " These spread in the test of 4 to 7 seconds, inclusive,
were mainly brushed or high pile cellulosic and the base fabric is ignited or fused.
fabrics used occasionally in such garments as
sweaters and children's costumes. Class 3. Rapid and Intense Burning
In 1967, the Act was amended to cover in-
terior furnishings as well as fabrics and all These textiles are considered dangerously
wearing apparel which present an unreasonable flammable and are recognized by the trade as
risk from fire. In 1972, an Act of Congress es- being unsuitable for clothing because of their
tablished a new Consumer Product Safety rapid and intense burning.
17.1 Fiber Properties and Technology 599
• textiles that do not have a raised fiber methods are explained in Chapter 20.0, Textile
surface, but that have a time of flame Testing. Flame retardant finishes are included
spread in the test of less than 3.5 seconds in Chapter 5.0, Section 5.1.
• textiles having a raised fiber surface that
have a time of flame spread in the test
of less than 4 seconds, and the base
25. RESISTANCE OF FIBERS TO
fabric is ignited or fused
MILDEW, AGING, SUNLIGHT
The chemical textile industries have expended AND ABRASION
large amounts of money and effort in developing
flame resisting finishes for apparel, decorative Table 17.11 lists mildew, aging, sunlight and
and industrial fabrics. By law, curtains, draper- abrasion properties of various fibers. Wool and
ies and other textiles in public buildings must be cotton tend to turn yellow with age. Where nec-
flameproof. Fire and flame resistance test essary, bleaching the cotton with hypochlorite
TABLE 17. 11 Resistance of Fibers to Mildew, Aging, Sunlight and Abrasion [2].
Fiber Resistance to Mildew, Aging, Sunlight and Abrasion
Polyester
A.C.Eilll Excellent resistance to mildew; good to abrasion, aging and sunlight with some de-
terioration after prolonged exposure to sunlight.
Competilll Excellent
Dacron® Not weakened by mildew. Excellent resistance to aging and abrasion. Prolonged
exposure to sunlight causes some strength loss.
Fortrelilll Excellent resistance to mildew, aging and abrasion. Prolonged exposure to sunlight
causes some strength loss.
Tairilinll!l Excellent resistance to mildew, aging, abrasion. Excellent resistance to sunlight,
but prolonged exposure causes some strength loss.
Trevirailll Not attacked by mildew. Excellent resistance to aging and abrasion. Excellent re-
sistance to sunlight, but prolonged exposure causes some strength loss.
Thornelilll carbon Excellent resistance to mildew, aging, and sunlight. Poor abrasion resistance.
Nylon
Nylon 6 Excellent resistance to mildew, aging and abrasion. Prolonged exposure to sunlight
causes some degradation.
Nylon 6,6 Excellent resistance to mildew, aging and abrasion. Prolonged exposure to sunlight
causes some deterioration.
Tencelilll lyocell Attacked by mildew. Good resistance to aging, sunlight and abrasion.
Rayon
Fibroilll Attacked by mildew. Resistance to aging, sunlight and abrasion is good. Long ex-
posure to sun yellows some intermediate rayons; aging deteriorates them.
Cuprammonium Attacked by mildew. Stable to aging. Not affected by sunlight. Good resistance to
abrasion.
Rayon Attacked by mildew. Good resistance to sunlight, abrasion and aging.
Saran
Saran® Not attacked by mildew. Good resistance to aging, sunlight and abrasion.
Acetate Impervious to aging. Good resistance to mildew discoloration and sunlight (some
lose strength from long exposure). Fair abrasion resistance.
Sulfar
Ryton® Excellent resistance to mildew, aging and sunlight. Fair abrasion resistance.
Acrylic
Acrilanilll Excellent resistance to mildew, aging and sunlight. Good resistance to abrasion.
Creslanilll and MicroSupreme Excellent.
SEfll!l modacrylic Excellent resistance to mildew, aging and sunlight. Good resistance to abrasion.
(cominued)
600 FIBER PROPERTIES AND TECHNOLOGY
TABLE 1 7. 11 (continued).
Olefin
Polyethylene Not attacked by mildew. Good resistance to aging, sunlight and abrasion.
Herculon~~'~ Not attacked by mildew. Good resistance to aging, indirect sunlight and abrasion.
Can be stabilized to give good resistance to direct sunlight.
Marvess~~'~ and Alpha~~'~ Not attacked by mildew. Good resistance to aging and abrasion. Stabilizers provide
good resistance to sunlight fading.
Spectra~~'~ Excellent resistance to mildew, aging and abrasion. Some loss of strength with
long exposure to sunlight.
Fibril on~~'~ Not attacked by mildew. Good resistance to aging and abrasion. Stabilizers provide
good resistance to sunlight fading.
Spandex
Glospan~~'~/Cleerspan, S-85 Excellent resistance to aging and abrasion. Sunlight exposure causes mild dis-
coloration but no loss of physical properties.
Lycra~~'~
Type 126,127 Mildew, aging: no effect. Strength loss from prolonged sunlight. Good abrasion
resistance.
Type 128 Excellent abrasion and aging resistance.
Glass Not attacked by mildew, although binder may be affected by it. Excellent resis-
tance to aging and sunlight.
Aramid
Kevlaril'l Excellent resistance to mildew and aging. Prolonged exposure to sunlight causes
deterioration, but fibers self-screening. Good abrasion resistance.
Nomex® Excellent resistance to mildew and aging. Prolonged exposure to sunlight causes
some strength loss. Good abrasion resistance.
Fluorocarbon
Gore-Tex~~'~ Excellent resistance to mildew, aging, sunlight and abrasion.
Teflon~~'~ Not weakened by mildew. Excellent resistance to aging and sunlight. Good abra-
sion resistance.
PBI Good resistance to mildew and aging. Prolonged exposure to sunlight will cause
darkening and some loss of tensile strength. Good abrasion resistance.
or peroxide, and the wool with sulfur dioxide or are most frequently of the bacillus or rod type.
peroxide will remove the yellow color. Exclu- The terms decay and mildew are usually asso-
sive of any microbial or mildew degradation, ciated with damage by fungi, and rot with bacte-
weathering and sunlight cause a slow but pro- rial damage.
gressive loss in strength and serviceability for Since microorganisms require water and
cotton and rayon. Acetate is probably more re- warmth to flourish and spread, all of the natural
sistant than rayon. Wool generally has good re- and regenerated hydrophilic vegetable and ani-
sistance to sunlight, weathering, and aging. mal fibers are susceptible to microbial dam-
This appears quite logical when one considers age. Cotton, linen, viscose and cuprammonium
the natural environment of sheep. rayons, and other cellulose based fibers, are
subject to breakdown where, via a process
25.1 Mildew and Rot Damage called glycolysis, the cellulose is converted by
the enzyme cellulase to cellobiose. This is then
The terms mildew, rot, and decay are vari- converted to glucose which serves as the food
ously used to indicate growth upon or damage to for the microorganism. Mildew is often mani-
textiles by microorganisms such as fungi and fested in cotton and other cellulosics by a musty
bacteria. The major types of fungi affecting tex- odor, the formation of discolored and black
tiles are the molds such as penicillium and areas, fabric tendering, and ultimately complete
aspergillus, and the soil molds such as actino- decay. Some mildews produce brightly colored
mycetes. Bacteria which cause textile damage spots, and often fluoresce strongly in ultraviolet
17.1 Fiber Properties and Technology 601
light. Therefore, an inexpensive ultraviolet or ing attacked. Tests usually show that while the
"black light" lamp is a useful tool for mildew fiber may be stained, it suffers no actual de-
identification. terioration and strength loss; only the finish is
Wool, other animal fibers, and regenerated attacked.
proteins are usually not quite so sensitive but
they, too, can be decomposed by specific bacte- 25.2 Insect and Rodent Damage
ria, actinomycetes, and molds which attack ker-
atin through the production of proteolytic en- Basically the same comments made above for
zymes by these organisms. The intact cuticle mildew and rot damage hold for insect damage.
and epicuticle of the wool fiber are relatively in- The natural fibers are susceptible to damage by
ert to such enzymes, hence such attack is more carpet beetles, cockroaches, ants, silverfish,
rapid on wool which previously has been and moth larvae. The synthetic fibers usually
mechanically or chemically damaged. are not attacked. Many insects will eat natural
Mildew most often develops when textiles are fibers. They may cut through synthetic or other
folded and stored for lengthy periods in a warm fibers which are not attractive as food in order
moist atmosphere. A relative humidity of about to liberate themselves or reach an attractive
82% for cotton and 85% for wool is required food source, or they may eat an unattractive
for mildew and mold growth. Bacterial require- fiber which is coated or contaminated with an
ments are higher. Wool must ordinarily be ex- attractive material. Thus, while synthetic fibers
posed to a relative humidity of approximately normally are not subject to insect damage, they
95%, or must have a moisture content on the can be damaged under specific environmental
order of 20% to support active bacteria growth. conditions. Rodents, in cases of extreme hunger,
Temperatures of 75 to 100°F are optimal for may attempt to eat cellulose or keratin base
most microorganisms. Local condensation can fibers. They probably will not eat synthetic
start mildew growth, occasionally at a relative fibers, but might damage them by gnawing.
humidity which is lower than expected. Once
started, mildew can absorb water hygroscop-
ically from the air or from local condensation 26. CHEMICAL RESISTANCE
and continue its growth. This is why packaged OF FIBERS
or folded fabrics, without adequate ventilation,
will sometimes mildew in relatively "dry" Table 17.12 lists the effect of acids, alkali sol-
rooms. vents, and special chemicals on various fibers.
Synthetic fibers have chemical structures not Because of the many fibers and many chemi-
found in nature. Therefore, microorganisms do cals, it is impractical to list all of the effects.
not attack them. Most synthetic fibers have little The "state of aggregation'' (i.e., position and ori-
or no tendency to absorb water, a necessary entation) of fibers in yarn, and yarn in fabric,
component required by all microorganisms if the chemical concentration, temperature, and
they are to survive. Clearly, this is another length of exposure time also influence reaction
reason why synthetic fibers are mildew resis- rates and extents of degradation.
tant. Even a slight modification in the chemical Cotton and rayon have fairly good resistance
structure of a natural or regenerated fiber may to weak acids, for example, but are severely
be sufficient to preclude microbial attack. The damaged by even dilute solutions of strong acids
nylons, polyesters, acrylics, and all other com- such as sulfuric and hydrochloric. These cellu-
pletely synthetic fibers are completely imper- losic fibers have good resistance to strong alka-
vious to mildew growth and attendant damage. lis. Mercerizing strength caustic (20% sodium
A word of caution is necessary. Often synthetic hydroxide) will swell the fibers and can ulti-
yarns may be sized, or fabrics finished, with mately degrade them.
natural gums, starches, waxes or the like that Wool shows high resistance to weak and
are susceptible to mildew growth. This may strong acids, but is disintegrated and dissolved
make it appear that the fibers themselves are be- by alkalis. Bleaching must be accomplished on
TABLE 17. 12 Chemical Resistance of Fibers [2].
Fiber Effects of Acids and Alkalis Effects of Bleaches and Solvents
Polyester
A.C.E® Good resistance to organic acids. Good re- Excellent resistance to bleaches and other
sistance to inorganic acids at room tempera- oxidizing agents.
ture; moderate resistance at 212°F. Disinte-
grates in concentrated hot alkalis.
Compet® Excellent resistance to acids.
Dacron® Good resistance to most mineral acids. Dis- Excellent resistance to bleaches and other
solves with partial decomposition in concen- oxidizing agents. Generally insoluble except
trated solution of sulfuric acids. Good re- in some phenolic compounds.
sistance to weak alkalis. Moderate resis-
tance to strong alkalis at room temperature.
Disintegrates in strong alkalis at boil.
FortreJ® Good resistance to most mineral acids. Dis- Excellent resistance to bleaches and other
solves with partial decomposition by con- oxidizing agents. Generally insoluble except
centrated solutions of sulfuric acid. Good in some phenolic compounds.
resistance to weak alkalis and moderate re-
sistance to strong alkalis at room tempera-
ture. Disintegrates in strong alkalis at boil.
Tairilin® Good resistance to most mineral acids; fair Excellent resistance to bleaches and other
resistance to concentrated sulfuric acid. oxidizing agents.
Good resistance to weak alkalis; moderate
resistance to strong alkalis at room tempera-
ture. Disintegrates in strong alkalis at boil.
Trevira® Excellent resistance to mineral and organic Excellent resistance to bleaches and oxidiz-
acids at room temperature. Good resistance ing agents.
to weak alkalis at room temperature. Good
resistance to weak alkalis at room tempera-
ture. Moderate resistance to strong alkalis,
depending on concentration, temperature
and time.
Thorne!® carbon Excellent resistance to acids and alkalis, Inert to all known solvents. Poor resistance
even at high concentrations and tempera- to hypochlorite.
tures. Strong oxidizers will degrade fiber.
Nylon
Nylon 6 Strong oxidizing agents and mineral acids Can be bleached in most bleaching solu-
cause degradation. Others cause loss in tions. Generally insoluble in organic sol-
tenacity and elongation. Resists weak acids. vents. Soluble in some phenolic compounds.
Soluble in formic and sulfuric acids. Hydro-
lyzed by strong acids at elevated tempera-
tures. Substantially inert in alkalis.
Nylon 6,6 Unaffected by most mineral acids, except Can be bleached in most bleaching solu-
hot mineral acids. Dissolves with partial tions. Generally insoluble in most organic
decomposition in concentrated solutions of solvents. Soluble in some phenolic com-
hydrochloric, sulfuric and nitric acids. Solu- pounds.
ble in formic acid. Substantially inert in
alkalis.
602
TABLE 17.12 (continued).
Fiber Effects of Acids and Alkalis Effects of Bleaches and Solvents
Tencel~ lyocell Similar to cotton. Hot dilute or cold concen- Attacked by strong oxidizing agents. Not
trated acids disintegrate fiber. Strong alka- damaged by bleaches. Generally insoluble in
line solutions cause swelling and reduce common organic solvents.
strength. Can be mercerized.
Rayon
Fibro® Similar to cotton. Hot dilute or cold concen- Attacked by strong oxidizing agents. Not
trated acids disintegrate fiber. Strong alka- damaged by hypochlorite or peroxide. Gen-
line solutions cause swelling and reduce erally insoluble except in cupranunonium
strength. and a few complex compounds.
Cupranunonium Hot acids or high concentrations tend to dis- Not affected by solvents. Insoluble in com-
integrate fiber. Strong caustic solutions tend mon organic solvents. Damaged by normal
to swell fiber and reduce strength. concentrations of hypochlorite or peroxide
bleaches.
Rayon Similar to cotton. Hot dilute or cold concen- Attacked by strong oxidizing agents. Not
trated acids disintegrate fibers. Strong alka- damaged by bleaches. Generally insoluble in
line solutions cause swelling and reduce common organic solvents.
fiber strength.
Saran
Saran® Generally good resistance to acids and most Generally good resistance to bleaches and
alkalis. Sodium hydroxide and anunonium solvents. Esters and ethers may be
derivatives, in conjunction with heat, cause detrimental in varying degrees.
discoloration.
Acetate Deteriorates in concentrated solutions of Attacked by strong oxidizing agents. Not
strong acids. Unaffected by weak acids. damaged by mild hypochlorite or peroxide
Strong alkalis saponify into regenerated cel- bleaching conditions. Soluble in phenol,
lulose. acetone, concentrated and glacial acetic
acid.
Sulfar
Ryton~ Outstanding resistance to acids and alkalis Excellent resistance to all solvents at high
except hot concentrated sulfuric acids and temperatures.
concentrated nitric acid.
Acrylic
Acrilan® Good to excellent resistance to mineral Good resistance to bleaches and common
acids. Fair to good resistance to weak alka- solvents.
lis; moderate resistance to strong, cold solu-
tions.
Creslan® and Generally good resistance to mineral acids Unaffected by dry cleaning solvents. Can be
MicroSupreme and weak alkalis. Moderate resistance to bleached with sodium chlorite.
strong alkalis at room temperature.
SEF® modacrylic Resistant to most acids. Good resistance to Good resistance to bleaches, dry cleaning
weak alkalis; moderate resistance to strong, fluids and most common solvents.
cold alkalis.
(continued)
603
TABLE 17.12 (continued).
Fiber Effects of Acids and Alkalis Effects of Bleaches and Solvents
Olefin
Polyethylene Low density: excellent resistance to acids Low density: resists well below 150°F.
and alkalis, with the exception of oxidizing Swells in chlorinated hydrocarbons at room
agents. High density: excellent resistance to temperature. Soluble at 160 to l75°F. High
acids and alkalis, with the exception of ox- density performs generally the same but not
idizing agents. as pronounced.
Herculon~ Excellent resistance to most acids and alka- Resistant to bleaches and most solvents.
lis with the exception of elevated tempera- Some swells in chlorinated hydrocarbons at
ture exposure to chlorosulfonic acid, con- room temperature and dissolves at l60°F
centrated nitric acid and certain oxidizing and higher. Others swell only at elevated
agents. temperatures.
Marvess® and Excellent resistance to concentrated acids Resistant to bleaches and most solvents.
Alpha~ and alkalis. Chlorinated hydrocarbons cause swelling at
room temperature and dissolve fibers at
l60°F and higher.
Essera~, Excellent resistance to most acids and alka- Resistant to bleaches and most solvents.
Marquesa Lana~, lis with the exception of elevated tempera- Some hydrocarbons will cause swelling at
Patlon~ III ture exposure to some acids. room temperature. Some solvents will dis-
solve above 200°F.
Spectra~ Excellent resistance to most acids and alka- Resistant to most solvents, good resistance
lis, with the exception of elevated tempera- to bleaches. Some hydrocarbons cause
ture exposure to some acids. swelling, especially at elevated tempera-
tures.
Fibril on~ Excellent resistance to concentrated acids Resistant to bleaches and most solvents.
and alkalis. Chlorinated hydrocarbons cause swelling at
room temperature and dissolve fiber at
160 oF and higher.
Spandex
Glospan~/ Resistant to mild acids and alkalis. Is Good resistance to deterioration by
Cleerspan, S-85 degraded by strong acids and alkalis at high bleaches. Discolored slightly by
temperatures. hypochlorite bleach. Resistant to solvents
and oils except glycols.
Lycra~
Type 126,127 Good resistance to most acids. Slightly yel- Hypochlorite bleaches discolor. Can use
lowed by dilute hydrochloric, sulfuric acids. perborate. Good resistance to most solvents,
Good resistance to most alkalis. oils.
Type 128 Resistant to mild acids and alkalis. Good resistance to discoloring. Strength loss
Degraded by strong acids and alkalis at high by hypochlorite bleaches.
temperatures.
604
17.1 Fiber Properties and Technology 605
the neutral or acid side. Certain reducing agents agents. Their general chemical and solvent re-
are employed to modify the wool by rupturing sistance is high. They are normally soluble in
sulfur-sulfur bonds. The wool is then more hot chlorinated hydrocarbons.
"plastic" and can be set into a desired shape.
Reoxidation then reforms the bonds and the
fiber then maintains its new configuration. 27. ELECTROSTATIC PROPERTIES
All of the natural fibers are unaffected by the OF FIBERS
common hydrocarbon and aromatic solvents.
The polyesters have good resistance to most Both in processing and in use, the generation
mineral acids and to weak alkalis, but are dis- of static electricity on textile materials is at least
integrated by strong hot alkali. They have good a nuisance, and can be expensive or dangerous.
resistance to oxidizing agents and to most or- During conversion of fiber to yarn and yarn to
ganic solvents except phenols. Generally speak- fabric, the large fiber surface areas are condu-
ing, the polyesters are considered to have better cive to generating and holding electrostatic
chemical resistance than the polyamides. The charges. These charges develop as the result of
acrylics and modacrylics generally have ex- fiber to fiber, fiber to machinery, or even fiber
cellent chemical resistance. They have excellent to air friction. Most textile fibers are good or
acid resistance, fair alkali resistance and are im- excellent electrical insulators; hence, electric
pervious to many solvents. The modacrylics are charges cannot be conducted away. So the inten-
softened or dissolved by certain ketones. Saran sity of charge increases until fibers or yarns, all
has excellent acid and alkali resistance although with the same charge, repel each other with ac-
it is sensitive to ammonia. It is unaffected by companying "wildness" of fibers which then
most common solvents, but is degraded by cer- will not process properly. If the charge on the
tain esters and ethers. Polyethylene and poly- fibers is opposite to that on card clothing, draft-
propylene have excellent acid and alkali resis- ing rolls, or other machinery parts, the fibers
tance, but are sensitive to alkaline oxidizing will stick to those parts of the machine oppo-
606 FIBER PROPERTIES AND TECHNOLOGY
sitely charged, and processing may be slowed exists between moisture regain and charge
down or stopped. Static generation by conveyor buildup, the intrinsic nature of the fiber
belts and the like operating in areas where there polymer substance may also have a great bear-
are solvent fumes may be dangerous because a ing on static forming characteristics.
discharge spark may cause explosion and fire.
Truly distilled water is a relatively poor elec-
trical conductor, but natural waters which con- 28. ELECTRICAL RESISTIVITY
tain even small quantities of soluble mineral
salts are excellent conductors. Those fibers Proper evaluation of the electrostatic proper-
which have high moisture regains usually do not ties of a fiber or fabric requires that all of the
present quite as many static problems as do mechanisms for charge generation and dissipa-
those which are impervious to water. If the tion be considered.
relative humidity is sufficiently high, almost all To pass a steady flow of electric charge, or
textile fibers can be processed without electro- current through any material requires a voltage.
static difficulty. As the humidity decreases, Ohm's law states that the ratio of applied voltage
processing problems increase, usually geomet- to current flow is called the electrical resis-
rically with the synthetic hydrophobic fibers be- tance. The lower the resistance, the more easily
ing the first to cause trouble. The polyesters, the current will flow. Flow can take place
acrylics, olefins, and the polyamides having the through either the volume of the material or
lowest moisture regain are most likely to de- along its surface, and the resulting resistances
velop static charges. Rayon, silk, wool, and cot- are called "volume resistance" and "surface re-
ton can absorb water and hence can dissipate sistance," respectively. Materials with high re-
charges more easily. However, at low relative sistance will build up and hold electrostatic
humidity all fibers may show processing diffi- charges because the current cannot flow easily
culty. The textile industry, therefore, makes and allow the charge to leak off. Thus, a direct
wide use of humidification during carding, relationship normally exists between a fabric's
combing, spinning, and weaving. Combing or surface or volume resistance and its tendency to
spinning oils, warp sizes, and other processing build up a bothersome electrostatic charge.
chemicals usually contain anti-stats to eliminate Since water (other than distilled) is a good
the static problem. Static also may be elim- conductor, surface and volume resistances for
inated by running the material over alpha parti- all fibers are essentially inversely functional
cle radioactive sources which ionize the sur- with moisture regain. Large changes in resis-
rounding air. tance result from small changes in regain. Many
Chemical anti-stats usually contain polar hydrophobic fibers may have high volume resis-
groups within their molecule. These act as con- tances because they are impervious to water.
ductors to prevent charge buildup or to conduct Their surface resistances may be propor-
away any charges which do develop. Anti-stats tionately lower, however, because they have thin
also may be nothing more than humectants or or even molecular layers of water adhering to
water absorbing materials. The ionized water their surfaces. Methods for measuring re-
present on the textile will dissipate the static sistivities are given in Chapter 20.0, Textile
electricity. While generally an inverse relation Testing.
17.2
References and Review Questions
607
18.0
YARN NOMENCLATURE, PROPERTIES
AND TECHNOLOGY
18.1
Yarn Nomenclature, Properties and Technology
S. ADANUR
Yarn nomenclature and the factors that in- sure where the number of grams of weight for a
fluence yarn properties are discussed in this given number of meters of yarn can be mea-
section. The textile industry has built a termi- sured and recorded as a whole number. The in-
nology that is dependent upon the nature of the direct system is conducive to English measure
fiber, yarn, or fabric, the country where the where the number of yards per pound of yarn
nomenclature developed, and the period in his- can be measured and recorded as a whole
tory during which common usage was estab- number.
lished. Unfortunately the industry has not yet "Yarn Number" by either system is a number
adopted one single standard terminology for of arbitrarily selected weights of yarn per unit
defining yarn weight, twist and twist direction, length, or a number of arbitrarily selected
number and direction of plies. The "Tex Sys- lengths of yarn per unit weight. Examples of
tem" is a universal international system for es- each system are as follows.
tablishing yarn weight per length and is ex-
plained below. The English system of length in 1.1 Direct Yarn Number
inches, feet and yards, and weight in grains,
ounces and pounds, is difficult and illogical not Tex: The tex is defined as the weight in grams
only for textile use, but in all industries. How- of one kilometer (1,000 meters) of yarn. A
ever, this system is still used by the textile indus- kilotex equals 1,000 tex, a decitex equals 0.1 tex;
try, and so it is described in the following sec- and a millitex equals .001 tex. For example, a
tions. 300 tex yarn weighs 300 grams per kilometer.
Denier: The weight in grams of 9,000 meters
of yarn. Commonly used in the man-made fiber
1. YARN NUMBER SYSTEMS industry, a 200 denier nylon yarn is one wherein
9,000 meters of yarn weigh 200 grams.
The yarn "number" or "count" defines the One tex equals one-ninth of the denier, and so
relationship between yarn weight and length. these two systems are easily convertible.
Two different systems are widely used in spe-
cific areas of the textile industry: 1.2 Indirect Yarn Number
(1) The direct yarn number, or weight per unit
Cotton Hank: The number of 840 yard
length system, so called because the heavier
lengths in one pound of cotton yarn is called a ls
the yarn the greater is the weight per unit
(ones) count yarn. A two hank cotton yarn con-
length
tains 2 x 840 = 1,680 yards per pound and is
(2) The indirect yarn number, or length per called a 2s (twos) count yarn.
unit weight system, so called because the The 840 yards per pound nomenclature is
lighter (in weight) the yarn, the greater is used primarily for cotton. Yarns composed of
the length per unit weight other fibers use different yardages to describe
The direct system is conducive to metric mea- their hanks. Thus a ls worsted yarn count yarn
611
612 YARN NOMENCLATURE, PROPERTIES AND TECHNOLOGY
contains 560 yards per pound, a ls linen yarn direction. For spun cotton yams, only the count
contains 300 yards per pound. and ply are usually given, e.g., Ss/10, meaning
Table 18.1 lists yarn numbering or count that ten plies of 8s singles are twisted together.
systems as defined by the ASTM D 2260. Table Twist and twist direction are not normally
18. 2 gives factors for converting yarn numbers listed. For continuous filament man-made pro-
from one system to another. ducer's yarn the nomenclature on the package
may read "nylon 210-34-lZ-300" which means
2. YARN TWIST DIRECTION that the yarn is 210 denier, contains 34 individ-
ual filaments, has 1 turn per inch Z twist, and
Twist is necessary in order to manufacture the manufacturer's code type is 300. The letters
staple fiber yarns and to give integrity, compact- B, D or SD may be given to identify bright, dull
ness, snag and abrasion resistance to filament or semi-dull yarn. The fiber producer also iden-
yarns as well as to cords and ropes, whether tifies each lot of yarn with a "merge number."
they be made from spun or continuous filament Since no two lots of yarn are exactly alike, in
singles. Ideally, the twist path of a single ele- some uses care must be taken not to mix lots,
ment in the yam is a perfect cylindrical helix. It otherwise streaks or bands may appear in the
is necessary to describe the nature of the helical
path with respect to whether the twist is "left" or
"right:' Thus when the yarn is held in a vertical
(north and south) position and the twist helix
rises to the right, the yam is stated to contain
"right-hand" twist; when the helix rises to the
left, the yam contains "left-hand" twist. Meth-
ods for determining the number of turns per
inch will be found in Chapter 20.0, Textile Test-
ing. The letters S and Z are used as designating
letters for left and right twist, respectively.
Figure 18.1 gives the usual form of illustration
that accompanies these definitions.
den 0.590 541 590.541 885.812 310.034 1 000 1 653.52 496 055
Texb (g/km) tex = · · · -
9 x gr
- -
cc
- ---
we
---
wr
--
me
---
lea
- -y -
y
American woolen run
(1,600 yd lengthsllb)
wr =
310.034
---
tex
2 790.31
den
-525
gr
0.525 X CC 0.35 X we ... 0.310 034
x me
0.187 5
x lea 1 600
Yards per pound 496 055 4 464 492 840 000 496.055
y= - - - --- 840 X CC 560 x we 1600 x wr 300 x lea
(yd/lb) tex den gr x me
•The conversion factors are based on the following relationships given in Metric Practice E 380: I yard = 0.9144 m, exactly, and lib (avoirdupois) = 0.453 592 37 kg, exactly. The conversion factors contain-
ing fewer than six significant digits are exact values.
bMultiples and submultiples of this basic unit may be used as a convenience to avoid large numbers or decimal fractions. For example, decitex (dtex) or tex x 10 is suitable for fine yarns and fibers; millitex
(mtex) or tex x I ,000 is suitable for fibers; while kilotex (ktex) or tex/1 ,000 is often used for ropes, cords, rovings, tops, and slivers.
Examples of use:
en
...... I) The English worsted count equivalent to a cotton count of 10 is 1.5 times 10, or 15 English worsted count.
(,J 2) The cotton count equivalent to 30 tex is 590.54 divided by 30, or 19.7 cotton count.
614 YARN NOMENCLATURE. PROPERTIES AND TECHNOLOGY
dyed fabric. Yarns of differing merge numbers Example 1: A continuous filament nylon
may have slightly different optical properties 210/3 plied yarn means that three singles yarns,
due to small differences in molecular weight, each being 210 denier, are plied together. Ex-
degree of crystallinity, orientation or amount of cluding any contraction due to "twist take-up;'
draw during manufacture. These differences the equivalent yarn count is 630 denier.
can cause small but different degrees of dye ac- Example 2: If five such 210/3 plied yarns are
ceptance, which will be manifested as streaks or again plied to form a cord, the cord is identified
bands. as 210/3/5, the equivalent yarn count being 3150
denier.
Sometimes the yarn is further described by
4. PLIED YARN NOMENCLATURE giving the singles and ply twist and direction;
for example, 210/3- 8S- 6Z indicates three 210
Because of the many singles yarn count sys- denier singles yarns, each with 8 turns per inch
tems used, in describing plied yarns care must S twist before plying, plied together with 6 turns
be taken to properly list the construction and per inch Z twist.
weight. However, once the singles yarn count
system is known, the description of the number
of plies is relatively straightforward. 5. YARN TWIST MATHEMATICS
! !
2 3 4 5 6 7
are kept taut. This produces a "corkscrew" ef- factor the "twist multiplier." This is a quantita-
fect where the slack ply entwines about the re- tive index of the relative steepness of the helix
maining straight strands. While useful as a nov- angle. Twist multiplier is defined as
elty effect, corkscrew yarns should be avoided
in any industrial fabric where high strength-to- T
TM = C112 (18.1)
weight ratios are desired. Corkscrew yarns are
weak because all plies do not break at the same
time, and the yarn is stated to be "inefficient" where
because lack of rupture elongation balance.
When tension is applied to such a yarn, the T = turns per inch
multi-yarn core, being shorter, will reach its C = cotton count
limiting strain and will break first. Then the
load is transferred to the corkscrewed yarn (or The twist multiplier is widely used as an em-
yarns). Depending upon their number, these pirical means for establishing proper twist in
may be too weak to support the load previously staple yarns. For cotton, for example, twist mul-
held by the straight core yarns, and so they, too, tipliers range from 2.5 for soft twisted yarns to
fail. Thus the strength of a corkscrew yarn must six for very hard twisted yarns. Qualitatively,
always be less than the theoretical attainable in cotton singles yarns having a TM of about 4.5
a yarn devoid of corkscrew (see Appendix 5 for have a surface helix angle of about 30°.
additional comments on corkscrew).
reached. For the example shown, this is at about yarn strength are more effective at higher twist,
22 turns per inch. Then the strength starts to and so a rising and then falling twist versus
decrease. Two phenomena working opposite to strength curve results.
each other produce this type of twist-strength To explain the translation of staple fiber
relationship. As the twist increases, the individ- strength into spun yarn strength is an exercise in
ual fibers assume helical paths and wrap around physics and mathematics of considerable com-
each other. The normal pressure and total fric- plexity. Yarn strength is based upon such intrin-
tion of the individual fibers pressing against sic fiber properties as strength, elongation,
each other progressively increase, with accom- cross-sectional shape, length, friction coeffi-
panying yarn strength increase, the theoretical cient, and upon such geometric factors involved
maximum being that force which will rupture in yarn formation, such as yarn diameter, turns
the fibers. per inch, degree of fiber packing (i.e., the ratio
However, as the twist increases, the helix an- of fiber space to void space within the yarn),
gle becomes more acute, and the force compo- and the randomness of fiber position within the
nent along the yarn axis becomes less. This pro- yarn.
duces a progressive reduction in yarn strength.
Furthermore, the randomness of the position of,
and points of contact between, the individual 12. YARN BREAKING STRENGTH
fibers in the yarn produces a distribution of AND ELONGATION TESTS
fiber lengths. When these varying fiber lengths
are stressed, elongation unbalance results, the There are mainly two types of yarn breaking
fibers break one at a time instead of as a group, strength-elongation tests: single end and skein
and a lower yarn strength results. This elonga- tests.
tion balance phenomenon is discussed in Chap-
ter 19.0, Fabric Properties and Technology. 12.1 Single End Test
Thus, the factors tending to produce increased
yarn strength are more effective at low twist, The single end test consists of inserting a
while the factors tending to produce decreased length of yarn between the jaws of the testing
FIGURE 18.4 Effect of twist (turns per inch) on skein breaking strength of cotton yarn.
618 YARN NOMENCLATURE, PROPERTIES AND TECHNOLOGY
machine, separating the jaws, and recording the chines can test the strength of individual yarns
load-elongation curve using tensile testing very fast (a few seconds per yarn test), in a con-
machines. To avoid yarn cutting and "jaw tinuous manner, and may be used to replace
breaks;' capstan rather than flat jaws are often skein tests.
employed. The yarn is wound around the cap-
stans with about ten inches of yarn in the "free
gauge length;' that is, the length between cap- 13. COTTON YARN
stan tangent points. During the test, yarn elon- STRENGTH-COUNT FACTOR
gation takes place not only in the free gauge
area but also progressively around the capstans For cotton yarns the higher the yarn number
where the yarn is being snubbed. This snubbing the lighter the yarn weight and (presumably) the
elongation around the capstan must be taken lower the breaking strength. Because of this in-
into account in calculating true rupture elonga- verse relationship, the product of pounds break-
tion of the yarn (Chapter 20.0, Textile Testing). ing strength and yarn number tends to remain
constant and it may be used as a criterion of
12.2 Skein Test breaking strength efficiency. The product is
called the strength-count factor and is compara-
Single end breaks give valid measures of ble to "tenacity," a term employed to describe
strength and elongation under the selected test the strength efficiency of man-made fibers, cal-
conditions, but are slow and time consuming for culated as grams breaking strength per denier
routine test purposes. At least five, and often (or tex). The strength-count factor, of course, is
fifteen or twenty tests are necessary to obtain a not an absolute constant for singles cotton
meaningful average. Therefore the skein test is yarns, but is dependent upon fiber strength and
widely used. Eighty 1.5 yard wraps of yarn are staple length, yarn twist, whether the yarn is
wound onto a reel, forming a skein which is combed, etc. Empirical equations have been de-
then placed over two capstan jaws on the testing veloped that relate skein strength and yarn
machine, and the breaking strength determined. count.
ASTM D 1578 gives several options for number
of turns and reel diameter. The strength per end
may be calculated by dividing the recorded 14. YARN TWIST BALANCE
strength by 160 ends, or the skein strength itself
may be used as an index of quality. In breaking Fibers in yarns assume an imposed helical
a multiplicity of yarns in this type of test, all shape that is not necessarily stable, there being
yarn ends do not break at the same instant of a desire for each individual fiber to revert to its
time. Because of weak spots, unequal rupture original configuration. The integrated effect
elongations and unequal tensions and lengths sets up a torque in the yarn opposite to the direc-
that develop in winding the skein, some yarns tion of inserted twist, i.e., the yarn tends to un-
will break sooner than others. When one yarn is twist and therefore is stated to be "unbalanced"
broken, the load that it supported is transferred or "wild." Usually the greater the amount of
to the others. This fractional additional load per twist, the greater is the tendency for unbalance.
yarn may exceed the capacity of another yarn, The term balanced yarn is applied to one exhib-
and it, in turn, will fail. The break is progres- iting no tendency to double, twist or kink when
sive through the skein, the phenomenon being held in a slack condition. To test for balance, a
called "serigraph effect" or lack of elongation four or five foot length of yarn is held by the
balance (Chapter 19.0, Fabric Properties and ends and allowed to hang freely in a loop while
Technology). Because of the serigraph effect, the ends are brought together. If this can be per-
individual yarn strengths calculated from skein formed without the loops exhibiting any ten-
strength tests are lower than single end test dency to rotate or twist, the yarn is said to be
values. balanced (Figure 18.5).
Fully automated modern yarn testing rna- When testing for twist balance it is important
18.1 Yam Nomenclature, Properties and Technology 619
fabric may pucker, curl or otherwise distort. Of
course, it will be apparent that for some pur-
poses unbalanced or wild yarns are desired- for
example in the manufacture of "twist" broad-
loom carpets or seersucker fabrics. Presumably
for most industrial uses, however, balanced
yarns and cords are an advantage.
Balance can be obtained via two mechanisms.
Balanced Yam Unbalanced Yarn First, if the relationship of turns per inch and
twist direction among singles, plies, and cords
FIGURE 18.5 Twist balance.
is correct, balance may result purely from the
geometry of the structure. Second, independent
to remove the yarn from the package without of the geometry, balance, particularly in sin-
changing the twist in so doing. Upon cutting a gles, can be obtained by relaxing the torques in-
length of yarn care must be taken not to permit duced during spinning and twisting. Depending
one end of the yarn to rotate relative to the upon the nature of the fiber, this can be ac-
other. It should also be remembered that yarn complished by immersion in water or steam for
twist can be changed by simply drawing the such hydrophilic fibers as cotton, rayon or
yarn over the top of the package. The yarn wool; or by dry heat for such hydrophobic fibers
should always be removed from the package by as the polyesters or the polyacrylics. Aging of
the same method which is to be used for the end the yarn for prolonged periods also is useful in
objective desired. Thus if the balance of a sew- allowing torque stresses to decay until the yarn
ing thread is to be determined, and the yarn nor- is "balanced." Chemical setting may also be
mally is paid off the spool by rotation rather used; in fact this is the basis of many of the so-
than over the top of the spool, the same tech- called wash and wear finishes.
nique should be followed in selecting the sample As a simple example of ply twist balance,
for testing. consider an unstabilized singles yarn that con-
tains eight turns of S twist. Referring to Figure
18.6 this would be accomplished by rotating the
15. RELATIONSHIP OF SINGLES end of a 1 inch element through eight complete
TO PLY TWIST turns in a clockwise direction. If three such 8
tpi S twist singles are now plied together with
In manufacturing plied yarns or cords, the at- eight (plus) Z turns, accomplished by rotating
tainment of yarn balance may be desirable in the three plies about the common axis in a coun-
order to obtain stability in the resulting fabric. If terclockwise direction, the original twist in the
twist balance is not obtained, the yarn will be singles will be removed (approximately).
wild and difficult to manage, and the resulting Thus, the plied structure will have eight
@~ 8Z
@Q~4S
4S
4Z
621
19.0
FABRIC PROPERTIES AND TECHNOLOGY
19.1
Fabric Properties and Technology
S. ADANUR
where weight
(19.2)
= unit area x thickness
C = cover factor
w = warp threads per inch A fabric is composed of both fiber substance
f = filling threads per inch and air space, but only the fiber substance con-
dw = warp yarn diameter in inches tributes to the weight. The theoretical maxi-
d1 = filling yarn diameter in inches mum density achievable if all yarn and fabric
voids are removed by compression is that of the
When a condition is reached where, for either fiber itself. The ratio of fabric density to fiber
warp or filling yarns, the product of the number density is a measure of the degree to which the
of yarns per inch and the diameter equals one, fibers are packed together and is called the
the yarns will touch each other, and the cover "Packing Factor:'
factor becomes one. When this condition exists
for both sets of yarns the cover factor remains . fabric density
one. Often in this latter case the maximum num- Packing Factor (P.F.) = fib d .ty
1 er enst
ber of warp and filling yarns possible has been
woven into the fabric. Any further increase in WIV, V,
picks or ends would result in yams piling up on = WIV, = V, (19.3)
each other to give a double or multiple layer of
yams. Of course the yarns may be compressible
where
and therefore more yams than the theoretical
maximum, calculated on the basis of uncom-
pressed yams, are often weavable into the
W = fiber (as well as fabric) weight
fabric. Fabric cover factor is of obvious impor-
v;= total volume of fabric
V1 = volume of fiber
tance with respect to water, moisture vapor, or
air permeability. In fabric coating the degree of
"Porosity" is the amount of open space within
openness will influence the penetration of coat-
a fabric. Porosity may be defined as the ratio of
ing into or through the fabric, and in part will
the volume of air or void contained within the
affect adhesion.
boundaries of a material to the total volume
(solid material plus air or void) expressed as a
3. FABRIC DENSITY, PACKING
percentage.
FACTOR, AND POROSITY
Vv
The density of a fabric is calculated by mea- Porosity (P) = - x 100 (19.4)
v,
suring its thickness and its weight per unit area:
where
weight
Density = unit volume P = porosity
19.1 Fabric Propenies and Technology 627
Vv = volume of voids in the fabric both yarns must assume a wavy path in order to
Vr = total volume of the fabric be accommodated within the fabric. This wavi-
ness is called yarn "crimp." Depending upon the
Since both packing factor and porosity are tension applied to the yarns during weaving,
measures of the ratio of fiber volume to total most, or theoretically all, of the crimp can be
fabric volume, they are negatively correlated as inserted into the warp, with the filling being
follows: perfectly straight, or the crimp can be inserted
into the filling, with the warp straight, or crimp
P.F.
