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Q.21
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Question ID : 3666942509
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Question ID : 3666942501
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Question ID : 3666942504
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Question ID : 3666942502
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Question ID : 3666942510
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Q.50
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Q.51
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Question Type : SA
Question ID : 3666942531
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Question ID : 3666942537
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Question ID : 3666942540
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Q.54
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Question ID : 3666942534
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Question ID : 3666942533
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Question ID : 3666942532
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Q.57
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Question ID : 3666942539
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Question ID : 3666942538
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Q.59
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Question ID : 3666942535
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Q.60
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Question ID : 3666942536
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Q.79
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Q.80
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Q.81
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Answer :
Question Type : SA
Question ID : 3666942562
Status : Not Answered
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Q.82
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Question ID : 3666942570
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Q.83
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Question ID : 3666942561
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Q.84
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Question ID : 3666942565
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Q.85
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Question ID : 3666942566
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Q.86
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Answer :
Question Type : SA
Question ID : 3666942564
Status : Not Answered
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Q.87
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Question Type : SA
Question ID : 3666942567
Status : Not Answered
Q.88
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Question Type : SA
Question ID : 3666942569
Status : Not Answered
Q.89
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Question ID : 3666942563
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Q.90
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Answer :
Question Type : SA
Question ID : 3666942568
Status : Not Answered
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Q.20
Options 1.
2.
3.
4.
Q.21
Given 21
Answer :
Question Type : SA
Question ID : 7155051192
Status : Answered
Q.22
Given 2
Answer :
Question Type : SA
Question ID : 7155051191
Status : Answered
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S18D60970/16752… 10/34
02/02/2023, 21:48 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.23
Given --
Answer :
Question Type : SA
Question ID : 7155051196
Not Attempted and
Status :
Marked For Review
Q.24
Given 2
Answer :
Question Type : SA
Question ID : 7155051197
Status : Answered
Q.25
Given 44
Answer :
Question Type : SA
Question ID : 7155051198
Status : Answered
Q.26
Given --
Answer :
Question Type : SA
Question ID : 7155051195
Status : Not Answered
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S18D60970/16752… 11/34
02/02/2023, 21:48 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.27
Given --
Answer :
Question Type : SA
Question ID : 7155051199
Status : Not Answered
Q.28
Given --
Answer :
Question Type : SA
Question ID : 7155051193
Status : Not Answered
Q.29
Given --
Answer :
Question Type : SA
Question ID : 7155051194
Status : Not Answered
Q.30
Given 45.6
Answer :
Question Type : SA
Question ID : 7155051200
Status : Answered
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S18D60970/16752… 12/34
02/02/2023, 21:48 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.31
Options 1.
2.
3.
4.
Q.32
Options 1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S18D60970/16752… 13/34
02/02/2023, 21:48 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.33
Options 1.
2.
3.
4.
Q.34
Options 1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S18D60970/16752… 14/34
02/02/2023, 21:48 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.35
Options 1.
2.
3.
4.
Q.36
Options 1.
2.
3.
4.
Q.37
Options 1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S18D60970/16752… 15/34
02/02/2023, 21:48 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.38
Options 1.
2.
3.
4.
Q.39
Options 1.
2.
3.
4.
Q.40
Options 1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S18D60970/16752… 16/34
02/02/2023, 21:48 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.41
Options
1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S18D60970/16752… 17/34
02/02/2023, 21:48 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.42
Options 1.
2.
3.
4.
Q.43
Options 1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S18D60970/16752… 18/34
02/02/2023, 21:48 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.44
Options
1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S18D60970/16752… 19/34
02/02/2023, 21:48 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.45
Options
1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S18D60970/16752… 20/34
02/02/2023, 21:48 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.46
Options 1.
2.
3.
4.
Q.47
Options 1.
2.
3.
4.
Q.48
Options 1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S18D60970/16752… 21/34
02/02/2023, 21:48 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.49
Options 1.
2.
3.
4.
Q.50
Options 1.
2.
3.
4.
Q.51
Given 1583
Answer :
Question Type : SA
Question ID : 7155051221
Status : Answered
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S18D60970/16752… 22/34
02/02/2023, 21:48 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.52
Given 0.7
Answer :
Question Type : SA
Question ID : 7155051226
Status : Answered
Q.53
Given --
Answer :
Question Type : SA
Question ID : 7155051224
Status : Not Answered
Q.54
Given --
Answer :
Question Type : SA
Question ID : 7155051227
Status : Not Answered
Q.55
Given --
Answer :
Question Type : SA
Question ID : 7155051223
Status : Not Answered
Q.56
Given --
Answer :
Question Type : SA
Question ID : 7155051222
Status : Not Answered
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S18D60970/16752… 23/34
02/02/2023, 21:48 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.57
Given 2
Answer :
Question Type : SA
Question ID : 7155051229
Status : Answered
Q.58
Given 3
Answer :
Question Type : SA
Question ID : 7155051228
Status : Answered
Q.59
Given --
Answer :
Question Type : SA
Question ID : 7155051225
Status : Not Answered
Q.60
Given 13
Answer :
Question Type : SA
Question ID : 7155051230
Status : Answered
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S18D60970/16752… 24/34
02/02/2023, 21:48 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.61
Options 1.
2.
3.
4.
Q.62
Options 1.
2.
3.
4.
Q.63
Options
1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S18D60970/16752… 25/34
02/02/2023, 21:48 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.64
Options
1.
2.
3.
4.
Q.65
Options 1.
2.
3.
4.
Q.66
Options 1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S18D60970/16752… 26/34
02/02/2023, 21:48 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.67
Options 1.
2.
3.
4.
Q.68
Options
1.
2.
3.
4.
Q.69
Options
1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S18D60970/16752… 27/34
02/02/2023, 21:48 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.70
Options 1.
2.
3.
4.
Q.71
Options
1.
2.
3.
4.
Q.72
Options 1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S18D60970/16752… 28/34
02/02/2023, 21:48 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.73
Options
1.
2.
3.
4.
Q.74
Options
1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S18D60970/16752… 29/34
02/02/2023, 21:48 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.75
Options 1.
2.
3.
4.
Q.76
Options 1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S18D60970/16752… 30/34
02/02/2023, 21:48 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.77
Options
1.
2.
3.
4.
Q.78
Options
1.
2.
3.
4.
Q.79
Options 1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S18D60970/16752… 31/34
02/02/2023, 21:48 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.80
Options 1.
2.
3.
4.
Q.81
Given --
Answer :
Question Type : SA
Question ID : 7155051260
Status : Not Answered
Q.82
Given 14
Answer :
Question Type : SA
Question ID : 7155051258
Status : Answered
Q.83
Given 0
Answer :
Question Type : SA
Question ID : 7155051255
Status : Answered
Q.84
Given 2
Answer :
Question Type : SA
Question ID : 7155051256
Status : Answered
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S18D60970/16752… 32/34
02/02/2023, 21:48 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.85
Given 0
Answer :
Question Type : SA
Question ID : 7155051253
Status : Answered
Q.86
Given --
Answer :
Question Type : SA
Question ID : 7155051259
Status : Not Answered
Q.87
Given --
Answer :
Question Type : SA
Question ID : 7155051254
Status : Not Answered
Q.88
Given --
Answer :
Question Type : SA
Question ID : 7155051257
Status : Not Answered
Q.89
Given --
Answer :
Question Type : SA
Question ID : 7155051252
Status : Not Answered
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S18D60970/16752… 33/34
02/02/2023, 21:48 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.90
Given 2
Answer :
Question Type : SA
Question ID : 7155051251
Status : Answered
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S18D60970/16752… 34/34
02/02/2023, 22:09 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.1
Options 1.
2.
3.
4.
Q.2
Options 1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S1D38832/1674967… 1/32
02/02/2023, 22:09 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.3
Options 1.
2.
3.
4.
Q.4
Options 1.
2.
3.
4.
Q.5
Options 1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S1D38832/1674967… 2/32
02/02/2023, 22:09 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.6
Options
1.
2.
3.
4.
Q.7
Options 1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S1D38832/1674967… 3/32
02/02/2023, 22:09 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.8
Options 1.
2.
3.
4.
Q.9
Options 1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S1D38832/1674967… 4/32
02/02/2023, 22:09 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.10
Options
1.
2.
3.
4.
Q.11
Options 1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S1D38832/1674967… 5/32
02/02/2023, 22:09 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.12
Options 1.
2.
3.
4.
Q.13
Options 1.
2.
3.
4.
Q.14
Options
1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S1D38832/1674967… 6/32
02/02/2023, 22:09 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.15
Options 1.
2.
3.
4.
Q.16
Options
1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S1D38832/1674967… 7/32
02/02/2023, 22:09 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.17
Options 1.
2.
3.
4.
Q.18
Options 1.
2.
3.
4.
Q.19
Options 1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S1D38832/1674967… 8/32
02/02/2023, 22:09 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.20
Options 1.
2.
3.
4.
Q.21
Given --
Answer :
Question Type : SA
Question ID : 7155051461
Status : Not Answered
Q.22
Given --
Answer :
Question Type : SA
Question ID : 7155051468
Status : Not Answered
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S1D38832/1674967… 9/32
02/02/2023, 22:09 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.23
Given 13
Answer :
Question Type : SA
Question ID : 7155051462
Status : Answered
Q.24
Given 12.05
Answer :
Question Type : SA
Question ID : 7155051465
Status : Answered
Q.25
Given --
Answer :
Question Type : SA
Question ID : 7155051466
Status : Not Answered
Q.26
Given 40
Answer :
Question Type : SA
Question ID : 7155051463
Status : Answered
Q.27
Given 25
Answer :
Question Type : SA
Question ID : 7155051467
Status : Answered
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S1D38832/167496… 10/32
02/02/2023, 22:09 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.28
Given --
Answer :
Question Type : SA
Question ID : 7155051464
Status : Not Answered
Q.29
Given --
Answer :
Question Type : SA
Question ID : 7155051470
Status : Not Answered
Q.30
Given 0.05
Answer :
Question Type : SA
Question ID : 7155051469
Status : Answered
Q.31
Options 1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S1D38832/167496… 11/32
02/02/2023, 22:09 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.32
Options 1.
2.
3.
4.
Q.33
Options
1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S1D38832/167496… 12/32
02/02/2023, 22:09 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.34
Options 1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S1D38832/167496… 13/32
02/02/2023, 22:09 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.35
Options
1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S1D38832/167496… 14/32
02/02/2023, 22:09 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.36
Options 1.
2.
3.
4.
Q.37
Options 1.
2.
3.
4.
Q.38
Options 1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S1D38832/167496… 15/32
02/02/2023, 22:09 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.39
Options 1.
2.
3.
4.
Q.40
Options 1.
2.
3.
4.
Q.41
Options 1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S1D38832/167496… 16/32
02/02/2023, 22:09 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.42
Options 1.
2.
3.
4.
Q.43
Options 1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S1D38832/167496… 17/32
02/02/2023, 22:09 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.44
Options 1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S1D38832/167496… 18/32
02/02/2023, 22:09 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.45
Options
1.
2.
3.
4.
Q.46
Options 1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S1D38832/167496… 19/32
02/02/2023, 22:09 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.47
Options 1.
2.
3.
4.
Q.48
Options 1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S1D38832/167496… 20/32
02/02/2023, 22:09 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.49
Options 1.
2.
3.
4.
Q.50
Options
1.
2.
3.
4.
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02/02/2023, 22:09 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.51
Given --
Answer :
Question Type : SA
Question ID : 7155051500
Status : Not Answered
Q.52
Given --
Answer :
Question Type : SA
Question ID : 7155051491
Status : Not Answered
Q.53
Given 2
Answer :
Question Type : SA
Question ID : 7155051497
Status : Answered
Q.54
Given --
Answer :
Question Type : SA
Question ID : 7155051496
Status : Not Answered
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02/02/2023, 22:09 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.55
Given 25
Answer :
Question Type : SA
Question ID : 7155051499
Status : Answered
Q.56
Given --
Answer :
Question Type : SA
Question ID : 7155051495
Status : Not Answered
Q.57
Given 2
Answer :
Question Type : SA
Question ID : 7155051494
Status : Answered
Q.58
Given --
Answer :
Question Type : SA
Question ID : 7155051492
Status : Not Answered
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02/02/2023, 22:09 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.59
Given 5832
Answer :
Question Type : SA
Question ID : 7155051493
Status : Answered
Q.60
Given 4
Answer :
Question Type : SA
Question ID : 7155051498
Status : Answered
Q.61
Options 1.
2.
3.
4.
Q.62
Options 1.
2.
3.
4.
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02/02/2023, 22:09 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.63
Options 1.
2.
3.
4.
Q.64
Options 1.
2.
3.
4.
Q.65
Options 1.
2.
3.
4.
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02/02/2023, 22:09 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.66
Options 1.
2.
3.
4.
Q.67
Options 1.
2.
3.
4.
Q.68
Options 1.
2.
3.
4.
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02/02/2023, 22:09 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.69
Options 1.
2.
3.
4.
Q.70
Options
1.
2.
3.
4.
Q.71
Options 1.
2.
3.
4.
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02/02/2023, 22:09 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.72
Options 1.
2.
3.
4.
Q.73
Options 1.
2.
3.
4.
Q.74
Options
1.
2.
3.
4.
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02/02/2023, 22:09 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.75
Options 1.
2.
3.
4.
Q.76
Options
1.
2.
3.
4.
Q.77
Options 1.
2.
3.
4.
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02/02/2023, 22:09 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.78
Options
1.
2.
3.
4.
Q.79
Options 1.
2.
3.
4.
Q.80
Options 1.
2.
3.
4.
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02/02/2023, 22:09 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.81
Given --
Answer :
Question Type : SA
Question ID : 7155051528
Status : Not Answered
Q.82
Given --
Answer :
Question Type : SA
Question ID : 7155051521
Status : Not Answered
Q.83
Given --
Answer :
Question Type : SA
Question ID : 7155051527
Status : Not Answered
Q.84
Given 350
Answer :
Question Type : SA
Question ID : 7155051525
Status : Answered
Q.85
Given 2880
Answer :
Question Type : SA
Question ID : 7155051522
Status : Answered
Q.86
Given --
Answer :
Question Type : SA
Question ID : 7155051526
Status : Not Answered
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02/02/2023, 22:09 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.87
Given --
Answer :
Question Type : SA
Question ID : 7155051523
Status : Not Answered
Q.88
Given --
Answer :
Question Type : SA
Question ID : 7155051524
Status : Not Answered
Q.89
Given --
Answer :
Question Type : SA
Question ID : 7155051529
Status : Not Answered
Q.90
Given --
Answer :
Question Type : SA
Question ID : 7155051530
Status : Not Answered
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02/02/2023, 22:15 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.1
Options 1.
2.
3.
4.
Q.2
Options 1.
2.
3.
4.
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Q.3
Options
1.
2.
3.
4.
Q.4
Options
1.
2.
3.
4.
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02/02/2023, 22:15 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.5
Options 1.
2.
3.
4.
Q.6
Options
1.
2.
3.
4.
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Q.7
Options 1.
2.
3.
4.
Q.8
Options 1.
2.
3.
4.
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02/02/2023, 22:15 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.9
Options
1.
2.
3.
4.
Q.10
Options 1.
2.
3.
4.
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02/02/2023, 22:15 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.11
Options 1.
2.
3.
4.
Q.12
Options 1.
2.
3.
4.
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02/02/2023, 22:15 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.13
Options 1.
2.
3.
4.
Q.14
Options 1.
2.
3.
4.
Q.15
Options 1.
2.
3.
4.
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02/02/2023, 22:15 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.16
Options 1.
2.
3.
4.
Q.17
Options 1.
2.
3.
4.
Q.18
Options 1.
2.
3.
4.
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Q.19
Options
1.
2.
3.
4.
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02/02/2023, 22:15 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.20
Options 1.
2.
3.
4.
Q.21
Given --
Answer :
Question Type : SA
Question ID : 7155051557
Status : Not Answered
Q.22
Given --
Answer :
Question Type : SA
Question ID : 7155051552
Status : Not Answered
Q.23
Given --
Answer :
Question Type : SA
Question ID : 7155051558
Status : Not Answered
Q.24
Given --
Answer :
Question Type : SA
Question ID : 7155051554
Status : Not Answered
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02/02/2023, 22:15 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.25
Given --
Answer :
Question Type : SA
Question ID : 7155051560
Status : Not Answered
Q.26
Given 105
Answer :
Question Type : SA
Question ID : 7155051555
Status : Answered
Q.27
Given 1
Answer :
Question Type : SA
Question ID : 7155051551
Status : Answered
Q.28
Given 32
Answer :
Question Type : SA
Question ID : 7155051553
Status : Answered
Q.29
Given 24
Answer :
Question Type : SA
Question ID : 7155051556
Status : Answered
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02/02/2023, 22:15 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.30
Given --
Answer :
Question Type : SA
Question ID : 7155051559
Status : Not Answered
Q.31
Options 1.
2.
3.
4.
Q.32
Options 1.
2.
3.
4.
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02/02/2023, 22:15 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.33
Options 1.
2.
3.
4.
Q.34
Options
1.
2.
3.
4.
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02/02/2023, 22:15 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.35
Options 1.
2.
3.
4.
Q.36
Options 1.
2.
3.
4.
Q.37
Options 1.
2.
3.
4.
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02/02/2023, 22:15 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.38
Options 1.
2.
3.
4.
Q.39
Options 1.
2.
3.
4.
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02/02/2023, 22:15 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.40
Options 1.
2.
3.
4.
Q.41
Options 1.
2.
3.
4.
Q.42
Options 1.
2.
3.
4.
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02/02/2023, 22:15 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.43
Options 1.
2.
3.
4.
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02/02/2023, 22:15 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.44
Options
1.
2.
3.
4.
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02/02/2023, 22:15 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.45
Options 1.
2.
3.
4.
Q.46
Options 1.
2.
3.
4.
Q.47
Options 1.
2.
3.
4.
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02/02/2023, 22:15 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.48
Options 1.
2.
3.
4.
Q.49
Options 1.
2.
3.
4.
Q.50
Options 1.
2.
3.
4.
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02/02/2023, 22:15 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.51
Given 4
Answer :
Question Type : SA
Question ID : 7155051588
Status : Answered
Q.52
Given 4
Answer :
Question Type : SA
Question ID : 7155051581
Status : Answered
Q.53
Given --
Answer :
Question Type : SA
Question ID : 7155051590
Status : Not Answered
Q.54
Given --
Answer :
Question Type : SA
Question ID : 7155051582
Status : Not Answered
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02/02/2023, 22:15 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.55
Given --
Answer :
Question Type : SA
Question ID : 7155051584
Status : Not Answered
Q.56
Given --
Answer :
Question Type : SA
Question ID : 7155051589
Status : Not Answered
Q.57
Given 314
Answer :
Question Type : SA
Question ID : 7155051585
Status : Answered
Q.58
Given --
Answer :
Question Type : SA
Question ID : 7155051586
Status : Not Answered
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S2D39069/167496… 22/32
02/02/2023, 22:15 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.59
Given --
Answer :
Question Type : SA
Question ID : 7155051587
Status : Not Answered
Q.60
Given --
Answer :
Question Type : SA
Question ID : 7155051583
Status : Not Answered
Q.61
Options 1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S2D39069/167496… 23/32
02/02/2023, 22:15 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.62
Options
1.
2.
3.
4.
Q.63
Options
1.
2.
3.
4.
Q.64
Options 1.
2.
3.
4.
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02/02/2023, 22:15 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.65
Options 1.
2.
3.
4.
Q.66
Options
1.
2.
3.
4.
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02/02/2023, 22:15 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.67
Options
1.
2.
3.
4.
Q.68
Options 1.
2.
3.
4.
Q.69
Options 1.
2.
3.
4.
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02/02/2023, 22:15 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.70
Options 1.
2.
3.
4.
Q.71
Options 1.
2.
3.
4.
Q.72
Options 1.
2.
3.
4.
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02/02/2023, 22:15 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.73
Options
1.
2.
3.
4.
Q.74
Options 1.
2.
3.
4.
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02/02/2023, 22:15 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.75
Options
1.
2.
3.
4.
Q.76
Options 1.
2.
3.
4.
Q.77
Options 1.
2.
3.
4.
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02/02/2023, 22:15 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.78
Options 1.
2.
3.
4.
Q.79
Options 1.
2.
3.
4.
Q.80
Options 1.
2.
3.
4.
Q.81
Given --
Answer :
Question Type : SA
Question ID : 7155051613
Status : Not Answered
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02/02/2023, 22:15 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.82
Given --
Answer :
Question Type : SA
Question ID : 7155051615
Status : Not Answered
Q.83
Given --
Answer :
Question Type : SA
Question ID : 7155051619
Status : Not Answered
Q.84
Given --
Answer :
Question Type : SA
Question ID : 7155051620
Status : Not Answered
Q.85
Given --
Answer :
Question Type : SA
Question ID : 7155051618
Status : Not Answered
Q.86
Given 9
Answer :
Question Type : SA
Question ID : 7155051611
Status : Answered
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S2D39069/167496… 31/32
02/02/2023, 22:15 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.87
Given --
Answer :
Question Type : SA
Question ID : 7155051617
Status : Not Answered
Q.88
Given --
Answer :
Question Type : SA
Question ID : 7155051616
Status : Not Answered
Q.89
Given --
Answer :
Question Type : SA
Question ID : 7155051612
Status : Not Answered
Q.90
Given --
Answer :
Question Type : SA
Question ID : 7155051614
Status : Not Answered
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Q.13
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Q.15
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Q.16
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Q.20
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Q.21
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Answer :
Question Type : SA
Question ID : 3666941195
Status : Not Answered
Q.22
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Answer :
Question Type : SA
Question ID : 3666941192
Status : Not Answered
Q.23
Given --
Answer :
Question Type : SA
Question ID : 3666941193
Status : Not Answered
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Q.24
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Answer :
Question Type : SA
Question ID : 3666941197
Status : Not Answered
Q.25
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Answer :
Question Type : SA
Question ID : 3666941191
Status : Not Answered
Q.26
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Answer :
Question Type : SA
Question ID : 3666941199
Status : Not Answered
Q.27
Given --
Answer :
Question Type : SA
Question ID : 3666941200
Status : Not Answered
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Q.28
Given --
Answer :
Question Type : SA
Question ID : 3666941194
Status : Not Answered
Q.29
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Answer :
Question Type : SA
Question ID : 3666941196
Status : Not Answered
Q.30
Given --
Answer :
Question Type : SA
Question ID : 3666941198
Status : Not Answered
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Q.34
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Q.38
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Q.40
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Q.42
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Q.47
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Q.48
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Q.49
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Q.50
Options 1.
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Q.51
Given 2
Answer :
Question Type : SA
Question ID : 3666941228
Status : Answered
Q.52
Given --
Answer :
Question Type : SA
Question ID : 3666941223
Status : Not Answered
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Q.53
Given --
Answer :
Question Type : SA
Question ID : 3666941221
Status : Not Answered
Q.54
Given 1
Answer :
Question Type : SA
Question ID : 3666941222
Status : Answered
Q.55
Given --
Answer :
Question Type : SA
Question ID : 3666941230
Status : Not Answered
Q.56
Given --
Answer :
Question Type : SA
Question ID : 3666941226
Status : Not Answered
Q.57
Given --
Answer :
Question Type : SA
Question ID : 3666941227
Status : Not Answered
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Q.58
Given --
Answer :
Question Type : SA
Question ID : 3666941224
Status : Not Answered
Q.59
Given --
Answer :
Question Type : SA
Question ID : 3666941225
Status : Not Answered
Q.60
Given --
Answer :
Question Type : SA
Question ID : 3666941229
Status : Not Answered
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Q.61
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Q.62
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Q.63
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Q.64
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Q.65
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Q.66
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Q.67
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Q.68
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Q.69
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Q.70
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Q.71
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Q.72
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Q.73
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Q.74
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Q.75
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Q.76
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Q.77
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Q.78
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Q.79
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Q.80
Options 1.
2.
3.
4.
Q.81
Given --
Answer :
Question Type : SA
Question ID : 3666941257
Status : Not Answered
Q.82
Given --
Answer :
Question Type : SA
Question ID : 3666941252
Status : Not Answered
Q.83
Given --
Answer :
Question Type : SA
Question ID : 3666941258
Status : Not Answered
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02/02/2023, 22:13 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.84
Given --
Answer :
Question Type : SA
Question ID : 3666941259
Status : Not Answered
Q.85
Given --
Answer :
Question Type : SA
Question ID : 3666941254
Status : Not Answered
Q.86
Given --
Answer :
Question Type : SA
Question ID : 3666941256
Status : Not Answered
Q.87
Given --
Answer :
Question Type : SA
Question ID : 3666941260
Status : Not Answered
Q.88
Given --
Answer :
Question Type : SA
Question ID : 3666941253
Status : Not Answered
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Q.89
Given --
Answer :
Question Type : SA
Question ID : 3666941255
Status : Not Answered
Q.90
Given --
Answer :
Question Type : SA
Question ID : 3666941251
Status : Not Answered
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Q.1
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Q.2
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Q.3
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Q.5
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Q.6
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Q.7
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Q.8
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Q.9
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Q.10
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Q.11
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Q.12
Options 1.
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Q.13
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Q.14
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Q.15
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Q.16
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Q.17
Options 1.
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Q.18
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Q.19
Options 1.
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Q.20
Options 1.
2.
3.
4.
Q.21
Given --
Answer :
Question Type : SA
Question ID : 7155051643
Status : Not Answered
Q.22
Given --
Answer :
Question Type : SA
Question ID : 7155051644
Status : Not Answered
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02/02/2023, 22:11 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.23
Given --
Answer :
Question Type : SA
Question ID : 7155051647
Status : Not Answered
Q.24
Given --
Answer :
Question Type : SA
Question ID : 7155051641
Status : Not Answered
Q.25
Given --
Answer :
Question Type : SA
Question ID : 7155051648
Status : Not Answered
Q.26
Given --
Answer :
Question Type : SA
Question ID : 7155051646
Status : Not Answered
Q.27
Given --
Answer :
Question Type : SA
Question ID : 7155051650
Status : Not Answered
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02/02/2023, 22:11 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.28
Given --
Answer :
Question Type : SA
Question ID : 7155051645
Status : Not Answered
Q.29
Given --
Answer :
Question Type : SA
Question ID : 7155051642
Status : Not Answered
Q.30
Given --
Answer :
Question Type : SA
Question ID : 7155051649
Status : Not Answered
Q.31
Options 1.
2.
3.
4.
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Q.32
Options
1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S4D40518/167497… 12/34
02/02/2023, 22:11 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.33
Options 1.
2.
3.
4.
Q.34
Options 1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S4D40518/167497… 13/34
02/02/2023, 22:11 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.35
Options 1.
2.
3.
4.
Q.36
Options 1.
2.
3.
4.
Q.37
Options 1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S4D40518/167497… 14/34
02/02/2023, 22:11 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.38
Options 1.
2.
3.
4.
Q.39
Options 1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S4D40518/167497… 15/34
02/02/2023, 22:11 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.40
Options 1.
2.
3.
4.
Q.41
Options 1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S4D40518/167497… 16/34
02/02/2023, 22:11 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.42
Options 1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S4D40518/167497… 17/34
02/02/2023, 22:11 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.43
Options
1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S4D40518/167497… 18/34
02/02/2023, 22:11 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.44
Options 1.
2.
3.
4.
Q.45
Options 1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S4D40518/167497… 19/34
02/02/2023, 22:11 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.46
Options 1.
2.
3.
4.
Q.47
Options 1.
2.
3.
4.
Q.48
Options 1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S4D40518/167497… 20/34
02/02/2023, 22:11 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.49
Options 1.
2.
3.
4.
Q.50
Options 1.
2.
3.
4.
Q.51
Given 12
Answer :
Question Type : SA
Question ID : 7155051679
Status : Answered
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S4D40518/167497… 21/34
02/02/2023, 22:11 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.52
Given --
Answer :
Question Type : SA
Question ID : 7155051678
Status : Not Answered
Q.53
Given --
Answer :
Question Type : SA
Question ID : 7155051674
Status : Not Answered
Q.54
Given --
Answer :
Question Type : SA
Question ID : 7155051671
Not Attempted and
Status :
Marked For Review
Q.55
Given --
Answer :
Question Type : SA
Question ID : 7155051673
Status : Not Answered
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S4D40518/167497… 22/34
02/02/2023, 22:11 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.56
Given --
Answer :
Question Type : SA
Question ID : 7155051672
Not Attempted and
Status :
Marked For Review
Q.57
Given --
Answer :
Question Type : SA
Question ID : 7155051677
Status : Not Answered
Q.58
Given --
Answer :
Question Type : SA
Question ID : 7155051680
Not Attempted and
Status :
Marked For Review
Q.59
Given 8.28
Answer :
Question Type : SA
Question ID : 7155051675
Status : Answered
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S4D40518/167497… 23/34
02/02/2023, 22:11 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.60
Given --
Answer :
Question Type : SA
Question ID : 7155051676
Not Attempted and
Status :
Marked For Review
Q.61
Options 1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S4D40518/167497… 24/34
02/02/2023, 22:11 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.62
Options
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2.
3.
4.
Q.63
Options
1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S4D40518/167497… 25/34
02/02/2023, 22:11 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.64
Options 1.
2.
3.
4.
Q.65
Options 1.
2.
3.
4.
Q.66
Options 1.
2.
3.
4.
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02/02/2023, 22:11 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.67
Options
1.
2.
3.
4.
Q.68
Options 1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S4D40518/167497… 27/34
02/02/2023, 22:11 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.69
Options
1.
2.
3.
4.
Q.70
Options 1.
2.
3.
4.
Q.71
Options 1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S4D40518/167497… 28/34
02/02/2023, 22:11 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.72
Options
1.
2.
3.
4.
Q.73
Options 1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S4D40518/167497… 29/34
02/02/2023, 22:11 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.74
Options
1.
2.
3.
4.
Q.75
Options
1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S4D40518/167497… 30/34
02/02/2023, 22:11 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.76
Options 1.
2.
3.
4.
Q.77
Options 1.
2.
3.
4.
Q.78
Options 1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S4D40518/167497… 31/34
02/02/2023, 22:11 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.79
Options 1.
2.
3.
4.
Q.80
Options 1.
2.
3.
4.
Q.81
Given --
Answer :
Question Type : SA
Question ID : 7155051706
Status : Not Answered
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S4D40518/167497… 32/34
02/02/2023, 22:11 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.82
Given --
Answer :
Question Type : SA
Question ID : 7155051701
Status : Not Answered
Q.83
Given --
Answer :
Question Type : SA
Question ID : 7155051708
Status : Not Answered
Q.84
Given --
Answer :
Question Type : SA
Question ID : 7155051704
Status : Not Answered
Q.85
Given --
Answer :
Question Type : SA
Question ID : 7155051703
Status : Not Answered
Q.86
Given --
Answer :
Question Type : SA
Question ID : 7155051702
Status : Not Answered
Q.87
Given --
Answer :
Question Type : SA
Question ID : 7155051705
Status : Not Answered
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S4D40518/167497… 33/34
02/02/2023, 22:11 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.88
Given --
Answer :
Question Type : SA
Question ID : 7155051710
Status : Not Answered
Q.89
Given --
Answer :
Question Type : SA
Question ID : 7155051709
Status : Not Answered
Q.90
Given --
Answer :
Question Type : SA
Question ID : 7155051707
Status : Not Answered
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S4D40518/167497… 34/34
02/02/2023, 22:02 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.1
Options 1.
2.
3.
4.
Q.2
Options
1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S11D56609/167528… 1/37
02/02/2023, 22:02 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.3
Options
1.
2.
3.
4.
Q.4
Options 1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S11D56609/167528… 2/37
02/02/2023, 22:02 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.5
Options
1.
2.
3.
4.
Q.6
Options
1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S11D56609/167528… 3/37
02/02/2023, 22:02 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.7
Options
1.
2.
3.
4.
Q.8
Options 1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S11D56609/167528… 4/37
02/02/2023, 22:02 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.9
Options 1.
2.
3.
4.
Q.10
Options 1.
2.
3.
4.
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02/02/2023, 22:02 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.11
Options
1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S11D56609/167528… 6/37
02/02/2023, 22:02 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.12
Options
1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S11D56609/167528… 7/37
02/02/2023, 22:02 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.13
Options 1.
2.
3.
4.
Q.14
Options
1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S11D56609/167528… 8/37
02/02/2023, 22:02 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.15
Options
1.
2.
3.
4.
Q.16
Options
1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S11D56609/167528… 9/37
02/02/2023, 22:02 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.17
Options
1.
2.
3.
4.
Q.18
Options
1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S11D56609/16752… 10/37
02/02/2023, 22:02 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.19
Options
1.
2.
3.
4.
Q.20
Options 1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S11D56609/16752… 11/37
02/02/2023, 22:02 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.21
Given --
Answer :
Question Type : SA
Question ID : 3666942036
Status : Not Answered
Q.22
Given --
Answer :
Question Type : SA
Question ID : 3666942030
Status : Not Answered
Q.23
Given --
Answer :
Question Type : SA
Question ID : 3666942034
Status : Not Answered
Q.24
Given --
Answer :
Question Type : SA
Question ID : 3666942028
Status : Not Answered
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S11D56609/16752… 12/37
02/02/2023, 22:02 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.25
Given --
Answer :
Question Type : SA
Question ID : 3666942035
Status : Not Answered
Q.26
Given 12
Answer :
Question Type : SA
Question ID : 3666942033
Status : Answered
Q.27
Given 92
Answer :
Question Type : SA
Question ID : 3666942027
Status : Answered
Q.28
Given 7
Answer :
Question Type : SA
Question ID : 3666942032
Status : Answered
Q.29
Given 1200
Answer :
Question Type : SA
Question ID : 3666942031
Status : Answered
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S11D56609/16752… 13/37
02/02/2023, 22:02 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.30
Given 20
Answer :
Question Type : SA
Question ID : 3666942029
Status : Answered
Q.31
Options
1.
2.
3.
4.
Q.32
Options
1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S11D56609/16752… 14/37
02/02/2023, 22:02 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.33
Options
1.
2.
3.
4.
Q.34
Options
1.
2.
3.
4.
Q.35
Options
1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S11D56609/16752… 15/37
02/02/2023, 22:02 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.36
Options 1.
2.
3.
4.
Q.37
Options
1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S11D56609/16752… 16/37
02/02/2023, 22:02 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.38
Options 1.
2.
3.
4.
Q.39
Options
1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S11D56609/16752… 17/37
02/02/2023, 22:02 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.40
Options
1.
2.
3.
4.
Q.41
Options 1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S11D56609/16752… 18/37
02/02/2023, 22:02 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.42
Options 1.
2.
3.
4.
Q.43
Options
1.
2.
3.
4.
Q.44
Options
1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S11D56609/16752… 19/37
02/02/2023, 22:02 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.45
Options
1.
2.
3.
4.
Q.46
Options
1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S11D56609/16752… 20/37
02/02/2023, 22:02 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.47
Options
1.
2.
3.
4.
Q.48
Options
1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S11D56609/16752… 21/37
02/02/2023, 22:02 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.49
Options
1.
2.
3.
4.
Q.50
Options
1.
2.
3.
4.
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S11D56609/16752… 22/37
02/02/2023, 22:02 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.51
Given 2
Answer :
Question Type : SA
Question ID : 3666942062
Status : Answered
Q.52
Given --
Answer :
Question Type : SA
Question ID : 3666942059
Status : Not Answered
Q.53
Given --
Answer :
Question Type : SA
Question ID : 3666942065
Status : Not Answered
https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234S11D56609/16752… 23/37
02/02/2023, 22:02 https://cdn3.digialm.com//per/g28/pub/2083/touchstone/AssessmentQPHTMLMode1//2083O234/2083O234…
Q.54
Given 2
Answer :
Question Type : SA
Question ID : 3666942064
Status : Answered
Q.55
Given --
Answer :
Question Type : SA
Question ID : 3666942058
Status : Not Answered
Q.56
Given --
Answer :
Question Type : SA
Question ID : 3666942061
Status : Not Answered
Q.57
Given --
Answer :
Question Type : SA
Question ID : 3666942057
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PHYSICS
SECTION - A 3. Two conducting solid spheres (A & B) are placed at
a very large distance with charge densities and radii
Multiple Choice Questions: This section contains 20
as shown:
multiple choice questions. Each question has 4 choices
(1), (2), (3) and (4), out of which ONLY ONE is correct.
Choose the correct answer:
1. Bob P is released from the position of rest at the
moment shown. If it collides elastically with an
identical bob Q hanging freely then velocity of Q, When the key K is closed, find the ratio of final
just after collision is (g = 10 m/s2) charge densities.
(1) 4 : 1 (2) 1 : 2
(3) 2 : 1 (4) 1 : 4
Answer (3)
Sol. Final potential is same
1 Q1 1 Q2
⇒ = .... (1)
4πε0 R 4πε0 2R
2
Also, Q1 + Q2 = σ · 4πR 2 + σ · 4π ( 2R ) ..... ( 2 )
(1) 1 m/s (2) 4 m/s
σ1
(3) 2 m/s (4) 8 m/s ⇒ 2.
=
σ2
Answer (3)
4. Position-time graph for a particle is parabolic and is
Sol. Velocity of P just before collision is = 2gl as shown:
= 2 m/sec
As collision is elastic and the mass of P and Q is
equal therefore just after collision velocity of P is 0
and that of Q is 2 m/sec.
2. Choose the option showing the correct relation
between Poisson’s ratio (σ), Bulk modulus (B) and
Choose the corresponding v – t graph
modulus of rigidity (G).
3B − 2G 6B + 2G
(1) σ = (2) σ =
2G + 6B 3B − 2G (1) (2)
9BG 3σ − 3G
(3) σ = (4) B =
3B + G 6σ + 2G
Answer (1)
Sol. E = 2G(1 + σ) ….(1)
(3) (4)
E = 3B(1 – 2σ) ….(2)
2G 1 + σ
1=
3B 1 − 2σ
Answer (2)
⇒ 3B – 6Bσ = 2G + 2Gσ Sol. Since x ∝ t2
⇒ 3B – 2G = σ (2G + 6B)
dx
⇒ =
v ∝ t′
3B − 2G dt
σ =
2G + 6B ⇒ Option 2 is correct
-2-
5. For a system undergoing isothermal process, heat 7. Momentum-time graph of an object moving along a
energy is supplied to the system. Choose the option straight line is as shown in figure. If (P2 – P1) < P1
showing correct statements and (t2 – t1) = t1 < (t3 – t2) then at which points among
(a) Internal energy will increase A, B and C the magnitude of force experienced by
the object is maximum and minimum respectively.
(b) Internal energy will decrease
(c) Work done by system is positive
(d) Work done by system is negative
(e) Internal energy remains constant
(1) (a), (c), (e) (2) (b), (d)
(3) (c), (e) (4) (a), (d), (e)
Answer (3)
Sol. For isothermal process,
dT = 0
(1) A, B (2) A, C
so, dU = 0 ⇒ Internal energy remains same
(3) B, C (4) B, A
dQ = dW
Answer (2)
as dQ is positive,
so dW is positive Sol.
6. The heat passing through the cross-section of a
conductor, varies with time ‘t’ as Q(t) = αt – βt2 + γt3.
(α, β and γ are positive constants.) The minimum
heat current through the conductor is
β2 β2
(1) α − (2) α −
2γ 3γ
β2 3β2
(3) α − (4) α − P1
γ γ FA =
t1
Answer (2)
Sol. Heat through cross section of rod P2 − P1
FB =
Q = αt – βt2 + γt3 t2 − t1
dQ P2 − P1
so heat current = FC =
dt t3 − t 2
dQ
heat current = = α − 2βt + 3 γt 2 Therefore the maximum force is at A and minimum
dt force is at C.
for heat current to be minimum 8. A particle moving in unidirectional motion travels
d Q 2 half of the total distance with a constant speed of
= −2β + 6 γt = 0 15 m/s. Now first half of the journey time it travels
dt 2
at 10 m/s and second half of the remaining journey
2β β time it travels at 5 m/s. Average speed of the
=
t = particle is
6γ 3γ
(1) 12 m/s (2) 10 m/s
so minimum heat current
(3) 7 m/s (4) 9 m/s
dQ β β2
= α − 2β × + 3γ × 2 Answer (2)
dt minimum 3γ 9γ
Sol.
2 2
2β β
=α− +
3γ 3γ
2x
v av =
β2 x
= α − + 2t
3γ 15
-3-
2x
=
x 2x
+
15 10 + 5
= 10 m/sec
9. A bullet strikes a stationary ball kept at a height as
shown. After collision, range of bullet is 120 m and The LCR circuit is in resonance stage
that of ball is 30 m. Find initial speed of bullet.
So, Z = R 2 + ( X L − XC )2
Collision is along horizontal direction.
Take g = 10 m/s2 Z=R
R R
P2 = cosφ = power factor= = = 1
Z R
1
P1 2 1
So,
= =
P2 1 2
11. Electromagnetic wave beam of power 20 mW is
(1) 150 m/s (2) 90 m/s incident on a perfectly absorbing body for 300 ns.
(3) 240 m/s (4) 360 m/s The total momentum transferred by the beam to the
body is equal to
Answer (4)
(1) 2 × 10–17 Ns (2) 1 × 10–17 Ns
Sol. m1V + m2 (O ) =m1v1′ + m2V2′ ...(1)
(3) 3 × 10–17 Ns (4) 5 × 10–17 Ns
2h Answer (1)
=
∆t = 2s ... ( 2 )
g Sol. Total energy incident = Pt
120 m Pt
v1′
⇒= = 60 m/s So total initial momentum =
2s c
Total final momentum = 0
30 m
&
= v 2′ = 15 m/s Pt
2s Total momentum transferred =
c
⇒ v = 360 m/s
10. If an inductor with inductive reactance, XL = R is 20 × 10−3 × 300 × 10 −9
=
connected in series with resistor R across an A.C 3 × 108
voltage, power factor comes out to be P1. Now, if a
capacitor with capacitive reactance, XC = R is also = 2 × 10–17 Ns
connected in series with inductor and resistor in the 12. The velocity of an electron in the seventh orbit of
P hydrogen-like atom is 3.6 × 106 m/s. Find the
same circuit, power factor becomes P2. Find 1 velocity of the electron in the 3rd orbit.
P2
(1) 4.2 × 106 m/s (2) 8.4 × 106 m/s
(1) 2 :1 (2) 1: 2 (3) 2.1 × 106 m/s (4) 3.6 × 106 m/s
(3) 1 : 1 (4) 1 : 2 Answer (2)
Answer (2) Sol. For hydrogen like atom,
Sol. 1
v∝
n
v1 n2
=
v 2 n1
=Z R2 + R2 3.6 × 106 3
⇒ =
v2 7
= 2R
7
R 1 ⇒ v 2 = × 3.6 × 106
P1 = cosφ = power factor = = 3
Z 2
= 8.4 × 106 m/s
When capacitor is also connected in series
-4-
a ˆ b ˆ dV 3T 2
13. Electric field in a region is given by=
E i + 3 j, Or = 3
x2 y VdT T
where x & y are co-ordinates. Find SI units of a & b. dV 3
(1) a – Nm2C–1 (2) a – Nm3C–1 =
VdT T
b – Nm3C–1 b – Nm2C–1 16. Consider a combination of gates as shown :
(3) a – NmC–1 (4) a – Nm2C–1
b – Nm2C–1 b – Nm2C–1
Answer (1)
Sol. E – NC–1
x2 – m2
y3 – m3
⇒ a – Nm2C–1
& b – Nm3C–1
14. Coil A of radius 10 cm has NA number of turns and
IA current is flowing through it. Coil B of radius
20 cm has NB number of turns and IB current is (1)
flowing through it. If magnetic dipole moment of
both the coils is same then
1 (2)
(1) IANA = 4IBNB (2) I A N A = I N
4 B B
1 (3)
(3) IANA = 2IBNB (4) I A N A = I N
2 B B
Answer (1)
(4)
Sol. Magnetic dipole moment µ = NIA = NIπR2
µ N AI A RA2 Answer (1)
So A
= = 1
µB NB IB RB2 Sol. y = (A′B′) = A + B
⇒ OR gate
N AI A (102 )
=1 ⇒ Option 1
NB IB (202 )
17. For the given YDSE setup. Find the number of
NAIA = 4NBIB fringes by which the central maxima gets shifted
15. An ideal gas undergoes a thermodynamic process from point O.
following the relation PT2 = constant. Assuming (Given d = 1 mm
symbols have their usual meaning then volume D=1m
expansion coefficient of the gas is equal to
λ = 5000 Å)
2 3
(1) (2)
T T
1 1
(3) (4)
2T T
Answer (2)
dV
Sol. Volume expansion coefficient =
VdT
For PT2 = constant
T3
Or = constant
V
(1) 10 (2) 15
dV
Or = (C ) 3T 2 (3) 8 (4) 12
dT
Answer (1)
-5-
Sol. di
Sol. VA − iR − L − 12 =
VB
dt
⇒ VA – VB = +18 volts
22. A particle undergoing SHM follows the position-time
π
equation given as=x A sin ωt + . If the SHM
3
motion has a time period of T, then velocity will be
T
maximum at time t= for first time after
β
t = 0. Value of β is equal to
at central position, path difference, is,
(µ – 1)t1 – (µ – 1)t2 Answer (03.00)
∆x = (µ – 1) (t1 – t2) π
Sol.=x A sin ωt +
3 3
∆x = − 1 ( 5.11 − 5.10 ) mm
2
π
1 ⇒ v = Aω cos ωt +
= × ( 0.01) mm 3
2
= 0.005 mm For maximum value of v
= 5 × 10–6 m π
cos ωt + =±1
∆x 5 × 10−6 m 3
No. of fringes shifted = =
λ 5 × 10−7 m π
= 10 ⇒ ωt + =π (for nearest value of t)
3
2π
ωt =
3
SECTION - B T
t=
Numerical Value Type Questions: This section 3
contains 10 questions. In Section B, attempt any five So β = 3
questions out of 10. The answer to each question is a
23. A block of mass 1 g is equilibrium with the help of a
NUMERICAL VALUE. For each question, enter the
current carrying square loop which is partially lying
correct numerical value (in decimal notation,
truncated/rounded-off to the second decimal place; in constant magnetic field (B) as shown. Resistance
e.g. 06.25, 07.00, –00.33, –00.30, 30.27, –27.30) using of the loop is 10 Ω. Find the voltage (V) (in volts) of
the mouse and the on-screen virtual numeric keypad in
the battery in the loop.
the place designated to enter the answer.
Sol. f = – 30 cm
1
Least count of scale = cm
20
1
1
Fractional error = 20 =
600
ilB = mg 30
−3
mg (1× 10 kg) × (10 m/s )
2 1 1
=i = as =
(0.1 m) × (0.1 T) 10 k 600
lB
= 1 × 10–3 × 103 k = 60
i=1A 26.
As resistance of loop = 10 Ω
V
=
i = 1A
R
V = (1 × 10) V
= 10 V In two circuit shown above the value of current I1 (in
24. Initial volume of 1 mole of a monoatomic gas is y
amperes) is equal to − A . Value of y is equal to
2 litres. It is expanded isothermally to a volume of 5
6 litres. Change in internal energy is xR. Find x. Answer (11.00)
Answer (00) Sol.
Sol. ∆U = nCV∆T
= nCV(0) ( isothermal)
⇒ ∆U = 0
25. An object is placed at a distance of 40 cm from the
pole of a converging mirror. The image is formed at Using Kirchoff’s law.
a distance of 120 cm from the mirror on the same I1 + I3 – I2 = –2 …(i)
side. If the focal length is measured with a scale I3 + 2I2 = 5 …(ii)
where each 1 cm has 20 equal divisions. If the
2I2 – (I3 – I2) – (I1 + I3 – I2) = 5 …(iii)
fractional error in the measurement of focal length
1 11
is Find k. ⇒ I1 = − A
10 k 5
⇒ y = 11
Answer (60.00)
Sol. u = – 40 cm
v = – 120 cm
1 1 1
+ =
v u f
-7-
CHEMISTRY
Answer (1)
Sol. Orange colour of dichromate solution (K2Cr2O7) It is sp3 hybridised therefore its shape will be bent
converts to green (Cr3+). or V-shaped.
-8-
7. Inhibitor of cancer growth Sol. 37 is Rubidium belonging to 1st group of s-block.
(1) Cisplatin 10. Consider the following reactions
(2) EDTA NO2 ⎯⎯⎯
UV
→A +B
(3) Cobalt
A + O2 ⎯⎯→ C
(4) Ethane 1, 2 - diamine
B + C ⎯⎯→ NO2 + O2
Answer (1) A, B and C are respectively
Sol. Cisplatin acts as an anticancer agent. (1) O, NO, O3 (2) NO, O, O3
8. Speed of e– in 7th orbit is 3.6 × 106 m/s then find the (3) NO, O3, O (4) O3, O, NO
speed in 3rd orbit
Answer (1)
(1) 3.6 × 106 m/s
Sol. NO2 ⎯⎯⎯ → NO+ O
UV
(2) 8.4 × 106 m/s (B ) ( A )
(3) 7.5 × 106 m/s O + O2 ⎯⎯→ O3 ( C)
Answer (2) 11. Which of the following option contains the correct
match:
Sol. Speed of electron in nth orbit of a Bohr atom is given (List-I) (Reactions) (List-II) (Products)
by (A) Wurtz (P)
Z (B) Fittig (Q) R – R
v n = ( v1 ) H
n
(C) Wurtz Fittig (R)
If n = 7
Z (D) Sandmeyer (S)
v 7 = ( v1 )H = 3.6 106 m / s
7 (1) A → Q; B → P; C → R; D → S
If n = 3 (2) A → P; B → Q; C → R; D → S
Z (3) A → S; B → R; C → Q; D → P
v 3 = ( v1 )H (4) A → R; B → S; C → P; D → Q
3
Answer (1)
7 3.6 106
=
3 Sol. The correct matches are
= 8.4 × 106 m/s (A) Wurtz → R – R
9. Match the following :
(B) Fittig →
Atomic Number
(C) Wurtz fittig →
(i) 52 (p) s-block
(ii) 37 (q) p-block (D) Sandmeyer →
(iii) 65 (r) d-block 12. If volume of ideal gas is increased isothermally,
(1) (i) → (q); (ii) → (p); (iii) → (r); (iv) → (s) (1) Increased
(2) (i) → (q); (ii) → (p); (iii) → (s); (iv) → (r) (2) Remains constant
(3) (i) → (s); (ii) → (r); (iii) → (p); (iv) → (q) (3) Is decreased
(4) (i) → (r); (ii) → (p); (iii) → (q); (iv) → (s) (4) Can be increased or decreased
Answer (2) Answer (2)
-9-
Sol. Internal energy of ideal gas depends only upon Sol. It converts FeO to FeSiO3
temperature. 17. Assertion: Ketoses gives seliwanoff test.
13. Arrange the following ligands according to their Reason : Ketoses undergo - elimination to form
increasing order of field strength furfural.
(1) Assertion and reason both are correct and
S2– , C2O2–
4 , NH3 , en, CO reason is the correct explanation of assertion
(1) S2– CO NH3 en C2O2–
4
(2) Assertion and reason both are correct but
reason is not the correct explanation of
(2) S2– NH3 en CO C2O2–
4
assertion.
(3) Assertion is correct and reason is incorrect
(3) S2– C2O2–
4 NH3 en CO (4) Assertion is incorrect but reason is correct.
(4) CO en NH3 C2O2–
4 S
2–
Answer (1)
Sol. Assertion and reason both are correct and reason
Answer (3)
is the correct explanation of assertion.
