CHƯƠNG 6:

CÂN BẰNG PHA HỆ MỘT CẤU TỬ

2
3
4
5
6
7
8
9
10
11
12
 13

using Eq. 6.4-25 at constant temperature

14
 15

Fugacity of a Pure Gaseous Species

P (MPa) Vˆ (m3/kg) V (m3/mol) [V - RT/P] (m3/mol)×104 16
0.01 26.445 0.47641 -1.020 -0.005
0.05 5.284 0.095191 -1.121 -0.043
0.1 2.639 0.047542 -1.101 -0.056
0.2 1.3162 0.023711 -1.145 -0.112
0.3 0.8753 0.015769 -1.154 -0.115
0.4 0.6548 0.011796 -1.167 -0.116
0.5 0.5226 0.0094146 -1.157 -0.116
0.6 0.4334 0.0078077 -1.342 -0.125
0.8 0.3241 0.0058387 -1.178 -0.252
1.0 0.2579 0.0046461 -1.191 -0.237
1.2 0.2138 0.0038516 -1.194 -0.239
1.4 0.18228 0.0032838 -1.199 -0.239
1.6 0.15862 0.0028575 -1.207 -0.241
1.8 0.14021 0.0025259 -1.214 -0.242
2.0 0.12547 0.0022603 -1.222 -0.244
2.5 0.09890 0.0017817 -1.244 -0.617
3.0 0.08114 0.0014617 -1.267 -0.628
3.5 0.06842 0.0012326 -1.289 -0.639
4.0 0.05884 0.0010600 -1.313 -0.651
4.5 0.05135 0.0009251 -1.339 -0.663
5.0 0.04532 0.0008164 -1.366 -0.676
6.0 0.03616 0.0006514 -1.428 -1.397
7.0 0.02947 0.0005309 -1.498 -1.463
8.0 0.02426 0.0004370 -1.586 -1.542
-10.656
 17

Fugacity of a Pure Gaseous Species

 18

Fugacity of a Pure Gaseous Species

19
20
21
22
23
 24

For hand calculations it is simpler, but less accurate, to compute the fugacity of
a species using a specially prepared corresponding-states fugacity chart.
25
 26

Fugacity coefficient Peng-Robinson equation of state

27
 28

Best approximation for fL

29
30
31
32
33
34
35
36
37
 38

two-phase mixture
39
40
41
 42

1/ Clausius-Clapeyron equation is reasonably accurate for estimating the

temperature dependence of the vapor pressure over small temperature ranges.

2/ Antoine equation is commonly used to

correlate vapor pressures accurately over
the range from 1 to 200 kPa.

3/ Riedel equation

4/ Harlecher-Braun equation is reasonably accurate from low vapor pressure

up to the critical pressure.
43
44
45