Vt can be present in both sets of yarns (Figure
v, 19.2).
Fabric tensioning in either the warp or fill-
and ing direction tends to remove the crimp and
straighten the tensioned set of yarns. The
straightening must inevitably produce increased
crimp in the perpendicular set of yarns. This
can be visualized by examining the top and mid-
therefore dle portions of Figure 19.2. Tensioning the
crimped filling produces a straight filling, but a
P = 1 - P.F. (19.5) crimped warp. This crimp transfer is called
"crimp interchange." It can result in important
4. YARN CRIMP AND TAKE-UP changes in fabric gemoetry, which, in turn, can
advantageously or negatively affect such prop-
Since a woven fabric consists of sets of in- erties as breaking strength and elongation, tear
terlacing yarns, either the warp, the filling or strength, energy absorption and crease resis-
filling
warp
• •
crimped warp and filling
• • •
FIGURE 19.2 Fabric crimp.
628 FABRIC PROPERTIES AND TECHNOLOGY
tance. "Negative tension" via water or heat centage of the original length marked in the
relaxation, with accompanying shrinkage, can fabric is the percent crimp. Crimp is normally
also produce crimp interchange. removed at very low loads and, therefore, me-
Fabric weave also influences the amount ticulous techniques are required if accurate
of yarn crimp. The greater the number of yam values are to be obtained.
intersections per unit area of fabric surface, It is important to distinguish between the
the longer must be the path of warp over fill- terms "percent yarn crimp" and "percent yam
ing or filling over warp. Thus a plain weave take-up" or "contraction." The measurement is
fabric will have greater yarn crimp than a the same, but the former is calculated on the
satin. In designing fabric constructions it basis of the crimped length of yarn while the lat-
is important that the crimp-elongation relation- ter is calculated on the extended length. Thus
ship be kept in mind. Thick bulky fabrics usu- according to ASTM [2]:
ally are designed with maximum yarn crimp.
Double and triple fabrics contain high crimp • Percent crimp is the difference in
yarns that travel from the face to the back of the distance between two points on a yarn
fabric. as it lies in a fabric, and the same two
In addition to the crimp resulting from the points when the yarn has been removed
passage of warp over filling, both the yarn itself from the fabric and straightened under
and the fibers composing the yarn can also have specified tension, expressed as a
different crimp frequencies as shown in Figure percentage of the distance between
19.3. Thus three different orders of crimp can the two points as the yarn lies in the
exist within a fabric structure. fabric.
The percentage crimp which a yarn contains • Percent take-up is the difference in
as it lies in a fabric is determined by placing distance between two points in a yarn as
gauge marks on the fabric, with crayon or ink, it lies in a fabric, and the same two
for example exactly ten inches apart, so that one points after the yarn has been removed
or more of the yarns will contain the marks. from the fabric and straightened under
Each marked yarn is then raveled out of the specified tension, expressed as a
fabric, taking care not to strain it or disturb its percentage based on the straightened
twist. The flat jaws of a low capacity constant out-of-fabric distance.
rate of extension tensile tester are adjusted to a
gauge length of exactly ten inches, and the yarn The weaver uses percent take-up because it tells
inserted so that the original gauge marks on the him the length of fabric he will obtain from a
yarn will exactly line up with the edge of each given length of yarn.
jaw. In this condition, because of the presence
of yarn crimp, the yarn will be loose and floppy
between the jaws. The lower jaw of the testing 5. FABRIC SKEW AND BOW
machine is slowly moved down, thus plotting an
accurate load-elongation diagram, until the load The filling yarns in a fabric may not always lie
required to straighten but not stretch, the yarn is perpendicular to the warp. Furthermore, be-
achieved. The resulting elongation, as a per- cause of tensions developed during weaving, the
filling yarns may assume the shape of an arc or
bow as they lie in the fabric. The former condi-
filling yarn
tion is known as skew; the latter as bow (Figure
~ 19.4).
Skew is defined as the distance, measured
parallel to and along the selvage, between the
point at which a filling yarn meets one sel-
fiber in yarn
vage, and perpendicular from the point at which
the same filling yarn meets the other selvage.
FIGURE 19.3 Three types of fiber and yarn crimp. It is expressed as a direct distance (AB in
19.1 Fabric Properties and Technology 629
warp warp
B c
A v --- ---.
--
v t-....
v ..- t-....
---
v ..- t-....
v ..- t-....
v ..- t-....
v D r--.,
F k f-"
- - 'E - r-- b G
selvages
Skewness Bow
Figure 19.4) or as a percentage of the fabric per weight, and is most often given as running
width: yards per pound. Area per unit weight-for ex-
ample, square yards per pound-is practically
% Skew = (AB/BC) X 100 (19.6) never used.
Bow is defined as the greatest distance,
measured parallel to the selvages, between a
filling yarn and a straight line drawn between 7. FABRIC THICKNESS
the points at which this yarn meets the two
selvages. It is expressed as a direct measure- Because fabrics are compressible, the mea-
ment DE in Figure 19.4, or as a percentage of surement of thickness should be made under
the fabric width: controlled pressure of the thickness gauge.
ASTM D 1777 specifies different pressures for
%Bow= DE/FG (19.7) different fabrics [3]. For dense compact fabrics,
thickness is not critically influenced by pres-
sures. For lofty, "soft," compressible fabrics it
6. FABRIC WEIGHT may be necessary to specify both the pressure
and the area of the presser foot. Also, because
As in the case for yarns, there are both direct the fabric might gradually compress and creep
and indirect systems for describing fabric under the dead load, often the time, usually in
weights. The direct system indicates weight per seconds, that has elapsed between initial load
area, or weight per running length for the full application and the reading of the gauge, should
width of the fabric. It is unfortunate that many be specified.
times when the fabric weight is given, the units
are not recorded, so that one cannot know (ex-
cept by experience) whether the weight per 8. FABRIC COMPRESSIBILITY
square yard or running yard is meant. Further- AND RESILIENCE
more, the weight per running yard is meaning-
less (again except by experience) unless the If a textile fabric is subjected to a progres-
width is given. sively increasing compresssional load, there
The indirect system indicates running length will be a progressive decrease in thickness.
630 FABRIC PROPERTIES AND TECHNOLOGY
fice. The proportionality constant includes co- cover factor is lowered, and the pore space of
efficients of contraction and velocity, the free area between yarns increases. This pro-
approach area, the fluid density and the gravita- duces an increase in air permeability.
tional constant. For a fabric, air flow at any Any construction factor or finishing tech-
selected pressure differential is directly propor- nique that changes the area, shape or length of
tional to the product of the amount of open area the air flow path can appreciably change air
within the fabric through which the air can flow, permeability. The effect of twist has been dis-
and the square root of the pressure drop across cussed above. Yarn crimp is important because
the fabric: it permits the yarns to extend easily, thus open-
ing up the fabric and increasing the free area
Q = K(FA)(Ap) 112 (19.15) when a pressure differential is applied. In addi-
tion, yarn crimp and fabric weave will influence
where the shape and length of the free area orifice. Hot
calendering is often used to reduce fabric air
Q = volume flow rate per unit fabric area permeability by flattening the yarns so that their
FA = free area (fractional area of the total cross-sectional shapes are elliptical rather than
fabric surface not occupied by yarns) circular, thus reducing free area.
K = proportionality constant dependent upon
fabric geometry and other fluid flow fac-
tors 11. MOISTURE VAPOR TRANSMISSION
Ap = pressure differential across the fabric
Water vapor will pass through a fabric pro-
For a hypothetical fabric composed of per- vided there is a relative humidity differential
fectly circular filaments that do not elongate across the fabric, and provided that the vapor
under the applied pressure differential, the air can transpire between yarns within the fabric,
flow can be calculated from the above formula, between fibers within the yarns, or through the
provided K is known. However, textile fibers fiber substance itself. For fabrics with low cover
are viscoelastic, and deform under the tensions factor where free space exists between yarns,
that develop as a result of the applied pressure. water vapor will pass through the yarn or fabric
The measurement of air permeability becomes voids. For high cover factor fabrics composed
further complicated because, as the pressure in- of yarns containing densely packed fibers, water
creases, the yarn elongations produce changes vapor cannot pass through the yarn or fabric in-
in the shape of the interstices and the total free terstices. If the fiber is hydrophobic, that is, has
area increases, thus producing a concomitant zero moisture regain and will not absorb or re-
increase in air flow. lease water vapor, the fabric will act as an im-
It is common practice in the laboratory to pervious membrane. However, if the fiber is
measure air flow in cubic feet of air per square hydrophilic and can easily absorb or release
foot of fabric per minute at a pressure differen- water vapor, significant although limited
tial across the fabric equivalent to 0.5 inches of amounts of vapor can be transmitted through the
water. In actual use of fabrics, much higher fabric. For synthetic hydrophobic fibers, when
pressure differentials may develop. It has been the fiber volume in the fabric exceeds about
established that at pressures up to about 50 35% of theoretical maximum, moisture trans-
inches of water, air flow takes place primarily mission resistance increases rapidly, while for
between adjacent yarns, and only to a minor hydrophilic fibers such as cotton and wool, the
degree between fibers within a yarn. The effects resistance increases slowly. If the fabric con-
of yarn twist on air permeability are twofold. In struction is proper, a fabric can have low air and
parachute fabrics composed of multi-filament liquid water permeability but nominal water
yarns, as twist increases, both the circularity vapor transmission.
and the packing density of the yarn increase. Moisture vapor transmission is determined
Therefore, yarn diameters are reduced, the by the "absorption cup" or the "evaporation"
19.1 Fabric Properties and Technology 633
method. In the former the test fabric is placed penetration of water or both. "Water repellency"
horizontally over a cup of calcium chloride or is defined as the ability of a textile fiber, yarn or
other desiccant, the assembly is placed in a con- fabric to resist wetting. Different tests for mea-
stant relative humidity atmosphere, and the ab- suring the water resistance or repellency of fab-
sorption of water by the desiccant is measured rics are defined in Chapter 20.0, Textile Testing.
by weighing the entire assembly at known time The tests are of varying degrees of severity, but
intervals. The second method consists of plac- basically they measure (1) the resistance of the
ing the test fabric horizontally over a cup of fabric to surface wetting and penetration by fall-
water, placing the assembly in a constant low ing drops of water; (2) the amount of water
relative humidity atmosphere, and plotting the that the fabric will absorb when immersed or
loss in weight of water with time. For both tests manipulated under water; (3) the hydrostatic
transmission is calculated as grams of water pressure required to cause fabric leakage, or the
transmitted per square meter of fabric per amount of water leakage at a given hydrostatic
twenty-four-hour period. While these methods pressure; and (4) determination of fiber, yarn,
give valid results for impermeable materials or fabric wettability by contact angle measure-
such as plastic films, and may be useful for ment.
comparing fabrics, they do not give precise Gray unbleached cotton and linen fabrics have
results for open fabrics of high moisture trans- considerable natural water repellency because
mission. This is because as the water is ab- of the natural waxes present. Scoured and
sorbed into the desiccant (first method), or bleached cotton and linen fabrics, and also
evaporates (second method), the relative humid- rayon fabrics are particularly hydrophilic unless
ity of the air adjacent to the fabric may not re- water-repellent chemical finishes are subse-
main constant. quently applied. Thus they enjoy wide usage
where large amounts of water are required to be
absorbed. Wool initially has a fair degree of
12. WATER REPELLENCY natural repellency, but when fmally wet out, it
AND RESISTANCE has a large capacity to hold free water.
The tendency of a drop of water to spread out
There are varying degrees of water repellency over a fiber, yarn, or fabric surface is dependent
and resistance depending upon the nature of the upon the angle of contact made by the water
fiber, the fabric construction, and whether the drop and the surface. If the fabric surface is
fabric is covered with an impermeable coating. water repellent, the drop will rest up on it and
The term waterproof is used to describe a fabric will not penetrate. The contact angle is stated to
that is completely impermeable to the passage be high. If the water can easily wet the surface,
of water and moisture when water pressure is spreading occurs with accompanying low con-
applied, and that will retain this property tact angle. A synthetic fiber may be completely
throughout its expected life under normal use. resistant to water absorption, and yet its surface
In trade practice the canvas goods industry may be thoroughly wetted by water. Therefore
applies the term waterproof or waterproofing to synthetic fabrics are often quickly and com-
knife coated finishes comprising such ingre- pletely wet out, the water coating the surface of
dients as paraffins, pigments, and resin binders each fiber, as well as filling the voids between
with add-on weights of 50 to 90%. These types fibers. Because many synthetic fibers are hydro-
of treatments may not in fact produce fabrics phobic, it does not follow that fabrics made
that meet the strict waterproof definition. Rub- from them will be water repellent. In fact, the
ber or vinyl coated fabrics that truly are water- voids that lie between fibers may act like capil-
proof are usually referred to as "coated fabrics." laries and actually enhance the spreading and
The American Association of Textile Chem- wicking of the water. Therefore many synthetic
ists and Colorists (AATCC) and the ASTM de- fibers must also be treated with special finishes
fine "water resistance" as a general term denot- if they are to be water repellent.
ing the ability of a fabric to resist wetting or Fabric structure can play an important part in
634 FABRIC PROPERTIES AND TECHNOLOGY
water resistance. For example, a tightly woven "Orion" must be brought below 2.5% regain, its
cotton fabric with high cover factor that, when 100% R.H. regain value before it feels dry.
dry, has sufficient interstices between yarns to Thus the original regain of each fiber is of little
allow moisture vapor to dissipate, thus making consequence.
the wearer comfortable. Upon wetting, the cot- The general statement that synthetic fabrics
ton fibers swell, making the fabric construction are "quick drying" is fallacious. It is true that a
"jammed" so that water cannot get through the thin, lightweight, low moisture regain synthetic
yarn and fabric interstices. filament fabric will dry more quickly than a
thick, heavy, high moisture regain spun yarn
fabric, but this is because the latter fabric must
13. DRYING RATES AND DRYING TIME have a great deal more water evaporated from it
before it becomes dry, not because it is made
The rate and time of drying for a textile mate- from hydrophilic fibers.
rial is a function of the state of aggregation (i.e.,
shape, position and distribution) of the fibers in
the yarn and the yarns in the fabric, and depends 14. FABRIC BREAKING STRENGTH
as well upon the relative humidity, temperature AND ELONGATION
and velocity of the air which is doing the drying
via moisture absorption and subsequent dissipa- The breaking strength of a fabric is popularly
tion. The moisture regain of the fiber itself has used both for quality control and as a perfor-
little influence on drying rate and time. mance standard. For industrial or other pur-
The drying mechanism consists of the water poses where the fabric is in fact subjected to
on the surface of the fibers evaporating into the tension, it is proper that breaking strength be
surrounding air. Diffusion then causes water measured. In cases where the fabric is not
held within the fabric to come to the surface called upon to withstand tensile forces, rightly
where it too can evaporate. The major part of or wrongly breaking strength is probably the
the drying cycle from near saturation down to most popular method for maintaining quality
within 15% regain above 100% R.H. equilib- control. It is an easy test to make, and gives a
rium moisture regain is characterized by a con- quick and reliable indication that the fiber, yarn
stancy in evaporation rate. This rate in grams or fabric is up to standard. It should be remem-
per square centimeter of fabric per hour is equal bered, however, that there are many textile ap-
for all fabrics of the same yarn and fabric con- plications where strength is of little conse-
struction, irrespective of fiber type, except quence, and its use as a standard or quality
that smooth-surfaced non-hairy fabrics exhibit index may be meaningless, improper, or far out-
somewhat higher rates. Total drying time under weighed by other important criteria. In some
household drying conditions is dependent upon cases the maximum or minimum elongation
the ratio of total moisture uptake to peripheral which is produced at a selected strength level
surface area of fabric. It is generally known that below rupture is specified as a criterion.
identical textile structures will evaporate via Two types of fabric strength tests are com-
identical mechanisms and at identical rates. An monly used: the "raveled strip" and "grab"
"Orion" acrylic fabric and a wool fabric, both of methods.
the same yarn and fabric type, will have equal
drying rates as measured by graphs of weight 14.1 Raveled Strip Strength Test
loss versus time. Drying times (i.e., the time re-
quired for the fabric to feel dry to the touch) A specimen 6 inches long and 1.25 inches
will also be the same. These statements hold wide is cut in either the warp or filling direc-
even though the "Orion" has a moisture regain tion. Edge yarns in the longer direction are rav-
of 1.5% and the wool about 16%. The wool will eled out and removed from the fabric until its
feel dry when it has reached a regain somewhat width becomes one inch. A fringe 118 inch thick
lower than 29%, its 100% R.H. regain; but the on each side of the fabric thus results (Figure
19.1 Fabric Properties and Technology 635
Jaw
Jaw 2xl" lxl"
6"
6"
Jaw
Jaw 2xl" lxl"
4"
Strip Grab
FIGURE 19.6 Raveled strip and grab breaking strength test specimens.
19.6). The test strip is clamped lengthwise in the rics, resin impregnated fabrics where warp and
flat jaws of the testing machine so that there are filling yarns are bonded at yarn intersections,
three inches between jaws. Each jaw is two felts and nonwovens are cut to one inch, and are
inches wide so that all yarns within the fabric not raveled. Another advantage of raveling is
are held and broken during the test. If the fringe that it permits the person conducting the tensile
is not present, as the tensile force progressively test to line up the yarns parallel with the direc-
increases, the edge yarns will pop out of the tion of pull on the testing machine. There is less
fabric, and while they are still held by both jaws, chance for a fabric to be tested slightly on the
in effect a combination of yarn and fabric is bias where yarns will not be through-going
tested, with the popped yarns not usually shar- from top to bottom jaws.
ing their full burden of the load. The fringe pre- The raveled or cut strip tensile test is an ex-
vents the yarns from popping out and hence the cellent method for studying the effects of chemi-
fabric is tested as a fabric. cal finishes, heat aging, weathering, microbial
Purely on a percentage basis, the need for ac- deterioration, and the like on tensile properties.
curately raveling coarse heavy fabrics where Modern tensile testing machines produce a
there may be fewer than thirty threads per inch record of the load-elongation diagram from
is obviously much greater than for fine light- which strength elongation and energy absorp-
weight fabrics of eighty threads per inch or tion can be determined. Strip strength values
higher. If for any reason the yarn in the fabric is are normally reported as pounds per inch.
not easily raveled, it is then not necessary to Breaking elongation is calculated as percent of
ravel, for the edge yarns will not pop out during original gauge length. Energy is given in inch-
the test. In such cases the fabric is cut exactly pounds per inch length and width of specimen
one inch wide, and tested directly. Coated fab- or gram-em per cm2 •
636 FABRIC PROPERTIES AND TECHNOLOGY
tion, primary and secondary creep, and their 16. BURSTING STRENGTH
geometric counterparts.
There are many industrial uses where textile
15. BIAXIAL STRESSING fabrics are called upon to withstand bursting
type forces that develop via air, fluid, or
The strip or grab tensile test is in general direct mechanical pressure. Pump diaphragms,
primarily concerned with the load-elongation screening, filter press fabrics, parachutes, hose,
characteristics of a specimen measured in a sin- tarpaulins, and bags, are typical examples. The
gle direction for any given test. Tests may of application of a pressure force perpendicular to
course be performed in more than one fabric the plane of the fabric is manifested as biaxial
direction, most commonly in warp and filling tensile forces along the warp and filling yarns
directions, but each is evaluated without respect within the fabric (Figure 19.8). The moduli of
to any phenomena along any axis other than that the yarns and the tensions that develop as the
of the test. Such tests are commonly classified result of the pressure will influence the overall
as "uniaxial." That such a title is a misnomer extension and shape of the fabric under pres-
can easily be seen by observing a simple strip sure.
tensile test, and noting the narrowing that takes Two common textile structures that are called
place in the unrestrained region. Deformations upon to withstand pressures, and that may be
are therefore occurring along more than one ax- analyzed for resulting stresses by classical
ial direction. What is really meant by a uniaxial engineering methods are "thin membrane" ma-
test is not that loads or deformations take place terials in the form of (1) a hemisphere or dia-
along only one axis but that they are applied and phragm, and (2) a pipe. Assuming that each
measured along only one axis. attains its proper respective shape upon applica-
For many purposes a uniaxial test is adequate. tion of pressure, the following relationships ex-
It is an index of relative strength, of the degra- ist between the pressure applied and the ten-
dation or improvement afforded by a treatment. sional stresses that develop.
Nonetheless, the practical applications of fab- For a diaphragm (Figure 19.8):
rics only rarely impose a truly uniaxial stress.
Some examples of this are tapes and belts used
(19.16)
for power transfer in machinery and ropes. In
the more common cases stresses are simultane-
where
ously imposed in more than one direction. Ob-
vious examples of this are the deformations at
the knee or elbow of a garment, the fabric in a
sl and s2 = membrane stresses
P = pressure
filter press, the walls of a fire hose, or the dry-
R = radius of sphere
ing of a fabric on a tenter frame where warp and
t = membrane thickness
filling tensions are exerted at the same time.
Biaxial testers require control of the ratio of
For a pipe (Figure 19.8):
loading rates in the warp and filling directions
and means for recording the resulting strains. • longitudinal stress
Usually a cruciform specimen is employed, the (lengthwise with the cylinder wall)
two sets of jaws gripping opposite tails (Figure
19.7). In order to prevent the central portion of S _ PR
the fabric from skewing during the test, all four I - 2t (19.17)
jaws must move at controlled rates. It is gener-
ally believed that the data obtained from the • hoop stress
biaxial tests are usually not worth the effort ap- (along the wall circumference)
plied. There are other empirical and easier ways
of gaining an insight into the biaxial properties S2 _- PR (19.18)
of fabrics, and these are the burst tests. t
638 FABRIC PROPERTIES AND TECHNOLOGY
(
l
i
jaw
II
•rim,
jaw jaw
jaw
)
Diaphragm stresses Pipe stresses
the interstices between yarns increase, i.e., the 17. YARN AND FABRIC
"free area" unoccupied by yarn increases and the ELONGATION BALANCE
"cover factor" is reduced. This results in more
air or liquid being capable of passing through In Chapter 17.0, Fiber Properties and Tech-
the fabric. Because textiles are viscoelastic and nology, it was pointed out that corkscrew, or the
will creep under the load, the air or liquid wrapping of one ply around the others in a plied
permeability of a fabric may increase with time yarn, is undesirable because it lowers yarn
because of the continuous application of a force strength efficiency. When tension is applied, the
upon warp and filling. It is important that the multi-singles core, being shorter, will reach its
fabric modulus be high enough so that the fabric limiting strain and will break first. Then the
will not get out of shape, distort, and open up to load is transferred to the corkscrewed singles
the point that it passes excessive air, or no yarn, but it is too weak to support alone the load
longer effectively filters. On the other hand, it is previously held by several singles, and it too
equally important that the fabric not be so inex- fails. Thus the theoretical maximum strength is
tensible that it cannot absorb energy, and fails not attained because all singles making up the
because it reaches a limiting stress instead of ply yarn do not break at the same time.
deforming. For repeated use, the fabric should It is equally desirable that all yarns in a fabric
have a high degree of creep recovery. break at the same limiting elongation and at the
Coated fabrics are often subjected to bursting- same time.
type forces and for proper continued function- Fabric elongation usually is composed of both
ing without cracking or delaminating, the elon- geometric and intrinsic components, and it is
gation of the coating at any load must always be necessary that total yarn elongations be equal
greater than that of the base fabric. To prevent for all yarns if high strength efficiency is to be
such types of failure, rubber and elastomer achieved. For example, a warp yarn of proper
coatings are normally made with rupture elon- elongation uniformity may be woven into a
gations considerably higher than those of the fabric with a weave such that some warp yarns
fabric to which the coating is applied. will be longer than others because of crimp dif-
Two types of bursting load measurements are ferences. When such a fabric is put under ten-
made in the laboratory. The "ball burst" test de- sion, the yarns with lower crimp will fail first,
termines the force necessary to drive a one inch the load will then be transferred to the remain-
diameter steel ball through a 1.75 inch diameter ing yarns of higher crimp, and they in turn will
ring clamped fabric sample. In the "diaphragm fail, but the maximum strength potentially avail-
test;' also commonly called the Mullen burst able in the cloth will not be achieved. In weav-
test, a rubber diaphragm actuated by hydraulic ing it is very important that warp tensions in the
oil is forced against a 1.2 inch diameter sample. loom be as uniform as possible in order that
The oil pressure necessary to rupture the fabric equal lengths of yarn be produced in the fabric.
is recorded. The ball burst test records total This is particularly necessary for low elonga-
force, i.e., pounds. The diaphragm test records tion yarns such as glass. With more extensible
pressure, i.e., pounds per square inch. There is yarns such as nylon, total elongations have a
no simple constant relationship between the two chance to even out, and the strength translation
set values. The rubber diaphgram in the di- efficiency is higher.
aphragm test accommodates to the configura-
tion of the fabric which in turn is distorting as a
function of the applied load. The area of the 18. IMPACT PROPERTIES
specimen is not a constant with load and is un-
known at the time of break. Therefore, the pres- In a great many applications, textile materials
sure recorded on the instrument dial is the oil are often called upon to withstand "high speed"
pressure within the machine, and is not neces- or "impact" loading. The cords in automobile
sarily a measure of the true pressure upon the and particularly airplane tires, auto and airplane
specimen. seat belts, parachutes, aircraft carrier arresta-
640 FABRIC PROPERTIES AND TECHNOLOGY
tion cables, and body armor are typical exam- when compared with service conditions, where
ples of textile products that must have high im- extension rates may be in the range of 500,000%
pact strength. In textile processing, fibers or per minute. It is well known that the strengths of
yarns may be impacted at low loads but at high most viscoelastic materials are greater, and rup-
frequencies in conjunction with picking, card- ture elongations are less, when tested under
ing, combing, spinning, and weaving. A sewing "impact" conditions as compared with "static" or
machine causes thread to be impacted at veloci- low extension rate conditions.
ties up to 180 ft/sec with short loading pulses of There are several kinds of test instruments de-
less than one millisecond duration. veloped to measure impact properties. Among
In cases where textiles are subjected to impact these are freely falling weights of various
forces it is required that they have the capacity masses, dropping pendulums, high speed rotat-
to absorb large amounts of energy in an ex- ing flywheels, which at a selected time will en-
ceedingly small period of time. The area under gage a jaw and elongate the test specimen, and
the load-elongation diagram is a measure of the guns of various types that fire a projectile at the
ability of the material to do work. The absorp- test specimen. Elongation or strain rates may
tion of energy can be accomplished via various range from 1 to 500,000% per minute. Since the
combinations of strengths and elongations. For time required to rupture a specimen is usually in
example, the kinetic energy of a plane landing the thousandths or millionths of a second range,
upon the deck of an aircraft carrier could be extremely sophisticated and expensive elec-
converted into strain energy by use of a solid tronic devices are necessary to record load,
concrete steel barrier, but the energy transfer elongation and time.
would take place via the buildup of a high load At values below the critical velocity (de-
in a very short time, and the plane would be scribed below) breaking strengths normally in-
demolished. If the deck length were no prob- crease and elongations decrease as impact speed
lem, the kinetic energy could be absorbed is increased. A simple explanation of this phe-
slowly by the friction of the brakes, or the rever- nomenon is that at slow speeds the viscoelastic
sal of the pitch of the propellers. In practice, of fibers have time to deform, and so plastic flow
course, the plane is stopped by arrestation rather than immediate failure takes place with
cables of both moderately high strength and accompanying greater rupture elongation. Un-
elongation, thus absorbing the plane's energy der impact conditions the viscous components
over a time period sufficiently long to prevent of the fiber require higher stresses to cause
excessive force buildup, but sufficiently short so deformations at high speeds. Therefore the
that the plane stops within the length of the breaking strength increases. At ballistic speeds,
flight deck. Where impact forces are involved, viscoelasticity has no opportunity to function at
the path of the load-elongation diagram, be- all, and primary or secondary creep elongation
cause it is a direct measure of energy absorp- cannot contribute to energy absorption. There-
tion, must be considered with respect to the fore the ability of a material to withstand ballis-
maximum stress and strain developed, and the tic impact loading is probably a function of the
time period during which the energy is being instantaneous elastic deflection portion of its
absorbed. conventional stress-strain diagram, the primary
In the laboratory the load-elongation diagram and secondary creep components not being con-
of a fabric or cord is normally determined by sidered. It has been found, however, that at the
separating the jaws of the testing machine at instant of impact, stress waves develop that
from about 1 to 12 inches per minute. The spec- travel through the fabric at a speed based pri-
imen length usually ranges from 3 to 20 inches. marily on the velocity of sound through the
Therefore the maximum rate of extension of the fibers. In effect this defines the length of speci-
specimen is about 12 inches per minute per 3 men which is being placed under load. The
inches original gauge length, or 400% per greater the speed of sound through the material
minute-a relatively slow rate of deformation the greater is the specimen length, and the
19.1 Fabric Properties and Technology 641
J5U = AVE. UPPER LOAD LEVEL from the resin applications and the binding of
lSM =/t./E. LOWER LOAD LEVEL yams so that they cannot shift to reinforce each
other. Yam extensions are lowered, the tear for-
~=J5U-!5M mation is changed, and instead of two or three
yarns breaking at the same time, they may be
breaking singly because they cannot bunch up.
Thus the tear strength is appreciably reduced.
0
It will be apparent that fabric weave can have
9 a great influence on tear strength. All other
construction factors being equal, a 2 x 2 bas-
ket weave will have more than twice the tear
strength of a 1 x 1 plain weave, the reason be-
JAW SEPARATION
ing that the two yarns act as one and they break
at the same time. A 3 x 1 twill has about 1.5
times the strength of the plain weave. For the
same yarns and the same weaves, tear strength
diminishes as thread count increases. A high
count plain weave cotton fabric will have a
lower strength than a low count fabric. It is dif-
ficult to tear a cheesecloth or gauze because the
construction is so open. The tear opening is
very large, and the yarns bunch up to reinforce
each other, so that tearing is difficult.
The higher original tear strength of a basket
weave, as compared with a plain weave, may not
be retained when such fabrics are coated. The
increased openness (i.e., lower cover factor) of
the basket weave causes greater resin coating
"strike-through" into the fabric structure. Yarns
may thus become immobile and be incapable of
bunching together to reinforce each other. The
yarns then break individually rather than in
groups, and the tear strength is thus severely
lowered.
FIGURE 19.10 Failure mechanism and tear diagram in Sometimes a fabric is constructed so com-
tongue tear test. pletely unbalanced with respect to warp and fill-
ing strengths and elongation that it is impossible
amount of tear energy or toughness. Low modu- to tear the stronger, tougher set of yarns. When
lus extensible yarns have an opportunity to ad- an attempt is made to tear across the stronger
just in the tearing area. Two or more may have set, the weaker set of yam fails, and the tongue
a chance to function together, and this produces is torn away from the specimen. It is impossible
a higher tear strength. For fabrics of the same to determine the tongue tear strength of such a
construction at equal yam strength levels, the fabric in the stronger direction. When this oc-
higher the breaking elongation the higher will curs the "trapezoid test" is sometimes used, but
be the tear strength and energy. Often when its meaning is highly questionable.
resin finishes are applied to fabrics the tear
strength is reduced severely, while the tensile 19.2 Trapezoid Tear Test
strength is hardly altered or may even be in-
creased. The answer lies with the embrittlement The test specimen is 6 X 3 inches with a
or increased modulus of the yam, resulting quarter inch cut placed midway along the longer
19.1 Fabric Properties and Technology 643
direction. The sample is inserted on the bias be- of both the intrinsic abrasion resistance of the
tween the jaws of the testing machine so that the fiber composing the yarn and the geometry of
yarns are caused to fail progressively. the yarn structure. Textiles are flexible, and de-
The increasing slack in the specimen from pending upon the end use, repeated flexing as
one side to the other causes individual yarns well as pure abrasion can contribute to product
progressively to be brought into tension and failure. Therefore to simulate service condi-
fail. The test is entirely of a tension type, and tions, in many abrasion test methods the yarn or
has little meaning in terms of the practical tear- fabric is repeatedly flexed and abraded.
ing characteristics of a fabric. Therefore, this Intrinsic abrasion resistance of fibers was dis-
test is not used much. cussed in Chapter 17.0, Fiber Properties and
Technology. The geometric arrangements of
19.3 Elmendorf Tear Test fibers in yarns and yarns in fabric are equally
important in designing fabrics with high abra-
The Elmendorf tester employs a pendulum to sion resistance. Consider a yarn composed of,
apply energy sufficient to tear through a fixed say, thirty continuous filaments. The turns per
length of fabric. The tear is of the tongue type. inch in the yarn, the yarn crimp and the fabric
The tester consists of a sector shaped pendu- weave will all influence the frequency with
lum, carrying a clamp that is in alignment with which a particular filament will appear on the
a fixed clamp when the pendulum is in the fabric surface, such that it will come in contact
raised starting position with maximum potential with the abradant. The relationships of yarn
energy. A rectangular specimen is fastened in singles to ply twist will govern yarn shape,
the clamps and a slit is made to start the tear. degree of fiber packing and these in turn will
The pendulum is released and the specimen is also influence the amount of fiber or yarn sur-
torn as the moving jaw separates from the fixed face in contact with the abradant, and the fre-
jaw. The energy required to tear is the potential quency with which a particular filament or yarn
energy difference at the beginning and end of ply will become abraded. Low twist yarns tend
the pendulum swing, as measured by the posi- to flatten, and a greater surface may be exposed
tion of the pendulum at the end of the test. A to abrasion, although by this arrangement the
graduated scale attached to the pendulum in- stress concentration may be lowered. In addi-
dicates the percentage of original potential en- tion, individual fibers in low twist yarns may
ergy available that was consumed in tearing the not be held together well, and they may be
test specimen. Tear energy is recorded as inch- snagged and broken by the abradant. Higher
pounds per inch of fabric torn (or gram-centi- twist yarns will retain roundness and cohe-
meters per centimeter). The average tearing siveness, presenting a smaller total surface to be
force may be calculated by dividing the energy abraded. However, the stress concentration may
by twice the length of tear, because during the be high, and the outer surface filaments may
test the jaws separate a distance equal to twice become more severely abraded. Higher yarn
the length of tear. twist may also reduce individual fiber mobility,
The Elmendorf test is quick and easy to use, and so flex resistance can be significantly
and gives a valid reading without the necessity lowered. For heavy plied yarns, cables, and
of making even limited calculations. The actual ropes, the number and diameter of filaments,
tearing time is in the order of one second, so and the singles-ply-cord twist relationships can
that the Elmendorf can almost be considered to be arranged so that certain fibers are buried
be an impact tear test. It does not show maxi- within the structure and bear the requisite ten-
mum and minimum tear strength levels, how- sile load, while other surface fibers bear the
ever. abrasive action, but are not subject to high ten-
sile forces.
20. ABRASION RESISTANCE Backer and Tanenhaus [4] list the following
factors as having an influence on fabric abra-
The abrasion resistance of a yarn is a function sion: geometric area of contact between fabric
644 FABRIC PROPERTIES AND TECHNOLOGY
and abradant; local pressures or stress concen- abrasion test and performance criteria carefully
trations developing on specific yarn points or selected in order to make the test meaningful.
area; threads per inch; crown height, or the ex- At best a laboratory abrasion test may be a
tent of yarn rise out of the fabric plane at warp hazardous way of predicting service perfor-
and filling intersections; yarn size; fabric thick- mance.
ness; yarn crimp; float length; yarn cohesive- When comparing two or more fabric samples,
ness; compressional resilience of fabric and two basic approaches may be taken. The most
backing; fabric tightness; and cover factor. direct method is to abrade all test specimens to
A number of laboratory abrasion testers are exactly the same number of cycles, and then,
used. Independent of the design, they all proba- evaluate their relative appearance, strength loss,
bly fall into one of the following categories in thickness loss or the like. A second method is to
terms of their actions. abrade all specimens until they appear equally
damaged or destroyed, and to record and then
(1) Plane unidirectional abrasion-The abra-
compare the number of cycles required.
dant travels back and forth in a straight line
The intensity of the abrasive action is of great
over the flat fabric surface.
significance. If the abrasion is too severe either
(2) Plane multi-directional abrasion-The abra- inadvertently or in order to reduce testing time,
dant rotates, producing a multi-directional so that fabric destruction occurs after a few
abrasive action over the flat fabric surface. cycles, the results may be meaningless. For ex-
On some machines each point on the fabric ample, if two lightweight fabrics are being eval-
surface is abraded in one direction only, uated and the abrasive action is so sharp, hard,
although the direction may change from or rough that both samples are destroyed in 25
point to point. On other machines the direc- or 30 rubs, no proper comparison can be made.
tions, ideally, are entirely random. If instead, a relatively mild abradant is used, re-
(3) Unidirectional flex abrasion-The fabric is quiring 1,000 or more rubs, then any differences
flexed and abraded back and forth over a which are observed become more meaningful.
cylindrical abrasive surface. The direction of the abrasive action relative to
(4) Random flex abrasion-The fabric is ran- the fabric construction can have a marked effect
domly flexed and abraded in all directions. on abrasion resistance.
(5) Flex without abrasion-An advantage of The problem of correlating laboratory abra-
many flex-abrasion testers is that the abra- sion tests and service performance exists be-
dant can be removed and replaced with a cause, in use, a textile may be subjected to
polished surface or minimum friction roller wind, water, weather, heat, cold, bending,
that will permit yarn or fabric flexing flexing, tension, punctures, tears, etc., all of
without surface abrasion. which are grouped under the general heading of
"wear:' In the laboratory more idealized condi-
Criteria of Abrasion Resistance tions prevail and usually only abrasion, with or
without flexing, is permitted to act upon the test
There are many variables that must be con- fabric.
trolled in order to give meaning to abrasion re-
sistance results. The abrasive surface should be
uniform and not change during the test. For the 21. STIFFNESS
planar abrasion tests, the weight of the abradant
and hence the pressure on the fabric surface is The importance of proper fabric stiffness or
significant. For the flex abrasion tests the ten- flexibility should not be overlooked with respect
sion on the fabric is also significant. to the proper functioning of an industrial textile
The three popular criteria of abrasion resis- fabric. Probably the prime reason textiles are
tance are visual assessment, cycles to form a useful is because of their flexibility. Two simple
hole and strength loss. The fabric's end use stiffness criteria are commonly used. The "can-
should be known, and the type of laboratory tilever bending length" is a measure of the
19.1 Fabric Propenies and Technology 645
tendency of the fabric to bend under its own root of the product of warp and filling values
weight. It is simply measured by sliding a strip [5].
of the fabric over the edge of a horizontal sur-
face until gravity causes the strip to bend to a (19.20)
prescribed angle. "Flexural rigidity" is the
fabric's resistance to bending. It is the resistance where
that is evidenced when the fabric is bent back
and forth between the fingers. Fabric stiffness is Go = overall flexural rigidity
a function of both the intrinsic stiffness of the Gw = warp flexural rigidity
fibers and the geometry of the yarn and fabric G1 = filling flexural rigidity
structure. Two fabrics of different weights can
have the same bending lengths because of their
intrinsic and geometrical differences, but the 22. DRAPE AND HAND
heavier of the t\\0 will exert a greater resistance
to bending and therefore will feel stiffer. Flex- For industrial textiles neither fabric "drape"
ural rigidity takes into account the fabric nor "hand" are normally important. Drape is
weight. generally considered to be a visual rather than
The mathematics of the bending length test tactile property observed as the tendency of the
have been worked out so that the length of over- fabric to bend under its own weight into pleas-
hanging fabric that subtends an arc of 41.5° ing "folds:' Both warp and filling bending
from the horizontal is twice the bending length lengths and their interactions will influence
(Figure 19.11). Flexural rigidity G is calculated drape. Hand or "handle" is a tactile property
according to the formula most often described by subjective reaction
rather than objective physical measurement.
(19.19) The Kawabata testing system has become popu-
lar in recent years in evaluating the hand prop-
where erties of fabrics.
~----------------L--------------~
are so thick that major permanent creases usu- creased, the fibers in the yarns and the yarns in
ally do not develop. However, lighter-weight the fabric have insufficient space to enable them
goods may present more difficulty. If a fabric to move and slide relative to each other. Instead,
composed of continuous filament parallel yams the fibers become permanently strained or elon-
is creased so that the angle of bend approaches gated beyond their yield points, consequently
180°, the fibers on the inner side of the bend are impairing the fabric's wrinkle recovery ability.
placed in compression and those on the outer Loosely woven fubrics allow more fiber redis-
side are placed in tension. There is a neutral tribution and motion during creasing, and so
plane where theoretically one fiber is neither less intrinsic fiber strain develops. However, the
compressed nor strained. If the intrinsic proper- geometric movement of fibers in yarns and
ties of the fibers, and the geometry of the yarn yarns in fabric may be large, with no inherent
and fabric system are such that non-recoverable ability for the fabric to recover, and so any
deformations result from the creasing action, a wrinkle which does develop may be more per-
permanent crease will result. This can stem manent.
from two mechanisms. First, the outer fibers For a given creasing force, a stiffer fabric will
may be strained and the inner fibers compressed become creased to a lesser degree than a more
beyond their respective yield points, thus pro- flexible one. The resulting total strain will be
ducing an objectionable crease which is called a less, and the amount of fabric creasing will be
wrinkle. Most often it is the tensional strain less. The crease recovery will depend upon the
which is non-recoverable. Second, fibers in the ability of the fibers and yams to return to their
yarn or yams in the fabric may slide by each original configuration. Thicker fubrics are gen-
other as the result of the creasing force, but erally stiffer than thin ones, and any crease
there is no restoring force which causes them to which is imparted to the thicker ones is usually
return to their original configuration. less permanent. For example, a crease in a
Fibers with high extensibility coupled with tightly woven worsted fabric is more durable
high instantaneous elastic recovery and primary and permanent than an identical crease in a
creep usually exhibit good-to-excellent wrinkle woolen fabric.
resistance. Fibers where high secondary creep At equal degrees of creasing, a thicker fabric
occurs at low load and strain levels have poor is more irrevocably deformed than a thin one,
wrinkle resistance. Low elongation fibers such and a more permanent crease results. However,
as glass or linen have poor wrinkle resistance, it is usually more difficult to produce equal
since their yield points are quickly reached degrees of creasing in a thick fabric, and this is
under the bending strain, and they cannot re- why thin fabrics appear to be more easily wrin-
cover. In the case of glass fiber the creasing ac- kled.
tion often causes a strain in excess of the break-
ing elongation of the fiber, and so fiber failure
occurs. The temperature and relative humidity 24. BLENDED AND
of the air, as it influences the thermal or mois- COMBINATION FABRICS
ture sensitivity of the fiber, will also influence
wrinkle resistance. Moisture sensitive fibers, In a strict sense, fabrics composed of more
particularly the rayons, have high wet secondary than one fiber are called blended fiber fabrics.
creep and this contributes to their poor wet Several types are common:
wrinkle resistance. Crosslinked rayons with
improved wet load elongation properties, and (1) Fabrics in which the spun yarns are com-
rayons resin-fmished with "wrinkle resisting" posed of two or more types of staple fiber
finishes, exhibit better strain recovery proper- intimately mixed together, for example, a
ties and better wrinkle resistance. "Wash and cotton-nylon blend. These are often called
wear" fabrics must have wet as well as dry intimate blend fabrics.
wrinkle resistance and crease recovery. (2) Combination yarn fabrics which contain
Tightly woven fabrics generally will re- plied yarns composed of two or more types
strict fiber movement. When such fabrics are of single yarns of different compositions.