Sol. The correct order of field strength is
18. Consider the following reactions:
S2– C2O2–
4 NH3 en CO
Answer (1)
(2)
Sol. The correct order of acidic strength is
HA > H D > H B > H C
Answer (1)
- 10 -
SECTION - B 23. 600 mL of 0.04 M HCl is mixed with 400 mL of 0.02
M H2SO4. Find out the pH of resulting solution
Numerical Value Type Questions: This section
(Nearest integer).
contains 10 questions. In Section B, attempt any five
Answer (01.00)
questions out of 10. The answer to each question is a
Sol. m moles of H+ from HCl = 0.04 × 600
NUMERICAL VALUE. For each question, enter the
= 24
correct numerical value (in decimal notation,
m moles of H+ from H2SO4 = 0.02 ×2 × 400
truncated/rounded-off to the second decimal place; e.g.
= 16
06.25, 07.00, –00.33, –00.30, 30.27, –27.30) using the
Total m moles of H+ = 24 + 16 = 40
mouse and the on-screen virtual numeric keypad in the
Final volume of solution = 1000 mL
place designated to enter the answer.
40
[H+ ] = = 0.04 M
21. For given cell, at T K 1000
Sol.
- 11 -
MATHEMATICS
1 1 (a, a) R
2. tan15 + + + tan195 = 2a, then
tan165 tan105 (b, c), (c, b) R
1 (b, b) R
value of a + is
a
(c, b), (b, c) R
−4 (c, c) R
(1) 4 − 2 3 (2)
3
elements to be added
3
(3) 2 (4) 5 − 3 {(b, a) (c, b) (b, b) (a, a) (a, c) (c, a) (c, c)}
2
Total 7 elements
Answer (2)
4. Let P(h, k) be two points on x2 = 4y which is at
Sol. tan15° + cot165° + cot105° + tan195°
shortest distance from Q(0, 33) then difference of
= tan15° – cot15° – tan15° + tan15° distances of P(h, k) from directrix of y2 = 4(x + y) is
= tan15° – cot15° (1) 2
= −2 3 (2) 4
a=− 3 (3) 6
(4) 8
1 1 −4
a+ =− 3− =
a 3 3 Answer (2)
- 12 -
Sol. For normal through (0, 33) Shaded area is the required area
2
x
A = x − 2
dx
1/4
2
x 2 x 3/2
= −
2 3
1/4
2 2 1 1
= 2 − − −
3 32 24
Normal at point (2t, t2)
1 2 2
x = –ty + 2at + at3 = 2+ −
96 3
0 = –t 33 + 2t + t3
1
3A = 6 + − 2 2 sq. units.
t = 0 OR 31 32
6. A die with points (2, 1, 0, –1, –2, 3) is thrown 5
Points at which normal are drawn are
times. The probability that the product of outcomes
A(0, 0), B ( 2 31, 31) , C(–2 31, 31) on all throws is positive is
521
Shortest distance (1)
2592
= PB = PC = 124 + 4 = 8 2 units 16
(2)
81
Given parabola ( y − 2)2 = 4( x + 1)
41
(3)
Directrix is x = –2, that is line L 288
(3) 32 C27
(4) 32 P27
Answer (2)
- 13 -
Sol. n(S) = 5 9. For solution of differential equation
n(P(S)) = 25 = 32 5 −1 3
dy 3 x tan x
− y =−
( )
x 3 tan−1 x 3
dx 3
1+ x6 2 ( )
1+ x6
1
−
No. of one-one function= 32 × 31 × 30 × 24 × 28 (2) 1− e 2 4 2
32! 1
=
27! (3) e 2 −e 2
4
angle of
from positive x-axis. If area of triangle −3 x 5 tan−1 x 3 ( ) dx
6 Sol. IF = 3
OAB =
98 3
sq. units, then 3 a + b is equal to
( )
1+ x6 2
(1) 28 (2) 14
Let tan−1 (x ) = t
3
= e(
− t sin t t cos t −sin t )
(3) 12 (4) 7 IF = e
Answer (1) Solution of Differential equation
Sol. Let the perpendicular distance of line from origin is
y e(
t cos t −sin t )
= e(
t cos t −sin t )
p.
( −t sin t ) dt
y e(
t cos t −sin t )
= e(
t cos t −sin t )
x 3 y +c
Equation of AB : + =p
2 2
t=0→y=0
x y
+ =1 c = –1
2p 2p
3
When x = 1, t =
4
2p
OA = , OB = 2p 1 1
3 − −
y e 4 2 2 = e 4 2 2 −1
1 2p 98
· · 2p = 1
2 3 3 −
y = 1− e 2 4 2
p=7
2
3(e − 1) 3
14 10. x 2e[ x ]+[ x ] dx equals
OA = a = e
3 1
OB = b = 14 (1) e9 − e (2) e8 − 1
3a + b (3) e8 − e (4) e9 − 1
14 + 14 = 28 Answer (3)
- 14 -
2 3
2 3 SECTION - B
Sol. I = x 2e[ x ]+[ x ]dx = e x 2 e[ x ]dx
1 1 Numerical Value Type Questions: This section
contains 10 questions. In Section B, attempt any five
Let x 3 = t
questions out of 10. The answer to each question is a
8
dt [t ] e (
I = e e = e + e2 + ... + e7 ) NUMERICAL VALUE. For each question, enter the
3 3 correct numerical value (in decimal notation,
1
x
(2) 12 t3
48 dt
6
(3) 12 0t +1
Sol. lim
(4) 24
x →0 x4
Answer (3) 0
As form, applying L’ hospital rule we get
0
Sol. a = b − nˆ
x3 1
a b = − nˆ b lim 48 = 48 = 12
Now,
x →0
( x + 1) 4x
6 3 4
| c (a b ) | −2 m
22. If an = and a1 + a2 + .... + a25 =
2
4n − 16n + 15 n
(
= | c −nˆ b | ) where m and n are coprime, then the value of
= | nˆ (12) − b(0) | m + n is
Answer (191)
= 12
−2 −2
Sol. an = =
2
4n − 16n + 15 ( 2n − 3 ) (2n − 5)
1 1
= −
2n − 3 2n − 5
1 1 1 1
a1 + a2 + .... + a25 = − + ... 47 − 45
−1 −3
1 1 50
= + =
47 3 141
m + n = 191
- 15 -
i + z (1 − i ) 15 −r
Sol. an ax 3 + 1
( )
15−r
23. If z = 1 + i and z1 = = z1 , then find the Tr +1 = Cr a15−r x 3
15
b −r x 3
z (1 − z )
bx1/3
r 10r
value of
12
arg ( z1 ) . 45 − 3r − = 15 = 30
3 3
r =9
Answer (3)
15
1 15 − r
i + z (1 − i ) i + (1 − i )(1 − i ) 1
Sol. z1 = = =
1 an ax 3 + Tr +1 = Cr a15 −r x
15 3 b − r x −3r
z (1 − z ) (1 − i )( −i ) 1− i bx 3
1 15 − r
arg z1 = arg = – arg (1 − i ) = − 3r = −15
3
1− i 4
15 − r − 9r = −45
12 12
arg ( z1 ) = =3 r=6
4
So, 15C9 a 6 b −9 = 15C6 a9 b −6
24. Mean & Variance of 7 observations are 8 & 16
respectively, if number 14 is omitted then a & b are a −3 b −3 = 1
Answer (19) ab − 5 = 4
Sol. Let x1, … x7 are observation 26. Using 1, 2, 3, 5, 4-digit numbers are formed, where
repetition is allowed. How many of them is divisible
8 7 − 14 by 15?
New mean = =7
6
Answer (21)
n Sol. Units digit will be 5
xi2 a b c 5
i −1
− 64 = 16 xi2 = 560
7
a + b + c = (3 + 1) type
1
f (1) f ( 2 ) = 5 320 = 1600 ...(ii) − t − 4 − 1 = 0
t
Put x = y = 1 in (i) 4
t+ =4
t
5f ( 2 ) = ( f (1) )
2
t=2
logcos x sin x = 2
f ( 2) =
( f (1) )
2
...(iii) cos2x = sinx
5
1 – sin2x – sinx = 0
Using (iii) in (ii), sin2x + sinx – 1 = 0
−1 5
f (1)
( f (1) )2 = 1600
So, sin x =
2
5
= – 1, = 5
( f (1) ) 3
= 8000 +=4
f (1) = 20
- 17 -
PHYSICS
SECTION - A Distance
Sol. v avg =
Multiple Choice Questions: This section contains 20 Time
multiple choice questions. Each question has 4 choices 4+4
(1), (2), (3) and (4), out of which ONLY ONE is correct. = km/h
4 4
+
Choose the correct answer: 3 5
1. In the given circuit the resistance between terminals 15
= km/h
A and B is equal to 4
3. A current 2 A is flowing through the sides of an
equilateral triangular loop of side 4 3 m as shown.
Find the magnetic field induction at the centroid of
the triangle.
3
(1) 2 Ω (2) Ω
2
2
(3) Ω (4) 6 Ω
3
Sol.
-2-
4. A particle is released at a height equal to radius of 7. In the AC circuit shown in the figure the value of Irms
the earth above the surface of the earth. Its velocity is equal to
when it hits the surface of earth is equal to
(Me : mass of earth, Re : Radius of earth)
2GMe GMe
(1) v = (2) v =
Re 2Re
GMe 2GMe
(3) v = (4) v = (1) 2A (2) 2 2A
Re 3Re
(3) 4A (4) 2A
Answer (3)
Answer (1)
Sol. Using energy conservation.
Sol.=
Z R 2 + ( X L – XC )2
GMm GMm 1
− =
− + mv 2
2Re Re 2 1002 + (100 – 100)2 =
= 100 Ω
GMe 200 2
v= So, i0
= = 2 2
Re 100
5. A faulty scale reads 5°C at melting point and 95°C i0
So, irms
= = 2A
at steam point. 2
Find original temperature if this faulty scale reads 8. A point charge Q is placed inside the cavity made
41°C. in uniform conducting solid sphere as shown. EA,
(1) 40°C (2) 41°C EB and EC are electric field magnitudes at points A,
(3) 36°C (4) 45°C B and C respectively, Then
Answer (1)
41 − 5 x −0
Sol. =
95 − 5 100 − 0
⇒ 9x = 360
⇒ x = 40
(1) EA = 0, EB = 0 and EC ≠ 0
6. A block stays in equilibrium as shown:
(2) EA ≠ 0, EB = 0 and EC ≠ 0
(3) EA ≠ 0, EB = 0 and EC = 0
(4) EA ≠ 0, EB ≠ 0 and EC ≠ 0
Answer (2)
Sol. Taking Q as positive
(1) 3g N (2) 3g N
g g
(3) N (4) N
2 3
-3-
9. In the shown mass-spring system when it is set into
oscillations along the spring, it has angular X1 = A ⋅ ( A ⋅ B ) ⋅ B ⋅ ( A ⋅ B )
frequency ω1, when m = 1 kg and ω2 if m = 2 kg. = A ⋅ ( AB ) + B.( AB )
ω
Then value of 1 is equal to = A ⋅ ( A + B) + B ⋅ ( A + B)
ω2
= AB + BA
= XOR gate
A B Y
0 0 0
0 1 1
(1) 1 (2) 2
1 0 1
1
(3) (4) 2 1 1 0
2
Answer (2) 11. A particle of mass m is moving under a force whose
delivered power P is constant. Initial velocity of
k k particle is zero. Find position of particle at t = 4s.
Sol. ω
=1 =
m 1 16 2P 4 2P
(1) x = (2) x =
k k 3 m 3 m
ω=
2 =
m 2 2 P 3 P
(3) x = (4) x =
ω1 k 3 m 10 m
So
= = 2
ω2 k /2 Answer (1)
10. For the given logic circuit which of the following W
Sol. P =
truth table is correct? t
1
⇒ mv 2 =
P ⋅t
2
2Pt dx
⇒ v= =
m dt
16 2P
⇒ x=
3 m
(1) (2)
12. Column-I list few physical quantities and column-II
lists their dimensions. Choose the correct option
matching the two lists correctly
Column-I Column-II
(P) Pressure gradient (A) [M1L2T–2]
(3) (4)
(Q) Energy density (B) [M1L1T–1]
(R) Torque (C) [M1L–2T–2]
(S) Impulse (D) [M1L–1T–2]
Answer (1) (1) P-C, Q-A, R-B, S-D (2) P-C, Q-D, R-A, S-B
Sol. (3) P-A, Q-D, R-B, S-C (4) P-A, Q-C, R-B, S-D
Answer (2)
dp ML–1T –2
Sol. [Pressure gradient] ⇒ =
dz L
= [ML–2 T 2 ]
-4-
dU ML2 T –2 Sol. When proton is accelerated by potential difference
–1 –2
[Energy density] ⇒ =
= [ML T ] V, the linear momentum of proton
dV L 3
P2
[Torque] ⇒ [F ] × [r ] =
[MLT –2 2 –2
] × [L] = [ML T ] = eV
2m
[Impulse] ⇒ [F] [t] = [MLT–2]
[T] = [MLT–1] h
=P 2meV=
⇒ λ1
So, P → C, Q → D, R → A, S → B 2meV
13. Consider the following assertion & reason: When accelerated by potential difference of 3V,
Assertion (A): At sink temperature of –273°C, the then linear momentum of proton is
efficiency of a Carnot engine will be 1.
P2
Reason (R): Efficiency of a Carnot engine is given = 3eV
T 2m
by η = 1 − sink . h
TSource =P 6meV=
⇒ λ2
(1) (A) is correct, (R) is correct and correctly 6meV
explains A λ1
= 3
(2) (A) is not correct, (R) is correct λ2
(3) Both (A) & (R) are incorrect
(4) Both (A) & (R) are correct, (R) does not explain
(A)
Answer (1)
T
Sol. η = 1 − sink
TSource SECTION - B
If Tsink = 0 K ⇒ η = 1 Numerical Value Type Questions: This section
14. Electric field in a region is contains 10 questions. In Section B, attempt any five
questions out of 10. The answer to each question is a
E = 2 x 2 iˆ − 4 yjˆ + 6zkˆ NUMERICAL VALUE. For each question, enter the
correct numerical value (in decimal notation,
truncated/rounded-off to the second decimal place;
e.g. 06.25, 07.00, –00.33, –00.30, 30.27, –27.30) using
the mouse and the on-screen virtual numeric keypad in
the place designated to enter the answer.
21. For the given electrical circuit, the potential
difference between points B and C is zero. The
Find the charge inside the cuboid shown: value of x is _______.
(1) –8ε0 (2) 36ε0
(3) 12ε0 (4) 24ε0
Answer (4)
Sol. φtotal = 2(1)2[2 × 3] – 4(2)[1 × 3] + 6(3)[1 × 2]
= 12 – 24 +36
= 24
q
⇒ = 24
ε0
Answer (00.50)
⇒ q = 24ε0
15. Find the ratio of de Broglie wavelength of proton, Sol.
when it is accelerated across v and 3v potential
difference.
(1) 3 : 1 (2) 1: 3
(3) 1 : 3 (4) 3 : 1]
Answer (4)
-5-
VB = VC f
Sol. Average kinetic energy = K BT
x 2
2 x + 1 ( Average kinetic energy )H2 TH2 2
then =
3 x = =
( Average kinetic energy )O2 TO2 1
2 1
⇒ = 25. The relation between velocity (v) and position (x) of
3 x +1
a particle moving along x-axis is given by
3 4v2 = 50 – x2. The time period of the oscillatory
x +1=
2 88
motion of the particle is seconds.
1 n
⇒x= Ω
2 22
22. Two waves of same intensity from sources in phase Find n use π =
7
are made to superimpose at a point. If path
difference between these two coherent waves is Answer (07.00)
zero then resultant intensity is I0. If this path Sol. 4v2 = 50 – x2
λ 1
difference is where λ is wavelength of these v2
= (50 − x 2 )
2 4
waves, then resultant intensity is I, and if the path
1
λ =v 50 − x 2
difference is then resultant intensity is I2. Value 2
4
I +I Comparing equation of S.H.M.
of 1 2 is equal to
I0 ω A2 − x 2
v=
Answer (00.50) A2 = 50
Sol. Let individual intensity from source is I thus =
A 50 5 2
=
2π
I0 = I + I + 2 I × I cos 0 × 1
λ w= = 0.5 rad/sec
2
⇒ I0 = 4I 2π 2π
λ 2π T= = = 4π second
I1 = I + I + 2 I × I cos × w 0.5
2 λ
22
⇒ I1 = 0 π =
7
λ 2π
I2 = I + I + 2 I × I cos × 88 88
4 λ =
T =
7 n
⇒ I2 = 2I So, n = 7
I +I 1 26. Prism A has angle of prism equal to 6° and its
So, 1 2 = or 0.5
I0 2 material has refractive index 1.5. It is used in
23. A bullet (mass 10 grams) is fired from a gun (mass combination with prism B of refractive index 1.8 to
10 kg without the bullet) with a speed of 100 m/s. produce dispersion without deviation. Prism angle
of prism B is equal to _____ degrees.
x
The recoil speed of gun is m/s. Find x. Answer (03.75°)
10
Sol. For dispersion without deviation
Answer (1)
AA(µA – 1) + AB(µB – 1) = 0
Sol. Conserving momentum
6(1.5 – 1) + A(1.8 – 1) = 0
10
10 × V
= × 100 3
1000 A=
− −3.75°
=
0.8
1
⇒ V = m/s
10
24. The ratio of temperature (in K) of hydrogen and
oxygen is 2 : 1. The ratio of their average kinetic
energy per molecule is
Answer (02.00)
-6-
CHEMISTRY
Choose the correct answer : (3) H2Te > H2Se > H2S > H2O
(4) H2Te > H2S > H2O > H2Se
1. Maximum no. of e– in n = 4 shell
(1) 72 Answer (1)
(2) 50 Sol. The correct order of bond strength is
(3) 16
H2O > H2S > H2Se > H2Te
(4) 32
5. The correct order of acidic strength of the following
Answer (4)
compounds is
Sol. Maximum number of e– = 2n2
= 2(4)2
= 32
2. BOD value of a water sample is 3 ppm.
Select the correct option about the given sample of
water.
(1) a > b > c > d (2) c > a > b > d
(1) It is highly polluted water
(3) d > c > b > a (4) c > b > a > d
(2) It is clean water
(3) Concentration of oxygen in the given sample is Answer (2)
very less
Sol. The correct acidic order is
(4) None of these
Answer (2)
3. Which of the following chloride is more soluble in 6. What is Cl – Co – Cl bond angle in [Co(NH3)3Cl3]?
organic solvent? (1) 120° and 90°
(1) Be
(2) 90° and 180°
(2) K
(3) 90°
(3) Ca
(4) Mg (4) 180°
Answer (1) Answer (2)
Sol. Out of the given elements, the chlorides of K and
Sol.
Ca are largely ionic. So, they will be more soluble
in water and less soluble in organic solvents. BeCl2
has higher covalent character than MgCl2.
Therefore, BeCl2 is more soluble in organic
solvents than MgCl2.
-7-
7. The correct decreasing order of stability of the 9. Lead storage battery have 38% (w/w) H2SO4. Find
following compounds is
the temperature at which the liquid of battery will
freeze
K.kg
(i = 2.67); kf of water = 1.86
mole
(1) –3.1°C
(2) –31°C
(1) a > b > c > d
(2) d > b > c > a (3) –0.31°C
(3) b > d > a > c (4) –0.031°C
(4) b > a > d > c
Answer (2)
Answer (3)
Sol. Tf = ikfm
Sol. The correct stability order is
= (2.67)(1.86)(m)
38(1000)
m= = 6.25
(98)(62)
Tf = (2.67)(1.86)(6.25)
8. Which of the following is correct order of SN1 = 31.06C
reaction? Freezing point = –31.06°C
–
10. KMnO4 oxidises I in acidic & neutral medium in
which form – respectively.
-8-
12. The option containing correct match is 15. Nessler's reagent is
(List-I) (List-II)
(1) K2[HgI4]
A. Ni(CO)4 (i) sp3
B. [Ni(CN)4]2– (ii) sp3d2 (2) K3[HgI4]
13. Statement 1:– Antihistamine prevents the secretion (4) Both (2) and (3)
of acid in stomach
Statement 2: – Antiallergic and antacid work on Answer (1)
same receptors
Sol. Due to H-bonding, boric acid is solid at room
(1) 1 is correct, 2 is incorrect
temperature.
(2) Both are correct
(3) 1 is incorrect, 2 is correct
(4) Both are incorrect
Answer (4)
Sol. Antihistamines do not affect the secretion of acid in
stomach. Antiallergic and antacid drugs work on
different receptors. Therefore, both the statements
are incorrect. SECTION - B
14. Statement-1: During hall-heroult process mixing of Numerical Value Type Questions: This section
CaF2 and Na3AlF6 decreases the M.P. of Al2O3.
contains 10 questions. In Section B, attempt any five
Statement-2: During electrolytic refining Anode is
pure and cathode is impure. questions out of 10. The answer to each question is a
(1) Both are correct NUMERICAL VALUE. For each question, enter the
(2) Statement-1 is correct, statement-2 is incorrect
correct numerical value (in decimal notation,
(3) Both are incorrect
truncated/rounded-off to the second decimal place; e.g.
(4) Statement-1 is incorrect, statement-2 is correct
06.25, 07.00, –00.33, –00.30, 30.27, –27.30) using the
Answer (2)
mouse and the on-screen virtual numeric keypad in the
Sol. Mixture of CaF2 and Na3AlF6 decreases the melting
point of Al2O3. place designated to enter the answer.
-9-
21. For given Ecell, Answer (3)
EY2+ /Y = +0.34
540
t 90 = = 1350 sec
0.4
2.303 RT
= 0.06
F 1350 = 1.35 10x
If Ecell = t, find 5t (closest integer). x=3
Answer (6) 24. 1 mole of a gas undergoes adiabatic process given
5t = 5.65 V T2 = 450 K
22. Find the number of formula units of FeO per unit 25. Volume strength of H2O2 solution is 60 ‘V’, strength
cell (Round off to the nearest integer) of solution is______ g/L.
Given that density = 4.0 gm/cm3 (Round off to the nearest integer)
a = 5Å Answer (182)
Answer (04) 60
Molarity of H2O2 solution = M
11.2
ZM density NA a3 60 34
Sol. Density = Z= Strength of H2O2 solution =
NA a3 M 11.2
(log4 = 0.6)
- 10 -
MATHEMATICS
3 n −1
2
r
h(x) = 2[x] + f(x) Sol. lim 2 + n
n → n r =0
([] denotes greatest integer function)
then limit g ( h( x − 1) ) is 1
= 3 ( 2 + x ) dx
2
x →1 0
(1)
sin1
(2)
sin2 ( 2 + x )3 1
1 2 =3
3 0
(3) –1 (4) 2 = 27 – 8
Answer (2) = 19
- 11 -
5. Let f ( x ) = 3 − x + x + 2. The range of f(x) is a1 = 1, a2 = 2....a2022 = 2022
( )
13
y 5, 10 Sol. Let P = I1 + f1, f = 8 3 − 13
1
( ) ( )
13 13
1
The value of tan−1 −1 1 I1 + f1 − f1 = 8 3 + 13 − 8 3 − 13
6. + tan + .... +
1 + a1 2
a 1 + a2a3
( ( ) ( )
12 10
= 2 13C1 8 3 (13 ) + 13 C3 8 3 (13 )3
1
1
tan−1
1 + a2021a2022
( ) (13 )5 + ... + 13C13 ( 8 ) (13 )13
8 0
+ 13C5 8 3 3
if a1 = 1 and ai are consecutive natural numbers
f1 − f = 0
(1) − cot −1 ( 2021)
4 So, I1 is even
− cot −1 ( 2022 )
( )
9
(2)
4 Let Q = I2 + f2 , f2 = 9 − 6 2
− tan−1 ( 2021) ( ) − (9 − 6 2 )
9 9
(3) I2 + f2 − f2 = 9 + 6 2
4
( )
2
(4) − tan−1 ( 2022 ) = 2 9C0 99 + 9C2 97 6 2 + ...
4
Again f2 − f2 = 0
Answer (2)
a −a a −a
Sol. tan−1 2 1 + tan−1 3 2 + .... + I2 = even
1 + a1a2 1 + a2a3
8. Let p : I am well.
a−1 − a2021
tan 2022 q : I will not take rest
1 + a2021a2022
r : I will not sleep properly, then
( ) (
= tan−1 a2 − tan−1 a1 + tan−1 a3 − tan−1 a2 + ... + ) “If I am not well then I will not take rest and I will not
sleep properly” is logically equivalent to
( tan −1
a2022 − tan−1 a2021 ) (1) (~ p → q) r (2) ~ p → (q r)
(3) (~ p q) → r (4) (~ p q) → r
= tan−1 a2022 − tan−1 a1
Answer (2)
- 12 -
Sol. ~ p : I am not well 2
y
2 2 3+
q : I will not take rest dy 3x + y x
Sol. =− =−
2 2 2
r : I will not sleep properly dx 3y + x y
3 + 1
I will not take rest and I will not sleep properly q r x
If I am not well then I will not take rest and I will not y
sleep properly ~ p → (q r) Let, =u
x
9. q is maximum value of p lying in interval [0, 10],
dy du
5p =u+x
roots of x 2 – px + = 0 are having rational roots. dx dx
d
Find area of region
du − 3 + u
2
( )
S : 0 y ( x − q )
2 u+x =
dx 3u 2 + 1
( ) ( )
(1) 243 (2) 723 2 2
du − 3 + u − u 3u + 1
(3) 81 (4) 3 x =
dx 3u 2 + 1
Answer (1)
Sol. D = p2 – 5p must be a perfect square i.e. possible 3 2
du − 3u + u + u + 3
x =
( )
when p = 9
dx 3u 2 + 1
Region for 0 y ( x − 9)2 , in 1st quadrant
x
du − ( u + 1) 3u − 2u + 3
=
2
( )
dx 3u 2 + 1
3u 2 + 1 dx
du = −
(u + 1) ( 3u 2
− 2u + 3 ) x
1 1
( 6u − 2) dx
u + 1 3u 2 − 2u + 3 du = − x
9 2 + 4
A = ( x − 9)2 dx
0
1 1
9 ln ( u + 1) + ln 3u 2 − 2u + 3 = − ln x + C
( x − 9)3 93 2 4
= =0+
3 0 3
= 243 sq. unit
1
2
1 1
ln ( x + y ) − ln x + ln 3y 2 − 2xy + 3 x 2
2 4
( )
dy 3x 2 + y 2
10. If =− , y (1) = 0, then f(x) is 1
dx 3y 2 + x 2 − 2ln x = − ln x + C
4
( )
2 xy
(1) log ( x + y ) + =0 ln ( x + y ) + ln 3 y 2 − 2 xy + 3 x 2 = C
2
(x + y ) 2
(2) log ( x + y ) −
2xy
=0 ( x + y )2 ( 3 x 2 − 2xy + 3y 2 ) = C
( x + y )2
y (1) = 0
(
(3) 3 = 3 y 2 − 2 xy + 3 x 2 ) ( x + y )2
C=3
(4) 3 = ( 3 y 2 − 2 xy + 3 x 2 ) ( x + y )
( x + y )2 ( 3x 2 − 2xy + 3y 2 ) = 3
Answer (3)
- 13 -
11. A bag contains 3 same balls and 3 different balls of SECTION - B
three different colours. Two balls are drawn
Numerical Value Type Questions: This section
randomly with replacement. The probability they
contains 10 questions. In Section B, attempt any five
have same colour is m. Again four balls are drawn
one by one with replacement, then probability of questions out of 10. The answer to each question is a
getting three same balls is n. The value of m. n is NUMERICAL VALUE. For each question, enter the
correct numerical value (in decimal notation,
3 6
(1) (2) truncated/rounded-off to the second decimal place; e.g.
49 49
06.25, 07.00, –00.33, –00.30, 30.27, –27.30) using the
43 8 mouse and the on-screen virtual numeric keypad in the
(3) (4)
147 81 place designated to enter the answer.
Answer (4)
21. Two A.P.’s are given as under
Sol. For m 3, 7, 11, ……
1 1 1, 6, 11, 16,….
both balls is one of different colours = ·3
6 6 Find 8th common term that is appearing in both the
series
1 1
both balls is from the same balls = Answer (151)
2 2
Sol. First common term is 11 and common terms will
1 1 1 appear in an A.P. having common difference as
m= + =
4 12 3 LCM of (4, 5) = 20
For n T8 = 11 + (8 – 1) 20
= 151
Same ball is from the different coloured balls
22. Using 1, 2, 2, 2, 3, 3, 5 find number of 7-digit odd
1 3 5 numbers that can be formed
= 3 4 ·
6 6 Answer (240)
6!
Or same ball is from the 3 same balls Sol. - - - - - - 1 → = 60
2!3!
1 3 1
= = 4 · 6!
2 2 ------3→ = 120
3!
6!
n=
10
+
1
=
8 ------5→ = 60
3!2!
63 4 27
Total = 240
8
mn = 23. 50th root of x is 12
81
50th root of y is 18
Remainder when x + y is divided by 25.
Answer (23)
Sol. 1250 + 1850 = 14425 + 32425
= (25K1 – 6)25 + (25K2 – 1)25
= 25 – 625 – 1
625 + 1 = (65)5 + 1
= (7776)5 + 1
= (251 + 1)5 + 1 = 25p + 2
1250 + 1850 = 25 – (25p + 2)
Remainder = 23
- 14 -
24. Let a = {1, 3, 5, … 99} 26. If area of the region bounded by the curves y = x2,
and b = {2, 4, 6, … 100} y = (1 – x)2 and y = 2x(1 – x) is A, then find the
The number of ordered pair (a, b) such that a + b value of 540A,
when divided by 23 leaves remainder 2 is Answer (135)
Answer (108) 1 ½ 1
Sol. a + b = 23 + 2 Sol. A = 2x(1 − x )dx – x 2dx – (1 − x )2 dx
0 0 ½
= 0, 1, 2, ….
But can’t be even
if =1 (a, b) → 12 pairs
=3 (a, b) → 35 pairs
=5 (a, b) → 42 pairs
=7 (a, b) → 19 pairs
=9 (a, b) → 0 pairs
b = iˆ − jˆ + 2kˆ
1
=
4
Line will be parallel to a b
540A = 135
iˆ jˆ kˆ 27. A = { 2, 4, 6, 8, 10}
ab = 1 3 – 2 = iˆ(4) − jˆ(4) + kˆ(– 4) Find total no. of functions defined on A such that
1 –1 2 f(m·n) = f(m) · f(n), m, n A
n = iˆ − jˆ − kˆ Answer (25)
Sol. f(4) = (f(2)2 = 4
(a2 − a1) n
d= f(8) = (f(2)3 = 8
|n|
a2 − a1 = 3iˆ + 7kˆ
iˆ ˆj kˆ
( a2 − a1 ) n = 3 0 7
1 –1 –1
For 6 and 10 we have 5 options
= iˆ(7) − jˆ(– 10) + kˆ(– 3)
Total functions = 5 × 5 = 25
100 + 49 + 9 158
d= = =
3 3
32 = 158
- 15 -
JEE Main 2023 Jan 31 Shift 2 Physics Question Paper (Memory-Based)
-2-
6. Match the physical quantities given in column-I with Answer (3)
the physical dimensions in column-II correctly. Sol. If angle of projection for projectile 1 is 60° then
Column-I Column-II angle of projectile 2 is 30° for same range
u 2 sin2 60° u 2 sin2 30°
A. Torque (P) ML–1T–2 =H1 = , H2
2g 2g
B. Stress (Q) ML2T–2
u2 402
C. Pressure gradient (R) ML–2T–2 H1 + H2 = = = 80 m
2g 2 × 10
D. Angular momentum (S) ML2T–1 9. A body has weight W on the surface of earth. Find
(1) A(S), B(P), C(R), D(Q) the weight at a height 9 times the radius of earth.
(2) A(Q), B(P), C(R), D(S) W W
(1) (2)
(3) A(P), B(S), C(R), D(Q) 100 81
-3-
11. For a medium, it is given that Sol. When lens is placed in air,
Young’s modulus = 3.2 × 1010 N/m2 1 µ2 1 1
= − 1 −
Density = 8000 kg/m3 f µ1 R1 R2
Find speed of sound in this medium.
1 1.5 1 1
(1) 1000 m/s = − 1 − ...(1)
15 1 R1 R2
(2) 2000 m/s
4
(3) 500 m/s When submerged in water µ =
3
(4) 4000 m/s
1.5
Answer (2) 1 −1 1 1
⇒ = 4 − ...(2)
f ′ R1 R2
Y 3
Sol. v =
ρ
Equation (1)
3.2 × 10 10 Equation (2)
=
8000 f ′ 0.5
= × 4
= 2000 m/s 15 0.5
12. When current of 4 amperes is made to run through f′ = 60 cm
a resistance of R ohms for 10 seconds, it produces
∆f = f′ – f = 60 – 15 = 45 cm
heat energy of H units. Now if 16 amperes of
current is made to flow through same resistance for 15. In a moving coil galvanometer, number of turns in
10 seconds than heat energy produced will be the coil are increased to increase the current
(1) 16 H (2) 4 H sensitivity by 50%. Find percentage change in
voltage sensitivity.
(3) 8 H (4) 2 H
(1) –50%
Answer (1)
(2) 50%
Sol. H = i2Rt = 42R × 10 = 160R
(3) No change
H′ = I2Rt = 162R × 10 = 2560R = 16 H
(4) 25%
13. Across an inductor of 5 mH an AC source with
potential given as 268 sin(200 πt) Volts is used. The Answer (3)
value of inductive reactance provided by inductor is Sol. Current sensitivity
equal to
θ nAB
π =
(1) 2π Ω (2) Ω I K
2
nAB
(3) 20π Ω (4) π Ω Voltage sensitivity =
KR
Answer (4)
As current sensitivity increases by 50%
Sol. XL = ωL = 200π × 5 × 10–3
So number of turns increases by 50%
=πΩ
Resistance also increases by 50%
14. A lens of refractive index 1.5 and focal length 15 cm
Therefore, voltage sensitivity remains constant.
in air is submerged in water. Change in focal length
4
of lens is r =
3
(1) 45 cm (2) 60 cm
(3) 30 cm (4) 10 cm
Answer (1)
-4-
SECTION - B 24. A ball was dropped from 20 m height from ground.
Numerical Value Type Questions: This section Find the height (in m) upto which it rises after the
1
contains 10 questions. In Section B, attempt any five collision. use
= e =
, g 10 m/s2
questions out of 10. The answer to each question is a 2
NUMERICAL VALUE. For each question, enter the
Answer (05.00)
correct numerical value (in decimal notation,
truncated/rounded-off to the second decimal place;
e.g., 06.25, 07.00, –00.33, –00.30, 30.27, –27.30) using Sol.
the mouse and the on-screen virtual numeric keypad in
the place designated to enter the answer.
21. In a series RLC circuit, R = 80 Ω, XL = 100 Ω,
XC = 40 Ω. If the source voltage is 2500cos(628t)
Volts, find peak current in the circuit (in Amperes)
Answer (25.00)
v′ = ev
2
Sol. Z = R + ( X L − XC )
2
(v ′)2 e2v 2 2
h′
= = = e= h (0.5)2 × 20
=
2
802 + (100 − 40 ) = 100 Ω 2g 2g
Vo 20
⇒ Io = = 25 A = = 5m
Z 4
22. Two discs of same mass, radii r1 and r2, thickness h′ = 5 m
1 mm and 0.5 mm have densities in the ratio 3 : 1. 25. A particle is in uniform circular motion with time
The ratio of their moment of inertia about diameter
period 4 s and radius 2 m. Find the magnitude of
is 1 : x. Find x
displacement (in m) in 3 s.
Answer (06.00)
Answer (02.00)
Sol. 3 3π
Sol. θ= × 2π=
4 2
Mass of both disc is equal ⇒ Displacement =
2R
So ⇒ M1 = M2
= 2m
( ) (
⇒ πr12 h1ρ1 = πr22 h2 ρ2) 26. Two wavelengths λ1 = 600 nm and λ2 = 800 nm are
h ρ
2 used in a YDSE experiment. Their maximas
r22
⇒r × 1× 1 =
1
h2 ρ2 coincide at certain locations on the screen. Find the
minimum separation (in mm) between such a
ρ1 ρ1 ρ 1
⇒ r12 × 2 × =r22 =3 ⇒ 2 = location and central maxima. It is given that d = 0.35
ρ2 ρ2 ρ1 3 mm & D = 7 m
r 2 ρ2 1 Answer (48.00)
⇒ 1= =
r22 2ρ1 6 λ1D λ D
Sol. n1 = n2 2
1 2 d d
Mr1 r12 1
4
Ratio of M.O.I = = = ⇒ 6n1 = 8n2
1 2 r22 6
Mr2 ⇒ Minimum n1 = 4
4
23. A body moving horizontally has an initial speed of & n2 = 3
20 m/s. Due to friction, body stops after 5 seconds. 4 × 600 nm × 7 m
x ⇒ Minimum separation =
If mass of body is 5 kg, co-efficient of friction is . 0.35 mm
5
Find x. Take g = 10 m/s2. = 48
Answer (02.00)
Sol. v = u + at
⇒ 0 = 20 + (–µg) (5)
⇒ µ = 0.4
-5-
JEE Main 2023 Jan 31 Shift 2 Chemistry Question Paper (Memory-Based)
multiple choice questions. Each question has 4 choices 4. Which of the following compound contain maximum
(1), (2), (3) and (4), out of which ONLY ONE is correct. number of chlorine atoms?
-6-
7. Which of the following metals of F-block have half- 10. A reaction follows 1st order kinetics with rate
filled f-subshell?
constant (k) = 20 min–1. Calculate the time required
(a) Samarium (Sm)
1
(b) Gadolinium (Gd) to reach to concentration to times of initial
32
(c) Europium (Eu) concentration
(d) Terbium (Tb)
(1) 0.17325 min (2) 1.7325 min
(1) (a) and (b)
(3) 17.325 min (4) 173.25 min
(2) (b) and (c)
(3) (c) and (d) Answer (1)
(4) (a) and (c) CO CO
Sol. C = =
[Atomic numbers : Sm = 62, Eu = 63, Gd = 64, (2)n 32
Tb = 65] n=5
-7-
Sol. (i) n = 3; l = 0; m = 0 3s orbital gives monocarboxylic acid with Br2/H2O and
(ii) n = 4; l = 0; m = 0 4s orbital tetraacetate with acetate and isopentane with
(iii) n = 3; l = 1; m = 0 3p orbital RedP/HI.
(iv) n = 3; l = 2; m = 0 3d orbital 15. Which of the following has more relative lowering in
The correct order of energy is 3d > 4s > 3p > 3s vapour pressure at the same temperature.
Hence correct answer is (2) (1) 0.1 M urea (2) 0.1 M NaCl
13. Two metals are given, (3) 0.1 M sucrose (4) 0.1 M CaCl2
Metal – 1 Work function = 4.8 ev Answer (4)
Metal – 2 Work function = 2.8 ev Sol. Relative lowering in vapour pressure is a colligative
Photons of wavelength 350 nm are incident on both property and colligative property depends only on
metals separately which metal will eject electrons the amount of solute from the given, CaCl2 will have
at this wavelength?
maximum amount, hence its solution will show
(1) Metal – 1 only
maximum relative lowering in vapour pressure
(2) Metal – 2 only hence the correct answer is option (4)
(3) Both metal – 1 and metal – 2
16. Assertion : First ionisation energy of 4d series
(4) None of metal – 1 and metal – 2 elements is always greater than those of 3d series
Answer (2) elements.
12400 Reason : 4d series elements have much more
Sol. Ephoton = = 3.54 ev
3500 nuclear charge than those of 3d series elements.
Wmetal – 1 > Ephoton > Wmetal – 2 (1) Assertion is correct but Reason is incorrect.
Only metal – 2 will emit photons (2) Assertion is incorrect but Reason is correct.
(3) Both the Assertion and Reason are correct.
14. A biomolecule gives following observations (4) Both the Assertion and Reason are incorrect.
(i) With Br2/H2O it gives monocarboxylic acid.
Answer (2)
(ii) With acetate it gives tetraacetate.
Sol. The first ionisation energy of 4d series elements is
(iii) With HI/RedP it gives isopentane.
not always greater than those of 3d series
The correct structure of the biomolecule is
elements. So Assertion is incorrect. The Reason is
(1) (2) correct because 4d series elements have much
more nuclear charge than those of 3d series
elements.
17. What is the structural formula of compound C4H11N,
which reacts with HNO2 and is optically active?
(3) (4)
(1) (2)
Answer (1)
Sol.
-8-
hc 22. For the given reaction
18. Energy of a radiation = . If = +96 kJ/mole
absorb C + O2 ⎯⎯→ CO2 (g)
thus find absorbed (in Å)
12 gm of C is reacted with 48 gm of O2 to give CO2.
(1) 12471Å (2) 124.71Å
If volume of CO2 gas produced at STP is t litre.
(3) 1247.1Å (4) 1.2471Å
Find out 2t (closest integer).
Answer (1) Given: Molar volume at STP = 22.4 L/mole
−34
6.626 10 3 10 8
Answer (45)
Sol. 6.023 1023 =
96 103 C + O2 ⎯⎯→ CO2
= 1. 2471 × 10–6 M 12 gm 48 gm ___
= 12471 Å Sol. 3
1 mole mole ___
19. 2
20. 0 1 mole
SECTION - B Volume = t = 22.4 litre
Numerical Value Type Questions: This section 2t = 44.8 litre
-9-
JEE Main 2023 Jan 31 Shift 2 Mathematics Question Paper (Memory-Based)
SECTION - A x 2 + 2x + 1
Sol. y =
Multiple Choice Questions: This section contains 20 x 2 + 8x + 1
multiple choice questions. Each question has 4 choices x2(y – 1) + x(8y – 2) + y – 1 = 0, xR
(1), (2), (3) and (4), out of which ONLY ONE is correct. If y 1
Choose the correct answer : D0
4(4y – 1)2 – 4(y – 1) (y – 1) 0
1. Let a = iˆ + 2 ˆj − 3kˆ , b = iˆ − jˆ + 3kˆ and c = iˆ + 2 jˆ + 2kˆ.
(4y – 1)2 – (y – 1)2 0
There is a u such that u a = b c & u a = 0. (4y – 1 – (y – 1)) (4y – 1 + y – 1) 0
2 (3y) (5y – 2) 0
Find 25 u
925
(1) 560 (2)
7
2
(3) 446 (4) 330 y ( – ,0 , – 1
Answer (2) 5
If y = 1
Sol. ( u a ) + ( u a ) = u
2 2 2 2
a 6x = 0 x = 0
2
bc
2
+ 0 = u 14
2 y ( – ,0 ,
5
−2 a b
(3) (– ) (4) −, 1, ) Now if 2 + 0 & 2+ 0
5 b c
a
Answer (2) then 2 + can be positive or negative.
c
- 10 -
xdx 6. Foot of perpendicular from origin to a plane which
4. If 2
x +x+2
; Af ( x ) + B g ( x ) + C where C is
cuts the coordinate axes at A, B, C is (2, a, 4). Area
constant of integration, then A + 2B is equal to of tetrahedron OABC is 144 m2. Which of the
following points does not lie on plane?
(1) 1 (2) 0
(1) (2, 2, 4)
(3) –1 (4) –2
(2) (0, 3, 4)
Answer (2)
(3) (1, 1, 5)
Sol. Let x = (2 x + 1) + (4) (5, 5, 1)
1 –1 Answer (2)
= ,=
2 2 Sol. Equation of required plane:
1 1 1 a2 20 + a2 20 + a2
= 2 x2 + x + 2 – +C A 10 + ,0,0 , B 0, ,0 ,C 0,0,
2 2 1
2
7 2 a 4
x + +
2 4
1
Area of tetrahedron = a b c = 144
2 1 1
= x + x + 2 – ln x + + x 2 + x + 2 + C 6
2 2
1 20 + a2 20 + a2 20 + a2
I = A f (x ) + B g(x ) + C = 144
6 2
a
4
–1
A = 1, B = (20 + a2)3 = 144 × 48a
2
a=2
6
3 x 2 + 1 + 3 x 2 – 1
Equation of plane: 2x + 2y + 4z = 24
5. limit is equal to
x→ 6 6
x + y + 2z = 12
x + x 2 – 1 + x – x 2 – 1
(0, 3, 4) does not lie on plane
27 i −1
(1) 27 (2)
2 7. If z = , then z is
sin + i cos
(3) 18 (4) 6 6 6
Answer (3) (1) 2 cos + i sin
12 12
6
3 x 2 + 1 + 3 x 2 – 1 1 5 5
(2) cos 12 + i sin 12
Sol. limit
6 6 2
x→
x + x 2 – 1 + x – x 2 – 1
5 5
(3) 2 cos + i sin
12 12
( 3)
6
2 x 6 + ....... ( lower power of x )
= limit 1
x → 2 x 6 + ........ ( lower power of x )
(4) cos 12 + i sin 12
2
= 27 Answer (3)
- 11 -
10. If a = 31, 4 b = c = 2 , Given that
i −1 i −1 –
Sol. z = = = (i − 1) · e 3
sin + i cos
6 6
cos + i sin
3 3 ( )
2 a b = 3 ( c a ) . If angle between b and c is
2 ac
z = (i − 1) cos − i sin
3 3 . Find
3 ab
1 3i
= (i − 1) − (1) 3 (2) – 3
2 2
(3) 1 (4) –3
1
(
= i + 3 − 1+ 3 i
2
) Answer (2)
3 −1
+i
3 + 1
(
Sol. a 2b + 3c = 0 )
2 2
5
a = 2b + 3c( )
arg(z) = &|z|= 2
12
5 5
a
2
( 2
= 2 4 b + 9 c + 12b c
2
)
z = 2 cos + i sin
12 12 31 = 312 = ± 1
Given that [0, 2], the largest interval of values
( )
8.
of which satisfy the inequation sin–1(sin) – cos–1 a = 2b + 3c
(sin) 0 is
ac 2 bc
3 =
(1) , (2) ,
4 4 4 2 ab 2b b + 3c b
5
(3) [0, ]
( )
(4) , 2 2
bc = b
2
c
2
– b c
2 4
Answer (1) 2
1 1
Sol. sin ( sin ) − − sin−1 sin 0
−1 = 4 – 1 –
2 4 2
1 3
sin–1 sin = 1– =
4 4 4
1
sin 1 ac 3 3
2 = =
ab 1 3 –1
3 2 –
4 2
4 4
11. Number of 7 digit odd numbers formed using 7
9. If ( ( p q ) (r q ) ) ( ( p r ) q ) is a tautology,
digits 1, 2, 2, 2, 3, 3, 5 will be
where r p, q,~ p,~ q , then the number of values
(1) 80 (2) 420
of r is
(1) 1 (2) 2 (3) 240 (4) 140
(3) 3 (4) 4 Answer (3)
Answer (2)
Sol. Even numbers formed
Sol. ( ( p q ) (r q ) ) ( ( p r ) q )
_______2
(( p q ) (r q )) ( p r q )
6!
(( p r (q q ) ) ( p r q ) Number of ways =
2!2!
= 180
T ( p r q)
7! 720 7
p r q Total numbers = = = 420
3!2! 12
For the above statement to be tautology r can be
p or q Odd numbers = 420 – 180
Two values of r are possible = 240
- 12 -
12. The minimum value of the function Sol. 5 + 6 – = 0
f ( x ) = x 2 – x + 1 + x 2 – x + 1 , where [x] denotes 6 + 3 + 3 = 0
greatest integer function, is 8 + 8 = 0 = −
3 5
(1) (2) & =
4 4
1 = k, = k, = – k
(3) (4) 0 2(k) + 5(– k) + 3(–k) = 5
4
5
Answer (1) k=−
6
Sol. x 2 – x + 1 = g ( x ) attains minimum value
5 5 5
1 = − , = , =
when x = 6 6 6
2
25 45
1 6 + 5 + = −5 + +
So, minimum value of f(x) will be at x = 6 6
2
40 20
1 3 = =
f = +0 6 3
2 4
3
=
4
x2 y2
13. If for = 1, ( 4, 0) are foci and e = 3 . Then
−
a2 b2
length of latus rectum is
16 SECTION - B
(1) 8 (2)
3
Numerical Value Type Questions: This section
(3) 4 (4) 2 3 contains 10 questions. In Section B, attempt any five
Answer (2)
questions out of 10. The answer to each question is a
Sol. ae = 4
NUMERICAL VALUE. For each question, enter the
4
a= correct numerical value (in decimal notation,
3
truncated/rounded-off to the second decimal place; e.g.
2b2
LR = 06.25, 07.00, –00.33, –00.30, 30.27, –27.30) using the
a
mouse and the on-screen virtual numeric keypad in the
2
= a2 (e2 − 1) place designated to enter the answer.
a
9
= 2a(e2 − 1) 4x 5
21. Coefficient of x–6 in expansion of − is
8 5 2x 2
= (3 − 1)
3 Answer (–5040)
9 −r r
16 4x −5
= Sol. Tr +1 = 9Cr 2
3 5 2x
5 6 8 9 – 3r = – 6
14. If [ ] 6 3 8 = [0 0 0] r =5
–1 3 0 4 5
4 5
Where (, , ) be a point on 2x + 5y + 3z = 5 then Coefficient of x −6 = 9C5 −
5 2
6 + 5 + 9 = ?
9! 44 −55
20 =
(1) 20 (2) 5!4! 54 25
3
(3) 21 (4) 7 = 6·7·3· 8(–5)
Answer (2) = –5040
- 13 -
22. The value of sum ( 2n + 1)! ( n − 1)! 11
Sol. =
1.12 – 2.32 + 3.52 – 4.72 …+ 15.(29)2 is ( n + 2)! ( 2n – 1)! 21
Answer (6952)
( 2n + 1)( 2n ) 11
Sol. Separating odd placed and even placed terms we =
get ( n + 2)( n + 1) n 21
S = (1.12 + 3.52 + …15.(29)2) – (2.32 + 4.72 + … + 2n + 1 11
=
14.(27)2) ( n + 1)( n + 2) 42
8 7
( 2n − 1)( 4n − 3 ) − ( 2n )( 4n − 1) n=5
2 2
S=
n =1 n =1 n2 + n + 15 = 25 + 5 + 15 = 45
Applying summation formula we get
x 16 + 20 2
= 29856 – 22904 = 6952 25. x+ – x
dx =
15
0
a b then is equal to
23. Let A = be a 2 × 2 matrix such that a, b, c,
c d Answer (02.00)
d {0, 1, 2, 3, 4, }. The number of matrices A such
( x + + x)
x
Sol.
that sum of elements of A is a prime number lying
0
between 2 and 13 is
1
Answer (204) ( x + )
3/2
– ( x + )1/2 + x 3/2
0
Sol. As given a + b + c + d = 3 or 5 or 7 or 11
if sum = 3 1 2 2 2
( x + )5/2 – ( x + )3/2 + x 5/2
5 3 5 0
(1 + x + x2 + ....+ x4)4 ⎯→ x3
12 5/2 2 2 2 2
(1 – x5)4 (1 – x)–4 ⎯→ x3 = (2 ) – (2 )3/2 + 5/2 – 5/2 + 5/2
5 3 5 5 3
4 + 3 –1C3 = 6C3 = 20 1 27/2 5/2 25/2 5/2 2 5/2
= − +
If sum = 5 5 3 3
If sum = 7 =
3/2
15
(
3 27/2 − 5 25/2 + 10 )
(1 – 4x5) (1 – x)–4 → x7
3/2 3/2
4+7–1C
7 – 4. 4+2–1C2 = 10C7 – 4. 5C2 = 80 =
15
(
24 2 − 20 2 + 10 =
15
)
4 2 + 10 ( )
If sum = 11
(1 – 4x5 + 6x10) (1 – x)–4 → x11 16 + 20 2
=
4 + 11 – 1C
11 – 4.4+6–1 C6 + 6.4+1–1C1 15
= 14C11 – 4.9C6 + 6.4 = 364 – 336 + 24 = 52 =2
Total matrices = 20 + 52 + 80 + 52 = 204
2n +1
Pn −1 11
24. If = , then n2 + n + 15 equals
2n +1 21
Pn
Answer (45)
- 14 -
SECTION-A
1. An arc PQ of a circle subtends a right angle at its centre O. The mid point of the arc PQ is R. If
OP u,O R vand OQ u v , then , 2 are the roots of the equation :
(1) 3x2 – 2x – 1 = 0 (2) 3x2 + 2x –1 = 0 (3) x2 – x – 2 = 0 (4) x2 + x –2 = 0
Sol. (3)
R
Q
P
v
u
Q q
R v
P u
O(0,0)
Let OP u i
OQ q j
R is the mid point of PQ
1 1
Then OR v i j
2 2
Now
OQ u v
1 1
j i i j
2 2
2, 0 1
2
Now equation
x2 2 x 2 0
x2 1 2 x (1)(2) 0
x2 x 2 0
2. A square piece of tin of side 30 cm is to be made into a box without top by cutting a square from each corner
and folding up the flaps to form a box. If the volume of the box is maximum, then its surface area (in cm2) is
equal to :
(1) 800 (2) 1025 (3) 900 (4) 675
Sol. (1)
Let the side of the square to be cut off be x cm.
