Themodynamics (HK)

poroces to
Un der a diabaic condeions, the co9et
condition ig Adiabahic astem does not
a AT= 0 b) Ap=D
d) w=O
exchamge heat with qwomdimgs.

4U ob combutin ob me thane is
-X K+/mde
to have
+ve enthopt
(8) (3) (a) bound
A+8’c+D+
) A uaction, be
heaction
The at
change b) Po5jbe
a) Pogible at hig h T T
Po-%i6a at any
%ible al T
) mot Po
AH-TAS AG
Here, AH=-Ve (AG-Ve at ay Temp tem and
AS=+e
ke at is abtobed by a
Jhat i4 the chamge
) In done by ehe
39 the PSOces ?
in intehnal enen
Ytem(G) = 1013
Heak absbed by the
wK done by the
gystem (y -34 J

and
at 948 K eaction be come
5) F& he
Nhal temp coytant oveh the
and AS be

3pontaneouy considern?

emp 5amge ?TAS = AH

AG AH-TAS = 200o K
= 400
T= AH
at eg AG=o AS
O= AH-TAS
319ng ob AH and AS.
ae the
them, What
eacton,

but aS=-ve
Ca) (8)
9eacton i I0.
Conytamt a
euiB5jUm
) TÁe
he Value ob AG ?
k
- 2303 RT Jag.
AG ==-2°303 *8314 x3oo

J/moe.
= - 5744 14
 ublmation ot gubgtance i8 22wal to (HK
Enttalpy
+ AH
ra) AH busion Va pourisaGon
AH"vapouis«hon
) twice the
b) AH busion ) ARyapoisation
nd out
thehmo chemi Cal euaton i) (i1),(i)
Gn the baig
adgeboie nelahionghip
(i) C

i)
LO)
) (3)
3) ()

The emthalpies element ther gtandahd tatis

(10
ahe t a km Compound

i4 always -Ve

+ve
)
-ve
be 4Ve

a) i mevehve

- 91-g KJ/mole.
cal culat the AH & the
bo.llowing
’Ng + 3 Ha
eac n ;
(a)
Aevesye the sation
KJ At=+183"6
NH3 AH = l8 mle N, + 3H1
(8) 2-NHa
AH=83:b e
(8) uaion
atoisation bA the
2
T L8)emthalpy ot a)
K5/mae. what is the

bond enent ot c-H bond ?

AH 1665
CH
c-H Bond emei
mee
(3) Givem that AMO gases . Explain (HK)
each o the
whethe dibtugion theye

contain 5pentane ous

closed but AS ig +ve.
Though the

The t e n TAS will be -ve, hen (e

les than
aceton
vapowisation
T mota enthelpy
that wate why ?
bakw een wate
walen is due to H-bond'ng
a vopouris ahion otor
moeules at
will be
a nd
Buanitt ut
wich

+ RT Jn, K

=-RT ne K
fntarnal eme an igolated tem
Predit ehe change
at conyt voune
i40laid ystem, t cost velume
N=0 6 B=0

Va ceUm
thee ex pannion
called
Exfnnon
w k done nd the Change in imtnal enent
imto Vaccum
calaulate the expands isothenmaly
ideal
when 5 itey
total vume
ox( 5-)= o
- P(YA-v,) = -
8=0
johermal expangion

axkengive psopet but speibic heat c)

between
) Heat capa iby eJ whet will be the nelation
intensive
mole
and
heat
pacity ot walirz 18 x specioic
He at ca p 18xc

K-nde.
 calate the dibtreence betwem Cp and Cy lo moag
HK)
jdea

calculate the heat

B0.5
The AHvepouisation
. ot cl at congt e
vapowisation ot 284
the
euíed
mays
(mda egujs= 305
154 ob c y

154
u4ed
(2) wjl CoTnp9Bion can beN K
w k done 6n ideal repssen t the
60
dene shaded aea
gay im
Lompeynon, gepesents theNK
when change n the .
dene
owt in
is cased
imbim te gtep3?

20
state 1
L-0 mole otb mono atomic as
to gtat 2
eypanded
calaulat the wK --}-stk
ghown in bi as tom
done 298 K 22
gtale 2. at
7
gtate
that he
seveible epansjon
is0thehmal
-Q3o3 n T

mAT Jo, P . =-A303 x Ix8-314 X298 0

- R303
NAich ob ehe bo lowing pV usve supssents
matimu done ?
it0theNmal
is0hen ) o- d)
-Hemal