19.1 Fabric Propenies and Technology 647
·-•
0..
>-
1-
a:
I.&J
0..
0
a:
0..
Examples are a rayon/nylon filament yarn, its contribution on a direct percentage basis.
or spun and filament nylon yarns twisted This rarely happens, and the full curved line
together, or a glass core yarn wrapped with shows the kind of relationship that may develop.
a cotton yarn cover. For example, when small amounts of a strong
(3) Combination fabrics composed of two or low-extension fiber are added to large amounts
more types of yarns of different fiber com- of a weaker high-extension fiber an initial re-
positions, for example, a cotton warp and a duction in yarn strength can develop so that the
nylon filling blended yarn is actually weaker. This phenome-
non is again explained by differences in break-
The objective of manufacturing a blend may ing elongation of the two fibers, i.e., elongation
stem from the utilization of a cheaper fiber as a balance. The two fibers do not add the full com-
diluent with a more expensive fiber or more ponents of their respective strengths when the
properly, the attainment of certain yarn proper- less extensible one fails. Therefore the maxi-
ties via the unique contribution that each com- mum strength theoretically attainable is not
ponent fiber gives to the blend. achieved.
It is well to consider, however, the influence In order to achieve the optimal blend at the
of blend composition on yarn properties. Yarn most economical cost it is necessary that the
strength and other properties do not necessarily property versus percentage composition curve
follow a linear relationship with blend propor- be properly established. This may be done via
tion. Figure 19.12 is a hypothetical graph that theoretical calculation but usually experimental
plots percent blend of a two-component mixture means are employed. Often two or more prop-
versus a selected property P. erties must be considered here, and obviously
The dotted line plots the linear relationship the selection of an optimum blend becomes
that would exist if each component fiber made more complicated.
19.2
References and Review Questions
648
20.0
TEXTILE TESTING
20.1
Textile Testing
S. ADANUR
L. B. SLATEN
D. M. HALL
fineness/coarseness among others. The poly- when they are wet, while most other fiber gen-
ester could vary in diameter (denier), cross- era will be weaker in strength. Thus, if the
sectional shape, excessive surface roughness moisture content of all fabrics was not precisely
due to the presence of oligomers (unreacted fixed in the standard testing procedures, then
monomers), fiber crimp variations, etc. Thus, the results could vary depending upon each
any yarn made from such fibers could be of laboratory or plant's test conditions. For this
poorer quality. Even if the fibers and blend con- reason virtually all physical tests done on textile
tent were perfect, quality defects in the yarn goods are done at the standard conditions of
such as thick/thin places, neps, twist variations, 70°F and 65% relative humidity (RH). Other
weight (count) or other yarn construction varia- variables such as time, reagent concentrations,
tions would again adversely impact the quality speeds, number of cycles, number of tests, test
of the final product. Further, the yarn produced apparatus employed, etc., will be precisely
will ultimately be constructed into a fabric fixed for each test so that the test will be both
(woven, knitted, nonwoven, braided, laminated, accurate and reproducible from one laboratory
bonded, etc.) where other variables such as to another. In this way the results of the tests
thread count variations, fabrication problems will be the same regardless of what laboratory
(machine abrasion, barre) could occur that performs the test.
would produce a variable product. The final A great deal of time and effort is put into the
fabric will often need to be finished in order to test standardization. There are two major or-
remove size (if the fabric is woven) or scoured ganizations which write standard tests for tex-
to remove lubricants (if knitted). The fabric may tiles. The American Society for Testing and
be mercerized, sanforized, singed, heat set, Materials (ASTM) writes standard tests not
among others, any of which will need to be only for textiles but also for virtually every
done properly in order to provide the proper other product such as steel, plastics, lumber,
end-use performance expected by the customer. etc. [1]. The society has over 135 technical com-
Thus, a quality failure in anything from one of mittees and over 2,000 subcommittees staffed
the subassemblies to the final fabric form could with over 20,000 technical experts drawn from
result in the entire product being classified as producers, users, general interest universities
being a poor quality product. For this reason and consumer participants. There are presently
testing of each component at each stage of the over forty volumes of standard texts written by
manufacturing process is required in order to this organization. Just the textile tests alone re-
arrive at a high quality product, containing zero quire two of these volumes. For textiles, ASTM
defects. writes primarily physical type tests such as
methods for testing the tensile strength, abra-
sion resistance, twist determination, fiber
2. STANDARD TEST METHODS AND maturity, denier and yarn count among many
STANDARDS ORGANIZATIONS others. Each test method will have a committee
or subcommittee of experts on that subject
Any testing which is to be done on a product drawn from academia, industry users, general
will need to be done by employing standard test interest personnel, consumer and government
methods. In this way, every possible variable participants that will meet periodically to
within the test method will be precisely con- review the standard test to determine if any
trolled. The reason for this is that reproducibil- research, technique, method or system may
ity must be absolutely assured. That is, the test have been developed and published which could
results in a plant or laboratory will need to be make the test method either more accurate or
the same as those obtained within the cus- reproducible. It is not unusual for a test method
tomer's laboratory; otherwise, lawsuits would to require developments by a consortia of re-
abound. For example, it is a known fact that search committees through extensive investiga-
goods containing 100% cotton will be stronger tions and inter-laboratory comparisons, often
20.1 Textile Testing 653
requmng years of work to finalize the test procedures or tests and develop one employing
method. Each standard test will be reviewed at their own test methodology to meet very spe-
least once every five years (yearly for the first cific requirements. For example, a nylon fishing
three years when first introduced) to determine line breaking at ten pounds when tested under
that the test is still the state of the art in method- standard conditions of 65% RH and 70°F will
ology, consistency, accuracy and reproducibility. be weaker when used under actual conditions in
Another organization which writes standard the wet state (nylon loses about 10% strength
tests for textiles is the American Association of when wet). Thus, the buyer may wish to have
Textile Chemists and Colorists (AATCC) [2]. the fishing line tested under conditions that will
This organization works very closely with more accurately reflect the end-use require-
ASTM but writes chemical type tests. There- ments of the textile item. In such cases, the
fore, the two organizations are complementary buyer and seller may agree on different testing
and not in direct competition with each other. procedures to meet their own requirements.
Thus, tests that deal with fastness properties Many professional organizations (e.g., INDA,
(light, laundering, color, perspiration, chlorine, TAPPI, American Filtration Society) and large
etc.) for example, will be written by this or- industrial corporations of the United States who
ganization. purchase large quantities of all sorts of materi-
In some cases standard tests written by both als and end items have established their own test
organizations will need to be run to determine methods and standards. The electrical, rubber,
the whole quality story. For example, the test automotive, abrasive, and plastic laminating in-
method that deals with fastness to chlorine dustries as well as many department store
bleach (a chemical reaction and thus a chemical chains have established their own test methods
type phenomena) will be written by AATCC. and standards in order to insure uniformity of
One of the properties required to be evaluated in product and the attainment of proper quality.
the AATCC test method is the strength of the Using one of the above types of standard tests
fabric before and after the chlorine treatment. will generally be the only ones that will ever be
The strength measurements would be done by employed by most textile mills. There is, how-
the appropriate ASTM standard test method ever, a significant amount of effort toward stan-
which would be referenced within the AATCC dardizing tests worldwide. The United States
test method. Thus, each organization does not and most of the industrialized nations of the
try to reinvent the wheel when there is already world have a continuing program that attempts
a recognized standard test method in existence. to standardize textile testing so that one single
Another organization having requirements for standard test for each specific subject (abrasion,
specific tests methods is the U.S. military [3]. strength, perspiration, etc.) can be employed
The U.S. Army has the primary responsibility worldwide. Thus, textile products that are im-
for the procurement and testing of several thou- ported or exported can employ standard test
sand different textile items used by the various methods under conditions that will be univer-
military organizations. The specific end-use re- sally accepted worldwide. The international or-
quirements for military textiles may be radically ganization under whose umbrella the various
different than those that are used in the civilian standardization efforts are being negotiated is
sector. Thus, the military establishment will the International Organization for Standardiza-
write and publish their own test methods which tion (ISO). For the negotiations, the United
will cater to the specific quality needs of that States has established national tests under the
military item. In most cases, the test method American National Standards Institute (ANSI).
will follow the equivalent ASTM or AATCC Thus, most of the AATCC and ASTM standards
test method quite closely but deviate when spe- have been adopted as the ANSI standards which
cific military needs dictate. form the basis for negotiations with the other
There may be times when the buyer and seller countries.
may wish to deviate from published standard Current federal policy states that where na-
654 TEXTILE TESTING
tiona! consensus standard test methods exist, also cause differences in processing and in yarn
these standards will be incorporated in Federal and fabric mechanical properties. Therefore, it
Standard Method 191A. This is an ongoing pro- is equally proper to test these materials under
cess and will gradually shift the responsibility constant temperature and humidity conditions.
for updating standard methods to the various na- By general agreement, "standard conditions" for
tional consensus organizations. the U.S. textile industry are defined as 65% ±
2% relative humidity (RH) and 70 o ± 2 °F.
Evaluation Procedures When testing a textile material, it should be
placed in a conditioning room under these con-
Most standard tests will give specific infor- ditions for several hours before testing. The
mation such as the actual breaking strength, length of time required for the textile to attain
number of abrasion cycles to failure, the num- moisture equilibrium in the conditioning room
ber of S or Z twist/inch, etc. Other tests will will depend upon its preconditioned regain, and
give a rating between 1 (very poor)-5 (ex- its "state of aggregation"; that is, the distribution
cellent). For example, when rating the crock and position of fibers in the yarns, and yarns in
fastness (fastness to rubbing of a dyed fabric) of the fabric.
a sample, the international gray scale is used to Densely packed materials originally at very
access the amount of color that is transferred to low or very high moisture regain may require
a white test swatch. In this manner the amount several hours, or even days, to come to true
of color transferred can be evaluated on the 1-5 moisture equilibrium at standard conditions.
scale. It is possible to have a rating between one Thin, lightweight, lofty textiles can be condi-
of these numbers. Using the gray scale a num- tioned in a few hours or even minutes. Figure
ber of 3.5 could be obtained. This would imply 17.16 shows that moisture absorption-desorption
that the rating was not as good as a 4.0 but not curves do not follow the same regain path, a
as bad as a 3.0, and that the rater felt that the hysteresis area existing. Therefore, the final
color transferred was about halfway between the moisture regain equilibrium which a material
two rating numbers. assumes when conditioned from the dry side
One should be aware that all the testing proce- usually is different from that which will result
dure will do is to supply an actual property by conditioning from the wet side. While for
value or a rating number. The number itself will most tests this difference will not be great and is
not necessarily tell if the customer will be satis- usually ignored, it can influence physical prop-
fied with the rating once the fabric is put into erties. Therefore, for meticulous work, or in the
use. event of a dispute, it is necessary to establish
whether the material is to be conditioned from
the dry or the wet side prior to testing.
3. ENVIRONMENTAL The ASTM states that moisture equilibrium
TEST CONDITIONS shall be approached from the dry side, but not
from a moisture-free condition. It is an exact-
Many textile materials are sensitive to tem- ing task to maintain a conditioning room at the
perature and relative humidity. When testing proper humidity and temperature level of
them, it is necessary that the environment be 65% ± 2% RH and 70° ± zoF. Humidistats
stipulated and held constant. When all of our and thermostats that record and control are
fibers were natural or of a regenerated animal or available to accomplish these standards. The
cellulose base, it was mandatory that relative ASTM manual contains a psychometric chart so
humidity and temperature be controlled, and that relative humidity can be calculated from
fabrics had to be brought to equilibrium in a wet and dry bulb thermometer temperatures.
standard atmosphere or "conditioned" before There are many test chambers on the market
testing. Synthetic hydrophobic fibers are not to aid in the testing of properties under specified
sensitive to moisture, and yet the surface mois- conditions of high or low relative humidities and
ture characteristics of some of these fibers can temperatures. It is often desirable to determine
20.1 Textile Testing 655
the strength-elongation properties of textiles The larger the number of tests and the lower
under such conditions. Table 20.1 lists several the variability of the results, the nearer will the
ASTM standard methods relating to environ- mean of the test results be likely to come to the
mental conditions and moisture. These methods true average. Precision is the difference be-
are guidelines for specific uses. Other guide- tween the mean of the test results and the true
average, which is unlikely to be exceeded. Pre-
lines may be different for other related products
cision can be expressed in percent (equation
such as plastics, glass fiber items, etc.
20.1) or in units of the property under test
(equation 20.2).
As an example, if a precision of ± 4% at a
4. SAMPLING AND QUALITY CONTROL probability level of 95% is specified, then
there is a 95% probability that the mean of the
The importance of properly selecting fibers, test results lies within ±4% of the true aver-
yarns or fabrics for quality control or specifica- age of the property under test. Note that the
tion testing cannot be overemphasized, if the expression "true average" is used here to sig-
time, effort, and money expended for physical nify the overall average of an infinite number
or chemical testing is to be worthwhile. In the of tests performed by the test method in use.
The general formula for number of tests are:
mill, the sampling of the product from each
machine must be done in a statistically sound
manner so that the samples taken are truly repre- (20.1)
sentative of production. Obviously, the greater
the number of samples tested, the more nearly
the resulting average will represent the true av- (20.2)
erage of the entire lot, but this increases the
amount of work and cost. Therefore, it becomes
necessary to establish the statistical probability where
one is willing to accept so that the values ob-
tained on the samples tested in fact represent the n = number of test specimens
entire lot. E% = desired precision of the mean of the
The ASTM states that test results expressed as a percentage
E = desired precision of the mean of the
the number of test specimens depends on the test results expressed in units of the
desired precision and the desired probability property under test
level, both of which can be selected at will. It P = coefficient of variation of individual
depends also on the variability of individual test results, determined from exten-
test results; this is a property of the test sive past records on similar material
method and of the material which is being (in %)
tested and must be determined experimentally. u = standard deviation of individual test
When a certain number of tests are performed, results, determined from extensive
the mean of the test results forms an estimate past records on similar material (in
of the true average of the property under test. units of property under test)
656 TEXTILE TESTING
t = constant depending on the probability cellent books are available on statistics and
level: quality control.
A list of selected standard test method and
Probability Level guidelines for sampling are given in Thble 20.2.
90% 1.645 This chapter gives information and discusses
95% 1.960 the significance of the multitude of physical and
chemical test methods and instrumentation for
For other probability levels, the values of t to fibers, yarns and fabrics which are available to
be used in the above formulas can be found in the textile scientist. ASTM D 123 (Standard
statistical tables. Terminology Relating to Textiles) gives the defi-
One of the most important rules in the selec- nitions of textile terms.
tion of test samples is the use of common sense.
If five specimens are to be selected for warp
breaking strength, it is logical to cut them so 5. FIBER TESTING
that there are entirely different warp and filling
yams in each specimen. If there is insufficient Fiber analysis includes identification, physi-
fabric to make such a completely random selec- cal properties, quality of natural fibers as well
tion, then the next most reasonable selection is as other characteristics. A selection of relevant
to cut the five specimens with different warp standard test methods is listed in Table 20.3.
yarns but with the same filling yarns. In addi-
tion to the mathematical and statistical require- 5.1 Fiber Identification
ments, an understanding of the reason for con-
ducting the test and carefully planning the Identification systems are based upon differ-
utilization of the test data will be most helpful. ences in optical, physical, and chemical proper-
As another example of proper sampling, con- ties of fibers. The following criteria can be
sider the evaluation in the laboratory of the tear employed qualitatively or, if necessary, quanti-
strength of a fabric before and after resin finish- tatively: longitudinal and surface characteris-
ing to establish whether the treatment has tics; cross section shape; specific gravity;
caused a deleterious effect. Here it is proper to refractive index; polarized light characteristics
mark out the fabric specimen pattern so that one including birefringence; melting point; mois-
piece of the fabric is treated and the adjacent ture regain; swelling and solubility characteris-
piece is retained as an untreated control. Then tics in water, organic solvents, or other chemi-
when the samples are cut for testing, the same cals; burning characteristics; dyeing and
yarns in each piece will be tested so that a direct staining characteristics; ultraviolet and infrared
comparison of the effect of the treatment will be spectra; and X-ray diagrams. Several of these
established. tests are normally employed in order to make
The proper employment of statistics for qual- the identification certain.
ity control and research is of great value. It is a ASTM Method D 7:16 gives detailed proce-
comprehensive subject unto itself. Several ex- dures for identifying the following textile fibers:
acetate (secondary), acrylic, anidex, aramid, determine the percent fiber compositiOn in a
asbestos, cotton, cuprammonium rayon, flax, yarn or fabric. All methods of fiber analyses are
fluorocarbon, glass, hemp, jute, modacrylic, based upon the premise that the fiber types in
novoloid, nylon, nytril, olefin, polycarbonate, the mixture to be analyzed are already known by
polyester, ramie, rayon (viscose), saran, silk, previous qualitative analysis techniques. The
spandex, triacetate, vinal, vinyon, and wool. design of a particular scheme for separation
must be based upon this knowledge. The
5.2 Quantitative Analyses of scheme should be as simple as possible.
Fiber Composition The ASTM and AATCC have a jointly ap-
proved test procedure where the test methods
Several quantitative test methods are used to are grouped under three headings:
658 TEXTILE TESTING
(1) Mechanical Separation or Dissection croscopes are of inestimable help in the identifi-
(2) Chemical Analysis cation and examination of fibers, the study of
(3) Microscopic Analysis fabric defects and the effect of chemical or resin
treatments on textile fibers and yarns. There are
The methods are intended primarily for the several excellent standard books on textile mi-
separation of binary mixtures, but by intelligent croscopy, as well as several texts on general
selection of the best combination of methods, microscopy, techniques and equipment involved.
multi-fiber mixtures can be analyzed. Fiber The lower power stereoscopic microscope,
composition is generally expressed either on the producing magnifications of about 6 to 60
oven-dry weight of the textile "as received" or times, permits the observer to use both eyes to
on the oven-dry weight of the clean fiber after see yarn or fabric structures in three dimen-
non-fibrous materials, such as finishes, are sions, that is, depth as well as length and width.
removed. In making quantitative separations, it An important point often overlooked is that
is vital that fiber weights are precisely much information can be obtained by the use of
measured. Analytical balances of proper sen- relatively low magnification instruments. The
sitivity are useful and often mandatory, depend- lower the magnification, the greater is the "field
ing upon the original size of sample and the of view;' i.e., the diameter of the circle viewed
weight of fiber remaining after a component has through the stereoscopic microscope. For exam-
been removed mechanically or by dissolution. ple, a warp streak may be very apparent to the
The reader is urged to examine ASTM Method naked eye when the fabric is viewed from a dis-
D 629 or AA1CC Methods 20-1990 and 20A- tance. Under excessive magnification, the
1989 for comprehensive information on test defect may disappear because one cannot ob-
details. serve a sufficient amount of acceptable fabric
If two or more components can easily be sep- adjacent to the defective streak to establish dif-
arated by raveling, for example a nylon warp ferences.
and a cotton filling, the easiest way to ascertain The compound microscope consists of a com-
percentage composition is to separate the fibers bination of a magnifying "objective;' an "ocular"
or yarns mechanically and weigh each group. and a "condenser." The latter gathers and
Plied or cored yarns composed of two different focuses the light so materials can be examined
fibers can also be handled in this fashion. in detail at magnifications ranging from about
Chemical separation of fibers normally consists 100 to 800 times. For fiber studies including
of selecting a solvent in which one constituent is identification, surface structure, damage, and
completely and easily soluble and the other con- the deposition of resins, pigments and dyestuffs,
stituent is completely insoluble. Thbles 17.12 the compound microscope is a valuable tool.
and 20.4 are particularly useful for selecting Generally, it is useless, as well as improper, to
proper solvents. Table 20.5lists keys to methods attempt to examine large yarns or fabrics with a
for the separation and determination of fiber compound microscope with even the lowest
content. order of magnification. The field of view is so
small, and the depth of focus so critical that
5.3 Stereoscopic, Compound, and only a tiny area of the yarn or fabric can be
Polarizing Microscopes viewed, with only a part of this in focus. It is
also important to point out that the objective
As an aid in observing the fine structure and lens of the microscope has the capability of "re-
character of fibers, as well as for examining solving" small distances, and thus completely
yarns and fabrics, a range of microscopes is controls the ability of the microscope to sepa-
available to the textile scientist. These instru- rate structural detail. The ocular magnifies
ments, in some ways, are unique for textile ap- what the objective sees. Usually, it does no
plications, but most of them were developed by good to employ high ocular magnification,
microscopists with broad interests in all types of without the proper previous resolution. "Empty
natural and synthetic materials. The various mi- magnification;• as it is called, gives no greater
TABLE 20.4 Solubilities of Fibers in Solvents Used in Chemical Methods (ASTM D 629). 8
Method No.: (1) (2) (3) and (9) (4) (5) (6) (7) (8) (10)
Butyrolactone
90% 59.5% 70% NaOCI Cuprammonia Hot N,N-dimethyl
80% Acetone (A) RT (B) 75°C Formic Acid H2S04 H2S04 Solution Solution Xylene acetamide
Acetate s s PS s s s
Triacetate I PS PS s I I I ... s
Acrylic I s s I I I I I I s
Aramid
Cellulosic, natural I I I I ss s I s
Modacrylic I s s
Nylon I I I s s s I I I
Olefin I I I I I I I I s
Polyester I I I I I I
Rayon I I I I s s I s I I
Silk I I I PS s s s ... . .. s
Spandex ... I I PS I I I ... . .. s
Wool and hair fibers I I I I I Ib s
•Key to symbols:
S = soluble
PS = partially soluble
SS = slightly soluble (a correction factor may be applied)
I = insoluble
bReworked wools are soluble in 70% H2S04 depending upon their previous history.
ffi
<0
m
~
TABLE 20.5 Chemical Methods for Analysis of Fiber Mixtures (ASTM 0 629).
Wool Spandex Silk Rayon Polyester Olefin Nylon Modacrylic Cellulosic, Natural Aramid Acrylic Triacetate
Acetate 1 1 1 1 1 1 1 1 1
Triacetate 3 (5) (75)b 9 39 (5) 9 (5) 3
Acrylic (6) (6) (75) 10 (8) 10 10 (57)
Aramid (6)
Cellulosic, natural (6)5 (10) (6) (4) 5 5 (3) (2)
Modacrylic 2 2 2 2 2 2 2
Nylon 3 (10) (6) 3 9 (8)
Olefin (6) (6) (75) 8
Polyester (6) (10) (6) (7)
Rayon 5 (6)
Silk 6
Spandex (6)
clarity of detail, and would be analogous to fiber's orientation, and its birefringence. The
placing a magnifying lens in front of a television polarizing microscope is also used to determine
screen to make the picture bigger. This adds the degree of cotton maturity.
nothing to the clarity of the picture nor to the Projection microscopes are useful for project-
ability of the observer to see finer detail. ing images onto screens for large scale viewing
By means of precise optical and mechanical or for easy quantitative measurement. In some
attachments, the compound microscope can be systems, the microscope, camera, computer,
used for making quantitative measurements monitor, video recorder and printer are all con-
such as fiber length, diameter, coating thick- nected. The picture can be viewed on the moni-
ness, cross section area, etc. Micrometer scales tor, stored on the computer disk, recorded on
placed on the stage and in the eye piece (ocular) the videotape or printed instantly (Figure 20.1).
of the microscope are calibrated and then used A wide range of photographic equipment has
for quantitative measurements. Glass slide hold- been developed for photographing specimens
ers with precise screw threads permit a speci- under the microscope. Such photos are properly
men to be moved a fixed distance east-to-west or called photomicrographs and can be taken in
north-to-south on the horizontal stage. A circu- color, often with polarized light. Other instru-
lar specimen stage marked with the degrees of ments useful in microscopy laboratories are tex-
rotation may be used to measure twist angles in tile specimen cross-sectioning devices or micro-
fine yarns or to make quantitative measure- tomes. Properly prepared cross sections are
ments under polarized light. useful for studying internal structure.
A polarizing lens converts ordinary light Fiber optic technologies developed for the
vibrating in many planes into polarized light computer and communications industries have
which vibrates in one plane. When viewed in been applied to imaging systems. Remote video
such light by a second polarizing lens the op- microscopic systems are available (Figure
tical rotation exhibited by a specimen is useful 20.2). These systems can provide continuous
to characterize molecular order, for example, a viewing at magnifications greater than x 1,000.
FIGURE 20.1 A modem vision system including microscope, computer, monitor and video recorder lor liber, yarn
and fabric analysis (courtesy of TexTest).
en
en
1\)
Lens
lllh--J Lens
LUJ}- X 1----,
r::j:r::=J X 5 Probe
PC forfmage
Qii:=J
I~ I
X 10 Anafysis/Proces. g
CJ dlr=:J I
Video Printer
([] dtr=J
0 dlc=J
0 C[Jr::::J
0 <[]JC_~ Main Unit
l¥tillc::3l
VCR
[CJ
CRT Monitor
0 <CilL=J j ajS .t¥ .. Ji!1i
-<=.} Still Video Recorder
FIGURE 20.2 Remote video microscope system and its schematic (courtesy of Lawson-Hemphill Sales, Inc.).
20.1 Textile Testing 663
Interfacing with computer accessories allows and denier of an individual filament, the prob-
for image storage, analysis and printing. lem becomes greatly expanded. In determining
the tenacity-elongation properties of individual
5.4 Scanning Electron Microscopy filaments, because of large or even minute vari-
ations in fiber diameter and weight, it is neces-
The scanning electron microscope (SEM) sary to establish the denier or tex of each individ-
consists of two major parts. An electronics con- ual breaking strength test specimen. Each fiber's
sole provides the necessary photography. The strength is then related to its own weight, and a
other section of the apparatus contains the elec- precise tenacity (grams breaking strength per
tron column where an electron gun generates an tex or denier) is obtained.
electron beam that is focused on a small spot.
This small spot is where specimens are placed. The Vibrascope
The spot is scanned with the electron beam and
secondary electrons generated in the specimen One method for determining denier is by mea-
provide the signal, which is viewed on the suring the fiber's average cross-sectional area.
screen. The electron beam is generated from a Then, knowing its specific gravity, the weight
metal filament and accelerated down an evacu- per unit length can be calculated. This is a time-
ated column. The vacuum is necessary since consuming task, requiring meticulous micro-
electrons cannot travel very far in air. scopical measurements of fiber cross sections.
The specimens must be conductive, so for A more rapid method is based upon the princi-
most textile or polymeric materials they are ple that the weight per unit length of a com-
coated in a vacuum with a conductive substance pletely flexible string can be calculated from its
such as gold-palladium or carbon. This tech- lateral frequency vibration characteristics, its
nique allows the observation and photographing length, and the applied tension. The basis of the
of material surfaces. Photographs of fiber sur- calculation is the well-known physical law that,
faces at different magnifications allow one to when a flexible string is vibrated transversely,
view the external makeup of the fibers, and in its resonant frequency is a known function of
some cases, can be used for identification of the tension, the length and the mass per unit
fiber type or to look at changes in fiber surfaces length.
due to external events. The advantage of SEM is Linear density or weight per unit length m is
the large depth of field at high magnification. calculated as follows:
The analysis of secondary X-rays excited by the
primary electron beam allows the qualitative T
m --- (20.3)
analysis of elements and their distribution in the 4[2!}
specimen.
where
5.5 Fiber Denier or Tex
m = linear density in grams per centimeter
Many of the tests on individual fibers are dif- T = fiber tension in dynes
ficult to execute because of a fiber's size and the l = effective fiber length in centimeters
extreme care needed in its manipulation. In cal- ji = fundamental resonant frequency in cycles
culating the yarn number it is relatively simple per second
to wind off a skein of yarn, weigh on a properly
sensitive balance, and determine the weight per The instrument, called a vibrascope, deter-
length. Even the somewhat more meticulous mines quickly and accurately the denier of in-
task of marking out specific lengths of yarns and dividual fibers 2 to 4 centimeters in length. The
weighing them on an analytical balance is not technique consists of holding a fiber in one end,
overly difficult. Today analytical balances with dead loading it with a small freely hanging
seven decimal places are available. However, weight, and clipping the other end of the fiber in
when it is necessary to determine the weight a jaw connected to a source of sinusoidally
664 TEXTILE TESTING
alternating energy. The fiber is then caused to tensioning weight. The fineness is then calcu-
vibrate transversely setting up fundamentals or lated. Assuming a uniform mass distribution
harmonics of vibrational nodes. A variable and a circular cross section, and disregarding
oscillator is used to adjust the frequency so the the influence of the bending rigidity (elastic
harmonic nodes are established. Knowing the modulus), the following formula is valid:
frequency, the length, and the tension, the
denier can be calculated. The new vibrascopes (20.4)
are completely automatic with respect to their
operation.
where
to remove short fibers and make the remaining removed and weighed. The breaking tenacity is
long ones completely parallel. A bundle of in- calculated as follows:
dividual fibers about 1/4-inch wide results. This
is inserted between two clamps, of either zero Breaking Tenacity (grams/tex)
or 1/8-inch gauge length. A knife cuts off the
fibers protruding from the outer sides of the 5.36 X lbs. breaking load
clamps. The clamp and fiber assembly is in- = bundle weight in mg.
(20.5)
serted in the Pressley Tester, an instrument
based upon the application of a force generated Tensile Strength (psi in thousands)
by a carriage rolling down an inclined plane. As
the carriage rolls down the plane a lever arm ex- 10.81 x lbs. breaking load
erts a progressively increasing load on the = (20.6)
bundle weight in mg. - 0.12
fibers until rupture occurs, at which time the
carriage stops automatically, and the breaking Note: Tenacity, grams per tex = (tensile
strength is recorded. The broken fiber bundle is strength, 1,000 psi + 0.12) x 0.4960; tensile
strength, 1,000 psi = (breaking tenacity, grams
per tex x 2.016) - 0.12; tex = denier/9.
Fiber bundle tests are widely used to charac-
terize cotton, but the man-made staple fiber
industry depends largely upon single fiber
strength tests in conjunction with the vibrascope
in order to establish quality.
Cross-Sectional Characteristics
or as the "diameter ratio;' i.e., the ratio of the The Shirley fiber maturity tester uses Micro-
major to the minor axis of the cross section. naire values at two compression loadings to esti-
mate maturity. Near Infra-Red (NIR) analysis is
Caustic Method also used to determine fiber maturity.
The fibers are immersed in cold 18% sodium 5.10 Wool "Grade" or Fiber Fineness
hydroxide which causes them to swell. The
swollen fibers are individually examined under All wool fibers have cross sections which are
the microscope and are considered to be mature round to oval in shape. There is no comparable
if the wall thickness is greater than one-half the property of degree of maturity as there is in cot-
diameter of the lumen. Thus, if the combined ton. However, since a fiber's stiffness is propor-
wall thicknesses are greater than the diameter of tional to the fourth power of its diameter, the
the lumen, the fiber is classed mature. If the mean and distribution of wool fiber diameters
combined wall thicknesses are less than the di- are used to grade wool in terms of its softness
ameter of the lumen, the fiber is classed imma- and luxuriousness. Several hundred very short
ture (ASTM D 1442). lengths of fiber, on the order of about 150
microns long, are cut by a microtome and dis-
Polarized Light Method persed in mineral oil on a microscopic slide. By
means of a projection microscope and cali-
When cotton fibers are longitudinally ex- brated scale, diameters of the fibers are
amined with a polarizing microscope, they ex- measured. From the calculated average and dis-
hibit different "interference" colors which are tribution of micron diameters, the fineness or
largely dependent upon the thickness of the cell grade is established. Specifications for grades
walls. As a result of their different degrees of 36 to 80 are shown in ASTM D 2130 and D 3991.
maturity, the fibers appear in different colors
when observed under polarized light using a 5.11 Wool Fiber Staple Lengths
first order red selenite plate. The fibers are
classified as follows: yellow fibers are fully Wool fiber staple lengths are determined ba-
mature, green fibers are partially mature, and sically in the same manner as for cotton. How-
blue and purple fibers are immature. ever, because the fibers are considerably longer,
different techniques for hand stapling and dif-
Differential Dyeing Method ferent types of combs for quantitative stapling
are required. ASTM D 1575 gives a method for
It has been observed that mature and imma- quantitatively measuring staple length, using
ture fibers will dye differently when treated wool sorting combs. ASTM D 1234 describes a
with specific dyestuffs. Thus, when a test speci- method for removing bundles of fibers from
men of cotton is immersed in a mixture of bags of wool, in the grease, laying the fibers on
Diphenyl Fast Red 5 BL (Supra I) and Chloran- a velvet board, and calculating the mean staple
tine Fast Green BBL, the red dye is retained pri- length from the resulting array.
marily by the thick-walled mature fibers, and
the green dye by the thin-walled immature 5.12 Determination of Moisture Regain
fibers. Thus, the degree of immaturity can be
determined from the dyeing behavior. Of addi- The most direct and obvious way to determine
tional importance, these dyes can be applied to the moisture regain of a textile fiber sample is to
yarns or fabrics to ascertain the amount and uni- weigh accurately a properly sampled amount of
formity of distribution of mature and immature the fiber, then dry it in an oven at a temperature
fibers. Thus, the technique is helpful in deter- above the boiling point of water, cool it in a
mining defects which may stem from fiber non- moisture-free atmosphere, reweigh, and calcu-
uniformity (ASTM D 1464). late the weight loss. This method presumes that
20.1 Textile Testing 669
no materials other than water are volatilized out a stipulated weight of material be placed be-
of the fiber by the drying method. In the event tween the condenser plates in order to obtain
that the product itself cannot withstand the dry- valid calibrated readings. The dielectric con-
ing temperature, usually about 105°C, vacuum stant of most textile and related organic prod-
drying ovens can be employed. Here, at reduced ucts is about five, while that of water is seventy-
pressure, the water will evaporate at a lower eight. Therefore, the dielectric constant method
temperature. For textiles, however, this proce- is applicable for the determination of the water
dure is normally not necessary. content in textiles and similar products.
The nature of the fiber, yarn, or fabric, the All electrical meters must be calibrated em-
size of sample, and the equipment available will pirically against known moisture determina-
all govern the specific techniques selected to de- tions made via standard oven "bone-dry" tech-
termine regain. ASTM D 2654 suggests use of a niques on the actual product being tested. Each
10-gram sample accurately weighed. instrument must be calibrated for the particular
The 10-gram sample is weighed and placed in type of fiber, yarn, or fabric under test. Further-
a previously accurately tarred weighing bottle more, the type of package or "form" which the
or can, equipped with a moisture-tight cover. product has, must be kept constant. Thus, if
With the cover off, the bottle and its contents bulk rayon is to be tested on a dielectric-
are dried in an oven for an hour at 105°C. While constant-type tester, the same approximate sam-
still in the oven, the cover is placed on the bot- ple weight, shape, and bulk density must be
tle, which is then removed and placed in a used. The instrument must be similarly and spe-
moisture-free desiccator containing calcium cifically calibrated for balls of worsted top or
chloride or other drying agent. After cooling, cones of cotton yarn of approximately the same
the cover is loosened for an instant to equalize size, weight and degree-of-tightness of wind.
pressure, is replaced, and the bottle and con- Modern moisture balances automatically de-
tents are reweighed. The procedure is repeated, termine moisture content and dry weight (Fig-
if necessary, until constant weight is obtained. ure 20.6).
The weight loss as a percentage of the bone-dry
weight of the sample is calculated as the mois-
ture regain. The textile industry has developed
special test equipment for determining the re-
gain of textiles.
When cobalt chloride is dissolved in absolute This instrument (Figure 20.8) can be used
(moisture-free) ethyl alcohol, a blue solution is with several different test modules. These
obtained. Upon the addition of water, a pink modules provide the capability to determine the
color results, the reaction being reversible. By following: nep count and nep size, fiber length
quantifying the reaction and using a spectropho- and diameter, number and size of particles and
tometer or other calorimetric method, the foreign matter, dust and trash. A standard test
amount of water in a test sample can be deter- method using this instrument for the determina-
mined. tion of neps is currently being balloted by the
ASTM.
5.15 The Shirley Analyzer
5.18 Blend Testing
The Shirley Analyzer is a machine which sep-
arates lint cotton fiber from non-lint and trash. Many textile mills run blends of fibers such as
Developed by the Shirley Institute in England, polyester/cotton, polyester/rayon, cotton/rayon,
the instrument and method are useful in deter- etc. Most of the blended stock is either a 50/50
mining the yield of spinnable cotton fiber, as or a 65/35 blend. The primary method of testing
well as the efficiency of ginning, opening, blended stock is to dissolve the cotton, or cellu-
cleaning, picking and carding. The cotton sam- lose fibers, in a 70% H2S04 solution. NIR is
ple is opened, and then via air-stream convey- another method of testing for blends.
ance and separation, the clean fibers are depos-
ited on the surface of a cage condenser, while 5.19 Tests for Fiber Damage
the heavier trash and other non-lint material fall
into a pan. Ultimately, the lint fiber is collected The textile scientist has many techniques for
from the condenser and deposited in a delivery determining whether textile fibers have been
box. The weights of lint cotton and non-lint ma- damaged, and the nature of such damage.
terial, respectively, are calculated as percent- Purely physical damage, which may result
ages of the input weight. from tension, abrasion, flexing, or cutting, can
FIGURE 20.7 Uster spinlab HVI 900 f1ber testing instrument.
671
672 TEXTILE TESTING
often be observed via microscopical examina- tion causes the pressing tongue roll to be dis-
tion. The many texts on fiber microscopy give placed upwards or downwards, and this motion
much information on the techniques for detect- is mechanically amplified and continuously
ing abraded or disrupted fiber surfaces, dam- recorded on a chart.
aged animal fiber scales, the presence of split or
"broomed" fibers, etc. The structure and chemi- 6.2 Pacific Evenness Tester for Sliver,
cal composition of the surfaces of many fibers Roving, and Yarn
are different from their inner portions. Often
these surface and inner components will react at This tester works on the same principle as the
different rates and to different degrees when Saco-Lowell sliver tester. Sliver thickness is
treated with dye stains or other chemicals. continuously measured via the displacement of
Chemical microbial, sunlight and weathering a convex pressing roll. However, by means of a
degradation of fibers normally will be mani- magnetic displacement gauge, the roll move-
fested by a reduction in the molecular weight ment is converted to an electrical signal which
and chain length of the polymer. This in turn is continuously recorded on a chart. Mating roll
will produce more chemically reactive "end sets of different groove sizes permits the testing
groups" which often can be qualitatively de- of sliver, roving and yarn.
tected and quantitatively measured. Fiber
degradation can also produce other changes in 6.3 Brush Uniformity Analyzer for
the chemical nature of the fiber which are detect- Sliver, Roving, and Yarn
able by specific chemical reactions. A knowl-
edge of the chemistry of each fiber, whether it This tester works on a capacitor principle. It
be natural or man-made is mandatory in order measures variation in the mass or weight of the
to ascertain the type and extent of fiber dam- product which continuously travels between
age. condenser plates. The capacitance signal is fed
into an electronic recorder.
6. SLIVER, ROVING, AND YARN 6.4 Uster Evenness Tester for Sliver,
EVENNESS TESTS Roving, and Yarn
The manufacture of good quality spun yarns This instrument also works on the electrical
is largely dependent upon uniformity of the capacitance principle (Figure 20.9). Because
sliver and roving-the intermediate forms pro- the shape of the sliver must be kept constant in
duced prior to yarn spinning. Textile mills use order to obtain valid data, a "Rotofil" attachment
several well-known testing instruments for puts false twist into the sliver to maintain a uni-
checking product uniformity. Most are based formly round cross section as it passes through
upon measurement of weight, mass or thickness the tester.
of the materials that pass continuously through
the tester. Many instruments have graphical 6.5 Beta Gauge Uniformity Tester
recorders so that point-to-point variations in
properties are plotted. A method for continuously recording and
controlling point-to-point thickness or weight
6.1 Saco-Lowell Sliver Graphic Tester uniformity of textile laps, slivers, etc., as well
as paper, nonwovens, coatings, and plastic films
The sliver is continuously tested for thickness is based upon the quantitative emission and de-
and mass uniformity by traveling through a pair tection of radioactive energy rays. The instru-
of mated tongue and groove rolls. The lower ment is called a beta <m ray gauge. It consists of
grooved roll carries the sliver, while the upper a {3 particle emitter of radioactive energy, and
tongued roll presses down on the sliver as it an accompanying receiver and recorder. The
moves through the groove. The thickness varia- test material continuously passes between the
20.1 Textile Testing 673
FIGURE 20.9 Uster strand evenness tester (courtesy of Wellington Sears Company).
emitter and receiver and the signal received is 7. YARN TEST METHODS
inversely proportional to the mass of product
passing through the instrument. While the use A selection of standard test methods for yam
of such equipment is scientifically feasible, properties are listed in Table 20.6.
costs have not yet been brought down to the
point where they are being used generally in the 7.1 Determination of Yarn Weight
textile manufacturing industry. or Number
Selection of the tension load is always a prob- An alternate to the skein weight method, use-
lem. A standard method is to use the "load re- ful for heavy ropes or expensive filaments, or
quired to straighten but not stretch the yarn." A where yarn supply is short, is to cut five or ten
suggested procedure is as follows. Cut a 14-inch precisely marked short lengths of yarn (e.g., ten
length of yarn and lay it flat and relaxed on a inches), weigh on a properly sensitive balance,
table. Make two precise ink marks on the yarn and calculate.
exactly ten inches apart. Place the yarn between Some new balances provide the direct read
the jaws of a low capacity, sensitive, constant for yarn count (Figure 20.12).
rate of extension, recording tensile testing
machine, with the jaws exactly ten inches apart.