Then, the length and breadth of the box will be (30 – 2x) cm each and the height of the box is x cm therefore,
J
(30 – 2x) cm
J
x cm
30 cm
The volume V(x) of the box is given by
V(x) = x(30 – 2x)2
dv
= (30 – 2x)2 + 2x × (30 – 2x) (–2)
dx
0 = (30 – 2x)2 – 4x (30 – 2x)
0 = (30 – 2x) [(30 – 2x) – 4x]
0 = (30 – 2x) (30 – 6x)
x = 15, 5
x 15 (Not possible)
{V 0}
Surface area without top of the box = b + 2(bh + h)
= (30 – 2x) (30 – 2x) + 2 [(30 – 2x) x + (30 – 2x) x]
= [(30 – 2x)2 + 4 {(30 – 2x)x}
= [(30 – 10)2 + 4(5) (30 – 10)]
= 400 + 400
= 800 cm2
3. Let O be the origin and the position vector of the point P be –iˆ – 2ˆj 3kˆ . If the position vectors of the A, B
and C are –2iˆ ˆj – 3k,
ˆ 2iˆ 4jˆ – 2kˆ and –4iˆ 2ˆj – kˆ respectively, then the projection of the vector OP on a
vector perpendicular to the vectors AB and AC is :
10 8 7
(1) (2) (3) (4) 3
3 3 3
Sol. (4)
Position vector of the point P(1, 2,3), A(2,1, 3) B(2,4, 2), and C(4,2, 1)
AB AC
Then OP.
(AB AC)
i j k
AB AC 4 3 1
2 1 2
5. Let two vertices of a triangle ABC be (2, 4, 6) and (0, –2, –5), and its centroid be (2, 1, –1). If the image of the
third vertex in the plane x + 2y + 4z = 11 is (, , ), then + + is equal to :
(1) 76 (2) 74 (3) 70 (4) 72
Sol. (2)
A(2, 4,6)
G(2,1, 1)
C(x, y, z)
B(0, 2, 5)
Given Two vertices of Triangle A(2, 4,6) and B(0, 2, 5) and if centroid G(2,1, 1)
Let Third vertices be (x, y, z)
20x 42 y 65 z
Now 2, 1, 1
3 3 3
x 4, y 1, z 1
Third vertices C(4,1, 4)
Now, Image of vertices C(4,1,–4) in the given plane is D()
C(4,1, 4)
x 2y 4z 11 0
D(, , )
Now
4 1 4 (4 2 16 11)
2
1 2 4 1 4 16
4 1 4 42
2
1 2 4 21
6, 5, 4
Then
(6 5) (5 4) (4 6)
30 20 24
74
x 2 y z 5 x 4 y 1 z 3
7. The shortest distance between the lines and is :
1 2 2 1 2 0
(1) 8 (2) 7 (3) 6 (4) 9
Sol. (4)
x 2 y z 5 x 4 y 1 z 3
and
1 2 2 1 2 0
a 2 a1 b 2 b1 c 2 c1
l1 m1 n1
l2 m2 n2
Shortest distance (d)
i j k
l1 m1 n1
l2 m2 n2
4 2 1 0 3 5
1 2 2
1 2 0
i j k
1 2 2
1 2 0
6 1 8
1 2 2
1 2 0
i(4) j(2) k(2 2)
54
4i 2 j 4k
54
16 4 16
54
6
9
13 13
1 1
If the coefficient of x in ax – 2 and the coefficient of x–5 in ax 2
7
8. are equal, then a4b4 is equal
bx bx
to :
(1) 22 (2) 44 (3) 11 (4) 33
Sol. (1)
13
1
ax – 2
bx
We have,
Tr+1 = nCr (p)n–r (q)r
r
1
Tr+1 = 13Cr (ax)13–r – 2
bx
r
1
= 13Cr (a)13–r – (x)13–r.(x)–2r
b
r
1
= 13Cr (a)13–r – (x)13–3r …(1)
b
Coefficient of x7
13 – 3r = 7
r=2
r in equation (1)
2
1
– (x)
13 13–2 13–6
T3 = C2 (a)
b
2
1
= 13C2 (a)11 (x)7
b
(a)11
Coefficient of x7 is 13C2
b2
13
1
Now, ax 2
bx
r
1
Tr+1 = 13Cr (ax)13–r 2
bx
r
13 13–r 1 13–r –2r
= Cr (a) (x) (x)
b
r
1
13
= Cr (a) 13–r
(x)
13–3r
…(2)
b
Coefficient of x–5
13 – 3r = –5
r=6
r in equation
6
T 13 13–6 1 13–18
7 = C6 (a) (x)
b
6
1
T7 = 13C6 (a)7 (x)–5
b
6
1
Coefficient of x–5 is 13C6 (a)7
b
ATQ
Coefficient of x7 = coefficient of x–5
T3 = T7
a11 13
6
1
13
C2 2 = C6 (a)7
b b
13
C6
a4.b4 = 13
C2
13 12 11 10 9 8 1
= = 22
13 12 6 5 4 3
9. A line segment AB of length moves such that the points A and B remain on the periphery of a circle of
radius . Then the locus of the point, that divides the line segment AB in the ratio 2 : 3, is a circle of radius :
2 19 3 19
(1) (2) (3) (4)
3 7 5 5
Sol. (4)
60°
P
A 2:3 B
Since OAB form equilateral
OAP = 60º
2
AP =
5
OA 2 AP 2 – OP 2
cos 60°=
2OA.AP
4 2
2 – OP 2
1 25
=
2 2
2
5
2 2
4 2
= 2 + – OP2
5 25
19 2
OP2 =
25
19
OP =
5
19
Therefore, locus of point P is
5
10. For the system of linear equations
2x – y + 3z = 5
3x + 2y – z = 7
4x + 5y + z = ,
which of the following is NOT correct ?
(1) The system in inconsistent for = –5 and = 8
(2) The system has infinitely many solutions for = – 6 and = 9
(3) The system has a unique solution for –5 and = 8
(4) The system has infinitely many solutions for = –5 and = 9
Sol. (2)
Given
2x – y + 3z = 5
3x + 2y – z = 7
4x + 5y + z =
2 –1 3
= 3 2 –1 = 7 + 35
4 5
= 7 ( + 5)
For unique solution 0
–5
For inconsistent & Infinite solution
=0
+ 5 = 0 = –5
5 –1 3
1 = 7 2 –1 = – 5( – 9)
5 –5
2 5 3
2 = 3 7 –1 = 11( – 9)
4 –5
2 –1 5
3 = 3 2 7
4 5
3 = 7 ( – 9)
For Inconsistent system : -
At least one 1, 2 & 3 is not zero = – 5, = 8 option (A) True
Infinite solution:
1 = 2 = 3 = 0
From here – 9 = 0 = 9
= – 5 & option (D) True
=9
Unique solution
–5, = 8 option (C) True
Option (B) False
For Infinitely many solution must be –5.
11. Let the first term a and the common ratio r of a geometric progression be positive integers. If the sum of
squares of its first three is 33033, then the sum of these terms is equal to :
(1) 210 (2) 220 (3) 231 (4) 241
Sol. (3)
Let a, ar , ar2 be three terms of GP
Given : a2 + (ar)2 + (ar2)2 = 33033
a2 (1 + r2+ r4) = 112.3.7.13
a = 11 and 1 + r2 + r4 = 3.7.13
r2 (1 + r2) = 273 – 1
r2(r2 + 1) = 272 = 16 × 17
r2 = 16
r=4 [ r > 0]
Sum of three terms = a + ar + ar2 = a (1 + r + r2)
= 11 (1 + 4 + 16)
= 11 × 21 = 231
x 3 y 2 1 z
12. Let P be the point of intersection of the line and the plane x + y + z = 2. If the distance
3 1 2
of the point P from the plane 3x – 4y + 12z = 32 is q, then q and 2q are the roots of the equation :
(1) x2 + 18x – 72 = 0 (2) x2 + 18x + 72 = 0 (3) x2 – 18x –72 = 0 (4) x2 – 18x + 72 = 0
Sol. (4)
x3 y 2 1– z
= = =
3 1 2
x = 3– 3, y = , z = 1–2
P(3– 3, – 2, 1–2) will satisfy the equation of plane x + y + z = 2.
3 – 3 + – 2 + 1 – 2 = 2
2– 4 = 2
=3
P(6, 1, – 5)
Perpendicular distance of P from plane 3x – 4y + 12 z – 32 = 0 is
3(6) – 4(1) 12(–5) – 32
q=
9 16 144
q = 6.
2q = 12
Sum of roots = 6 + 12 = 18
Product of roots = 6(12) = 72
Quadratic equation having q and 2q as roots is x2 – 18x + 72.
2
Let f be a differentiable function such that x2 f(x) – x = 4 tf (t) dt , f (1)
x
13. . Then 18 f (3) is equal to :
0 3
(1) 180 (2) 150 (3) 210 (4) 160
Sol. (4)
x
x2f(x) – x = 4 tf (t)dt
0
Differentiate w.r.t. x
x2f’(x) + 2x f(x) – 1 = 4xf(x)
Let y = f(x)
dy
x2 – 2xy – 1 = 0
dx
dy 2 1
– y= 2
dx x x
–2
e x
dx 1
I.F. = =
x2
Its solution is
y 1
2
= 4 dx + C
x x
y –1
2
= +C
x 3x 3
2 2
f(1) = y(1) =
3 3
2 1
=– +C
3 3
C=1
1
y=– + x2
3x
1
f(x) = – + x2
3x
1 80
f(3) = – + 9 = 18f(3) = 160
9 9
m
14. Let N denote the sum of the numbers obtained when two dice are rolled. If the probability that 2 N < N! is ,
n
where m and n are coprime, then 4m –3n equal to :
(1) 12 (2) 8 (3) 10 (4) 6
Sol. (2)
2N < N! is satisfied for N 4
Required probability P (N 4) = 1 – P(N < 4)
N = 1 (Not possible)
N = 2 (1, 1)
1
P(N = 2) =
36
N = 3 (1, 2), (2, 1)
2
P(N = 3) =
36
1 2 3
P(N < 4) = + =
36 36 36
3 33 11 m
P(N 4) = 1 – = = =
36 36 12 n
m = 11, n = 12
4m – 3n = 4(11) – 3 (12) = 8
If I(x) esin
2
15. x
(cos x sin 2x –sinx) dx and I (0) = 1, then I is equal to :
3
3 3
1 34 1 3
(1) e 4 (2) –e 4 (3) e (4) – e 4
2 2
Sol. (3)
I = esin x sin 2x cos xdx – esin x sin xdx
2 2
II I
I (0) = 1
1=1+C
C=0
2
I= e
sin x
cos x
2
sin
3
I = e cos
3 3
3
e4
=
2
2 4 8 16
16. 96cos cos cos cos cos is equal to :
33 33 33 33 33
(1) 4 (2) 2 (3) 3 (4) 1
Sol. (3)
2 22 23 24
96 cos cos cos cos cos
33 33 33 33 33
sin(2 n A)
cos A cos 2A cos 22A …. Cos 2n–1 A = n
2 sin A
Here A = ,n=5
33
96sin 25
= 33
25 sin
33
32
96sin
= 33
32sin
33
3sin –
= 33
=3
sin
33
2z – 3i
17. Let the complex number z = x + iy be such that is purely imaginary. If x + y2 = 0, then y4 + y2 – y is
2z i
equal to :
3 2 4 3
(1) (2) (3) (4)
2 3 3 4
Sol. (4)
z = x + iy
(2z – 3i)
= purely imaginary
2z i
2z – 3i
Means Re =0
2z i
(2z – 3i) 2(x iy) – 3i
=
(2z i) 2(x iy) i
2x 2yi – 3i
=
2x i2y i
2x i(2y – 3) 2x – i(2y 1)
= ×
2x i(2y 1) 2x – i(2y 1)
2z – 3i 4x 2 (2y – 3)(2y 1)
Re = =0
2z i 4x 2 (2y 1) 2
4x2 + (2y – 3) (2y + 1) = 0
4x2 + [4y2 + 2y – 6y – 3] = 0
x + y2 = 0 x = –y2
4(–y2)2 + 4y2 – 4y – 3 = 0
4y4 + 4y2 – 4y = 3
3
y4 + y2 – y =
4
Therefore, correct answer is option (4).
f f x x
4 4
f f
x x
4
f f x f f
x
AM GM
4
x 4
x
x 2 y2
19. The slope of tangent at any point (x, y) on a curve y = y(x) is , x 0 . If y (2) = 0, then a value of y (8)
2xy
is :
(1) 4 3 (2) –4 2 (3) –2 3 (4) 2 3
Sol. (1)
dy x 2 y
=
dx 2xy
y = vx
y(2) = 0
y(8) = ?
dv dv
vx
dx dx
xdv x 2 v2 x 2
v+ =
dx 2vx 2
dv v2 1
x. = – v
dx 2v
2vdv dx
=
(1 – v )
2
x
– ln (1 – v2) = ln x + C
ln x + ln (1 – v2) = C
y2
ln x 1 – 2 = C
x
x 2 – y 2
ln = C
x
x2 – y2 = cx
y(2) = 0 at x = 2, y = 0
4 = 2C C = 2
x2 – y2 = 2x
Hence, at x = 8
64 –y2= 16
y= 48 = 4 3
y(8) = 4 3
Option (1)
20. Let the ellipse E : x2 + 9y2 = 9 intersect the positive x-and y-axes at the points A and B respectively. Let the
major axis of E be a diameter of the circle C. Let the line passing through A and B meet the circle C at the
m
point P. If the area of the triangle with vertices A, P and the origin O is , where m and n are coprime, then
n
m – n is equal to :
(1) 16 (2) 15 (3) 18 (4) 17
Sol. (4)
y
B(0,1)
A
x
(3,0)
x2 + y2 = 9
Equation of line AB or AP is
x y
1
3 1
x 3y 3
x (3 3y)
Intersection point of line AP & circle is P(x 0 , y0 )
x 2 y 2 9 (3 3y) 2 y 2 9
32 (1 y 2 2y) y 2 9
5y2 9y 0 y(5y 9) 0
y 9/5
9 4
Hence x 3(1 y) 3 1 3
5 5
12
x
5
12 9
P(x 0 , y0 ) ,
5 5
1
Area of AOP is OA height
2
Height 9 / 5 , OA 3
1 9 27 m
3
2 5 10 n
Compare both side m 27, n 10 m n 17
Therefore, correct answer is option-D
SECTION-B
21. Some couples participated in a mixed doubles badminton tournament. If the number of matches played, so
that no couple in a match, is 840, then the total numbers of persons, who participated in the tournament, is
____.
Sol. 16
Let number of couples = n
nC2 × n–2C2 × 2 = 840
n(n – 1) (n– 2) (n – 3) = 840 × 2
= 21 × 40 × 2
=7×3×8×5×2
n(n– 1) (n – 2) (n – 3) = 8 × 7 × 6 × 5
n=8
Hence, number of persons = 16.
22.
The number of elements in the set n Z :| n 2 –10n 19 | 6 is _____.
Sol. 6
– 6 < n2 – 10 n + 19 < 6
n2 – 10 n + 25 > 0 and n2– 10n + 13 < 0
(n – 5)2 > 0 5–3 2 <n<5+3 2
N Z – {5} n = {2, 3, 4, 5, 6, 7, 8}
…(i) …(ii)
From (i) (ii)
N = {2, 3, 4, 5, 6, 8,}
Number of values of n = 6
23. The number of permutations of the digits 1, 2, 3, …., 7 without repetition, which neither contain the string 153
nor the string 2467, is _____.
Sol. 4898
Numbers are 1, 2, 3, 4, 5, 6, 7
Numbers having string (154) = (154), 2, 3, 6, 7 = 5!
Numbers having string (2467) = (2467), 1,3, 5 = 4!
Number having string (154) and (2467)
= (154), (2467) = 2!
Now n (154 2467) = 5! + 4! – 2!
= 120 + 24 – 2 = 142
Again total numbers = 7! = 5040
Now required numbers = n (neither 154 nor 2467)
= 5040 – 142
= 4898
25. Let a common tangent to the curves y2 = 4x and (x – 4)2 + y2 = 16 touch the curves at the points P and Q.
Then (PQ)2 is equal to ____ :
Sol. 32
y 2 4x
(x 4) 2 y 2 16
Let equation of tangent of parabola
y mx 1/ m ..(1)
Now equation 1 also touches the circle
4m 1/ m
4
1 m2
(4m 1/ m)2 16 16m 2
16m4 8m2 1 16m2 16m4
8m2 1
m2 1/ 8 m 4
0 m
For distinet points consider only m 1/ 8 .
2
f i x i
x =
N
10 45 25x 175 130
28 =
14 x
28 × 14 + 28 x = 410 + 25 x
3x = 410 – 392
18
x= =6
3
1
Variance = fixi2 – ( x )2
N
1
= 18700 – (28)2
20
= 935 – 784 = 151
28. Let y = p(x) be the parabola passing through the points (–1, 0), (0, 1) and (1, 0). If the area of the region
(x, y) : (x 1) 2
(y– 1) 2 1, y p(x) is A, then 12(– 4A) is equal to _____:
Sol. 16
There can be infinitely many parabolas through given points.
Let parabola x2 = – 4a (y – 1)
(–1, 1) (0, 1)
(1 – x )dx
2
Now area covered by parabola =
–1
b
x3 1
= x – = (0 – 0) – –1
3 1 3
2
=
3
Required Area = Area of sector – {Area of square – Area covered by Parabola}
2
= – 1 –
4 3
1
= –
4 3
1
12 ( – 4A) = 12 – 4 –
4 3
4
= 12 –
3
= 16
Let a, b, c be three distinct positive real numbers such that 2a bc and bloge 2 a loge c . Then 6a +
loge a loge b
29.
5bc is equal to _____.
Sol. Bouns
(2a)ln a (bc)ln b 2a 0, bc 0
ln a(ln 2 ln a) ln b(ln b ln c)
ln 2 ln b ln c ln a
ln 2 ,ln a x,ln b y,ln c z
y xz
x( x) y(y z)
xz
y
xz
x x y(y z)
y
x (z y) y 2 (y z)
2
y z 0 or x 2 y 2 x y
bc 1 or ab 1
bc = 1 or ab = 1
a=1
lna
1 if bc = 1 ⇒ 2a =1
a = 1/2
1 1 1
(a, b, c) , λ, , λ 1, 2,
2 λ 2
then
6a + 5bc = 3 + 5 = 8
1 1 1
(II)(a, b, c) λ, , , λ 1, 2,
λ 2 2
So, Bonus.
30. The sum of all those terms, of the arithmetic progression 3, 8, 13, …., 373, which are not divisible by 3, is
equal to _____.
Sol. 9525
A.P : 3,8,13.....373
Tn a (n 1)d
373 3 (n 1)5
370
n
5
n 75
n
Now Sum a l
2
75
3 373 14100
2
Now numbers divisible by 3 are,
3,18,33........363
363 3 (k 1)15
360
k 1 24 k 25
15
25
Now, sum 3 363 4575 s
2
req. sum 14100 4575
9525
SECTION - A
31. The equivalent capacitance of the combination shown is
5 C
(1) 4C (2) C (3) (4) 2C
3 2
Sol. (4)
Capacitor (3) & (4) are short ckt
C1 & C2 are in parallel
Ceq. = C + C = 2C
X L X C (conductor of resonance)
Z min R V & I in same phase
35. The range of the projectile projected at an angle of 15o with horizontal is 50 m. If the projectile is projected with
same velocity at an angle of 45o with horizontal, then its range will be
(1) 100 2m (2) 50 m (3) 100 m (4) 50 2m
Sol. (3)
u 2 sin 2 15 u 2 u2
So R = So 100
g 2g g
2
u sin 2 45 u 2
R' 100 m
g g
36. A particle of mass m moving with velocity collides with a stationary particle of mass 2m. After collision,
they stick together and continue to move together with velocity
(1) (2) (3) (4)
2 3 4
Sol. (2)
pi = pf mv + 2m (0) = 3m (v')
v
v'
3
37. Two satellites of masses m and 3m revolve around the earth in circular orbits of radii r & 3 r respectively. The
ratio of orbital speeds of the satellites respectively is
(1) 3 : 1 (2) 1 : 1 (3) 3 :1 (4) 9 : 1
Sol. (3)
GM 1
v v ; M = mass of earth, r = radius of earth
r r
v1 r2 3r
3
v2 r1 r
R
38. Assuming the earth to be a sphere of uniform mass density, the weight of a body at a depth d from the
2
surface of earth, if its weight on the surface of earth is 200 N, will be :
(1) 500 N (2) 400 N (3) 100 N (4) 300 N
Sol. (3)
mg = 200 N
d R g
g ' = g 1 g 1
R 2 R 2
mg 200
weight = mg'= 100 N
2 2
39. The de Broglie wavelength of a molecule in a gas at room temperature (300 K) is 1 . If the temperature of the
gas is increased to 600 K, then the de Broglie wavelength of the same gas molecule becomes
1 1
(1) 21 (2) 1 (3) 21 (4) 1
2 2
Sol. (2)
h
3mK T
1 T2
2 T1
T1
2 1
T2
300 2
1
600 2
43. The positon-time graphs for two students A and B returning from the school to their homes are shown in figure.
44. The energy of an electromagnetic wave contained in a small volume oscillates with
(1) double the frequency of the wave
(2) the frequency of the wave
(3) zero frequency
(4) half the frequency of the wave
Sol. (1)
double the frequency of the wave
E = E0 sin (wt – kx)
1
Energy density = 0 Enet
2
1
= 0 E 0 sin2 (wt – kx)
2
2
1
= 0 E 02 (1 – cos (2wt – 2kx))
4
45. The equivalent resistance of the circuit shown below between points a and b is :
48. The angular momentum for the electron in Bohr's orbit is L. If the electron is assumed to revolve in second orbit
of hydrogen atom, them the change in angular momentum will be
L
(1) (2) zero (3) L (4) 2L
2
Sol. (3)
nh
Angular momentum =
2
h
n = 1, L1 = =L
2
2h
n = 2, L2 = = 2L
2
L= 2L – L = L
49. An object is placed at a distance of 12 cm in front of a plane mirror. The virtual and erect image is formed by
the mirror. Now the mirror is moved by 4 cm towards the stationary object. The distance by which the position
of image would be shifted, will be
(1) 4 cm towards mirror (2) 8 cm away from mirror
(3) 2 cm towards mirror (4) 8 cm towards mirror
Sol. (4)
/ / // / / / / / // / / / / // / / / / /
O I
x = –12 x=0 x = 12
4
/ / / / // / / / / / // / / / / / // / /
8 cm
O 8
8 I´ I´
4 12
8 cm towards mirror
Image will be shifted 8 cm towards mirror.
50. A zener diode of power rating 1.6 W is be used as voltage regulator. If the zener diode has a breakdown of 8 V
and it has to regulate voltage fluctuating between 3 V and 10 V. The value of resistance R8 for safe operation of
diode will be
51. Unpolarised light of intensity 32 Wm-2 passes through the combination of three polaroids such that the pass axis
of the last polaroid is perpendicular to that of the pass axis of first polaroid. If intensity of emerging light is 3
Wm-2, then the angle between pass axis of first two polaroids is _______o.
Sol. (30 & 60)
I0
cos2
I I0 2 I
2
32 I0
Inet = 3 = (sin 2)2 = cos2 sin2
8 2
3 I
Sin(2) = 2 = 60 & 120° = 0 (sin 2)2
2 8
= 30° & 60°
1
52. If the earth suddenly shrinks to th of its original volume with its mass remaining the same, the period of
64
24
rotation of earth becomes h . The value of x is _________ .
x
Sol. (16)
By AMC
2
2 2 R
MR212 = M 2
5 5 4
1 1 T T
= = 2 = 2
2 16 T1 24
24
T2 = x = 16 Ans.
16
53. Three concentric spherical metallic shells X, Y and Z of radius a, b and c respectively [a < b < c] have surface
charge densities , and , respectively. The shells X and Z are at same potential. If the radii of X & Y are
2 cm and 3 cm, respectively. The radius of shell Z is __________ cm.
Sol. (5)
qx = 4a2
qy = – 4b2
qz = 4c2
Potential of y
qx qy qz qx qy qz
=
4 0 a 4 0 b 4 0 c 4 0 c 4 0 c 4 0 c
4 a 2 4 b 2 4 c 2 (a 2 b 2 c 2 )
– = 4
a b c C
c(a – b + c) = a – b + c
2 2 2
c(a – b) + c2 = (a + b)(a – b)
c(a – b) = (a + b)(a – b)
c=a+b =2+3
c = 5 cm Ans.
55. 10 resistors each of resistance 10 can be connected in such as to get maximum and minimum equivalent
resistance. The ratio of maximum and minimum equivalent resistance will be ______.
Sol. (100)
Rmax in series 10R = 10 × 10 = 100
R 10
Rmax in parallel = = = 1
10 10
R max 100
= = 100 Ans.
R min 1
100
Rmin = 100 Ans.
1
56. The decay constant for a radioactive nuclide is 1.5 × 10-5 s-1. Atomic weight of the substance is 60 g mole-1,
(NA = 6 × 1023). The activity of 1.0 g of the substance is _________ ×1010 Bq.
Sol. (15)
1 10 –6 10 –7
No. of moles = =
60 6
–7
10
No. of atom = n(NA) = × 6 × 1023 = 1016
6
at (t = 0) A0 = No= 1016 × 1.5 × 10–5 = 15 × 1010 Bq
57. Two wires each of radius 0.2 cm and negligible mass, one made of steel and the other made of brass are loaded
as shown in the figure. The elongation of the steel wire is _______ × 10-6 m. [Young's modulus for steel = 2 ×
1011 Nm-2 and g = 10 ms-2
Sol. (20)
///////////////////
T2 1.6 (steel)
2g 1m Brass (1m)
T1
1.14
1.14 = 11.4
T2 = T1 + 20 = 20 + 11.4
T2 = 31.4
Elongation in steel wire
T L
L = 2
AY
31.4 1.6
=
(0.2 10 –2 ) 2 2 1011
= 2 × 10–5
L = 20 × 10–6 m
58. A closed circular tube of average radius 15 cm, whose inner walls are rough, is kept in vertical plane. A block
of mass 1 kg just fit inside the tube. The speed of block is 22 m/s, when it is introduced at the top of tube. After
completing five oscillations, the block stops at the bottom region of tube. The work done by the tube on the
block is ____ J. (Given : g = 10 m/s2)
Sol. (245)
Rarg = 15cm = .15 m
By WET
Wf + Wgravity = K = Kf – Ki
1
Wf + 10 × .3 = 0 – × 1 × (22)2
2
484
Wf = –3 – = 3 – 242 = – 245
2
Work by friction = – 245
By NTA (+245)
59. A 1 m long metal rod XY completes the circuit as shown in figure. The plane of the circuit is perpendicular to
the magnetic field of flux density 0.15 T. If the resistance of the circuit is 5 , the force needed to move the rod
in direction, as indicated, with a constant speed of 4 m/s will be _______ 10-3N.
Sol. (18)
e (B )B B2 2
F = IB = B = =
R R R
(•15) (1) 4
2 2
= = 180 × 10–4
5
=18 × 10–3 = 18 Ans.
60. The current required to be passed through a solenoid of 15 cm length and 60 turns in order to demagnetize a bar
magnet of magnetic intensity 2.4 × 103 Am-1 is ________A.
Sol. (6)
H = 2.4 × 103 A/m
N
H = nI = I
H 2.4 10 3 15 10 –2
I= =
N 60
I = 6A
SECTION - A
Q.61 The major product ‘P’ formed in the given reaction is
(1) (2)
(3) (4)
Sol. (1)
CH2–CH3
COOH
COOH
C H COOH
Alk kMnO4
Q.62 Prolonged heating is avoided during the preparation of ferrous ammonium sulphate to
(1) prevent hydrolysis (2) prevent reduction (3) prevent breaking (4) prevent oxidation
Sol. (4)
It may oxidise ferrous ion to ferric ions.
Q.63 Identify the correct order of reactivity for the following pairs towards the respective mechanism
(A) (B)
(C) (D)
Choose the correct answer from the options given below:
(1) (A), (C) and (D) only (2) (A), (B) and (D) only
(3) (B), (C) and (D) only (4) (A), (B), (C) and (D)
Sol. (4)
(A) SN 2 for SN 2 Reaction 1o 2o 3o
Br
Br >
Br
Br
>
So,
(C) Electrophilic Substitution reaction
1
rate
EWG
(D) Nucleophilic substitution :- rate × no. of EWG atloched at benzons
Br Br
>
NO2
Q.64 Given
(A) 2CO(g)+O2(g) 2CO2(g) H1o = –x KJ mol–1
(B) C(graphite)+O2(g) CO2(g) Ho2 = –y KJ mol–1
The Ho for the reaction
1
C(graphite)+ O2(g) CO(g) is
2
x 2y x 2y 2x y
(1) (2) (3) (4) 2y – x
2 2 2
Sol. (1)
2CO(g) O2 (g) 2CO2 (g) H1o y kJ / mol ………(1)
C(graphite) O2 (g) CO2 (g) H o2
–y k J / mol ………(2)
__________________________________________________
C(graphite) ½O2 (g) CO(g) H3o ?
H1o –x
H3o H o2 – –y –
2 2
x x 2y
H3o y
2 2
Q.65 Using column chromatography mixture of two compounds ‘A’ and ‘B’ was separated. ‘A’ eluted first, this
indicates ‘B’ has
(1) high Rf, weaker adsorption (2) high Rf, stronger adsorption
(3) low Rf, stronger adsorption (4) low Rf, weaker adsorption
Sol. (3)
More Polar the compound, the more it will adhere to the adsorbent and the smaller the distance it will travel
from baseline, and Lower its Rf value.
B has Low Rf value and strong Adsoption
distance covered by substance from base line
Rf =
total distance covered by solvent form base line
Q.66 Lime reacts exothermally with water to give ‘A’ which has low solubility in water. Aqueous solution of ‘A’ is
often used for the test of CO2. a test in which insoluble B is formed. If B is further reacted with CO2 then soluble
compound is formed. ‘A’ is
(1) Quick lime (2) Slaked lime (3) White lime (4) Lime water
Sol. (2)
CaO H 2O Ca(OH)2
A(lesssoluble)
Ca(OH)2 CO2 CaCO3 H 2O
B(insoluble)
CaCO3 H2O CO2 Ca(HCO3 )2
B So lub le
Q.69 The one that does not stabilize 2o and 3o structures of proteins is
(1) H-bonding (2) –S–S–linkage
(3) van der waals forces (4) –O–O–linkage
Sol. (4)
Fact
The main forces which stabilize the secondary and tertiary structure of proteins are
Hydrogen bonds
S – S Linkages
vanderwaals force
electrostatic force of attraction
Q.71 Given below are two reactions, involved in the commercial production of dihydrogen (H2). The two reactions
are carried out at temperature “T1” and “T2”, respectively
C(s)+H2O(g)
T1
CO(g)+H2(g)
CO(g)+H2O(g) T2
catalyst
CO2(g)+H2(g)
The temperatures T1 and T2 are correctly related as
(1) T1 = T2 (2) T1 < T2 (3) T1 > T2 (4) T1 = 100 K, T2 = 1270 K
Sol. (3)
T1 = 1270 K T2 = 673 K
T1 > T2 on the basis of data
Q.72 The enthalpy change for the adsorption process and micelle formation respectively are
(1) Hads < 0 and Hmic < 0 (2) Hads > 0 and Hmic < 0
(3) Hads < 0 and Hmic > 0 (4) Hads > 0 and Hmic > 0
Sol. (3)
Adsorption Exothermic H ads –ve
Micelle formation Endothermic H mic ve
Hads O and Hmic O
Q.73 The pair from the following pairs having both compounds with net non-zero dipole moment is
(1) cis-butene, trans-butene (2) Benzene, anisidine
(3) CH2Cl2, CHCl3 (4) 1,4-Dichlorohenzene, 1,3-Dichlorobenzene
Sol. (3)
Me
(1)
Me Me Me
≠0
=0
OCH3
NH2
(2)
=0 ≠0
(3) CH 2 Cl 2 CHCl3
0 0
Cl Cl
(4) Cl
≠0
Cl
=0
Q.74 Which of the following is used as a stabilizer during the concentration of sulphide ores?
(1) Xanthates (2) Fatty acids (3) Pine oils (4) Cresols
Sol. 4
Cresol is used as stabilizer
Q.77 The octahedral diamagnetic low spin complex among the following is
(1) [CoF6]3– (2) [CoCl6]3– (3) [Co(NH3)6]3+ (4) [NiCl4]2–
Sol. (3)
(1) Paramagnetic, High Spin & Tetrahedral
(2) Paramagnetic, High Spin & Octahedral
(3) Paramagnetic, High Spin & Octahedral
(4) Diamagnetic, Low Spin & Octahedral
[Co(NH3 )6 ]3 ,CN 6 CN = 6 (Octahedral)
NH3 SFL
Co 3 [Ar]3d 6
Q.78 Isomeric amines with molecular formula C8H11N given the following tests
Isomer (P) Can be prepared by Gabriel phthalimide synthesis
Isomer (Q) Reacts with Hinsberg’s reagent to give solid insoluble in NaOH
Isomer (R) Reacts with HONO followed by -naphthol in NaOH to given red dye.
Isomer (P), (Q) and (R) respectively are
(P) (Q) (R)
(1)
(2)
(3)
(4)
Sol. (2)
P = Can be prepased by Gabriel phthalimide synthesis it should be i-amine
Q = React with Hinsberg’s reagent and insoluble in NaOH it should be 2o–amine
R = React with HNO2 followed by B–Napthol in NaOH it give red dye it must be Aromatic Amine
+
NH2 N2
HNO2
+
OH
NaCH
(pH= 9–10)
OH
Red–Dye
Q.79 The number of molecules and moles in 2.8375 litres of O2 at STP are respectively
(1) 7.527×1022 and 0.125 mol (2) 1.505×1023 and 0.250 mol
23
(3) 7.527×10 and 0.125 mol (4) 7.527×1022 and 0.250 mol
Sol. (1)
Moles of O2 n O2
Volumeof O2
22.7
0.125moles
Molecules of O2 moles NA
= 0.125 × 6.022 × 1023
= 7.527 × 1022 molecules
Ans (1) 7.527 × 1022 and 0.125 mole
List I List II
polymer Type/Class
(A) Nylon-2-Nylon-6 (I) Thermosetting polymer
(B) Buna-N (II) Biodegradable polymer
(C) Urea-Formaldehyde resin (III) Synthetic rubber
(D) Dacron (IV) Polyester
Choose the correct answer from the options given below:
(1) (A)-(IV), (B)-(III), (C)-(I), (D)-(II)
(2) (A)-(II), (B)-(I), (C)-(IV), (D)-(III)
(3) (A)-(IV), (B)-(I), (C)-(III), (D)-(II)
(4) (A)-(II), (B)-(III), (C)-(I), (D)-(IV)
Sol. (4)
Fact Base
(A) Nylon–2–Nylon–6 It is Biodegradable polymer
CN
N N
n
It is a thermos setting polymer
(D) Dacron
O
It is a polyester.
SECTION - B
Q.81 If the degree of dissociation of aqueous solution of weak monobasic acid is determined to be 0.3, then the
observed freezing point will be_____________ % higher than the expected/theoretical freezing point. (Nearest
integer)
Sol. 30
For mono basic acid n = 2
i 1 (n 1) 1 (2 –1)0.3
i = 1.3
(Tf )obs – (Tf )cal
%increase 100
(Tf )cal
K i m – Kf m
f 100
Kf m
i 1
100 30%
1
Q.82 In the following reactions, the total number of oxygen atoms in X and Y is__________
Na2O+H2O 2X
Cl2O7+H2O 2Y
Sol. 5
Na 2O H2O 2NaOH
Cl2O7 H2O 2HClO4
1+4=5
Q.83 The sum of lone pairs present on the central atom of the interhalogen IF5 and IF7 is______
Sol. 1
IF5 = 1 lone pair
IF7 = 0 lone pair
1+0=1
Q.84 The number of bent-shaped molecule/s from the following is__________
N3 , NO2 ,I3 ,O3 ,SO2
Sol. 3
N 3– linear
NO 2– bent
I 3– linear
O 3 bent
SO2 bent
Q.85 The number of correct statement/s involving equilibria in physical from the following is__________
(1) Equilibrium is possible only in a closed system at a given temperature.
(2) Both the opposing processes occur at the same rate.
(3) When equilibrium is attained at a given temperature, the value of all its parameters
(4) For dissolution of solids in liquids, the solubility is constant at a given temperature.
Sol. 3
(A) is correct
(B) for equilibrium rf rb
(B) is correct
(C) at equilibrium the value of parameters become constant of a given temperature and not equal
⇒ (C) is incorrect
(D) for a given solid solute and a liquid solvent solubility depends upon temperature only
⇒ (D) is correct
Q.86 At constant temperature, a gas is at pressure of 940.3 mm Hg. The pressure at which its volume decreases by
40% is__________ mm Hg. (Nearest integer)
Sol. 1567
Pinitial = 940.3 mm Hg Vinitial = 100 (Assume)
Pfinal =?
PiVi = Pf Vf
940.3 × 100 = Pf × 60
Pf = 1567.16 mm of Hg
Pf = 1567
2.2V 0.70V
Q.87 4
FeO2– Fe3 Fe2
–0.45V
Feo
EoFeO2– /Fe2 is x×10–3 V. The value of x is___________
4
Sol. 1825
FeO 4 2 3e Fe3 G1
Fe3 e Fe 2 G 2
FeO 42 4e Fo 2 G 3
G3 G1 G2
(–)4E3o F (–)3 2.2 F (–)1 0.7 f
4E3o 6.6 0.7 7.3
7.3
E3o 1.825 1825 10 –3
4
Q.88 A molecule undergoes two independent first order reactions whose respective half lives are 12 min and 3 min.
If both the reactions are occurring then the time taken for the 50% consumption of the reactant is__________
min. (Nearest integer)
Sol. 2
k eff k1 k 2
n2 n2 n2
t eff t1 t2
1 1 1 1 4 5
t eff 12 3 12 12
12
teff = 2.4 2
5
Q.89 The number of incorrect statement/s about the black body from the following is_________
(1) Emit or absorb energy in the form of electromagnetic radiation.
(2) Frequency distribution of the emitted radiation depends on temperature.
(3) At a given temperature, intensity vs frequency curve passes through a maximum value.
(4) The maximum of the intensity vs frequency curve is at a higher frequency at higher temperature compared
to that at lower temperature.
Sol. 0
Q.90 In potassium ferrocyanide, there are___________ pairs of electrons in the t2g set of orbitals.
Sol. 3
K4 [Fe(CN)6 ]
Fe2 [Ar]3d 6
CN– SFL
t 2g contain 6 electron so it become 3 pairs
SECTION - A
1. If the coefficients of x and x2 in (1 + x)p (1 x)q are 4 and 5 respectively, then 2p + 3q is equal to
(1) 60 (2) 63 (3) 66 (4) 69
Sol. (2)
(1 x)p (1 x)q
p(p 1) 2
1 px x
2!
q(q 1)
1 qx x 2
2!
pq 4
p(p 1) q(q 1)
pq 5
2 2
p2 q 2 p q 2pq 10
(q 4)2 q 2 (q 4) q 2(4 q)q 10
q 2 8q 16 q 2 q 4 q 8q 2q 2 10
2q 22
q 11
p 15
2(15) 3(11)
30 33 63
2. Let A = {2, 3, 4} and B = {8, 9, 12}. Then the number of elements in the relation R= {((a1, b1), (a2,b2)) (A ×
B, A × B) : a1 divides b2 and a2 divides b1} is
(1) 18 (2) 24 (3) 12 (4) 36
Sol. (4)
a1 divides b2
Each elements has 2 choices
3 2 6
a2 divides b1
Each elements has 2 choices
3 2 6
Total = 6 × 6 = 36
3. Let time image of the point P(1,2,6) in the plane passing through the points A(1,2,0), B (1, 4, 1) and C (0, 5, 1)
be Q (, , ). Then (2 + 2 + 2) is equal to
(1) 70 (2) 76 (3) 62 (4) 65
Sol. (4)
Equation of plane A(x -1) + B(y - 2) + C(z - 0) = 0
Put (1,4,1) 2B C 0
Put (0,5,1) A 3B C 0
Sub : B A 0 A B,C 2B
1(x 1) 1(y 2) 2(z 0) 0
x y 2z 3 0
Image is (, , )pt (1,2,6)
1 2 6 2(1 2 12 3)
1 1 2 6
1 2 6
4
1 1 2
5, 6, 2 2 2 2
25 36 4 65
Let S x , : 91 tan x 9 tan x 10 and
2 2
5.
2 2
x 1
b tan 2 , then ( is equal to
xS 3 6
(1) 16 (2) 32 (3) 8 (4) 64
Sol. (2)
Let 9tan x P
2
9
P 10
P
P2 10P 9 0
(P 9)(P 1) 0
P 1,9
1,9tan 9
2 2
9tan x x
tan x 0, tan x 1
2 2
π π p
x 0, x ,
4 2 2
π π
β tan 2 (0) tan 2 tan 2
12 12
0 2 tan15
2
2(2 3) 2
2(7 4 3)
1
Than (14 8 3 14) 2 32
6
6. If the points P and Q are respectively the circumecenter and the orthocentre of a ABC, the PA + PB + PC
is equal to
(1) 2QP (2) PQ (3) 2PQ (4) PQ
Sol. (4)
PA PB PC a b c
abc
PG
3
a b c 3PG PQ
Ans. (4)
7. Let A be the point (1,2) and B be any point onthe curve x2 + y2 = 16. If the centre of the
locus of the point P, which divides the line segment AB in the ratio 3 : 2 is the point C (,) then the length of
the line segment AC is
6 5 2 5 3 5 4 5
(1) (2) (3) (4)
5 5 5 5
Sol. (3)
12cos 2
h 12cos 5h 2
5
sq & add
144 (5h 2)2 (5k 4)2
2 2
2 4 144
x y
5 5 25
2 4
Centre , (α, β )
5 5
2 2
2 4
AC 1 2
5 5
9 36 45 3 5
25 25 5 5
where f i 62. If [x] denotes the greatest integer x, then [2 + 2] is equal to
(1) 8 (2) 7 (3) 6 (4) 9
Sol. (1)
fi 62
3k 2 16k 12k 64 0
16
k 4or (rejected)
3
μ
f xi i
f i
8 12 15 13 17 16 25 156
2
62 62
2
500 156
σ2
62 62
500
σ 2 μ2
62
σ μ 8
2 2
1
9. If Sn = 4+ 11 + 21 + 34 + 50 + ....to n terms, then (S29 S9) is equal to
60
(1) 220 (2) 227 (3) 226 (4) 223
Sol. (4)
Sn 4 11 21 34 50 n terms
Difference are in A.P.
Let Tn an2 bn c
T1 a b c 4
T2 4a 2b c 11
T3 9a 3b c 21
By solving these 3 equations
3 5
a ,b ,c 0
2 2
3 5
So Tn n 2 n
2 2
Sn ΣTn
3 5
2
n 2 n
2
3 n(n 1)(2n 1) 5 (n)(n 1)
2 6 2 2
n(n 1)
[2n 1 5]
4
n(n 1) n(n 1)(n 3)
Sn (2n 6)
4 2
1 29 30 32 9 10 12
223
60 2 2
10. Eight persons are tobe transported from city A to city B in three cars different makes. If each car can accomodate
at most three persons, then the number of ways, in which they can be transported, is
(1) 1120 (2) 560 (3) 3360 (4) 1680
Sol. (4)
8!
Ways 3!
3!3!2!2!
8∣ 7 6 5 4
4
56 30
1680
5! 6! 7!
11. If A =
1 6! 7! 8! , then |adj(adj(2A))| is equal to
5!6!7!
7! 8! 9!
(1) 216 (2) 28 (3) 212 (4) 220
Sol. (1)
1 6 42
1
| A | 5!6!7!1 7 56
5!6!7!
1 8 72
R3 R3 R2
R2 R2 R1
1 8 42
| A | 0 1 14 2
0 1 16
| 2 A |4
23 | A |
4
212 | A |4 216
12. Let the number (22)2022 + (2022)22 leave the remainder when divided by 3 and when divided by 7. Then (2
+ 2) is equal to
(1) 13 (2) 20 (3) 10 (4) 5
Sol. (4)
(22)2022 (2022)22
divided byy 3
(21 1)2022 (2022)22
3k 1
(α 1)
Divided by 7
(21 1)2022 (2023 1)22
7k 1 1 ( β 2)
7k 2
So α 2 β 2 5
13. Let g(x) = f(x) + f(1-x) and fn (x) > 0, x (0,1). If g is decreasing in the interval (0, ) and increasing in the
1
interval (,1), then tan1 (2) + tan1 is equal to
5 3 3
(1) (2) (3) (4)
4 4 2
Sol. (2)
g ( x) f ( x) f (1 x)&f ( x) 0, x (0,1)
g ( x) f ( x) f (1 x) 0
f ( x) f (1 x)
x 1 x
1
x
2
g ( x) 0
1
atx
2
g ( x) f ( x) f (1 x) 0
g is concave up
1
hence α
2
1 α 1
tan 1 2α tan 1 tan 1
α α
1 1 1
tan 1 tan 2 tan 3 π
x ln x x t
ln x dx dt
e e2t dt
2t
e2t e 2t
C
2 2
2x 2x
1 x 1 e
C
2 e 2 x
α β γ δ 2
α 2β 3γ 4 4
t2
4 3 2
0
2
15. Let f be a continuous function satisying (f (x) x )dx t , t 0. Then f is equal to
3 4
2 3 3 3
(1) 2 1 (2) 1 (3) 1 (4) 2 1
16 16 16 16
Sol. (2)
t2
f (x) x dx 3 t
4
2 3
, t 0
0
f t t 2t
2 4
f t 2 2t t 4
π π 2 2π π 4
t f
2 4 2 16
π4 π3
π π 1
16 16
16. Let a dic be rolled n times. Let the probability of getting odd numbers seven times be equal to the probability
k
of getting odd numbers nine times. If the probability of getting even numbers twice is 15 , then k is equal to
2
(1) 60 (2) 30 (3) 90 (4) 15
Sol. (1)
P(odd number7times) =P(odd number9times)
7 n7 9 n 9
1 1 1 1
n
C7 C9
n
n 16
Required
16
1
P 16 C2
2
16 15 1 15
16 13
2 2 2
60
15 k 60
2
17. Let a circle of radius 4 be concentric to the ellipse 15x2 + 19y2 = 285. Then the common tangents are inclined
to the minor axis ofthe ellipse at the angle.
(1) (2) (3) (4)
6 12 3 4
Sol. (3)
x2 y 2
1
19 15
Let tang be
y mx 19m2 15
mx y 19m2 15 0
Parallel from (0, 0) = 4
19m 2 15
4
m2 1
19m2 15 16m2 16
3m2 1
1
m
3
π
θ with x-axis
6
π
Required angle .
3
and c.d 12 . The ˆi ˆj kˆ . c d -is equal to
(1) 24 (2) 42 (3) 48 (4) 44
Sol. (4)
a 2iˆ 7 ˆj kˆ
b 3iˆ 5kˆ
c iˆ ˆj 2kˆ
iˆ ˆj kˆ
d λ(a b ) λ 2 7 1
3 0 5
d λ(35iˆ 13 ˆj 21kˆ)
λ(35 13 42) 12
λ2
d 2(35iˆ 13 ˆj 21kˆ)
(iˆ ˆj kˆ)(c d )
1 1 1
1 1 2 44
70 26 42
2z 3i
19. Let S = z x iy : is a real number . Then which of the following is NOT correct ?
4z 2i
1 1 1
(1) y , , (2) (x, y) 0,
2 2 2
1
(3) x = 0 (4) y + x2 + y2
4
Sol. (2)
2 z 3i
R
4z 2i
2( x iy) 3i 2 x (2 y 3)i 4 x (4 y 2)i
4( x iy) 2i 4 x (4 y 2)i 4 x (4 y 2)i
4x(2 y 3) 2x(4 y 2) 0
1
x0 y
2
Ans. = 2
x 6 y z 8 x 5 y7 z 2 x 3 3 y z 6
20. Let the line = intersect the lines and at the points
1 2 5 4 3 1 6 3 1
A and B respectively. Then the distance of the mid-point of the line segment AB from the plane 2x 2y + z =
14 is
10 11
(1) 3 (2) (3) 4 (4)
3 3
Sol. (3)
x y 6 z 8
λ ….(1)
1 2 5
x5 y 7 z 2
μ ….(2)
4 3 1
x3 y 3 z 6
γ ….(3)
6 3 1
Intersection of (1) & (2) “A”
( λ, 2λ 6,5λ 8)&(4μ 5,3μ 7, μ 2)
λ 1, μ 1
A(1,4, 3)
Intersection (1) & (3) “B”
( λ, 2λ 6,5λ 8)&(6γ 3, 3γ 3, γ 6)
λ3
γ 1
B(3,0,7)
Mod point of A & B (2, 2, 2)
Perpendicular distance from the plane
2x 2 y z 14
2(2) 2(2) 2 14
4
4 4 1
SECTION - B
21. The sum of all the four-digit numbers that can be formed using all the digits 2, 1, 2, 3 is equal to _______.
Sol. (26664 )
2,1, 2,3
3!
1 3
2!
2 3! 6
3!
3 3
2!
Sum of digits of unit place 3 1 6 2 3 3 = 24
Required sum
24 1000 24 100 24 10 24 1
24 1111
= 26664
22. In the figure, 1 + 2 = and 3 (BE) = 4 (AB). If the area of CAB is 2 3 3 unit2, when 2 is the largest,
2 1
thenthe perimeter (in unit) of CED is equal to _______.