Separate the jaws of the machine at a slow con- 7. 2 Twist Testers
stant speed, thus plotting an accurate load-
elongation diagram (Figure 20.11). A tangent A twist tester normally consists of two jaws,
line is drawn from the linear low-load portion of one fixed and the other rotatable, about 10
the curve back to zero load (point A). The ex- inches apart into which a selected length of yarn
tension from 0 to A is the crimp or elongation is fastened for untwisting. The rotating jaw has
required to straighten the specimen. Line AB a counter so that the number of turns required to
parallel to the load axis is drawn. The intersec- untwist the yarn can be recorded. The other jaw
tion at point B defines the load required to is usually attached to a pulley tensioning mech-
straighten but not stretch. anism so that a fixed length of yarn under a
FIGURE 20.10 Universal count analyzer (courtesy of James H. Heal & Co.).
2Ql Textile Testing 675
LOAD
0
EXTENSION
FIGURE 20.11 Determination of load required to straighten but not stretch a yarn.
selected tension can be clamped between the completely parallel. The resulting number of
jaws. Figure 20.13 shows a twist tester. turns, when divided by the original length in
The twist in a filament singles, or in a plied inches, gives the turns per inch.
yam or cord, is determined by damping a fixed When twist exists in the singles, ply and cord,
length of the specimen between the jaws of the the untwisting action to achieve parallelism in
tester and untwisting until its components are the largest component will produce a change in
FIGURE 20.12 Digital yarn count balance (courtesy of J. A. King & Company Inc.).
676 TEXTILE TESTING
the twist of the remaining smaller components. in the remaining singles is determined by un-
Ply twisting will insert or remove singles twist, twisting in the usual fashion.
depending upon whether the ply twists and For spun staple yarns it is obviously impossi-
singles twists are in the same or opposite direc- ble to untwist the yam until all fibers are paral-
tions. Similarly, when ply turns per inch are lel, since yam fuilure will occur at one point
removed by untwisting, if the ply and singles while twist still remains at other points in the
twist are in the same direction, the singles will yarn. Instead, an untwist-twist method is used.
become untwisted as the plies are untwisted. If A length of yarn is inserted in the twist tester at
the twist directions are opposite, untwisting the a selected tension. The yarn is then untwisted
ply will add twist to the singles. In either case, and twisted in the opposite direction until the
when the ply is untwisted, the singles will have original length and yarn tension is restored. It is
approximately the same number of turns that it assumed that the same amount of twist has been
had before plying, i.e., the turns inserted during reinserted as was originally present in the yarn.
its manufacture. The turns per inch are calculated, first by divid-
It is often desirable to determine the twist in a ing by two the total number of turns necessary
singles as it lies in the plied yarn. Here it is nec- to untwist and retwist, and then dividing by the
essary to remove all of the singles yarns except original yam length:
the one which is to be tested, while being care-
ful not to disturb its twist. The technique con- T/2 T
sists of clamping the plied yarn in the twist T.P.I. - L = 2L (20.7)
tester in the usual manner. A fine scissors or
knife is used to cut away all of the singles except
where
the one to be tested. Some twist testers have
cluth mechanisms whereby both jaws can be
rotated at the same time and at the same speed, T.P.I. = turns per inch
so that the cut discarded yams can be raveled T = turns required to untwist and retwist
away from the test specimen without altering its L = original yam length
twist. After the extraneous yams have been re-
moved, the clutch is disengaged, and the twist The ASTM points out that the method is only
20.1 Textile Testing 677
an approximation because torsional effects may 8. TENSILE TESTING OF YARNS
cause the fibers to resist retwisting in the oppo- AND FABRICS
site direction after being untwisted, and fiber
slippage may occur during the test. Breaking strength-elongation testing machines
Various devices are available for establishing are useful for determining the load-deformation
and controlling the tension during untwisting characteristics of materials, as well as yarn
and retwisting. In the photoelectric tension con- crimp, energy absorption, tensional modulus, re-
trol instrument, the yam is placed under a fixed peated stress properties, burst and tear strengths.
tension in the twist tester, is untwisted, and re- These testers, when of proper sensitivity, are
twisted in the opposite direction until the origi- also useful in measuring the viscosity and sur-
nal yarn tension is reached, at which point the face tension of liquids, and adhesion properties
twist tester automatically shuts off. The number of laminates.
of turns is thus automatically recorded. Tensile testers operate on one of the following
A commonly used modification of the twist- three principles:
untwist method is the "twist-break" method. In-
(1) Constant rate of traverse
stead of untwisting and retwisting until the
selected original tension is reobtained, addi- (2) Constant rate of specimen loading
tional twist, in the same direction as was used in (3) Constant rate of specimen extension
manufacturing the yarn, is inserted until the The ASTM test methods related to tensile
yarn breaks. A second specimen is untwisted testing include:
and retwisted in the opposite direction until the
yarn breaks again. The difference in twist, • ASTM D 76 Standard Specification for
divided by twice the yarn length, gives the turns Tensile Testing Machines for Textiles
per inch. This is basically the same as the ten- • ASTM D 1578 Breaking Strength of
sion method except that the limiting breaking Yarn in Skein Form
tension is used. It is not as accurate as the ten- • ASTM D 1775 Tension and Elongation
sion method however, since the number of turns of Wide Elastic Fabrics (Constant Rate-
per inch, instead of being solely a function of of-Load-Type Tensile Testing
the yarn's tension, is also a function of the yam's Machine)
breaking strength. • ASTM D 2256 Tensile Properties of
Twist can also be determined optically via a Yarns by the Single-Strand Method
microscope with a rotating stage for measuring • ASTM D 4964 Tension and Elongation
helix angles. Knowing the helix angle and the of Elastic Fabrics (Constant Rate-of-
yarn diameter, the number of turns per inch can Extension-Type Tensile Testing
be calculated from simple mathematics. How- Machine)
ever, this method is more often used as a re- • ASTM D 5034 Breaking Force and
search tool rather than for quality control pur- Elongation of Textile Fabrics (Grab
poses. Test)
• ASTM D 5035 Breaking Force and
7.3 Classification of Yarn Defects Elongation of Textile Fabrics (Strip
Test)
Yarn defects can be classified using a capaci-
tance method. This is a very common test in 8.1 Pendulum Testers
spun yarn mills that is important in checking
yarn quality. This test classifies the defects by In these testers, using heavy pendulums and
change in mass and length. Instruments such as bobs that produce a large mechanical moment,
Keisokki Classifault II or Uster Classimat may loads up to about 2,000 pounds can be applied
be used for this type of test. A standard method to cordage, ropes and fabrics, without the test-
is currently being written by a subcommittee of ing machine itself becoming excessively large
ASTM for this test. or heavy.
678 TEXTILE TESTING
icant help when measuring the properties of ASTM specifies the rate, and more properly,
paper, glass, metals or other materials with low the time to break. For constant rate of traverse
breaking elongations. An "extensometer" or pendulum machines, the specified pulling jaw
strain transducer can also be attached to the speed is 12 ± 0.5 inches per minute. An alter-
specimen to measure elongation. nate suggestion is that the machine be operated
Modern tensile testers provide the capability at such a rate that the yarn will break within
of converting the load cell or transducer re- 20 ± 3 seconds from the start of the test. For a
sponse into a digital output that can then be discussion of tensile testing machines the reader
stored or processed directly using a personal is referred to ASTM D 76.
computer. The various equipment manufactur-
ers can also provide computer software that can 8.4 Determination of
produce reports, plot data and do statistical Breaking Elongation
analyses (Figure 20.16).
For most tensile testing machines, the "elon-
8.3 Testing Speeds gation" axis of the load-elongation recorder
runs at a constant speed so a direct measure of
The rate of loading or extension can influ- jaw separation results. In the case of electronic
ence the ultimate breaking strength. Therefore, constant rate of extension testers, the chart is
driven electrically at a constant speed, and is in- held in each jaw, called jaw penetration, that
dependent of the jaw motion. Usually, it runs at may make the gauge length slightly greater than
the same speed as the pulling jaw, or at a multi- three inches, and the true elongation corre-
ple speed, and so the time axis can be converted spondingly slightly less, but this error is usually
to jaw separation, and ultimately to specimen negligible and is ignored in the calculation.
elongation. When testing thick and heavy cords, tapes,
With flat jaws, the recorded jaw separation braids or webbings, flaw jaws may not be sat-
can be taken as a direct measure of the speci- isfactory. Slippage occurs if the jaws are not
men's elongation. For example, in a raveled tightened sufficiently, while cutting and "jaw
strip tensile test, the gauge length (jaw separa- breaks" result if the jaw is tightened too much.
tion) at the start of the test is three inches. At the To avoid such difficulties capstan jaws are
instant of rupture, if the jaw has moved 0.6 employed. The cord is wound around the cap-
inches, the breaking percent elongation can be stans with about ten inches of yam placed in the
calculated as (0.6/3) x 100 = 20%. There may "free gauge length," that is, the length between
be slight elongation of the ends of the specimen capstan tangent points. During the test, yam
20.1 Textile Testing 681
elongation takes place not only in the free gauge and fixed scale being visible in the field of view.
length, but also progressively around the cap- The pointer traverses the scale, and by means of
stans where the yarn is being snubbed. Thus, the magnifying glass, the number of threads per
the yarn is gradually held and a jaw break is inch or other unit distance can be counted.
avoided. Because the yarn around the capstans Transmitted light through the fabric or incident
is elongating, the jaw separation cannot be used light upon the fabric is usually helpful in count-
as a direct measure of true elongation, and other ing the threads.
means must be utilized. An approximate method A lighting table with top incident illumination
is to place two marks on the yarn in the free or bottom transmitted illumination through a
gauge length. A ruler is placed beside the speci- translucent glass plate is a useful piece of
men. Keeping one mark at zero, the displace- laboratory equipment for such work.
ment of the other mark is noted at the time of There are fabrics of very high sley, those
rupture. This technique only gives the breaking which have been felted, and those where yarns
elongation, and does not permit the plotting of a overlap and are superimposed one upon the other
load-elongation diagram. When used on materi- so as to make direct visual counting impossible.
als with high strength and high elastic recovery, It is necessary to cut a small swatch of such
a danger to the operator exists. Some materials, fabrics; for example, one-half to one inch on a
particularly nylon, stretch a considerable amount side, and to ravel and count the yarns by hand.
with accompanying storage of energy. At the in- Using optical/electronic technology, fabric
stant of rupture, this energy is released with threads per unit length can be measured rapidly
considerable "snapback" of the broken speci- with extreme accuracy and repeatability. Figure
men. The unrestrained movement of the broken 20.17 shows a thread measuring device.
end can act like a whip and break a finger or
arm of the person making the measurement. 9.2 Fabric Weight
Therefore, this technique should be avoided
when working with elastic materials above Fabric weight is determined by weighing the
about 50 pounds breaking strength. complete piece, roll, cut, or bolt, or by select-
An alternate method is to employ calibrated ing and weighing a full width sample, 1/4-yard
telescopes or cathetometers to follow the gauge in length therefrom. The weight per square
marks on the specimen. This is expensive yard, weight per linear yard, or the number of
because two observers are necessary. Movie linear yards per pound may be calculated as fol-
cameras, multi-flash photography and elec- lows:
tronic extensometers are also useful.
Full Piece, Roll, Cut, or Bolt
Selected standard fabric test methods are pre- fabric weight in lbs. x 16 X 36
sented in Table 20.7. This table does not include = ----------=------------------
fabric length in yards X width in inches
company methods or ISO methods. The conver-
sion of many company methods into standard (20.8)
methods is an ongoing process and in the area of
nonwovens many are being processed by the con- Weight per linear yard (ounces)
sensus organizations, particulary the ASTM.
fabric weight in lbs. x 16
= (20.9)
9.1 Threads per Inch fabric length in yards
A "pick counter" or pick glass is a convenient Number of linear yards (per pound)
means of determining the threads per inch in a
fabric. A low-power magnifier is mounted on a fabric length in yards
= (20.10)
traveling screw with a moving reference point fabric weight in pounds
TABLE 20.7 Standard Test Methods Used for Fabric Testing.
ASTM D 434 Resistance to Slippage of Yarns in Woven Fabrics Using a Standard Seam
ASTM D 737 Air Permeability of Textile Fabrics
ASTM D 885 Testing of Tire Cords, Tire Cord Fabrics, and Industrial Filament Yarns Made from Man-Made
Organic-Base Fibers (D 885 M is in metric units)
ASTM D 1117 Testing Nonwoven Fabrics
ASTM D 1230 Test Method for Flammability of Clothing Textiles
ASTM D 1388 Stiffness of Fabrics
ASTMD 1424 Tear Resistance of Woven Fabrics by Falling Pendulum (Elmendorf Apparatus)
ASTM D 1683 Failure in Sewn Seams of Woven Fabrics
ASTM D 1777 Thickness of Textile Materials
ASTM D 1908 Needle-Related Damage due to Sewing in Woven Fabrics
ASTM D 2261 Tearing Strength of Woven Fabrics by the Tongue (Single Rip) Method (CRE Tensile Testing
Machine)
ASTM D 2262 Tearing Strength of Woven Fabrics by the Tongue (Single Rip) Method (CRT Tensile Testing
Machine)
ASTM D 2475 Standard Specification for Wool Felt
ASTM D 2594 Stretch Properties of Knitted Fabrics Having Low Power
ASTM D 2646 Backing Fabrics
ASTM D 3107 Stretch Properties of Fabrics Woven from Stretch Yarns
ASTM D 3511 Pilling Resistance and Other Related Surface Changes of Textile Fabrics; Brush Pilling Tester
Method
ASTM D 3512 Pilling Resistance and Other Related Surface Changes of Textile Fabrics; Random Tumble Pilling
Tester Method
ASTM D 3514 Resistance of Apparel Fabrics to Pilling (Elastomeric Pad Method)
ASTM D 3597 Woven Upholstery Fabrics-Plain, Tufted or Flocked
ASTM D 3773 Length of Woven Fabrics
ASTM D 3774 Width of Woven Fabrics
ASTM D 3775 Fabric Count of Woven Fabric
ASTM D 3776 Mass per Unit Area (Weight) of Woven Fabric
ASTM D 3786 Hydraulic Bursting Strength of Knitted Goods and Nonwoven Fabrics-Diaphragm Bursting
Strength Tester Method
ASTM D 3787 Bursting Strength of Knitted Goods-Constant-Rate-of-Traverse (CRT) Ball Burst Test
ASTM D 3884 Abrasion Resistance of Textile Fabrics (Rotary Platform, Double-Head Method)
ASTM D 3885 Abrasion Resistance of Textile Fabrics (Flexing and Abrasion Method)
ASTMD 3886 Abrasion Resistance of Textile Fabrics (Inflated Diaphragm Method)
ASTM D 3887 Standard Specification for Knitted Fabrics
ASTM D 3936 Delamination Strength of Secondary Backing of Pile Floor Coverings
ASTM D 3940 Bursting Strength (Load) and Elongation of Sewn Seams of Knit or Woven Stretch Textile
Fabrics
ASTM D4032 Stiffness of Fabric by the Circular Bend Procedure
ASTMD4033 Resistance to Yarn Slippage at the Sewn Seam in Upholstery Fabrics (Dynamic Fatigue Method)
ASTMD4034 Resistance to Yarn Slippage at the Sewn Seam in Woven Upholstery Fabrics
ASTM D 4157 Abrasion Resistance of Textile Fabrics (Oscillatory Cylinder Method)
ASTM D 4158 Abrasion Resistance of Textile Fabrics (Uniform Abrasion Method)
ASTM D 4848 Standard Terminology of Force, Deformation and Related Properties of Textiles
ASTM D 4852 Coated and Laminated Fabrics for Architectural Use
ASTM D 4966 Abrasion Resistance of Textile Fabrics (Martindale Abrasion Tester Method)
ASTM D 4970 Pilling Resistance and Other Related Surface Changes of Textile Fabrics (Martindale Pressure
Tester Method)
AATCC 22 Water Repellency: Spray Test
AATCC 35 Water Resistance: Rain Test
AATCC 42 Water Resistance: Impact Penetration Test
AATCC 66 Wrinkle Recovery of Fabrics: Recovery Angle Method
AATCC 70 Water Repellency: Tumble Jar Dynamic Absorption Test
AATCC 76 Electrical Resistivity of Fabrics
AATCC 79 Absorbency of Bleached Textiles
AATCC 93 Abrasion Resistance of Fabrics: Accelerator Method
AATCC 115 Electrostatic Clinging of Fabrics: Fabric-to-Metal Test
AATCC 127 Water Resistance: Hydrostatic Pressure Test
AATCC 136 Bond Strength of Bonded and Laminated Fabrics
682
20.1 Textile Testing 683
684
20.1 Textile Testing 685
Tensile testers are easily converted to com- The most popular air permeability tester is
pressional resilience testers. The load-recording the Frazier type (Figure 20.20). The air flow in
cell is mounted below the lower traveling jaw. cubic feet per minute passing through one
The test specimen is placed on a flat plate at- square foot of fabric under a pressure drop
tached to the cell and is thus compressed as the equal to one-half inch of water is normally
lower jaw moves downward. Plots of load versus measured.
specimen compression, i.e., jaw travel, are The apparatus contains a suction fan for
recorded. drawing air through a known area of fabric that
A sliding cage is also useful for measuring is clamped and sealed in place by a pressure
compressional characteristics. This permits the ring. A rheostat controls the speed of the fan, so
use of tension testers in a conventional fashion. that the pressure drop across the fabric, in-
The sliding yoke arrangement puts the specimen dicated by a manometer, can be precisely con-
in compression as the lower jaw travels down- trolled, usually at a standard 0.5 inches of
ward. water. The resulting volume of air must then be
measured. This is accomplished by utilizing a
calibrated orifice through which all the air that
9. 7 Air Permeability Testers originally passed through the fabric must also
pass. A second manometer measures the pres-
ASTM D TJ7 describes standard test method sure drop across the calibrated orifice, the
for air permeability of textile fabrics. readings being convertible to air flow in cubic
feet per minute per square foot of fabric. A set Spray Test (AATCC 22)
of nine calibrated orifices ranging in diameter
from 1 to 16 millimeters is furnished for inser- A fixed quantity of water is sprayed on a
tion into the tester. They cover a wide permeabil- 6-inch diameter circle of fabric mounted in an
ity range. The selection of the proper orifice is embroidery hoop at an angle of 45 ° with the
by experience and by trial and error, and, of horizontal. After spraying, tile fabric in the
course, depends upon the air permeability char- hoop is tapped smartly against a solid object to
acteristics of the fabric being tested. While most remove excess water. The surface condition is
test methods stipulate a pressure of0.5 inches of then graded.
water across the fabric, the Frazier permeome-
ter can measure air flow at pressures ranging Drop Penetration Test (AATCC 79)
from 0.1 to 1.0 inches. With special manometers
the pressure drop across the fabric can be in- A drop of water is allowed to fall from a fixed
creased to about 20 inches for low permeability height onto the taut surface of a test specimen.
fabrics. The time required for the reflection of the water
to disappear is measured and recorded as wet-
ting time.
Textest Air Permeability Tester
Dynamic Absorption Test (AA TCC 70)
A different type of tester employs a mufflered
suction pump drawing air through an inter-
A preweighed specimen is tumbled in water
changeable test head with a circular opening.
for a fixed period of time and is then reweighed
The test head appropriate for the selected test
after the excess water has been removed by blot-
standard is mounted in the instrument. The
ting and wringing through squeeze rolls. The
specimen is clamped over the test head which
percent weight increase is taken as a measure of
starts the suction pump. The preselected test
the absorption or resistance to internal wetting.
pressure is automatically set and maintained;
after a few seconds the air permeability of the
Static (Immersion) Absorption Test
test specimen is digitally displayed. The instru-
ment is equipped with an asynchronous data
This method measures the amount of water
port allowing computer data acquisition and
absorbed when the fabric is immersed but not
analysis.
tumbled or otherwise agitated. Therefore, it is
TRI air permeability tester is also commer-
not as severe a test as the dynamic absorption
cially available.
method. The 3 x 3-inch test specimens are im-
mersed so that their plane surfaces are vertical,
9.8 Water Repellency and presumably to permit the discharge of air bub-
Permeability Tests bles. By means of hooked sinkers, the fabric
swatches are kept under water for twenty
Water resistance tests measure resistance to minutes, following which they are blotted and
(1) surface wetting, (2) water absorption and in- sent through squeeze rolls. The percent weight
ternal wetting, and (3) water penetration and increase is taken as a measure of absorption.
transmission. To determine the extent of surface
wetting, the spray test is used. Water absorption Rain Penetration Test (AA TCC 35)
is determined by the "drop penetration;' "dy-
namic absorption" and "static immersion" tests. To simulate the effect of rain, a horizontal
Water penetration and transmission are mea- water spray of fixed and constant intensity is
sured by the rain penetration, drop penetration, allowed to impinge against the vertically
impact penetration, and hydrostatic pressure mounted test specimen. The water penetration
tests. All of these tests are described below. during a five minute spray period is determined
20.1 Textile Testing 687
by measuring the increase in weight of a blotter face of the lower clamp ring by adding water
placed behind the fabric. through the open orifice. The specimen is then
clamped into place and pressure is applied until
Impact Penetration Test (AATCC 42) leakage occurs. The pressure, in psi, at the first
sign of water leakage through the fabric is
With an apparatus similar to the spray test, recorded.
500 rnl of water are sprayed from a height of two
feet against the taut surface of the test specimen 9.9 Abrasion Resistance Testers
backed by a weighed blotter. After the test, the
blotter is reweighed and the percent weight in- Abrasion is wearing away of material through
crease is recorded as the water transmitted. some type of frictional interaction between
materials. This may occur between fibers,
Low Range Hydrostatic Pressure yams, fabrics or between textile materials and
Test (AATCC 127) other surfaces. The nature of the expected wear
a particular textile product would be exposed to
Method 1-This test measures the resistance should dictate the type of abrsion test that is
of fabrics to wear penetration under static pres- most appropriate. A description of seven widely
sure. It is suitable for testing heavy, closely used laboratory abrasion testers are described
woven fabrics that are expected to be used in below.
contact with water, such as ducks and tarpau-
lins. The test is not suitable for proofed or Inflated Diaphragm Test (ASTM D 3886)
coated fabrics. A test specimen of fixed area,
mounted over a well of water, is subjected to This method is intended for determining the
water pressure that increases at a constant rate abrasion resistance of woven and knitted fabrics
until leakage appears on the fabric surface. The when the specimen is mounted over an inflated
pressure is increased by means of a hydrostatic rubber diaphragm and is then rubbed either uni-
bead which is raised at the rate of one centime- directionally or multi-directionally by an emery
ter per second. The height reached when leak- cloth-type abradant under controlled pressure
age occurs is recorded as the measure of water conditions. The abradant is mounted upon a
resistance. plate in a manner so that it can rest upon the
Method II-A modification to the above tech- specimen under a selected load of 0 to 5 pounds.
nique consists of applying a preselected hydro- The abradant moves back and forth unidirec-
static head to the fabric and measuring the tionally over the specimen surface. The speci-
amount of water leakage in milliliters which men remains in a fixed orientation or can be
passes through the fabric in ten minutes or other continuously rotated, depending upon whether
specified time. unidirectional or multi-directional abrasion is
desired.
High Range Hydrostatic Pressure Test
for Coated Cloth Flexing and Abrasion Method
(ASTM D 3885)
This method is useful for determining the re-
sistance of coated cloth to the passage of water This method is used for determining the re-
under high pressure. A modified Mullen-type sistance of woven fabrics to flexing and abrasion
diaphragm burst tester is used to make the test. when the specimen is subjected to unidirec-
The rubber diaphragm is removed and is re- tional reciprocal folding and rubbing over a bar
placed by the test specimen. The oil or glycer- having specified characteristics under known
ine commonly used is replaced with water. In conditions of pressure and tension. The same
conducting the test, the water level in the instrument as described in the inflated di-
pressure chamber is brought flush with the sur- aphragm test is used but with necessary modifi-
688 TEXTILE TESTING
cations and attachments. A specimen 8 inches resistance when the specimen is subjected to
long and 1.25 inches wide, raveled to 1 inch, is rotary rubbing action under controlled condi-
looped around either a hard carbide bar or a tions of pressure and abrasive action. The tester
blade which acts as the abradant. The bar or consists of a 4-inch diameter record player-type
blade is attached to a pulley loaded with weights turntable which rotates in a horizontal plane,
so a constant tension can be applied to the test and upon which the test specimen is clamped.
specimen. An upper movable reciprocating Above the turntable there are mounted two sep-
plate contains a jaw for clamping the top edge of arate halves of a weighted frame, each contain-
the specimen. A lower fixed plate also contains ing a rubber emery composition abrading wheel
a jaw for clamping the lower edge of the speci- similar in dimensions to a small grinding
men. The upper plate, which can be loaded in wheel. These are free to rotate in a vertical
order to apply a specified pressure to the speci- plane. At the start of the test, the wheels are
men, moves back and forth, thus causing the lowered so they rest on the turntable and thus on
specimen to be both abraded and flexed over the the fabric. The weight of the frame can be
edge of the blade. The greater the headweight varied, and in this manner the pressure on the
on the upper plate, and the greater the tension sample is controlled. The turntable is driven;
applied by the bar, the more severe will be the the abrasive wheels are not. The lines of abra-
abrading action. The bars and blades are edged sion are in the form of two arcs which crisscross
with smooth synthetic sapphire, silicon carbide, each other, forming a circular track on the spec-
or other highly wear-resisting surfaces, and imen. The specimen is not flexed during abra-
must be precisely ground so that the abradant sion. Figure 20.21 shows single and double head
will remain constant for long time periods. Bars abrasers.
and blades are calibrated by the manufacturer
Uniform Abrasion Method
but should be rechecked regularly against a
(ASTM D 4158)
standard cloth which should be set aside by each
laboratory for calibration purposes.
This instrument multi-directionally abrades a
Oscillatory Cylinder Method flat surface of fabric (Figure 20.22). The essen-
(ASTM D 4157) tial parts of the tester consist of two flat parallel
plates that rotate horizontally and can be placed
This method is used for determining abrasion in contact with each other. The lower plate sup-
resistance when the specimen is subjected to ports the specimen, the upper the abradant. The
unidirectional rubbing action under known con- plates rotate in the same direction at very nearly
ditions of pressure, tension and abrasive action. the same angular velocity (250 rpm) on two par-
The instrument is composed of a 6-inch diame- allel, but not coaxial shafts. The abradant is suf-
ter oscillating cylinder upon which is mounted a ficiently larger than the specimen so that all
sheet of emery cloth or other abrasive material. points on the specimen's surface are abraded
The specimens, each 9 X 1.875 inches, are equally and unifOrmly in all directions.
mounted between clamps under a selected ten-
The Accelerator (AATCC 93)
sion and are placed against the cylinder which
oscillates through an arc 3 inches long at the
This instrument, developed by the American
rate of 90 cycles (double rubs) per minute. The
Association of Textile Chemists and Colorists,
unidirectional abrasive action is parallel with
flex abrades specimens in a completely random
the long direction of the specimens, which are
manner. An unfettered fabric specimen is driven
also subjected to mild flexing action during the
by a rotor in a random path so that it repeatedly
test.
impinges the walls and abradant liner of the
Rotary Platform Double Head Method abrading chamber. The zigzag orbit taken by the
(ASTM D 3884) specimen is generally circular while it is being
continuously subjected to extremely rapid,
This method is used in determining abrasion high-velocity impacts. The specimen is sub-
FIGURE 20.21 Single and double head abrasers (courtesy of Taber).
689
690 TEXTILE TESTING
jected to flexing, rubbing, shock, compression, length of webbing over a 114-inch maximum di-
stretching and other forces. Frictional abrasion ameter rigid hexagonal steel bar of specified
is produced by the rubbing of surface against hardness. A 13-inch traverse of webbing is
surface, and surface against abradant. The abraded over the bar at a rate of 60 cycles per
results of the abrasive action may be evaluated minute. The dead load tension applied to the
by visual comparisons, determination of strength webbing during the test is a function of its origi-
loss or by determination of weight loss. Usually, nal strength. Visual appearance or strength loss
a new fabric subjected to the Accelerotor's ac- after a selected number of cycles are normally
tion will look well-worn and threadbare after used as abrasion resistance criteria. If it is
a relatively short time, for example, 2 to 5 desirable to study the effect of flexing without
minutes. abrasion, a smooth, freely rotating rod can be
substituted for the rigid hexagonal bar. A new
Martindale Abrasion Tester abrasion tester developed by the University of
(ASTM D 4966) Georgia is also becoming popular.
FIGURE 20.23 Nu-Martindale abrasion and pilling tester (courtesy of James H. Heal & Co.).
20.1 Textile Testing 691
hexagonal
rod
specimen
niques are used to evaluate pilling (Figure trolled rubbing against an elastomeric pad pos-
20.25). sessing specific mechanical properties. The
evaluation of resulting pills is accomplished by
Brush Pilling Tester (ASTM D 3511) comparison with photographic standards.
Fabrics are brushed to form free fiber ends. Martindale Pressure Tester
Two of the specimens are then rubbed together
in a circular motion. This rubbing action pro- This method evaluates the tendency of textile
duces the pills. The wear as evidenced by pills fabrics to form pills under light pressure. Fab-
is evaluated by comparison to photograph stan- rics are in the tester in a manner such that the
dards showing different degrees of pilling. face of the specimen is rubbed against another
portion of the same specimen. The rubbing is
Random Tumble Pilling Tester done in the form of a geometric figure in an
(ASTM D 3512) ever-widening ellipse. The pilling is evaluated
against visual standards, either actual fabrics or
The wear conditions that cause pilling are photographs of pilled fabrics.
simulated by tumbling the specimens in a cylin-
drical test chamber lined with a mildly abrasive 9.11 Fabric Stiffness Tests
material. The pills formed are produced from
short cotton fiber added to simulate the pres- The following test methods are used for fabric
ence of broken fibers that may be present in ac- stiffness.
tual wear situations.
Cantilever Test
Elastomeric Pad Method (ASTM D 3514)
A 1 X 6-inch specimen is extended out from
The Stoll Quartermaster Universal Wear the horizontal until an angle of 41.5° is achieved
Tester with the Frosting attachment is used for (see Figure 19.11). One-half of the resulting
this method. The fabric specimens are washed overhanging length is the bending length
or dry-cleaned and are then subjected to con- (ASTM D 1388). The stiffness or flexural rigid-
692 TEXTILE TESTING
FIGURE 20.25 ICI pilling tester (courtesy of James H. Heal & Co.).
693
694 TEXTILE TESTING
in fabrics when washed in commercial laun- marks. These are measured before and after the
dries, as well as in the home. Because wool washing, drying and restoration treatment. The
fabrics can undergo felting shrinkage, they are shrinkage is calculated as the change in length
excluded from these tests. Five washing proce- in each direction, as a percentage of the original
dures ranging from mild hand washing to length.
severe commercial laundering, five drying pro- The tension presser is used when, upon flat-
cedures encompassing methods used in homes bed pressing, the shrinkage exceeds 2% in
and commercial laundries, and three methods either direction. The fabric is then rewet, sub-
for determining the dimensional restorability jected to tensions by means of the pulleys and
characteristics, are listed for those textiles weights, and dried by means of a drying plate
which require ironing or wearing after launder- and iron. The gauge marks are then remeasured.
ing. The washing, drying and restoration pro- Other methods for determining the shrinkage
cedures may be used in various combinations. of synthetic fabrics consist of immersing a
For example, Test III-A-3 refers to a fabric 20 X 20-inch marked sample (1) in boiling
which has been washed at 145°F for 45 water for 15 minutes, drying it flat in an oven at
minutes, tumble dried and subjected to hand a temperature not above 212°F; or (2) in an
ironing. This type of code is widely used to autoclave under stream pressure at 290°F for
describe various wash test combinations. Selec- 15 minutes. The percent changes in warp and
tion of washing temperatures, and type of soap filling lengths are calculated as shrinkages.
or detergent, depends upon the nature of the
fabric being evaluated. 9.14 Thermal Property Tests
The test fabric is washed, as part of a full
load, in a cylinder reversing wash wheel, dried Transmittance Test
and subjected to restorative forces. Normally,
specimens about 22 inches square are cut and The ASTM Method D 1518 determines the
precisely marked with 18 or 20-inch gauge overall thermal transmission coefficient of a test
TABLE 20.11 Flammability Standards Consumer Product Safety Commission (courtesy of CPSC).
16 CFR 1610 Standard for the Flammability of Clothing Textiles (General Wearing Apparel)
16 CFR 1611 Standard for the Flammability of Vinyl Plastic Films (General Wearing Apparel)
16 CFR 1615 Standard for the Flammability of Children's Sleepwear: Sizes 0 through 6X (FF 3-71)
16 CFR 1616 Standard for the Flammability of Children's Sleepwear: Sizes 7 through 14 (FF 5-74)
16 CFR 1630 Standard for the Surface Flammability of Carpets and Rugs (FF 1-70)
16 CFR 1631 Standard for the Surface Flammability of Small Carpets and Rugs (FF 2-70)
16 CFR 1632 Standard for the Flammability of Mattresses (and Mattress Pads) (FF 4-27)
16 CFR 1633 DRAFT Proposed Standard for the Flammability (Cigarette Ignition Resistance) of Upholstered
Furniture (PFF 6-81)
cent, and xenon-arc lamps. In the past ten years, change, breaking or tear strength loss, flexibil-
xenon-arc lamps have gained favor in the textile ity, etc.
industry because of their superior spectral
match to sunlight throughout the solar spec-
Accelerated Aging by Heat
trum, and especially in the 300-400 nm UV
range, the wavelength range which exerts the
Heat aging at elevated temperatures with cir-
most deleterious effect upon materials.
culating air is a useful method for evaluating
The weathering chamber includes one to
treated and coated cloths. A circulating air
three lamps which emit elevated levels of radia-
oven, thermostatically controlled and of large
tion to the samples. Typical weathering cham-
capacity so that many specimens may be hung
bers also can control chamber temperature and
without touching each other, is all that is neces-
can periodically spray samples with water or
sary. The temperature and time of exposure de-
create a high-humidity atmosphere in the cham-
pends upon the nature of the material being
ber to simulate outdoor moisture conditions the
tested. For example, impregnated fire-weather-
material might encounter. Samples are verti-
water-resistant duck is aged at 200°F for five
cally mounted in holders on a cylindrical rack
days and then tested for flexibility change (Fed.
which rotates around the central light source for
Std. 191A 5850).
a specified test duration, typically measured in
accumulated Langleys or in accumulated MJ/m2
UV. Weathering chambers also are able to be Accelerated Aging by Oxygen
programmed for light and dark phases, again to Bonds Methods
simulate the outdoor environment to which a
material is actually exposed. Specific testing An accelerated oxygen aging test is useful in
standards published by various organizations assessing the resistance of many organic ma-
such as ASTM, AATCC and SAE give specific terials to oxidation degradation. The test ap-
instructions on what test cycle should be paratus, popularly called an "oxygen bomb;' is a
run for specific materials. As with outdoor vessel capable of maintaining and withstanding
real-time exposure testing, physical property an internal oxygen gas pressure of 300 psi for
changes that are typically assessed include color ten days at 160°F (Fed. Std. 191A 5852). The
2a1 Textile Testing 699
test specimens are inserted into the preheated systems are usually preferable. Spectropho-
chamber, which is then securely closed and fas- tometric systems are based upon the fact that
tened. Oxygen is introduced until the desired white light is composed of a visible spectrum of
pressure is reached. The selected pressure and colors of continuously changing wavelength
temperature must be maintained for the dura- ranging from 400 millimicrons (1 mJ.t =
tion of the test. At its conclusion, the oxygen is 1/25,400,000 inches) for violet, to 700 millimi-
released and the specimens are removed for ex- crons for red. The subdivision of light into the
amination and testing. Because of the danger of six standard colors as shown in Thble 20.14 is
fire and explosion, the oxygen bomb test should one of convenient identity. The color of the
be carried out with extreme caution. spectrum varies continuously throughout its
length, the physical difference being the con-
tinuous change in wavelength.
9.17 Color Measurements and The spectrophotometer is an instrument
the Spectrophotometer which can produce light of any desired wave-
length (actually a narrow band of wavelengths)
There are two basic systems for identifying within the 400-700 millimicron range. The col-
and defining colors. One is the subjective ored specimen to be measured is viewed under
method wherein the observer makes use of a these progressively changing wavelengths
previously assembled comprehensive collection (colors) and the percent light reflected back is
of standard color samples and visually matches plotted. For example, a "green" fabric will ex-
his "unknown" specimen against the nearest hibit high reflectance when viewed with a green
known standard. He depends upon his eye to light (500-570 millimicrons), but low reflec-
judge and decide when a match is achieved. The tance when viewed in violet, orange and red
second is an objective method wherein the color light.
is quantitatively determined and characterized The depth of shade influences the percent
by certain physical measurements based upon reflectance, and so governs the position of the
the wavelength of light. The instrument which curve along the reflectance axis. A perfect white
makes these measurements is called a spec- specimen, as exemplified by a freshly scraped
trophotometer. Many textile mills use spec- surface of calcium carbonate, will show 100%
trophotometers together with subjective meth- reflectance, and a perfect black will show 0%
ods for matching against a "standard for shade" reflectance at all wavelengths. Therefore, the
submitted for duplication. extent of sample grayness is also measurable
The two best known systems for subjective from the spectrophotometric curve.
matchings are the Munsell system and Pantone The percent transmission of clear dyestuff
Professional Color System. These and all other solutions can be determined by utilizing an op-
subjective visual classification systems are tical chamber with absolutely parallel sides into
based upon three criteria of color to which the which the dyestuff solution is poured. A graph
human eye responds: of wavelength versus light transmitted through
• Hue indicates the color itself, e.g., red,
orange, blue, etc. TABLE 20.14 Wavelength Bands
• Value or lightness is the lightness or for Visible Colors.
darkness of a color and depends upon
Wavelength
its black or white content. Color (millimicrons)
• Chroma or saturation is the strength or
intensity of the "pure" color. Violet 400-450
Blue 450-500
The disadvantages of visual color classifica- Green 500-570
tion systems are that they are qualitative and Yellow 570-590
based upon the personal reaction of the Orange 590-610
Red 610-700
observer. Objective quantitative reproducible
700 TEXTILE TESTING
the solution is plotted. The concentration and neously to the intense light from a calibrated
thickness of a dye solution is related to its trans- light source for a time sufficient to produce
mission according to Beer's law: "just appreciable fading" in the standard or the
test specimen. Colorfastness is rated in terms of
I = Ioe-acx (20.14) the number of AA1CC Fading Units (AFU) of
exposure required to produce this amount of
where fading. The common practice is to mount a
2.75 X 10.5-inch fabric specimen in a frame es-
I = intensity of light transmitted pecially prepared for insertion into the Fade-
Io = intensity of incident light ometer. The specimen is held and covered by a
e = natural logarithm base protective frame in which there is a rectangular
c = concentration of dyestuff opening 1.75 x 5 inches. The arc light impinges
x = thickness of solution on that part of the specimen which is exposed in
a = absorption coefficient the frame opening. The surrounding area is pro-
tected and does not change color during the test.
One use of color measure is for fibers which The specimen is examined periodically in order
is explained in ASTM D 2253 Color of Raw to note when fading develops.
Cotton using the Nickerson-Hunter Cotton Col- While formerly the Fade-ometer and Weather-
orimeter. ometer were entirely different instruments, they
were later combined using the same cabinet for
Colorfastness Tests both testers. The ultraviolet carbon arc or xenon
lamp components are interchangeable so that
A number of standard test methods deal with one cabinet is useful for conducting any desired
the fate of colored textiles when exposed to dif- Fade-ometer or Weather-ometer test. The
ferent use conditions. A number of these Weather-ometer is also used for determining the
methods are given in Table 20.15. effect of a carbon arc light and water spray on
colorfastness (Fed. Std. 191A 5660 and 5671).