Sol. (6)
3BE 4AB
Ar(CAB) 2 3 3
1 2
x tan θ1 2 3 3
2
BE BD DE
x tan θ1 tan θ2
BE AB tan θ1 cot θ1
4 1
tan θ1 cot θ1 tan θ1 3,
3 3
π π
θ1 2
6 3
π π
θ1 θ2
3 6
θ2 π π
as is largest θ1 θ2
θ1 6 3
(2 3 3) 2 3(2 3) 2
x2
tan θ1 π
tan
6
x 2 12 6 3 (3 3) 2
x 3 3
Perimeter of CED
CD DE CE
3 3 (3 3) 3 (3 3) 2 6
Ans. (6)
1
23. Let the tangent at any point P on a curve passing through the points (1,1) and ,100 , intersect positive x-
10
axis and y-axis at the points A and B respectively . If PA : PB =1 : k and y = y (x) is the solution of the differential
dy
k
equation e = kx , y(0) = k, then 4y then 4y(1) 5loge3 is equal to_______.
dx
2
Sol. (5)
dy
Y y ( X x)
dx
Y 0
ydx
X x
dy
k 1 dx
x y x
k dy
x dx
x y x
k dy
dy
x ky 0
dx
dy k
y0
dx x
y xk C
C 1
k
1
100 1
10
K2
dy
ln(2x 1)
dx
(2x 1)
y (ln(2x 1) 1) c
2
1
2 (0 1) C
2
1 5
C 2
2 2
3 5
y (1) ( ln 3 1)
2 2
3
ln 3 1
2
4 y(1) 6ln3 4
4 y(1) 5ln3 4 ln3
24. Suppose a1, a2, 2, a3, a4 be in an arithemetico-geometric progression. If the common ratio of the corresponding
49
geometric progression in 2 and the sum of all 5 terms of the arithmetico-geometric progression is , then a4
2
is equal to_______.
Sol. (16)
( a 2d ) ( a d )
, , a, 2(a d ), 4(a 2d )
4 2
a2
1 1 49
1 6 2 (1 2 8)d
4 2 2
3 49
2 7 9d
4 2
49 62 98 62
9d 9
2 4 4
d 1
a4 4(a 2d )
16
25. If the area of the region {(x,y) : |x2 2| x} is A, then 6A + 16 2 is equal to _____.
Sol. (27)
x x
2 2
A x 2 x 2 dx 2
2 dx
1 2
2 2 1 1 8 2 2
1 2 2 2 2 4 1 2 2
3 2 3 3 3
4 2 7 10 8 2 9
4 2
3 6 3 3 2
6A 16 2 27 6A 16 2 27
Ans. 27
26. Let the food of perpendicular from the point A (4, 3, 1) on the plane P : x y + 2z + 3 = 0 be N. If B(5, , ),
, Z is a point on plane P such that the area of the triangle ABN is 3 2 , then 2 + 2 + is equal to
_______.
Sol. (7)
AN 6
5 α 2β 3 0
α 8 2β
N is given by
x 4 y 3 z 1 (4 3 2 3)
1 1 2 11 4
x 3, y 4,z 1
N
(3,4, 1)
BN 4 (α 4)2 ( β 1)2
4 (2 β 4)2 ( β 1)2
1
Area of ABN AN BN 3 2
2
1
6 BN 3 2
2
BN 2 3
4 (2 β 4)2 ( β 1)2 12
(2 β 4)2 ( β 1)2 8 0
5 β 2 18 β 9 0
(5 β 3)( β 3) 0
β 3
α2
α 2 β 2 αβ 9 4 6 7
27. Let S be the set of values of , for which the system of equations
6x 3y + 3z = 42,
2x + 6y + 4z = 1,
3x + 2y + 3z = has no solution. Then 12 | | is equal to _______.
lS
Sol. (24)
6 λ 3 3
Δ 2 6λ 4 0
3 2 3λ
2 λ 9 λ2 4 (3λ 6) (2 9 λ) 0
18λ3 14λ 4 0
( λ 1)(3λ 1)(3λ 2) 0
λ 1, 1 / 3, 2 / 3
6 λ 3 4 λ 2
For each values of λ,Δ1 2 6 λ 1 0
3 2 λ
1 2
12 1 24
3 3
2x
28. If the domain of the function f(x) = sec is [, ) U (, ], then |3+10(+)+21| is equal to ______.
5x 3
Sol. (24)
2x
f ( x) sec1
5x 3
2x
5x 3
2x
1 | 2 x || 5 x 3|
5x 3
(2 x)2 (5 x 3)2 0
(7 x 3)(3x 3) 0
1 3
7
3 3 3
domain 1, ,
5 5 7
3 3 3
α 1, β , γ , δ
5 5 7
3α 10( β γ) 21δ 3
6 3
3 10 21 24
5 7
29. Let the quadratic curve passing through the point (1,0) and touching the line y = x at (1,1) be y = f(x). Then
the x-intercept of the normal to the curve at the point (, + 1) in the first quadrant is _______.
Sol. (11)
f (x) (x 1)(ax b)
1 2a 2b
f (x) (ax b) a(x 1)
1 (3a b)
b 1 / 4,a 1 / 4
(x 1) 2
f (x)
4
x 1 ( 1) 2
f (x) 1 , 1
2 2 4
1 4
3
normal at (3, 4)
1
y 4 (x 3)
2
y 0 x 83
Ans. 11
30. Let the equations of two adjacent sides of a parallelogram ABCD be 2x3y =23 and 5x + 4y = 23. If the
equation of its one diagonal AC is 3x + 7y = 23 and the distance of A from the other diagonal is d, then 50 d2 is
equal to _______.
Sol. (529)
32. The ratio of intensities at two points P and Q on the screen in a Young's double slit experiment where phase
difference between two waves of same amplitude are /3 and /2, respectively are
(1) 3:2 (2) 3:1 (3) 2:3 (4) 1:3
Sol. (1)
Ires = 4Io cos2
2
If = , Ires = 4Io . cos2
3 6
2
3
= 4Io .
2
3
I1 = (4Io) = 3Io
4
If = , Ires = 4Io . cos2
2 2
2
1
= 4Io
2
1
= (4Io)
2
I2 = 2Io
I1 3
I2 2
33. The time period of a satellite, revolving above earth's surface at a height equal to R will be
(Given g = 2 m/s2, R = radius of earth)
(1) 32R (2) 4R (3) 2R (4) 8R
Sol. (1)
42 r 3
T2
GM
4 2 (2 R)3
T2
GM
2 R 3
= 48
GM
(g) (R 3 )
= 48
GR 2
GM
At surface of earth g
R2
So, GM = g. R2
Also 2 = g
T2 = 32R
T 32R
34. In a metallic conductor, under the effect of applied electric field, the free electrons of the conductor
(1) Move with the uniform velocity throughout from lower potential to higher potential
(2) Move in the curved paths from lower potential to higher potential
(3) Move in the straight line paths in the same direction
(4) Drift from higher potential to lower potential.
Sol. (2)
Electrons moves in curved path because there velocity u may make any angle with acceleration a between
time interval of two successive collisions.
35. A message signal of frequency 3kHz is used to modulate a carrier signal of frequency 1.5 MHz. The bandwidth
of the amplitude modulated wave is
(1) 6 kHz (2) 3 kHz (3) 6 MHz (4) 3 MHz
Sol. (1)
Bond width of Amplitude modulated signal (AM) = 2 × f(message signal)
= 2 × 3 KHz
= 6 KHz
36. In an experiment with vernier calipers of least count 0.1 mm, when two jaws are joined together the zero of
vernier scale lies right to the zero of the main scale and 6th division of vernier scale coincides with the main
scale division. While measuring the diameter of a spherical bob, the zero of vernier scale lies in between 3.2 cm
and 3.3 cm marks, and 4th division of vernier scale coincides with the main scale division. The diameter of bob
is measured as
(1) 3.25 cm (2) 3.22 cm (3) 3.18 cm (4) 3.26 cm
Sol. (3)
The zero error in verniel scale is = 6 × 0.1mm = 0.6 mm (+ve zero error)
Note: +ve zero error will have to be subtracted
From the reading of the object.
Now, the diameter measured with the help of Vernier scale is
Given by M.S.D + V.S.D × L.S
3.2 cm + 0.1 mm × 4
= 3.24 cm
The actual diameter is 3.24 mm – (zero error) = 3.24 – 0.6 = 3.18 cm
37. Two projectiles are projected at 30° and 60° with the horizontal the same speed. The ratio of the maximum
height attained by the two projectiles respectively is:
(1) 2 : 3 (2) 1 : 3 (3) 3 :1 (4) 1 : 3
Sol. (4)
u 2 sin 2
In projectile motion, H many
2g
u 2 sin 2 30
at = 30°, H1
2g
u 2 sin 2 60
at = 60°, H 2
2g
1
H1 sin 30 2
2 1
H 2 sin 2 60 3 2 3
2
38. Given below are two statements : one is labelled as Assertion A and then other is labelled as Reason R
Assertion A : An electric fan continues to rotate for some time after the current is switched off.
Reason R : Fan continues to rotate due to inertia of motion.
In the light of above statements, choose the most appropriate answer from the options given below.
(1) A is not correct but R is correct
(2) Both A and R are correct and R is the correct explanation of A
(3) Both A and R are correct but R is NOT the correct explanation of A
(4) A is correct but R is not correct
Sol. (2)
Inertia is the property of mass due to which the object continues to move until any external force do not stops it.
In the case of rotation of fan, if we switch off then also it moves for some time as air resistance takes time to
stop it and due to inertia of fan it moves for some time.
39. The distance between two plates of a capacitor is d and its capacitance is C1, when air is the medium between
2d
the plates. If a metal sheet of thickness and of the same area as plate is introduced between the plates, the
3
C
capacitance of the capacitor becomes C2. The ratio 2 is
C1
(1) 4 : 1 (2) 3 : 1 (3) 2 : 1 (4) 1 : 1
Sol. (2)
2d
t=
3
K = for metals
A 0 A 0 A 3 A
C1 = 0 C2 = = = 0
d t 2d d
dt d 0
k 3
3 0 A
C 3
= 2 d
C1 0 A 1
d
40. The amplitude of magnetic field in an electromagnetic wave propagating along y-axis is 6.0 × 10–7 T. The
maximum value of electric field in the electromagnetic wave is
(1) 2 × 1015 Vm–1 (2) 2 × 1014 Vm–1 (3) 6.0 × 10–7 Vm–1 (4) 180 Vm–1
Sol. (4)
In electromagnetic wave, E0 = B0 C
E0 =6×10–7×3×108 E0 Amplitude of electric field
= 18×101 B0 Amplitude of magnetic field
= 180 v C Speed of light
m
41. If each diode has a forward bias resistance of 25 in the below circuit,
42. A gas mixture consists of 2 moles of oxygen and 4 moles of neon at temperature T. Neglecting all vibrational
modes, the total internal energy of the system will be,
(1) 4RT (2) 11RT (3) 8RT (4) 16RT
Sol. (2)
5 5
Internal energy of O2 = nRT 2RT 5RT
2 2
3 3
Internal energy of Ne nRT nRT 4RT 6RT
2 2
Total energy of mixture (system) = 5RT + 6RT = 11RT
43. For a periodic motion represented by the equation y = sin t + cos t the amplitude of the motion is
(1) 0.5 (2) 1 (3) 2 (4) 2
Sol. (4)
If equation of SHM is in the form y = a sin(t) + Bcos(t)
1 1 2
2 2
Therefore, Amplitude =
44. A person travels x distance with velocity v1 and then x distance with velocity v2 in the same direction. The
average velocity of the person is v, then the relation between v, v1 and v2 will be.
1 1 1 2 1 1 v1 v 2
(1) v = v1 + v2 (2) (3) (4) v
v v1 v 2 v v1 v 2 2
Sol. (3)
x
Time taken b/w A & B t1 =
v1
x
Time between b/w B & C t 2
v2
Totaldisplacement x x 2x
Average velocity (v) =
Total time t1 t 2 x x
v1 v 2
2v1 v 2 2 1 1
(v) = or
v1 v 2 v v1 v 2
7
45. The half life of a radioactive substance is T. The time taken, for disintegrating th part of its original mass will
8
be:
(1) T (2) 2T (3) 3T (4) 8T
Sol. (3)
7 1
If th is disintegrated it means only th part is radioactive active no. of nuclears after ‘n’ half lives
8 8
No No
2n 8
2n = 8 = n = 3
So, the elapsed is 3 half lives = 3T
46. A gas is compressed adiabatically, which one of the following statement is NOT true.
(1) There is no change in the internal energy
(2) The temperature of the gas increases.
(3) The change in the internal energy is equal to the work done on the gas
(4) There is no heat supplied to the system
Sol. (1)
In Adiabatic process, Q = 0
If gas is compressed, then w (by gas) 0
Therefore by 1st law Q = u + w
0 = u + w
u = –w 0
It implies in adiabatic compression, internal energy of gas changes.
47. Given below are two statements:
Statement I : For diamagnetic substance, –1 X < 0, where X is the magnetic susceptibility.
Statement II : Diamagnetic substances when placed in an external magnetic field, tend to move from stronger
to weaker part of the field.
In the light of the above statements, choose the correct answer from the options given below
(1) Both Statement I and Statement II are false
(2) Statement I is incorrect but Statement II is true
(3) Both Statement I and Statement II are true
(4) Statement I is correct but Statement II is false
Sol. (3)
Diamagnetic substances have the property due to which they tends to move away from stronger magnetic field
to weaker magnetic field, as their magnetic susceptibility is negative.
Therefore both statements are correct.
48. Young's moduli of the material of wires A and B are in the ratio of 1:4, while its area of cross sections are in
the ratio of 1:3. If the same amount of load is applied to both the wires, the amount of elongation produced in
the wires A and B will be in the ratio of
[Assume length of wires A and B are same]
(1) 12 : 1 (2) 1 : 36 (3) 1 : 12 (4) 36 : 1
Sol. (1)
W W
Y. 1
4Y. 2
A 3A
W W
l1 = l2 =
AY 12AY
1 12
2 1
49. The variation of stopping potential (V0) as a function of the frequency () of the incident light for a metal is
shown in figure. The work function of the surface is
50. A bar magnet is released from rest along the axis of a very long vertical copper tube. After some time the magnet
will
(1) Oscillate inside the tube
(2) Move down with an acceleration greater than g
(3) Move down with almost constant speed
(4) Move down with an acceleration equal to g
Sol. (3)
According to lenz’s law, the rate of charge of flum produced by bar magnet will be approused by the conducting
loops.
SECTION – B
51. If 917 Å be the lowest wavelength of Lyman series then the lowest wavelength of Balmer series will be
_________ Å.
Sol. (3668)
52. A square loop of side 2.0 cm is placed inside a long solenoid that has 50 turns per centimeter and carries a
sinusoidally varying current of amplitude 2.5 A and angular frequency 700 rad s–1. The central axes of the loop
and solenoid coincide. The amplitude of the emf induced in the loop is x × 10–4 V. The value of x is _______ .
22
(Take, )
7
Sol. (44)
emf induced in solenoid BAWN sin(t), w = 700 rad/s
Amplitude BAWN
Area (A) = 2cm × 2 cm
= 4 cm2
= 4 × 10-4 m2
(B)solenoid = 0ni
= 4 × 10-7 × 5000 × 2.5
= 5 × 10-3
50 turns 5000
n= =
cm m
i = 2.5
Amplitude of emf = (5p × 10-3) (4 × 10-4) (700) (1)
22
=5× × 4 × 700 × 10-7 = 44 × 10-4
7
53. A rectangular parallelepiped is measured as 1 cm × 1 cm × 100 cm. If its specific resistance is 3 × 10 –7m,
then the resistance between its tow opposite rectangular faces will be __________ × 10–7 .
Sol. (3)
= 3 × 10-7 -cm
l
R = .
A
=
3 10 7 10 2 m = 3 × 10-7
100 10 4
m 2
54. A force of –P k̂ acts on the origin of the coordinate system. The torque about the point (2, –3) is P(aiˆ bj)
ˆ , The
a x
ratio of is . The value of x is -
b 2
Sol. (3)
rF
head tail
= 0 2 ˆi 0 3 ˆj
= 2iˆ 3jˆ
2iˆ 3jˆ pkˆ
= 2pjˆ 3piˆ
= p 3piˆ 2pjˆ a 3 x
b 2 2
x=3
55. A straight wire carrying a current of 14 A is bent into a semicircular arc of radius 2.2 cm as shown in the figure.
The magnetic field produced by the current at the centre (O) of the arc. is _________ × 10–4T
Sol. (2)
II i
I II
Sol. (80)
By equation of continuity
A1V1 = A2V2
(2 cm2) (4 cm/s) = (10 × 10–2 cm2) (v)
8cm 3
10 1 cm 2 (v)
s
V = 80 cm/s
57. A rectangular block of mass 5 kg attached to a horizontal spiral spring executes simple harmonic motion of
amplitude 1 m and time period 3.14 s. The maximum force exerted by spring on block is __________N.
Sol. (20)
When an object executes S.H.M, its morning acceleration is given by amax = 2A
2
Where =
T
42 A
Therefore, amax =
T2
4 3.14 3.14
(Max force) Fmax = mamax = 5 (1)
3.14 3.14
= 20 N
58. An electron revolves around an infinite cylindrical wire having uniform linear charge density 2 × 10–8 C m–1 in
circular path under the influence of attractive electrostatic field as shown in the figure. The velocity of electron
with which it is revolving is ________ × 106 m s–1. Given mass of electron = 9 × 10–31 kg
Sol. (8)
In uniform circular motion
Fc = mac
mv 2
(q)(E) =
r
2k mv
2
(e)
r r
(e)(2 k ) (1.6 10 19 ) 2 (9 109 ) (2 10 8 )
v2 =
m 9 10 31
= 1.6 × 4 × 1013
V2 = 16 × 4 × 1012 v = 8 × 106 m/s
Ans. 8
59. A point object, 'O' is placed in front of two thin symmetrical coaxial convex lenses L1 and L2 with focal length
24 cm and 9 cm respectively. The distance between two lenses is 10 cm and the object is placed 6 cm away
from lens L1 as shown in the figure. The distance between the object and the image formed by the system of
two lenses is __________ cm.
Sol. (34)
Due to lens L1
u = –6m
f = +24m
1 1 1
v u f
1 1 1 1 4
v = –8m
v 24 6 24
Due to lens L2
U = –18m
F = +9m
1 1 1
x
v u f
1 1 1
v 9 18
1 2 1
V=
v 18
V = 18m
60. If the maximum load carried by an elevator is 1400 kg (600 kg – Passengers + 800 kg - elevator), which is
moving up with a uniform speed of 3 m s–1 and the frictional force acting on it is 2000 N, then the maximum
power used by the motor is __________ kW (g = 10 m/s2)
Sol. (48)
Mole Easy
63. Match List I with List II
LIST I LIST II
A 16 g of CH4 (g) I. Weight 28 g
23
B 1 g of H2 (g) II 60.2 × 10 electrons
C 1 mole of N2 (g) III Weight 32 g
D 0.5 mol of SO2 (g) IV Occupies 11.4 L volume at STP
Choose the correct answer from the options given below:
(1) A-II, B-IV, C-I, D-III (2) A-II, B-IV, C-III, D-I
(3) A-II, B-III, C-IV, D-I (4) A-I, B-III, C-II, D-IV
Sol. 1
16g CH4 = mole = 1
e– = 60.0 × 1023
19Hz = 0.5mole = 11.4(L) STP
1 mole N2 = 2rg
0.5 mol SO2 = weights 32g.
Ca
Increases
K
In period Metallic
Character
decreases So K > Ca > Be
Metallic character decreases
GOC Medium
65. The correct order for acidity of the following hydroxyl compound is :
A. CH3OH B. (CH3 )3 COH
C. D.
E.
Mn+3 3d4
NH2
(i) Na2O2 BaSO4
H3C OH
S (i) BaCl2 (White PPt)
O
So Methionine is correct answer
S-block Medium
68. Number of water molecules in washing soda and soda ash respectively are:
(1) 1 and 0 (2) 1 and 10 (3) 10 and 0 (4) 10 and 1
Sol. 3
Washing Soda Na2CO3.10H2O
0.2
Soda Ash Na2CO3
No. of water = 10 + 0 = (10)
Metallurgy Medium
69. Gibbs energy vs T plot for the formation of oxides is given below.
(1) (2)
(3) (4)
Sol. 2
CH=CH2 ( CH2–C=C–CH2–CH–CH2 )n
n CH2 = HC–CH=CH2 +n
Hydrogen Medium
71. Given below are two statements: one is labelled as Assertion 𝐀 and the other is labelled as Reason 𝐑
Assertion A : Physical properties of isotopes of hydrogen are different.
Reason : Mass difference between isotopes of hydrogen is very large.
In the light of the above statements, choose the correct answer from the options given below:
(1) Both 𝐀 and 𝐑 are true but 𝐑 is NOT the correct explanation of 𝐀
(2) A is false but 𝐑 is true
(3) A is true but 𝐑 is false
(4) Both 𝐀 and 𝐑 are true and 𝐑 is the correct explanation of 𝐀
Sol. Correct – (4)
The Physical properties of isotope of Hydrogen are different due to Large mass difference
A. B.
C. D.
Chapter: carbonyl
Level : Med.
74. Incorrect method of preparation for alcohols from the following is:
(1) Ozonolysis of alkene.
(2) Hydroboration-oxidation of alkene.
(3) Reaction of alkyl halide with aqueous NaOH.
(4) Reaction of Ketone with RMgBr followed by hydrolysis.
Sol. 1
1) Ozonolysis of alkene–
3) R – X NaOH
R – OH NaX
{Chap – Aldehyele, ketone, SO - Med}
75. In the reaction given below:
(1) (2)
(3) (4)
Sol. 4
O
(i) LiAlH4
NH2 C NH2 – CH2
(ii) H3O+
O OH
s-block Medium
76. Given below are two statements: one is labelled as Assertion A and the other is labelled as Reason R
Assertion A : The energy required to form Mg 2 from Mg is much higher than that required to produce Mg
IE1+ IE2
2+ +
In formation of Mg IE1 + IE2 is required while in formation of Mg IE1 is required
2+
(R) Mg is small ion and carry more change than Mg
77. The major product ‘P’ formed in the given reaction is:
(1) (2)
(3) (4)
Sol. 1
Cl
CH3O CH3O
Anhy +
AcCl3
NO2 NO2
–
Cl
H
CH3O CH3O
+
NO2 NO2
78. Ferric chloride is applied to stop bleeding because -
(1) Blood absorbs FeCl3 and forms a complex.
(2) FeCl3 reacts with the constituents of blood which is a positively charged sol.
(3) Fe3 ions coagulate blood which is a negatively charged sol.
(4) Cl– ions cause coagulation of blood.
Sol. 3
3+
Fe coagulation negatively charged sol blood.
SECTION - B
Chemical bonding Medium
81. The number of molecules from the following which contain only two lone pair of electrons is________
H2O, N2 ,CO,XeF4 , NH3 , NO,CO2 ,F2
Sol. 4
lp
••
•
H • 2
H
•
• N N •• 2
•
• C O •• 2
F F
Xe 2
F F
••
NH3 1
••
• N O 3
••
82. The specific conductance of 0.0025M acetic acid is 5 10 –5 S cm –1 at a certain temperature. The dissociation
constant of acetic acid is________ 10–7 . (Nearest integer)
Consider limiting molar conductivity of CH3COOH as 400 S cm2 mol –1 .
Sol. 66
k
m 1000
C
Given k = 5 × 10–5 S cm–1
C = 0.0025 M
5 10 5 103 5 10 2
m
0.0025 2.5 10 3
20Scm2 mol 1
20 1
400 20
1 1
2 0.0025
C 20 20
Ka
1 19
20
0.0025 6
6.6 10
19 20
7
66 10
83. An aqueous solution of volume 300cm3 contains 0.63 g of protein. The osmotic pressure of the solution at 300
K is 1.29 mbar. The molar mass of the protein is _______ g mol –1
Given : R = 0.083 L bar K 1 mol –1
Sol. 40535
CRT
n
RT
V
RT
V M
RT
M
V
0.63 0.083 300
M
1.29 103 300 103
M = 40535 gm/moL
p-block Medium
84. The difference in the oxidation state of Xe between the oxidised product of Xe formed on complete hydrolysis
of XeF4 and XeF4 is ____________
Sol. 2
+4 +6
XeF4 + H2O Xe + XeO3 + O2 + HF
Difference = 6 – 4 = (2)
85. The number of endothermic process/es from the following is
A. I2 (g) 2I(g)
B. HCl(g) H(g) Cl(g)
C. H2O(l) H2O(g)
D. C(s) + O2 (g) CO2 (g)
E. Dissolution of ammonium chloride in water
Sol. 4
A Endothermic (Atomisation) B Endothermic (Atomisation)
C Endothermic (Vapourisation) D Exothermic (Combustion)
E Endothermic (Dissolution)
87.
The electron in the nth orbit of Li2 is excited to ( n + 1) orbit using the radiation of energy 1.47 × 10 –17 J (as
shown in the diagram). The value of n is___________
Given: R H 2.18 10 –18 J
Sol. 1
1 1
E R H Z2 2 2
n1 n 2
1
1.47 1017 2.18 1018 9 2
n (n 1) 2
1.47 3 1 1
2
1.96 4 n (n 1)2
So, n = 1
d-block Medium
88. For a metal ion, the calculated magnetic moment is 4.90BM. This metal ion has___________ number of
unpaired electrons.
Sol. 4
4.90BM.
n n 2
So, n 4
89. In alkaline medium, the reduction of permanganate anion involves a gain of electrons.
Sol. 3
+7 – +4
MnO4 Mn
(3)
Mean
y i
100
1 100 2
3i 2i
100 i 1
1 3 100 101 201 100 101
100 6 2
201
101 1 101 99.5
2
= 10049.50
2. The number of elements in the set S = { [0, 2] : 3cos4 – 5 cos2 – 2 sin6 + 2 = 0} is :
(1) 10 (2) 9 (3) 8 (4) 12
Sol. (2)
3cos4 5cos2 2sin 2 0
3cos4 3cos2 2cos2 2sin6 2 0
3cos4 3cos2 2sin2 2sin6 0
3cos2 cos2 1 2sin 2 sin 4 1 0
3cos2 sin 2 2sin 2 1 sin 2 cos2 1
sin 2 cos2 2 2sin 2 3 0
sin 2 cos2 2sin 2 1 0
C1 sin 2 0 3 solution; 0, ,2
2 5 2
2 2 5
2
(1) log e 5
(2) log e – 5
2
1 5 2 1 5
2 3– 5
2 2 5
2 2
(3) log e 5
2 (4) log e – 5
2
1 5 1 5
Sol. (4)
e ln e 1 e2x dx
ln 2
I x x
ln 2
Put ex t ex dx dt
ln t 1 t 2 dt
2
I
1/2
t ln t 1 t 2 1
2 2
t 2t
2
t
1/2
21
1 t 2 1 t2
dt
1 1 5
2
2ln 2 5 ln
t
2 2 1/2 1 t 2
dt
1 1 5
2ln 2 5 ln
5
2 2 2
2 5 2
ln 5
1
2
5 1 2
2
ad = bc =1 no. of (a,b,c,d) = 12 = 1
ad = bc = 2 no. of (a,b,c,d) = 22 = 4
ad = bc = 4 no. of (a,b,c,d) = 12 = 1
31 50
: P A pA
81 81
5. Let f : [2, 4] be a differentiable function such that (x loge x) f ' (x) + (loge x) f(x) + f(x) 1, x [2, 4]
1 1
with f(2) = and f(4) = . Consider the following two statements :
2 4
(A) : f(x) 1, for all x [2, 4]
1
(B) : f(x) , for all x [2, 4]
8
Then,
(1) Only statement (B) is true
(2) Only statement (A) is true
(3) Neither statement (A) nor statement (B) is true
(4) Both the statements (A) and (B) are true
Sol. (4)
x nxf ' x ln xf x f x 1, x 2,4
1 1
And f(2) = , f(4) =
2 4
dy
Now xlnx, ln 1 y 1
dx
d
y x ln x 1
dx
d
f x .x ln x 1
dx
d
x ln xf x x 0, x 2, 4
dx
The function g(x) = x ln x f(x) – x is increasing in
[2,4]
And g(2) = 2 ln 2f(2) – 2 = ln 2– 2
g(2) = 4 ln 4f(4) – 4 = ln 4 – 4
= 2(ln 2 – 2)
Now g 2 g x g 4
Ln 2 – 2 x lnx f(x) – x 2(ln 2– 2)
ln 2 2 1 2 ln 2 2 1
f x
x ln x ln x x ln x ln x
Now for x 2,4
2 n2 2 1 2 ln 2 2 1 1
1 1
x ln x nx 2ln 2 ln 2 ln 2
f x 1 for x 2, 4
ln 2 2 1 ln 2 2 1 1 1 1
x ln x ln x 4ln 4 ln 4 8 2ln 2 8
1
f x for x 2,4
8
Hence both A and B are true.
6. Let A be a 2 × 2 matrix with real entries such that A' = A + I, where a – {–1, 1}. If det (A2 – A) = 4,
then the sum of all possible values of is equal to :
5 3
(1) 0 (2) (3) 2 (4)
2 2
Sol. (2)
AT A I
A AT I
A A I I
A 2 A 1 I
A 1 2 1 I
I
A= … (1)
1
1
A … (2)
1 2
A2 A A A 1 … (3)
I
AI I I
I 1
2
AI … (4)
1
Now A2 A 4
A AI 4
1 2
4
1 2 1 2
2
1 2
2 1
2
22 3 2 0
5
1 2 R
2
2
x–7
7. The number of integral solutions x of log 7 0 is :
x 2x – 3
2
log 7 0
x 2x 3
2
7 7
Feasible region: x 0x
2 2
7
And x 1 x
2 2
7 5 3
Taking intersection: x , , ,7
2 2 2
Now loga b 0 if a > 1 and b 1
a 0,1 and b 0,1
x 7
2
7
C – I; x 1 and 1
2 2x 3
5
x ; 2x 3 x 7 0
2 2
2
2x 3 x 7 2x 3 x 7 0
3x 10 x 4 0
10
x 4,
3
5 10
Intersection: x ,
2 3
x 7
2
7
C – II: x + 0,1 and 0,1
2 2x 3
x 7
2
7
0 x 1; 1
2 2x 3
7 5
x ; x 7 2x 3
2 2
2 2
10
x , 4 ,
3
No common values of x.
Hence intersection with feasible region
5 10 3
We get x ,
2 3 2
Integral value of x are {–2, –1, 0, 1, 2, 3}
No. of integral values = 6
a a 3 = max a1 , a 2 , a 3
A is true
a a1 a 2 a 3 a 3 a 3 a 3
2 2 2 2 2 2 2
a 3 a3
2 2
a 3 a 3 3 max a1 , a 2 , a 3
3max a1 , a 2 , a 3
(2) is true
9. The number of triplets (x,y,z), where x, y, z are distinct non negative integers satisfying x + y + z = 15, is :
(1) 136 (2) 114 (3) 80 (4) 92
Sol. (2)
x + y + z = 15
Total no. solution = 1531C3 136 … (1)
Let x = y z
2x+ z = 15 z = 15 – 2t
r 0,1, 2,7 5
7 solutions
there are 21 solutions in which exactly
Two of x, y, z are equal … (2)
There is one solution in which x = y = z … (3)
Required answer = 136 – 21 – 1= 144
10. Let sets A and B have 5 elements each. Let mean of the elements in sets A and B be 5 and 8 respectively and
the variance of the elements in sets A and B be 12 and 20 respectively. A new set C of 10 elements is formed
by subtracting 3 from each element of A and adding 2 to each element of B. Then the sum of the mean and
variance of the elements of C is ______.
(1) 36 (2) 40 (3) 32 (4) 38
Sol. (4)
A a1 ,a 2 ,a 3 ,a 4 ,a 5
B b1 , b 2 , b3 , b 4 , b5
5 5
Given, ai 25, bi 40
i 1 i 1
2 2
5
5
5
5
a i2 i a b 2
i bi
i 1
i 1
12, i 1
i 1 20
5 5 5 5
5 5
a i2 185, b 2
i 420
i 1 i 1
Mean of C, C
a i 15 bi 10
10
10 50
C 6
10
10
C 2
i
C
2
2 i 1
10
a 3 b i 2
2 2
6
i 2
10
a b 6 a i 4 bi 65
2
i
2
i
36
10
185 420 150 160 65
36
10
= 32
Mean + Variance = C 2 6 32 38
1
2 2 22 4
4
2 x2
Required area = 2 dx 4
0 2
x3
2 |02 4
6
4
2 4
3
8
2
3
6
2
6
12. Let R be a rectangle given by the line x = 0, x = 2, y = 0 and y = 5. Let A (, 0) and B (0, ), [0, 2] and
[0, 5], be such that the line segment AB divides the area of the rectangle R in the ratio 4 : l. Then, the mid-
point of AB lies on a :
(1) straight line (2) parabola (3) circle (4) hyperbola
Sol. (4)
ar OPQR 4
or OAB 1
Let M be the mid-point of AB.
M h, k ,
2 2
1
10
2 4
1
2
5
10 4
2
2h 2K 4
Locus of M is xy = 1
Which is a hyperbola.
13. Let a be a non-zero vector parallel to the line of intersection of the two places described by ˆi ˆj, ˆi kˆ and
ˆi – ˆj, ˆj – kˆ . If is the angle between the vector a and the vector b 2iˆ – 2jˆ kˆ and a.b 6 , then ordered pair
,| a b | is equal to :
(1) ,6 (2) ,3 6 (3) ,3 6 (4) ,6
3 4 3 4
Sol. (4)
n1 and n 2 are normal vector to the plane ˆi ˆj, ˆi kˆ and ˆi ˆj, ˆi kˆ respectively
ˆi ˆj ˆj
n1 1 1 0 ˆi ˆj kˆ
1 0 1
ˆi ˆj ˆj
n 2 1 1 0 ˆi ˆj kˆ
1 0 1
a n2 n2
ˆi ˆj ˆj
1 1 1 2ˆj 2kˆ
1 1 1
ab 0 4 2 6
1
2jˆ 2kˆ
ab
cos
a b
6 1
cos
2 2 3 2
4
2 2
Now a.b a b a b
2 2
36 a b2 8 9 72
a b 36
2
ab 6
14. Let w1 be the point obtained by the rotation of z1 = 5 + 4i about the origin through a right angle in the
anticlockwise direction, and w2 be the point obtained by the rotation of z2 = 3 + 5i about the origin through a
right angle in the clockwise direction. Then the principal argument of w1 – w2 is equal to :
8 8 33 33
(1) – tan –1 (2) – tan –1 (3) – tan –1 (4) – tan –1
9 9 5 5
Sol. (1)
W1 zi i 5 4i i 4 5i … (i)
W1 z2 i 3 5i i 5 3i … (2)
W1 W2 9 8i
8
Principal argument = tan 1
9
15. Consider ellipse Ek : kx2 + k2y2 = 1, k = 1, 2,…., 20. Let Ck be the circle which touches the four chords joining
the end points (one on minor axis and another on major axis) of the ellipse Ek. If rk is the radius of the circle Ck
20
1
then the value of 2 is
k 1 rk
Equation of
x y
A1B2 ; 1 Kx Ky 1
1/ K 1/ K
rK r distance of (0, 0) from line A1B1
0 0 1 1
rK
KK K K2
2
20
1 20
2
K K2 2 K K2
rK k 1 rK K 1
20 20
K K2
K 1 K 1
20 21 20.21.41
2 6
= 210 + 10 × 7 × 41
= 210 + 2870
= 3080
16. If equation of the plane that contains the point (–2,3,5) and is perpendicular to each of the planes 2x + 4y + 5z
= 8 and 3x – 2y + 3z = 5 is x + y + z + 97 = 0 then + + = :
(1) 15 (2) 18 (3) 17 (4) 16
Sol. (1)
The equation of plane through (–2,3,5) is
a(x+2) + b(y – 3) + c (z – 5) = 0
it is perpendicular to 2x + 4y + 5z = 8 & 3x – 2y + 3z = 5
2a + 4b + 5c =0
3a – 2b + 3c = 0
a b c
4 5 2 5 2 4
2 3 3 3 3 2
a b c
22 9 16
Equation of plane is
22(x + 2) + 9(y – 3) –16(z – 5) = 0
22x + 9y – 16z + 97 = 0
Comparing with x y x 97 0
We get 22 9 16 15
17. An organization awarded 48 medals in event ‘A’, 25 in event ‘B’ and 18 in event ‘C’. If these medals went to
total 60 men and only five men got medals in all the three events, then, how many received medals in exactly
two of three events ?
(1) 15 (2) 9 (3) 21 (4) 10
Sol. (3)
A 48
B 25
C 18
A B C 60 [Total]
A BC 5
ABC A A B A BC
A B 48 + 25 + 18 + 5 – 60
= 36
No. of men who received exactly 2 medals
AB 3 ABC
= 36 – 15
= 21
18. Let y = y(x) be a solution curve of the differential equation. (1 – x2y2)dx = ydx + xdy. If the line x = 1
intersects the curve y = y(x) at y = 2 and the line x = 2 intersects the curve y = y(x) at y = , then a value of
is :
1 3e2 1 – 3e2 3e2 3e2
(1) (2) (3) (4)
2(3e2 1) 2(3e2 1) 2(3e2 – 1) 2(3e2 1)
Sol. (1)
1 x 2 y2 dx ydx xdy, y 1 2
y 2
d xy
dx
1 xy
2
d xy
dx 1 xy 2
1 1 xy
x ln C
2 1 xy
Put x = 1 and y = 2:
1 1 2
1 ln C
2 1 2
1
C 1 ln 3
2
Now put x = 2 :
1 1 2 1
2 ln 1 ln 3
2 1 2 2
1 1 2
1 ln 3
2 2 1 2
1 2
2 ln 3
1 2
1 2
3e 2
1 2
2
3e 2 , 3e 2
1 2
1 2 3e2 1
3e2
1 2 2 3e2 1
1 2 3e2 1
And 3e2
1 2 2 3e2 1
19. Let (, , ) be the image of the point P (2, 3, 5) in the plane 2x + y – 3z = 6. Then + + is equal to :
(1) 5 (2) 9 (3) 10 (4) 12
Sol. (3)
2 3 5 2x2 3 3 5 6
2 2 2
2 1 3 2 1 1 32
2
2 3 2 5 6
2
6 5 1
10
20. Let f(x) = [x2 – x] + |–x+[x]|, where x and [t] denotes the greatest integer less than or equal to t. Then,
f is :
(1) not continuous at x = 0 and x = 1
(2) continuous at x = 0 and x = 1
(3) continuous at x = 1, but not continuous at x = 0
(4) continuous at x = 0, but not continuous at x = 1
Sol. (3)
Here f(x) = [x(x – 1)] + {x}
f 0 1 0 1 f 1 0 0 0
f 0 0 f 1 0
f 1 1 1 0
f(x) is continuous at x = 1, discontinuous at x = 0
SECTION-B
680
1 1
21. The number of integral terms in the expansion of 32 5 4 is equal to :
Sol. (171)
The number of integral term in the expression of
3
2
5 4
1 680
is equal to
C 3 5
1 680 r 1 r
General term 680
r
2 4
680 r r
680
Cr 3 2
5 4
r
Values' s of r, where goes to integer
4
r = 0, 4, 8, 12, …… 680
680 r
All value of r are accepted for as well so
2
No of integral terms = 171.
22. The number of ordered triplets of the truth values of p, q and r such that the truth value of the statement (p
q) (p r) (q r) is True, is equal to _____:
Sol. (7)
0 1 2
23. Let A a 0 3 , where a, c . If A3 = A and the positive value of a belongs to the interval (n – 1, n],
1 c 0
where n , then n is equal to ______:
Sol. (2)
0 1 2
A a 0 3
1 c 0
3
A =A
0 1 2 0 1 2
A a 0 3 a 0 3
2
1 c 0 1 c 0
a 2 2c 3
A 3
2 a 3c 2a
ac 1 2 3c
a 2 2c 3 0 1 2
A 3
3 a 3c 2a a 0 3
ac a 2 3c 1 c 0
2ac 3 a 2 3c 2a 4 6c
A a a 3c 2a
3
3 2ac 6 3a 9c
a 2 3c ac c 2 3c 2ac 3
Given A3 = A
2ac + 3 = 0 … (1) and a + 2 + 3c = 1
a + 1 + 3c = 0
9
a + 1 0
2a
2a2 + 2a – 9 = 0
f(1) < 0, f(2) > 0
a 1, 2
n=2
2
24. For m, n > 0, let (m, n) t m (1 3t)n dt . If 11(10, 6) + 18(11, 5) = p (14)6 , then p is equal to _____:
0
Sol. (32)
2
m,n t m 1 3t dt
n
t 1 3t
2 10 6
11 10 t11 1 3t dt
2
0
II I
2
6 t
11
t11
2
11 1 3t 6 1 3t 3 18 t11 1 3t dt
5
11 11 0 0
t11 1 3t
6 2
0
211 7
6
25 14
6
32 14
6
108 107 2 1
25. Let S = S 109 2 .... 107 108 . Then the value of (16S – (25)–54) is equal to _____:
5 5 5 5
Sol. (2175)
108 107 1
S 109 2 108
5 5 5
S 09 108 2
2 108 109
5 5 5 5 5
4S 1 1 1 1
109 2 108 09
5 5 5 5 5
1
1 1 5109
109
5 1 1
5
1
109 1 109
4 5
1 1 1
109 109
4 4 5
5 1 1
s 109
4 4 4.5109
1
16S = 20×109 – 5+ 108
5
54
16S – 25 = 2180 – 5 = 2175
x2 y2
26. Let H H n : – 1, n N . Let k be the smallest even value of n such that the eccentricity of Hk is a
1 n 3 n
rational number. If l is the length of the latus rectum of Hk, then 21 l is equal to ____:
Sol. (306)
x2 y2
Hn 1
1 n 3 n
b2 3 n 2n 4
e 1 1
a 2
1 n n 1
2n 4
e
n 1
n = 48 (smallest even value for which e Q )
10
e
7
a n 1
2
b2 n 3
=49 = 51
2b 2
l =length of LR =
a
51
L = 2
7
102
1
7
21 306
27. The mean of the coefficients of x, x2, …. x7 in the binomial expansion of (2 + x)9 is _____:
Sol. 2736
Coefficient of x = 9 C1 28
Coef. x 2 9 C2 27
Coef. x 7 9 C7 22
9
C1 28 9 C2 27 9 C7 2
Mean =
7
1 2 9 9 C0 29 9 C8 21 9 C9
7
3 2 18 1
9 9
7
9152
2736
7
a 21 b 21 a17 b17
28. If a and b are the roots of the equation x2 –7x –1 = 0, then the value of is equal to _____:
a19 b19
Sol. (51)
a
x2 – 7x – 1 = 0
b
By newton's theorem
Sn 2 7Sn 1 Sn 0
S21 7S20 S19 0
S20 7S19 S18 0
S19 7S18 S17 0
S21 S17 S21 S19 7S18
S19 S19
50S19 S21 7S20
S19
S 19
51 51
S 19
29. In an examination, 5 students have been allotted their seats as per their roll numbers. The number of ways, in
which none of the students sits on the allotted seat, is ______.
Sol. (44)
Derangement of 5 students
1 1 1 1 1
D5 5!1
1! 2! 3! 4! 5!
1 1 1
120
2 6 24 120
= 60 – 20 + 5 – 1
= 40+ 4
= 44
30. Let a line l pass through the origin and be perpendicular to the lines
l :r ˆi – 11jˆ – 7kˆ ˆi 2jˆ 3kˆ , and
1
32. A coin placed on a rotating table just slips when it is placed at a distance of 1 cm from the center. If the angular
velocity of the table in halved, it will just slip when placed at a distance of ______ from the centre :
(1) 8 cm (2) 4 cm (3) 2 cm (4) 1 cm
Sol. (2)
fr = m2r
mg = m2r = const.
2r = const
12 r1 22 r2
2
(1) r2
2
2
r2 4cm
33. Three vessels of equal volume contain gases at the same temperature and pressure. The first vessel contains
neon (monoatomic), the second contains chlorine (diatomic) and third contains uranium hexafluoride
(polyatomic). Arrange these on the basis of their root mean square speed (vrms) and choose the correct answer
from the options given below :
(1) Vrms (mono) > vrms (dia) > vrms (poly) (2) Vrms (dia) < vrms (poly) < vrms (mono)
(3) Vrms (mono) < vrms (dia) < vrms (poly) (4) Vrms (mono) = vrms (dia) = vrms (poly)
Sol. (1)
RT
VRMS = ....(1)
m
2
=1+ so rmonochromic > rdiatomic > rpoly.
f
Vmono > Vdiatomic > Vpoly. Ans.(1)
34. Two radioactive elements A and B initially have same number of atoms. The half life of A is same as the average
life of B. If A and B are decay constants of A and B respectively, then choose the correct relation from the
given options.
(1) A 2 B (2) A B (3) A ln 2 B (4) A B ln 2
Sol. (4)
A B T half life
t = 0 N0 N0 ang life
TA = B given in question
ln(2) l
Now = A = B · ln(2)
A B
35.
As per the given graph, choose the correct representation for curve A and curve B.
{Where XC = reactance of pure capacitive circuit connected with A.C. source
XL = reactance of pure inductive circuit connected with A.C. source
R = impedance of pure resistive circuit connected with A.C. source.
Z = impedance of the LCR series circuit}
(1) A = XL, B = R (2) A = XL, B = Z (3) A = XC, B = R (4) A = XC, B = XL
Sol. (4)
XL = WL = 2fL
1 1
XC = =
Wc 2fc
R = const.
A XC
B XL
36. A transmitting antenna is kept on the surface of the earth. The minimum height of receiving antenna required
to receive the signal in line of sight at 4 km distance from it is x × 10-2 m. The value of x is ______.
(Let, radius of earth R = 6400 km)
(1) 125 (2) 12.5 (3) 1250 (4) 1.25
Sol. (1)
d = 2R·h
d2 = 2Rh
(4)2 = 2 × 6400 × h h d
16 1
=h= km
2 6400 800
1000 5
h= = m
800 4
5
x × 10–2 =
4
500
x= = 125 Ans. Option (1)
4
37. The logic performed by the circuit shown in figure is equivalent to :
a
a
(a b)
b
b
38. The electric field in an electromagnetic wave is given as
x
E 20sin t j NC 1
c
where and c are angular frequency and velocity of electromagnetic wave respectively. the energy contained
in a volume of 5 × 10-4 m3 will be (Given 0 8.85 10 12 c 2 / Nm 2 )
(1) 88.5 × 10-13 J (2) 17.7 × 10-13 J (3) 8.85 × 10-13 J (4) 28.5 ×10-13 J
Sol. (3)
x
E = 20 sin w t
c
Eo 2o
1
Energy density = o E o2
2
1
= × 8.85 × 10–12 × 400
2
= 200 × 8.85 × 10–12 × 5 × 10–4
= 8.85 × 10–12 × 10–4 × 1000
Energy = 8.85× 10–13 J option (1)
39. Two identical heater filaments are connected first in parallel and then in series. At the same applied voltage, the
ratio of heat produced in same time for parallel to series will be :
(1) 1 : 2 (2) 4 : 1 (3) 1 : 4 (4) 2 : 1
Sol. (2)
V2 2V 2
H1 = t= ........... (1)
R / 2 R
R R
V2
H2 = t ........... (2)
2R
V
H1 2V 2 t 2R 4
= × 2 =
H2 R V t 1
40. A parallel plate capacitor of capacitance 2 F is charged to a potential V, The energy stored in the capacitor is
E1. The capacitor is now connected to another uncharged identical capacitor in parallel combination. The energy
stored in the combination is E2. The ratio E2/E1 is :
(1) 2 : 3 (2) 1 : 2 (3) 1 : 4 (4) 2 : 1
Sol. (4)
+ –
C = 2F C
1
E1 = CV2 ....... (1)
2
Now
VC
+ –
+ –
C
C
+ –
VC
C1V1 C 2 V2
VC =
C1 C 2
CV O V
VC = =
2C 2
V2
E2 = CVC 2 = C· ........ (2)
4
CV 2
4 2
=
E2
= option (4)
E1 CV 2 1
2
41. An average force of 125 N is applied on a machine gun firing bullets each of mass 10 g at the speed of 250 m/s
to keep it in position. The number of bullets fired per second by the machine gun is :
(1) 25 (2) 5 (3) 100 (4) 50
Sol. (4)
F = 125N
dp
F= n No. of bullets
dt
d(nmv) dn
F= = mv
dt dt
10n dn
125 = × 250 ×
1000 dt
125 1000 dn
=
2500 dt
dn
= 50 option (4)
dt
42. The variation of kinetic energy (KE) of a particle executing simple harmonic motion with the displacement (x)
starting from mean position to extreme position (A) is given by
(1) (2)
(3) (4)
Sol. (1)
K·E =T·E–P·E
1 1
K · E = KA2 – Kx2
2 2
Graph b/w K · E and x will be parabola
Option (1)
43. From the v – t graph shown, the ratio of distance to displacement in 25 s of motion is :
3 1 5
(1) (2) (3) (4) 1
5 2 3
Sol. (3)
Displacement = Area of graph with sign
1 1 1 1
Displacement = 10 5 + (10×5) + 5 30 + 5 20 – (5)(20)
2 2 2 2
= 25 + 50 + 75 + 50 – 50
= 150 m
Distance Area of graph with positive value
Distance = 25 + 50 + 75 + 50 = 250
Dis tan ce 250 5
= = option (3)
Displacement 150 3
44. On a temperature scale 'X', the boiling point of water is 65o X and the freezing point is-15o X. Assume that the
X scale is linear. The equivalent temperature corresponding to -95o X on the Farenheit scale would be :
(1) -63o F (2) -148o F (3) -48o F (4) -112o F
Sol. (3)
XT – XL T – 32
= F
XH – XL 212 – 32
–95º –(–15º ) TF – 32
=
65º –(–15º ) 180
–80º TF – 32
=
80º 180º
–180 = TF – 32
TF = – 180 + 32 = –148º F Ans. option (2)
45. The free space inside a current carrying toroid is filled with a material of susceptibility 2 × 10-2. The percentage
increase in the value of magnetic field inside the toroid will be
(1) 0.2% (2) 1% (3) 2% (4) 0.1%
Sol. (3)
X = 2 × 10–2
r = 1 + x = 1 + 0.02 = 1.02
Bo magnetic field due to magnetic material
Bm magnetic field due to magnetic material
Bm = rB0
B – B0 B – B0
B = m × 100 = r 0 × 100
B0 B0
(X 1) – 1
B% = × 100 = X × 100
1
B% = 2×10–2 × 100 = 2% Ans. Option (3)
46. The critical angle for a denser-rarer interface is 45o. The speed of light in rarer medium is 3 × 108 m/s. The
speed of light in the denser medium is :
(1) 2.12 × 108 m/s (2) 5 × 107 m/s (3) 3.12 × 107 m/s (4) 2 108 m / s
Sol. (1)
Sin ic = r sin 45º = r
d d
r = 2 ...........(1)
d
We know
1 V
V d r
Vr d
Vd 1
=
3 10 8
2
3
Vd = 108 = 3 × 0.7 × 108
2
Vd = 2.12 × 108 m/sec Ans. Option (1)
48. The current sensitivity of moving coil galvanometer is increased by 25%.This increase is achieved only by
changing in the number of turns of coils and area of cross section of the wire while keeping the resistance of
galvanometer coil constant. The percentage change in the voltage sensitivity will be :
(1) +25% (2) -25% (3) -50% (4) Zero
Sol. (1)
= mB A = area of coil
K = IANB B = magnetic field
ANB
= Currect senstivity
I K
1.25 ........... (1)
I 2 I 1
AN 2 B AN1B
1.25 =
K K
N 5
1.25 = 1 = ...... (2)
N2 4
R= = const.
a
=a
Current sensitivity
Voltage sensitivity = = =
V IR R
R = constant
Voltage sensitivity current sensitivity Ans. option (A)
49. A metallic surface is illuminated with radiation of wavelength , the stopping potential is Vo. If the same
V
surface is illuminated with radiation of wavelength 2 , the stopping potential becomes 0 . The threshold
4
wavelength for this metallic surface will be
3
(1) (2) 4 (3) 3 (4)
2 4
Sol. (3)
E = K.E + 0
Now
hc
= ev0 + 0 ....... (1)
hc eV0
And = + 0 ........ (2)
2 4
(2) × 4 .......... (1)
2hc hc
– = 0 + (4 0 – 0)
hc
= 30
hc hc
=3
0
0 = 3
50. 1 kg of water at 100oC is converted into steam at 100oC by boiling at atmospheric pressure. The volume of water
changes from 1.00 × 10-3 m3 as a liquid to 1.671 m3 as steam. The change in internal energy of the system during
the process will be
(Given latent heat of vaporisation = 2257 kJ/kg, Atmospheric pressure = 1 × 105 Pa)
(1) + 2476 kJ (2) -2426 kJ (3) -2090 kJ (4) +2090 kJ
V1 V2
Sol. (4)
Water Steam
1kg 100°C
100°C
Change in volume at constant pressure and temp
V = V2 – V1 = 1.671 – 0.001
V = 1.67 m3 ...... (1)
Q = U + w
mLv = U + (1.013 × 105) (1.67)
U = (2257 – 170)103
U = 2090 kJ (approx.) Ans. Option 4
51. The radius of curvature of each surface of a convex lens having refractive index 1.8 is 20 cm. The lens is now
immersed in a liquid of refractive index 1.5. The ratio of power of lens in air to its power in the liquid will be
x : 1. The value of x is _________
Sol. (4)
R = 20cm
1 1 1
= 1
f m R R air = 1.8
2 1.8 1.8
P1 = 1
R 1
2 1.6
P1 = (0.8) = .... (1)
R R
Now,
2 1.8
P2 = 1
R 1.5
2 0.3 2 1 2
P2 = = = Liquid Liquid
R 1.5 R 5 5R
1.6
Pair P1 R 4
= = = Ans. 4
Pliquid P2 0.4 1
R
52. The magnetic field B crossing normally a square metallic plate of area 4 m2 is changing with time as shown in
figure. The magnitude of induced emf in the plate during t = 2s to t = 4s, is __________ mV.
Sol. (8)
d
emf =
dt
dBA AdB
Emf = =
dt dt
Emf = 4 · Slope of B.t curve
8 – 4
=4· =4×2
4 – 2
Emf = 8 Volt
53. The length of a wire becomes l1 and l2 when 100 N and 120 N tensions are applied respectively. If 10 l2 = 11 l1,
1
the natural length of wire will be l1 . Here the value of x is _______ .
x
Sol. (2)
F = kx
yA 0 = natural length
F= ·x .
0
Sol when F = 100 N
100 = k(1 – 0) ..... (1)
When F = 120N
120 = K ((1 – 0)
Given that 102 = 111
2 = 1.1 1
So 120 = K(1.11 – 0) .... (2)
Now (2)\(1)
120 K(1.1 1 – 0 )
=
100 K( 1 0 )
1.1 1 – 0
1.2 =
1 0
1.21 – 1.20 = 1.11 – 0
0.11 = 0.20
0 = 1
So x = 2 Ans.
2
54. A monochromatic light is incident on a hydrogen sample in ground state. Hydrogen atoms absorb a fraction of
light and subsequently emit radiation of six different wavelengths. The frequency of incident light is x × 10 15
Hz. The value of x is _______.
(Given h = 4.25 × 10–15 eVs)
Sol. (3)
n=4
n=3
n=2
n=1
Total emission lines = 6 (given)
So electron absorbed energy and jump from n = 1 to n = 4
1
E 13.6 – ev
2
42
1
= 13.6 1– ev
16
E = hf
12.75 = 4.5 × 10–15,
12.75
f= × 1015 = 3×1015 Hz
4.25
x = 3 Ans.
55. A force F (2 3x)iˆ acts on a particle in the x direction where F is in newton and x is in meter. The work done
by this force during a displacement from x = 0 to x = 4 m, is ______ J.
Sol. (32)
F = (2 + 3x)i
4 4
w= 0 F.dx = 0 (2 3x).dx
4
3x 2
w = 2x = (8 + 24)
2
w = 32J
56. As shown in the figure, a configuration of two equal point charges (q0 = + 2 C) is placed on an inclined plane.
Mass of each point charge is 20 g. Assume that there is no friction between charge and plane. For the system of
two point charges to be in equilibrium (at rest) the height h = x × 10-3 m. The value of x is _________.
1
(Take 9 109 N m 2 C 2 ,g 10ms 2 )
4 0
Sol. (300)
Point charge on equilibrium is at rest.
So Fe = mg sin
kq 0 ·q 0
= mg sin 30°
r2
kq 02 mg
2
=
h 2
q0
•
Fe
sin 30
9 109 (2 10 –6 ) 2 20 10 –3 10 mg Mg sin
=
4h 2 2 r
9 4 109 10 –12 h
= 10–1
•q
4h 2 30° 0
2 –2
h = 9×10
h = 0.3 m = 300 × 10–3 m
x = 300 Ans.
57. A solid sphere of mass 500 g and radius 5 cm is rotated about one of its diameter with angular speed of 10 rad
s-1. If the moment of inertia of the sphere about its tangent is x × 10 -2 times its angular momentum about the
diameter. Then the value of x will be ____________ .
Sol. (35)
2
I1 = mR2
5
2 7
I2 = mR2 + mR2 = mR2
5 5
Angular moment about diameter is
2
Lcom = I1w = mR2w
5
Now,
7
mR 2
I2 7
5 = w
L com 2 mR 2 w 2
5
I2 7 7
L com 2 10 20
7
Now = x × 10–2
20
7
x= × 100
20
x = 35 Ans.
58. The equation of wave is given by Y = 10-2 sin 2 (160t – 0.5x + /4)
where x and Y are in m and t in s. The speed of the wave is _________ km h-1.
Sol. (1152)
Y = 10–2 sin 2 (160t – 0.5x + /4)
w 160 18
Speed of wave = = = 320 m/sec = 320 × = 1152 km/h Ans.
k 0.5 5
x
59. In the circuit diagram shown in figure given below, the current flowing through resistance 3 is A.
3
The value of x is _________
Sol. (1)
3.6
Req. = 0.5 + 1 + 4.5 +
9
Req. = 6 + 2 = 8
4v 8v 1
84 1 I
I= = A = 0.5A
8 2
1 1 0.5
I1 : I2 = :
3 6 3
I1 : I2 = 2 : 1 I1
and I1 + I2 = 0.5 A
2 1
I1 = × 0.5 = A 4.5
3 3 I2 6
1 x
So = x=1
3 3
60. A projectile fired at 30o to the ground is observed to be at same height at time 3s and 5s after projection, during
its flight. The speed of projection of the projectile is ________ ms-1.
(Given g = 10 ms–2)
Sol. (80)
Time of flight = 5 + 3 = 8 sec.
t=3
t = 5 sec
30º
t=0
2u sin
Now, T=
g
2u·sin 30
8=
10
u = 80 m/sec Ans.
SECTION - A
61. Which of the following complex has a possibility to exist as meridional isomer?
(1) [Co(en)2Cl2] (2) [Pt(NH3)2Cl2]
(3) [Co(en)3] (4) [Co(NH3)3(NO2)3]
Sol. 4
[MA3B3] type of compound exists as facial and meridional isomer.
62. L-isomer of tetrose X (C4H8O4) gives positive schiff’s test and has two chiral carbons. On acetylation. ‘X’ yields
triacetate. ‘X’ undergoes following reactions
'A'
HNO3
'X '
NaBH 4
'B'
Chiralcompound
‘X’ is
(1) (2)
(3) (4)
Sol. 4
Optically active
(x) gives positive schiff's test due –CHO group
(x) is L-tetrose.
63. Match list I with list II:
List I List II
A. K I. Thermonuclear ractions
B. KCl II. Fertilizer
C. KOH III. Sodium potassium pump
D. Li IV. Absorbent of CO2
Choose the correct answer from the options given below:
(1) A-III, B-IV, C-II, D-I (2) A-IV, B-III, C-I, D-II
(3) A-III, B-II, C-IV, D-I (4) A-IV, B-I, C-III, D-II
Sol. 3
K+ –Sodium- Potassium Pump
KCl – Fertiliser
KOH – absorber of CO2
Li – used in thermonuclear reactions
64. For compound having the formula GaAlCl4, the correct option form the following is
(1) Cl forms bond with both Al and Ga in GaAlCl4
(2) Ga is coordinated with Cl in GaAlCl4
(3) Ga is more electronegative than Al and is present as a cationic part of the salt
(4) Oxidation state of Ga in the salt GaAlCl4 is +3
Sol. 3
Gallous tetrachloro aluminate Ga AlCl4–
190
2Ga Ga Cl4– 2Al2Cl6 4Ga AlCl4–
Structure of Ga AlCl4–
According to the observation, A is more mobile and interacts with the mobile phase more than C, and C is more
drawn to the mobile phase than B.
Hence, the correct order of elution in the silica gel column chromatography is - B < C <A
66. When a solution of mixture having two inorganic salts was treated with freshly prepared ferrous sulphate in
acidic medium, a dark brown ring was formed whereas on treatment with neutral FeCl3. it gave deep red colour
which disappeared on boiling and a brown red ppt was formed. The mixture contains
2– – 2– 2–
(1) C2O4 & NO3 (2) SO3 & C2O4
– – 2– –
(3) CH3COO & NO3 (4) SO3 & CH3COO
Sol. 3
CH3COO– + FeCl3 Fe(CH3COO)3 or [Fe3 (OH)2 (CH3COO)6]+
Blood red colour
Fe(OH)2 (CH3COO)
Red-brown precipitate
2NO3– + 4H2SO4 + 6Fe2+ 6Fe3+ + 2NO + 4SO42– + 4H2O
[Fe(H2O)6]2+ + NO [Fe(H2O)5 (NO)]2+ + H2O
Brown
67. The polymer X-consists of linear molecules and is closely packed. It prepared in the presence of
triethylaluminium and titranium tetrachloride under low pressure. The polymer X is-
(1) Polyacrylonitrile (2) Polytetrafluoroethane
(3) High density polythene (4) Low density polythene
Sol. 3
Ethene undergoes addition polymerisation to high density polythene in the presence of catalyst such as AlEt 3
and TiCl4 (Ziegler – Natta catalyst) at a temperature of 333 K to 343 K and under a pressure of 6–7 atmosphere.
68. Match list I with list II
List I Species List II Geometry/ Shape
+
A. H3O I. Tetrahedral
B. Acetylide anion II. Linera
+
C. NH4 III. Pyramidal
–
D. ClO2 IV. Bent
Choose correct answer from the options given below:
(1) A-III, B-IV, C-I, D-II (2) A-III, B-IV, C-II, D-I
(3) A-III, B-I, C-II, D-IV (4) A-III, B-II, C-I, D-IV
Sol. 4
Molecule/Ion Hybridisation Shape
69. Given below are two statement :
Statement I : Methane and steam passed over a heated Ni catalyst produces hydrogen gas
Statement II : Sodium nitrite reacts with NH4Cl to give H2O, N2 and NaCl
In the light of the above statements, choose the most appropriate answer from the options given below:
(1) Both the statement I and II are incorrect
(2) Statement I is incorrect but statement II is correct
(3) Statement I is correct but statement II is incorrect
(4) Both the statements I and II are correct
Sol. 4
CH4 (g) H2 O(g) Ni
1270K
CO(g) 3H2 (g)
Steam
70. The set which does not have ambidentate ligand (s) is
2– – – 4– – 2–
(1) C2O4 , NO2 , NCS (2) EDTA , NCS , C2O4
– 2– 4– 2–
(3) NO2 , C2O4 , EDTA (4) C2O4 , ethylene diamine, H2O
Sol. 4
NO2– NCS– are ambidentate ligand
71. Arrange the following compounds in increasing order of rate of aromatic electrophilic substitution reaction
Correct order
c<a<b<d
72.
Find out the correct statement from the options given below for the above 2 reactions.
st nd
(1) Reaction (I) is of 1 order and reaction (II) is of 2 order
nd
(2) Reaction (I) and (II) both are 2 order
st
(3) Reaction (I) and (II) both are 1 order
nd st
(4) Reaction (I) is of 2 order and reaction (II) is of 1 order
Sol. 1
(1) (2)
(3) (4)
Sol. 3
o-Phenylenediamine
74. For elements B, C, N, Li, Be, O and F, the correct order of first ionization enthalpy is
(1) B>Li>Be>C>N>O>F (2) Li<Be<B<C<N<O<F
(3) Li<Be<B<C<O<N<F (4) Li<B<Be<C<O<N<F
Sol. 4
First I.E.
F > N > O > C > Be > B > Li
Li – 520 kJ/mol
Be – 899 kJ/mol
B – 801 kJ/mol
C – 1086 kJ/mol
N – 1402 kJ/mol
O – 1314 kJ/mol
F – 1681 kJ/mol
75. In the extraction process of copper, the product obtained after carrying out the reactions
(i) 2Cu2S+3O2 2Cu2O+2SO2
(ii) 2Cu2O+Cu2S 6Cu+SO2 is called
(1) Reduced copper (2) Blister copper
(3) Copper matte (4) Copper scrap
Sol. 2
2Cu2S + 3O2 2Cu2O + 3SO2
2Cu2O + Cu2S 6Cu + SO2
Blister copper
Due to evolution of SO2, the solidified copper formed has a blistered look and is referred to as blister copper.
76. 25 mL of silver nitrate solution (1M) is added dropwise to 25 mL of potassium iodide (1.05 M) solution. The
ion(s) present in very small quantity in the solution is/are
– + – + –
(1) NO3 only (2) Ag and I both (3) K only (4) I only
Sol. 2
On adding AgNO3 into KI, AgI will form and solubility of AgI is very low.
+ –
So, [Ag ] and [I ] will be present in very small quantity.
78.
(1)
(2)
(3)
(4)
Sol. 3
79. Given below are two statements : one is labelled as Assertion A and the other is labelled as Reason R:
Assertion A : In the photoelectric effect electrons are ejected from the metal surface as soon as the beam of light
of frequency greater than threshold frequency strikes the surface.
Reason R : When the photon of any energy strikes an electron in the atom transfer of energy from the photon to
the electron takes place.
In the light of the above statements, choose the most appropriate answer from the options given below:
(1) A is correct but R is not correct
(2) A is not correct but R is correct
(3) Both A and R correct and R is the correct explanation of A
(4) Both A and R are correct but R is NOT the correct explanation of A
Sol. 1
Assertion A is correct but Reason is not correct.
SECTION - B
81. Solid fuel used in rocket is a mixture of Fe2O3 and Al (in ratio 1 : 2) the heat evolved (KJ) per gram of the
mixture is _______ (Nearest integer)
–1
Givne Hf (Al2O3) = –1700 KJ mol
–1
Hf (Fe2O3) = –840 KJ mol
Sol. 4
Fe2O3 + 2Al Al2O3 + 2Fe
Hr = (Hf) Al2O3 – Hf°(Fe2O3)
= –1700 – (–840)
= –860 kJ
Fe2O3 & Al 1 : 2
Fe2O3 = 1 mole = (2 × 25 + 48)
= 112 + 48 = 160 gm
Al = 2 mole = 2 × 27 = 54 gm
Total mass = 160 + 54 = 214 gm
–860
Heat evolved per gm = kJ = –4.01 4 kJ
214
84.
The number of hyperconjugation structures involved to stabilize carbocation formed in the above reaction
is______
Sol. 7
85. A mixture of 1 mole of H2O and 1 mole of CO is taken in a 10 litre container and heated to 725 K. At equilibrium
40% of water by mass reacts with carbon monoxide according to the equation : CO(g)+H 2O(g)
2
CO2(g)+H2(g). The equilibrium constant Kc×10 for the reaction is_________ (Nearest integer)
Sol. 44
CO(g) + H2O(g) CO2(g) + H2(g)
1mole 1mole
At equilibrium 1–0.4 1–0.4 0.4 0.4
0.4 0.4 4
Kc
0.6 0.6 9
4 400
K c 102 100 44.44 44
9 9
–1
86. An atomic substance A of molar mass 12 g mol has a cubic crystal structure with edge length of 300 pm. The
no. of atoms present in one unit cell of A is ________ (Nearest integer)
–1 23 –1
Given the density of A is 3.0 g mL and NA = 6.02×10 mol
Sol. 4
Z
M
NA
d
a3
Z 12
3
6.02 10 23
(300 10–10 )3
3 6.02 27 106 10 –30 1023
Z
12
–1
= 40.635 × 10 = 4.0635 4
87.
x = 2 mole
x 2
2
y 1
90. A solution of sugar is obtained by mixing 200g of its 25% solution and 500g of its 40% solution (both by mass).
The mass percentage of the resulting sugar solution is_______(Nearest integer)
Sol. 36
25
Solution (I) Mass of sugar = 200 × = 50 gm
100
Mass of solution = 200 gm
Solution (II) Mass of solution = 500 gm
40
Mass of sugar = 500 = 200 gm
100
Total mass of sugar
Final % w/w = 100
Total mass of solution
50 200 250
= 100
200 500 7
= 35.71% 36
SECTION - A
1. The angle of elevation of the top P of a tower from the feet of one person standing due South of the tower is 45°
and from the feet of another person standing due west of the tower is 30°. If the height of the tower is 5 meters,
then the distance ( in meters) between the two persons is equal to
5
(1) 10 (2) 5 5 (3) 5 (4) 5
2
Sol. (1)
B
5m
A
30
Q 45°
P
Tower AB = 5 m
APB = 45°
PAB = 90°
B
45°
A
P
AB
tan 45° =
AP
AB
1=
AP
AP 5m
B
30°
A
Q
AB
tan 30° =
AQ
1 5
1 3 AQ
AQ 5 3
2
PQ2 = 52 + 5 3
PQ2 = 25 + 75 = 100
PQ 10cm
Option (A) 10 cm correct.
2. Let a, b, c and d be positive real numbers such that a + b + c + d = 11. If the maximum value of a 5 b3c2 d is
3750, then the value of is
(1) 55 (2) 108 (3) 90 (4) 110
Sol. (3)
Given a + b + c + d = 11 (a, b, c, d > 0}
5 3 2
(a b c d)max. = ?
Let assume Numbers –
a a a a a b b b c c
, , , , , , , , , ,
5 5 5 5 5 3 3 3 2 2
We know A.M. G.M.
a a a a a b b b c c
d 5 3 2 11
1
5 5 5 5 5 3 3 3 2 2 a b c d
5 3 2
11 5 .3 .2 .1
1
11 a 5 b3c 2 d 11
11 55.33.22.1
a5.b3.c2.d55.33.22,
max(a5b3c2d) = 55.33.22 = 337500
= 90 3750 = 3750
90
Option (C) 90 correct
2 4
3. If f : R R be a continuous function satisfying f sin 2x sin xdx f cos 2x cos xdx 0 , then the value
0 0
of is
(1) – 3 (2) 3 (3) – 2 (4) 2
Sol. (3)
F:RR
2 4
F sin 2x sindx F cos 2x .cos xdx 0
0 0
4 2 4
F sin 2x sin xdx F sin 2x .sin xdx F cos 2x .cos xdx 0
0 0
4
a a
Let x = t
4
4 4 4
F cos 2 x
4
2 cos x dx 0
0
F cos 2x cos x dx 0
4
2
0
in interval 0, F cos 2x & cos x is NOT Zero.
4
2 0
2
x 1, x 0 x 1, x 0
4. Let f and g be two functions defined by f x and g x
x 1, x 0 1, x0
Then (gof ) (x) is
(1) continuous everywhere but not differentiable at x = 1
(2) continuous everywhere but not differentiable exactly at one point
(3) differentiable everywhere
(4) not continuous at x = –1
Sol. (2)
x 1, x 0
f x 1 x,0 x 1
x 1,1 x
x 1, x 0
gx
1, x 0
x 2, x 1
g f x
1, x 1
g(f (x)) is continuous everywhere
g(f (x)) is not differentiable at x = – 1
Differentiable everywhere else
5. If the radius of the largest circle with centre (2, 0) inscribed in the ellipse x 2 + 4y2 = 36 is r, then 12r2 is equal
to
(1) 69 (2) 72 (3) 115 (4) 92
Sol. (4)
C(2,0)
Ellipse x2 + 4y2 = 36
x 2 y2
1
36 9
Equation of Normal at P(6cos, 3sin) is (6sec)x – (3cosec)y = 27
It passes through (2,0)
27 9
sec =
12 4
4 65
cos , sin =
9 9
8 65
P ,
3 3
8 65
P , c 2,0
3 3
2
65
2
8 69
2
3 3 3
2
69
Value of 12
2
12
3
12 69
92
9
6. Let the mean of 6 observations 1, 2, 4, 5 x and y 5 and their variance be 10. Then their mean deviation about
the mean is equal to
7 10 8
(1) (2) (3) (4) 3
3 3 3
Sol. (3)
Mean of 1, 2, 4, 5, x, y is 5
and variance is 10
12 x y
mean 5
6
12 + x + y = 30
x + y = 18
x 2 y 2 46 2
and by variance 5 10
6
x2 + y2 = 164
x = 8 y = 10
xx
mean daviation =
6
4 3 1 0 3 5 16 8
6 6 3
7. Let A = {1, 3, 4, 6, 9} and B = {2, 4, 5, 8, 10}. Let R be a relation defined on A×B such that R ={((a1, b1), (a2,b2
)): a1 b2 and b1 a 2 }. Then the number of elements in the set R is
(1) 52 (2) 160 (3) 26 (4) 180
Sol. (2)
Let a1 =1 5 choices of b2
a1= 3 4 choices of b2
a1 = 4 4 choices of b2
a1= 6 2 choices of b2
a1 = 9 1 choices of b2
For (a1, b2) 16 ways .
Similarly, b1 = 2 4 choices of a2
b1 = 4 3 choices of a2
b1 = 5 2 choices of a2
b1 = 8 1 choices of a2
Required elements in R = 160
8. Let P be the plane passing through the points (5, 3, 0), (13, 3, –2) and (1, 6, 2). For N, if the distances of the
points A(3, 4, ) and B(2, , a) from the plane P are 2 and 3 respectively, then the positive value of a is
(1) 5 (2) 6 (3) 4 (4) 3
Sol. (3)
i j kˆ
8 0 2 i 6 8j 24kˆ
4 3 2
4 4! + 3! 1 + 0 + 0 + 0
96 + 6 = 102
Ran k THAMS = 102 + 1 = 103
10. If four distinct points with position vectors a, b,c and d are coplanar, then abc is equal to
Sol. (1)
a, b,c,d coplanar
a b c ?
b a c b, d c 0
ba . cb d c 0
b a . c b c a a d 0
bcd bca ba d a cd 0
a b c d c a b d a c d b
11. The sum of the coefficients of three consecutive terms in the binomial expansion of (1 + x) n+2, which are in the
ratio 1 : 3 : 5, is equal to
(1) 63 (2) 92 (3) 25 (4) 41
Sol. (1)
n+2
cr–1 : n+2cr : n+2cr+1 :: 1 : 3 : 5
n 2 !
r! n 2 r ! 1
r 1! n r 3! n 2 ! 3
r 1
n r 3 3r
n – r 3 3
n 4r 3 0
n 1! r 1! n r 1! 3
r! n 2 r ! n 2 ! 5
r 1 3
n2r 5
8r–1= 3n ……..(2)
By equation 1 and 2
8r 1
4r 3 n 4r 3
3
r2 n 4 2 3
n 5
Sum : C1 C2 C3 7 21 35 63
7 7 7
2
dy 5 x5 1
12. Let y = y (x) be the solution of the differential equation y , x > 0. If y(1) = 2, then
dx x x 5 1
x7
y(2) is equal to
693 637 697 679
(1) (2) (3) (4)
128 128 128 128
Sol. (1)
5dx 5 x 6dx
x x5 1
x5 1
I.F = e e e
Put, 1 + x = t –5x–6 dx = dt
–5
dt
e
1 x5
1
t 1 x5
x5 x5 1 x
5 2
y
1 x 5
1 x x 7
5
dx
x3dx x 2dx
x5 x4 1
y c
1 x5 4 x
Given than: x = 1 y = 2
1 1
2 1 c
2 4
c
4
x5 x4 1 7
y
1 x5 4 x 4
Now put, x = 2
32 21
y
33 4
693
y
128
P ~ q ~ r
2022
4x 5
14. If the 1011th term from the end in the binominal expansion of is 1024 times 1011th term from
5 2x
the beginning, the |x| is equal to
(1) 8 (2) 12 (3) 10 (4) 15
Sol. (3)– Bouns
T1011 from beginning = T1010+1
012
5
1010
4x
2022
C1010
5 2x
T1011 from end
5
1012 1010
4x
2022
C1010
2x 5
5
1012 1010
4x
Given: 2022
C1010
2x 5
5
1010 1012
4x
210 2022 C1010
2x 5
5
2 2
10 4x
2
2x 5
54
x4
216
5
x
16
15. If the system of linear equations
7x + 11y + z = 13
5x + 4y + 7z =
175x + 194y + 57z = 361
has infinitely many solutions, then + + 2 is equal to :
(1) 3 (2) 6 (3) 5 (4) 4
Sol. (4)
7x + 11y + z = 13
5x + 4y + 7z =
175x + 194y + 57z = 361
4sc condition of Infinite Many solution
0 & x, y, z 0 check.
After solving we get 13 2 4
16. Let the line passing through the point P (2, –1, 2) and Q (5, 3, 4) meet the plane x – y +z = 4 at the point T. Then
x 7 y3 z2
the distance of the point R from the plane x + 2y + 3z +2 = 0 measured parallel to the line
2 2 1
is equal to
(1) 3 (2) 61 (3) 31 (4) 189
Sol. (1)
x 5 y3 z4
Line :
3 4 2
R(3 + 5,4 + 3,2 + 4)
3 + 5 – 4 – 3+ 2 + 4 = 4
+6=4 = –2
R (–1,–5,0)
x 1 y 5 z 0
Line :
2 2 1
Point T = (2μ -1,2μ - 5,μ )
It lies on plane
2μ –1+ 2(2μ – 5) + 3μ + 2 = 0
μ =1
T = (1,–3,1)
RT = 3
e 1 e2
1 3e 1
(1) (2) 1 (3) 2e – (4) 2e –1
2 2 2
Sol. (3)
F[0,2] R
min x 2 ,x ; x 0,1
F x
x log e x 1; x 1, 2
ex : x 0,1
2
F x
e x 1,2
2 1
= e 1 4 1 e
2 2
1
2e
2
x 1 x x
9
19. If x x x = 103x 81 , then , are the roots of the equation
8 3
x x x 2
(1) 4x2 –24x –27 = 0 (2) 4x2 +24x +27 = 0 (3) 4x2 –24x +27 = 0 (4) 4x2 +24x –27 = 0
Sol. (3)
x 1 x x
9
x xd x 103x 81
8
x x x d2
Put x 0
1 0 0
9
0 0 81
8
0 0 2
93
3
8
9
2
9 3
3 23 2
3
3 2
Option (C) 4x2 24x 27 0
3 9
has Root ,
2 2
1
20. The domain of the function f(x) = is (where [x] denotes the greatest integer less than or equal
[x] – 3[x] –10
2
to x )
(1) – , –3 6, (2) – , –2 5, (3) – , –3 5, (4) – , –2 6,
Sol. (4)
1
F x
x 3 x 10
2
x 2 x 5 0
+ – +
–2 5
x 2 or x 5
x 3 or x 6
x 2 or x 6
x , 2 6,
SECTION - B
21. If A is the area in the first quadrant enclosed by the curve C : 2x2 – y + 1 = 0, the tangent to C at the point (1,3)
and the line x + y = 1, then the value of 60 A is ______.
Sol. 16
y = 2x2 + 1
Tangenet at (1, 3)
y = 4x – 1
1
A 2x 2 1 dx area of QOT area of
0
22. Let A = {1, 2, 3, 4, 5} and B= {1, 2, 3, 4, 5, 6}. Then the number of functions f:AB satisfying f(1) + f(2) =
f(4)–1 is equal to ______.
Sol. 360
f 1 f 2 1 f 4 6
f 1 f 2 5
23. Let the tangent to the parabola y2 = 12 x at the point (3, ) be perpendicular to the line 2x+2y = 3. Then the
square of distance of the point (6,–4) from the normal to the hyperbola 2 x2 – 9y2 = 92 at its point ( –1, +
2) is equal to _____.
Sol. 116
P 3, lies on y2 12x
6
dy 6
But, 1 6 6 reject
dx 3,
x 2 y2
1, normal at
Now, hyperbola 9 36
9x 36y
Q 1, 2 is 45
5 8
2x + 5y – 50 = 0
Now, distance of (6, –4) from 2x + 5y – 50 = 0 is equal to
2 6 5 4 50 58
2 5
2 2
29
Square of distance = 116
4 8 13 19
24. For kN, if the sum of the series 1 …… is 10, then the value of k is___
k k 2 k3 k 4
Sol. 2
4 8 13 19
10 1 ......upto
k k 2 k3 k 4
4 8 13 19
9 2 3 4 ......upto
k k k k
9 4 8 13
2 3 4 ......upto
k k k k
1 4 4 5 6
S 9 1 2 3 4 ......upto
k k k k k
S 4 4 5
2 3 4 ......upto
k k k k
1 4 1 1 1
1 S 3 4 5 .....
k k k k k
1
2
1 4 3
9 1 k
k k 1
1
k
3
9(k – 1) = 4k(k – 1) + 1
k=2
1 y z 3
25. Let the line : x , R meet the plane P : x + 2y + 3z = 4 at the point ( ). If the angle
–2
5
between the line and the plane P is cos1 , then + 2 + 6 is equal to ____.
14
Sol. 11
y 1 z 3
:x ,
2
Dr's of line 1, 2,
Dr's of normal vector of plane P : x + 2y + 3z = 4
are (1, 2, 3)
Now, angle between line and plane P is given by
1 4 3 3 5
sin given cos
5 2 . 14 14 14
2
3
2
Let variable point on line is t,2t 1, t 3
3
line of plane P.
t = –1
7
1, 1, , ,
3
2 6 11
26. The number of points where the curve f(x) = e8x – e6x – 3e4x – e2x 1, x R cuts x-axis, is equal to ________
Sol. 2
Let e2x = t
t4 – t3 – 3t2 - t +1= 0
1 1
t2 t 3 0
t2 t
2
1 1
t t 5 0
t t
1 1 21
t
t 2
Two real values of t.
27. If the line l1 : 3y– 2x = 3 is the angular bisector of the line l2 : x –y + 1 = 0 and l3 : ax +y + 17, then 2 + 2 –
– is equal to ______.
Sol. 348
Point of intersection of 1 : 3y 2x 3
2 : x y 1 0 is P 0,1
Which lies on 3 : x y 17 0,
17
Consider a random point Q 1,0
on 2 : x y 1 0, image of Q about
17 6
2 : x y 1 0, is Q' , which is calculated by formulae
13 13
x 1 y0 2 3
2
2 3 13
Now, Q' lies in 3 : x y 17 0
7
Now, 2 2 348
1
28. Let the probability of getting head for a biased coin be . It is tossed repeatedly until a head appears. Let N be
4
p
the number of tosses required. If the probability that the equation 64x2 + 5Nx + 1 = 0 has no real root is ,
q
where p and q are co-prime, then q – p is equal to ______.
Sol. 27
64x2 5Nx 1 0
D 25N2 256 0
256 16
N2 N
25 5
N 1, 2,3
1 3 1 3 3 1 37
Pr obability
4 4 4 4 4 4 64
q p 27
29. Let a ˆi 2jˆ 3kˆ and b ˆi ˆj – kˆ . If c is a vector such that a.c 11 , b. a c 27 and b.c – 3 b , then
2
a c is equal to ______.
Sol. 285
a ˆi 2jˆ 3k,
ˆ b ˆi ˆj kˆ
b. a c 27,a.b 0
b a c 3a
b . a c cos 27
14
sin
95
b a c 3 95
a c 3 95
z 2 8iz – 15 13
30. Let S z C – {i, 2i}: 2 R . If i S, a R–{0} , then 2422 is equal to ______.
z 3iz – 2 11
Sol. 1680
z 2 8iz 15
2 R
z 3iz 2
1
1liz 13 R
z 2
3iz 2
13
Put Z = i
11
z2 3iz 2 is imaginary
Put z = x + iy
x 2 y2 2xyi 3ix 3y 2 Imaginary
Re x 2 y2 3y 2 2xy 3x i 0
x 2 y2 3y 2 0
x 2 y2 3y 2
13
x 2 y 1 y 2 z i
11
13
Put x , y
11
13 13
2 11 2
11 11
2
24 35
121
242 48 35 1680
2
SECTION - A
31. Eight equal drops of water are falling through air with a steady speed of 10 cm/s. If the drops collapse, the new
velocity is :-
(1) 10 cm/s (2) 40 cm/s (3) 16 cm/s (4) 5 cm/s
Sol. (2)
4 4 6 rv
8 × r3 = R3 B
3 3
R = 2r
2r 2
V= (b – air)
9
mg
V r2
2
V1 r
V2 = V1 × 4 = 10 × 4 = 40 km/s–1
V2 R
32. Given below are two statements : one is labelled as Assertion A and the other is labelled as Reason R
Assertion A : A bar magnet dropped through a metallic cylindrical pipe takes more time to come down
compared to a non-magnetic bar with same geometry and mass.
Reason R : For the magnetic bar, Eddy currents are produced in the metallic pipe which oppose the motion of
the magnetic bar.
In the light of the above statements, choose the correct answer from the options given below
(1) A is true but R is false
(2) Both A and R are true but R is NOT the correct explanation of A
(3) A is false but R is true
(4) Both A and R are true and R is the correct explanation of A
Sol. (4)
Due to Eddy current in the metallic pice which opposes the motion of magnetic bar. So, it takes more time to
comes down compared to non-magnetic bar.
33. A space ship of mass 2 × 104 kg is launched into a circular orbit close to the earth surface. The additional
velocity to be imparted to the space ship in the orbit to overcome the gravitational pull will be (if g = 10 m/s2
and radius of earth = 6400 km):
(1) 7.9 2 1 km / s (2) 7.4 2 1 km / s (3) 11.2 2 1 km / s (4) 8 2 1 km / s
Sol. (4)
GM
V = ( 2 – 1)
R
GM
= R ( 2 – 1)
R2
= gR ( 2 – 1) = 8000 ( 2 – 1) ms–1
= 8( 2 – 1) kms–1
34. A projectile is projected at 30° from horizontal with initial velocity 40 ms–1. The velocity of the projectile at t =
2 s from the start will be :
(Given g = 10 m/s2)
(1) Zero (2) 20 3 ms–1 (3) 40 3 ms–1 (4) 20 ms–1
Sol. (2)
Ux = 40 cos 30 = 20 3
Uy = 40 sin 30 = 20
Vx = 20 3
Vy = uy – gt = 20 – 10 × 2 = 0
V= v x 2 v y 2 = 20 3 = ms–1
35. A plane electromagnetic wave of frequency 20 MHz propagates in free space along x-direction. At a particular
space and time, E 6.6jˆ v / m . What is B at this point?
(1) –2.2 × 10–8 k̂ T (2) –2.2 × 10–8 î T (3) 2.2 × 10–8 k̂ T (4) 2.2 × 10–8 î T
Sol. (3)
E 6.6
|B| = = = 2.2 ×10–8
C 3 108
For direction of B
= EB C
= ˆj B ˆi
B (2.2 10 –8 ) kˆ T
36. A car P travelling at 20 ms–1 sounds its horn at a frequency of 400 Hz. Another car Q is travelling behind the
first car in the same direction with a velocity 40 ms–1. The frequency heard by the passenger of the car Q is
approximately [Take, velocity of sound = 360 ms–1]
(1) 471 Hz (2) 514 Hz (3) 421 Hz (4) 485 Hz
Sol. (3)
Vc = 20 ms–1
f = 400 Hz
Q = 40 ms–1 P 20 ms–1
0
S
Vs – (– VQ )
fapp = f
VS – (– Vp )
360 40 400
= ×400 = × 400 = 421 Hz Ans. (3)
360 20 380
37. A body of mass 500 g moves along x-axis such that it's velocity varies with displacement x according to the
relation = 10 x m/s the force acting on the body is:-
(1) 25 N (2) 5 N (3) 166 N (4) 125 N
Sol. (1)
dv 10 5
v = 10 x = =
dx 2 x x
dv
a=v
dx
5 5
a=v× = 10 x× = 50 ms–2
x x
500
F = ma = × 50 = 25 N
1000
38. The ratio of the de-Broglie wavelengths of proton and electron having same Kinetic energy:
(Assume mp = me × 1849)
(1) 1:62 (2) 1:30 (3) 1:43 (4) 2:43
Sol. (3)
h h
= =
P 2mK
P me me 1
= = =
e mp 1840me 1840
P 1
= Ans. (3)
e 43
39. If force (F), velocity (V) and time (T) are considered as fundamental physical quantity, then dimensional
formula of density will be:
(1) FV–2T2 (2) FV4T–6 (3) FV–4T–2 (4) F2V–2T6
Sol. (3)
= Fx Vy Tz
[ML-3] = [MLT-2]x [LT-1]y [T]z
1=x x=1
–3 = x + y y = –4
0 = –2x –y + z z =2x + 4 = 2 – 4 = –2
= F V T
–4 –2
Ans. (3)
40. An electron is allowed to move with constant velocity along the axis of current carrying straight solenoid.
A. The electron will experience magnetic force along the axis of the solenoid.
B. The electron will not experience magnetic force.
C. The electron will continue to move along the axis of the solenoid.
D. The electron will be accelerated along the axis of the solenoid.
E. The electron will follow parabolic path-inside the solenoid.
Choose the correct answer from the options given below:
(1) A and D only (2) B, C and D only (3) B and E only (4) B and C only
Sol. (4)
We know that
In the solenoid magnetic field along the axis of solenoid.
When charge particle moving inside solenoid along the axis F = 0
Fm = q (V B)
So, Fm =
And it moves with constant velocity.
41. The Thermodynamic process, in which internal energy of the system remains constant is
(1) Isobaric (2) Isochoric (3) Adiabatic (4) Isothermal
Sol. (4)
U = nCVT, for all process
For isothermal process, T = 0
So, U = 0
That means internal energy of system remains constant.
43. The logic operations performed by the given digital circuit is equivalent to:
Y = AB + AB
(A • B)
Y = (A.B)
Y = AND Gate
44.
Req = 4
8
i= 2A
4
23 2
i1 = A
36 3
2/3 1
i2 = A
2 3
45. When vector A 2iˆ 3jˆ 2kˆ is subtracted from vector B , it gives a vector equal to 2ˆj . Then the magnitude
of vector B will be:
(1) 3 (2) 5 (3) 13 (4) 6
Sol. (Bonus)
A 2iˆ 3jˆ 2kˆ
B – A 2ˆj
| B| = 2 2 52 2 2 = 4 25 4 = 8 25 = 33
46. If V is the gravitational potential due to sphere of uniform density on it's surface, then it's value at the center of
sphere will be:-
4 3V V
(1) V (2) V (3) (4)
3 2 2
Sol. (3)
GM
V= – 3
(1.5R2 – 0.5r2)
R
GM
V =– [At the surface]
R
3
3GM V
Vcentre = – = 2
2R
47. The root mean square speed of molecules of nitrogen gas at 27°C is approximately : (Given mass of a nitrogen
molecule = 4.6 × 10–26 kg and take Boltzmann constant kB = 1.4 × 10–23 JK–1)
(1) 1260 m/s (2) 91 m/s (3) 523 m/s (4) 27.4 m/s
Sol. (3)
3RT 3RT 3KT
Vrms = = =
Mw mN A m
9 1.4 10 5
=
4.6
= 2.73 10 5
= 27.3 10 4
= 522.4 ms–1
= 523 ms–1
48. The energy of He+ ion in its first excited state is, (The ground state energy for the Hydrogen atom is –13.6 eV):
(1) –13.6 eV (2) –54.4 eV (3) –27.2 eV (4) –3.4 eV
Sol. (4)
13.6z 2
E=–
n 2
eV
First excited state
n=2
–13.6 z 2
E= = –13.6 eV
22
49. When one light ray is reflected from a plane mirror with 30° angle of reflection, the angle of deviation of the
ray after reflection is:
(1) 140° (2) 130° (3) 120° (4) 110°
Sol. (3)
30° 30°
\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\
= – 2i = – 2 × 30
= 180 – 60 = 120°
50. A capacitor of capacitance C is charge to a potential V. The flux of the electric field through a closed surface
enclosing the positive plate of the capacitor is :
CV 2CV CV
(1) Zero (2) (3) (4)
0 0 2 0
Sol. (2)
q
=
0
CV
=
0
SECTION – B
51. A coil has an inductance of 2H and resistance of 4 . A 10 V is applied across the coil. The energy stored in the
magnetic field after the current has built up to its equilibrium value will be __________ × 10–2 J.
Sol. (625)
At steady state, inductor will act as a short circuit.
V 10 5
I= = = A
R 4 2
2
1 2 1 5 25
E= LI = × 2 × = = 6.25 = 625 × 10–2 J
2 2
2 4
at steady state
52. A metallic cube of side 15 cm moving along y-axis at a uniform velocity of 2 ms–1. In a region of uniform
magnetic field of magnitude 0.5T directed along z-axis. In equilibrium the potential difference between the
faces of higher and lower potential developed because of the motion through the field will be _________ mV.
Sol. (150)
qVB = qE
E = VB
V = EL = VBL
15 15
V = 2 × 0.5 × = volt
100 100
= 15 × 10–2 volt
= 150 × 10–3 v
Sol. (4)
Ceq = 0.5 F
Q = 0.5 × 10 = 5 C
5C 0.8
Q’ = = 4C
0.8 0.2
54. A nucleus disintegrates into two nuclear parts, in such a way that ratio of their nuclear sizes is 1 : 2 1/3. Their
respective speed have a ratio of n : 1. The value of n is __________
Sol. (2)
From LCM :
m1v1 = m2v2
3
V1 m 2 r2 3 r2
V2 m1 r13 r1
3
1
V1 2 3 2
V2 1 1
n= 2
55. The surface tension of soap solution is 3.5 × 10–2 Nm–1. The amount of work done required to increase the radius
of soap bubble from 10 cm to 20 cm is __________ × 10–4 J. (take = 22/7)
Sol. (264)
W = U
W = 25 × (Af – Ai)
= 2 × 5 × 4 (rf 2 – ri 2)
22
= 2 × 3.5 × 10–2 × 4 × × 10–4 (300)
7
= 264 × 10–4 J
56. A circular plate is rotating horizontal plane, about an axis passing through its center perpendicular to the plate,
with an angular velocity . A person sits at the center having two dumbbells in his hands. When he stretches
out his hands, the moment of inertia of the system becomes triple. If E be the initial Kinetic energy of the system,
E
then final Kinetic energy will be . The value of x is
x
Sol. (3)
I11 = I22
I = 3I2
2 =
3
1 2
E= I
2
1 2
2 I
1 2
Ef = × 3I × =
2 3 3
x=3
57. A block of mass 5 kg starting from rest pulled up on a smooth incline plane making an angle of 30° with
horizontal with an affective acceleration of 1 ms–2. The power delivered by the pulling force at t = 10 s from the
starts is __________ W. [use g = 10 ms–2] (Calculate the nearest integer value)
Sol. F – mg sin 30 = ma 0
F = 5 × 1 + 25 = 30 N g s in3
m
V = u + at = 0 + 1 × 10 = 10
P = FV = 30 × 10 = 300 watt 30°
58. As shown in the figure, a plane mirror is fixed at a height of 50 cm from the bottom of tank containing water
4
. The height of water in the tank is 8 cm. A small bulb is placed at the bottom of the water tank. The
3
distance of image of the bulb formed by mirror from the bottom of the tank is ___________ cm.
Sol. (98)
42cm
8
8cm × 3 = 6cm
I 4 4
d
Apparent depth of O = 6
Distance between O and I2 = 48 + 50 = 98 cm
59. Two identical cells each of emf 1.5 V are connected in series across a 10 resistance. An ideal voltmeter
connected across 10 resistance reads 1.5 V. The internal resistance of each cell is ___________ .
Sol. (5)
1 r 1 r
10
2 1.5
I= =
10 2r 10
20 = 15 + 3r
20 × 1.5 = 15 + 3r
30 = 15 + 3r
r = 5
60. A wire of density 8 × 103 kg/m3 is stretched between two clamps 0.5 m apart. The extension developed in the
wire is 3.2 × 10–4 m. If Y = 8 × 1010 N/m2, the fundamental frequency of vibration in the wire will be _________
Hz.
Sol. (80)
1 T
f=
2
1 YA
f=
2
1 8 1010 3.2 10 –4
f=
2 0.5 8 10 3 0.5
1
f= 6400
1
f = 80 Hz
SECTION - A
61. The magnetic moment is measured in Bohr Magneton (BM). Spin only magnetic moment of Fe in [Fe(H 2O)6 ]3
and [Fe(CN)6 ]3– complexes respectively is:
(1) 3.87 B. M. and 1.732 B.M. (2) 6.92 B.M. in both
(3) 5.92 B.M. and 1.732 B.M. (4) 4.89 B.M. and 6.92 B.M.
Sol. 3
[Fe(H2O)6]3+
Fe3+ [Ar] 3d5 4s0
No pairing
Unpaired e– = 5
n(n 2)
= 5(5 2)
35 5.92B.M.
[Fe(CN)6]–3
Unpaired e– = 1
n(n 2)
= 1(1 2) 3 1.732B.M.
62. Which one of the following pairs is an example of polar molecular solids?
(1) SO2 (s),CO2 (s) (2) SO2 (s), NH2 (s) (3) MgO(s),SO2 (s) (4) HCl (s), AlN(s)
Sol. 2
SO2 and NH3 are polar molecules. They are constituent particles of polar molecular solids.
List I List II
Complex Colour
A. Mg(NH4 )PO4 I. Brown
B. K3[Co(NO2 )6 ] II. White
C. MnO(OH)2 III. Yellow
D. Fe4[Fe(CN)6 ]3 IV. blue
65. If Ni2 is replaced by Pt 2 in the complex [NiCl2 Br2 ]2 – , which of the following properties are expected to get
changed?
A. Geometry
B. Geometrical isomerism
C. Optical isomerism
D. Magnetic properties
(1) A, B and C (2) A and D (3) B and C (4) A, B and D
Sol. 4
[NiBr2Cl2]2– This complex species is tetrahedral as Br & Cl are weak field ligands.
[PtBr2Cl2]2– As Pt belongs to 5d series. This complex species is square planar.
Both the complex species are optically inactive.
[NiBr2Cl2]2–, being tetrahedral does not show Geometrical Isomerism.
[PtBr2Cl2]2– shows two Geometrical Isomers.
D
H
OH
Sol. 1
(i) NaI, H3PO4
CH3 – CH2 – CH – CH3 CH3 – CH2 – CH – CH3
OH I
Mg
D2O
CH3 – CH2 – CH – CH3 CH3 – CH2 – CH – CH3
D MgI
N O O H
533-543K
–C–(CH
[ 2)5–N–
]
H2O
Caprolactam Nylon-6
69. For a chemical reaction A + B Product, the order is 1 with respect to A and B.
(1) (2)
(3) (4)
Sol. 1
ON H2N
NaNO2 NH4SH
HCl H2O
OH OH OH
72. Given below are two statements, one is labelled as Assertion A and the other is labelled as Reason R.
In the light of the above statements, choose the correct answer from the options given below:
(1) Both A and R are true and R is the correct explanation of A
(2) A is true but R is false
(3) Both A and R are true but R is NOT the correct explanation of A
(4) A is false but R is true
Sol. 4
Assertion (A)
O
NH2 – NH2
OH Major
Cl
Reason (R)
O
NH2 – NH2
OH
73. Given below are two statements, one is labelled as Assertion A and the other is labelled as Reason R.
Assertion A : [CoCl(NH3 )5 ]2 absorbs at lower wavelength of light with respect to [CoCl(NH3 )5 (H 2O)]3
Reason R : It is because the wavelength of the light absorbed depends on the oxidation state of the metal ion.
In the light of the above statements, choose the correct answer from the options given below:
(1) Both A and R are true but R is NOT the correct explanation of A
(2) A is true but R is false
(3) Both A and R are true and R is the correct explanation of A
(4) A is false but R is true
Sol. 4
Since H2O is strong field ligand compared to chloride and Co3+ ion is present.
CFSE is higher for [Co(NH3)5H2O]+3, hence it will absorb at lower wavelength.
74. Compound from the following that will not produce precipitate on reaction with AgNO3 is :
(1) (2)
(3) (4)
Sol. 2
AgNO3
Br +
Aromatic
Br +
AgNO3
Unstable
Br
AgNO3
Benzylic
Br
AgNO3
CH = CH CH = CH –
Allylic
75. Given below are two statements, one is labelled as Assertion A and the other is labelled as Reason R.
Assertion A : A solution of the product obtained by heating a mole of glycine with a mole of chlorine in
presence of red phosphorous generates chiral carbon atom.
Reason R : A molecule with 2 chiral carbons is always optically active.
In the light of the above statements, choose the correct answer from the options given below:
(1) A is false but R is true
(2) Both A and R are true but R is NOT the correct explanation of A
(3) A is true but R is false
(4) Both A and R are true and R is the correct explanation of A
Sol. 3
Cl2 *
H2N – CH2 – COOH H2N – CH – COOH
Red P
Cl
76. Alkali metal from the following with least melting point is:
(1) K (2) Cs (3) Rb (4) Na
Sol. 2
On moving down the group in alkali metals melting point decreases.
77. Which hydride among the following is less stable?
(1) HF (2) NH3 (3) BeH2 (4) LiH
Sol. 3
BeH2 is hypovalent
A.
B.
C.
D.
79. One mole of P4 reacts with 8 moles SOCl2 to give 4 moles of A, x mole of SO2 and 2 moles of B. A, B and x
respectively are
(1) POCl3 ,S2Cl2 and 4 (2) POCl3 ,S2Cl2 and 2 (3) PCl3 ,S2Cl2 and 4 (4) PCl3 ,S2Cl2 and 2
Sol. 3
P4 + 8 SOCl2 4PCl3 + 2S2Cl2 + 4SO2
80. What weight of glucose must be dissolved in 100 g of water to lower the vapour pressure by 0.20 mmHg?
(Assume dilute solution is being formed)
Given : Vapour pressure of pure water is 54.2 mmHg at room temperature. Molar mass of glucose is 180g mol –1
(1) 2.59 g (2) 3.59 g (3) 3.69 g (4) 4.69 g
Sol. 3
P 0 – Ps n
(for dilute solution)
P0 N
0.2 n 18
54.2 100
100
n=
271 18
100 180
w= ; w = 3.69 g
271 18
SECTION - B
81. The total number of intensive properties from the following is__________ new line volume, Molar heat
capacity, Molarity, Eθ cell, Gibbs free energy change, Molar mass, Mole
Sol. 4
Extensive Mole, Volume, Gibbs free energy.
Intensive Molar mass, Molar heat capacity, Molarity, E cell.
82. The volume of hydrogen liberated at STP by treating 2.4 g of magnesium with excess of hydrochloric acid is
__________ 10–2 L .
Given: Molar volume of gas is 22.4 L at STP. Molar mass of magnesium is 24 g mol–1
Sol. 224
Mg + 2HCl MgCl2 + H2
w = 2.4 g
2.4
N= 0.1mole
24
1 mole of gas at STP 22.4 lit.
0.1 mole of gas = 0.1 × 22.4
= 2.24 lit. = 224 × 10–2 litre
83. The number of correct statements about modern adsorption theory of heterogeneous catalysis from the following
is
A. The catalyst is diffused over the surface of reactants.
B. Reactants are adsorbed on the surface of the catalyst.
C. Occurrence of chemical reaction on the catalyst's surface through formation of an intermediate.
D. It is a combination of intermediate compound formation theory and the old adsorption theory.
E. It explains the action of the catalyst as well as those of catalytic promoters and poisons.
Sol. 3
B, C and D are correct.