Colorfastness to Light: In addition to these two accelerated methods,
the Fade-ometer lightfastness may be assessed by natural day-
light and by sunlight exposures. In the daylight
The AA1CC developed test methods and grad- method (AA1CC 16; Fed. Std. 191A 5662.1), a
ing scales for evaluating colorfastness. Fastness specimen, together with the standard is exposed
to light is one of the most important properties. to daylight continuously under prescribed con-
A test specimen and a "standard" dyeing of ditions while being protected from the rain. The
known light colorfastness are exposed simulta- fastness is assessed by the color change of the
20.1 Textile Testing 701
test specimen with that of the standard. The "gas fading" of dyed acetate and other syn-
sunlight test is the original AATCC lightfastness thetics. These dyes fade or change color when
test (AATCC 16B). The test specimen and blue exposed to oxides of nitrogen produced in in-
wool lightfastness standards are exposed be- dustrial gases and smoke in urban areas. Gas
tween 9:00 A.M. and 3:00 P.M. when the sun is fading can also occur in some sensitive resin
at its highest intensity. Comparison of the test bonded pigments.
specimen and the standard is made directly. The laboratory test for evaluating gas fading
consists of exposing small swatches of the test
Colorfastness to Washing: specimen, together with a dyed control sample,
the Launder-ometer to oxides of nitrogen fumes until the control
fades a prescribed standard amount. The test
The colorfastness to laundering test consists specimen is then examined to ascertain if fading
of laundering the test specimen which is at- has occurred. If it has not, the cycle is repeated
tached to a standard white test cloth and observ- until fading is obvious. The specimen is then
ing the color change in both the test fabric and ranked from Class 1 (poor) to Class 5 (ex-
the standard. Two 2 x 4-inch test specimens are cellent) depending upon the number of expo-
sewn against (1) a swatch of white cotton cloth sures required to produce an appreciable shade
and (2) a swatch of white "multi-fiber test cloth" change. The test apparatus consists of a labora-
containing yarns of several different fiber types: tory, oven-type, thermostatically controlled
acetate, cotton, nylon, silk, viscose, and wool. chamber containing a slowly rotating fan. Con-
The faces of the specimen and each test cloth ventional illuminating gas is burned in a burner,
are thus in contact with each other, affording the and the combustion products conveyed into the
maximum opportunity for the dye to bleed and exposure chamber. In this test, an exposure cy-
transfer from one fabric to the other. Each cle to cause fading of the standard may take 5 to
swatch assembly is inserted into a stainless steel 10 hours. This time can be reduced in an "accel-
can containing several 0.25-inch diameter stain- erated" test by introducing nitrous oxide into the
less steel balls for agitation. Depending upon gas flame, thus increasing its concentration in
test requirements, a selected washing formula- the chamber. By this technique a test cycle can
tion of soap, bleach, detergent, etc., is added. be completed in about 1 hour. This accelerated
The can with its contents is inserted into the method should be carried out with care. The
rotating rack of a constant temperature bath, test should not be so severe as to cause speci-
where it is rotated for a selected period of time. mens to fade quickly, for then no distinction
The swatch assembly is then removed, and ex- among samples can be made.
amined for color change in the specimen and
staining of the white test standards by means of Colorfastness to Crocking
special color charts. The can-steel ball-rotating
rack-constant temperature system is called a The crocking test determines the extent to
Launder-ometer. It enjoys wide use in evaluat- which color may be transferred from the surface
ing the wet colorfastness and dry cleaner's sol- of a dyed fabric to another surface by rubbing.
vent colorfastness properties of fabrics. The The test specimen is fastened to the base of a
Launder-ometer is also used to evaluate the Crockmeter, and is rubbed under a controlled
permanence to repeated laundering of textile pressure by a standard white cotton print cloth
finishes such as water repellents, softeners, for twenty rubbing cycles. The white standard
wrinkle resisting finishes, etc. cloth is then examined for the presence of color.
The test may be conducted dry or wet. The ex-
Gas Fading, Colorfastness to Oxides of tent of crocking is classified according to an
Nitrogen in the Atmosphere AATCC color chart based upon Munsell color
chips, with rankings ranging from five for no
A serious colorfastness problem in the past, color transfer to one for large color transfer or
and one which, in part, still prevails is that of the gray scale for staining.
702 TEXTILE TESTING
Colorfastness to Other Conditions along straight lines between the two conductors
but will have a very complicated electrical field
There are many other colorfastness require- pattern. In this case, the current flow is appre-
ments which textiles may be called upon to ciably higher and the effective surface resis-
meet. Many of these involve apparel and deco- tance lower than that observed previously, al-
rative fabric needs, rather than industrial tex- though there has been no change in the fabric
tiles. These tests can be found in the AATCC material properties. Therefore in any resistance
manuals. measurement the test conditions must be con-
sidered in the determination of meaningful
9.18 Electrical Resistivity values. To do this, it is necessary to establish the
quantitative relationship which exists between
The electrical resistance of a material is the geometry of the testing device, the measured
defined by Ohm's Law as the ratio between the resistance, and the specific resistance of the
voltage impressed across the material and the material under test.
resultant current flow through it. This observed Two types of electrical resistance can be
resistance to current flow is a function of the in- defined, one of which relates to the resistance to
trinsic material properties, the geometrical current flow through the volume of bulk of the
shape of the material, and the size, shape, and material, called volume resistivity e; the other
location of the measuring electrodes. is the resistance to current flow along the sur-
For example, consider two electrodes placed face of a piece of material and is called surface
upon the surface of a fabric specimen and a volt- resistivity u.
age applied between them. Because the elec-
trodes span the full width of the fabric sample, Volume Resistivity
the current flow along the fabric is in parallel
lines as shown in Figure 20.27 by the arrows. Mathematically, volume resistivity is defined
From the values of current and voltage indicated as
by the two meters the effective electrical resis-
tance applicable to this situation can be com- R.A
puted.
e =T ohm-centimeters
Now, if we use the same electrode configura-
tion and electrical system on a larger piece of where R. is the volume resistance in ohms, L is
the same fabric, the current flow will not be the average thickness of the material, A is the ef-
FABRIC SAMR...E
ELECTRODE LECTRODE
fective electrode area and e is the resistivity of evaluation of hand. Sueo Kawabata of Japan ap-
the material under test. proached the task of providing a single value for
By Ohm's Law hand by starting with the development of instru-
ments that would be capable of evaluating the
E volts desired fabric properties under low-load condi-
Rv= tions. He believed that this would more closely
/amps
relate to the human concept of hand. His instru-
Hence the resistivity of the material may be ments were designed to measure the hand-related
computed. properties: tensile and shear behavior, bending
behavior, compressive behavior, and surface
E volts x A cm2 roughness and friction (Figure 20.28). These
e= .
I amps X L centimeters
= ohm-centimeters properties are similar to those listed by the
ASTM with the exception of thermal character-
(20.15)
istics. Kawabata developed an equation that
gives a weighing to each of the measured prop-
In certain test procedures, a simple ammeter
erties and called the resultant summation Total
cannot be used due to the very high value of Rv,
Hand Value. The weighing factors were devel-
and consequent difficulty in measuring the very
oped through extensive human subjective evalu-
small current flow through the specimen. Usu-
ations of a range of fabric types and the ranking
ally an electrometer would be used in this in-
of characteristics. The weighing factors are be-
stance using calibrated shunt resistances.
lieved to be appropriate for the population
within which the data was taken but there is
Surface Resistivity
some question as to the application of the same
weighing factors in a different culture. The in-
Surface resistivity may be measured using the
struments of the KES system can be used for de-
same apparatus used for volume resistivity stud-
termining the listed fabric properties and are
ies, except that the electrodes are rearranged to
useful in providing relative data for fabric com-
induce current flow along the surface of the
parisons.
material rather than through the mass. In
mathematical terms, the surface resistivity
10. AATCC TEST METHODS
R.W ohm-centimeters
u= L . .
per centimeter 'dth
WI
10.1 Acidity and Alkalinity
(20.16)
An acid is defined as any hydrogen containing
where compound which yields hydrogen ions (H +) in
water, and an alkali or base is defined as any
u = surface resistivity in ohm-centimeters per hydroxyl compound which yields hydroxyl ions
centimeter width (OH-) in water. At equal concentrations of
R. = observed surface resistance along a path (H +) and (OH-) ions, the solution is neutral.
of length L centimeters and of width W Acids and alkalis which dissociate or ionize
centimeters completely to produce 100% of their available
(H +) or (OH-) ions in solution are called
9.19 Fabric Hand-Kawabata System strong acids or alkalis. Those which do not dis-
sociate completely are called weak acids or
An analysis of fabric hand has been described alkalis.
by the ASTM as being composed of eight com-
ponents: compressibility, flexibility, extensibil- 10.2 Hydrogen lon Concentration, pH
ity, density, resilience, surface contour, surface
friction, and thermal properties. The measure- An acidity-alkalinity scale from 0 to 14, com-
ment of these properties does not give one an monly called the pH scale is used to measure
FIGURE 20.28 Kawabata surface tester (courtesy of Kato Tech
Co., Ltd.).
0
t--
STRONG .ACIDITY -
t--
N
(JI
MODERATE ACIDITY
..
1--
()1
pH NEUTRAL --.1
CXl
WEAK ALKALINITY (--
<0
0
MODERATE ALKALINITY (--
--
i\>
t--
STRONG ALKALINITY ()j
t--
~
704
TABLE 20.16 Alphabetical List of AATCC Test Methods and Procedures (Copyright 1993 AATCC).
Test Title Method Number
(continued)
705
TABLE 20.16 (continued).
Colorfastness to (continued)
Laundering, Home and Commercial: Accelerated 61-1993
Light 16-1993
Light at Elevated Temperatures and Humidity: Water Cooled Xenon Lamp Apparatus 177-1993
Light: Detection of Photochromism 139-1989
Non-Chlorine Bleach in Home Laundering 172-1990
Oxides of Nitrogen in the Atmosphere under High Humidities 164-1992
Ozone in the Atmosphere under Low Humidities 109-1992
Ozone in the Atmosphere under High Humidities 129-1990
Perspiration 15-1989
Pleating, steam 131-1990
Solvent Spotting: Perchloroethylene 157-1990
Staving 9-1989
Water 107-1991
Water: Chlorinated Pool 162-1991
Water: Sea 106-1991
Water Spotting 104-1989
Water and Light: Alternate Exposure 125-1991
Water (High Humidity) and Light: Alternate Exposure 126-1991
Compatibility of Basic Dyes for Acrylic Fibers 141-1989
Creases; in Fabrics, Retention of, after Repeated Home Laundering 88C-1992
Dimensional Changes in Automatic Home Laundering of Woven or Knit Fabrics 135-1992
Dimensional Changes in Automatic Home Laundering of Garments 150-1992
Dimensional Changes in Commercial Laundering of Woven and Knitted Fabrics Except
Wool 96-1993
Dimensional Changes on Dry-cleaning in Perchloroethylene: Machine Method 158-1990
Dimensional Changes of Woven or Knitted Textiles: Relaxation, Consolidation and Felting 99-1993
Dimensional Restoration of Knitted and Woven Fabrics after Laundering 160-1992
Disperse and Vat Dye Migration: Evaluation of 140-1992
Dispersibility of Disperse Dyes: Filter Test 146-1989
Dispersion Stability of Disperse Dyes at High Temperature 166-1993
Dry-cleaning: Durability of Applied Designs and Finishes 86-1989
Dusting Propensity of Powder Dyes: Evaluation of 170-1989
Electrical Resistivity of Fabrics 76-1989
Electrical Resistivity of Yarns 84-1989
Electrostatic Clinging of Fabrics: Fabric-to-Metal Test 115-1989
Electrostatic Propensity of Carpets 134-1991
Extractable Content of Greige and/or Prepared Textiles 97-1989
Fabric Hand: Subjective Evaluation of EP5
Fabrics; Appearance of, after Repeated Home Laundering 124-1992
Fiber Analysis: Qualitative 20-1990
Fiber Analysis: Quantitative 20A-1989
Finishes in Textiles: Identification 94-1992
Fluidity of Dispersions of Cellulose from Bleached Cotton Cloth 82-1989
Foaming Propensity of Disperse Dyes 167-1993
Formaldehyde Release from Fabric, Determination of: Sealed Jar Method 112-1993
Frosting (Color Change due to Flat Abrasion)
Emery Method 120-1989
Screen Method 119-1989
Gray Scale for Color Change EP1
Gray Scale for Staining EP2
706
TABLE 20.16 (continued).
Test Title Method Number
707
708 TEXTILE TESTING
the intensity of (H +) or (OH-) ions. pH is fiber or fabric scouring, bleaching, dyeing, and
defined as the logarithm, to the base 10, of the resin finishing. Selected dyestuffs which are
reciprocal of the hydrogen ion concentration. color sensitive in specific pH ranges can be
Because of the conversion of the power scale to used to identify those ranges.
the reciprocal-log scale the pH range is 7 to 0 The pH of a solution is directly related to the
for progressively stronger acids and 7 to 14 for electrical voltage potential which develops be-
progressively stronger alkalis (Figure 20.29). tween the solution and a reference electrode.
It is reiterated that the pH of a solution does Electronic instruments capable of measuring
not indicate the total amount of acidity or alka- these potentials have been developed and are
linity. It only indicates the hydrogen or hydroxyl called pH meters. The meters are usually cali-
ion concentration. brated to read direction in units.
pH measurement and control methods enjoy Table 20.16 shows the major AATCC test
wide usage in the textile industry, for example in methods and procedures for textile materials.
20.2
References and Review Questions
709
21.0
TEXTILE WASTE MANAGEMENT
21.1
Textile Waste Management
S. ADANUR
TABLE 21.1 Breakdown of Recycled Post- Discarded textiles are complex as far as mate-
Consumer Textile Product Waste in 1992 [2]. rial characteristics are concerned. They usually
Domestic Exports Total consist of different fibers and their quality is
(%) (%) (%) difficult to define (nature of manufacture, prod-
uct characteristics, extent of wear). Due to laun-
Used clothing 35 35
dering, exposure to light, etc., fiber strength
Fiber for reprocessing 7 26 33
Recycled products 25 25 can drop to 25 % of its original value.
Landfill 7 7 Cadieux and Godfrey suggest the following
Total 39 61 100 steps for waste management [4]:
3. SOURCE REDUCTION
Efficient use of raw materials may reduce the TABLE 21.2 Recycled Textiles
waste generated. Improved product quality may (courtesy of A TMI).
help in reducing the textile waste. There have • Mattress pads/covers
been many successful case histories in waste • Carpet underlay
source reduction [6] . • Decorative pillows
The main goals of source reduction are to • Toys
• Punching bags
reduce the amount of waste and to improve
• Q-tips
waste characteristics such as persistence, treat- • Cotton balls
ability, toxicity and dispersibility. • Blankets
Source reduction techniques can be applied at • Diapers
various levels during the operations. Raw • Package trays in autos
• Mops
materials can be prescreened and better quality
• Insulation for homes
controlled. Existing processes can be modified • Firemen's suits
or alternative processes can be found to mini- • Quilts
mize waste. Optimization, automation and ad- • Sleeping bag liners
vanced process control can also help. • Furniture decking pads
• Sound deadening pads in cars
• Casket liners
• Sanitary products
4. RECYCLING • Jewelry wrap/packaging
• Baby wipes
Recycling is the most viable approach to re- • Wiping clothes
• Sponges
ducing solid waste stream after source reduc-
• Ski jacket insulation
tion. The main goal of textile recycling efforts is • Air filters
to reprocess the textile and fiber by-products so • Geotextiles
that they can be recycled back into the original • Ironing board pads
stream or into useful end products. Putting the • Plastic wood (used to make furniture)
waste back into the original system has the
greatest economic value. It might go back into
the original synthetic fiber, usually at a low from very technically sophisticated items used
percentage versus the virgin material. Ther- in automobiles and aircraft to very mundane
moplastic waste could be diverted to less critical items such as a flower pot.
end uses such as a fiberfill, melt blown products
or spunbonded products. Injection molding is 4.2 Textile Waste Industry Operations
also another possibility for textile waste [7].
Recycling methods should be technically Traditional textile wastes can be in fiber,
feasible, ecologically friendly and economically thread or fabric form. Textile waste may include
viable. To achieve this for textiles, the recycling card waste, motes, thread waste, selvages, sub-
aspect must rank as high as development and standard fibers and fabrics, filament and tow
production. To determine the ecological advan- waste. There are two main processes for recy-
tage, comparison should be made between the cling textile wastes: tearing process and clean-
recycling method in question and what would ing process [5,8].
happen if the product in question were burned
in a modern incinerator or deposited in land- Tearing Process
fills. Recycling for the sake of it without any
ecological and economical advantage would not The tearing process consists of the following:
serve any purpose.
• grade incoming material
4.1 Recycled Textiles • collect together mixes to ensure proper
consistency
Recycled textiles are used in various products • prepare the mix for feeding onto a
as shown in Table 21.2. These products range conveyor
716 TEXTILE WASTE MANAGEMENT
• blend the material while feeding the to fibers and are used in the absorbent cotton in-
conveyor dustry. They may be bleached and purified for
• sort out trash, also while feeding sanitary applications. Coloration of wasted
• cut the material to manageable size, fibers is also possible.
typically 2 inch to 6 inch Recycled absorbent pads are used for oil drips
• tear the material with tearing machines and spills, walkways, packaging and cushion-
to return it to opened fiber form ing. Mattress and furniture insulator pads are
• bale the end product also made from recycled fibers (Figure 21.2).
Knobs are mixed with staple fibers to produce
In this way, polyester/cotton threads are ma- novelty yarns.
chined into open fiber. These fibers can be used
for stuffing and for some industrial applications Cleaning Process
such as filters and caskets. In general, these
fibers may be spun into very coarse count yarns The cleaning process handles the cleaning of
such as mop yarns (a mop cord is made of four soft cotton or polyester/cotton card waste and
to eight plied yarns). Friction spinning is gin motes. The raw materials are blended and
suitable for this process. Polyester filaments are processed through step cleaners and lint clean-
cut and opened so that the end product can be ers using equipment similar to that used in cot-
used as polyester stuffing. Carpet waste can be ton gins. Through this process, card waste can
opened up so that it may be used to produce be cleaned up until it can be substituted for a
carpet underlay. Apparel cuttings are processed low grade of cotton usable in mop yarns and
into the raw materials for sound deadening pads other course count yarns. Gin motes are
used in automobiles. Cotton threads are opened handled in the same way.
FIGURE 21.2 Nonwoven mattress pad made of recycled fibers (courtesy of Wellington Sears Utilization Plant).
21.1 Textile Uflste Management 717
The mote waste, the by-product of cotton may hurt and help the environment is the indus-
waste cleaning operation, has been used in trial filters. They are used to reduce pollution,
farming fields by mixing with the soil. Compost which helps the environment. When they are re-
made of recycling waste is an excellent fertilizer placed, they are disposed of in landfills or con-
with good carbon and nitrogen components. fined if they contain noxious or radioactive
Lehner lists the major challenges in recycling substances. This will diminish the landfills.
textile and fiber products as follows [5]: Polymers can be classified as thermoset and
thermoplastic. A thermoplastic material can be
• poorly segregated by-products: This repeatedly heated to its softening point, shaped
occurs when different types of wastes and then cooled to preserve the remolded shape.
are collected and mixed together in a In a thermoset polymer the heating process can-
way that reduces the overall value of the not be repeated due to charring and degrada-
waste. tion. The reason for this behavior is the cross-
• contaminated by-products: When linking which does not exist in thermoplastic
possible, textile waste should not be materials. Examples of thermoplastic materials
mixed with other waste such as metal, are polyester, polyethylene and polypropylene;
wood or cardboard. examples of thermoset materials are nitrile and
• poorly packaged material: Poorly butyl. Technical textiles that are made of ther-
packaged fiber materials in bad bales, moset polymers cannot be remelted for recy-
flimsy cartons, or unmanageable bags cling purposes.
increase the cost of handling and
storage. 5.1 Recycling Technology
perature with liquid nitrogen or other cold tem- changes in the structure of some coated and
perature materials which makes the coatings or laminated fabrics. It is known that some types of
film brittle. Polymers are then broken and sepa- irradiation increase crosslinking in certain
rated. To increase separation efficiency, mechan- polymers. Ice blast is a low-impact surface
ical or ultrasonic vibration is used. scrubbing process that uses phase changes in
rapidly melting ice. When small ice particles,
fired from a nozzle at high speed, hit the sur-
Pyrolysis Kiln face, they melt and transfer energy to the sur-
face. When the surface coating rebounds, it ex-
Pyrolysis is the thermal decomposition of or- plodes outward and the surface is gently
ganic material in an oxygen-deficient environ- cleaned.
ment. This technique has been used for the pro-
duction of fuels and chemicals from organic
feedstocks such as waste tires. The thermal or- 5.2 Recycling of Multi-
ganic reactor uses molten lead in a sealed cham- Component Structures
ber to reduce the organic materials to their or-
ganic residues, without harmful emissions Industrial textile end products are quite often
resulting from incomplete combustion. A con- multi-component structures. Typical products
veyor and filter system separates and removes include tarpaulins, container curtain materials,
the residue, allowing a continual feed process. conveyor belting, foam-laminated textiles, rub-
ber reinforced textiles, membranes, decorative
textiles on rigid moldings, nonwoven products
Powdering (Solid-State Shear Extrusion)
and flocked substrates. For example, textile
composites are made of reinforcement fibers
This method, being developed at the Illinois
and matrix materials. Nylon yarns are inserted
Institute of Technology, uses high pressure at
in the filling direction in polyester paper-
low temperatures to grind the material for fur-
making fabrics for abrasion resistance. A film
ther processing.
with excellent chemical resistance is laminated
to a substrate having good dimensional stability,
Other Recycling Technologies but allows liquid penetration. This pairing usu-
ally requires that different polymers are used
Potential future methods for recycling tech- for substrate and top layer. The more compo-
nology include hydrolysis to monomers, alco- nents are contained in a textile product, the
holysis to monomers, catalysis and biological more difficult it is to recycle it. The success of
separation. a recycling process depends on two criteria [10]:
Hydrolysis and alcoholysis are chemical pro-
• reduction of material vareity: Fewer
cesses used to reduce polymers to their constit-
fiber materials and finishing agents in a
uent monomers. Catalysis uses additives or ac-
textile product make it easier to separate
celerating agents that do not get used up during
the individual components from each
the chemical reaction. Biological organisms can
other and recycle them in a good quality
break down certain synthetic chemicals.
process.
Other longer term potential methods may in-
• reversible manufacturing processes: It is
clude thermal processing, microwave heating,
important that manufacturing processes,
surface heating, gamma irradiation, ice blast,
such as joining and bonding, are
and remanufacturing.
reversible for successful recycling.
In thermal processing, heat is applied to melt
the polymers into their constituent parts. In- Some of the current and possible future recy-
frared heating of the fabric surfaces (surface cling methods for multi-component textile
heating) to loosen the coatings or adhesives may products were reviewed by Ehrler et al. They
prove effective. Gamma irradiation (non- summarize the major steps in recycling of multi-
ionizing radiation) may induce favorable component textile products as follows [11]:
21.1 Textile Ufzste Management 719
(1) Separation-Separation or splitting is the For small dimension items:
treatment by which a bond between two or
(1) Tearing
more materials is removed. During the sep-
aration process, the components should not • principle: tensile force (in association
be destroyed. Mechanical and chemical with local tearing out), shear forces
separation processes are possible. • technique: rag tearing machines
• appraisal: widely used method also
(2) Isolation/fractionation- Following the sep-
used for items of medium size;
aration, the "batch" produced by separation
mechanism is unsatisfactory in
is isolated or fractionated. Criteria influ-
numerous special cases due to
encing isolation include source material,
inadequate clamping action; unsuitable
size and specific gravity.
for textiles containing elastomers
(3) Reclamation
• material reclamation (mechanical (2) Dry milling
processing, melt-down) • principle: impact, shear and bending
• chemical reclamation (alcoholysis, etc.) forces depending on the requirement
• "return to root" reclamation • technique: usually an impact-type
(hydrogenation, gasification) (hammer mill or pinned disc mill)
• heat recovery cutting mill
• appraisal: metal or thermoplastic items
In mechanical separation, the interface of the are troublesome depending on the type
textile composite is overstressed and destroyed of mill
by mechanical forces (tensile, shear, bending,
(3) Abrasion/peeling
impact, compression-decompression and tor-
• principle: shear and bending forces
sion). A pretreatment process can be applied
• technique: peeling machine as used in
before the release process to facilitate the sepa-
the foodstuffs industry
ration. Pretreatment techniques can be low tem-
• appraisal: selective comminution
perature treatment (inducing temporary brittle-
possible, ~epending on product
ness), high temperature treatment (reducing
adhesion), steam infusion and swelling of one of (4) Wet milling
the components. Ehrler et al. suggested the fol- • principle: shear and bending forces
lowing techniques. assisted by swelling
For sheet materials (larger than 0. 3 m2): • technique: beater, pulper
• appraisal: drying necessary, cleaning
(1) Friction calendering usually occurs simultaneously, effluent
• principle: shear forces problems
• technique: calender
• appraisal: only suitable for planar In physicochemical and chemical methods,
items the interface of the multi-component is stressed
and destroyed by causing mutual interaction be-
(2) Brushing technique
tween the components of the material. The phys-
• principle: abrasion, shear and tensile
icochemical processes vary from artificial aging
forces (ripping apart)
of the interface through to its actual integration.
• technique: brushing machine
Different methods can be used for separation.
• appraisal: highly flexible, unsuitable
for three-dimensional items
(3) Hydraulic technique Destruction of the Interface
• principle: hydromechanical forces
applied by high-pressure water jets • principle: infiltration of the bond by
• technique: pump and jet array, pressure agents that destroy the adhesion
range below 100 bar (swelling/dissolving agents)
• appraisal: highly flexible, effluent • technique: impregnation, mechanical
problem due to scouring action separation
720 TEXTILE WASTE MANAGEMENT
pressed to make relatively flat, moderate per- tor, secondary granulator and fines separa-
formance, fiber reinforced plastic panels. tor. The primary granulator reduces the
The Deutsche Forschungsanstalt fur Luft und material size that will pass through a
Raunfahrt (DLR) of Germany has recently in- screen. The particles are then passed over
troduced biodegradable construction materials an agitator bar and advanced to the compac-
called biocomposites that can be recycled as tion chamber. An auger discharges the ma-
well. It was reported that the material can be terial between a rotating and a stationary
used in many cases where glass fiber reinforced disc where the material is forced through
plastics have been used in the past. The biocom- the stationary disk by pressure. The ma-
posites developed by DLR are based on natural terial out of the compactor is air-veyed to
fibers (hemp, flax or ramie) and biodegradable the secondary granulator where it is re-
matrix material. The matrix material can be duced to its final desired particle size. From
polyester, modified cellulose, starches and here it is air-veyed to the fines separation
starch-containing products. It was reported that section.
ramie or flax products achieves 50% of the ri-
(4) Aggregator-extruder combination-This
gidity of glass fiber reinforced plastics, and
system consists of shredder-compactor, ex-
hemp materials as much as 100% [14].
trusion screw, melt filter and pelletizer (or
granulator). The shredder cuts the material
into small lengths. The material is ther-
5.4 Thermoplastic Reclamation
mally compacted. Then the material is
Equipment and Techniques
melted at the extruder. The molten polymer
produced by the extruder is forwarded
Thermoplastic waste recovery systems in-
through a melt filter. The filtered melt is
clude the following [7]:
converted to strands and granulated for very
(1) Chemical depolymerization-In chemical low viscosity materials like nylon and poly-
depolymerization, the waste is converted ester. For materials like PE and PP, hot
back to pure basic raw materials. PET bot- granulation is preferred. The hot granules
tles are recycled with this process. are immediately cooled by a water spray
and taken away to a vibration sieve for dry-
(2) Discontinuous shredder: aggregators-This ing.
type of system generally consists of guillo-
tine, rotary cutter, granulator, pelletizer and
extrusion screw. The guillotine cuts off a
slab of material by its moving blade acting
against its fixed blade. The rotary cutter 6. ENERGY RECOVERY
reduces the tangled web of fibers to much
shorter lengths. The granulator keeps cut- It is possible to burn solid waste in an
ting the fiber until it is small enough to fall environmentally acceptable manner in state-of-
through the screen. The particles can be the-art energy incinerations. After source re-
changed to a greater and uniform bulk den- duction and recovery of economically recycla-
sity if it is composted by a pelletizer. To get ble materials, solid waste incineration of textile
the material into a pellet it is necessary to waste is a vital and attractive alternative.
feed it into an extruder for remelting and Textile materials have excellent waste BTU
cooling. It should be noted that the quality values. Materials that do not contain PVC give
of the thermoplastic suffers from the multi- good energy value when used in an efficient
ple reheating. furnace. For example, polypropylene, a basic
hydrocarbon, has the same heat value as gaso-
(3) Continuous aggregators or friction-disk line. After it gets hot enough, it burns at the
compactors-This system consists of pri- rate of approximately 20,000 BTU/lb of mate-
mary granulator, feeding system, compac- rial [4].
21.1 Textile »aste Management 723
"Closed Loop Recycling of Textile Sizing/De- 2. Explain source reduction. Is "zero waste"
sizing Effluents;' American Dyestuff Re- possible in textiles? Why?
porter, October 1988. 3. Explain the current methods to recycle tex-
tiles.
4. Why is recycling industrial textiles more dif-
ficult than recycling traditional textiles? Ex-
2. REVIEW QUESTIONS plain with examples.
5. Which application area(s) of industrial tex-
1. What are the choices in waste management?
tiles has more potential to use recycled tex-
Explain.
tiles? Give examples.
22.0
COMPUTERS AND AUTOMATION
IN TEXTILES
22.1
Computers and Automation in Textiles
S. ADANUR
bly language still consists of English letters, puters that they can fit in a briefcase. The com-
although the words are abbreviated and may not puter (CPU), monitor and keyboard are all con-
mean anything in English, e.g., CMP for "com- solidated into one piece. Due to size limitation,
pare;' INC for "increase." It is more difficult and the monitor screen is LCD type, i.e., similar to
takes longer to write a program in assembly lan- calculator screens.
guage compared to writing it in a high level lan-
guage. However, the programmer has more Desktop
control over the operation of the computer.
There is no need for "compilation." This also A computer that can physically fit on top of a
makes assembly language a lot faster than the desk. Most of the PCs that are used in offices
corresponding high level language. That is why and at homes are desktop size.
video games, where speed is critical, are writ-
ten in assembly language. Each CPU type has Mini Frame, Midi Frame, Main Frame
its own assembly language.
These terms are used to indicate successively
Machine Language larger host computer systems. Depending on the
size, many personal computers or workstations
This is the language that the CPU can under- are connected to these host computer systems or
stand, i.e., lowest level from the human level. It "frames." In simplistic terms, a Mini Frame may
is made of O's and l's. Although a program can be used to run several computers in an office en-
be written in machine language, it is extremely vironment. A Midi Frame can be used to run
difficult and time consuming for a human to computers in small- to medium-size companies.
write a program in machine language. However, A Main Frame is usually used in large corpora-
machine language gives the full control to the tions, R&D centers and universities where large
programmer and therefore it is very powerful. numbers of computers are used.
In fact one can create new computer commands
by using machine langauge. Super Computers
2.3 Classification of Computers These are extremely fast and powerful main
frames specially built for research purposes.
Personal Computer (PC) The processors in the computers are made of
special type semiconductors. These systems are
A computer that can operate by itself, i.e., very expensive and can only be justifiable for
without being connected to a larger computer institutions such as NASA and big universities.
system or network (of course a PC can be con-
nected to a larger computer system or network). 3. COMPUTER AIDED DESIGN (CAD)
A personal computer has the necessary oper-
ating system software to run itself, therefore it is Computer Aided Design is fast becoming one
self-sufficient. All that is needed to run the of the most used software packages in the indus-
computer is electrical power, a monitor and a try. CAD refers to any activity that utilizes a
keyboard. The two largest personal computer computer to assist in the creation, modification,
manufacturers in the United States and in the presentation and analysis of a design. Typical
world are IBM (International Business Ma- components of a CAD system are computer,
chines) and Apple Computer, Inc. A laptop and monitor, scanner, plotter, printer, and digitizer
a desktop are considered personal computers. as shown in Figure 22 .1.
The three major functions are synthesis, anal-
Laptop ysis and presentation. Synthesis involves mental
processes such as decision making and creativ-
A compact computer that can fit on one's lap. ity. After this process, the object is analyzed,
Laptops are so small compared to other com- evaluated and modified. It is then prepared for
22.1 Computers and Automation in Textiles 733
presentation and approval. Experience has CAD systems is in the design of industrial tex-
shown that the CAD speeds up the engineering tile products. CAD programs can be used to
process. This process takes away the paperwork design and characterize polymer molecules,
that inhibits productivity and creativity. fibers, yarns, fabrics and composites (Figure
CAD's success relies on building blocks that 22.2). In addition to creation of a design on the
have been previously put into the computer. The computer using a software package, designs and
computer programs have been set up to draw on patterns can also be digitized or scanned into
its experience and programs already used. This the computer. Design, development and testing
allows the computers to expand the knowledge of high performance textile structures with
given them and become more useful in future CAD shorten the development time of new, in-
endeavors. novative products. Figure 22.3 shows a plain
Computer aided design and manufacturing is weave structure developed using a computer
more essential for industrial textiles compared aided design system and Figure 22.4 shows a
to consumer textiles. Raw materials that go into fabric pattern developed with a computer.
industrial textiles are more expensive which re- Powerful CAD systems allow modeling of tex-
quires the minimum waste possible. In general, tile structures using engineering principles.
the structures of technical textiles are also more Current technology allows the combination of
complicated than consumer textiles which the power of today's computer capabilities with
makes it a lot more difficult to visualize the fundamental research in fibers, yarns and
structure without a prototype. With computer fabrics in order to model structure of textile
aided design, the correct geometry of the prod- goods and be able to predict their engineering
uct can be modeled on the computer screen properties and performance. CAD of industrial
which helps the designer to modify or change textiles may lead to development of new, in-
the design. Complex computer programs (e.g., novative textile products. Figure 7.38 (Chapter
AutoCAD®, Versa CAD®) have been developed 7.0) shows a typical composite design produc-
in different computer programming languages tion cycle.
(e.g., Basic, FORTRAN, C) for this purpose. Computer modeling of textile structures is
Producers of textile CAD software include needed especially in the industrial high-tech
Modacad, AVL, CDL and others. fabric markets. Industrial textile structures are
subject to significant static and dynamic forces
3.1 Product Design during their end use. There are some mechani-
cal models in technical literature to model
The most important and beneficial use of various textile structures and determine their
FIGURE 22.2 Synthetic polymer molecules designed with computer modeling (courtesy
of Sandia National Labs).
734
22.1 Computers and Automation in Textiles 735
FIGURE 22.4 Fabric pattern developed by a CAD system (courtesy of Johnston Industries).
properties and performance. Modeling of high model and analyze the structures. However,
performance structures must be based on theo- these software packages are written for general
retical and empirical data available in the litera- use and not specifically for textile materials.
ture or through experience. An extensive data Textile materials show non-linear viscoelastic
base should be established for this purpose. behavior which may not be handled by some
CAD of industrial textile products allows the software packages. Moreover, some industrial
manufacturer to visualize the final product even textile structures are highly specialized and
before a decision to produce it is made. As a complicated. Therefore, industrial textile prod-
result, the cost of manufacturing trials and pro- uct manufacturers are usually left with the
totype development could be reduced. CAD choice of developing their own software pro-
helps the companies with quick response to grams for their specific needs. Intense competi-
market needs by reducing the development and tion is another factor that justifies this choice.
manufacturing time of new, innovative high-tech
textile products. The capabilities offered by the 3.2 Product Analysis
CAD systems will help the decision makers
(management and technical personnel) with Various computerized vision systems are com-
modification and improvement of existing mercially available to analyze the structure of
designs and development of new products. fibers, yarns and fabrics. The magnification and
Various software and hardware packages are resolution of these systems depend on the so-
commercially available for CAD. Most of the phistication of the hardware. Figure 22.5 shows
software uses finite element analysis (FEA) to a microvision system.
736 COMPUTERS AND AUTOMATION IN TEXTILES
labor and service facilities used in a factory to Opinions of a user group about their CAD
produce and ship a salable item. A good plant system would be very valuable to make a
layout is an arrangement that permits the prod- decision about that particular system.
uct to be produced with minimum unit cost in (4) Documentation (user manuals)-Con-
the shortest time span. CAD/CAM can be used sidering the high employee turnover in the
in this capacity to design an appropriate layout textile industry, good documentation is es-
that will benefit the plant. This will lead to bet- sential to train the new staff members.
ter space utilization and greater profit for all in- Documentation should be understandable,
volved. It will also allow working with floor easy to follow and complete. It should ex-
plans to let the user get familiar and experiment plain the different functions and tools
with the placement of the machines. available within the program using real ex-
Process layout includes areas that have one amples.
kind of production equipment. CAD is used in
(5) Development-Software is a living thing
this area to put the equipment around on the
and must be continuously developed and
floor to get the most out of its use. The second
updated in order to be viable. A prospec-
type of layout, production layout, is the arrange-
tive buyer should investigate the vendor's
ment of equipment in sequence to make the
software development plans and revenue
product. CAD used in this way allows for the
allocation for that purpose.
most efficient use of an entire plant.
Although the use of CAD and CAM started (6) Focus-It would be wiser to purchase a
earlier, the commercial introduction of CAD/ CAD system from a vendor that focuses
CAM systems for textiles took place at ITMA solely on the development of textile design
'07 in Paris. and manufacturing software. Relatively re-
cent introduction of computer aided de-
3.4 Purchasing a CAD System sign systems to an industry that is well es-
tablished and traditional, necessitates such
Purchasing a CAD system is a strategic deci- a need for specialization.
sion that should be carefully and fully evalu- (7) Flexibility-Since CAD/CAM software
ated. INFO DESIGN suggests ten points to con- for textile design applications is not an off-
sider before purchasing a CAD system [1]. the-shelf item, a vendor should tailor the
software programs to the client's specific
(1) Simplicity-CAD system should be
needs. As the need for new applications
assessed for ease of use which should in-
develops, software modules should be
clude "user friendliness." Some of the added to the system.
other indicators to determine use are the
variety of naturally interactive input de- (8) The user pool-The user pool of a CAD
vices, communication between different system should be as large as possible.
operation formats and easy installation. (9) Service-Before purchasing a CAD sys-
(2) Customer support-It should cover two tem, most companies believe that they will
consecutive and connected periods: 1) be doing the work they were doing before,
from installation through the integration only faster and probably with fewer em-
and 2) technical and commercial mainte- ployees. The reality is that, once the CAD
nance and development thereafter. system is integrated, the companies put
(3) User groups-It would be to the advantage out far more work than before. Therefore,
of a purchaser if a user group is already the vendor should be able to offer assis-
established either by the vendor or by tance and service to their client who may
users of the textile CAD system. A user need more resources in terms of hardware
group meeting is a natural forum to or software.
change ideas and help each other to dis- (10) Resources-It would be wise to purchase
cover the potentials of the CAD system. one of the most successful and widespread
22.1 Computers and Automation in Textiles 739
ciated with machine parameters. Machine data Stocks and inventories are easily managed us-
includes machine running times, details of ing computer assisted stock control systems.
defects, malfunction and waiting times, etc. The Stock control systems can be interfaced with
process and machine data can be stored and ac- production planning and control systems.
cessed via computers built in the machines. The Production planning and stock control sys-
data can be continuously monitored and/or tems are very valuable for the success of Just in
transferred to a master computer for analysis Time (JIT) and Quick Response (QR) systems.
which can be used to optimize machine capacity The JIT system requires having the right quan-
planning and reduce downtime. tity of product, at the right time and in the right
place. The purpose of the QR system is to pro-
4.2 Production Planning and vide fast flow of information from raw material
Control Systems supplier to the consumer. Reduction of cycle
(delivery) time of a product is shortened with
Production planning and control systems are the QR system.
designed to help the managers and planners. Figure 22.9 shows schematics of an inte-
They are usually part of the Management Infor- grated production control system to control the
mation Systems (MIS). MIS focuses on macro- entire process in a weaving mill. Figure 22.10
level performance and valuation monitoring. shows the central control room of a modern
Production planning and control systems are spinning mill with CIM. A central computer
used to integrate planning, control and execu- directly monitors state-of-the-art equipment.
tion of manufacturing processes. Production
planning and control systems allow planning of
quantities, checking delivery dates, monitoring 5. EXPERT SYSTEMS
order progress, materials management, capac-
ity planning and scheduling. Process and Expert systems are computer programs based
machine data provide the necessary input for on scientific information systems in which the
production planning and control systems. empirical and theoretical knowledge of experts
SICOM TCCS
000
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(
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$
000
880
eeo
880
800
FIGURE 22.9 Schematic of an integrated production control system in a weaving mill (courtesy of Tsudakoma).
741
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22.1 Computers and Automation in Textiles 743
744
23.0
STANDARDS AND REGULATIONS
23.1
Standards and Regulations
S. ADANUR
ment to record all changes and decisions. The ity assurance in design/develop-
unwritten rule concerning the application of ment, production, installation
ISO 9000 is that if all personnel were suddenly and servicing
replaced, the new people, properly trained, ISO 9002: Quality Systems-Model for qual-
could use the documentation to continue mak- ity assurance in production and
ing the product or providing the services as installation
before. ISO 9003: Quality Systems-Model for qual-
ISO 9000 standards were developed by the ity assurance in final inspection
ISO Technical Committee 176 (ISO TC 176). and testing
The committee was formed in 1980 and issued ISO 9004: Quality management and quality
the first ISO 9000-9004 series of standards in system elements
1987. The standards are reviewed and updated if Guidelines for interpretation of the
necessary, every five years. standards
2.1 Contents of ISO 9000 Series Figure 23.1 shows the relationships among
the ISO standards. ISO 9001 contains all the re-
As mentioned earlier, the ISO series is made quirements in ISO 9002 which, in turn, con-
up of five standards. ISO 9000 (Q90), the first tains all the requirements in ISO 9003.
standard in the series, is the road map for ISO 9001 is a quality system model for quality
understanding the rest of the series and provides assurance in design, development, production,
key quality definitions. This helps an organiza- installation and servicing. It is like a contract
tion to choose which contractual standard between supplier and customer that demon-
(9001, 9002 or 9003) is best suited for their strates the supplier's capabilities in the above
business. Each element of the ISO 9000 series areas. This is the highest ISO qualification an
is suitable for a different type of business: organization can have. It addresses all of the op-
erations that affect the quality or fitness for use
ISO 9000: Quality management and quality of a good or service. The elements of ISO 9001
assurance standards are shown in Table 23.1 along with 9002 and
Guidelines for selection and use 9003.
ISO 9001: Quality Systems-Model for qual- ISO 9002 is a quality system model for qual-
FIGURE 23.1 ISO 9000 standards (courtesy of DuPont ISO 9000 Services).
23.1 Standards and Regulations 7 49
TABLE 23.1 The Elements of ISO 9001-9003 Systems (courtesy of DuPont ISO 9000 Services).