(NCERT – Surface Chemistry)
84. The number of correct statements from the following is
A. For 1 s orbital, the probability density is maximum at the nucleus
B. For 2 s orbital, the probability density first increases to maximum and then decreases sharply to zero.
C. Boundary surface diagrams of the orbitals encloses a region of 100% probability of finding the electron.
D. p and d-orbitals have 1 and 2 angular nodes respectively
E. probability density of p-orbital is zero at the nucleus
Sol. 3
A, D and E statements are correct.
For 2s orbital, the probability density first decreases and then increases.
At any distance from nucleus the probability density of finding electron is never zero and it always have some
finite value.
86. Mg(NO3 )2 XH2O and Ba(NO3 )2 YH2O , represent formula of the crystalline forms of nitrate salts. Sum of X
and Y is______________
Sol. 6
Mg(NO3)2·6H2O is a hydrated salt whereas Ba(NO3)2 is a anhydrous salt.
x+y=6
87. The number of possible isomeric products formed when 3-chloro-1-butene reacts with HCl through carbocation
formation is_____________
Sol. 4
88. 4.5 moles each of hydrogen and iodine is heated in a sealed ten litre vessel. At equilibrium, 3 moles of HI were
found. The equilibrium constant for H2 (g) I2 (g) 2HI(g) is______________
Sol. 1
H2(g) + I2(g) 2HI(g)
t = 0 4.5 4.5 –
teq 3 3 3
[HI]2 (3)2 9
Kc 1
[H2 ][I2 ] 3 3 9
89. Number of compounds from the following which will not produce orange red precipitate with Benedict solution
is _______________
Glucose, maltose, sucrose, ribose, 2-deoxyribose, amylose, lactose
Sol. 2
Benedict test :
Glucose –
maltose –
sucrose –
ribose –
2-deoxyribose –
amylose –
lactose –
90. The maximum number of lone pairs of electrons on the central atom from the following species is__________
ClO3– , XeF4 ,SF4 and I3–
Sol. 3
SECTION - A
6
1. e
0
3x
6e 11e x 6
2x
dx
32 256 512 64
(1) loge (2) log e (3) log e (4) loge
27 81 81 27
Sol. 1
6
I dx
0 e 1 e 2 e 3
x xx
1 1
2
1
6 x x x 2 dx
0
e 1 e 2 e 3
e x e x dx e x
3 dx 6 0 1 2e x 0 1 3e x dx
3
0
1 e x
3 ln 1 e x 6 ln 1 2e x
1
0 2 0
ln 1 3e x
3
3 0
3ln 2 3ln 3 ln 4
2
3ln ln 4
3
32
ln
27
2. Among
1
(S1) : lim 2 4 6 ..... 2n 1
n2
n
3. The number of symmetric matrices of order 3, with all the entries from the set {0, 1, 2, 3, 4, 5, 6, 7, 8, 9}, is
(1) 109 (2) 106 (3) 910 (4) 610
Sol. 2
a b c
A b d e , a, b, c, d, e, f {0,1, 2, .9} ,Number of matrices = 106
c e f
5. A coin is biased so that the head is 3 times as likely to occur as tail. This coin is tossed until a head or three tails
occur. If X denotes the number of tosses of the coin, then the mean of X is-
21 15 81 37
(1) (2) (3) (4)
16 16 64 16
Sol. 1
3
P(H) =
4
1
P(T) =
4
3 3 1 3
MeanX 3
4 8 64 64
3 3 3
4 8 16
7 21
3
16 16
1
6. max x 2sin x cosx sin3x
0 x
3
5 2 3 3 23 3
(1) 0 (2) (3) (4)
6 6
Sol. 3
1
f (x) x sin 2x sin 3x
3
f (x) 1 2cos 2x cos3x 0
5
x ,
6 6
f (x) 4sin 2x 3sin 3x
5
f 0
6
5
is point of maxima
6
5 5 3 1
f
6 6 2 3
7. The set of all a R for which the equation x |x – 1| + |x + 2| + a= 0 has exactly one real root, is
(1) (– ,–3) (2) (– , ) (3) (– 6, ) (4) (– 6, –3)
Sol. 2
f (x) x | x 1| | x 2 |
x | x 1| | x 2 | a 0
x | x 1| | x 2 | a
8. Let PQ be a focal chord of the parabola y² = 36x of length 100, making an acute angle with the positive x-axis.
Let the ordinate of P be positive and M be the point on the line segment PQ such that PM:MQ = 3:1. Then which
of the following points does NOT lie on the line passing through M and perpendicular to the line PQ?
(1) (3, 33) (2) (6, 29) (3) (– 6, 45) (4) (– 3, 43)
Sol. 4
2
1
9 t 100
t
t 3
P(81,54) &Q(1, 6)
M(21,9)
4
L is (y 9) (x 21)
3
3y 27 4x 84
4x 3y 111
10. Let s1, s2, s3, ......, s10 respectively be the sum to 12 terms of 10 A.P. s whose first terms are 1, 2, 3, ..., 10 and
10
the common differences are 1, 3, 5, ........., 19 respectively. Then s
i 1
i is equal to
Sk 144k 66 10
1 k 1
10 11
144 660
2
7920 660
7260
1 1 1
11. For the differentiable function f: R - {0} R, let 3f(x)+2f 10 , then f (3) f ' is equal to
x x 4
29 33
(1) 13 (2) (3) (4) 7
5 5
Sol. 1
1 1
3f (x) 2f x x 10 3
1
2f (x) 3f x x 10 2
3
5f (x) 2x 10
x
1 3
f (x) 2x 10
5 x
1 3
f (x) 2 2
5 x
1 1 1
f (3) f (1 6 10) (48 2)
4 5 5
| 3 10 | 13
13.
Let the tangent and normal at the point 3 3,1 on the ellipse
x 2 y2
36 4
1 meet the y-axis at the points A and
B respectively. Let the circle C be drawn taking AB as a diameter and the line x = 2 5 intersect C at the points
P and Q. If the tangents at the points P and Q on the circle intersect at the point (, ), then ² – ² is equal to
304 314
(1) (2) 60 (3) (4) 61
5 5
Sol. 1
x 2 y2
Given ellipse 1
36 4
x y
1
4 3 4
y=4
x 4 2
4 4 3 3
y=–8
x 2 y2 4y 32 0
hx ky 2(y k) 32 0
k 2
hx 2k 32 0
hx 36
36
h
2 5
k 2
304
2 2
5
14.
The distance of the point (-1, 2, 3) from the plane r. ˆi 2jˆ 3kˆ 10 parallel to the line of the shortest distance
between the lines r ˆi ˆj 2iˆ kˆ and r 2iˆ ˆj ˆi ˆj kˆ is
17. Let the equation of plane passing through the line of intersection of the planes x+2y+az=2 and x-y+z=3 be 5x
2 ab
– 11y + bz = 6a – 1. For c Z, if the distance of this plane from the point (a, –c, c) is , then is equal
a c
to
(1) – 4 (2) 2 (3) – 2 (4) 4
Sol. 1
(x 2y az 2) (x y z 3) 0
1 2 a 2 3
5 11 b 6a 1
7
, a 3, b 1
2
2 5a 11c bc 6a 1
a 25 121 1
c 1
a b 3 1
4
c 1
42022
18. Fractional part of the number is equal to
15
4 8 1 14
(1) (2) (3) (4)
15 15 15 15
Sol. 3
42022 24044 (1 15)1011 1
15 15 15 15
dy
19. Let y = y1 (x) and y = y2 (x) be the solution curves of the differential equation = y+7 with initial conditions
dx
y1 (0) = 0 and y2 (0)=1 respectively. Then the curves y = y1 (x) and y = y2 (x) intersect at
(1) no point (2) infinite number of points
(3) one point (4) two points
Sol. 1
dy dy
y7 y7
dx dx
I.F. e x
ye x 7e x dx
ye x 7e x c
y 7 cex
7 7ex 7 8ex ex 0 .
No solution
20. The area of the region enclosed by the curve f(x)= max{sin x, cosx}, – ≤ x ≤ and the x-axis is
(1) 2 2 2 1 (2) 4 2
(3) 4 (4) 2 2 1
Sol. 3
Area =
3
4 2 4
SECTION - B
21. The sum to 20 terms of the series 2.2 – 3 +2.42 – 52 + 2.62– ........ is equal to _______.
2 2
Sol. 1310
2 2
32 42 52 20terms 22 42 . 10terms
(2 3 4 5 .. 11) 4 1 22 ..102
21 22 10 11 21
1 4
2 6
1 231 14 1110
1540 1 231
1310
3
be 5. If m and are respectively the mean deviation about the mean and the variance of the data, then
m 2
is equal to ________.
Sol. 8
5 x
x fi i
4 72 140 7 72
f i 64
320 5 288 7 2 32 16
fi xi x where f 64 16 80
M.D.(x) i
fi
4 4 24 2 28 0 16 2 8 4 8
M.D. (x)
80 5
f x x
2
Variance
i i
f i
4 16 24 4 0 16 4 8 16 352
80 80
3 3 16
8
m 2
128
352
80 80
n
6
23. Let be the constant term in the binomial expansion of x 3 , n 15 . If the sum of the coefficients of
x2
the remaining terms in the expansion is 649 and the coefficient of x–n is λ, then is equal to ________.
Sol. 36
n k 3
k
Tk 1 Ck (x)
n 2
(6) (x) k 2
nk 3
k0
2 2
n 4k 0
n
(5)n n C n (6) 4 649
4
By observation (625 + 24 = 649) , we get n = 4
n 4&k 1
Required is coefficient of
4
6
x 4 is 4 3
x2
4
C1 (6)3
By calculating we will get 36
24. Let zz k1z k 2iz 1 i , k1 , k 2 R . Let Re() = 0 be the circle C of radius 1 in the first quadrant
touching the line y = 1 and the y-axis. If the curve Im() = 0 intersects C at A and B, then 30(AB)2 is equal to
______.
Sol. 24
zz k1z k 2iz (1 i)
Re() x 2 y 2 k1x k 2 y 0
k k
Centre 1 , 2 (1, 2)
2 2
k1 2, k 2 4
radius 1 4
Im k1y k 2 x 0
2x y 2 0
2
d
5
12 4 1
1
4 5 5
301 24
2
Let a 3iˆ ˆj kˆ and c 2iˆ 3jˆ 3kˆ . If b is a vector such that a b c and b 50, then 72 b c is
2 2
25.
equal to ______.
Sol. 66
| a | 11,| c | 22
| a || b c || b || c | sin θ
11 50 22 sin θ
1
sin θ
10
| b c | | b |2 | c |2 2b c
2
| b |2 | c |2 2 | b || c | cos θ
99
50 22 2 50 22
10
72 66
2
72 b c 66
y2 x 2
26. Let m1 , and m 2 be the slopes of the tangents drawn from the point P(4,1) to the hyperbola H: 1. If
25 16
Q is the point from which the tangents drawn to H have slopes m1 and m 2 and they make positive intercepts
PQ
2
P : (4, 1)
PQ 2 128
PQ 2 128
8
16
5 5 8
27. Let the image of the point , , in the plane x – 2y + z – 2 = 0 be P. If the distance of the point Q(6, –2,
3 3 3
), > 0, from P is 13, then is equal to ______.
Sol. 15
5 5 8
Image of point , ,
3 3 3
5 5 8 5 8 8
x y z 2 1 (2) 1 2
3 3 3 3 3 3
1 2 1 1 2 1
2 2 2
1
3
x 2, y 1, z 3
132 6 2 2 1 3
2 2 2
put k 2 and x = 3
3
S2 (3) C2 (3) 2S1 (t)dt ……(1)
0
x
Also, S1 ( x) C1 ( x) S0 (t )dt
0
2
x
C1 x
2
t2
3
S2 (3) 3C2 2 C1t dt
0
2
3C2 9C1 9
Also,
1
1
C1 1 S0 ( x)dx
0
2
1
C2 1 S1 ( x)dx 0
0
1
C3 1 S2 ( x)dx
0
1
x3 3
1 C2 x C1 x dx
2
0
3 4
x
S2 ( x) C2 x 2S1 (t )dt
0
x3
C2 x C1 x 2
3
S2 3 6C3 6C3 3C2 9C1 9 18
x 1 x
29. If S x R : sin 1 sin 1 , then
x 2x 2 x 1 4
2 2
is equal to _________.
Sol. 4
( x 1) x π
sin 1 sin 1
( x 1)2 1
2
4
x 1
t
(1,1)
t 1
2
(x 1) x π
sin 1 sin 1
(x 1) 1
2
2
4
x 1
( x 1) 1 x 1 x
cos sin 1
( x 1) 2 1 2
x 1 2 x2 1
2
1 1 x
2
2 x 1 x2 1
( x 1) 1 1 x
( x 1) 2 1 2 x2 1
5π 5π
sin cos(5π ) sin cos(5π ) = 4
2 2
30. The number of seven digit positive integers formed using the digits 1, 2, 3 and 4 only and sum of the digits
equal to 12 is _______.
Sol. 413
x1 x2 x3 x4 x5 x6 x7 12, xi {1, 2,3, 4}
5 7 1 7! 7!
No. of solutions C7 1 413
6! 5!
SECTION - A
31. Different combination of 3 resistors of equal resistance R are shown in the figures. The increasing order for
power dissipation is:
(A) (B)
(C) (D)
(1) PC < PB < PA < PD (2) PC < PD < PA < PB (3) PB < PC < PD < PA (4) PA < PB < PC < PD
Sol. (1)
Power dissipation, P = I2R
R 3R
(A) R eq R
2 2
(2 R)(R) 2R
(B) R eq
2R R 3
R
(C) R eq
3
(D) R eq 3R
RD > RA > RB > RC
Since, P Req
PD > PA > PB > PC
32. For the following circuit and given inputs A and B, chose the correct option for output 'Y'
(1) (2)
(3) (4)
Sol. (3)
AAA
A
Y
BBB
B
Output, y A.B A B
yAB
t1 to t2 , A = 0, B = 1, Y = 0
t2 to t3 A=1, B = 1, Y = 1
t3 to t4 A = 0, B = 0, Y = 1
t4 to t5, A = 1, B = 1, Y = 1
t5 to t6, A = 1, B = 0, Y = 1
After t6, A = 0, B = 0, Y = 1
33. A bullet of 10 g leaves the barrel of gun with a velocity of 600 m/s. If the barrel of gun is 50 cm long and mass
of gun is 3 kg, then value of impulse supplied to the gun will be:
(1) 12 Ns (2) 6 Ns (3) 3 Ns (4) 36 Ns
Sol. (2)
Impulse, | I || p |
= mV – 0
= (10 × 10–3 kg) (600 m/s)
I = 6 N–S
34. Which of the following Maxwell's equation is valid for time varying conditions but not valid for static
conditions:
(1) D.dA Q (2) E.dl B (3) E.dl 0 (4) B.dl 0 I
t
Sol. (2)
For static conditions
E.d l 0
For time varying condition,
B
E.d l – t
35. Match List – I with List – II
List – I List – II
(Layer of atmosphere) (Approximate height over earth's surface)
(A) F1 – Layer (I) 10 km
(B) D – Layer (II) 170 – 190 km
(C) Troposphere (III) 100 km
(D) E – layer (IV) 65 – 75 km
Choose the correct answer from the options given below:
(1) A – II, B – I, C – IV, D – III (2) A – II, B – IV, C – III, D – I
(3) A – II, B – IV, C – I, D – III (4) A – III, B – IV, C – I, D – II
Sol. (3)
F1 Lower part of F layer of ionosphere (170 – 190Km)
D Lowest layer of ionosphere (65 – 75 Km)
Troposphere Lowest layer of atmosphere (10 Km)
E Middle part of ionosphere (100 Km)
1
5 2
36. The rms speed of oxygen molecule in a vessel at particular temperature is 1 , where is the average
x
22
speed of the molecule. The value of x will be: (Take = )
7
(1) 28 (2) 27 (3) 8 (4) 4
Sol. (1)
3RT
Vrms
M
8RT
Vavg
M
3
Vrms
8
1/ 2
3 22 33
Vrms
8 7 28
1/ 2
5
Vrms 1
28
x = 28
3 x
37. The ratio of powers of two motors is , that are capable of raising 300 kg water in 5 minutes and 50 kg
x 1
water in 2 minutes respectively from a well of 100 m deep. The value of x will be
(1) 16 (2) 2 (3) 4 (4) 2.4
Sol. (1)
Work
P
Time
mgh (300)g(100)
P1
t1 5
(50)g(100)
P2
2
P1 600 12 3 4
P2 250 5 4 1
P1 3 16
P2 16 1
x = 16
38. Two trains 'A' and 'B' of length 'l' and '4l' are travelling into a tunnel of length 'L' in parallel tracks from opposite
directions with velocities 108 km/h and 72 km/h, respectively. If train 'A' takes 35s less time than train 'B' to
cross the tunnel then, length 'L' of tunnel is:
(Given L = 60 l)
(1) 2700 m (2) 1800 m (3) 1200 m (4) 900 m
Sol. (2)
L
A
4 L
B
5
VA 108 30m / s
18
5
VB 72 20m / s
18
L 4 L
TA ,TB
30 20
TA TB 35
L 4 L
35
30 20
Given, L = 60
61 64
35
30 20
192 122
35
60
70 60 35
30m
L 60 1800m
39. Two bodies are having kinetic energies in the ratio 16 : 9. If they have same linear momentum, the ratio of their
masses respectively is:
(1) 16 : 9 (2) 4 : 3 (3) 9 : 16 (4) 3 : 4
Sol. (3)
P2
Kinetic energy, KE
2m
k1 m 2
k 2 m1
16 m 2
9 m1
m1 9
m 2 16
40. The figure shows a liquid of given density flowing steadily in horizontal tube of varying cross – section. Cross
sectional areas at A is 1.5 cm2, and B is 25 mm2, if the speed of liquid at B is 60 cm/s then (PA – PB) is:
(Given PA and PB are liquid pressures at A and B points)
Density = 1000 kg m–3
A and B are on the axis of tube
41. 238
92 A 234
90 B 24 D Q
In the given nuclear reaction, the approximate amount of energy released will be:
2
[Given, mass of 238
92 A = 238.05079 × 931.5 MeV/c ,
2
mass of 234
90 B = 234.04363 × 931.5 MeV/c ,
42. A disc is rolling without slipping on a surface. The radius of the disc is R. At t = 0, the top most point on the
disc is A as shown in figure. When the disc completes half of its rotation, the displacement of point A from its
initial position is
2R
A′
πR
Displacement = A ' A
A 'A ( R) 2 (2R) 2
A 'A R 2 4
43. Which graph represents the difference between total energy and potential energy of a particle executing SHM
vs it's distance from mean position?
(1) w (2)
(3) (4)
Sol. (2)
Total energy in SHM = E
E=K+U
E–U=K
1
E – U = m2 (A 2 x 2 )
2
E–U
–A 0 +A
x
44. Two charges each of magnitude 0.01 C and separated by a distance of 0.4 mm constitute an electric dipole. If
the dipole is placed in an uniform electric field ' E ' of 10 dyne/C making 30° angle with E , the magnitude of
torque acting on dipole is
(1) 1.5 × 10–9 Nm (2) 2.0 × 10–10 Nm (3) 1.0 × 10–8 Nm (4) 4.0 × 10–10 Nm
Sol. (2)
Dipole moment, P = qd
P = 0.01 × 0.4 × 10–3
P = 4 × 10–6 C-m
Torque, pE sin
4 10 6 (10 10 5 ) sin 30
4 10 10 N m
45. Under isothermal condition, the pressure of a gas is given by P = aV–3, where a is a constant and V is the volume
of the gas. The bulk modulus at constant temperature is equal to
P
(1) (2) 2P (3) P (4) 3P
2
Sol. (4)
P aV 3
dP
3aV 4
dV
dP
Bulk modulus, B V
dV
3a
B V 4
V
a
B 3 3 3P
V
46. A planet having mass 9 Me and radius 4Re, where Me and Re are mass and radius of earth respectively, has
escape velocity in km/s given by:
(Given escape velocity on earth Ve = 11.2 × 103 m/s)
(1) 11.2 (2) 67.2 (3) 33.6 (4) 16.8
Sol. (4)
2GM
Escape velocity, ve
R
2G(9m e ) 3
Vp = = (Ve)earth
4Re 2
3
vp 11.2 km / s
2
vp 16.8 km / s
47. A body of mass (5 0.5) kg is moving with a velocity of (20 ± 0.4) m/s. Its kinetic energy will be
(1) (1000 ± 140) J (2) (500 ± 140) J (3) (500 ± 0.14) J (4) (1000 ± 0.14) J
Sol. (1)
1
Kinetic energy, KE mv 2
2
1
KE 5 20 2
2
KE 1000 J
K m 2 v
K m v
K 0.5 0.4
2
1000 5 20
K 1000(0.1 0.04)
K 1000 0.14
K 140 J
KE (1000 140) J
48. The difference between threshold wavelengths for two metal surfaces A and B having work function A = 9 eV
and B = 4.5 eV in nm is:
{Given, hc = 1242 eV nm}
(1) 276 (2) 264 (3) 540 (4) 138
Sol. (4)
hc
1242
A 138 nm
9
1242
B 276 nm
4.5
B – A 276 138 138 nm
50. A vessel of depth 'd' is half filled with oil of refractive index n1 and the other half is filled with water of refractive
index n2. The apparent depth of this vessel when viewed from above will be -
d(n1 n 2 ) d n1n 2 d n1n 2 2d(n1 n 2 )
(1) (2) (3) (4)
2n1n 2 n1 n 2 2 n1 n 2 n1 n 2
Sol. (1)
d d n 2d
n
app 1
2n1
2 1
n2
d
d
d
app 1
2
app 2
n2
n2 d
1
1 2
n
n2
n1 n 2 d
d
app 2
2n1n 2
SECTION – B
51. When a resistance of 5 is shunted with a moving coil galvanometer, it shows a full scale deflection for a
current of 250 mA, however when 1050 resistance is connected with it in series, it gives full scale deflection
for 25 volt. The resistance of galvanometer is __________ .
Sol. (50)
For ammeter,
Ig (G) (250 Ig )5
1250
Ig mA
5G
For voltmeter,
V Ig R
25 Ig (G 1050)
From equation (1),
1250 10 3
25 (G 1050)
G5
20(G 5) G 1050
19 G = 1050 – 100
950
G 50
19
52. The radius of 2nd orbit of He+ of Bohr's model is r1 and that of fourth orbit of Be3+ is represented as r2. Now the
r2
ratio is x : 1. The value of x is __________
r1
Sol. (2)
n2
r
Z
2
r2 n 2 z1
r1 n1 z 2
2
r2 4 2
r1 2 4
r2
2
r1
x2
53. A solid sphere is rolling on a horizontal plane without slipping. If the ratio of angular momentum about axis
of rotation of the sphere to the total energy of moving sphere is : 22 the, the value of its angular speed will
be rad/s.
Sol. (4)
Angular momentum,
L I
2
L MR 2
5
1 1
Energy MV 2 I2
2 2
1 12
E M( R) 2 MR 2 2
2 2 5
7
M2 R 2
10
L 4
E 7 22
88 88
4 rad / s
7 22
7
7
54. A fish rising vertically upward with a uniform velocity of 8 ms –1, observes that a bird is diving vertically
4
downward towards the fish with the velocity of 12 ms–1. If the refractive index of water is , then the actual
3
velocity of the diving bird to pick the fish, will be ______________ ms–1.
Sol. (3)
dapp d1 d
vapp v1 v
4
12 8 v
3
4
4 v
3
v 3m / s
55. The elastic potential energy stored in a steel wire of length 20 m stretched through 2 cm is 80 J. The cross
sectional area of the wire is ___________ mm2.
(Given, y = 2.0 × 1011 Nm–2)
Sol. (40)
1
Energy, U kx 2
2
1
80 k(2 10 2 ) 2
2
160
k
4 10 4
k 4 10 5 N / m
yA
4 105
4 105 20
A
2 1011
A 40 106 m 2
A 40mm 2
56. From the given transfer characteristic of a transistor in CE configuration, the value of power gain of this
configuration is 10x, for RB = 10 k , RC = 1 k . The value of x is ______________
Sol. (3)
IC
Current gain,
I B
10mA
100A
100
RC
Power gain 2
RB
1
10 4
10
103
So, x 3
Ea
57. In the given figure, an inductor and a resistor are connected in series with a batter of emf E volt. J/s
2b
represents the maximum rate at which the energy is stored in the magnetic field (inductor). The numerical value
b
of will be _____________
a
Sol. (25)
1 2
U LI
2
I I 0 1 e t /
dU
Rate of energy, P
dt
dI
P LI
dt
dP d 2 I dI 2
L I 2
dt dt dt
dP
For maximum rate, 0
dt
2
d2I dI
I ….. (1)
dt
2
dt
I I 0 1 e t /
dI I0 t /
e
dt
d2I I
02 e t /
dt 2
By equation (1),
I 0 t / I 02 2 t /
I 0 1 e t / e 2 e
2
Let e t / x
x x2 x2
1
x
2
Maximum power,
dI
P LI
dt
1 I 1
P L I0 1 0
2 2
L I 02 I2 R
P 0
L 4
4
R
E2
P
4R
a 2, 2b 4R
b 2R 50
b
25
a
58. A potential Vo is applied across a uniform wire of resistance R. The power dissipation is P 1. The wire is then
cut into two equal halves and a potential of Vo is applied across the length of each half. The total power
dissipation across two wires is P2. The ratio P2 : P1 is x :1 . The value of x is _______________
Sol. (16)
v2
P1 0
R
v 02 v2
P2 0
R R
2 2
P2 4P1
P2 4 x
P1 1 1
x 16
59. At a given point of time the value of displacement of a simple harmonic oscillator is given as y = A cos (30°).
If amplitude is 40 cm and kinetic energy at that time is 200 J, the value of force constant is 1.0 × 10x Nm–1. The
value of x is ___________
Sol. (4)
v A2 x 2
3
y A
2
3A 2 A
v A2
4 2
Given, KE 200 J
1 2 A 2
m 200
2 4
KA 2 1600 K m
2
1600
K
40 10 2 2
K 10 4 N / m
x4
60. A thin infinite sheet charge and an infinite line charge of respective charge densities + and + are placed
3 4
parallel at 5 m distance from each other. Points 'P' and 'Q' are at m and m perpendicular distances from
line charge towards sheet charge, respectively. 'EP' and 'EQ' are the magnitudes of resultant electric field
E 4
intensities at point 'P' and 'Q' respectively. If P for 2 | | = | |, then the value of a is ___________
EQ a
Sol. (6)
λ
σ 4
+ m
+ π
+ +
+ +
+ + Q P
+
+ +
+ 3
π
m
5m
2K
EP –
r 2 0
EP
2 0 3
2 0
2 2
EP
20 60 60
2
Similarly, E Q
2 0 4 0
4
2 0
EP 4
EQ 6
a=6
SECTION - A
61. Given below are two statements :
Statement I: Permutit process is more efficient compared to the synthetic resin method for the softening of
water.
Statement II: Synthetic resin method results in the formation of soluble sodium salts.
In the light of the above statements, choose the most appropriate answer from the options given below:
(1) Both the Statements I and II are correct
(2) Statement I is incorrect but Statement II is correct
(3) Statement I is correct but Statement II is incorrect
(4) Both the Statements I and II are incorrect
Sol. 4
Nowadays hard water is softened by using synthetic ion exchangers. This method is more efficient than zeolite
process/Permutit process
63. The energy of an electron in the first Bohr orbit of hydrogen atom is –2.18 10 –18 J . Its energy in the third Bohr
orbit is__________.
1 1
(1) of this value (2) th of this value
27 9
(3) One third of this value (4) Three times of this value
Sol. 2
E1,1 = –2.18 × 10–18 J
12
E 3,1 E1,1
32
1
E 3,1 E1,1
9
64.
In the above reaction, left hand side and right hand side rings are named as ' A ' and ' B ' respectively. They
undergo ring expansion. The correct statement for this process is:
(1) Finally both rings will become six membered each.
(2) Ring expansion can go upto seven membered rings
(3) Finally both rings will become five membered each.
(4) Only A will become 6 membered.
Sol. 1
‘B’ is:
(1) (2)
(3) (4)
Sol. 3
CH3
2- methylpentane
(major)
69. 2-Methyl propyl bromide reacts with C2H5 O– and gives 'A' whereas on reaction with C2 H5OH it gives 'B'. The
mechanism followed in these reactions and the products 'A' and 'B' respectively are :
(1) SN 1, A= tert-butyl ethyl ether; SN1, B= 2-butyl ethyl ether
(2) SN2, A= 2-butyl ethyl ether; SN2, B= iso-butyl ethyl ether
(3) SN2, A= iso-butyl ethyl ether; SN1, B= tert-butyl ethyl ether
(4) SN1, A= tert-butyl ethyl ether; SN2, B= iso-butyl ethyl ether
Sol. 3
‘A’ is
(1) (2)
(3) (4)
Sol. 2
73. The pair of lanthanides in which both elements have high third - ionization energy is:
(1) Dy, Gd (2) Eu,Gd (3) Lu,Yb (4) Eu,Yb
Sol. 4
Eu 2 :[Xe]4f 7
14
2
High IE due to half filled & fully filled configurations
Yb :[Xe]4f
78. The incorrect statement from the following for borazine is:
(1) It is a cyclic compound. (2) It has electronic delocalization.
(3) It can react with water. (4) It contains banana bonds.
Sol. 4
Borazine is B3N3H6
79. Among the following compounds, the one which shows highest dipole moment is
(1) (2)
(3) (4)
Sol. 2
Among the given compounds, the following compound has the highest dipole moment because both the +ve
and -ve ends acquire aromaticity.
80. Be(OH)2 reacts with Sr(OH)2 to yield an ionic salt. Choose the incorrect option related to this reaction from the
following :
(1) Be is tetrahedrally coordinated in the ionic salt.
(2) The reaction is an example of acid - base neutralization reaction.
(3) The element Be is present in the cationic part of the ionic salt.
(4) Both Sr and Be elements are present in the ionic salt.
Sol. 3
Be(OH)2 is amphoteric in nature.
Sr(OH)2 is basic in nature.
These two undergo acid – base reaction to form a salt.
Be(OH) 2 Sr(OH) 2 Sr[Be(OH) 4 ]
(salt)
SECTION - B
81. Solution of 12 g of non-electrolyte (A) prepared by dissolving it in 1000 mL of water exerts the same osmotic
pressure as that of 0.05M glucose solution at the same temperature. The empirical formula of A is CH 2O. The
molecular mass of A is____________ g. (Nearest integer)
Sol. 240
= glucose
CART = CRT
12 / M A
0.05
1
12 1200
MA(Molar mass of A) = 240gm
0.05 5
82. KMnO4 is titrated with ferrous ammonium sulphate hexahydrate in presence of dilute H2SO4. Number of water
molecules produced for 2 molecules of KMnO4 is_________.
Sol. 68
2KMnO4 + 8H2SO4 + 10FeSO4·(NH4)2 SO4·6H2O K2SO4 + 2MnSO4 + 5 Fe2(SO4)3 + 10 (NH4)2SO4 + 68H2O
On the basis of above equation,
68 molecules of water will be produced from 2 molecules of KMnO4.
83. 20 mL of calcium hydroxide was consumed when it was reacted with 10 mL of unknown solution of H 2SO4.
Also 20 mL standard solution of 0.5MHCl containing 2 drops of phenolphthalein was titrated with calcium
hydroxide, the mixture showed pink colour when burette displayed the value of 35.5 mL whereas the burette
showed 25.5 mL initially. The concentration of H2SO4 is____________ M.(Nearest integer)
Sol. 1
miliequivalent of Ca(OH)2 = miliequivalent of H2SO4
M1 × 2 × 20 = M2 × 2 × 10
2M1 M 2
miliequivalent of HCl = miliequivalent of Ca(OH)2
20 × 0.5 = 10 × M1 × 2
M1 = 0.5 M
Concentration of H2SO4 = M2 = 2M1
= 2 × 0.5
=1M
84. t 87.5 is the time required for the reaction to undergo 87.5% completion and t50 is the time required for the reaction
to undergo 50% completion. The relation between t 87.5 and t 50 for a first order reaction is ____________ t 87.5
= x × t 50 . The value of x is____________ . (Nearest integer)
Sol. 3
t t t
A0 1/2 A0/2 1/2 A0/4 1/2 A0/8
85. A certain quantity of real gas occupies a volume of 0.15 dm3 at 100 atm and 500 K when its compressibility
factor is 1.07 . Its volume at 300 atm and 300 K (When its compressibility factor is 1.4 ) is × 10 –4 dm 3 . (Nearest
integer)
Sol. 392
PV
Z
nRT
Z1 P1V1 nRT2
Z 2 nRT1 P2 V2
1.07 100 0.15 300
1.4 500 300 V2
0.03 1.4
V2 0.03925
1.07
= 392 × 10–4 dm3
86. A metal surface of 100cm 2 area has to be coated with nickel layer of thickness 0.001 mm. A current of 2A was
passed through a solution of Ni(NO 3 ) 2 for 'x' seconds to coat the desired layer. The value of x is____________.
(Nearest integer)
( Ni (density of Nickel) is 10 g mL–1 , Molar mass of Nickel is 60 g mol –1 F = 96500 C mol –1 )
Sol. 161
Volume of nickel required = 100 × 0.001 × 10–3 × 100
= 0.01 cm3
Mass of Nickel required = 0.01 × 10
= 0.1 gm
0.1 1
Moles = mol
60 600
Ni2+ + 2e– Ni(s)
for coating of 1 mol Ni, charge required = 2 × 96500 C
1 1
for coating of mol, charge required = 2 96500 C
600 600
965
= C
3
q
I
t
965
t= 3 = 160.83 sec 161
2
87. 25.0 mL of 0.050 MBa(NO3)2 is mixed with 25.0 mL of 0.020 M NaF. Ksp of BaF2 is 0.5 10 –6 at 298 K. The
ratio of [Ba 2 ][F– ]2 and K sp is_______________. (Nearest integer)
Sol. 5
25 0.05
Ba 2 0.025M
50
25 0.02
F– 0.01M
50
2
Ba 2 F – 25 10 7
K sp 5 10 –7 (given)
2
Ba 2 F –
Ratio 5
K sp
88. A 2 B 2 2AB . H0f –200kJ mol –1 new line AB, A 2 and B 2 are diatomic molecules. If the bond enthalpies
of A 2 , B 2 and AB are in the ratio 1 : 0.5:1, then the bond enthalpy of A 2 is _________kJ mol –1 . (Nearest
integer)
Sol. 800
A2 + B2 2AB H f –200kJ / mol
Bond enthalpy of A2 = x
Bond enthalpy of B2 = 0.5 x
Bond enthalpy of AB = x
H f = x + 0.5 x – 2x = –2(200)
–0.5x = – 400
400
x= 800kJ / mol
0.5
Bond enthalpy of A2 = x = 800 kJ/mol
89. An organic compound gives 0.220 g of CO2 and 0.126 g of H2O on complete combustion. If the % of carbon is
24 then the % of hydrogen is ____________ 10 –1 . ( Nearest integer)
Sol. 56
0.220
12
% of carbon = 44 100
x
(x = mass of organic compound)
6
24
x
x = 0.25 gm
0.126
2 1
% of H = 18 100
0.25
= 5.6 = 56 × 10–1
90. For the given reaction
(1)
3
4
4 2 1 (2) 4 2 1
4
3
(3)
3
4
4 2 1 (4)
4
3
4 2 1
Sol. (2)
0
–2 0 2
–2
2 4
4
Required area = 2 ydy 4 ydy 4 2 1
1 2 3
cxe cx
eax cos bx
2. If lim 2 17 , then 5a2+b2 is equal to
x 0 1 cos 2x
(1) 76 (2) 72 (3) 64 (4) 68
Sol. (4)
cxecx
eax cos bx
lim 2 17
x 0 1 cos 2x
On expansion
(ax) 2 (bx) 2 cx (cx) 2
1 ax ... 1 ... 1 cx
lim 2! 2! 2 2!
17
x 0 1 cos 2 x
(2 x)
2
2
(2x)
c a 2 b2 c2
x a x2
2 2 2 2
lim 17
x 0 1 2
(4x )
2
For limit to be exist
c
a 0 c 2a
2
a 2 b 2 c2
2 2 2 17
2
a 2 b 2 4a 2
34
2 2 2
5a 2 b2 68
x 3 y 1 z 5
3. The line, that is coplanar to the line , is
3 1 5
x 1 y 2 z 5 x 1 y 2 z 5
(1) (2)
1 2 5 1 2 5
x 1 y 2 z 5 x 1 y 2 z 5
(3) (4)
1 2 4 1 2 4
Sol. (1)
Condition of co-planarity
x 2 x1 a 1 a 2
y 2 y1 b1 b 2 0
z 2 z1 c1 c 2
Where a1, b1, c1 are direction cosine of 1st line and a2, b2, c2 are direction cosine of 2nd line.
Now. Solving options
Point (-3, 1, 5) & point (-1, 2, 5)
3 1 5
1 1 2 5
2 1 0
= –3(5) – (10) + 5(– 1 + 4)
= – 15 – 10 + 15 = – 10
(2) point (–1, 2, 5)
3 1 5
1 2 5
2 1 0
= 3(5) – (10) + 5(1 + 4)
– 25 + 5 = 0
(3) point (-1, 2, 5)
3 1 5
1 2 4
2 1 0
–3(4) – (8) + 5(1 + 4)
–12 –8 + 25 = 5
(4) point (–1, 2, 5)
3 1 5
1 2 5
4 1 0
–3(–5) – (–20) + 5(–1 – 8)
15 + 20 – 45=–10
4. The plane, passing through the points (0, -1, 2) and (-1, 2, 1) and parallel to the line passing through (5,1,-7)
and (1,-1,-1), also passes through the point
(1) (0, 5, -2) (2) (-2, 5, 0)
(3) (2, 0, 1) (4) (1, -2, 1)
Sol. (2)
Plane passing through (0, –1, 0) and (–1, 2, 1)
Then vector in plane 1,3, 1 vector parallel to plane is 4,2, 6
ˆi ˆj kˆ
Normal vector to plane n 1 3 1
4 2 6
C B
< α, β, γ >
CA AB CB
4,3, . 2,1,3 CB
CB 2, 4,3
ˆi ˆj kˆ
AB AC 2 1 3
4 3
ˆ 9 ˆj 2 12 k 10
AB AC 9 2 12 10
2 2 2 2
1 2 3
6. Let for A= 3 1 , A 2. If |2 adj (2 adj (2A))| = 32n, then 3n + is equal to
1 1 2
(1) 10 (2) 9 (3) 12 (4) 11
Sol. (4)
|A| = 2
adj(kA) = km–1 adjA {m = order of matrix}
2
adj(2A) = 2 adjA = 4adj(A)
adj (2adj (2A)) = adj (8adj A)
= 82 adj adj (A)
|2 adj 2adj (2A)| = |27 adj adj (A)|
2
= (27 )3 | A |2
= 221 | A |4
= 221.24
225 (32) n
225 25n
n=5
|A| = 2
(6 1) 2(2 1) 3( 3) 2
5 4 2 3 9
4
3n 11
x2
7. The range of f(x) = 4 sin-1 2 is
x 1
(1) [0, π) (2) [0, π] (3) [0, 2π) (4) [0, 2π]
Sol. (3)
x2
f (x) 4sin 1 2
1 x
x2
0 1
1 x2
x2
0 sin 1 2
1 x 2
x2
0 4sin 1 2
2
1 x
Range : [0,2)
8. Let a1, a2, a3, .... be a G. P. of increasing positive numbers. Let the sum of its 6th and 8th terms be 2 and the
1
product of its 3rd and 5th terms be . Then 6(a2 + a4) (a4+ a6) is equal to
9
(1) 2 (2) 3 (3) 3 3 (4) 2 2
Sol. (2)
1
a 3 .a 5
9
1
ar 2 .ar 4
9
1
2
ar 3
9
1
ar 3 …(i)
3
a 6 a8 2
ar5 ar 7 2
ar 3 (r 2 r 4 ) 2
1
r 2 (1 r 2 ) 2
3
r 2 (1 r 2 ) 2 3
r2 2 r 2
a 3
3 r
1
3 2 2 6 2
6(a 2 a 4 )(a 4 a 6 )
6(ar ar 3 )(ar 3 ar 5 )
ar 3 1 1 1
6 2 r2 3
r 3 3 3
9. If the system of equations
2x+y -z=5
2x-5y+z=
x+2y-5z=7
has infinitely many solutions, then (+)2 + (-)2 is equal to
(1) 904 (2) 916 (3) 912 (4) 920
Sol. 2
Δ0
2 1 1
2 5 λ 0
1 2 5
2(25 2 λ) 1(10 λ) 1(4 5) 0
51 3x 0
λ 17
Δx 0
5 1 1
5 17 0
7 2 5
5(25 34) 1(5 119) 1(2 35) 0
45 5 119 2 35 0
39 3 0 13
( ) 2 ( ) 2 42 (30) 2
916
p ~ q
P q
~ pq
P q
~ p ~ q
P q
p ~ q ~ p q ~ p ~ q
,
(~ p) (~ q)
Plane passing through 0, 1, 2
and 1,2,1
then vector in plane 1,3, 1
vector parallel to plane is 4, 2, 6
normal vector to plane L 2
ˆl ˆj kˆ
n 1 3 1
4 2 6
7 5
(1) 4 (2) (3) 3 (4)
2 2
Sol. (1)
Let z = x + iy
z i(z 2 Re(z))
x iy i(x 2 y 2 2ixy x)
x iy 2xy i(x 2 y 2 x)
x 2xy 0 and x 2 y 2 x y 0
x(1 2y) 0 and x 2 y 2 x y 0
If x = 0 then y2 y 0
y 1,0
1 1 1
If y then x 2 x 0
2 4 2
3 1
x ,
2 2
3 1 1 1
0 i0,0 i, i, i
2 2 2 2
9 1 1 1
| Z |2 0 1 4
ZS 4 4 4 4
12. Let , be the roots of the equation x2 2x +2=0, Then 14+ is equal to
(1) 128 2 (2) 64 2 (3) –128 (4) –64
Sol. (3)
x2 2x 2 0
2 6
x
2
1 i 3
2
2
2, 22
2, 22
14 14 27 (14 28 ) 27 (2 ) –128
2
13. Let a =2, b = 3 and the angle between the vectors a and b be . Then a 2b 2a 3b is equal to
4
(1) 482 (2) 841 (3) 882 (4) 441
Sol. (3)
a.b
cos
4 a b
1 a.b
a.b 3 2
2 2 3
Let p a 2b
q 2a 3b
2
p a 4 b 4 a.b
2 2
4 36 12 2
40 12 2
2
q 4 a 9 b 12 a b
2 2
16 81 36 2
97 36 2
2
p.q 2 a 6 b a.b
2
8 54 3 2
46 3 2
p q p q p.q
2 2
2
40 12 2 97 36 2 3 2 46
3016 276 2 2134 276 2
882
4
e 4
e x tan 50 xdx
0
14. The value of
is
e tan x tan 51 x dx
4
x
I2 49
0
e x tan 49 x sec 2 x dx
4
0
tan 50 x 4
1 4
e
x x
e tan 50 xdx
50 0
50 0
/4
e 4 1 I1
e
x
tan 50 xdx
50 50 0
50
I1
then 50
I2
5
1
15. The coefficient of x5 in the expansion of 2x 3 2 is
3x
80 26
(1) (2) 8 (3) 9 (4)
9 3
Sol. (1)
5
1
general term for 2x 3 2
3x
r
1
Tr 1 5Cr 2 (2x 3 )5 r
3x
5Cr (1)r 3 r 25r.x155r
15 5r 5 r 2
Coeff. Of x 5 5C2 (1)2 32 23
1
10 8
9
80
=
9
16. The random variable X follows binomial distribution B (n, p), for which the difference of the mean and the
variance is 1. If 2P(x = 2) = 3P(x = 1), then n2P(X > 1) is equal to
(1) 16 (2) 11 (3) 12 (4) 15
Sol. 2
2P(x 2) 3P(x 1)
2 n c 2 P 2 (1 P) n 2 3 n c1P1 (1 P) n 1
n(n 1)
2 P 3n(1 P)
2
(n 1)P 3(1 P) (i)
nP nPq 1
nP nP(1 p) 1
1
nP 2 1 n 2
p
put in equ (i)
1
2 1 P 3(1 p)
p
1
P 3 3P
p
1 P 2 3P 3p 2
2P2 3P 1 0
2P2 2P P 1 0
2P(P 1) 1(P 1) 0
1
P , P 1{Re jected}
2
1
n 4
(1/ 2) 2
n 2 P(x 1) n 2 p(1 P(x 0) P(x 1))
n 2 P 1 (1 P)n nP(1 P)n 1
1 4 2
4
(4) 1 4
2
2 2
16 1 4 11
17. Let the centre of a circle C be (,) and its radius r < 8. Let 3x + 4y =24 and 3x – 4y = 32 be two tangents and
4x + 3y =1 be a normal to C. Then (– +r) is equal to
(1) 5 (2) 6 (3) 7 (4) 9
Sol. (3)
L1
,
L2
3 3
(reject) 7
18. Let N be the foot of perpendicular from the point P (1, –2, 3) on the line passing through the points (4, 5, 8) and
(1, –7. 5). Then the distance of N from the plane 2x–2y+z+5=0 is
(1) 6 (2) 7 (3) 9 (4) 8
Sol. (2)
P 1, 2,3
N ሺℓ + 1, 4ℓ − 7, ℓ + 5ሻ
PN , 4 5, 2
PN. 1, 4,1 0
16 20 2 0
1
N 2, 3,6
Distance of N from 2x 2y z 5 0 is
2 2 2 3 6 5
d
22 2 1
2 2
21
7
3
19. All words, with or without meaning, are made using all the letters of the word MONDAY. These words are
written as in a dictionary with serial numbers. The serial number of the word MONDAY is
(1) 328 (2) 327 (3) 324 (4) 326
Sol. (2)
5!
A 120
5!
D 120
4!
M A 24
4!
M D 24
4!
M N 24
3!
M O A 6
3!
M O D 6
2!
M O N A 2
M O N D A Y 1
Rank = 120 + 120 + 24 + 24 + 24 + 6 + 6 + 2 + 1
= 327
20. Let (, ) be the centroid of the triangle formed by the lines 15x–y = 82, 6x–5y= –4 and 9x + 4y =17. Then
+ 2 and – are the roots of the equation
(1) x2–13x+42=0 (2 )x2–10x+25=0 (3) x2–7x+12=0 (4) x2–14x+48=0
Sol. (1)
A (6,8)
6 1 5 8 7 2
Centroid , , 4,1
3 3
2 4 2 6
2 8 1 7
Quadratic equation
x2 6 7 x 6 7 0
x 2 13x 42 0
SECTION - B
21. Let A={-4,-3,-2,0,1,3,4} and R = {(a, b) A×A: b = |a| or b2 = a+ 1} be a relation on A. Then the minimum
number of elements, that must be added to the relation R so that it becomes reflexive and symmetric, is
_________
Sol. (7)
R = [(–4, 4), (–3, 3), (3, –2), (0, 1), (0, 0), (1, 1),
(4, 4), (3, 3)}
For reflexive, add (–2, –2), (–4, –4), (–3, –3)
For symmetric, add (4, –4), (3, –3), (–2, 3), (1, 0)
n 2
n
22. Let f n sin k 1x 2k 1 sin k 1x cos xdx,n N. Then f21 – f20 is equal to _______
0 k 1 k 1
Sol. (41)
/2 n k 1
n
k 1
fn sin x 2k 1 sin x cosxdx
0
k 1 k 1
sinx t
cos xdx dt
1 n n
fn tk 1 2k 1 tk 1 dt
0
k 1 k 1
1 t t2 ...tn1 1 3t 5t2 .... 2n 1 tn1 dt
1
1 n1 n1
fn1 tk 1 2k 1 tk 1 dt
0
k 1 k 1
1 t t2 ...tn 1 3t 5t2 .... 2n 1 tn dt
1
1 t t2 ...tn1 2n 1 tn dt
1
put n 20
f21 f20 1 3t 5t2 ...41.t20 t20dt 1 t t2 ...t19 41.t20 dt
1 1
0 0
1 3 5 39 41 41 41 41
21 22 23 40 41 21 22 40
1 41 3 41 39 41
... 1 40 1 41
21 22 40
dy 4x x2
23. If y = y(x) is the solution of the differential equation 2 y , x 1 such that
dx x – 1 5
x 2
1 2
2
y 2 log e 2 3 and y 2 log e , Nthen is equal to ___.
9
Sol. (6)
dy 4x x 2
given differential equation 2 y is linear D.E.
dx x 1 x 1
2 5/2
dx e 2ln x 1 e ln x 2 1 x 2 1
4x 2 2
I.F.
e
x 2
1
x 2
y x 2 1 x 1 dx
2 2 2
x 1
2 5/2
x 2dx
dx
x2 1 x2 1
x2 1 2ln x x2 1 C
2
put y 2 ln 2 3
9
2
9
ln 2 3 9 3 2ln 2 3 C
C 3
put x 2
y 1 2ln 2 1 3
2, 1 3
2 1 3 6
24. Total numbers of 3-digit numbers that are divisible by 6 and can be formed by using the digits 1, 2, 3, 4, 5 with
repetition, is _____.
Sol. 16
a b 2
10
26. Let f x k x k , x R If 2 f(2) –f ' (2) = 119(2)n + 1 then n is equal to ____
k 1
Sol. 10
10
f (x) kx k
k 1
x 1 x10
f (x)(1 x) 10x11
1 x
x 1 x10 10x11
f (x)
(1 x)2 (1 x)
f (2) 2 g(2)11
(1 – x)2 f(x) = x(1 – x10) –10x11 (1 – x)
diff. w.r.t. x
(1 x) 2 f (2) f (2)2(1 x)( 1)
28. The mean and standard deviation of the marks of 10 students were found to be 50 and 12 respectively, Later, it
was observed that two marks 20 and 25 were wrongly read as 45 and 50 respectively. Then the correct variance
is ______.
Sol. 269
x
Mean i
10
x
50 i
10
xi 500
correct xi 500 45 50 20 25 450
xi2
2
2 x
10
x 2
144 i 2500
10
xi2 26440
correct xi2 26440 45 50 20 25
2 2 2 2
= 26440-2025-2500+400+625
= 22940
2
correctxi2 correctx i
2
10 10
2
22940 450
= 2294 – 2025
10 10
269
3
29. The foci of a hyperbola are ( 2, 0) and its eccentricity is . A tangent, perpendicular to the line 2x + 3y = 6,
2
is drawn at a point in the first quadrant on the hyperbola. If the intercepts made by the tangent on the x and y -
axes are a and b respectively, then |6a| + |5b| is equal to ______.
Sol. 12
2ae 4
3
2a 4
2
4
a
3
b2
e2 1
a2
9 9
1 b2
4 16
5 16 20
b2
4 9 9
3
slope of tangent m
2
equation of tangent is
y mx a2m2 b2
3 16 9 20
y x
2 9 4 9
3x 4
y
2 3
8
y 0a
9
4
x 0 b
3
16 20
6a 5b 12
3 3
30. Let [] denote the greatest integer . Then 1 2 3 .... 120 is equal to ____.
Sol. 825
S 1 2 3 .... 120
1 3 1 3
4 8 2 5
9 15 3 7
100 120 10 21
S 1 3 2 5 3 7 ... 10 21
10
r(2r 1)
r 1
10 10
2 r2 r
r 1 r 1
2 10 11 21 10 11
6 2
= 770 + 55
= 825
SECTION - A
31. Given below are two statements :
Statements I : An AC circuit undergoes electrical resonance if it contains either a capacitor or an inductor.
Statement II : An AC circuit containing a pure capacitor or a pure inductor consumes high power due to its
non-zero power factor.
In the light of above statements, choose the correct answer form the options given below :
(1) Statement I is false but Statement II is true
(2) Statement I is true but Statement II is false
(3) Both Statement I and Statement II are false
(4) Both Statement I and Statement II are true
Sol. (3)
Statement-I: An AC circuit for resonance inductor and capacitor both should required.
Statement-II: An AC circuit containing a pure capacitor and pure inductor have no power loss
For resonance, = 0
means both capacitor and inductor must be present.
32. A passenger sitting in a train A moving at 90 km/h observes another train B moving in the opposite direction
for 8 s. if the velocity of the train B is 54 km/h, then length of train B is :
(1) 120 m (2) 200 m (3) 320 m (4) 80 m
Sol. (3)
90km
VA 25ms 1
hr
54km
VB 15ms 1
hr
VBA VB VA 40ms 1
Length of train
Time of crossing
Re lative velocity
8
40
8 40 320 meter
33. The output from a NAND gate having inputs A and B given below will be,
(1) (2)
(3) (4)
Sol. (1)
Truth table for NAND gate is
A B Y A.B
0 0 1
0 1 1
1 0 1
1 1 0
On the basis of given input A and B the truth table is
A B Y
1 1 0
0 0 1
0 1 1
1 0 1
1 1 0
0 0 1
0 1 1
34. The distance travelled by an object in time t is given by s = (2.5)t2. The instantaneous speed of the object at t =
5 s will be :
(1) 25 ms-1 (2) 12.5 ms-1 (3) 5 ms-1 (4) 62.5 ms-1
Sol. (1)
S 2.5t 2
ds
Speed v 5t
dt
At, t 5sec.
v 5 5 25ms 1
35. In a Young's double slits experiment, the ratio of amplitude of light coming from slits is 2 : 1. The ratio of the
maximum to minimum intensity in the interference pattern is :
(1) 9 : 1 (2) 9 : 4 (3) 2 : 1 (4) 25 : 9
Sol. (1)
Given that
A1 2
A2 1
I max A1 A 2
2
9
I min A1 A 2 2
1
9 :1
36. Given below are two statements : one is labelled as Assertion A and the other is labelled as Reason R
Assertion A : The binding energy per nucleon is practically independent of the atomic number for nuclei of
mass number in the range 30 to 170.
Reason R : Nuclear force is short ranged.
In the light of the above statements, choose the correct answer from the options given below
(1) Both A and R are true but R is NOT the correct explanation of A
(2) Both A and R are true and R is the correct explanation of A
(3) A is true but R is false
(4) A is false but R is true
Sol. (2)
37. Two planets A and B of radii R and 1.5 R have densities and /2 respectively. The ratio of acceleration due
to gravity at the surface of B to A is :
(1) 2 : 3 (2) 2 : 1 (3) 4 : 3 (4) 3 : 4
Sol. (4)
4
G R 3
GM 3 4
g 2 2
GPR
R R 3
g 2 R 2 2 1 3
1.5
g1 R 1 1 2 4
38. The mean free path of molecules of a certain gas at STP is 1500d, where d is the diameter of the gas molecules.
While maintaining the standard pressure, the mean free path of the molecules at 373 K is approximately :
(1) 750d (2) 1500d (3) 1098d (4) 2049d
Sol. (4)
mean free path
RT
2 d 2 N A P
T
1500d 273
373
2049d
39. To radiate EM signal of wavelength with high efficiency, the antennas should have a minimum size equal to:
(1) (2) (3) 2 (4)
2 4
Sol. (4)
Minimum length of antenna
Should be
4
40. A particle executes SHM of amplitude A. The distance from the mean position when its's kinetic energy
becomes equal to its potential energy is :
1 1
(1) 2A (2) A (3) A (4) 2A
2 2
Sol. (3)
K.E = P.E
1 1
M 2 ( A2 x 2 ) M 2 x 2
2 2
( A2 x 2 ) x 2
2x 2 A2
A
x
2
41. In an electromagnetic wave, at an instant and at a particular position, the electric field is along the negative z
axis and magnetic field is along the positive x-axis. Then the direction of propagation of electromagnetic wave
is :
(1) negative y-axis (2) at 45o angle from positive y-axis
(3) positive y-axis (4) positive z-axis
Sol. (1)
Direction of propagation of EM wave will be in the direction of E B
42. Given below are two statements :
Statement I : Out of microwaves, infrared rays and ultraviolet rays, ultraviolet rays are the most effective for
the emission of electrons from a metallic surface.
Statement II : Above the threshold frequency, the maximum kinetic energy of photoelectrons is inversely
proportional to the frequency of the incident light.
In the light of above statements, choose the correct answer form the options given below
(1) Statement I is false but statement II is true
(2) Both Statement I and Statement II are true
(3) Statement I is true but statement II is false
(4) Both Statement I and Statement II are false
Sol. (3)
UV rays have maximum frequency hence are most effective for emission of electrons from the metallic surface.
KEmax hf hf0
44. A vehicle of mass 200 kg is moving along a levelled curved road of radius 70 m with angular velocity of 0.2
rad/s. The centripetal force acting on the vehicle is:
(1) 2800 N (2) 560 N (3) 2240 N (4) 14 N
Sol. (2)
Fc m2r 200 0.2 70
2
560N
45. A 10 C charge is divided into two parts and placed at 1 cm distance so that the repulsive force between them
is maximum. The charges of the two parts are:
(1) 7 C, 3 C (2) 8 C, 2 C (3) 9 C, 1 C (4) 5 C, 5 C
Sol. (4)
Divide q 10c into parts x and q x
K x q x
F
r2
For F to be maximum
dF
0
dx
q 10C
x = 5 C
2 2
q – x = 10C – 5C = 5 C
a
46. In the equation x 2 [Y – b] = RT, X is pressure, Y is volume, R is universal gas constant ant T is
y
a
temperature. The physical quantity equivalent to the ratio is :
b
(1) Coefficient of viscosity (2) Energy
(3) Impulse (4) Pressure gradient
Sol. (2)
a
x and 2 have same dimensions
y
y and b have same dimensions
a ML5 T 2
b L3
a ML2 T 2
has dimension of energy
b
47. An electron is moving along the positive x-axis. If the uniform magnetic field is applied parallel to the negative
z-axis, then
A. The electron will experience magnetic force along positive y-axis
B. The electron will experience magnetic force along negative y-axis
C. The electron will not experience any force in magnetic field
D. The electron will continue to move along the positive x-axis
E. The electron will move along circular path in magnetic field
Choose the correct answer from the options given below :
(1) B and E only (2) A and E only (3) B and D only (4) C and D only
Sol. (1)
F q V B
F e V B
Force will be along ve y axis As magnetic force is r to velocity, path of electron must be circle.
48. Given below are two statements : one is labelled as Assertion A and the other is labelled as Reason R
Assertion A : A spherical body of radius (5 0.1) mm having a particular density is falling through a liquid
of constant density. The percentage error in the calculation of its terminal velocity is 4%
Reason R : The terminal velocity of the spherical body falling through the liquid is inversely proportional to
its radius.
In the light of the above statements, choose the correct answer from the options given below
(1) Both A and R are true but R is NOT the correct explanation of A
(2) Both A and R true and R is the correct explanation of A
(3) A is false but R is true
(4) A is true but R is false
Sol. (4)
Terminal velocity of a spherical body in liquid
Vt r 2
Vt r
2
Vt r
Vt 0.1
100% 2 100 4%
Vt 5
Also, Vt r 2
Reason (R) is false
49. The initial pressure and volume of an ideal gas are Po and Vo. The final pressure of the gas when the gas is
Vo
suddenly compressed to volume will be :
4
(Given = ratio of specific heats at constant pressure and at constant volume)
1
50. In the network shown below, the charge accumulated in the capacitor in steady state will be :
i1 i1
i2
4𝜇F 6Ω
i1 6Ω i1
In steady state, no current will pass through capacitor hence capacitor will act as open circuit.
i2 = 0
3 3
i1 A
6 4 10
3
Potential difference on 6 resistor 6 1.8 volt capacitor will have same potential so charge
10
cv 4 1.8 7.2c
SECTION - B
51. In an experiment with sonometer when a mass of 180 g is attached to the string, it vibrates with fundamental
frequency of 30 Hz. When a mass m is attached, the string vibrates with fundamental frequency of 50 Hz. The
value of m is _______ g.
Sol. (500)
1 T
f
2
f2 T
2
f1 T1
2
50 mg
30 180g
25
m 180 500gram
9
52. Two plates A and B have thermal conductivities 84 Wm-1 K-1 and 126 Wm-1K-1 respectively. They have same
surface area and same thickness. They are placed in contact along their surfaces. If the temperatures of the outer
surfaces of A and B are kept at 100 oC and 0 oC respectively, then the temperature of the surface of contact in
steady state is ______ oC.
Sol. (40)
A B
TA = 100°C T TB = 0°C
Sol. (75)
A
4Ω
I1
3Ω I2
12v
6𝜇F
C D
9Ω 2Ω
I1
I2
B
12
I1 1A
39
12
I2 2A
42
VA VC 3I1 3V
VA VD 2 4 8V
So, VA VD 5V
1 1
U CV 2 6 52 75J
2 2
54. A light rope is wound around a hollow cylinder of mass 5 kg and radius 70 cm. The rope is pulled with a force
of 52.5 N. The angular acceleration of the cylinder will be ________ rad s-2.
Sol. (15)
I
FR mR 2
F 52.5
15rads 2
mR 5 0.7
55. A straight wire AB of mass 40 g and length 50 cm is suspended by a pair of flexible leads in uniform magnetic
field of magnitude 0.40 T as shown in the figure. The magnitude of the current required in the wire to remove
the tension in the supporting leads is _______A. (Take g = 10 ms-2)
Sol. (2)
For equilibrium :
Mg IlB
Mg 40 10 3 10
I 2A
lB 50 10 2 0.4
56. An insulated copper wire of 100 turns is wrapped around a wooden cylindrical core of the cross-sectional area
24 cm2. The two ends of the wire are connected to a resistor. The total resistance in the circuit is 12 . If an
externally applied uniform magnetic field in the core along its axis changes from 1.5 T in one direction to 1.5 T
in the opposite direction, the charge flowing through a point in the circuit during the change of magnetic field
will be ______ mC.
Sol. (60)
2NBA
Q
R R
2 100 1.5 24 10 4
12
6 102 c
60mc
57. A bi convex lens of focal length 10 cm is cut in two identical parts along a plane perpendicular to the principal
axis. The power of each lens after cut is _______ D.
Sol. (5)
1
P1 P1 P
f
1
2P1
0.1
P1 5D
3
58. Three point charges q, -2q and 2q are placed on x-axis at a distance x = 0, x R and x = R respectively from
4
origin as shown. If q = 2 × 10-6 C and R = 2 cm, the magnitude of net force experienced by the charge -2q is
____N.
Sol. (5440)
3𝑅
4
2q
B c
A
q FBA -2q FBC
32kq 2 64kq 2
FBA FBC
9q 2 R2
544kq 2
FB FBC FBA
9R 2
5440N
59. An atom absorbs a photon of wavelength 500 nm and emits another photon of wavelength 600 nm. The net
energy absorbed by the atom in this process is n × 10-4 eV. The value of n is ______.
[Assume the atom to be stationary during the absorption and emission process]
(Take h = 6.6 × 10-34 Js and c = 3 × 108 m/s)
Sol. (4125)
1 1
E E1 E 2 hc
1 2
E 6.6 1020 J
E 4.125 101 eV
E 4125 10 4 eV
60. A car accelerates from rest to u m/s. The energy spent in this process is E J. The energy required to accelerate
the car from u m/s to 2 u m/s is nE J. The value of n is ______.
Sol. (3)
1 1
E1 mu 2 0 mu 2 E
2 2
1 1
m 24 mu 2
2
E2
2 2
3
mu 2 3E
2
SECTION - A
61. Which of the following are the Green house gases ?
(A) Water vapour (B) Ozone (C) I2 (D) Molecular hydrogen
Choose the most appropriate answer from the options given below :
(1) C and D only (2) A and B only (3) B and C only (4) A and D only
Sol. 2
Green house gases are CO2, CH4, water vapour, nitrous oxide, CFCs and ozone.
(1) (2)
(3) (4)
Sol. 2
63. In the wet tests for detection of various cations by precipitation, Ba2+ cations are detected by obtaining
precipitate of :
(1) Ba(OAc)2 (2) BaCO3 (3) BaSO4 (4) Ba(ox) : Barium oxalate
Sol. 2
In wet testing, (NH4)2CO3 is used as group reagent for 5th group cations (Ba2+, Ca2+, Sr2+)
Ba 2 (NH4 )2 CO3 BaCO3 NH4
(white precipitate)
64. Compound A from the following reaction sequence is :
(1) Phenol (2) Benzoic Acid (3) Aniline (4) Salicylic Acid
Sol. 3
65. Given below are two statements, one is labelled as Assertion A and the other is labelled as Reason R.
Assertion A : Isotopes of hydrogen have almost same chemical properties, but difference in their rates of
reaction.
Reason R : Isotopes of hydrogen have different enthalpy of bond dissociation.
In the light of the above statements, choose the most appropriate answer from the options given below :
(1) A is not correct but R is correct
(2) Both A and R correct but R is NOT the correct explanation of A
(3) Both A and R are correct and R is the correct explanation of A
(4) A is correct but R is not correct
Sol. 3
Source NCERT
Since the isotopes have the same electronic configuration, they have almost same chemical properties. The only
difference is in their rates of reactions, mainly due to their different enthalpy of bond dissociation.
68. Identify the correct order of standard enthalpy of formation of sodium halides.
(1) NaI < NaBr < NaF < NaCl (2) NaF < NaCl < NaBr < Nal
(3) NaCl < NaF < NaBr < Nal (4) Nal < NaBr < NaCl < NaF
Sol. 4
For a given metal fH0 always becomes less negative from fluoride to iodide.
69. Which of the following complexes will exhibit maximum attraction to an applied magnetic field ?
(1) [Zn (H2O)6]2+ (2) [Ni (H2O)6]2+ (3) [Co(en)3]3+ (4) [Co (H2O)6]2+
Sol. 4
Complex with maximum number of unpaired electron will exhibit maximum attraction to an applied magnetic
field
[Zn(H2O)6]2+ d10 system t 62g eg4, 0 unpaired e–
70. The correct group of halide ions which can be oxidized by oxygen in acidic medium is
(1) Cl–, Br– and I– only (2) Br– only (3) Br– and I–only (4) I–only
Sol. 4
Only I– among halides can be oxidised to Iodine by oxygen in acidic medium
4I–(aq) + 4H+(aq) + O2(g) 2I2(s) + 2H2O(l)
71. The total number of stereoisomers for the complex [Cr(ox)2ClBr]3– (where ox = oxalate) is :
(1) 3 (2) 1 (3) 4 (4) 2
Sol. 1
[Cr(Ox)2 ClBr]–3
No. of isomers-
This structure has plane of symmetry, So no optical isomerism will be shown.
This structure does not contain plane of symmetry, So two forms d as well as 1 will be shown.
CH3 – CH2 – CH2 – Br + CH3 – COOAg CH3 – COO – CH 2 – CH2 – CH3 + AgBr
(Ester)
73. The covalency and oxidation state respectively of boron in [BF4]–, are :
(1) 3 and 5 (2) 4 and 3 (3) 4 and 4 (4) 3 and 4
Sol. 2
Number of covalent bond formed by Boron is 4
Oxidation number of fluorine is –1,
Oxidation number of B + 4 × (–1) = –1,
Thus, Oxidation number of B = + 3
74. What happens when methance undergoes combustion in systems A and B respectively ?
(1)
System A System B
Temperature remains same Temperature rises
(2)
System A System B
Temperature falls Temperature rises
(3)
System A System B
Temperature falls Temperature remains same
(4)
System A System B
Temperature rises Temperature remains same
Sol. 4
Adiabatic boundary does not allow heat exchange thus heat generated in container can't escape out thereby
increasing the temperature. In case of Diathermic container, heat flow can occur to maintain the constant
temperature.
75. The naturally occurring amino acid that contains only one basic functional group in its chemical structure is :
(1) histidine (2) lysine (3) asparagine (4) arginine
Sol. 3
1. histidine
2. Lysine
3.
4. Arginine
LIST I LIST II
A. Weak intermolecular farces of attraction I. Hexamethylenendiamine + adipic
B. Hydrogen bonding II. AlEt3 + TiCl4
C. Heavily branched polymer III. 2–chloro –1, 3 – butadiene
D. High density polymer IV. Phenol + formaldehyde
Tropolone is an aromatic compound and has 8 electrons (6e– are endocyclic and 2e– are exocyclic) and
electrons of group in tropolone is not involved in aromaticity.
80. Given below are two statements, one is labelled as Assertion A and the other is labelled as Reason R.
Assertion A : Order of acidic nature of the following compounds is A > B > C.
SECTION - B
81. If the formula of Borax is Na2B4Ox (OH)y. zH2O, then x + y + z = _____.
Sol. 17
Formula of borax is Na2B4O5 (OH)4 · 8H2O
82. Sea water contains 29.25% NaCl and 19% MgCl2 by weight of solution. The normal boiling point of the sea
water is _____°C(Nearest integer)
Assume 100% ionization for both NaCl and MgCl2
Given : Kb(H2O) = 0.52 K kg mol–1
Molar mass of NaCl and MgCl2 is 58.5 and 95 g mol–1 respectivley.
Sol. 116
Amount of solvent = 100 – (29.25 + 19) = 51.75g
2 29.25 1000 3 19 1000
Tb 0.52
58.5 51.75 95 51.75
Tb = 16.075
Tb = (Tb)solution – (Tb)solvent
(Tb)solution = 100 + 16.07
= 116.07°C
83. 20 mL of 0.1 M NaOH is added to 50 mL of 0. 1 M acetic acid solution. The pH of the resulting solution is
____ × 10–2 (Nearest integer)
Given : pKa (CH3 COOH) = 4.76
log 2 = 0.30
log 3 = 0.48
Sol. 458
CH3COOH + NaOH CH3COONa + H2O
Initially 5mmol 2mmol 0 0
after Rxn 3mmol 0 2 mmole 2 mmole
[salt]
pH = pKa + log10
[acid]
2
pH = 4.76 + log10
3
pH = 4.58 = 458 × 10–2
84. At 298 K, the standard reduction potential for Cu2+/Cu electrode is 0.034 V.
Given : Ksp Cu(OH)2 = 1 × 10–20
2.303RT
Take 0.059V
F
The reduction potential at pH = 14 for the above couple is (–) x × 10–2 V.
The value of x is _____.
Sol. 25
Cu(OH)2(s) Cu2+(aq) + 2OH–(aq)
Ksp = [Cu2+] [OH–]2
pH = 14; pOH = 0; [OH–] = 1M
Ksp
[Cu 2 ] 10 –20 M
[1]2
Cu2+(aq) + 2e– Cu(s)
0.059 1
E E – log10
2 [Cu 2 ]
0.059 1
= 0.34 – log10 –20
2 10
–2
= –0.25 = –25 × 10
85. Sodium metal crystallizes in a body centred cubic lattice with unit cell edge length of 4 Å. The radius of
sodium atom is ____×10–1 Å (Nearest integer)
Sol. 17
3a 4r
3 4 4r
r = 1.732Å
= 17.32 × 10–1
86. A (g) 2B (g) + C (g) is first order reaction. The initial pressure of the system was found to be 800 mm Hg
which increased to 1600 mm Hg after 10 min. The total pressure of the system after 30 min will be ____ mm
Hg. (Nearest integer)
Sol. 2200
t 1 = 10 minutes
2
30/10
1
(PA )30 min (PA )0
2
(PA)30 min = 100 mm Hg
A(g) 2B(g) + C(g)
at t = 0 800 mm 0 0
at t = 30 l00 mm 1400 mm 700 mm
Total pressure after 30 minutes = 2200 mm Hg
87. 1g of a carbonate (M2CO3) on treatment with excess HCl produces 0.01 mol of CO2. The molar mass of
M2CO3 is ____ g mol–1. (Nearest integer)
Sol. 100
M2CO3 2HCl 2MCl H2O CO2
1gm Excess 0.02mole 0.01mole
88. 0.400 g of an organic compound (X) gave 0.376 g of AgBr in Carius method for estimation of bromine. % of
bromine in the compound (X) is ____. (Given : Molar mass AgBr = 188 g mol–1, Br = 80 g mol–1)
Sol. 40
0.376
mole of AgBr =
188
0.376
mole of Br– = mole of AgBr =
188
0.376
mass of Br– = 80
188
0.376 80
% of Br– = 100 40%
188 0.4
xh
89. The orbital angular momentum of an electron in 3s orbital is . The value of x is ____ (nearest integer)
2
Sol. 0
h
Orbital angular momentum = 1(1 1)
2
Value of 1 for s = 0
90. See the following chemical reaction :
Cr2 O72– XH 6Fe2 YCr 3 6Fe3 ZH 2O
The sum of X, Y and Z is _____
Sol. 23
Cr2O72– + 14H+ + 6Fe2+ 6Fe3+ + 2Cr3+ + 7H2O
x = 14
y=2
z=7
Hence (x + y + z) = 14 + 2 + 7 = 23
SECTION-A
1. The straight lines 11 and 12 pass through the origin and trisect the line segment of the line L : 9x + 5y = 45
between the axes. If m1 and m2 are the slopes of the lines 11 and 12, then the point of intersection of the line y
= (m1 + m2) x with L lies on.
(1) 6x + y = 10 (2) 6x – y = 15 (3) y – 2x = 5 (4) y – x = 5
Sol. (4)
B 2
Q
1
P
A
L : 9x + 5y = 45
A(5,0) , B : (0,9)
A P Q B
(5,0) (0,9)
2 5 1 0 10
Px
1 2 3
0 2 9 1
Py =3
1 2
10
P : ,3
3
1 5 2 0 5
Similarly → Q x
1 2 3
1 0 2 9
Qy =6
1 2
5
Q: ,6
3
3–0 9
Now m1= =
10 10
–0
3
6 0 18
m2 =
5
0 5
3
9
Now L1 : y (m1 + m2)x y = x 9x = 2y ...(2)
2
from (1) & (2) 9x + 5y = 45
9x – 2y = 0
– + –
45
7y = 45 y
7
10
x
7
which satisfy y – x = 5 Ans. 4
2. Let the position vectors of the points A, B, C and D be 5iˆ 5jˆ 2k,i ˆ ˆ 2jˆ 3k,
ˆ –2iˆ ˆj 4kˆ and
–iˆ 5jˆ 6k.
ˆ Let the set S { : the points A, B, C and D are coplanar}. Then ( 2) 2 is equal to :
S
37
(1) (2) 13 (3) 25 (4) 41
2
Sol. (4)
A, B, C, D are coplanar
–4 –3 3 – 2
ABACAD = 0 –7 – 5 4 – 2 = 0
–6 0 6 – 2
s
x 2 x sec2 x tan x
3. Let I(x) dx . If I(0) = 0, then I is equal to :
x tan x 1
2
4
( 4) 2
2 ( 4)2 2
(1) log e (2) log e –
16 4( 4) 32 4( 4)
( 4)2 2 ( 4)2 2
(3) log e – (4) log e
16 4( 4) 32 4( 4)
Sol. (2)
Ix
x 2 xsec2 x tanx dx
xtanx 1
2
Let xtan x + 1 = t
1 2x
I x2 dx
x tan x 1 x tan x 1
1 2x
I x2 2 dx
x tan x 1 x tan x 1
1
I x2 2ln x sin x cos x C
x tan x 1
As I (0) = 0 C = 0
4 2 2
I ln
4 32 4 4
20.21.41 3.20.21
S20 = + + 20
6 2
S20 = 2870 + 630 + 20
S20 = 3520
5. A pair of dice is thrown 5 times. For each throw, a total of 5 is considered a success. If probability of at least 4
k
successes is 11 , then k is equal to :
3
(1) 164 (2) 123 (3) 82 (4) 75
Sol. (2)
n(total 5) = {1, 4), (2, 3), (3, 2),(4, 1)} = 4
4 1
P(success) = =
36 9
P(at least 4 success) = P (4 success) + P(5 success)
4
1 8
5
= 5C4. . + 5C5 = 5 = 10 = 11 = 11
1 41 41 123 k
9 9 9 9 3 3 3
K = 123
6. Let A = [aij]2×2, where aij 0 for all i, j and A2 = I. Let a be the sum of all diagonal elements of A and b = |A|.
Then 3a2 + 4b2 is equal to :
(1) 14 (2) 4 (3) 3 (4) 7
Sol. (2)
A2 = I |A|2 = 1 |A| = ±1 = b
Let A =
A2 = =I
2 1 0
2
= 2 + = 1
0 1
( + ) = 0 + = 0 = a
( + ) = 0
+ 2 = 0
Now 3a2 + 4b2 = 3(0)2 + 4 (1) = 4
7. Let a1, a2, a3, …., an be n positive consecutive terms of an arithmetic progression. If d > 0 is its common
d 1 1 1
difference, then : lim ....... is
n n a1 a 2 a 2 a3 a n –1 a n
1
(1) (2) 1 (3) d (4) 0
d
Sol. (2)
d a1 – a 2 a – a3 a – an
Lt 2 ...... n –1
n n a1 – a 2 a2 – a3 a n –1 – a n
d a1 – a 2 a 2 a 3 ...... a n–1 – a n
= Lt
n n –d
d a n – a1
= Lt
n n d
1 a1 (n – 1)d – a1
= Lt
n n d
1 a1 d a
= Lt d– – 1
n d n n n
=1
9. Let A = {x : [x + 3] + [x + 4] 3},
x –3
x 3
B x :3 r
3–3x. , where [t] denotes greatest integer function. Then,
r 1 10
x 3
3
3x r 33x
r 1 10
x 3
1
32x 3 10 33x
1 1
10
x 3
1
35x 3
9
36 2x 335x
6 2x 3 5x
3 3x
x 1 ...(B)
A=B
10. One vertex of a rectangular parallelepiped is at the origin O and the lengths of its edges along x, y and z axes
are 3, 4 and 5 units respectively. Let P be the vertex (3, 4, 5). Then the shortest distance between the diagonal
OP and an edge parallel to z axis, not passing through O or P is :
12 12 12
(1) (2) 12 5 (3) (4)
5 5 5 5
Sol. (3)
x y z
Equation of OP is
3 4 5
a1 = (0, 0, 0) a2 = (3, 0, 5)
b1 = (3, 4, 5) b2 = (0, 0, 1)
Equation of edge parallel to z axis
x 3 y0 z 5
0 0 1
a 2 a1 b1 b2
S.D
b1 b2
3 0 5
3 4 5
0 0 1 3 4 12
i j kˆ 4i 3j 5
3 4 5
0 0 1
11. If the equation of the plane passing through the line of intersection of the planes 2x – y + z = 3, 4x – 3y + 5z +
x 1 y 3 z – 2
9 = 0 and parallel to the line is ax + by + cz + 6 = 0, then a + b + c is equal to :
–2 4 5
(1) 15 (2) 14 (3) 13 (4) 12
Sol. (2)
Using family of planer
P :P1 + P2 = 0 P(2 + 4) x – (1 + 3) y + (1 + 5) z = (3 – 9)
x 1 y3 z–2
P is || to = =
–2 4 5
Then for : n p . vL = 0
–2 (2 + 4) – 4(1 + 3) + 5 (1 + 5) = 0
3
–3 + 5 = 0 =
5
Hence : P : 22x –14 y + 20 z = –12
P : 11 x – 7y + 10z + 6 = 0
a = 11
b=–7
c = 10
a + b + c = 14
Ans. 2
12. If the ratio of the fifth term from the beginning to the fifth term from the end in the expansion of
n
1
4
2 is 6 :1 , then the third term from the beginning is :
3
4
x1 = 5 + 3 x2 = 5 – 3 (reject) x3 = 4 x4 = 2 (reject)
Sum of of roots is = 5 + 3 +4=9+ 3
Ans. 3
y
A x
3 4 5 5+
14. From the top A of a vertical wall AB of height 30 m, the angles of depression of the top P and bottom Q of a
vertical tower PQ are 15° and 60° respectively, B and Q are on the same horizontal level. If C is a point on
AB such that CB = PQ, then the area (in m2) of the quadrilateral BCPQ is equal to :
(1) 200 3 – 3 (2) 300 3 1 (3) 300 3 –1 (4) 600
3 –1
Sol. (4)
ABQ
15º
60º
30 C P
x
B
y Q
AB
= tan 60°
BQ
30
BQ = = 10 3 = y
3
& ACP
AC (30 – x)
= tan 15° = (2– 3 )
CP y
30 – x = 10 3 (2 – 3)
30 –x = 20 3 – 30
x = 60 – 20 3
Area = x.y = 20 (3– 3 ).10 3
= 600 ( 3 –1)
Ans. (4)
1 1
2
19. Let 5f (x) 4f 3, x 0 . Then 18 f (x)dx is equal to :
x x 1
Combine var. = 1
n1 n 2 n1 n 2
15 14 15 2 15 15 12 14
2
13
30 30 30
14 2
4
13
2 4
2 = 10
SECTION-B
21. Let the tangents to the curve x2 + 2x –4y + 9 = 0 at the point P(1, 3) on it meet the y-axis at A. Let the line
passing through P and parallel to the line x – 3y = 6 meet the parabola y2 = 4x at B. If B lies on the line 2x –
3y = 8, then (AB)2 is equal to ______.
Sol. (292)
C : x2 + 2x – 4y + 9 = 0
C : (x + 1)2 = 4(y – 2)
TP(1,3) : x.1 + (x + 1) – 2(y + 3) + 9 =0
: 2x – 2y + 4 = 0
Tp : x – y + 2 = 0
A : (0, 2)
Line || to x–3y = 6 passes (1, 3) is x – 3y + 8 = 0
Meet parabola : y2 = 4x
y2 = 4(3y – 8)
y2 – 12y + 32 = 0
(y – 8) (y – 4) = 0
point of intersection are
(4, 4) & (16,8) lies on 2x – 3y = 8
B
Hence A : (0, 2)
B : (16, 8)
(AB)2 = 256 + 36 = 292
22.
Let the point (p, p + 1) lie inside the region E (x, y) : 3 – x y 9 – x 2 ,0 x 3 . If the set of all values
of p is the interval (a, b), then b2 + b – a2 is equal to _____.
Sol. (3)
3–xy 9 – x2 ; 0 x 3
L:x+y=3 A : (P, P + 1)
S:y=
A
B y
23. Let y = y(x) be a solution of the differential (xcos x)dy + (xysin x + ycos x – 1)dx = 0, 0 < x < . If
2
y 3 , then y '' 2y ' is equal to _____.
3 3 6 6 6
Sol. (2)
(x cos x) dy + (xysinx + ycos x –1) dx = 0, 0 < x <
2
dy x sin x cos x 1
y
dx x cos x x cos x
IF = x secx
x secx
y.x sec x dx tan x c
x cos x
3 3
Since y Hence c 3
3
Hence y'' y' 2 2
6 6 6
24. Let a and [t] be the greatest integer t. Then the number of points, where the function f(x) = [a + 13 sin
x], x (0, ) is not differentiable, is _____.
Sol. (25)
f(x) = [a+ 13 sin x] = a + [13 sin x] in (0, )
x (0, )
0 < 13 sin x 13
[13 sin x] = {0, 1, 2, 3,… 12,13,}
2 2 1
Total point of N.D. = 25.
n2
25. If the area of the region S = {(x, y) : 2y – y2 x2 2y, x y} is equal to – , then the natural
n 1 n –1
number n is equal to ____.
Sol. (5)
x2 + y2 – 2y 0 & x2 – 2y 0 , x y
1
2
1 x2
Hence required area = 2 2 dx
2 0
2 4 2
7
n 5
6 4
26. The number of ways of giving 20 distinct oranges to 3 children such that each child gets at least one orange is
_____.
Sol. 3483638676
Total – (one child receive no orange + two child receive no orange)
= 320 –( 3C1 (220 –2) + 3C2 120) = 3483638676
27. Let the image of the point P (1, 2, 3) in the plane 2x – y + z = 9 be Q. If the coordinates of the point R are (6,
10, 7). then the square of the area of the triangle PQR is ____.
Sol. (594)
Let Q () be the image of P, about the plane
2x – y + z = 9
1 2 3
2
2 1 1
= 5, = 0, = 5
1
Then area of triangle PQR is = PQ PR
2
12i 3j 21kˆ 144 9 441 594
Square of area = 594
28. A circle passing through the point P(. ) in the first quadrant touches the two coordinate axes at the points A
and B. The point P is above the line AB. The point Q on the line segment AB is the foot of perpendicular
from P on AB. If PQ is equal to 11 units, then value of is ____.
Sol. (121)
2
242 = 2 + 2 – 2a – 2a + a2 + 2
242 = 2
= 121
15
1
29. The coefficient of x18 in the expansion of x 4 – 3 is _____.
x
Sol. (5005)
15
4 1
x 3
x
1
r
Tr 1 15 Cr x 4
15 r
3
x
60 –7r = 18
r=6
Hence coeff. of x18 = 15C6 = 5005
30. Let A = {1, 2, 3, 4, …., 10} and B = {0, 1, 2, 3, 4}. The number of elements in the relation R = {(a, b) A ×
A: 2 (a – b)2 + 3 (a – b) B} is _____.
Sol. (18)
A = {1,2,3,......10}
B = {0,1, 2,3, 4}
R = {(a, b) A × A: 2(a – b)2 + 3(a – b) B}
Now 2 (a – b)2 + 3 (a – b) = (a – b) (2 (a – b) + 3)
a = b or a – b = –2
When a = b 10 order pairs
When a– b = –2 8 order pairs
Total = 18
SECTION - A
31. The kinetic energy of an electron, -particle and a proton are given as 4 K, 2 K and K respectively. The
de-Broglie wavelength associated with electron ( e) , -particle ( ) and the proton ( p) are as follows :
(1) p e (2) p e
(3) p e (4) p e
Sol. (4)
h
According to De-Broglie, Momentum P = λ , where h is plank’s constant and λ is wavelength.
Also, relation between Kinetic energy(KE) and momentum(P) is given by: P = √2mKE
h h
Now, λ = P = √2mKE
h h h
λe = = =
√2me KEe √2me × 4k √8me k
h h
λp = =
√2mp KEp √2mp k
h h h h
λα = = = =
√2mα KEα √2mα . 4k √2 × 2mp . 2k √8mp k
From the above data, 𝜆𝛼 < 𝜆𝑃 < 𝜆𝑒
32. Given below are two statements : one is labelled as Assertion A and the other is labelled as Reason R.
Assertion A : Earth has atmosphere whereas moon doesn't have any atmosphere.
Reason R : The escape velocity on moon is very small as compared to that on earth.
In the light of the above statements. choose the correct answer from the options given below:
(1) Both A and R are correct and R is the correct explanation of A
(2) A is false but R is true
(3) Both A and R are correct but R is NOT the correct explanation of A
(4) A is true but R is false
Sol. (1)
2𝐺𝑀
𝑉𝑒𝑠𝑐 = √ = √2𝑔𝑟
𝑟
Radius of moon is less than that of earth and acceleration due to gravity is also less on moon as compared to
that on earth.
Thus , Vesc of Moon < Vesc of Earth
This is also the reason behind escape of atmosphere from moon.
33. A source supplies heat to a system at the rate of 1000 W. If the system performs work at a rate of 200 W. The
rate at which internal energy of the system increase is
(1) 500 W (2) 600 W (3) 800 W (4) 1200 W
Sol. (3)
From Ist law of thermodynamics,
𝑑𝑄 = 𝑑𝑈 + 𝑑𝑊
𝑑𝑄 𝑑𝑈 𝑑𝑊
Also, we can write this as, = +
𝑑𝑡 𝑑𝑡 𝑑𝑡
𝑑𝑈
⟹ 1000𝑊 = + 200𝑊
𝑑𝑡
𝑑𝑈
⟹ = 800𝑊
𝑑𝑡
34. A small ball of mass M and density is dropped in a viscous liquid of density o . After some time, the ball
falls with a constant velocity. What is the viscous force on the ball?
(1) F Mg 1 0 (2) F Mg 1 (3) F Mg 1 o (4) F Mg (1 o )
o
Sol. (3)
At terminal velocity, net force on the ball is Zero.
B
f
Mg
𝑀𝑔 = 𝑓 + 𝐵
⟹ 𝑀𝑔 = 𝑓 + 𝑉𝑏𝑎𝑙𝑙 𝜌𝑜 𝑔 … . (𝑖)
𝑀
Volume of ball = 𝜌
From eq (i),
𝑀
𝑀𝑔 = 𝑓 + 𝜌𝑜 𝑔
𝜌
𝑀
⟹ 𝑓 = 𝑀𝑔 − 𝜌𝑜 𝑔
𝜌
𝜌𝑜
⟹ 𝑓 = 𝑀𝑔(1 − )
𝜌
35. A small block of mass 100 g is tied to a spring of spring constant 7.5 N/m and length 20 cm. The other end of
spring is fixed at a particular point A. If the block moves in a circular path on a smooth horizontal surface with
constant angular velocity 5 rad/s about point A, then tension in the spring is –
(1) 0.75 N (2) 1.5 N (3) 0.25 N (4) 0.50 N
Sol. (1)
𝑘𝑥 = 𝑚𝜔2 𝑟
⟹ 𝑘𝑥 = 0.1 × 25 × (0.2 + 𝑥)
⟹ 7.5𝑥 = 2.5(0.2 + 𝑥)
⟹ 3𝑥 = 0.2 + 𝑥
⟹ 2𝑥 = 0.2
⟹ 𝑥 = 0.1𝑚
Now, tension in the spring = 𝑘𝑥 = 7.5 × 0.1 𝑁 = 0.75 𝑁
36. A particle is moving with constant speed in a circular path. When the particle turns by an angle 90o , the ratio of
instantaneous velocity to its average velocity is : x 2. The value of x will be -
(1) 7 (2) 2 (3) 1 (4) 5
Sol. (2)
𝑉𝐴 = 𝑣𝑗̂ v
And 𝑉𝐵 = −𝑣𝑖̂ B
2𝜋𝑅 1 𝜋𝑅
Time to reach from A to B = 4 × 𝑣 = 2𝑣
Displacement from A to B = 𝑅√2
𝐷𝑖𝑠𝑝𝑙𝑎𝑐𝑒𝑚𝑒𝑛𝑡 𝑅√2 2√2𝑣
Now, Average velocity from A to B = = 𝜋𝑅 =
𝑇𝑖𝑚𝑒 𝜋
2𝑣
Instantaneous velocity at B is −𝑣𝑖̂ A
𝑖𝑛𝑠𝑡𝑎𝑛𝑡𝑎𝑛𝑒𝑜𝑢𝑠 𝑣𝑒𝑙𝑜𝑐𝑖𝑡𝑦 𝜋
According to question, 𝑎𝑣𝑒𝑟𝑎𝑔𝑒 𝑣𝑒𝑙𝑜𝑐𝑖𝑡𝑦 = 𝑥√2
𝑣 𝜋
2√2𝑣
=
𝑥√2
𝜋
𝜋 𝜋
⟹ =
2√2 𝑥√2
⟹𝑥=2
37. Two resistances are given as R 1 (10 0.5) and R 2 (15 0.5). The percentage error in the measurement
of equivalent resistance when they are connected in parallel is -
(1) 2.33 (2) 4.33 (3) 5.33 (4) 6.33
Sol. (2)
1 1 1
In parallel combination, 𝑅 = 𝑅 + 𝑅
𝑒𝑞 1 2
1 1 1 5 1
⟹ = + = =
𝑅𝑒𝑞 10 15 30 6
Now, for error calculation,
𝑑𝑅𝑒𝑞 𝑑𝑅1 𝑑𝑅2
2 = +
𝑅𝑒𝑞 𝑅12 𝑅22
𝑑𝑅𝑒𝑞 0.5 0.5
⟹ = +
36 100 225
13 13 26
𝑑𝑅𝑒𝑞 = 36 × 0.5 × ( ) = 18 × = = 0.26
900 900 100
𝑑𝑅𝑒𝑞 0.26 26
Now , × 100 = × 100 = = 4.33
𝑅𝑒𝑞 6 6
38. For a uniformly charged thin spherical shell, the electric potential (V) radially away from the entre (O) of shell
can be graphically represented as –
(1) (2)
(3) (4)
Sol. (4)
𝐾𝑄
For 𝑟 ≤ 𝑅, 𝑉 = 𝑅 , i.e., Constant everywhere inside.
𝐾𝑄
For 𝑟 > 𝑅, 𝑉 = 𝑟
, i.e., Decreases with r.
39. A long straight wire of circular cross-section (radius a) is carrying steady current I. The current I is uniformly
distributed across this cross-section. The magnetic field is
(1) zero in the region r < a and inversely proportional to r in the region r > a
(2) inversely proportional to r in the region r < a and uniform throughout in the region r > a
(3) directly proportional to r in the region r < a and inversely proportional to r in the region r > a
(4) uniform in the region r < a and inversely proportional to distance r from the axis, in the region r > a
Sol. (3)
It is a case of solid infinite current carrying wire.
Using ampere circuital law,
CASE I: if r ≤ R
𝜇0 𝑖
𝐵= 𝑟
2𝜋𝑅 2
CASE II: r>R
𝜇0 𝑖
𝐵=
2𝜋𝑟
40. By what percentage will the transmission range of a TV tower be affected when the height of the tower is
increased by 21% ?
(1) 12% (2) 15% (3) 14% (4) 10%
Sol. (4)
New range is given by √2𝑅(ℎ + 0.21ℎ)
= √2𝑅ℎ × 1.21
= 1.1√2𝑅ℎ
It means new range increases by 10 %.
41. The number of air molecules per cm3 increased from 3 × 1019 to 12 × 1019. The ratio of collision frequency of
air molecules before and after the increase in the number respectively is :
(1) 0.25 (2) 0.75 (3) 1.25 (4) 0.50
Sol. (1)
Collision frequency is given by 𝑍 = 𝑛𝜋𝑑 2 𝑉𝑎𝑣𝑔 , where n is number of molecules per unit volume.
𝑍1 𝑛1 3 1
= = = = 0.25
𝑍2 𝑛2 12 4
42. The energy levels of an hydrogen atom are shown below. The transition corresponding to emission of shortest
wavelength is
44. A planet has double the mass of the earth. Its average density is equal to that of the earth. An object weighing
W on earth will weigh on that planet:
(1) 21/3 W (2) 2 W (3) W (4) 22/3 W
Sol. (1)
Average Density of planet = average density of earth
𝑀𝑒 𝑀𝑝
4 =4
𝜋𝑅𝑒3 3
𝜋𝑅𝑝
3 3
𝑀𝑒 2𝑀𝑒
⟹ =
𝑅𝑒3 3
𝑅𝑝
1
⟹ 𝑅𝑝 = 23 𝑅𝑒 − − − − − − − − − (𝑖)
𝐺𝑀
Now, 𝑔 = 𝑅2
2
𝑅𝑝 2 1
𝑔𝑒 𝑀𝑒
= × = 23−1 = 2−3
𝑔𝑝 𝑅𝑒2 2𝑀𝑒
1
⟹ 𝑔𝑝 = 23 𝑔𝑒
1
⟹ 𝑊𝑝 = 23 𝑊𝑒
45. The resistivity ( ) of semiconductor varies with temperature. Which of the following curve represents the
correct behavior
(1) (2)
(3) (4)
Sol. (3)
A semiconductor starts conduction more as the temperature increases. It means resistance decreases with
increase in temperature. So, if temperature increases, its resistivity decreases.
𝑚
Also, 𝜌 = 𝑛𝑒 2 𝜏
As Temperature increase, 𝜏 decreases but n increases and n is dominant over 𝜏.
46. A monochromatic light wave with wavelength 1 and frequency 1 in air enters another medium. If the angle
of incidence and angle of refraction at the interface are 45o and 30o respectively, then the wavelength 2 and
frequency 2 of the refracted wave are :
1 1
(1) 2 1 , 2 1 (2) 2 1 , 2 1
2 2
(3) 2 1 , 2 21 (4) 2 21 , 2 1
Sol. (1)
1 × 𝑠𝑖𝑛45 = 𝜇𝑠𝑖𝑛30
1 1
⟹ =𝜇×
√2 2
⟹ 𝜇 = √2 − − − −(𝑖)
𝜇 𝑉 𝜆
Now, 1 = 2 = 2 − − − − − (𝑖𝑖)
𝜇2 𝑉1 𝜆1
Using eq (i) and (ii),
1
𝜆2 = 𝜆
√2 1
1
And 𝑉2 = √2 𝑉1
Now, for relation between frequencies,
𝑉
Frequency, 𝑣 = 𝜆
𝑣 𝑉 𝜆
Or 𝑣1 = 𝑉1 × 𝜆2 = 1
2 2 1
𝑣1 = 𝑣2
47. A mass m is attached to two strings as shown in figure. The spring constants of two springs are K 1 and K2. For
the frictionless surface, the time period of oscillation of mass m is
m 1 K1 K 2 1 K1 K 2 m
(1) 2 (2) (3) (4) 2
K1 K 2 2 m 2 m K1 K 2
Sol. (4)
Both the springs are in parallel.
𝐾𝑒𝑞 = 𝐾1 + 𝐾2
𝑚 𝑚
𝑇 = 2𝜋√ = 2𝜋√
𝐾𝑒𝑞 𝐾1 +𝐾2
50. Given below are two statements : one is labelled as Assertion A and the other is labelled as Reason R.
Assertion A : When a body is projected at an angle 45o , it’s range is maximum.
Reason R : For maximum range, the value of sin 2 should be equal to one.
In the light of the above statements, choose the correct answer from the options given below :
(1) Both A and R are correct but R is NOT the correct explanation of A
(2) A is false but R is true
(3) Both A and R are correct and R is the correct explanation of A
(4) A is true but R is false
Sol. (3)
𝑢2 𝑠𝑖𝑛2𝜃
For a ground to ground projectile, Horizontal range is given by 𝑅 = 𝑔
And for 𝑅𝑚𝑎𝑥 , 𝑠𝑖𝑛2𝜃 must be maximum.
SECTION - B
51. Two identical circular wires of radius 20 cm and carrying current 2 A are placed in perpendicular planes as
shown in figure. The net magnetic field at the centre of the circular wires is _________ × 10-8 T.
Sol. (628)
𝜇 𝑖 𝜇 𝑖
⃗⃗⃗⃗⃗⃗⃗⃗
𝐵𝑛𝑒𝑡 = 0 𝑖̂ + 0 𝑗̂
2𝑟 2𝑟
𝜇0 𝑖 1
⟹ 𝐵𝑛𝑒𝑡 =
2𝑟
√2 = 4𝜋 × 10−7 × √2 × √2 × 2×0.2 = 2 × 3.14 × 10−6 = 628 × 10−8 𝑇
52. A steel rod bas a radius of 20 mm and a length of 2.0 m. A force of 62.8 kN stretches it along its length. Young's
modulus of steel is 2.0 × 1011 N/m2 . The longitudinal strain produced in the wire is _______ × 10-5
Sol. (25)
𝑠𝑡𝑟𝑒𝑠𝑠
𝑌=
𝑠𝑡𝑟𝑎𝑖𝑛
𝑠𝑡𝑟𝑒𝑠𝑠 𝐹 62.8×1000 62.8×1000 200
⟹ 𝑠𝑡𝑟𝑎𝑖𝑛 = = = = = × 10−5 = 25 × 10−5
𝑌 𝐴𝑌 𝜋𝑟 2 ×2×1011 3.14×400×10−6 ×2×1011 8
53. The length of a metallic wire is increased by 20% and its area of cross section is reduced by 4%. The percentage
change in resistance of the metallic wire is ______
Sol. (25)
𝜌𝑙
𝑅=
𝐴
𝜌×1.2𝑙 10
𝑅′ = = × 𝑅 = 1.25 𝑅
0.96𝐴 8
It means 25 % increase in Resistance.
54. The radius of fifth orbit of the Li++ is __________ × 10-12 m.
Take : radius of hydrogen atom = 0.51 Å
Sol. (425)
0.51𝑛2
𝑟𝑛 = 𝐴0
𝑍
++
For Li , z=3.
25
So 𝑟5 = 0.51 × 3 × 10−10 𝑚 = 17 × 25 × 10−12 𝑚 = 425 × 10−12 𝑚
55. A particle of mass 10 g moves in a straight line with retardation 2x, where x is the displacement in SI units. Its
n
10
loss of kinetic energy for above displacement is J. The value of n will be ____________
x
Sol. (2)
Given, 𝑎 = −2𝑥
𝑣𝑑𝑣
⟹ = −2𝑥
𝑑𝑥
⟹ 𝑣𝑑𝑣 = −2𝑥𝑑𝑥
𝑣 𝑥
⟹ ∫𝑣 2 𝑣𝑑𝑣 = −2 ∫0 𝑥𝑑𝑥
1
𝑣22 𝑣12 2𝑥 2
⟹ − =−
2 2 2
𝑚𝑣12 𝑚𝑣22 10 2 10 −2
⟹ − = 𝑚𝑥 2 = 𝑥 = 10−2 𝑥 2 = ( )
2 2 1000 𝑥
n=2.
56. An ideal transformer with purely resistive load operates at 12 kV on the primary side. It supplies electrical energy
to a number of nearby houses at 120 V. The average rate of energy consumption in the houses served by the
transformer is 60 kW. The value of resistive load (Rs) required in the secondary circuit will be ________ m .
Sol. (240)
𝑉𝑠 𝑁𝑠
=
𝑉𝑝 𝑁𝑝
120 𝑁𝑠
⟹ =
12000 𝑁𝑝
𝑁𝑠 1
⟹ = − − − (𝑖)
𝑁𝑝 100
For an ideal transformer, input power = Output power
And power is given by 𝑃 = 𝑖𝑉
𝑖𝑝 𝑉𝑝 = 𝑖𝑠 𝑉𝑠 = 60000𝑊
60000
𝑖𝑝 = =5
12000
𝑉𝑝 12000
Now, 𝑅𝑝 = = = 2400 Ω
𝑖𝑝 5
𝑉𝑠 120 120 120
𝑅𝑠 = = = 120 × = = 0.240Ω = 240 𝑚Ω
𝑖𝑠 60000/120 60000 500
57. A parallel plate capacitor with plate area A and plate separation d is filed with a dielectric material of dielectric
constant K = 4. The thickness of the dielectric material is x, where x < d.