1. Management responsibility X X X
2. Quality system X X X
3. Contract review X X
4. Design control X
5. Document control X X X
6. Process control X X
7. Purchasing X X
8. Purchaser supplied product X X
9. Product identification traceability X X X
I0. Inspection and testing X X X
11. Inspection, measuring and test equipment X X X
12. Inspection and test status X X X
13. Control of non-conforming product X X X
14. Corrective action X X
15. Handling, storage, packaging and delivery X X X
16. Quality records X X X
17. Internal quality audits X X
18. Training X X X
19. After-sales servicing X
20. Statistical techniques X X X
FIGURE 23.2 Global impact of ISO 9000 (Sources: DuPont, Robert Peach & Associates, 1994).
the customer directly audits the supplier. Ex- certain criteria, and if appropriate, accredits
perience showed that an impartial third party that registrar to audit companies against the ISO
audit was the best. Just as companies require an 9000 standards. The RAB publishes a directory
impartial auditor to examine financial systems, of accredited registrars and a directory of sup-
a third party auditor should assess quality plier companies registered by accredited regis-
systems. Therefure, today, a company who trars.
wants to get registered for ISO 9000 must be
certified by an accredited registrar agency. This
2.3 ISO 9000 Registration Process
is called registration by a third party and is
shown in Figure 23.3.
There are several action steps that need to be
Each registrar is accredited by a national ac-
completed before the ISO registration. These
creditation body. In the United States, the
can be summarized as follows:
~erican National Accreditation Program for
Registrars of Quality Systems" is established by • Implementation must start at the top
the ANSI and the Registrar Accreditation Board management level with complete
(RAB, an affiliate of the American Society for commitment.
Quality Control) for accrediting registrars of • Obtain all of the information possible on
quality systems. The operation of the program is the ISO requirements from standards
administered by the RAB. The RAB examines a organization, and others who have
registrar's procedures and performance against already been through the process.
FIGURE 23.3 Third party registration (courtesy of DuPont ISO 9000 Services).
23.1 Standards and Regulations 751
• Define the scope and choose which ISO of about ten to fourteen months. It is estimated
certification best suits your organization. that one mean-year of preparation time is re-
• Assemble a steering committee and quired per 100 employees. The average cost of
develop action plans. registration is $20,000-25,000, plus preparation
• Select an ISO registrar to register the costs that depend on how well the existing qual-
organization with an application. ity system is developed. Training costs are not
• Confirm scope and chosen ISO included in this estimation. After registration,
qualification with registrar. there will be surveillance twice a year and re-
• Train employees and spell out exactly certification every three years, each of which
what is expected from them. requires additional expenses. The first pass rate
• Assess the organization's current quality for companies is around 30%. Figure 23.5
programs against the chosen ISO quality shows typical audit results for deficiencies.
system.
• Record and update the existing quality
system in a quality manual. Assemble
all other documentation. 3. ASSOCIATIONS FOR STANDARDS,
• Send a copy of the quality manual to the REGULATIONS, AND SPECIFICATIONS
registrar for inspection.
• Be audited by the registrar; take The following organizations can provide
corrective measures based on findings copies, information and/or assistance on re-
by the registrar's audit team. vised/draft/current/new standards, guides, cata-
• Final visit by the registrar and official logs, indices, publications and related docu-
certification. ments.
These steps may differ slightly from registrar
to registrar. DuPont Quality Management and • American Association of Textile
Technology Center (QM&lC) identifies nine Chemists and Colorists (AA1CC)
basic milestones and related activities that must P.O. Box 12215
be completed as shown in Figure 23.4. Research Triangle Park, NC Z7709
The registration process will have a duration USA
REGISTRATION
0
NOTE: The 12 month timefine represents an approximation
The actual time required to attain quality system registration
depends on the initial status of the quality system. the
presence of management commitnet, and the degree of
0 CONTINUOUS
' IMPROVEMENT
involvement of every member of the organization.
0
• 1
Contmued
Internal Aud1ts,
CorrectiVe
Actions.
Management
Reviews, and
Surveillance
Audits
0
INTERNAL
AUDITS BEGIN • Corrective
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MANAGEMENT Af~d;~a,~r : Circulate & 1 Management
REPRESENTATIVE Compliance 1 p':gf~~~~es , ReVIew#1
STEERING GROUP Audit #1 , . , 1
AREA Provide Trammg Submit Manual :
FIGURE 23.4 Roadmap to ISO 9000 registration (courtesy of DuPont ISO 9000 Services).
752 STANDARDS AND REGULATIONS
2% 3o/o
1o/o •
II
statistics
process control
II non-conforming products
m1 product identification
D SOP missing/Incorrect
15% 4°/o
•m quality records
training
BD inspection and test standardj;
6% ~ document control
D corrective action
•
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754
24.0
FUTURE OF INDUSTRIAL TEXTILES
24.1
Future of Industrial Textiles
S. ADANUR
Airbag 4 7 12 20 32
Architectural fabrics 3 3 3.25 3.5 3.7
Automotive 285 290 300 292 347
Awning and canopies 19 19.5 19.5 20 22
Banners and flags 9 10 11 13 15
Casual furniture 49 50 50 50 52
Geosynthetics 360 380 400 435 466
Marine products 19 18 18.5 19.2 17
Medical (in billions of sq. yards) 2.1 2.3 2.4 2.6 2.8
Safety and protective 225 250 275 300 322
Single-ply roofing 115 110 110 115 117
Tarpaulin 105 110 110 112 113
Tent and tent rental 10 10 10 10.5 11
Another growth area in industrial textiles will shape. The polymer's shape memory properties
be "environmentally friendly" materials. Cur- can be tailored for various applications by for-
rently, there is extensive research in this area mulating the polymer for a specific T8 (to
to develop high performance "biodegradable" within 1°F) over a wide range (- 30°F to
fibers. Regulations to protect the environment + 158°F).
will continue to play a major role for the efforts Mitsubishi combined its shape memory poly-
in this area. In fact, some believe that in the mer with Komatsu Seiren's polymer coating
future, products that cannot be recycled or are technology to make "dream cloth." It is claimed
non-biodegradable may not be allowed for pro- that the dream cloth polymer molecule stretches
duction through regulation. and shrinks in response to temperature; similar
to the body skin, the cloth opens when hot and
closes when cold. Therefore the breathability of
2. SMART MATERIALS the fabric changes. Possible application areas
include skiwear and other sportswear.
If the patent literature is any indication, one Research is being done on photochrornic ma-
potential future growth area is "smart materials" terials. A material whose absorption spectrum
or "intelligent materials." A smart polymer or changes when it is irradiated with light and
material can be described as a material that will reverts to its initial state upon cessation of ir-
change its characteristics according to outside radiation is called a photochromic material.
conditions or a stimulus [3]. This is a relatively These types of polymers are already available.
new area and deserves some attention. A possible application of photochromic poly-
Mitsubishi developed a Shape Memory Poly- mers is the fabrics that change their color ac-
mer (SMP) which is a thermoplastic polyure- cording to the weather and intensity of light.
thane with "elastic memory:' When the polymer This, in turn, changes the reflectance properties
part is heated above its glass transition- of the fabric.
temperature (Tg) but below its melting temper- Resistively shunted piezocerarnic fibers used
ature (Tm), it changes from a rigid, glassy state as reinforcement in a structural composite ma-
to a rubbery state at which it is highly flexible terial offer the potential to significantly increase
and pliant. This allows it to be deformed to a vibration damping capability.
new shape that can be "frozen" in by cooling In general, polymers do not conduct electric-
below the T8 • If the part is subsequently heated ity, which has been an advantage in many appli-
above the T8 , the polymer will "remember" its cations. However, within the last twenty years,
original shape and spontaneously return to that research has been done to develop a new class of
24.1 Future of Industrial Textiles 759
organic polymers with the ability to conduct soldier's position to the enemy. The size and
electrical current. If these conductive polymers location of a wound could also be determined
would be used in fibers and fabrics, the electri- from a distance. The timing is critical to save a
cal and mechanical properties of the fabric could wounded soldier's life.
be changed. For example, the color of fubric Polymers are suitable to develop biologically
may be changed by use of a small battery that active materials. Biologically active textile ma-
would be invaluable for military applications. terials are antibacterial, antifungal, anticancer,
Another research area for military fabrics is X-ray active, insecticidal, anti-inflammatory,
"adaptive camouflage" fabrics. Color control in anesthetic, antivirus, antioxidant, fermentative
a fabric could be achieved by using hollow active, hemadilutative, immunodepressant, etc.
fibers using a principle called electrophoresis. Extensive research was done in the former So-
The fibers, with the diameter of human hair, vient Union in these areas.
would be filled with electrically charged par-
ticles of paint pigment suspended in a different
colored dye .. Different combinations of pig- 3. CONCLUSIONS
ments and dyes would be used in the same uni-
form. The color combination would be con- In the United States alone there are approx-
trolled by moving the solid pigment toward and imately 30,000 patents granted for polymers.
away from the outer surface of the fabric so that Combined with virtually endless possibilities of
a viewer would see either the paint color or the fiber and fabric structures and ever-advancing
dye color at any one time. manufacturing technologies, development of
Research is also being done to develop fabrics products with custom tailored properties for any
that would allow medical teams to pinpoint type of application will be limited only by hu-
wounded soldiers on the battlefield. The fabric, man imagination. Industrial textiles will con-
woven with metallic fibers, would emit low- tinue their growth and penetrate in almost every
intensity signals when ripped. These signals other non-textile industry. Industrial textiles can
would be strong enough to be detected by a only increase their presence in mankind's jour-
friend but not strong enough to give away the ney in the years to come.
24.2
References and Review Questions
1. Strzetelski, A., "Here Comes the Future;' 1. What is the definition of a "smart material"?
Industrial Fabric Products Review, January What are its characteristics?
1995. 2. A densely woven cotton fabric swells in the
2. Hall, D. M., private communication. rain and becomes an even more dense or
3. Hongu, T. and Phillips, G. 0., New Fibers, tight structure. This, in turn, causes the
Ellis Harwood, 1990. fabric to resist further water or rain penetra-
tion. Should, therefore, a fabric made of cot-
ton be considered a smart structure? Why?
3. What are the possible development areas of
industrial textiles in the future? Discuss your
predictions.
760
Appendix 1
Air, Tent, and Tensile Structures-
Fabric Specification Table
This table was originally published in Fabrics and 1. Distributed by the Astrup Co.
Architecture, Specguide 1995, November-December, 2. The Awntop line includes multiple products.
1994 by the Industrial Fabrics Association Interna- When a range of values is given, it reflects the
tional (IFAI). values of the entire product line.
3. FED-STD-191 (5041).
Disclaimer statement: 4. Distributed by MacKellar Associates.
')\Jl information included in the table was submitted 5. Overlapping weld after grinding.
by the IFAI Awning Division member firms. The spe- 6. Regional, national and international distribu-
cifications were submitted voluntarily and their ac- tion.
curacy is the responsibility of the manufacturer. This 7. The material is ultraviolet protected, anti-
table is not an endorsement of a company or product mildew, wicking resistant, and topside acrylic
by Fabrics & Architecture, the Awning Division, or coated for reinforced abrasion and easy clean-
IFAI. The reader is encouraged to contact the compa- ing.
nies directly for further information." 8. Tenara fabric is woven by C. Cramer & Co.
9. The polyester material is Hoechst Trevira, a
Footnotes: registered trademark of Hoechst A.G.
NA Information not available or not provided. 10. FED-STD-191 (5134) modified.
761
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1\)
Architent Architent
Trade Name: 8028 9032 Air Tite 1528 Architent Blackout Wideside
Trade name owner Seaman Corp. Seaman Corp. Erez Thermoplastic Herculite Products Herculite Products 1 Herculite Products
Base fabric
Material Polyester Polyester Polyester Polyester Polyester Polyester
Weight 7.5 oz/yd 2 10 oz/yd 2 8.9 oz/yd 2 NA NA NA
Weave style NA NA Weft insertion NA NA NA
Yam count (warp, fill) NA NA 120, 188 tpi NA NA NA
Coating
Material Vinyl Vinyl Vinyl Vinyl laminate Vinyl laminate Vinyl laminate
Weight (top, bottom) NA NA 10.9, 9.4 oz/yd2 NA NA NA
UV topcoat material NA NA Acrylic or PVFD NA NA NA
UV topcoat weight NA NA NA NA NA NA
Finished fabric
Test method NA NA ASTM D 3776 NA NA NA
Thickness NA NA NA NA NA NA
Weight NA NA 28-29 oz/yd 2 14 oz/yd 2 16 oz/yd2 10 oz/yd2
Roll width, usable 56 in 56 in 71-73 in 61 in 61 in 90 in
Tongue tear (warp, fill) 275, 275 lb/in 300, 300 lb/in 315, 280 lb/in 115, 125 lb/in 140, 165 lb/in 30, 35 lb/in
Test method FED-STD-191 FED-STD-191 ASTM D 2261 FED-STD-191 FED STD-191 FED-STD-191
(5134) (5134) (5134) (5134) (5134)
Trapezoidal tear
(warp, fill) 85, 85/lb/in 140, 140 lb/in 80, 60 lb/in NA NA NA
Test method FED-STD-191 FED-STD-191 ASTM D1117 NA NA NA
(5136) (5136)
Grab tensile (warp, fill) 700, 700 lb/in 840, 840 lb/in 670, 620 lb/in 240, 215 lb/in 250, 220 lb/in 115, 115 lb/in
Test method FED-STD-191 FED-STD-191 ASTM D 751 FED-STD-191 FED-STD-191 FED-STD-191
(5100) (5100) (5100) (5100) (5100)
Strip tensile (warp, fill) 515, 515 lb/in 650, 650 lb/in 440, 405 lb/in NA NA NA
Test method FED-STD-191 FED-STD-191 ASTM D 751 NA NA NA
(5102) (5102)
Architent Architent
Trade Name: 8028 9032 Air Tite 1528 Architent Blackout Wideside
Architent Architent
Trade Name: 8028 9032 Air Tite 1528 Architent Blackout Wideside
Seams (recommended
style) Lap or butt Lap or butt NA NA NA NA
Construction method Heat sealed Heat sealed NA Heat sealed or Heat sealed or Heat sealed or
sewn sewn sewn
Usefiil temperature
range NA NA -10-150°F NA NA NA
Dead load, seams, warp/
fill
Inch seam@ F 2 in@ room 2 in@ room NA NA NA NA
temp. temp.
lb/in warp/lb/in fill 266 lbs 266lbs NA NA NA NA
Inch seam@ F 2 in@ 160°F 2 in@ 160°F NA NA NA NA
lb/in warp/lb/in fill 133 lbs 133 lbs NA NA NA NA
Structural properties
Effect. modulus,
warp, fill NA NA NA NA NA NA
Poisson's ratio,
warp/fill NA NA NA NA NA NA
Poisson's ratio,
fill/warp NA NA NA NA NA NA
Shear modulus NA NA NA NA NA NA
Stretch properties NA NA NA NA NA NA
Uniaxial, warp NA NA NA NA NA NA
Uniaxial, fill NA NA NA NA NA NA
Biaxial, warp (1:1) NA NA NA NA NA NA
Biaxial, fill (1: 1) NA NA NA NA NA NA
Mil spec/Fed spec # NA NA NA NA NA NA
Recommended uses Air and Air and Architectural NA NA NA
tension tension structures
structures structures
KWB-22 KWN-18
Trade Name: Awntopl Calliope Gala Tentage (Blackout) (Non-Blackout)
Trade name owner Duracote Corp. Graniteville Co. Graniteville Co. 1 Super Tex Super Tex
Base fabric
Material Polyester Polyester Cotton Polyester Polyester
Weight 2.7 oz/yd2 NA NA NA NA
Weave style Weft inserted 2 ply plain weave Army duck Weft inserted Weft inserted
Yarn count
(warp, fill) 9, 9 tpi NA NA 18, 18 tpi 18, 18 tpi
Coating
Material Vinyl Pigmented vinyl resin Flame-retardant vinyl Vinyl coated Vinyl coated
Weight (top, bottom) 4-7, 5-7 oz/yd 2 NA NA NA NA
UV topcoat material None NA NA NA NA
UV topcoat weight NA NA NA NA NA
Finished fabric
Test method FED-STD-191 (5041) FED-STD-191 FED-STD-191 NA NA
Thickness NA NA NA NA NA
Weight 13-18 oz/yd 2 12.5 oz/yd2 3 12.5 oz/yd2 22 oz/yd 2 22 oz/yd2
Roll width, usable 61 in 60 in 31 in 61-81 in 61-81 in
Tongue tear
(warp, fill) 100, 105 lb/in 22, 19 lb/in 5.0, 7.0 lb/in 200, 180 lb/in 200, 180 lb/in
Test method ASTM D 2262 (8 in) FED-STD-191 (5134) FED-STD-191 (5134) FED-STD-191 (5134) FED-STD-191 (5134)
Trapezoidal tear
(warp, fill) 40, 30 lb/in NA NA NA NA
Test method ASTM D 1117 NA NA NA NA
Grab tensile
(warp, fill) 250-265, 225-240 500, 391 lb/in 160, 145 lb/in 280, 260 lb/in 280, 260 lb/in
lb/in
Test method ASTM D 5034 FED-STD-191 (5100) FED-STD-191 (5100-1) FED-STD-191 (5102) FED-STD-191 (5102)
Strip tensile
(warp, fill) 160-180, 140-155 NA NA NA NA
lb/in
Test method ASTM D 5304 NA NA NA NA
........
0>
(J1 (continued)
......
m
m
KWB-22 KWN-18
Trade Name: Awntop Calliope Gala Tentage (Blackout) (Non-Blackout)
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Trade name owner Super Tex Graniteville Co. 1 Snyder Mfg. Snyder Mfg. Snyder Mfg. Snyder Mfg.
Inc. Inc. Inc. Inc.
Base fabric
Material Polyester Polyester/cotton Polyester Polyester Polyester Polyester
Weight NA NA NA NA NA NA
Weave style Weft inserted Plain weave NA NA NA NA
Yam count
(warp, fill) 18, 18 tpi NA NA NA NA NA
Coating
Material Vinyl coated Pigmented vinyl Vinyl Vinyl Vinyl Vinyl
coat.
Weight (top, bottom) NA NA NA NA NA NA
UV topcoat material NA NA NA NA NA NA
UV topcoat weight NA NA NA NA NA NA
Finished fabric
Test method NA FED-STD-191 FED-STD-191 FED-STD-191 FED-STD-191 FED-STD-191
(5041) (5041) (5041) (5041)
Thickness NA NA NA NA NA NA
Weight 22 oz/yd2 11 oz/yd 2 13 oz/yd 2 14 oz/yd2 16 oz/yd2 16 oz/yd 2
Roll width, usable 61-81 in 60 in 61 in 61 in 61 in 61 in
Tongue tear (warp, fill) 200, 180 lb/in 8.5, 7.5 lb/in 50, 60 lb/in 30, 30 lb/in 55, 63 lb/in 85, 85 lb/in
Test method FED-STD-191 FED-STD-191 FED-STD-191 FED-STD-191 FED-STD-191 FED-STD-191
(5134) (5134) (5134) (5134) (5134) (5134)
Trapezoidal tear
(warp, fill) NA NA NA NA NA NA
Test method NA NA NA NA NA NA
Grab tensile (warp, fill) 280, 260 lb/in 145, 145 lb/in 220, 200 lb/in 140, 125 lb/in 230, 205 lb/in 320, 300 lb/in
Test method FED-STD-191 FED-STD-191 FED-STD-191 FED-STD-191 FED-STD-191 FED-STD-191
(5102) (5100-1) (5100-1) (5100-1) (5100-1) (5100)
KWN-22 PRV 1310Q PRV 1444K PRV 16100 PRV 1613W
Trade Name: (Non-Blackout) Polaris Tentage Weatherspan FR Klearspan Weatherspan 61" Gloss
Strip tensile (warp, fill) NA NA 160, 140 lb/in 85, 85 Jb/in 164, 145 lb/in 225, 210 lb/in
Test method NA NA FED-STD-191 FED-STD-191 FED-STD-191 FED-STD-191
(5304.1) (5304-1) (5304-1) (5304)
Adhesion 10 lb/in NA 26 1b/in 20 lb/in 26 lb/in 25 lb/in
Test method FED-STD-191 NA FED-STD-191 FED-STD-191 FED-STD-191 FED-STD-191
(5970) (5970) (5970) (5970) (5970)
Hydrostatic resistance NA 35 em 345 psi 200 psi 360 psi 425 psi
Test method NA FED-STD-191 FED-STD-191 FED-STD-191 FED-STD-191 FED-STD-191
(5514) (5512) (5512) (5512) (5512)
Cold crack Pass -40°F NA Pass -40°F Pass -30°F Pass -40°F Pass -40°F
Test method Mii-C-20696 NA FED-STD-191 FED-STD-191 FED-STD-191 FED-STD-191
(5874) (5874) (5874) (5874)
Burning characteristics
Test method(s) CSFM CSFM, CPAI-84 NA NA NA NA
2-s flame-out
Light values
Test method NA NA NA NA NA NA
Transmission, ref!.,
absorp. NA NA NA NA NA NA
Acoustical properties
Test method NA NA NA NA NA NA
Sound transmission NA NA NA NA NA NA
Sound absorption NA NA NA NA NA NA
Coefficient of thermal
expansion/contraction NA NA NA NA NA NA
Test method NA NA NA NA NA NA
(continued)
.......
m
c.o
-....!
-....!
0
Seams (recommended
style) NA NA NA NA NA NA
Construction method NA Sewn NA NA NA NA
Useful temperature
range NA NA NA NA NA NA
Dead load, seams,
warp/fill
Inch seam@ F NA NA NA NA NA NA
lb/in warp/lb/in fill NA NA NA NA NA NA
Inch seam@ F NA NA NA NA NA NA
lb/in warp/lb/in fill NA NA NA NA NA NA
Structural properties
Effect. modulus,
warp, fill NA NA NA NA NA NA
Poisson's ratio,
warp/fill NA NA NA NA NA NA
Poisson's ratio,
fill/warp NA NA NA NA NA NA
Shear modulus NA NA NA NA NA NA
Stretch properties NA NA NA NA NA NA
Uniaxial, warp NA NA NA NA NA NA
Uniaxial, fill NA NA NA NA NA NA
Biaxial, warp (1:1) NA NA NA NA NA NA
Biaxial, fill ( 1: 1) NA NA NA NA NA NA
Mil spec/Fed spec # NA NA NA NA NA NA
Recommended uses Tension Sidewalls, tops NA NA NA NA
structures, on family
non-blackout cabin,
scouting tent
PRV 2213W Precontraint 702 Precontraint 1002 Precontraint 1202 Precontraint 1502
Trade Name: Twin Color Precontraint 392 Opaque Fluotop S Fluotop T Fluotop T
Trade name owner Snyder Mfg. Ferrari4 Ferrari4 Ferrari4 Ferrari 4 Ferrari4
Inc.
Base fabric
Material Polyester Hi. ten. polyester Hi. ten. polyester Hi. ten. polyester Hi. ten. polyester Hi. ten. polyester
Weight NA NA NA NA NA NA
Weave style NA Mesh fabric NA NA NA NA
Yarn count
(warp, fill) NA NA NA NA NA NA
Coating
Material Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl
Weight (top, bottom) NA NA NA NA NA NA
UV topcoat material NA NA NA Fluotop S Fluotop T Fluotop T
UV topcoat weight NA NA NA NA NA NA
Finished fabric
Test method FED-STD-191 NA NA NA NA NA
(5041)
Thickness NA NA 240-micron top 350-micron top NA NA
coating coating
Weight 22 oz/yd2 25 oz/yd2 22 oz/yd 2 31 oz/yd2 37 oz/yd2 43 oz/yd 2
Roll width, usable 61 in 71 in 71 in 71 in NA NA
Tongue tear (warp, fill) 95, 95 lb/in NA NA NA NA NA
Test method FED-STD-191 NA NA NA NA NA
(5134)
Trapezoidal tear
(warp, fill) NA 86, 84 lb/in 53, 38 lb/in 74, 73 lb/in 153, 131 lb/in 157, 151 lb/in
Test method NA FED-STD-191 FED-STD-191 FED-STD-191 FED-STD-191 ASTM D 1117
(5136) (5136) (5136) (5136)
Grab tensile (warp, fill) 315, 305 lb/in NA 445, 440 lb/in 735, 705 lb/in 945, 930 lb/in 1300, 1200 lb/in
Test method FED-STD-191 NA FED-STD-191 FED-STD-191 FED-STD-191 FED-STD-191
(5100.1) (5100) (5100) (5100) (5100)
.....
..... (continued)
.....
.......
.......
N
PRV 2213W Precontraint 702 Precontraint 1002 Precontraint 1202 Precontraint 1502
Trade Name: Twin Color Precontraint 392 Opaque Fluotop S Fluotop T Fluotop T
Strip tensile (warp, fill) 235, 200 lb/in 310, 360 lb/in 320, 285 lb/in 440, 435 lb/in 600, 565 lb/in 917, 831 lb/in
Test method FED-STD-191 FED-STD-191 FED-STD-191 FED-STD-191 FED-STD-191 FED-STD-191
(5304.1) (5102) (5102) (5102) (5102) (5102)
Adhesion 20 lb/in 18 lb/2 in 22 1b/2 in 26 lb/2 in 26 lb/2 in NA
Test method FED-STD-191 NFG 31107 NFG 31107 NFG 31107 NFG 31107 NA
(5970) (France) (France) (France) (France)
Hydrostatic resistance 525 NA NA NA NA NA
Test method FED-STD-191 NA NA NA NA NA
(5512)
Cold crack Pass -40°F NA NA NA NA NA
Test method FED-STD-191 NA NA NA NA NA
(5874)
Burning characteristics
Test method(s) NA NFPA-701 NFPA-701, CSFM NFPA-701, CSFM NFPA-701, CSFM NFPA-701
Light values
Test method NA ASHRAE 74-73 NA NA NA NA
Transmission, refl.,
absorp. NA 26%, 59%, 15% NA NA NA NA
Acoustical properties
Test method NA NA NA NA NA NA
Sound transmission NA NA NA NA NA NA
Sound absorption NA NA NA NA NA NA
Coefficient of thermal
expansion/contraction NA NA NA NA NA NA
Test method NA NA NA NA NA NA
Seams (recommended
style) NA NA Overlapping weld Overlapping weld NA Overlapping weld5
Construction method NA NA HF welded HF welded NA HF welded
Useful temperature
range NA NA NA NA NA NA
PRV 2213W Precontraint 702 Precontraint 1002 Precontraint 1202 Precontraint 1502
Trade Name: Twin Color Precontraint 392 Opaque Fluotop S Fluotop T Fluotop T
-....!
-....!
(...)
~
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Trade Name: Softglassll, 200 Softglassll, 500 Softglassll, 600 Startire Sunbrella Sunbrella Firesist
Trade name owner DCI Inc. DCI Inc. DCI Inc. The Astrup Co. Glen Raven Mills6 Glen Raven Mills 6
Base fabric
Material Fiberglass fabric Fiberglass fabric Fiberglass fabric Polyester /cotton Solution-dyed Modacrylic
acrylic
Weight 7 oz/yd2 12 oz/yd 2 18 oz/yd2 8 oz/yd2 9.25 oz/yd2 9.25 oz/yd2
Weave style Plain Plain ZENDPlain Army duck Plain weave Plain weave
Yarn count (warp, fill) 44, 22 tpi 28, 20 tpi 27, 14 tpi 51, 40 tpi 75, 35 tpi 75, 35 tpi
Coating
Material Silicon Silicon Silicon Vinyl impregnated Resin and water Resin and water
repell. repell.
Weight (top, bottom) 4, 4 oz/yd2 6, 6 oz/yd 2 9, 9 oz/yd 2 NA NA NA
UV topcoat material NA NA NA NA NA NA
UV topcoat weight NA NA NA NA NA NA
Finished fabric
Test method FED-STD-191 FED-STD-191 FED-STD-191 FED-STD-191 Hydr. press. Hydr. press.
(5041) (5041) (5041) AATCC127 AATCC127
Thickness 12 mil 17 mil 35 mil NA NA
Weight 15 oz/yd2 24 oz/yd 2 35 oz/yd2 NA 9.25 oz/yd2 9.25 oz/yd2
Roll width, usable 60 in 96, 60 in 96, 60 in NA 46, 60 in 60 in
Tongue tear (warp, fill) NA NA 55, 70 lb/in NA 13.5, 8. 7 lb/in 15, 9 lb/in
Test method NA NA NA FED-STD-191 ASTM D 2262-83 ASTM D 2262-83
(5134)
Trapewidal tear
(warp, fill) 25, 30 lb/in 40, 45 lb/in 55, 70 lb/in NA NA NA
Test method FED-STD-191 FED-STD-191 FED-STD-191 NA NA NA
(5136) (5136) (5136)
Grab tensile (warp, fill) NA NA NA NA 250, 151 lb/in 280, 160 lb/in
Test method NA NA NA FED-STD-191 ASTM D 1682-64 ASTM D 1682-64
(5100)
Trade Name: Softglassll, 200 Softglassll, 500 Softglassll, 600 Starfire Sunbrella Sunbrella Firesist
Strip tensile (warp, fill) 200, 200 lb/in (min) 540, 420 lb/in 650, 575 lb/in NA NA NA
Test method FED-STD-191 FED-STD-191 FED-STD-191 NA NA NA
(5102) (5102) (5136)
Adhesion NA NA NA NA NA NA
Test method NA NA NA NA NA NA
Hydrostatic resistance NA NA NA NA NA NA
Test method NA NA NA FED-S-191 NA NA
(5514/5516)
Cold crack -30°F -30°F -30°F NA NA NA
Test method Fabricator Fabricator Fabricator NA NA NA
Burning characteristics
Test method(s) ASTM E 84, E 108, ASTM E 84, ASTM E 84, FED-STD-191 Not flame NFPA-701
E 136, UL-94, E 108, E 136, E 108, E 136, (5903), CSFM, retardant
NFPA-701 UL-94, UL-94, MVSS-302,
NFPA-701 NFPA-701 NFPA-701
(small sc.)
Light values
Test method ASTM E 124 ASTM E 124 ASTM E 124 NA NA NA
Transmission, refl., 32%, 55%, NA 25%,60%, NA 18%, 65%, NA NA NA NA
absorp.
Acoustical properties
Test method NA NA NA NA NA NA
Sound transmission NA NA NA NA NA NA
Sound absorption NA NA NA NA NA NA
Coefficient of thermal
expansion/contraction NA NA NA NA NA NA
Test method NA NA NA NA NA NA
Seams (recommended
style) Lap joint Lap joint Lap joint NA Lap Lap
Construction method Chemically bonded Chemically Chemically Sewn Heat sealed or Heat sealed or
bonded bonded sewn sewn
.......
....... (continued)
C1l
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(J) I Trade Name: Softglassll, 200 Softglassll, 500 Softglassll, 600 Starfire Sunbrella Sunbrella Firesist
Seams (recommended
style) (continued)
llseful temperature
range 80-150°F 80-150°f 80-150°F NA NA NA
Dead load, seams,
warp/fill
Inch seam@ F 3 in seam @ 180°F 3 in seam@ 3 in seam@ NA NA NA
180°f 180°F
lb/in warp/lb/in fill 150 lb/in/130 lb/in 180 lb/in/ 200 lb/in/ NA NA NA
130 lb/in 180 lb/in
Inch seam@ F 3 in seam @ 70°F 3 in seam@ 3 in seam@ NA NA NA
70°F 70°F
lb/in warp/lb/in fill 150 lb/in/130 lb/in 240 lb/in/ 270 lb/in/ NA NA NA
220 lb/in 240 lb/in
Structural properties
Effect. modulus,
warp, fill NA NA NA NA NA NA
Poisson's ratio,
warp/fill NA NA NA NA NA
Poisson's ratio,
fill/warp NA NA NA NA NA NA
Shear modulus NA NA NA NA NA NA
Stretch properties NA NA NA NA NA NA
llniaxial, warp 0.5% @ 20 lb/in NA NA NA 1% @ 40 lb/in NA
llniaxial, fill 1-2% @ 20 lb/in NA NA NA 3.5% @ 40 lb/in NA
Biaxial, warp (1:1) -0.25%@ -0.3%@ -0.2%@ NA NA NA
20 lb/in 20 lb/in 20 lb/in
Biaxial, fill ( 1: 1) 2% @ 20 lb/in 2% @ 20 lb/in 1.8% @ NA NA NA
20 lb/in
Mil Spec/Fed spec # NA NA NA NA NA NA
Recommended uses Skylights, green- Skylights, Tensile struc- Tents, canopies, NA NA
houses, acoustic greenhouses, tures, cable awning, ban-
liners, awning tensile domes ners, boat
structures covers
Trade Name: Supertent 14 Supertent 18 Tenara Weblon Holiday Weblon Tent Wall
Trade name owner Super Tex Super Tex W. L. Gore & Weblon Inc.' Weblon Inc.
Associatess
Base fabric
Material Polyester Polyester Expanded PTFE Polyester9 Polyester
Weight NA NA 15.4 oz/yd 2 1.6 oz/yd 2 1.74 oz/yd2
Weave style Woven Woven 3 X 1 twill Woven Weft insertion
Yarn count (warp, fill) 16, 16 tpi 18, 18 tpi 66, 66 tpi 24, 24 tpi 18, 9 tpi
Coating
Material Vinyl coated Vinyl coated None Vinyl laminated Vinyl laminated
Weight (top, bottom) NA NA NA 6.4 oz/yd2 4.4 oz/yd2
UV topcoat material NN NA None Rainkleen NA
UV topcoat weight NA NA NA NA NA
Finished fabric
Test method NA NA ASTM D 1777 NA NA
Thickness NA NA 0.014 in NA NA
Weight 14 oz/yd2 18 oz/yd 2 15.4 oz/yd2 12 oz/yd 2 10 oz/yd 2
Roll width, usable 61-81 in 61-81 in 157 in 62 in 62 in
Tongue tear (warp, fill) 110, 90 lb/in 100, 10 lb/in NA 18, 18 lb/in 25, 30 lb/in
Test method FED-STD-191 (5314) FED-STD-191 (5134) NA FED-STD-191 FED-STD-191
(5134) 10 (5134) 10
Trapezoidal tear
(warp, fill) NA NA NA NA NA
Test method NA NA NA NA NA
Grab tensile (warp, fill) 200-170 lb/in 300, 300 lb/in 378, 385 lb/in 120, 120 lb/in 115, 115 lb/in
Test method FED-STD-191 (5102) FED-STD-191 (5102) DIN 53857 (Germany) FED-STD-191 (5100) FED-STD-191 (5100)
(continued)
.......
.......
.......
.....
.....
(X)
Trade Name: Supertent 14 Supertent 18 Tenara Weblon Holiday Weblon Tent Wall
"'-.1
~
Appendix 2
Awnings and Canopies-Fabric Specification Table
This table was originally published in Fabrics & 6. Also passes 2,000 hrs. xenon test.
Architecture, Specguide 1995, November-December, 7. In-house test methods used.
1994 by the Industrial Fabrics Association Interna- 8. Also passes NFPA-701.
tional (IFAI). 9. Also passes CPAI-84.
10. Also passes ASTM E-84, Class A.
11. Also passes UL-C-109.
Disclaimer statement:
12. Test method FED-STD-191A (5803).
'~II specifications included in the table were sub- 13. Also passes UL-48.
mitted voluntarily by the firms and their accuracy is 14. Test method FED-STD-191A (5803).
the responsibility of the manufacturer. This table is 15. Distributed by The Astrup Co.
not an endorsement of a company or product by Fab- 16. Test method ASTM D 3107.
rics & Architecture or the Industrial Fabrics Associa- 17. Test method FED-STD-191A (5803).
tion International (IFAI). The reader is encouraged to 18. Test method AATCC 30.
contact the companies directly for further informa- 19. Passes VFAC Class 1.
tion." 20. Test method SAE J1960 "modified" xenon
Weatherometer.
21. Test method AATCC 30, Parts 3 and 4.
Footnotes:
22. Distributed by the Astrup Co., John Boyle Co.,
1. Test method ASTM 1204 (sic.). Unitex and others.
2. Distributed by Western Rim & Baer Fabrics. 23. Test method GM Automotive 260-15 min.
3. Test method not specified. 24. Test method ASTM D 2594 modified.
4. Also passes UL-214. 25. Not recommended for exterior use.
5. 5-Year adhesion warranty with 3M's Scotchcal. 26. Distributed by Unitex.
780
Fabric Type: Vinyl Laminated or Coated Polyester (Backlighting)
Trade Name: Awnlit 8000 Awnlit Plus Awnmax Canopy Canopy Plus Cool Glo
Trademark owner Duracote Corp. 26 Duracote Corp. 26 Hiraoka & Co.2 Meridian Mfg. Corp. Meridian Mfg. Corp. Unltex
Construction
Base fabric Polyester Polyester Polyester Polyester Polyester Polyester
Finish/coating Vinyl lam./ Vinyl lam./ Vinyl/NZ-1 Vinyl PVDF/Fluorex-P Vinyl coated
acrylic acrylic acrylic
Put up (per roll) 50 yds .50 yds 32 or 45 yds 35 yds 35 yds 40 yds
Finished width(s) 61 in 61 in 61 in or 80 in 61 in 60 in 61 in
Finished weight (oz/sq yd) 19 oz 16 oz 19.1 oz 17-18 oz 17-18 oz 13 oz
Aesthetics
Number of colors, top 12 solids 16 solids 27 solids 16 solids 16 solids 22 solids
Number of colors,
underside Clear Clear White White White Same as top
Opaque No No No No No By color
Translucent, inherent Yes Yes NA Yes Yes Yes, by
color
Translucent, backlighting Yes Yes Yes Yes Yes No
Durability
Life expectancy* 8-10 yrs 5-8 yrs 10+ yrs 5-8 yrs 7-10 yrs 5-8 yrs
WarrantyI duration Yes/8 yrs Yes/5 yrs Yes/5-8 yrs Yes/5 and 3 yrs Yes/7 and 10 yrs Yes/5 yrs
UV resistance** 2,000 hrs 2,000 hrs 2,000 + hrs 3 2,000 hrs 6 2,000 hrs6 1,000 hrs
Water repellent Yes Yes Yes Yes Yes Yes
Hydrostatt NA NA NA NA NA NA
Flame resistant
(meets CSFM) Yes 8 Yes 8 Yes4 Yes Yes Yes 8
Mildew resistant** Yes, ASTM G21 Yes, ASTM G21 Yes, ASTM Yes, ASTM G21 Yes, ASTM G21 Yes, ASTM
021 G21
Wick resistant** Yes, DTM-36 Yes, DTM-36 Yes, JIS L Yes7 Yes 7 NA
1096
(continued)
-..J
())
......
--..1
00
1\)
Trade Name: Awnlit 8000 Awnlit Plus Awnmax Canopy Canopy Plus Cool Glo
Handling
Heat sealable
(w/o seam tape) Yes Yes Yes Yes Yes, with primer Yes
Heat sealable
(w/seam tape) Yes Yes Yes Yes Yes Yes
Shrinkage (warp, fill)** 0.5%, 0.2% 0.5%, 0.2% 1 0.9%, 0.1% 3 1.4%, 1.5% 7 1.4%, 1.5% 7 NA
Stretch factor (warp, fill)** NA NA 1.6%, 1.53% 3 1.6%, 1.7% 7 1.6%, 1.7% 7 NA
Cleaning agents available Yes Yes Yes No No Yes
Graphics
Heat transfer films Yes Yes Yes Yes Yes Yes
Heat sealed inset fabric Yes Yes Yes Yes Yes Yes
Sewn-in inset fabric Yes Yes Yes Yes Yes Yes
Eradication No No No No No No
Pressure-sensitive vinyl Yes Yes Yes5 No Yes Yes
Silk-screening Yes Yes Yes Yes Yes Yes
Hand painting Yes Yes Yes Yes Yes Yes
Other NA NA NA NA NA NA
Support material
Fabrication or technical
manual No No Yes No No No
Specification sheet
available Yes Yes Yes Yes Yes Yes
*Depends on care and climate conditions.
**Results depend on test method used.
tResult cited to ASTM D 583.
Fabric Type: Vinyl Laminated or Coated Polyester (Backlighting)
Trademark owner Dickson Elberton Duracote Corp. 26 Meridian Mfg. Corp. Astrup Astrup Astrup
Construction
Base fabric Polyester Polyester Polyester Polyester Polyester Polyester
Finish/coating Vinyl/acrylic Vinyl/Tedlar PVDF/Fluorex-P Vinyl/acrylic Vinyl/urethane Vinyl/acrylic
Put up (per roll) 38 yds 50 yds 35 yds 25 yds 25 yds 50 yds
Finished width(s) 61 in 61 in 60 in 76 in 76 in 61 in
Finished weight (oz/sq yd) 16 oz 20 oz 17 oz 16 oz 16.5 oz 15 oz
Aesthetics
Number of colors, top 18 solids/ 12 solids 2 solids 10 solids 4 solids 26 solids
5 mat. fin.
Number of colors,
underside White Clear 2 White White White
Opaque No No Yes No No No, except black
Translucent, inherent No Yes No No No No
Translucent, backlighting Yes Yes No Yes Yes Yes
Durability
Life expectancy* 5 yrs 10-12 yrs 7-10 yrs 5+ yrs 8+ yrs 5+ yrs
Warranty /duration Yes/5 yrs Yes/10 yrs Yes/7 and 5 yrs Yes/5 yrs Yes/8 yrs Yes/5 yrs
UV resistance** 2,000 hrs 2,000 hrs 2,000 hrs6 3000 hrs3 3,000 hrs3 3,000 hrs 3
Water repellent Yes Yes Yes Yes Yes Yes
Hydrostatt NA NA NA NA NA NA
Flame resistance
(meets CSFM) Yes Yes8 Yes Yes Yes Yes
Mildew resistant** NA Yes, ASTM G21 Yes, ASTM G21 Yes 3 Yes 3 Yes3
Wick resistant** Yes 3 Yes, DTM 36 Yes 7 Yes 3 Yes 3 Yes 3
(continued)
......
Q)
(,)
-....J
(X)
~
Handling
Heat sealable
(w/o seam tape) Yes Yes Yes, with primer Yes Yes Yes
Heat sealable
(w/seam tape) Yes Yes Yes Yes Yes Yes
Shrinkage (warp, fill)** NA 0.5%, 0.2% 1 1.6%, 1.8% 7 1%,0% 1%,0% maxi I%, 0% max 1
max 1
Stretch factor (warp, fill)** NA NA 1.8%, 1.9% 7 4% max 1 4% max 1 4% max 1
Cleaning agents available Yes Yes No Yes Yes Yes
Graphics
Heat transfer films Yes No Yes Yes Yes Yes
Heat sealed inset fabric Yes Yes Yes Yes Yes Yes
Sewn-in inset fabric Yes Yes Yes Yes Yes Yes
Eradication No No No No No No
Pressure-sensitive vinyl Yes Yes Yes Yes Yes Yes
Silk-screening Yes Yes Yes Yes Yes Yes
Hand painting Yes Yes Yes Yes Yes Yes
Other NA NA NA NA NA NA
Support material
Fabrication or technical
manual No Yes No Yes Yes Yes
Specification sheet
available Yes Yes Yes Yes Yes Yes
*Depends on care and climate conditions.
**Results depend on test method used.
tResult cited to ASTM D 583.
Vinyl Laminated or Coated Polyester
Fabric Type: (Backlighting) Vinyl Laminated Polyester
--
Signmaster Weblon
Trade Name: Supreme Starlit Patio 500 Unishade Coastline+ Weblon Vanguard
Trademark ovvner John Boyle & Co. John Boyle & Co. John Boyle & Co. Unitex Weblon 15 Weblon 15
Construction
Base fabric Polyester Polyester Polyester Polyester Polyester Polyester
Finish/coating Vinyl Vinyl/Tedlar Vinyl Vinyl Vinyl/urethane Vinyl/urethane
Put up (per roll) 50 yds As specified 50 yds 50 yds 50 yds 50 yds
Finished width(s) 61 in 60 in 61 in 61 in 62 in 62 in
Finished weight (oz/sq yd) 16 oz 18 oz 17 oz 16 oz 15 oz 17 oz
Aesthetics
Number of colors, top 30 30 30 solids/6 stripes 22 48 solids/ 15 solids
36 stripes
Number of colors,
underside White White Same or Same as top Solids/print Same as top
white/tan
Opaque No No, except black Yes Depends on color NA NA
Translucent, inherent Yes Yes No, exc. clear Yes Yes (dep. on Yes (dep. on color)
and white color)
Translucent, back-lighting Yes Yes No No No No
Durability
Life expectancy* 5-8 yrs 8-10 yrs 5-8 yrs 5-8 yrs 5+ yrs 8+ yrs
WarrantyI duration Yes/5 yrs Yes/8 yrs Yes/5 yrs Yes/5 yrs Yes/5 yrs Yes/8 yrs
UV resistance** 2,000 hrs 2,000 hrs 2,000 hrs 1,000 hrs 2,000 hrs3 10,000 hrs 3
Water repellent Yes Yes Yes Yes Yes Yes
Hydrostatt NA NA NA NA NA NA
Flame resistant
(meets CSFM) Yes4.B-II Yes 10•13 Yes4.S-II Yes8 Yes Yes
Mildew resistant** Yes 12 Yes 12 Yes 12 Yes, ASTM G 21 Yes 3 Yes 3
Wick resistant** Yes 7 Yes7 Yes 7 NA Yes, light Yes 3
colors 3
.....
(X) (continued)
C11
~
0')
Signmaster Weblon
Trade Name: Supreme Starlit Patio 500 Unishade Coastline+ Weblon Vanguard
Handling
Heat sealable
(w/o seam tape) Yes No Yes Yes Yes Yes
Heat sealable
(w/seam tape) Yes Yes Yes Yes Yes Yes
Shrinkage (warp, fill)** NA NA NA NA <1 %3 <1%3
Stretch factor (warp fill)** NA NA NA NA < 1%3 < 1%3
Cleaning agents available Yes Yes Yes Yes Yes Yes
Graphics
Heat transfer films Yes No Yes Yes Yes Yes
Heat sealed inset fabric Yes Yes Yes Yes Yes Yes
Sewn-in inset fabric Yes Yes Yes Yes Yes Yes
Eradication No No No No No No
Pressure-sensitive vinyl No Yes No No Yes Yes
Silk-screening Yes No Yes Yes Yes Yes
Hand painting Yes No Yes Yes Yes Yes
Other NA NA NA NA NA NA
Support material
Fabrication or technical
manual No Yes No No Yes Yes
Specification sheet
available Yes Yes Yes Yes Yes Yes
*Depends on care and climate conditions.
**Results depend on test method used.
tResult cited to ASTM D 583.
Vinyl Laminated or
Fabric Type: Coated Mesh Acrylic or Resin Coated Polyester or Polyester/Cotton
Trademark owner Astrup Astrup Graniteville 15 John Boyle & Co. Unitex Unitex
Construction
Base fabric Polyester Polyester Polyester PolyesterI cotton Polyester/cotton Polyester/cotton
Finish/coating Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl
Put up (per roll) 30 yds 30 yds 70 yds 30 yds Special order 50 or 60 yds
Finished width(s) 60 in 60 in 60 in 60 in/61 in 58 in 60 in
Finished weight (oz/sq yd) 9 oz 17 oz 12.5 oz 13 oz 13.5-14.5 oz 13.5-14.5 oz
Aesthetics
Number of colors, top 12 solids 12 solids 25 solids 19 Unlimited 30 solids
Number of colors,
underside Same as top Same as top Same as top Same 30 solids Same as top
Opaque No No Yes Yes Yes Yes
Translucent, inherent Yes Yes No No No No
Translucent, backlighting No No No No No No
Durability
Life expectancy* 5+ yrs 5+ yrs 5+yrs 5 yrs 5 yrs 5-8 yrs
Warranty/duration Yes/5 yrs Yes/5 yrs Yes/5 yrs No Yes/5 yrs Yes/5 yrs
UV resistance** NA NA 800 hrs 17 1,000 hrs 1,000 hrs 1,000 hrs
Water repellent No No Yes Yes Yes Yes
Hydrostatt NA NA NA NA NA NA
Flame resistant
(meets CSFM) Yes Yes Yes Yes9 Yes8 Yes 8
Mildew resistant** Yes 3 Yes 3 Yes, AATCC30-1988 Yes 12 Yes, Yes,
ASTM G 21 ASTM G 21
Wick resistant** Yes 3 Yes 3 Yes 3 Yes7 Yes7 Yes7
(continued)
-..J
(X)
-..J
~
())
Vinyl Laminated or
Fabric Type: Coated Mesh Acrylic or Resin Coated Polyester or Polyester/Cotton
Trade Name: Awntex 70 Awntex 90 Calliope Fyrecote Mirage Pyrotone
Handling
Heat sealable
(w/o seam tape) Yes Yes No No No No
Heat sealable
(w/seam tape) Yes Yes Yes Yes Yes Yes
Shrinkage (warp, fill) NA NA 1-2% 3 2%, 2% 7 2%, 2% 7 2%, 2% 7
Stretch factor (warp, fill)** 1%, 2% 3 0.5%, 4.0% 3 1-2% 3 07 07 07
Cleaning agents available Yes Yes Yes Yes Yes Yes
Graphics
Heat transfer film No No Yes No No No
Heat sealed inset fabric Yes Yes Yes No No No
Sewn-in inset fabric Yes Yes Yes Yes Yes Yes
Eradication No No No No No No
Pressure-sensitive vinyl No No No No No No
Silk-screening Yes Yes Yes Yes Yes Yes
Hand painting Yes Yes Yes Yes Yes Yes
Other NA NA NA NA NA NA
Support materials
Fabrication or technical
manual Yes Yes Yes No No No
Specification sheet
available Yes Yes Yes Yes Yes Yes
*Depends on care and climate conditions.
**Results depend on test method used.
tResult cited to ASTM D 583.
Acrylic or Resin Coated PET
Fabric Type: or PET /Cotton Vinyl Coated Cotton, Polyester or Polyester/Cotton
Trademark owner Astrup John Boyle & Co. Graniteville 15 Graniteville 15 John Boyle & Co. John Boyle & Co.
Construction
Base fabric Polyester/cotton Polyester Cotton Cotton Polyester Polyester/cotton
Finish/coating Vinyl/acrylic Acrylic Vinyl Vinyl Vinyl Acrylic
Put up (per roll) 45 yds 50 yds 50 yds 50 yds 35 yds 50 yds
Finished width(s) 60 in S.61 in, 30-31 in 30-31 in 61 in 31 in
str31!36/61
Finished weight (oz/sq yd) 15 oz 9.6 oz 15 oz 15 oz 15 oz 13 oz
Aesthetics
Number of colors, top 20 25 solids/ 43 solids/ 19 solids/3 stripes 20 30 solids/
15 stripes 26 stripes 26 stripes
Number of colors, Same as top Sol. same/ Dyed pearl gray Dyed pearl gray Pearl gray Gray, tan, white,
underside str. nat. floral
Opaque Yes Yes Yes Yes Yes Yes
Translucent, inherent No Yes (dep. on No No No No
color)
Translucent, backlighting No No No No No No
Durability
Life expectancy* 5+yrs 5-8 yrs 5 + yrs 5+ yrs 5-8 yrs 5-8 yrs
WarrantyI duration Yes/5 yrs Yes/5 yrs Yes/5 yrs Yes/5 yrs Yes/5 yrs Yes/5 yrs
UV resistance** 1,000 hrs 2,000+ hrs 800 hrs 17 800 hrs 17 2,000+ hrs 2,000+ hrs
Water repellent Yes Yes Yes Yes Yes Yes
Hydrostatt NA NA NA NA NA NA
Flame resistant
(meets CSFM) Yes Yes No Yes 10 No No
Mildew resistant** Yes 3 Yes 12 Yes 18 Yes 18 Yes 12 Yes 12
Wick resistant** Yes 3 Yes7 No No Yes 7 Yes 7
(continued)
--.1
CD
<0
«i
0
Trade Name: Pee Gee Diklon 32 Sunbrella Sunbrella Plus Sunbrella Firesist Tempotest
Trademark owner Graniteville 15 Dickson Elberton 15 Glen Raven Glen Raven Glen Raven Alutex
Mil!s22 Mills22 Mills 22
Construction
Base fabric Polyester/cotton SoL-dyed acrylic SoL-dyed acrylic SoL-dyed acrylic Sol. -dyed modacr. SoL-dyed acrylic
Finish/coating Acrylic Resin/fluorocarbon Resin/ Back polyure- Resin/fluorochem. Teflon impregnated
fluorochem. thane
Put up (per roll) 50 yds 65 yds 55 yds 55 yds 50 yds 65 yds
Finished width(s) 31 in 47 in/61 in 46 and 60 in 60 in 60in 47.60 in
(some)
Finished weight (oz/sq yd) 12 oz 10 oz 9.25 oz 10 oz 9.25 oz 8.85 oz
Aesthetics
Number of colors, top 27 solids/ 37 solids, 47 solids/ 14 solids 21 solids/7 stripes 50 solids/68 stripes
23 stripes 66 stripes/ 57 stripes
13 solids
Number of colors,
underside Pearl gray Same as top Same Same Same Same
Opaque Yes Yes Yes, darker Yes, darker Yes, darker colors Yes
colors colors
Translucent, inherent No Yes Yes, most colors Yes, light colors Yes, most colors No
Translucent, backlighting No Yes Yes Yes, light colors Yes No
Durability
Life expectancy* 5+ yrs 5 yrs 5+ yrs 5+ yrs 5+ yrs 5 yrs
Warranty /duration Yes/5 yrs Yes/5 yrs Yes/5 yrs Yes/5 yrs Yes/5 yrs Yes/5 yrs
UV resistance** 800 hrs 17 2,000 hrs 3 1,500 hrs 20 1,500 hrs 20 1,500 hrs20 Yes
Water repellent Yes Yes Yes Yes Yes Yes
Hydrostatt NA NA NA NA NA 32 em
Flame resistant
(meets CSFM) No NAJ9 NA NA Yess-to
Mildew resistant** Yes 18 Yes 18 Yes 21 Yes21 Yes21 Yes
Wick resistant** No Yes3 No No No Yes
......
<0
...... (continued)
«:!
1\)
Acrylic p.
Fabric Type: Cot, or PIC 100% Woven Acrylic
Trade Name: Pee Gee Diklon 32 Sunbrella Sunbrella Plus Sunbrella Firesist Tempotest
Handling
Heat sealable
(w/o seam tape) No No No No No No
Heat sealable
(w/seam tape) No Yes Yes Yes Yes Yes
Shrinkage (warp, fill)** 2-3% 3 NA 3%, 1%23 3%, 1%23 3%, 1%23 0.5%/0.5%
Stretch factor (warp, fill)** 1%3 NA 1%, 3%24 1%, 3%24 1%, 3%24 0.5%/0.5%
Cleaning agents available Yes Yes Yes Yes Yes Yes
Graphics
Heat transfer films No No Yes Yes Yes Yes
Heat sealed inset fabric No Yes Yes Yes Yes Yes
Sewn-in inset fabric Yes Yes Yes Yes Yes Yes
Eradication No No No No No No
Pressure-sensitive vinyl Yes Yes Yes 25 Yes 25 Yes 25 No
Silk-screening Yes Yes Yes Yes Yes Yes
Hand painting Yes Yes Yes Yes Yes Yes
Other· NA NA NA NA NA NA
Support materials
Fabrication or technical
manual Yes No Yes Yes Yes No
Specification sheet
available Yes Yes Yes Yes Yes Yes
*Depends on care and climate conditions.
**Results depend on test method used.
tResult cited to ASTM D 583.
Appendix 3
Geotextile Fabric Properties
This table was originally published in Geotechnical directly for additional information. The opinions ex-
Fabrics Report (GFR) 1995 Specifier's Guide, De- pressed and the technical data provided do not neces-
cember 1994, by the Industrial Fabrics Association sarily represent the opinion of the Industrial Fabrics
International. Association International. IFAI makes no representa-
tion or warranty, either expressed or implied, as to (1)
Disclaimer Statement:
the fitness of any particular purpose of any of the in-
"All information included in this Appendix which has formation, designs or standards contained in this
been excerpted from the 1995 Geosynthetic Fabrics book or any products manufactured or constructed in
Report (GFR) Specifier's Guide was compiled from accordance therewith; or (2) the merchantability of
data submitted by firms in the geosynthetics industry. any such information, designs, standards or products.
Specifications were submitted voluntarily and their The use of any individual or entity of any such infor-
accuracy is the responsibility of the manufacturer. mation, designs, standards or products constitutes an
The appearance of a listing herein is not an endorse- acknowledgement and agreement by such individual
ment of the company or product by GFR or the In- or entity that the Industrial Fabrics Association Inter-
dustrial Fabrics Association International (IFAI). national made no representation or warranty with re-
This information is intended only as a guide, and spect to the fitness, merchantability or quality of such
readers are encouraged to contact the manufacturers information, designs, standards or products."
793
.......
co Phyaical Prope..- Filtration/Hydraulic Properties MechanicaiPrope..-
~
Percent Wide Width Tensile Elongation"'
P-.:!Niune Open Area Apparent Permittivity ASTM Mullen Trapezoid Grab/Tensile ASTM 0 4595-86
(wownsonly) Opening Size'31 0449t-92 Burst Tear Strength Elongation kN/m(lblin) Manufacturer's
ASl Puncture
Polymer CW0-22t25 ASTM 0 475t -87 sec~ 1/Fiow Rate TMD4833-88 ASTM 0 3786-87 ASTM 0 4533-9t ASTM 0 4632-9t SUggested
[ Mus per unH ]
---
p~m2 (ozJyrP-) Structural' I Cornpositiorl" % mm (U.S. sieve)
--
Vminlm2 (gaVminm2) kN (lb) kPs (psi) kN(Ib) kN(Ib)% MD
I XD Applications"'
Amoco Fabrics & Fibers Co. Amoco Fabrics & Fibers Co.
Amoco 1198 w pp NA 0 425 (40) 0.05/2032 0.53 (120) 3100 (450) 0.29 (65) 1.34 X 0.89/15 NP NP E, O,F
(50) (300 X 200)/15
Amoco 1199 w pp NA 0.212 (70) 0.28/731 0.60 (135) 3307 (480) 0.42 (95) warp 1.56 X 1.11/15 NP NP E, 0, F
(18) 0.24 (55) fill (350 X 250)/15
Amoco 1380 w pp NA 0.600 (30) 0.40/1219 0.36 (80) 2067 (300) 0.22 (50) 0.78 (175)/25 NP NP SIF
(30)
Amoco2000 w pp NA 0.600 (30) 0.04/163 0.29 (65) 2239 (325) 0.20 (45) 0.62 (140)/15 NP NP SIS
(4)
Amoco2002 w pp NA 0.300 (50) 0.04/163 0.40 (90) 2756 (400) 0.33 (75) 0.89 (200)/15 21 (120)/10 21 (120)/6 SIS
(4)
Amoco 2006 w pp NA 0.425 (40) 0.02/81 0.53 (120) 4134 (600) 0.53 (120) 1.34 (300)/15 31 (175)/15 31 (175)/15 SIS, R
(2)
Amoco 2016 w pp NA 0.425 (40) 0.55/1625 0.53 (120) 5512 (BOO) 0.53 (120) 1.34 (300)/20 35 (200)115 35 (200)/7 E, SIS
(40)
Amoco 2019 w pp NA 0.212 (70) 0.04/203 0.62 (140) 3514 (510) 0.29 (65) 1.56 X 1.11/15 NP NP E
(5) (350 X 250)/15
Amoco 2044 w pp NA 0.600 (30) 0.15/406 0.62 (140) 9302 (1350) 1.11 (250) 2.67 X 2.23/15 70 (400)/18 70 (400)/8 SIS, R
(10) (600 X 500)/15
All values were requested to be minimum average roll values and all
[1] w =WrNefl [4] Aelnlorcementapplicat•onsonly S/F =Slit Fence
claims are the responsibility of the manufacturer. All product data
--M
NW =Nonwoven [5] SIS =Separatlonlstabollzatlon OIC =Oiherorcombmat•on
0/C =Oiherorcomblnatloo R =Ae•nlorcement NA = Manulacturer determmed thatlh•s data was not
[2] PET F :FiltratiOn apphcabietotheproductorthedatawasunav!lllable are intended as a guide and are not all·inclusive. Geotechnical
NP = Datanotprov•dedbymanu!acturer
PP
PE
=Polypropytene
=Polyethylene
0
p
=Dra•nage
=Protection
Fabrics Report recommends you contact manufacturers before
0/C .. Other or combinallor1 E =Erosion Control making any specifying/purchasing decisions.
[3J Maximum opening si;ze ollested rolls AJO = Asphalt Overlay
Physical Properties Filtration/Hydraulic Properties Mechanical Properties
Amoco Fabrics & Fibers Co. (cont.) Amoco Fabrics & Fibers Co. (cont.)
Amoco2122 w pp NA 0.600 (30) NA/3657 0.29 (65) 1895 (275) 0.22 (50) 0.53 X 0.45/15 NP NP S/F
(90) (120 X 100)/15
Amoco2125 w pp NA 0.850 (20) NA/609 0.27 (60) 1895 (275) 0.22 (50) 0.45 (100)115 NP NP S/F
(15)
Amoco 2127 w pp NA 2.00(10) NA/1219 0.13(30) 1723 (250) 0.27 (60) 0.42 X 0.36/15 NP NP S/F
(30) (95 X 80)/15
Amoco2130 w PP NA 0.600(30) NA/408 0.27 (60) 2343 (340) 0.36 (80) 0.53 ){ 0.53.115 ){ 20 NP NP S/F
(10) (120 X 120)115 X 20
Amoco 2155 w pp NA 0.250 (20) NA/609 0.27 (60) 1895 (275) 0.22 (50) 0.45 (100)/15 NP NP SIF
(15)
Amoco4504 NW pp NA 0.212 (70) 2.0/4064 0.245 (55) 1550 (225) 0.16 (35) 0.42 (95)/50 NP NP F (landfill)
(100)
Amoco4506 NW pp NA 0.212 (70) 1.7/3657 0.401 (90) 2412 (350) 0.29 (65) 0.67 (150)/50 NP NP F (landfill)
(90)
Amoco4508 NW pp NA 0 150(100) 1.5/3251 0.579 (130) 3101 (450) 0.36 (80) 0.89 (200)/50 NP NP F (landfill)
(80)
Amoco 4510 NW pp NA 0.150(100) 1.112544 0.734 (165) 3790 (550) 0.42 (95) 1.05 (235)/50 NP NP F(landfill)
(70)
Amoco4512 NW PP NA 0.150 (100) 0.9/2438 0.823 (185) 4479 (650) 0.51 (115) 1.22 (275)/50 NP NP F (lancflll)
(60) P (geomembrane)
Amoco4516 NW pp NA 0.150(100) 0.7/2032 0.979 (220) 5168 (750) 0.58 (130) 1.56 (350)/50 NP NP P (geomembrane)
(50)
Amoco4535 NW pp NA 0.212 (70) 2.2/6298 0.200 (45) 1102 (160) 0.16 (35) 0.36(80)150 NP NP F, D
(155)
Amoco4645 NW pp NA 0.212 (70) 2.116095 0.245 (56) 1275 (185) 0.18 (40) 0.40 (90)150 NP NP F,D
(150)
Amoco4646 NW pp NA 0.212 (70) 2.0/5689 0.299 (65) 1550 (225) 0.20 (45) 0.45 (100)150 NP NP F, D, SIS
(140)
Amoco4547 NW pp NA 0.212 (70) 1.814876 0.311 (70) 1664 (240) 0.22 (50) 0.53 (120)/50 NP NP F. D, SIS, E
(120)
Amoco4550 NW pp NA 0.212 (70) 1.7/4673 0.336 (75) 1826 (265) 0.25 (55) 0.58 (130)150 NP NP F, 0, SIS. E
(115)
[1] w =Woven [4] Aemtorcement appiK;aliOns only Sif' "'Sill Fence All values were requested to be minimum average roll values and all
= Separa~on.lstablhzatlon = Other or combmatJOn
NW =Nonwoven [5] SIS
A ""Remlorcement
0/C
NA = Manufacturer determined lhat this data was not
claims are the responsibility of the manufacturer. All product data
o<e =Other or comb•nal10n
[2] PET = Polyeslef F =FiltratiOn applicable to the product or the data was unavailable are Intended as a guide and are not all-inclusive. Geolflehn/cal
pp =Polypropy~ne 0 =Drainage NP ~ Data not provided by 1(18nUiacturef
PE = PolyethyWle p =PrOleclion Fabrics Report recommends you contact manufacturers before
-..J 0/C ~ Other Of combination E = Erosion Control
making any specifying/purchasing decisions.
co ]3] Max1muf11 open1ng size of tested rolls NO = Asphalt Overlay
01
~ Physical Properties Fittratiorv'HydrauHc Properties Mechanical Properties
m Percent Wide Width Tensile Elongationl•l
Product Name Open Area Apparent PermittivityASTM Mullen Trapezoid Grab/Tensile ASTM D 4595-86
(W<MinS only) Opening Size'" D4491-92 Puncture Burst Tear Strength Elongation kN/m(lblin) Manufacturer's
[ Mass per unH ] Polymer CW0-22125 ASTM D 4751-87 sec· 11flow Rate ASTM D 4833-88 ASTM D 3786-87 ASTM D 4533-91 ASTM D 4632-91 Suggested
g/m2 (ozly(l2) Structurel' 1 Composition121
-
%
-
mm (U.S. sieve)
------
Vmin!m2 (gallminift2) kN (lb) kPa (psi) kN (lb) kN (lb)% MD
----
_[ __ XD
----
Applica~~~
Amoco Fabrics & Fibers Co. (cont.) Amoco Fabrics & Fibers Co. (cont.)
Amoco4551 NW pp NA 0.150 (100) 1.614470 0.401 (90) 2170 (315) 0.29 (65) 0.67 (150)150 NP NP F. D. SIS, E I
(110)
Amoco4555 NW pp NA 0.150 (100) 1.312844 0.668 (150) 3445 (500) 0.42 (95) 1.20 (270)150 NP NP F, D. SIS, E
(70)
Amoco 4557 NW pp NA 0.150 (100) 1.112438 0.779 (175) 4134 (600) 0 51 (115) 1.22 (275)/50 NP NP railroad
(60) stabilization
F. D, SIS, E
Amoco4561 NW pp NA 0.150 (100) 0.712032 1 024 (230) 5168 (750) 0.58 (130) 1.45 (325)150 NP NP railroad
(50) stabilization
F, D, SIS, E
- - ----
776 w PP NA 0.425 (40) 0.10/326 (8.0) 0.36 (80) 27>;8 (400) 0.24 (55) MD 0.89 (200)114 NA NA SIS
0.40 (90) XMD
-- - --- L_ - ---
kN(Ib)
Burst
kPa (psi)
Tear Strength
kN (lb)
Elongebon
f'<STM D 4833-88 ASTM D 3786-87 ASTM D 4533-91 ASTM D 4632-91
kN(Ib)% MD
kN/m(lblin)
l XD
Menufacturor's
Suggested
Apptlcatlona"'
I
113 w pp NA 0.425 (40) NA 0.82 (185) 4826 (700) 0.44 (100) MD 1.78 (400)/15 MD NA NA SIS
0.33 (75) XMD 1.51 (340)115XMD
806 w pp NA 0.850 (20) 0.4511222 (30) 0.09 (20) 1379(200) 0.13(30) 0.31 (70)/10 NA NA SIF
751 w pp NA 0.600 (30) 0.231610 (15) 0.20 (45) 2068 (300) 0.22 (50) 0.53 (120)110 MD NA NA SIF
0.42 (95)110 XMD
751 w pp NA 1.30(15) 0.35/978 (24) 0.09 (20) 1034 (150) 0.09 (20) 0.31 (70)/10 MD NA NA SIF
0.18 (40)110 XMD
·-
,_
Pl1oenix M-288-D NW PET NA 0.300 1.9 (45) (180) (35) (90)60 NIA NIA D. E. F, SIS
(SO) (145)
Phoenix M-288-E NW PET NA 0.210 1.09 (95) (370) (75) (200) 60 NIA N/A D, E, F, SIS, R
(70) (90)
Phoenix M-288-S NW PET NIA 0.210 1.6 (55) (190) (45) (130) 60 N/A NIA D. E. F, SIS
(70) (120)
Phoenix'" NW PET NA NA NA NIA NIA NIA NIA NIA NIA R,D, E. F. SIS
(4-60)
Car1hage 10% w pp 1D-12% 0.425-.30 1.213621 0.578 (130) 3514 (510) 0.356 X 0.333 1.22 X 1.16 27.15 28.9 E. F. D, SIF,
(calendered) (4D-50) (89) (80 X 75) (275 X 260)/16 (155)119 (165)117 SIS, R
Carthage 15% w pp 12-15% 0.42&-.30 1.514878 0.533 (120) 3514 (510) 0.511 X 0.356 1.64 X 0.91 35.9 24.52 E. F, D, S/F,
(4Q-50) (115) (115x80) (370 X 205)/10 (205)119 (140)18 SIS, R
{1] w
""
CK:
(21 PET
pp
Q'C
·-
·Woven
.. Qiher~C01'111*1ab0!1
m~
- -
•CJt.OI'~
(41 Reinlort:emenl applications only
(5] SIS
R
F
D
P
E
~ Separataon/statHiiZatioo
,.Reinfon:emenl
,fillratioo
,. Drainage
"'Protection
=Ero&ionControl
SIF
OIC
=Sii!Fenc:e
= Other or combination
[A) Custom rtJanufactuffld to~~ design spedfications
NA ,.MarJufacturer~thalthisdatawasnot
apphcableiDihel)fOduelor'lhedalawaaunavailable
NP = Data not prwided by manufacturef
All values were requested to be minimum average roll values and all
claims are the responsibility of the manufacturer. All product data
are intended as a guide and are not all-inclusive. Geotechnicsl
Fabrics Report recommends you contact manufacturers before
PE
[3J Maxlnun · .-
opening . . ol teeted roll NO =AsphaltOIIerlay making any specifying/purchasing decisions.
-...,J
<0
-...,J
~ Phyalcal Properties Flltratlcn/Hydraullc p._- Mechank:at Properties
CXl
Parcent Wide Wodlh Tensile Elongation"'
Product Name Open Area Apparent PannittivityASTM Mullen ~ Grab/Tensile ASTM D 4595-86
(W<M>nSonly) OpaningSizel'l D 4491-92 Puncture Bunll Tear Strength Elongation kN/m (lblin) Manufacturer's
[-perri]
rjrriJ (ozJyc{J-)
--·-
Structure'' 1
---
Polymer
Composition"'
CWQ-22125
%
ASTM D 4751-87
mm(U.S......)
sec-lfAow Rate
Vminfrn2 (gaVminm2)
ASTM D 4833-88 ASTM D 3788-87 ASTM D 4533-91 ASTM 0 4632·91
kN (lb) kPa (poi) kN(Ib) kN(Ib)% MD
I XD
SU9Q8Siod
Application~ 1
ea,._30% w pp 25-30% 0.425-.30 2.1/6143 0.533(120) 2859 (415) 0.422 X 0.244 1.47 x0.93 31.52 20.14 E. F. D. SIF.
(palmared) (40-50) (151) (95x 55) (330 X 210)/15 (180)/20 (115)/15 SIS, A
ea,._8%-HD w pp 6-8% 0.30-.25 0.82412441 0.933(210) 5925 (660) 0.578 X 0.667 1.78x2.0 NIP NIP E. F, 0, SIF,
(calendered) (50-80) (80) (130 X 150) (400 X 450)/17 SIS, A
FX-400MF w pp NP 0.80 NA 0.733 (185) 8371 (1215) 0.822 X 0.822 1.82x 1.8 70.05 70.05 SIS, A
(30) (185 X 185) (410 X 405)/9 (400)/13 (400)19
FX-11 w PP <1% 0.85-.80 0.2011139 0.287 (80) 1660 (270) 0.244 0.533 NA NA SIF
(20-30) (28) (55) (120)/15
FX-33 w pp <1% 0.30 NA 0.289 (85) 1660 (270) 0.222 0.533 NA NA SiS
(SO) (50) (120)/20
FX-44 w pp <1% 0.425 NA 0.311 (70) 2067 (300) 0.267 0.644 NA NA SIS
(40) (80) (145)120
FX-55 w pp <1% 0.425 NA 0.487 (105) 3189(480) 0.378 0.889 21.02 21.02 SIS, R
(40) (85) (200)/15 (120) (120)
FX-66 w pp 3.8, 4.5. 5.3 <1% 0.425-0.30 NA 0.558(125) 4134 (800) 0.533 1.33 30.65 SIS. A
(40-50) (120) (300)/15 (175) (175)
FX-80NS NW pp NA 0.212 1.1/3661 0.80 (135) 3032 (440) 0.422 1.0 NA NA SIS, D
(70) (90) (95) (225)/50
{1] w
----
·-
. ·-
[4] Retnlorcemefll applocabOOS only
"""
......, All values were requested to be minimum IIV8I'IIg8 roll values and all
·-·-
NW [5) SIS claims are the responsibility of the manufacturer. All product dats
121
OIC
P£T
.. Qiherorcombinllltion R
F
"Separation/stabiliulion
= Reinforcerneol
=Filtration
""" •Oitlerorcombination
NA .. ~...-mlnedltlallhilldllta.,..nol
IIPPIICiblltDhiJI'OWCI:orlhedm-~
are Intended as a guide and are not all-Inclusive. ~technlclll
NP=O...nolproWdlldboj~
PE
D
p Fabrics Report recommends you contact manufacturers before
(31
OIC Olhllr or combination
z
Mulmum openng size ol' ~ fl)lls •
AJO
=&:.ion Control
.. ~o-tay
making any apecltylng/pun:heslng decisions.
Physical Properties Fittralion/Hydraulic Properties Mechanical Properties
FX-120HS NW pp NA 0.150 0.81 0.756 (170) 3790 (550) 0.511 1.444 NA NA SIS, P,D
(hea1bonded) (100) 2644 (65) (115) (325)
FX-160HS NW pp NA 0.150 0.61 1.111 (250) 5168 (750) 0.733 1.889 NA NA SIS, P. D
(heatbonded) (100) 1831 (45) (165) (425)
Trevtta0111140 NW PET NA 0.300 (50) 2.01/102 (150) 0.222 (50) 1311 (190) 0.178 (40) 0.489 {110) 60 10.9{62.1) 7.4 (42) F, D, E, A/0
138(4.0) 69.6IAJ 70.41"'1
Trovtre 0111200 NW PET NA 0.210 (70) 1.74/88 {130) 0.358 (80) 1965 {285) 0.267 (60) 0.711 (160) 60 14.4 (82.5) 7.4(42) F. D. E, SIS
193 (5.7) 70.4"" 70.41"1
Trev1ta0111250 NW PET NA 0.210 (70) 1.47175 (110) 0.423 (95) 2484 (360) 0.334 (75) 0.933 (210) 60 17.1 (97.6) 14.8 (84.6) F, D, E. S/S
241 (7.1) 65.QIAI 75.()1Al
-0111280 NW PET N\ 0.210 (70) 1.20/61 (90) 0.444 (100) 2622 (380) 0.356 (80) 1.023 (230) 18.3 (104.6) 18.8 (107.5) F, D, E, SIS. A
271 (8.0) 60 68.11AI 72.11A1
Trev1la011/350 NW PET NA 0.210 (70) 1.07154 (80) 0.578 (130) 3519 (510) 0.444 (100) 1.356(305) 26.8 (152.9) 25.5 (134.1) A, F. P, E,
339 (10.0) 60 74.2 72.1 SIS
-011/420 NW PET NA 0.210 (70) 0.87/44 (65) 0.867 (130) 3795 (550) 0.534 (120) 1.556 (350) NA NA A, P,S/S
408(12.0) 60
-0111450 NW PET NA 0.149(100) 0.53127 (40) 0.867 (195) 5382 (780) 0.667 (150) 2.224 (500) 36.0 (205.5) 28.8 (164.7) A, P,S/S
441 (13.0) 70
w
--
--
--
•Wa<en [4] Relnton::ementapplicattonsonly SIF "S1lt Fence
All values were requested to be minimum average roll values and all i
--
[1)
NW [5] SIS "'SEJperatiOn/slabilization 0/C = Other or combination
NA = Manufacturer deterrruned that thos data was 1'101
claims are the responsibility of the manufacturer. All product data
• Olhllr ot combinatiOn A =Aeinfolt:ement
(21 """
PET F =Filtration appliCable to the product or ltlo Data was unavailable are intended as a guide and are not all-inclusive. Geotechnical
,.
Pf'
·Oihefot~
D
p
E
=Drainage
=ProlecliOn
•Erosion Control
NP = Data not pn:Mde<l by manu1acturer
[A] lndependenl test lab values-not minimum average roll Fabrics Report recommends you contact manufacturers before
"""" making any specifying/purchasing decisions.
[3] ""'
Mulnurl opening size"' te.ted . . AJO = Aaphan Overlay (8] "-age values
I
~
(X)
0
0 Physical Properties Filtration/Hydraulic Properties Mechanical Properties
Contech Construction Products Inc. (cont.) Contech Construction Products Inc. (cont.)
Trevira 0111550 NW PET NA 0.149 (100) 0.53127(40) 0.689 (155) 4416 (640) 0.578 (130) 1.734 (390) 32.1 (183.5) 27.6 (157.6) R, P, SIS
542 (16.0) 65
C200 w pp NA 0.60 (30) 0.07/244 (6) 0.450 (100) 3101 (450) 0.38 x0.40 0.89 X 0.89/15 21.0(120) 21.0(120) 55,0/C
(85 X 90) (200 X 200¥15
C300 w pp NA 0.60 (30) 0.06/203 (5) 0.533 (120) 4134 (600) 0.53 X 0.53 1.33 X 1.33/15 30.6 (175) 30.6 (175) SS, 0/C, R
(120 X 120) (300 X 300)/15
C70106 w pp 4.00 0.212 (70) 0.28/732 (18) 0.667 (150) 3307 (480) 0.42 X 0.24 1.76x 1.16/24 NA NA SS, 0/C, F. D. E
monofilament (95 X 55) (395 X 260)/24
Trevira 011/140 NW PET NA 0.300 (50) 2.01/102 (150) 0.222 (50) 1311 (190) 0.178 (40) 0.489 (110) 60 10.9(62.1) 7.4(42) F, D. E, A/0
136(4.0) 69.61A1 70.4"
Trevira 011/200 NW PET NA 0.210 (70) 1.74/88 (130) 0.356 (80) 1965 (285) 0.267 (60) 0.711 (160) 60 14.4 (62.5) 7.4 (42) F, D, E. SIS
193(5.7) 68.6 70.4"
Trevira 011/250 NW PET NA 0.210 (70) 1.47/75 (110) 0.423 (95) 2464 (360) 0.334 (75) 0.933 (210) 60 17.1 (97.6) 14.8 (64.8) F. D. E. SIS
241 (7.1) 65.()1"'1 75.0'"'
Trevira 011/280 NW PET NA 0.210 (70) 1.20/61 (90) 0.444 (100) 2622 (380) 0.356 (80) 1.023 (230) 18.3 (104.6) 18.8 (107.5) F. D, E. SIS, R
271 (8.0) 60 68.1"' 72.1IAI
Trevira 011/350 NW PET NA 0.210 (70) 1.07/54 (80) 0.578 (130) 3519 (510) 0.444 (100) 1.356 (305) 26.8 (152.9) 25.5 (134.1) R,F,P,E.
339(10) 60 74.2 73.8 SIS
Trevira 011/420 NW PET NA 0.210 (70) 0.87/44 (65) 0.667 (130) 3795 (550) 0.534 (120) 1.556 (350) NA NA R, P, SIS
406 (12) 80
Trevira 011/450 NW PET NA 0.149 (100) 0.80/40 (60) 0.689 (155) 4416 (640) 0.578 (130) 1.734 (390) 32.1 (183.5) 27.8 (157.6) R, P, SIS
441 (13) 65 n.9" 60.4"
TnMra 011/550 NW PET NA 0.149 (100) 0.53127 (40) 0.867 (195) 5382 (780) 0.667 (150) 2.224 (500) 36.0 (205.5) 28.8 (164.7) R,P,SIS
541 (16) 70 81.9" n.2"'
Trevira ProEarth NW PET NA NA NA NA NA NA NA NA NA F. P, D. E. SIS
140-550 (4-16)
------
[1] w
""
OK: --
•Wollen
,.Oiherorc:orrtlinlltion
[4)
[5)
Reinfon:ementapplicatioosonly
SIS
R
F
= Separation /stabilization
"'Rei~
zFIItration
SIF
0/C
=Silt Fence
" Olher or combination
NA = Manufaclurvrdelemlinedthatthisdatawaanot
appllcabletoltleproductortnedlltawasiii'I8VIIilable
All values were requested to be minimum average roll values and all
claims are tha responsibility of tha manufacturer. All product data
are lntanded as a guide and are not all-Inclusive. Geotachn/ca/
-
121 PET ·- 0 =Drainaga NP ,. Oatanotpn)Yideclbymanufactu111r Fabrics Report recommends you contact manufacturers before
p =Protection (A] Independent test lab values---not minimum ave~&g~~ roll
P£
PP
Ot'C
· -
•Oiherorc::omblndon
· me - E =Erosion Control making any specifying/purchasing decisions.
(3) Mulmum CIJ*IIng or lellted ro1s A/0 =Aiphai!O'Ieriay
Physical Properties FiHralion/Hydraullc Properties Mechanical Properties
Comtrac 60.006 w pp <1 (40-70) (0.1) 0.53 (120) 4134 (600) NA NA eo (400)113 80(400)113 R
Comtrac 270.270 w PET <1 0.4 (40) (0.2) 2.0(460) 10335 (1500) (600) NA 270 (1500)111 270 ( 1500)111 R
Comtrac 450.140 w PET <1 0.4 (40) (0.2) 2.0(460) 10335 (1500) (600) NA 450 (2500)111 140(800)111 R
Comtrac 750.285 w PET <1 0.4 (40) (0.2) 2.& (600) 11700(1700) (700) NA 750 (4200)111 285 (1600)111 R
--------- ------
GTF200 w PP NP 0.60 (30) 0.03 (100) (450) (90) (200)/15 (150)115 (150)115 SIS, R
GTF300 w pp NP 0.60 (30) 0.02 (145) (600) (115) (300)/15 (180)115 (210)115 SIS, R
Typar 3301 NW pp NP 0.30 (50) 0.6 (25) (90) (35) (120)160 NP NP F,D
Typar 3341 NW pp NP 0.25 (60) 0.7 (30) (90) (40) (120)160 NP NP F,D
Typar 3401 NW pp NP 0.21 (70) 0.7 (40) (140) (60) (130)160 NP NP SIS, F, D
-
Typar 3601 NW pp NP 0.10 (140) 0.1 (70) (210) (90) (240)160 NP NP SIS, F, D, E
Typar 3631 NW pp NP 0.10 (140) 0.1 (75) (210) (90) (250)/60 NP NP SIS, F. D. E
(1J w =Woven
,,, SIF =Silt Fence
All values were requested to be minimum average roll values and all
NW :Nonwoven [5[
NA
OIC
=
"'Other or combinat1on
Manulactunlr Mtermined thai this data was not
claims are the responsibility of the manufacturer. All product data
0/C =Other or combmahon
[2J PET "'Polyester applialbla to the product or the clata was unevwlable are intended as a guide and are not all-inclusive. Geotechnical
pp =PolyprOpylene Drainage NP = Data not provided by manufacturer
PE = Polyethylene Protection (B) lndependltnl tut values---not MARV Fabrics Report recommends you contact manufacturers before
(X) OiC = 01her or combmal•oo E ~Eros•on Conuol making any specifying/purchasing decisions.
0 [3] Maximur1' opening Slle of tested rolls AJO =Asphalt Overlay
......
p--
-
(X)
--
Allrallon/Hydraulc Pmpertlee Mechanical Plll!>"rtles
0 Pl1yoicll
1\)
Wide Width Tensile Elongation"'
Open"""' Apparent PermltllvllyASTM Mullen ~zoid Grab/Tensile ASTM 0 4595-86
(_,.only) OpenlngSizel" 0 4491·92 Puncture Bum Tear Strength Elongation kN/m (ll>ln) Manufacturer's
[-per""'" 1
~(rszJyril} Structurel''
Polymer
Compooltlon"'
CW0-22125
%
-
ASTM 04751-87
nvn(U.S.-.)
---
sec·1 /Flow Rate
Vmintm2 (gaVminift2)
---
ASTM 0 4833-88 ASTM 0 3786-87 ASTM 0 4533-91 ASTM 0 4632-91
kN (lb) kPe (psi) kN (lb) kN(Ib)% MD
I XD
Suggested
Applications"'
GTF570 w PP NP 0.60 (30) 0.4 (160) (1200) (180) (415)115% (400)113% (400V8% R, E
(410)115%
GTF550T w PET NP 0.43 (40) 0.1 (140) (750) (380) NP (500)110% (500)110% R
GTF1000T w PET NP 0.43 (40) 0.1 (150) (1000+) (400) NP (1000)110% (800)110% R
-·
111 w
·-
.w...... [4] Reinforcement applicabons only SIF "'S1tt Feoce All values were requested to be minimum average roll values and all
·-
NW [5] SIS = Separationlstabilizat•on OoC "' Other or combination
0/C "' Other or combination R = Reinforcement NA = Manufacturer determined that !tlis data was not claims are the responsibility of the manufacturer. All product data
]2] PET =Polyester F = Fillration applicable to I~ product or the data was unava•lable
pp
PE
0/C
.,.,........
= Other or combination
D
p
E
=Dratnage
=Protection
=ErOSion Control
NP = Data r'\01 prOVlded by manufacturer are intended as a guide and are not all-inclusive. Geotechnical
Fabrics Report recommends you contact manufacturers before
(3) Maximum opening siZe ot tested rolls IVO = Asphalt Overlay making any specifying/purchasing decisions.
Physical Properties Filtration/Hydraulic Properties Mechanical Properties
Product Name
Percent
Open Area
(wovens only)
Apparent
Opening &ze13l
PermiltivityASTM
D4491·92 Puncture
Mullen
Burst
Trapezoid
Tear Strength
II
GrabfTensile
Elongation
Wide Width Tensile Ek>ngation 1• 1
ASTM D 4595-86
kN/m (lblin) Manufacturer's
Potymer CW0-22125 ASTMD475HI7 sec-1/Fiow Rate ASTM D 4833·88 ASTM D 3786-87 ASTM D 4533·91 ASTM D 4632·91 Suggested
[ Mass per unn ]
gtm2 (ozly<f2) Structure111 Composition111 % mm (U.S. sieve) Vminim2 (gal/min!f12) kN(Ib) kPa (psi) kN (lb) kN (lb)% MD
I XD Applications1''
Nioolon HS1150 w PET NA 0.59 (30) 0.84 NA NA NA NA 201 (1150) 123 (700) R
2648 (65) I
Nicc»on HS1715 w PET NA 0.59 (30) 0.65 NA NA NA NA 298 (1700) 123 (700) R
2037 (50)
Nioolon 5400 (4.0) rfW pp NA 0.212 (70) 2.28 0.299(65) 1585 (230) 0.200 (45) 0.467 (105V60 NA NA F, D, E
7333 (180)
Nioolon 5600 (6.0) NW pp NA 0.212 (70) 1.63 0.422 (95) 2412 (350) 0.29 (65) 0.712 (160)150 NA NA SIS, D, E
5296 (130)
Nioolon S700 (7.0) NW PP NA 0.212 (70) 1.41 0.511 (115) 2756 (400) 0.358 (80) 0.99 (200)/50 NA NA SIS, D, E
4481 (110)
Nioolon 5600 (8.0) NW pp NA 0.212 (70) 1.26 0.58 (130) 3101 (450) 0.4 (90) 1.001 (225)150 NA NA A, P, D. F, SIS
4074 (100)
Nioolon 61000 (10) NW pp NA 0.15(100) 0.936 0.73(165) 3858 (560) 0.47 (105) 1.246 (280VSO NA NA R, P, D. F, SIS
3056 (75)
Nioolon S1200 (12) rfW PP NA 0.15(100) 0.751 0.65(190) 4479 (650) 0.58 (130) 1.6 (360)160 NA NA R, P.SIS
2444 (60)
Nioolon S1400 (14) NW pp NA 0.15 (100) 0.642 0.98 (220) 4495 (725) 0.62 (140) 1.99 (425)/60 NA NA R,P,SIS
2037 (50)
Nioolon 61600 (16) NW pp NA 0.15(100) 0.571 1.07 (240) 5512 (600) 0.69(155) 2.225 (500V80 NA NA R. P, SIS
1833 (45)
Mirafi100X w PP 1 0.841 (20) 0.2 0.27 (60) 2067 (300) 0.27 (60) 0.53 X 0.45/10 NA NA NP
815 (20) (120 X 100)110
Mirafi 500XL w pp 1 0.595 (30) 0.04 0.31 (70) 2412 (350) 0.20(45) 0.62 (140V15 NA NA NP
163(4)
I
MiniiiSOOX w pp 1 0.595(30) 0.03 0.40(90) 2756 (400) 0.33 (75) 0.89 X 0.89/15 18(100) 21 (120) NP
163(4) (200 X 200)/15
-- ------ I
(X)
(1)
(2)
QC
w
""
QtC
PET
pp
·-
~Wo.wn
.. Qiworoomblnlllon
..
- -
~
•Oiheror~
1"1
[S]SIS
"
F
0p
e
·-
~appiicdonaonly
.. ~
·-
·
- -
.. em.~on
- Contnll
NA
NP
SIF
OIC
=
=Silt Fence
=OtheroroornbinaiiDn
MlntliKturetdetllrminedthalthiadata'IIIIMnot
applc;lbletolheproductorlledala-~
=Datanoiprovldild~manufactuler
All values were requested to be minimum average roll values and all
claims are the responsibility of the manufacturer. All product data
are Intended as a guide and are not all-inclusive. Geotechnical
Fabrics Report recommends you contact manufacturers before
making any speclfylnglpurcheslng decisions.
8 PE · -
PI .....,..,DPW*'a._ot....-ro~a NO .. AapMII~
(X)
Physical Properties Fittratiorv'Hydraulic Properties Mechanical Properties
0
--
~
Percent Wide Wldlh T . . - Eionglollonl"
Product Name Open Area Apparenl PermittivityASTM Mullen Trapezoid GrabiTensile ASTMD45115-88
(wovens only) OpeningSiz.,.. 04491-92 Puncture Burst Tear Strengtll Elongation kNim (b'ln)
Polymer CW0-22125 ASTM D 4751-87 sec·1fF~ Rate ASTM D 4833-88 ASTM D 3786-87 ASTM D 4533-91 ASTM D 4632-91 SUpolod
[ Mass per unn ]
g;m2 (ozlyd2) Structurel' 1 Composition121 % mm (U.S. sieve) Vmintm2 (gaVminm2) kN (lb) kPe(psi) kN (lb) kN (lb)%
--
MD
--- 1 XD ~
Mirafi 700X w pp 4 0.210 (70) 0.28 0.60 (135) 3307 (480) 0.45 X 0.27 1.65 X 1.11115 39 (225) 25(145) NP
733 (18) (100 X 60) (370 X 250115)
Mirafi 700XG w pp 10 0.420 (40) 1.36 0.51 (115) 3445 (500) 0.51 X 0.33 1.82 X 0.89110 35 (200) 24(135) NP
4074 (100) (115 X 75) (365 X 200/10)
Filterweave 70/20 w pp 10 0.250 (60) 0.506 0.65 (145) 4065 (590) 0.47 X 0.62 1.22 X 1.74/15 31.5(180) 32(165) NP
1426 (35) (105 X 140) (275 X 390/15)
Filterweave 40/10 w pp 10 0.420 (40) 0.95 0.56 (125) 3445 (500) 0.36 X 0.31 1.18x 1.13115 26(150) 29(165) NP
2852 (70) (80 X 70) (265 X 255115)
Filterweave 40130A w pp 20 0.420 (40) 2.14 0.51 (115) 2756 (400) 0.40 X 0.22 1.45 X 0.89115 31 (175) 19(110) NP
5907 (145) (90 X 50) (325 X 200/15)
Mirafi HPSOOX w pp 1 0.210 (70) 0.1 0.80 (180) 4823 (700) 0.53 X 0.82 1.49 X 1.89117 NA NA NP
326 (8) (120 X 140) (335 X 425117)
Nicolon HPSOO w pp 8 0.595 (30) 1.5 0.65 (145) 4995 (725) 0.65 X 0.56 1.78 X 1.49115 40 (230) 39 (225) NP
4685 (115) (145 X 125) (400 X 335115)
Nicolon HP550 w pp 6 0.420 (40) 0.96 0.73 (165) 4789 (695) 0.65 X 0.56 1.89 X 1.56/21 47 (270) 39 (225) NP
2852 (70) (145 X 125) (425 X 350121)
Nicolon HP565 w pp NA 0.420 (40) 0.07 0.89 (200) 8268 (1200) 0.78 X 0.96 2.23 X 2.23110 61 (350) 66 (375) NP
204(5) (175 X 215) (500 X 500/10)
Nicolon HP570 w pp NA 0.595 (30) 0.4 0.71 (160) 8268 (1200) 0.80 X 0.80 1.85 X 1.82/8 70 (400) 70(400) NP
1222 (30) (180 X 180) (415 X 410/8)
Mirafi 140Nl NW pp NA 0.210 (70) 2.0 0.24 (55) 1275 (185) 0.16 0.40 NA NA NP
4481 (110) (35) (90)150
Mirafi 140NC NW pp NA 0.210 (70) 1.5 0.31 (70) 1654 (240) 0.22 0.49 X 0.58/50 NA NA NP
4889 (120) (50) (110 X 130/50)
Mirafi 140N NW pp NA 0.210 (70) 1.5 0.31 (70) 1654 (240) 0.22 0.53 NA NA NP
4889 (120) (50) (120V50
Mirafi 160N NW pp NA 0.210 (70) 1.3 0.42 (95) 2239 (325) 0.27 0.67 NA NA NP
4481 (110) (60) (150)150
Mirafi 180N NW pp NA 0.177 (80) 1.5 0.58 (130) 2756 (400) 0.36 0.89 NA NA NP
4481 (110) (85) (200)150
Mirafi 1100N NW pp NA 0.149 (100) 1.2 0.71 (160) 3617 (525) 0.45 1.11 NA NA NP
3463 (85) (100) (250)150
All values were requested to be minimum average roll values and all I
[1] w :Woven (4] Reinlorcement applications only SIF "S1lt Fence claims are the responsibility of the manufacturer. All product data
=Nonwoven [5] SIS = Separat•onlstabiiiZabon = Other or combination
"" 0/C
·-
are intended as a guide and are not all-inclusive. Geotechnical 1
..""
0/C = Other or combinatiOn A = Reinforcement NA = Manufacturer (jetermined that this data was not
[2] PET =Polyester F =Filtration applicable to the produc:t or tl'le data was unavailable
.. PolypropJiena D =Drainage NP = Data not provi(jed by manufacturer Fabrics Report recommends you contact manufacturers before
p = PrOiection
0/C = Olhar or combination E =Erosion ContrtM making any specifying/purchasing decisions.
[3] Maximum opening size of tested rolls NO = Asphalt Overlay
Physical Properties Filtration/Hydraultc Properties Mechanical Properties
Mirafi 1160N NW pp NA 0.149 (100) 0.7 1.07 (240) 5512 (800) 0.65 1.69 NA NA NP
2037 (50) (145) (380)/50
Mirapave (3) NW pp NA 0.210 (70) NA 0.27 (60) 1378 (200) 0.16 0.40 NA NA NP
(35) (90)/55
MCF 1212 w PE NA NA NA 0.45 (100) 2963 (430) 0.22 X 0.22 0.89 X 0.89/15 NA NA NP
(typical values) (coated) (50 X 50) (200 x200115)
TSSOO NW pp NA 0.300 2.2 0.265 1380 0.220 0.510 8.8"' 8.8"' SIS, R, F, D,
135 (4) (50) 6720 (165) (60) (200) (50) (115) 50 (50)80 (50)30 P,E
TS550 NW pp NA 0.300 1.9 0.310 1655 0.265 0.580 9.6'"' 9.6'"' SIS, R,F, D,
170 (5) (50) 5700 (140) (70) (240) (60) (130)80 (55)30 (55) 30 P, E, SIF
TS600 NW pp NA 0.250 1.8 0.335 2000 0.310 0.710 10.51"1 10.5"' SIS, R, F, D,
205(6) (60) 5490 (135) (75) (290) (70) (160)50 (80)80 (80) 30 P,E
TS700 NW pp NA 0.212 1.3 0.445 2760 0.380 0.935 13.11"1 15.8"' SIS, R,F, D,
270 (B) (70) 4070 (100) (100) (400) (85) (210) 50 (75)60 (90) 30 P,E
TS750 NW PP NA 0.180 1.1 0.55c5 3105 0.445 1.11 15.81"1 17.&'1 SIS, R, F, D,
340(10) (80) 3260 (80) (125) (450) (100) (250) 50 (90)60 (100)40 P,E
;r--
0
0)
--- --------
Fihration/Hydraulic Properties
-------------- Mechanical Properties ·~-- -------·---- ----
Physrcal Prop ~rties
c
Polyfelt Americas Inc. (cont.)
is~~52~) NA
,. -· ·--· ',_, --
NA
-+:=[
The Reinforced Earth Co.
-
r ~- -~~;:.-
---~
pp 10 0.425140 1.36 (115) (500) (115 X 75) (365/24 X (200) (160) F,R
220110)
t_______-±_
pp 8 0.600130 1.5 (145) (725) (145 X 125) (400/20 X (230) (225) F, R
335115)
pp 6 0.425140 0.96 (165) (695) (145 X 125) (425/21 X (270) (225) F,R
350121)
ST35 NW PP NA 0.212 (70) 2.2/6110 (150) 0.24 (55) 1379 (200) 0.18(40) 0.42 (95) 50 NA NA SIS. F, D
ST40 NW pp NA 0_212 (70) 2.015700 (140) 0-26 (60) 1482 (215) 0.20 (45) 0.47 (105) 50 NA NA SIS, F,D
ST45 NW pp NA 0.212 (70) 1.815290 ( 130) 0-31 (70) 1793 (260) 0.22 (50) 0.53 (120) so NA NA SIS, F, D
STBO NW pp NA 0.180 (80) 1.514070 (110) 0.40 (90) 2140 (310) 0.29(65) 0.73 (165) 50 NA NA SIS, F. D, R,
P, E
ST70 NW PP NA 0.180 (80) 1.314480(110) 0.44 (100) 2276 (330) 0.33 (75) 0.89 (200) 50 NA NA SIS, F. D. R.
P. E
ST80 NW PP NA 0.180 (80) 1.213255 (80) 0.51 (115) 2482 (360) 0.39(85) 0.96 (215) 50 NA NA SIS, F, D. A,
P, E
ST100 NW pp NA 0.150 (100) 1.112850 (70) 0.67 (150) 3103 (450) 0.44 (100) 1.27 (285) 50 NA NA SIS. A.
P. E
ST120 NW pp NA 0.150(100) 0.812445 (60) 0.76 (170) 3793 (550) 0.51 (115) 1.45 (325) 50 NA NA SIS, R,
P, E
-- ------------ ---- - -·- - -----
[1) W =Woven [4) Reinforcement appl•cat•ons only S/F =Silt Fence All values were requested to be minimum average roll values and all
NW
OIC =
NOflW<:lven
Other or comb•natron
(5] SIS
R
= Separation /stabilization
=Reinforcement
0/C =Olher or combination
NA = Manufacturer !Setermtned that this data was not
claims are the responsibility of the manufacturer. All product data
f2J PET =Polyester F = F111ration applicable to the product or the data was <~nava•lat>le are intended as a guide and are not all-inclusive. Geotechnical
PP " Polypropylene D = Dra~nage NP "' Data no1 p10voded by manoJiacturer
PE " Polyf'thylene P =Protection [A) Typicalvalues Fabrics Report recommends you contact manufacturers before
OIC =Other or combmai!Oo E: = Erosoon Control
[3) Ma;.Omum opuning sile of tested rolls = AsphaltO\Ieriay
making any specifying/purchasing decisions.
Filtration/Hydraulic Properties Mechanical Properties
Phyaical Properties
91050" W/8"1 pp <1%~'~ 0.850 (20) 0.20 0.26 (58) 1826 (265) 0.22 X 0.22 0.45 X 0.45 NA NA SIF
611 (15) (50x 50) (100 X 100)/15 X 15
91350" W/S"l pp <1%1111 0.850 (20) 0.05 0.16 (35) 1826 (265) 0.22 X 0.18 0.45 X 0.45 NA NA S/F
122 (3) (50 X 40) (100 x 100)19x 13
914SC WICI"' pp 4.4%141 0.600 (30) 0.90 0.27 (60) 2411 (350) 0.27 X 0.27 0.67 X0 45 NA NA S/F
3055 (75) (60 X 60) (150 X 100)/15 X 15
994 WiS"' PP <1%1111 0.600 (30) 0.04 0.31 (70)'" 1860 (270) 0.22 X 0.18 0.62 X 0.42 NA NA S/F
81 (2) (50 X 40) (140 )( 95)115 X 15
200ST WI&" pp <1%1111 0.600 (30) 0.07 0.45 (100) 3101 (450) 0.38 X 0.40 0.89 X 0.89 21.0 (120) 21.0(120) SIS, R, E
244(6) (85 X 90) (200x200)115x15
JOOST WI&" pp <1%181 0.600 (30) 0.06 0.53 (120) 4134 (600) 0.53 X 0.53 1.33x 1.33 30.6 (175) 30.6 (175) SIS, R, E
203 (5) (120 X 120) {300 X 300)/15 X 15
400R W/0"' pp <1%!111 0.600 (30) 0.60 0.62 (140) 8270 (1200) 0.82 X 0.85 NA 70.0 (400) 70.0 (400) SIS, R
1830 (45) (185x 190)
Erooion I WM" pp 4%"' 0.212 (70) 0.28 0.67 (150) 3307 (480) 0.42 x0.24 1.76x 1.16 NA NA SIS, E, F, D
732 (18) (95 X 55) (395 X 260)124 X 24
Erooion Ill WM" pp 5%"' 0.425 (40) 0.30 0.62 (140) 3548 (515) 0.44 X 0.27 1 sox 1.16 NA NA SIS, E, F, D
1220(30) (100 X 60) (360 X 260)120 X 20
Erooion V WM" pp 11%tal 0.600 (30) 1.10 0.58 (130) 3548 (515) 0.44 X 0.36 1.60x 1.16 NA NA SIS, E. F, D
4475 (110) (100 X 80) (360 X 260)/27 X 15
Erooion X WM' pp 17%1111 0.850 (20) 1.50 0.60 (135) 2894 (420) 0.18 X 0.22 1.13x 1.22 NA NA E, F,O
8136 (200) (40 X 50) (255 X 275/20 X 15
Erooion XV WM' pp 3%"' 0.425 (40) 0.55 047 (165) 5546 (805) 0.53 X 0.53 1.47 X 1.94 28.0 (160)/ 30.6 (175)1 E, F,O,
1630(40) (120x 120) (330 X 435/15 X 20 12 12 SIS, R
381"' NW PP NA NA NA 0.27 (60) 1447 (210) 0.18 (40) 0.40 (90)150 NA NA AID
--~ - - ~-·----
(X)
[1]
(2]
w
NW
0/C
PET
PP
PE
0-
~woven
0-
" Other or combination
=Polyeeter
"Polypropylene
(4]
(5]
Ratnfoleement applicahons only
SIS
R
F
0
P
~ Separation /atabillzatJOn
=Remlorcemenl
"Filtration
=Dnur~age
"Pmtection
SIF
0/C
=Sii!Fance
"'O!her or combination
NA " Manu1acturar cietermmed ltlatlhis data was not
applicable to the prodUCT or the data was unava!lable
NP = Data not provided by manufacturer
[A] Typical or average value reported in absence at MAAV
!CJ
[01
!Fl
projection test
Product calelldared lor pavement overlay appl1cat1on
IndiCates products available either wittl or w1thout
drawstringfunctiOfl
[E) Wovenshll1lm
Woven monofilament
All values were requested to be minimum average roll values and all
claims are the responsibility of the manufacturer. All product data
are Intended as a guide and are not all-Inclusive. Geotechnlclll
Fabrics Report recommends you contact manufacturers before
0 OIC "' Other or combination E
A/0
" ErosiOn Control
= Asphah Overlay [B] "'"
Area ol openings +total area oetermmed trom a hgtll
!Gl Woven combination
making any specifying/purchasing decisions.
[3) Ma.Kimum opening size of tested rolls
-...!
OJ Rltralion/Hydraulic Properties Mechanical Properties
0 Physical Properties
OJ
Percent Wide Widlll Tensile Elongation"'
Product Name Open Area Apparent PsrmlttivilyASTM Mullen Trapezoid Grab/Tensile ASTM045115-86
(wovens only) Opening Siz.,.. 04491-92 Puncture Burst Tear Strenglh Elongation kNim (lbiin) Manufacturer's
Polymer CW0-22125 ASTM 04751-87 sec-1/Fiow Rate ASTM 0 4833-88 ASTM 0 3788-87 ASTM 0 4533-91 ASTM 0 4632-91 SUgges18d
[Maaoperunrt]
g/~(oz/y#) Structurel' 1 Composition"' % mm(U.S.sitMt) Vmi.vm2 (gaVminm2)
-
kN(Ib) kPs (psi) kN (lb) kN(Ib)% MD
I XO Applicstiono"'
351 NW pp NA 0.212 (70) 2 0.24(55) 1275 (185) 0.16 (35) 0.4 (90)/50 NA NA F, D, E
4462 (110)
401 NW pp NA 0.212 (70) 2 0.29 (65) 1550 (225) 0.2 (45) 0.44 (100)/50 NA NA F,O,E
5704 (140)
451 NW pp NA 0.212 (70) 1.5 0.31 (70) 1654 (240) 0.22 (50) 0.53 (120)/50 NA NA F, 0, E
4889(120)
501 NW pp NA 0.212 (70) 1.4 0.38 (85) 1894 (275) 0.25 (57) 0.60 (135)/50 NA NA F, 0, E, SIS
4686 (115)
601 NW pp NA 0.212 (70) 1.3 0.42(95) 2239 (325) 0.27 (60) 0.67 (150)/50 NA NA F, D, E, SIS
4482 (110)
701 NW pp NA 0.212 (70) 1.5 0.49(110) 2411 (350) 0.33 (75) 0.8 (180)/50 NA NA F, D, E, SIS
4482 (110)
801 NW pp NA 0.18(80) 1.5 0.56 (130) 2756 (400) 0.38 (85) 0.89 (200)/50 NA NA F, 0, E, SIS
4482 (110)
1001 NW pp NA 0.15 (100) 1.2 0.71 (160) 3514 (510) 0.44 (100) 1.11 (250)/50 NA NA F. D, P, SIS
3463 (85)
1201 NW pp NA 0.15(100) 1.0 0.8 (180) 4134 (600) 0.51 (115) 1.33 (300)/50 NA NA F, D, P, SIS
3056 (75)
1601 NW PP NA 0.15(100) 0.7 1.07 (240) 5512 (800) 0.64 (145) 1.69 (380)/50 NA NA F,D, P,S/S
2037 (50)
----- - -
Texellnc. Texellnc.
Texel7643 NW PET, PP NA 0.06-Q.1 0.22 NP 10200 1.3(293) 3.2 (720)1 NA NA E
1460 (230-140) (1479) 65-95
Texel918 NW PET, PP NA 0.065-0.09 0.68 NP 3500 0.6 (135) 1.350 (304)/ NA NA E, P (liner)
475 (230-170) (508) 50-70
TNS A100 NW pp NP 125 0.90 (75) (180) (500) (110) (250)/50 NP NP S/S,D,E,P,R
339(10.0) (120)
TanaTexHD w pp <1 0.21 (70) 0.02 (2) (120) (600) (120) (300)115 (175V10 (175V10 SIS, P, E
-- --- - - --- -- -- -- - --- -
(1) w
----
·- J4)Reintorcern.nl~only SIF =Silt Fa1ce
All values were requested to be minimum average roll values and all
claims are the responsibility of tha manufacturer. All product data
--
·-
(51 SIS = Separationltdabillzatlol'l 0/C "' Other or combir'IS.b0!1
""
.""'
NA "' Manufaduret determined !hal this data was not are Intended as a guide and are not all·incluslve. Geotechnlclll
OIC "'Otherotcombinlllion
" =Rainfolcemant
·-
(2JI'ET F =FIItnltion applicablalo lhe producl or !he data. was unavailable
.... D
p
.. o..;nage NP .. o.tanotprovicledbymanufecturer Fabrics Report recommends you contact manufacturers before
making any specifying/purchasing decisions.
OD
{31
• Olher or eombiMIIon
.......... cpening.U.oflllltldn*
E
MJ
........ """""
•Erosion Control
0
co
(X)
~--
!
...... Physical Properties Filtration/Hydraulic Properties MechanicaJ Properties
0
Percent Wkie Width Tensile Elongationl•l
Open Area Apparent Permittivity ASTM MUllen Trapezoid Grab/Tensile ASTM D 4595-86
I
(wovens only) Opening SizeP1 D 4491-92 Puncture Burst Tear Strength Elongation kN/m(lblin) Manufacturer's
Mass per unit ] Polymer CW0-22125 ASTM 0 4751-87 sec·1/Fiow Rate ASTM 0 4833-88 ASTM D 3786-67 ASTM D 4533-91 ASTM 0 4632-91 Suggested
g/~(ozJy<J2) Structure''1 Compositionl2 1 % mm (U.S. sieve) Vmin/~ (gaVminm2) kN (lb) kPa (psi) kN (lb) kN (lb)% MD XD Applications1' 1
I
Webtec Inc. (cont.) Webtec Inc. (cont.)
TerraTex GS w pp <1 0.30 (50) 0.04(4) (90) (400) (75) (200)/15 (120)/10 (175)/10 SIS. P, E
Terra Tax GS-150 w PP <1 0.~(30) 0.04 (4) (65) (325) (45) (140)/15 NA NA SIS, E
TerraTex SC w pp <1 0.60 (30) 1.3 (15) (60) (340) (80) (120)/20 NA NA SIF
Terra Tex 802 NW pp NA 0.60 (30) 1.0 (110) (18) (65) (25) (60)/60 NA NA D. F
TerraTex N03 NW pp NA 0.59 (30) 2.0 (110) (50) (170) (25) (80)/50 NA NA D.F
TerraTex N04 NW pp NA 0.21 (70) 2.2 (150) (55) (200) (40) (95)/50 NA NA D. F
TerraTex 804 NW pp NA 021 (70) 0.7 (55) (40) (140) (60) (130)/60 NA NA P, F, SiS
TerraTex NOS (5.0) NW pp NA 021 (70) 1.6 (110) (80) (270) (55) (135)/50 NA NA D. F, SIS
Terralex N06 (6.0) NW pp NA 0.18 (80) 1.5(100) (90) (310) (65) (165V50 NA NA F/D, SIS
TerraTex NOS (8.0) NW pp NA 0.18 (80) 1.2 (80) (115) (360) (85) (215)/50 NA NA P. F. E
TerraTex N010 (10.0) NW pp NA 0.15 (100) 1.1 (70) (150) (450) (100) (285)/50 NA NA P, F, SIS
TerraTex N012 (12.0) NW pp NA 0.15 (100) 0.8 (60) (170) (550) (115) (325)/50 NA NA P, F, SIS
TerraTex N016 (16.0) NW pp NA 0.12 (120) 0.6 (45) (250) (750) (165) (425)/50 NA NA P. F. SiS
-
(5] SIS = SeparationlstabiiiZ<I.IIon 0/C = Other or combination
o'c other or comblnatu)n R = Re•nforcement NA = Manufacturer determined that thiS data was not
(2] PET
pp
Polyester F ~ Foltratlorl applicable to the product Of the data was unavailable are intended as a guide and are not all-inclusive. Geotechnical
Polyplopylene D = Dramage NP = Data not provided by manulacturer
PE P = Protec11on Fabrics Report recommends you contact manufacturers before
o'c O ther or combtnatiOO e ~ ErOSIOn Control
making any specifying/purchasing decisions.
f3J Max1mum open•ng s1ze of tested rolls AJO = Asphalt Overlay
Phystcal Properties Filtration/Hydraulic Properties Mechanical Properties
W0400 NW PET NA 100 1.04 (70) (130) (425) (110) 85 (120) NP R, P, SIS, E
400(12)
WQ475 NW PET NA 100 0.97 (65) (165) (525) (120) 85 (155) NP R. P. SIS
475 (14)
WQ550 NW PET NA 100 0.90 (60) (200) (590) (135) 85 (185) NP R.P,SIS
550 (16)
All values were requested to be minimum average roll values and all
--
(1] w •Woven (4] Aeinloroe!neotapplk:atiorlsonly SIF ""SiltF.-.ce
claims are the responsibility of the manufacturer. All product data
(5] SIS '" Seplrationlstabllizattoo OIC • Other or combinatKm
•OII'Ieforoomlliodor1 NA = Manullctu!W dllermined lhatlhis data was not
QIC
NW · -
F '"Altratloo eppllcabletolheproductorltlecletawasunavailabje
are Intended as a guide and are not all-Inclusive. Geotechnical
.
R · -
121 PET ·- 0 '"Drainage NP = o.t. not provided by manufllcturer Fabrics Report recommends you contact manufacturers before
co
..... pp
ewe
- -
•Dift.or~
p
E
.. Protection
.. E!'Qelon Control making any speclfylngfpurchaslng decisions.
..... (31 Mlldrnlllfl opeMig lim of -.a.d , . MJ .. Aephalt()yerlay
Appendix 4
Characteristics, Industrial Uses, and Manufacturers
of Major Generic Fibers and Trade Names*
*Sources: American Fiber Manufacturers Association, Textile World Man-Made Fiber Chart, McLean Hunter Publication,
Fiber Manufacturers.
812
Fiber Manufacturer Major Characteristics Industrial and Home Furnishing Uses
ACETATE ............................................... Luxurious feel and appearance; wide range of Cigarette filters, draperies, upholstery,
Celebrate! Hoechst Celanese Corporation colors and lusters; excellent drapeability and fiberfill for pillows, quilted products
Chromspun Eastman Chemical Products softness; relatively fast drying; shrink-,
Estron Eastman Chemical Products moth- and mildew-resistant
Celanese Hoechst Celanese Corporation
ACRYLIC ................................................ Soft and warm, wool-like, lightweight; re- Auto tops, awnings, geotextiles,
Acrilan Monsanto Chemical Company tains shape; resilient; quick drying; resistant various industrial fabrics, blankets,
Creslan Cyctec Industries to moths, sunlight, oil and chemicals carpets, draperies, upholstery
Duraspun Monsanto Chemical Company
Du-Rel Monsanto Chemical Company
Fi-lana Monsanto Chemical Company
Orion E. I. du Pont de Nemours & Company, Inc.
Pil-Trol Monsanto Chemical Company
Zefkrome Mann Industries, Inc.
Zefran Mann Industries, Inc.
ARAMID ................................................ No melting point; highly flame and temper- Hot-gas filtration fabrics, protective
Kevlar E. I. du Pont de Nemours & Company, Inc. ature resistant; high strength; high modulus clothing, military helmets, protective
Nomex E. I. duPont de Nemours & Company, Inc. vests, structural composites for aircraft
Twaron Akzo Industrial Fibers and boats, sailcloth, tires, ropes and
cables, mechanical rubber goods,
marine and sporting goods
CARBON ................................................ Does not melt; high tensile strength Composites; conductive fabrics
Thorne! Amoco Fabrics and Fibers Co.
AS-4 Hercules, Inc.
AS-6 Hercules, Inc.
T40 To ray
T300 Union Carbide/Toray
Celion Hoechst Celanese Corporation/ ToHo
HMS-4 Hercules, Inc.
PAN 50 To ray
GY-70 Hoechst Celanese Corporation
. P-55 Union Carbide
CXl
......
(o) (continued)
<XI
......
.j:o.
Fiber Manufacturer Major Characteristics Industrial and Home Furnishing Uses
GLASS .................................................. Does not burn; resists alkalis and acids Composites, insulation, sporting
Glass Owens/Corning goods, marine products
PPG Industries
LYOCELL ............................................... Good resistance to aging, sunlight and Similar to cotton
Tencel Courtaulds Fibers Inc. abrasion
MODACRYLIC ........................................... Soft, resilient, abrasion and flame resistant; Industrial fabrics, filters, paint rollers,
SEF Monsanto Chemical Company quick drying; resists acids and alkalis; retains stuffed toys, nonwoven fabrics,
shape awnings, blankets, carpets, flame-
resistant draperies and curtains, knit
pile fabric backings
NYLON ................................................. Exceptionally strong; supple, abrasion resis- Air hoses, conveyor belts, seat belts,
A.C.E. AlliedSignal Inc. tant; lustrous; easy to wash; resists damage parachutes, racket strings, ropes and
Anso AlliedSignal Inc. from oil and many chemicals; resilient nets, sleeping bags, tarpaulins, tents,
Antron E. I. du Pont de Nemours & Company, Inc. thread, tire cord, geotextiles, raincoats,
Cantrece E. I. du Pont de Nemours & Company, Inc. ski and snow apparel, windbreakers,
Capima AlliedSignal Inc. bedspreads, carpets, draperies, cur-
Caplana AlliedSignal Inc. tains, upholstery
Caprolan AlliedSignal Inc.
Captiva AlliedSignal Inc.
Compet AlliedSignal Inc
Cordura E. I. du Pont de Nemours & Company, Inc.
Crepeset BASF Corporation
Hydrofil AlliedSignal Inc.
Patina AlliedSignal Inc.
Resistant BASF Corporation
Shimmereen BASF Corporation
Softglo BASF Corporation
Tolaram Tolaram Fibers, Inc.
Viyana BASF Corporation
Worry Free AlliedSignal Inc.
Zefsport BASF Corporation
Zeftron BASF Corporation
Fiber Manufacturer Major Characteristics Industrial and Home Furnishing Uses
OLEFIN ................................................. Unique wicking properties that make it very Geotextiles, filter fabrics, dye nets, au-
Alpha Amoco Fabrics and Fibers Company comfortable; abrasion resistant; quick drying; tomotive interiors, laundry and sand-
Essera Amoco Fabrics and Fibers Company resistant to deterioration from chemicals; bags, cordage, doll hair, industrial
Fibrilon Synthetic Industries mildew, perspiration, rot and weather resis- sewing thread, carpet and carpet back-
Genesis Amoco Fabrics and Fibers Company tance; sensitive to heat; soil resistant; strong; ing, slipcovers, upholstery
Herculon Hercules very lightweight; excellent colorfastness
Marquesa Lana Amoco Fabrics and Fibers Company
Marvess Amoco Fabrics and Fibers Company
Patlan Amoco Fabrics and Fibers Company
Spectra AlliedSignal Inc.
Synera Amoco Fabrics and Fibers Company
Trace Amoco Fabrics and Fibers Company
Tolaram Tolaram Fibers, Inc.
POLYESTER ............................................. Strong; resistant to stretching and shrinking; Fire hose, power belting, ropes and
A.C.E. AlliedSignal Inc. resistant to most chemicals; quick drying; nets, tire cord, sail, V-belts, fiberfill
Ceylon Hoechst Celanese Corporation crisp and resilient when wet or dry; wrinkle for various products, carpets, curtains,
Comfort Fiber Hoechst Celanese Corporation and abrasion resistant; retains heat set pleats draperies, sheets and pillow cases, in-
Compet AlliedSignal Inc. and creases; easy to wash sulated garments
Dacron E. I. du Pont de Nemours & Company, Inc.
E.S.P. Hoechst Celanese Corporation
Fortrel Wellman, Inc.
Golden Glow BASF Corporation
Golden Touch BASF Corporation
Hollofil E. I. duPont de Nemours & Company, Inc.
Kodaire Eastman Chemical
Kadel Eastman Chemical
KodOfill Eastman Chemical
KodOsoff Eastman Chemical
Pentron Hoechst Celanese Corporation
Polarguard Hoechst Celanese Corporation
(X)
(continued)
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(11
(X)
.....
m
Fiber Manufacturer Major Characteristics Industrial and Home Furnishing Uses
POLYESTER
Strialine BASF Corporation
Tolar am Tolaram Fibers, Inc.
Trevira Hoechst Celanese Corporation
Trevira Finesse Hoechst Celanese Corporation
Untra Touch BASF Corporation
PBI ..................................................... Highly flame resistant; outstanding comfort Suitable for high performance protec-
PBI logo Hoechst Celanese Corporation factor combined with thermal and chemical tive apparel such as firemens' turnout
stability properties; will not burn or melt; coats, astronaut space suits and appli-
low shrinkage when exposed to flame cations
RAYON ................................................. Highly absorbent; soft and comfortable; easy Medical/surgical products, tire, cord,
Beau-Grip North American Rayon to dye; versatile; good drapeability industrial products, bedspreads, blan-
Fibro Courtaulds Fibers Inc. kets, carpets, curtains, draperies,
sheets, tablecloths, upholstery
SPANDEX ................................... Can be stretched 500 percent without break- Surgical hose, ski pants, athletic ap-
Glospan/ ing; can be stretched repeatedly and recover parel
Clearspan, S-85 Globe original length; lightweight; stronger, more
Lycra E. I. du Pont de Nemours & Company, Inc. durable than rubber; resistant to body oils
SULFAR ................................................. High performance fibers with excellent resis- Filter fabric for coal-fired boiler bag
Ryton Amoco Fibers tance to harsh chemicals and high tempera- houses, paper machine clothing, elec-
tures; excellent strength retention in adverse trical insulation, electrolysis mem-
environments; flame retardant; non- branes, filter fabrics for liquid and gas
conductive filtration, high performance compos-
ites, gaskets and packings
VINYON ................................................. Softens at low temperature; high resistance to Used in industrial applications as a
Vinyon Hoechst Celanese Corporation chemical; non-toxic bonding agent for nonwoven fabrics
and products such as tea bags and auto-
motive headliners
Appendix 5
Derivation of Mathematical Equations
In Figure A5.1, if the helical path l' of each ply is The relationship among turns per inch, singles and
equal to l before plying, then L', the plied yarn plied yarn diameters for perfect cylindrical helices
length, must be less than L, the original untwisted can be shown to be
yarn length. The contraction or take-up can be calcu-
lated from the simple geometry of the structure: tan Q = 1rTDK
cos Q = L' !!' where
therefore D = 2d
(l' - l' cos Q) therefore
% c= l' 100 = (1 - cos Q) 100
(2d - d)/2d = 0.5
If the length of the plied yarn L' is known, the
length of the singles composing the ply l' can be For a three-ply yarn D/2 (Figure A5.2) is slightly
calculated as larger than d, and K is slightly larger than 0.5, the
theoretical value being 0.54.
l' =L'/cosQ It was shown that K ranges from 0.80 to 0.85 as the
817
818 APPENDIX 5
L=l
/ .....
(
\ I
•I
I ()
\.
' -- --
\
II
I
..... ...
... , .... ", ...... ..._ 1'
, , """'"'--........,
I ...... ....._.._--
plies increase from 16 to 30. Theoretically K will ap- 3. CORKSCREW YARN ANALYSIS
proach unity as the number of plies increases to in-
finity. Obviously in multi-ftlament singles yarns the The strength of a corkscrew yarn must always be
number of ftlaments becomes large and K will range less than the theoretical attainable if the yarn were
from 0.8 to 0.99. When ftlament or singles yarn cross free of corkscrew. This may be demonstrated by the
sections are not circular, instead of using diameters, examples in Figures A5.3 and A5.4.
radial distances from the plied yarn center to the In Figure A5.3 where a single ply is wrapped about
center of gravity of the singles should be employed. a central core of six, core yarn lengths lc are always
r
D
1
2 ply yarn model
kT
I
"" ,
/ /
""
where
(Py)tt2
TM = tanQ--
cpK
where
Py = yam density
FIGURE A5.4 Six yarns "corkscrewed" about a cen- cp = dimensional constant
tral core of yarn. K = (D- d)ld
820 APPENDIX 5
X.w
FIGURE A5.5 Cover factor diagram.
Referring to Figure A5.5, if w and fare warp and = (1/wf) - (1/w - dw)(llf- dt)
filling threads per inch, and dw and d1 are warp and
filling yarn diameters, fractional closed area (cover factor)
open area per fabric unit = (1/w - dw)(l/f- dt) cover factor = wdw + fdJ - wfdwdt
Appendix 6
Measurement Units
Sources:
-ASTM
- Mark's Standard Handbook for Mechanical Engineers, McGraw-Hill Book Company, 1978.
- Standard Mathematical Tables, CRC Press, 1982.
1 pint = 4 gills
1 quart = 2 pints
1 gallon = 4 quarts
1 cubic foot = 7.4805 gallon
dry measures
1 quart = 2 pints
1 peck = 8 quarts
1 bushel = 4 pecks
2. SI PREFIXES
multiplication factors prefix SI symbol
3. SI UNITS
Base Units
length meter m
mass kilogram kg
time second s
electric current ampere A
thermodynamic temperature kelvin K
amount of substance mole mol
luminous intensity candela ai
Derived Units
acceleration meter per second square rnJs2
area square meter m2
density kilogram per cubic meter kg/m3
energy joule J N.m
force newton N kg.m/s2
frequency hertz Hz lis
power watt w J/s
pressure pascal Pa Ntm2
velocity meter per second m/s
voltage volt v W/A
volume cubic meter m3
work joule J N.m
1 meter = 100 em = 1000 millimeter
1 kilogram = 1000 gram
1 angstrom = 10-8 centimeter
Measurement Units 823
1 yard= 0.9144 m
1 inch= 25.4 nun
1lb = 0.453 59 kg= 453.59 g
to ::et multiply
US Customery to Metric
to :;et multioly
5. TEMPERATURE CONVERSION
°F = 9/5 (°C) + 32
825
826 Index
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