1 2d
Let C1 and C2 be the capacitance of the system for x d and x , respectively. If C1 = 2F the value of
3 3
C2 is __________ F
Sol. (3)
𝜖0 𝐴 4𝜖0 𝐴
2𝑑 × 𝑑
3 3 18 𝜖0 𝐴 2 𝜖0 𝐴 4 𝜖0 𝐴
𝐶1 = 𝜖0 𝐴 4𝜖0 𝐴 =3 = 18 × =
+ +12 𝑑 27 𝑑 3 𝑑
2𝑑/3 𝑑/3 2
4 𝜖0 𝐴 𝜖0 𝐴 3
According to qn, 3 =2⟹ = − − − − − (𝑖)
𝑑 𝑑 2
𝜖0 𝐴 4𝜖0 𝐴
𝑑 × 2𝑑
3 3 18 𝜖0 𝐴 𝜖0 𝐴 3
Now, 𝐶2 = 𝜖0 𝐴 4𝜖0 𝐴 =
3+6 𝑑
=2×
𝑑
=2× =3
2
+
𝑑/3 2𝑑/3
58. Two identical solid spheres each of mass 2 kg and radii 10 cm are fixed at the ends of a light rod. The separation
between the centres of the spheres is 40 cm. The moment of inertia of the system about an axis perpendicular
to the rod passing through its middle point is __________ × 10-3 kg-m2
Sol. (176)
Using parallel axix theorem,
2
𝐼𝑠𝑦𝑠 = ( 𝑚𝑟 2 + 𝑚𝑑 2 ) × 2
5
2
⟹ 𝐼𝑠𝑦𝑠 = ( × 2 × 0.01 + 2 × 0.04) × 2 = (0.008 + 0.08) × 2 = 0.088 × 2 = 176 × 10−3
5
59. A person driving car at a constant speed of 15 m/s is approaching a vertical wall. The person notices a change
of 40 Hz in the frequency of his car's horn upon reflection from the wall. The frequency of horn is ______ Hz.
Sol. (420)
𝑓 ′ = 𝑓0 + 40
330+15
⟹ 𝑓0 ( ) = 𝑓0 + 40
330−15
345
⟹ 𝑓0 × = 𝑓0 + 40
315
30
⟹ 𝑓0 × = 40
315
315
⟹ 𝑓0 = 40 × = 420 𝐻𝑧
30
60. A pole is vertically submerged in swimming pool, such that it gives a length of shadow 2.15 m within water
when sunlight is incident at an angle of 30o with the surface of water. If swimming pool is filled to a height of
1.5 m, then the height of the pole above the water surface in centimeters is (nw = 4/3) ____________
Sol. (50)
4
𝑠𝑖𝑛60 = 𝑠𝑖𝑛𝑟
3
3 √3 3√3
⟹ 𝑠𝑖𝑛𝑟 = × = − − − (𝑖) y
4 2 8 600
27 √37
𝑐𝑜𝑠𝑟 = √1 − = = 0.75
64 8
27 r
⟹ 𝑡𝑎𝑛𝑟 = √
37
𝑥 1.5m
⟹ = 0.85
1.5
⟹ 𝑥 = 0.85 × 1.5 = 1.275𝑚
𝑦 𝑦 x
𝑡𝑎𝑛30 = =
2.15−1.275 0.875
0.875 2.15m
𝑦= = 0.50
1.732
So length of pole above water surface = 0.50m=50cm
SECTION - A
61. Match List I with List II
List I List II
(Natural Amino acid) (One Letter Code)
(A) Arginine (I) D
(B) Aspartic acid (II) N
(C) Asparagine (III) A
(D) Alanine (IV) R
Choose the correct answer from the options given below:
(1) (A) – III, (B) – I, (C) – II (D) –IV (2) (A) – IV, (B) – I, (C) – II (D) –III
(3) (A) – IV, (B) – I, (C) – III (D) –II (4) (A) – I, (B) – III, (C) – IV (D) –II
Sol. 2
Natural Amino acid One Letter Code
(i) Arginine R
(ii) Aspartic acid D
(iii) Asparagine N
(iv) Alanine A
62. Formation of which complex, among the following, is not a confirmatory test of Pb2 ions
(1) lead sulphate (2) lead nitrate (3) lead chromate (4) lead iodide
Sol. 2
Pb(NO3)2 is a soluble colourless compound so it cannot be used in confirmatory test of Pb+2 ion.
63. The volume of 0.02 M aqueous HBr required to neutralize 10.0 mL of 0.01 M aqueous Ba(OH)2 is (Assume
complete neutralization)
(1) 5.0 mL (2) 10.0 mL (3) 2.5 mL (4) 7.5 mL
Sol. 2
m.eq. of HBr = m.eq. of Ba(OH)2
M1 × n1 × V1(mL) = M2 × n2 × V2(mL)
0.02 × 1 × V1(mL) = 0.02 × 2 × 10
V1(mL) = 10 mL
64. Group–13 elements react with O 2 in amorphous form to form oxides of type M2O3 (M = element). Which
among the following is the most basic oxide?
(1) Al2O3 (2) Tl2O3 (3) Ga 2 O3 (4) B2 O3
Sol. 2
As electropositive character increases basic character of oxide increases.
B2O3 Al2O3 Ga 2O3 In 2O3 Tl2O3
acidic amphoteric basic
68. From the figure of column, chromatography given below, identify incorrect statements.
a
b
c
Sol. 4
OH OH OH OH
Cl CH3 NO2
–I +I –I
Since –I of –NO2 > Cl
So, most acidic will be (4)
(1) (2)
(3) (4)
Sol. 4
H
OH OH2
–CH3–Shift
H
72. Structures of BeCl2 in solid state, vapour phase and at very high temperature respectively are:
(1) Polymeric, Dimeric, Monomeric (2) Dimeric, Polymeric, Monomeric
(3) Monomeric, Dimeric, Polymeric (4) Polymeric, Monomeric, Dimeric
Sol. 1
In solid state BeCl2 as polymer, in vapour state it form chloro-bridged dimer while above 1200K it is monomer.
73. Consider the following reaction that goes from A to B in three steps as shown below:
AC-1 AC-3
A
Inter- Inter- B
mediate-1 mediate-2
Number of Intermediate 2
Number of Activated complex 3
Rate determining step II
74. The product, which is not obtained during the electrolysis of brine solution is
(1) HCl (2) NaOH (3) Cl2 (4) H 2
Sol. 1
Brine solution (NaCl + H2O)
NaCl Na+ + Cl–
Electrolyte
H2O 2H+ + OH–
At Cathode 2H + 2e H2
At Anode 2Cl– Cl2 + 2e
Na+ + OH– NaOH
Answer 1 (HCl)
75. Which one of the following elements will remain as liquid inside pure boiling water?
(1) Li (2) Ga (3) Cs (4) Br
Sol. 2
Li, Cs reacts vigorously with water.
Br2 changes in vapour state in boiling water (BP = 58°C)
Ga reacts with water above 100°C (MP = 29°C, BP = 2400°C)
76. Given below are two statements: one is labelled as “Assertion A” and the other is labelled as “Reason R”
Assertion A: In the complex Ni(CO)4 and Fe(CO)5 , the metals have zero oxidation state.
Reason R: Low oxidation states are found when a complex has ligands capable of –donor character in addition
to the – bonding.
In the light of the above statement, choose the most appropriate answer from the options given below
(1) A is not correct but R is correct.
(2) A is correct but R is not corret
(3) Both A and R are correct and R is the correct explanation of A
(4) Both A and R are correct but R is NOT the correct explanation of A.
Sol. 2
Low oxidation state of metals can stabilized by synergic bonding so ligand has to be -acceptor.
77. Given below are two statements:
Statement I: Morphine is a narcotic analgesic. It helps in reliving pain without producing sleep.
Statement II: Morphine and its derivatives are obtained from opium poppy.
In the light of the above statements, choose the correct answer from the options given below
(1) Statement I is true but statement II is false (2) Both statement I and statement II are true
(3) Statement I is false but statement II is true (4) Both Statement I and Statement II are false
Sol. 3
Fact
Morphine
(i) Morphine is a narcotic analgesic, it help in relieving plan and producing sleep.
(ii) Morphine and its derivatives are obtained from opium.
78. Find out the major product from the following reaction.
(1)MeMgBr/CuI
(2)n Pr l
(1) (2)
(3) (4)
Sol. 3
O O
Me + MgBr n—Pr—I
CuI
79. During the reaction of permanganate with thiosulphate, the change in oxidation of manganese occurs by value
of 3. Identify which of the below medium will favour the reaction
(1) aqueous neutral (2) aqueous acidlic
(3) both aqueous acidic and neutral (4) both aqueous acidic and faintly alkaline
Sol. 1
In neutral or weakly alkaline solution oxidation state of Mn changes by 3 unit
7 4
Mn O4–1 Mn O2
80. Element not present in Nessler’s reagent is
(1) K (2) N (3) I (4) Hg
Sol. 2
Nessler reagent is- K2[HgI4]
SECTION - B
81. The standard reduction potentials at 298 K for the following half cells are given below:
NO3– 4H 3e – NO(g) 2H2O E 0.97V
V2 (aq) 2e – V E –1.19V
Fe3 (aq) 3e – Fe E –0.04V
Ag (aq) e – Ag(s) E 0.80V
Au 3 (aq) 3e – Au(s) E 1.40V
The number of metal(s) which will be oxidized by NO3– in aqueous solution is ____________
Sol. 3
Metal + NO3– Metal Nitrate
(V, Fe, Ag)
Less value of reaction potential then 0.97 volt.
Answer 3
82. Number of crystal system from the following where body centred unit cell can be found, is__________
Cubic, tetragonal, orthorhombic, hexagonal, rhombohedral, monoclinic, triclinic
Sol. 3
BCC present in Cubic, Tetragonal orthorhombic
83. Among the following the number of compounds which will give positive iodoform reaction is________
(a) 1–Phenylbutan–2–one (b) 2–Methylbutan–2–ol
(c) 3–Methylbutan–2–ol (d) 1–Phenylethanol
(e) 3,3–dimethylbutan–2–one (f) 1–Phenylpropan –2–ol
Sol. 4
Iodo form test
(a) Ph –NO
O
(b) –NO
OH
(c) –Yes
OH
Ph
(d) –Yes
OH
(e) –Yes
O
OH
(f) –Yes
Ph
For carbonyl compound —C—CH3 for alcohol —CH—CH3 should be present for idoform test.
O OH
84. Number of isomeric aromatic amines with molecular formula C8 H11 N , which can be synthesized by Gabriel
Phthalimide synthesis is_________
Sol. 6
By Gabriel phthalimide synthesis i-amine is prepared
C8H11N Should be aromatic & i-amine
H–N
Du = C + 1 –
2
11 – 1
=8+1–
2
10
= 9– = 9 – 5 = 4 it means benzene ring
2
NH2 NH2 NH2
NH2 *
NH2
(v)
85. Consider the following pairs of solution which will be isotonic at the same temperature. The number of pairs of
solutions is/are______________
A. 1 M aq. NaCl and 2 M aq. Urea
B. 1 M aq. CaCl2 and 1.5 M aq. KCl
C. 1.5 M aq. AlCl3 and 2 M aq. Na 2SO4
D. 2.5 M aq. KCl and 1 M aq. Al2 (SO4 )3
Sol. 4
A. 1 M aq. NaCl 2 M aq. Ions
Isotonic
2 M aq. Urea 2 M aq. Urea
86. The number of colloidal systems from the following, which will have ‘liquid’ as the dispersion medium,
is_________
Gem stones, paints, smoke, cheese, milk, hair cream, insecticide sprays, froth, soap lather
Sol. 5
Liquid dispersion medium
Paints, milk, hair cream, froth, soap lather
87. In an ice crystal, each water molecule is hydrogen bonded to neighbouring molecules.
Sol. 4
O
H H
H O H
O H H O
H H
H
O H
90. The number of species having a square planar shape from the following is___________________
XeF4 ,SF4 ,SiF4 ,BF4– ,BrF4– [Cu(NH3 ) 4 ]2 ,[FeCl4 ]2– ,[PtCl 4 ]2–
Sol. 4
XeF4 ,BrF4– [Cu(NH3 )4 ]2 ,[PtCl4 ]2– has square planar shape.
SECTION-A
1. If gcd (m, n) = 1 and
12 – 22 + 32 – 42 + ….. + (2021)2 – (2022)2 + (2023)2 = 1012 m2n
then m2 – n2 is equal to :
(1) 180 (2) 220 (3) 200 (4) 240
Sol. (4)
(1 – 2) (1 + 2) + (3 – 4) (3 + 4) +……+ (2021 – 2022) (2021 + 2022) + (2023)2 = (1012) m2n
(– 1) [1 + 2 + 3 + 4 + … + 2022] + (2023)2 = (1012) m2n
2022 2023
( – 1) + (2023)2 =(1012) m2n
2
(2023) [ 2023 – 1011 ] = (1012) m2n
(2023) (1012) = (1012) m2n
m2n = 2023
m2n = (17)2 × 7
m = 17, n = 7
m2 – n2 = (17)2 –72 = 289 – 49 = 240
Ans. Option 4
1
A= [1+3] [2]
2
=4
Ans. Option 2
S2
P Q qp ~p (~p)^q (qp) (~p^q)
T T T F F F
T F T F F F
F T F T T T
F F T T F F
Ans. Option 3
1 1
1 1
1 1
5. lim 2 2 – 2 3 2 2 – 2 5 ...... 2 2 – 2 2n 1 is equal to
n
1
(1) (2) 2 (3) 1 (4) 0
2
Sol. (4)
12 1
12 1
12 1
P= lim 2 2 3
2 2 5
......... 2 2 2n 1
n
Let
1 1
2 2 23 Smallest
1 1
2 2
2 2n 1 Largest
Sandwich th.
n n
12 1
1 1
2 2 3 P 2 2 2 2n 1
n
lie b / w
0 and 1
n
1 1
lim 2 2 2 3 0
n
n
1 1
lim 2 2 2 2n 1 0
n
P = 0
7. A plane P contains the line of intersection of the plane r.(iˆ ˆj k)ˆ = 6 and r.(2iˆ 3 ˆj 4k)
ˆ –5. If P passes
through the point (0, 2, –2), then the square of distance of the point (12, 12, 18) from the plane P is :
(1) 620 (2) 1240 (3) 310 (4) 155
Sol. (1)
eqn of plane P1 + P2 = 0
(x + y + z – 6) + (2x + 3y + 4z +5) = 0
pass th. (0, 2, – 2)
(– 6) + (6 – 8 + 5) = 0
(– 6) + [3] = 0 = 2
eqn of plane
5x + 7y + 9z + 4 = 0
distance from (12, 12, 18)
60 84 162 4
d
25 49 81
310
d
155
310 310
d2
155
d2 620
Ans. Option 1
8. Let f(x) be a function satisfying f(x) + f ( – x) = 2, x . Then f (x)sin x dx is equal to :
0
2
2
(1) (2) 2 (3) 22 (4)
2 4
Sol. (2)
I f x sin x dx …..(1)
0
Add
2I f x f x sinx dx
0
2I 2 sinx dx
0
2 I 2 2
I 2
Ans. Option 2
11 11
1 1
9. If the coefficients of x7 in ax 2 –7
and x in ax – 2
are equal, then :
2bx 3bx
(1) 64 ab = 243 (2) 32 ab = 729 (3) 729 ab = 32 (4) 243 ab = 64
Sol. (3)
11
2 1
ax
2bx
11 2 7
r 5
3
5
6 1
Coefficient of x7 is 11 C5 a
2b
11
1
ax
3bx 2
11 1 7
r 6
3
a5
Coefficient of x–7 is 11 C6
36 b6
1 a5
11 C5 (a 6 ) 5 5 11 C6 6 6
2 b 3b
25
ab
36
729 ab 32
Ans. Opiton 3
9
10. If the tangents at the points P and Q are the circle x2 + y2 –2x + y = 5 meet at the point R ,2 , then the area
4
of the triangle PQR is :
5 13 5 13
(1) (2) (3) (4)
4 4 8 8
Sol. (3)
x2 + y2 – 2x + y = 5
R P' P
(9/4, 2)
Q
p
11. Three dice are rolled. If the probability of getting different numbers on the three dice is , where p and q are
q
co-prime, then q – p is equal to :
(1) 1 (2) 2 (3) 4 (4) 3
Sol. (3)
Fav.
6
C3 3!
666
20 6 20 5 p
6 6 6 36 9 q
p 5
qp4
q 9
Ans. Option 3
12. In a group of 100 persons 75 speak English and 40 speak Hindi. Each person speaks at least one of the two
languages. If the number of persons, who speak only English is and the number of persons who speak only
Hindi is , then the eccentricity of the ellipse 25 2 x 2 2 y2 22 is :
Only E 60 = 60
Only H 25 = 25
Both = 15
2
25x 25y2
1
2 2
25x 2
25y 1
2
60 25
2 2
25 25
e2 1
60
2
60 25
2 2
e
2
60
2
e2
60 25 60 25
60 60
e2
35 85 119
60 60 144
119
e
12
dx
13. If the solution curve f(x, y) = 0 of the differential equation (1 + loge x) – x loge x e y , x 0, passes through
dy
the points (1, 0) and (, 2), then is equal to :
2 e2 2 2 2
(1) e (2) e e (3) e 2e (4) e2e
Sol. (4)
dx
1 n x x n x ey
dy
Let x nxt
dx dt
1 n x
dy dy
dt
t ey P = – 1, Q = ey
dy
I F e
dy
e y
Solution -
t e y e y ey dy
t(e–y) = y + c
(x n x) e–y = y + c pass (1, 0) c = 0
pass (, 2)
e2e
2
Ans. Option 4
1
14. Let the sets A and B denote the domain and range respectively of the function f (x) , where [x]
[x] – x
denotes the smallest integer greater than or equal to x. Then among the statements :
(S1) : A B = (1, ) – N and
(S2) : A B = (1, )
(1) only (S1) is true (2) neither (S1) nor (S2) is true
(3) only (S2) is true (4) both (S1) and (S2) are true
Sol. (1)
1
f x
x x
If x I x = [x] (greatest integer function)
If x I x [x] 1
1
[x] x , x I
f (x)
1
, x I
[x] 1 x
1
{x} , x I,(does not exist)
f (x)
1
, x I
1 {x}
domain of f(x) = R –I
1
Now, f(x) = , x I
1 {x}
x < {x} < 1
0 1 1 {x} 1
1
1
1 {x}
Range (1, )
A=R–I
B = (1 )
So, A B (1, ) N
A B (1, )
S1 is only correct.
15. Let a b be two-zero real numbers. Then the number of elements in the set
X {z : Re(az2 bz) a and Re(bz 2 az) b} is equal to :
(1) 0 (2) 2 (3) 1 (4) 3
Sol. (1) Bonus
z z 2Re z If z = x + iy z z 2x z2 + ( z )2 = 2 (x2 – y2)
(az2 + bz) + (a z 2 + b z ) = 2a ……….(1)
(bz2 + az) + (b z 2 + a z ) = 2b ……….(2)
add (1) and (2)
(a + b) z2 + (a + b) z + (a +b) z 2 + (a + b) z =2(a + b)
(a + b) [z2 + z + ( z )2 + z ] = 2(a + b) ……….(3)
sub. (1) and (2)
(a – b) [z2 – z + z 2 – z ] = 2(a – b) ……….(4)
z + z –z–z =2
2
Case I: If a + b 0
From (3) & (4)
2x + 2 ( x2 – y2) = 2 x2 – y2 + x =1 ……….(5)
2( x – y ) – 2x = 2
2 2
x – y – x =1
2 2
……….(6)
(5) – (6)
2x = 0 x = 0
from (5) y2 = – 1 not possbible
Ans = 0
Case II: If a + b = 0 then infinite number of solution.
So, the set X have infinite number of elements.
16. The sum of all values of , for which the points whose position vectors are i 2j 3k, 2i 3j 4k, 1 i 2k
and 9iˆ ( – 8)ˆj 6kˆ are coplanar, is equal to :
(1) –2 (2) 2 (3) 6 (4) 4
Sol. (2)
A 1, 2,3
B 2, 3, 4
C 1,0, 2
D 9, 8,6
AB AC AD 0
1 1 1
2 1 0
8 6 3
(6 + – 6) + 1 (3 + 8) + (2 – 6 – 16) = 0
2 – 2 –8 = 0
= 4, –2
sum of all values of = 2
Ans. option 2
x –1 y – 2 z – 3
17. Let the line L pass through the point (0, 1, 2), intersect the line and be parallel to the
2 3 4
plane 2x + y – 3z = 4. Then the distance of the point P(1, –9, 2) from the line L is :
(1) 9 (2) 54 (3) 69 (4) 74
Sol. (4)
(2, 1, –3)
P(0, 1, 2)
Q [2+1, 3 + 2, 4 +3]
line
x 1 y 2 z 3
2x + y – 3z = 4 2 3 4
PQ = (2 +1, 3 +1, 4 + 1)
PQ n 0 (2 +1).(2) +( 3 +1) (1) + (4 + 1) (–3) = 0
– 5 = 0
= 0
Q = (1, 2, 3)
eqn of line
x 0 y 1 z 2
1 1 1
distance of line from (1, –9, 2)
(P'Q').(1, 1, 1) = 0
–+ = 0
–+=
–
Q' = (– 3, –2, 1)
P'Q' = 16 49 9 74
18. All the letters of the word PUBLIC are written in all possible orders and these words are written as in a
dictionary with serial numbers. Then the serial number of the word PUBLIC is :
(1) 580 (2) 578 (3) 576 (4) 582
Sol. (4)
B ––––––––––––––––– = 5! = 120
C ––––––––––––––––– = 5! = 120
I –––––––––––––––––– = 5! = 120
L ––––––––––––––––– = 5! = 120
PB –––––––––––––––– = 4! = 24
PC –––––––––––––––– = 4! = 24
PI ––––––––––––––––– = 4! = 24
PL –––––––––––––––– = 4! = 24
PUBC ––––––––––––– = 2! = 2
PUBI –––––––––––––– = 2! = 2
PUBLC –––––––––––– = 1
PUBLIC ––––––––––– = 1
582
Rank = 582
Ans. Option 4
19. Let the vectors a, b,c represent three coterminous edges of a parallelepiped of volume V. Then the volume of
the parallelepiped, whose coterminous edges are represented by a,b c and a 2b 3c is equal to :
(1) 2 V (2) 6 V (3) 3 V (4) V
Sol. (4)
v a b c
v1 a b+c a + 2b + 3c
1 0 0
v1 0 1 1 a b c
1 2 3
v1 = (3–2)v
=v
Ans. Option 4
SECTION-B
21. The value of tan 9° – tan 27° – tan 63° + tan 81° is ____ :
Sol. 4
(tan 9º + cot 9º) – (tan 27º + cot 27º)
1 1
sin 9º cos9º sin 27º cos 27º
2 2
sin18º sin 54º
2 4 2 4
5 1 5 1
8 5 1 8 5 1
4 4
2 5 1
5 1
=4
22. If (20) 19 + 2(21)(20)18 + 3(21)2 (20)17 + …. + 20(21)19 = k(20)19, then k is equal to _____ :
Sol. 400
S = (20)19 + 2(21) (20)18 + ……. + 20(21)19
21
S = 21(20)18 + 2(21)9 (20)17 + ……. + (21)20
20
Subtract
21
1 S = (20) + (21) (20) + (21) (20) + ……. + (21) – (21)
19 18 2 17 19 20
20
21 20
1
1 19 20 – (21)20
S = (20) 21
20
1 20
1
S = (21) – (20) – (21)
20 20 20
20
S = (20)21 = K (20)19 (given)
K = (20)2 = 400
x 2 y2
23. Let the eccentricity of an ellipse 1 is reciprocal to that of the hyperbola 2x2 –2y2 = 1. If the ellipse
a 2 b2
intersects the hyperbola at right angles, then square of length of the latus-rectum of the ellipse is _____:
Sol. 2
x 2 y2
E : 2 2 1 e
a b
1
H : x 2 y 2 e' 2
2
1
e
2
1
e2
2
b2 1 b2 1
1 2
2
a 2 a 2
a 2 2b2
E & H are at right angle
they are confocal
Focus of Hyperbola = focus of ellipse
1 a
2,0 ,0
2 2
a 2
a 2 2b2 b2 1
2b 2 1
Length of LR
a 2
= 2
Square of LR = 2
24. For , , z and > 1, if – 1 is the radius of the circle |z –|2 + |z –|2 = 2, then | – | is equal to
____:
Sol. 2
z z1 z z2 z1 z2
2 2 2
z1 , z2
2
2
2
2r 2
2 1 2
4 1 2
2
2
3 1
25. Let a curve y = f(x), x (0, ) pass through the points P 1, and Q a, . If the tangent at any point
2 2
R (b,f(b)) to the given curve cuts the y-axis at the points S(0, c) such that bc = 3, then (PQ)2 is equal to _____:
Sol. 5
x –1 2 – y z – 3 x – 4 y –1 z
26. If the lines and intersect, then the magnitude of the minimum value of
2 –3 5 2
8 is _____:
Sol. 18
x –1 2 – y z – 3 x – 4 y –1 z
If the lines and intersect Point of first line (1, 2, 3) and point on second
2 –3 5 2
line (4, 1, 0).
Vector joining both points is 3i j 3k
Now vector along second line is 2i 3j k
Also vector along second line is 5i 2 j k
Now these three vectors must be coplanar
2 3
5 2
3 1 3
2(6 – ) –3(15 + 3) + (11) = 0
– = 3
Now = 3 +
Given expression 8(3 + ). = 8 (2 + 3)
2
9 9 3
8 2 3 8 18
4 4 2
So magnitude of minimum value = 18
x
27. Let f (x) 1
,x – {–1}, n ,n 2. If fn (x) =n (fofof….. upto n times) (x), then
n n
1 x
1
lim x n –2 f n (x) dx is equal to _____:
n
0
Sol. 0
x
Let f (x) 1
,x – {–1}, n ,n 2.
n n
1 x
If f (x) =n (fofof….. upto n times) (x)
n
1
then lim x n –2 f n (x) dx
n
0
f f x
x
1 2x n 1/n
f f f x x
1 3x n 1/n
x
Similarly f n x
1 n x n 1/n
x n 2 xdx x n 1 dx
Now lim lim
n
1 n x n 1/n n
1 n x n 1/n
Now 1 + nxn = t
n2 xn 1dx dt
dt
x n 1dx 2
n
1 1 n dt
lim 2
n n 1 t1/n
1 n
1 1
1 t n
lim 2
n n 1
1
n 1
1 n 1
1
lim
n n n 1
1 n n 1 Now let n
h
1 h
1
1 1
lim
h
h 0 1 1 h
h h
Using series expansion
0
N f i 40
f x i i 360 6 12
f x i
2
i 3904 36 144
Mean x
f xi i
9
f i
f
2 i 1
fi i
40
3904 180
9 15.08
2
40 2
= 5
Now, + 2 – = 2 = 25
29. The number of points, where the curve y = x5 –20x3 + 50x + 2 crosses the x-axis is ____:
Sol. 5
y = x5 – 20x3 + 50x + 2
dy
= 5x4 – 60x2 + 50 = 5(x4 – 12x2 + 10)
dx
dy
= 0 x4 – 12x2 +10 = 0
dx
12 144 40
x2 =
2
x 2 6 26 x 2 6 5.1
x 2 11.1,0.9
x 3.3, 0.95
f(0) = 2, f (1) = + ve, f (2) = – ve
f(–1) = – ve, f (–2) = +ve
30. The number of 4-letter words, with or without meaning, each consisting of 2 vowels and 2 consonants, which
can be formed from the letters of the word UNIVERSE without repetition is _____:
Sol. 432
UNIVERSE
Vowels Consonant
E, E N, V,
I, U R, S
Case I 2 vowels different, 2 consonant different
3
C2 4 C2 4!
= (3) (6) (24)
= 432
SECTION - A
31. The temperature of an ideal gas is increased from 200 K to 800 K. If r.m.s. speed of gas at 200 K is v 0 . Then,
r.m.s. speed of the gas at 800 K will be:
v0
(1) 4v 0 (2) 2v 0 (3) v 0 (4)
4
Sol. (2)
3RT
using vrms =
m
3R 200
v0 = ….(1)
m
3R 800
(v’) = ….(2)
m
dividing (2) by (1)
v' 800
= = 4 =2
v0 200
or v’ = 2v0
32. Given below are two statements : one is labelled as assertion A and the other is labelled as Reason R
Assertion A : The phase difference of two light wave change if they travel through different media having same
thickness, but different indices of refraction
Reason R : The wavelengths of waves are different in different media.
In the light of the above statements, choose the most appropriate answer from the options given below
(1) Both A and R are correct and R is the correct explanation of A
(2) A is not correct but R is correct
(3) A is correct but R is not correct
(4) Both A and R are correct but R is NOT the correct explanation of A
Sol. (1)
Both the statements are true
As we know speed of light in a medium
c c
v= or f =
1
therefore
when light will travel through two different mediums their phase difference will change
2
Q = x
and R is correction explanation
33. For an amplitude modulated wave the minimum amplitude is 3 V, while the modulation index is 60%. The
maximum amplitude of the modulated wave is :
(1) 10 V (2) 12 V (3) 15 V (4) 5 V
Sol. (2)
Given, modulation index = 60% = 0.6
A m 0.6
Ac 1
Using componendo – dividendo, we can write
Am Ac 0.6 1 1.6
= =
Am Ac 0.6 1 0.4
1.6
Am + Ac = × (Am – Ac)
0.4
1.6
= × (-3) = 12 V
0.4
34. The ratio of speed of sound in hydrogen gas to the speed of sound in oxygen gas at the same temperature is :
(1) 1 : 4 (2) 1 : 2 (3) 1 : 1 (4) 4 : 1
Sol. (4)
RT
Using v =
m
U H2 m O2 32 16
= = = =4:1
v O2 m H2 2 1
(since both hydrogen and oxygen are di-atomic, will be same)
35. A dipole comprises of two charged particles of identical magnitude q and opposite in nature. The mass 'm' of
the positive charged particle is half of the mass of the negative charged particle. The two charges are separated
by a distance 'l'. If the dipole is placed in a uniform electric field ' E '; in such a way that dipole axis makes a
very small angle with the electric field, ' E '. The angular frequency of the oscillations of the dipole when
released is given by :
4qE 8qE 8qE 4qE
(1) (2) (3) (4)
3ml ml 3ml ml
Sol. (1)
In this case, since masses of both charges are not same, therefore, we need to find center of mass (COM), about
which dipole will oscillate and then we will find moment of Inertia about this axis, to find torque & hence .
As we know, COM will divide length in the inverse ratio of the masses, therefore, COM will be at a distance of
L 2L
from 2m & from m.
3 3
MI about this axis E
2 2 q1 m
L 2L L q
I = 2m +
3 3 –q2 m
2mL2 4mL2 6mL2 2mL2
Or I = + = =
a a a 3
2mL2
Using = & p = qL
3
qLE 3qE
= 2
= None of these given option is correct. (BONUS)
2L 2mL
3
36. Given below are two statements: one is labelled as Assertion A and the other is labelled as Reason R
Assertion A : When you squeeze one end of a tube to get toothpaste out from the other end. Pascal's principle
is observed.
Reason R : A change in the pressure applied to an enclosed incompressible fluid is transmitted undiminished
to every portion of the fluid and to the walls of its container.
In the light of the above statements, choose the most appropriate answer from the options given below
(1) A is correct but R is not correct
(2) Both A and R are correct and R is the correct explanation of A
(3) A is not correct but R is correct
(4) Both A and R are correct but R is NOT the correct explanation of A
Sol. (2)
As per pascal’s law, when we apply pressure to an ideal liquid it is equally distributed in the entire liquid and
to the walls as well.
Since due to applied pressure, every morning, the tooth paste does not get compressed and we can safely
consider it on incompressible liquid.
Therefore both statements are true and R is correct explanation of A.
37. A student is provided with a variable voltage source V, a test resistor R T 10 , two identical galvanometers
G 1 and G 2 and two additional resistors, R 1 10M and R 2 0.001 . For conducting an experiment to
verify ohm's law, the most suitable circuit is :
(1) (2)
(3) (4)
Sol. (2)
This question is based on the conceptual clarity that we should connect ammeter in series and voltmeter in
parallel to measure current and potential difference, respectively
Also, when we use a galvanometer to create an ammeter, shunt resistance should be very small and should be
in parallel.
When we create a voltemeter shunt should be large and in series with galvanometer.
All these criteria are satisfied in option (2)
38. A body cools in 7 minutes from 60 o C to 40 o C . The temperature of the surrounding is 10o C . The temperature
of the body after the next 7 minutes
(1) 30 o C (2) 34 o C (3) 32 o C (4) 28o C
Sol. (4)
Method-1
Using exact law of cooling
T – Ts = (T0 – Ts) e-Kt
Case-I: (40 – 10) = (60 – 10) e-7K
30 = 50e-7K ….(1)
Case-II: (T – 10) = (40 – 10) e-7K or T - 10 = 30 e–7K
Dividing (2) by (1)
T 10 30
=
30 50
30 30
T – 10 = = 18
50
or T = 28 °C
Methode-2
Using newton’s average law of cooling
Ti Tf T Tf
=k i Ts
t 2
60 40 60 40 20
Case-I:- =R 10 = k [40] ….(i)
7 2 7
40 T 20 T
Case-II:- =R ….(2)
7 2
Dividing (2) by (1)
40 T 20 T
=
20 80
160 – 4T = 20 + T
5T = 140
T = 28 °C
39. The energy density associated with electric field E and magnetic field B of an electromagnetic wave in free
space is given by ( 0 permittivity of freespace, 0 permeability of freespace)
0 E 2 B2 E2 B2
(1) U E , UB (2) U E , UB 0
2 2 0 2 0 2
E2 B2 0 E 2 B2
(3) U E , UB (4) U E , UB 0
2 0 2 0 2 2
Sol. (1)
By theory of electromagnetic waves
1
UE = 0E2 and
2
1 B2
UB =
2 0
40. The weight of a body on the surface of the earth is 100 N. The gravitational force on it when taken at a height,
from the surface of earth, equal to one-fourth the radius of the earth is :
(1) 64 N (2) 25 N (3) 100 N (4) 50 N
Sol. (1)
GMm
using newton’s formula F =
r2
GM e m
at surface of earth, 100 = ….(1)
Re 2
R 5
at r = Re + e = Re
4 4
GM e m 16 GM e m
F’ = 2
= ×
5 25 R e2
R e
4
16
F’ = × 100 = 64 N
25
41. A capacitor of capacitance 150.0 F is connected to an alternating source of emf given by E = 36 sin(120t) V.
The maximum value of current in the circuit is approximatively equal to :
1
(1) 2A (2) 2 2A (3) A (4) 2A
2
Sol. (4)
Given alternating AC source E = 36 sin (120 t) v & capacitor C = 150 F
using Q = CV
we can write Q = (CE0 sin t)
dQ
Current i = = (CE0 cos t)
dt
max. value of current i0 = CE0
or i0 = 150 × 10-6 × 36 × 120
= 2.03 A
42. A 2 meter long scale with least count of 0.2 cm is used to measure the locations of objects on an optical bench.
While measuring the focal length of a convex lens, the object pin and the convex lens are placed at 80 cm mark
and 1 m mark., respectively. The image of the object pin on the other side of lens coincides with image pin that
is kept at 180 cm mark. The % error in the estimation of focal length is :
(1) 0.51 (2) 1.02 (3) 0.85 (4) 1.70
Sol. (4)
Based on the data provided
U = 100 – 80 = 20 cm
V = 180 – 100 = 80 cm
1 1 1 uv 20 80
Using or f = = or f = 16 cm
f v u u v 20 80
For error analysis,
1 1 1
f v u
Differentiating
Df Dv u
–
2
= – 2
–
f v u2
To calculate u & v
U = (100 ± 2) – (80 ± 0.2) = (20 ± 0.4) cm
Therefore u = 0.4 cm,
Similarly v = 0.4 cm.
f v u
Now = f 2 2 80
f v u
0.4 100
f 0.4
= 16 180 cm
f 80 2 (20) 2
(Note: every data is in cm)
f 16 0.4 1
= 2 1
f 20 4
2
16 0.4 17 17 0.4
= =
2 16 400
20
f 17 0.4
% Error : × 100 = 1000
f 400
= 1.7
43. Figure shows a part of an electric circuit. The potentials at points a, b and c are 30 V, 12 V and 2 V respectively.
The current through the 20 resistor will be
1
44. A small particle of mass m moves in such a way that its potential energy U m 2 r 2 where is constant
2
and r is the distance of the particle from origin. Assuming Bohr's quantization of momentum and circular orbit,
the radius of nth orbit will be proportional to,
1
(1) n (2) n2 (3) (4) n
n
Sol. (4)
1
Given U = m2r2, to find radius r as f (n), where n is orbit
2
nh
Using Bohr’s postulate : angular momentum L = mvr =
2
nh
or mr2 =
2
r n
45. Given below are two statements : one is labelled as Assertion A and the other is labelled as Reason R
Assertion A : Diffusion current in a p-n junction is greater than the drift current in magnitude if the junction is
forward biased.
Reason R: Diffusion current in a p-n junction is from the n-side to the p-side if the junction is forward biased.
In the light of the above statements, choose the most appropriate answer from the options given below
(1) A is not correct but R is correct
(2) Both A and R are correct and R is the correct explanation of A
(3) Both A and R are correct but R is NOT the correct explanation of A
(4) A is correct but R is not correct
Sol. (4)
Statement A is correct and Statement R is wrong as per the theory of p-n junction.
47. A child of mass 5 kg is going round a merry-go-round that makes 1 rotation in 3.14 s. The radius of the merry-
go-round is 2 m. The centrifugal force on the child will be
(1) 40 N (2) 100 N (3) 80 N (4) 50 N
Sol. (1)
Given, m = 5kg, R = 2 m
time t for 1 rev = 3.14 sec or sec
q for 1 rev = 2 rad
q 2
Therefore = = = 2 rad/s
t
centrifugal force F = mR2
or F = 5 × 2 × 22 = 40 N
48. As shown in the figure, a particle is moving with constant speed m/s. Considering its motion from A to B, the
magnitude of the average velocity is :
49. The work functions of Aluminium and Gold are 4.1 eV and and 5.1 eV respectively. The ratio of the slope of
the stopping potential versus frequency plot for Gold to that of Aluminium is
(1) 1 (2) 2 (3) 1.24 (4) 1.5
Sol. (1)
Using KEmax = eVs = hf –0
where 0 is work function, Vs is stopping potential and f is frequency
h
or Vs = f 0
e e
therefore the slope m will be same for all graphs and will be independent of 0.
50. A particle starts with an initial velocity of 10.0 ms-1 along x-direction and accelerates uniformly at the rate of
2.0 ms-2. The time taken by the particle to reach the velocity of 60.0 ms-1 is __________.
(1) 3s (2) 6s (3) 25s (4) 30s
Sol. (3)
Using Ist equation of motion
vu
t=
a
60 10 50
t= = = 25 sec
2 2
SECTION - B
51. A simple pendulum with length 100 cm and bob of mass 250 g is executing S.H.M. of amplitude 10 cm. The
x
maximum tension in the string is found to be N . The value of x is __________.
40
Sol. (99)
For pendulum
mv 2
Tmax = mg + ….(1)
L
1
Given m = kg, L = 1m, g = 9.8 m/s2
4
1
and amplitude A = m
10
1 1
For SHM, KEmax = mv2 = m2A2
2 2
g
using =
L
2
g 2 mgA 2
mv = m
2
A = ….(2)
L L
using (2) in (1)
mgA 2
Tmax = 2 mg +
L2
1 1 01
= mg 1 2 = × 9.8 ×
10 4 100
98.98
or Tmax =
40
Therefore x = 99
52. Experimentally it is found that 12.8 eV energy is required to separate a hydrogen atom into a proton and an
9
electron. So the orbital radius of the electron in a hydrogen atom is 10 10 m . The value of the x is : _______.
x
1
(1 eV = 1.6 × 10-19 J, 9 109 Nm 2 / C2 and electronic charge = 1.6 × 10-19 C)
40
Sol. (16)
ke 2
Using E =
2r
Re 2
r=
2E
Given E = 12.8 eV = 12.8 × e Joule
9 109 e 2 9 109 1.6 10 19
r= =
2 12.8e 2 12.8
9 10 10
9 10 10
r= = m
(2 12.8 / 1.6) 10
Therefore x = 16
53. A beam of light consisting of two wavelengths 7000 Å and 5500 Å is used to obtain interference pattern in
Young's double slit experiment. The distance between the slits is 2.5 mm and the distance between the place of
slits and the screen is 150 cm. The least distance from the central fringe, where the bright fringes due to both
the wavelengths coincide, is n × 10-5 m. The value of n is ______.
Sol. (462)
Let n1 maxima of 7000 Å coincides with n2 maxima of 5500 Å
therefore n11 = n22
n 5500 11
or 1 2 = =
n 2 1 7000 14
therefore 11 maxima of 7000 Å will coincide with 14th maximum of 5500 Å
th
54. Two concentric circular coils with radii 1 cm and 1000 cm, and number of turns 10 and 200 respectively are
placed coaxially with centers coinciding. The mutual inductance of this arrangement will be _______ × 10-8 H.
(Take, 2 10)
Sol. (4)
Given
a = 1000 cm
b = 1 cm
or b << a
we will take larger coil as primary
0i p N
B=
2a
0i p N
flux s = BA = × b2 × n
2a
s
Mutual inductance M =
ip
0 Nnb 2
M=
2a
4 10 7 200 10 1 10 4
or M =
2 1000 10 2
2 -9
= 4 × 10
or M = 4 × 10-8 (using 2 = 10)
55. As shown in the figure, two parallel plate capacitors having equal plate area of 200 cm2 are joined in such a way
that b. The equivalent capacitance of the combination is x 0 F. The value of x is _______.
Sol. (5)
As per the arrangement given, distance between the capacitor plates are a and b and a b
using the diagram we can write
b = 5 – a – 1 = (4 – a) in mm
A
as we know capacitance of capacitor C = 0
d
and in series arrangement
1 1 1
Ceq C1 C 2
1 a 4a 4(in mm)
= + =
C eq 0 A 0 A 0 A
0 A
or Ceq =
4(mm)
Given A = 200 cm2
200 10 4
Ceq = 0
4 10 3
= 0 50 × 10-1
or Ceq = 50 farad
therefore n =5
56. A proton with a kinetic energy of 2.0 eV moves into a region of uniform magnetic field of magnitude 10 3 T.
2
The angle between the direction of magnetic field and velocity of proton is 60 o. The pitch of the helical path
taken by the proton is ______ cm.
(Take, mass of proton = 1.6 × 10-27 kg and Charge on proton = 1.6 × 10-19 C).
Sol. (40)
B= × 10-3
2
1
K.E. = mV2
2
2KE
V=
m
57. A body is dropped on ground from a height 'h1' and after hitting the ground, it rebounds to a height 'h2'. If the
ratio of velocities of the body just before and after hitting ground is 4, then percentage loss in kinetic energy of
x
the body is . The value of x is ________.
4
Sol. (375)
Let u and v be speeds, just before and after body strikes the ground.
u 4
Given
v 1
1 1
mu 2 mv 2
loss in KE: KE = 2 2
1
mu 2
2
2
v 1 15
KE = 1 - = 1
u 16 16
15
Percentage loss = × 100 = 375
16
58. A ring and a solid sphere rotating about an axis passing trough their centers have same radii of gyration. The
2
axis of rotation is perpendicular to plane of ring. The ratio of radius of ring to that of sphere is . The value
x
of x is ______.
Sol. (5)
Given radius of gyration is same for ring and solid sphere
KR = Kss
2
RR = R ss
5
R 2
or R =
R ss 5
therefore x = 5
59. As shown in the figure, the voltmeter reads 2 V across 5 resistor. The resistance of the voltmeter is ___ .
Sol. (20)
Method-I:
5R 10 7R
Req = 2 + =
5R 5R
3 3(5 R)
i= =
R eq 10 7R
2 2
i1 = , i2 =
5 R
i = i1 + i2
3(5 R) 2 2 2(5 R)
= =
10 7R 5 R 5R
15R (5 + R) = 2 (5 + R) (10 + 7R)
75R + 15R2 = 2 (50 + 35R + 10R + 2R2)
15R2 + 75R = 14R2 + 90R + 100
R2 – 15 R – 100 = 0
15 225 1 100
R=
2
15 625 15 25
= =
2 2
R = 20
Method-II:
Given potential across 5and voltmeter is 2V. To find resistance R of voltmeter.
Let current in 5 be i1, and in R i2.
2 2
i1 = and i2 =
5 R
1
V across 2will be 1 volt and i = A.
2
Using junction law: i = i1 + i2
1 2 2
= +
2 5 R
2 1 2 1
= – =
R 2 5 10
R = 20
60. A metal block of mass m is suspended from a rigid support through a metal wire of diameter 14 mm. The tensile
stress developed in the wire under equilibrium state is 7 × 105 Nm-2 . The value of mass m is _____kg.
22
(Take, g = 9.8 ms-2 and )
7
Sol. 11
force mg
Using stress =
area A
S A 7 105 R 2
m= =
g g
22
7 105 (7 10 3 ) 2
7 (Note: 14 mm is diameter)
9.8
= 11 kg
SECTION - A
61. Match List I with List II
List I List II
(Natural Amino acid) (One Letter Code)
(A) Arginine (I) D
(B) Aspartic acid (II) N
(C) Asparagine (III) A
(D) Alanine (IV) R
Choose the correct answer from the options given below:
(1) (A) – III, (B) – I, (C) – II (D) –IV (2) (A) – IV, (B) – I, (C) – II (D) –III
(3) (A) – IV, (B) – I, (C) – III (D) –II (4) (A) – I, (B) – III, (C) – IV (D) –II
Sol. 2
Natural Amino acid One Letter Code
(i) Arginine R
(ii) Aspartic acid D
(iii) Asparagine N
(iv) Alanine A
62. Formation of which complex, among the following, is not a confirmatory test of Pb2 ions
(1) lead sulphate (2) lead nitrate (3) lead chromate (4) lead iodide
Sol. 2
Pb(NO3)2 is a soluble colourless compound so it cannot be used in confirmatory test of Pb+2 ion.
64. Group–13 elements react with O 2 in amorphous form to form oxides of type M2 O3 (M = element). Which
among the following is the most basic oxide?
(1) Al2O3 (2) Tl2 O3 (3) Ga 2 O3 (4) B2O3
Sol. 2
As electropositive character increases basic character of oxide increases.
B2 O3 Al2 O3 Ga 2 O3 In 2 O3 Tl2 O3
acidic amphoteric basic
a
b
c
(i) Since C is eluting first and a is last that means C is least power and a is most polar.
(ii) So incorrect options will be (A), (B), (C)
69. Ion having highest hydration enthalpy among the given alkaline earth metal ions is:
(1) Be2 (2) Ba 2 (3) Ca 2 (4) Sr 2
Sol. 1
1
Hydration enthalpy
size
Down the group as size increases hydration enthalpy decreases
Order: Be2+ > Mg+2 > Ca+2 > Sr+2 > Ba+2
Topic : Alcohol
Sub Topic : Acidic Strength
Level : Easy
70. The strongest acid from the following is
Sol. 4
OH OH OH OH
Cl CH3 NO2
–I +I –I
Since –I of –NO2 > Cl
So, most acidic will be (4)
Topic : Hydrogen
Sub Topic : Alkene-Chemical Properties
Level : Moderate
71. In the following reaction, ‘B’ is
(1) (2)
(3) (4)
Sol. 4
H
OH OH2
–CH3–Shift
H
72. Structures of BeCl2 in solid state, vapour phase and at very high temperature respectively are:
(1) Polymeric, Dimeric, Monomeric (2) Dimeric, Polymeric, Monomeric
(3) Monomeric, Dimeric, Polymeric (4) Polymeric, Monomeric, Dimeric
Sol. 1
In solid state BeCl2 as polymer, in vapour state it form chloro-bridged dimer while above 1200K it is monomer.
Topic : Chemical Kinetic
Sub Topic : Complex Reaction/Activation energy
Level : Moderate
73. Consider the following reaction that goes from A to B in three steps as shown below:
AC-1 AC-3
A
Inter- Inter- B
mediate-1 mediate-2
Number of Intermediate 2
Number of Activated complex 3
Rate determining step II
Topic : Electrochemistry
Sub Topic : Electrolyte Cell
Level : Easy
74. The product, which is not obtained during the electrolysis of brine solution is
(1) HCl (2) NaOH (3) Cl2 (4) H 2
Sol. 1
Brine solution (NaCl + H2O)
NaCl Na+ + Cl–
Electrolyte
H2O 2H+ + OH–
At Cathode 2H + 2e H2
At Anode 2Cl– Cl2 + 2e
Na+ + OH– NaOH
Answer 1 (HCl)
75. Which one of the following elements will remain as liquid inside pure boiling water?
(1) Li (2) Ga (3) Cs (4) Br
Sol. 2
Li, Cs reacts vigorously with water.
Br2 changes in vapour state in boiling water (BP = 58°C)
Ga reacts with water above 100°C (MP = 29°C, BP = 2400°C)
76. Given below are two statements: one is labelled as “Assertion A” and the other is labelled as “Reason R”
Assertion A: In the complex Ni(CO)4 and Fe(CO)5 , the metals have zero oxidation state.
Reason R: Low oxidation states are found when a complex has ligands capable of –donor character in addition
to the – bonding.
In the light of the above statement, choose the most appropriate answer from the options given below
(1) A is not correct but R is correct.
(2) A is correct but R is not corret
(3) Both A and R are correct and R is the correct explanation of A
(4) Both A and R are correct but R is NOT the correct explanation of A.
Sol. 2
Low oxidation state of metals can stabilized by synergic bonding so ligand has to be -acceptor.
78. Find out the major product from the following reaction.
(1) MeMgBr/CuI
(2)n Pr l
(1) (2)
(3) (4)
Sol. 3
O O
Me + MgBr n—Pr—I
CuI
O
79. During the reaction of permanganate with thiosulphate, the change in oxidation of manganese occurs by value
of 3. Identify which of the below medium will favour the reaction
(1) aqueous neutral (2) aqueous acidlic
(3) both aqueous acidic and neutral (4) both aqueous acidic and faintly alkaline
Sol. 1
In neutral or weakly alkaline solution oxidation state of Mn changes by 3 unit
7 4
Mn O4–1 Mn O2
Topic : Carbonyl
Sub Topic : Chemical Properties
Level : Easy
83. Among the following the number of compounds which will give positive iodoform reaction is________
(a) 1–Phenylbutan–2–one
(b) 2–Methylbutan–2–ol
(c) 3–Methylbutan–2–ol
(d) 1–Phenylethanol
(e) 3,3–dimethylbutan–2–one
(f) 1–Phenylpropan –2–ol
Sol. 4
Iodo form test
(a) Ph –NO
O
(b) –NO
OH
(c) –Yes
OH
Ph
(d) –Yes
OH
(e) –Yes
O
OH
(f) –Yes
Ph
For carbonyl compound —C—CH3 for alcohol —CH—CH3 should be present for idoform test.
O OH
NH2
(v)
Topic : Liquid Solution
Sub Topic : Osmotic Pressure
Level : Easy
85. Consider the following pairs of solution which will be isotonic at the same temperature. The number of pairs of
solutions is/are______________
A. 1 M aq. NaCl and 2 M aq. Urea
B. 1 M aq. CaCl2 and 1.5 M aq. KCl
C. 1.5 M aq. AlCl3 and 2 M aq. Na 2SO4
D. 2.5 M aq. KCl and 1 M aq. Al2 (SO4 )3
Sol. 4
A. 1 M aq. NaCl 2 M aq. Ions
Isotonic
2 M aq. Urea 2 M aq. Urea
O
H H
H O H
O H H O
H H
H
O H
Topic : Thermochemistry
Sub Topic : Heat of Combustion
Level : Moderate
88. Consider the following date
Heat of combustion of H2 (g) = –241.8 kJ mol–1
Heat of combustion of C(s) = –393.5 kJ mol–1
Heat of combustion of C2 H5OH(l) = –1234.7 kJ mol–1
The heat of formation of C2 H5OH(l) is (–) __________________kJ mol–1 (Nearest integer).
Sol. 278
2C(s) + O2 2CO2 –393.5 × 2 = –787 kJ …(1)
3
3H2 + O2 3H2O –241.5 × 8 × 3 = –725.4 kJ …(2)
2
C2H5OH + 3O2 2CO2 + 3H2O –1234.7 kJ …(3)
3H2O + 2CO2 C2H5OH + 3O2 +1234.7 kJ …(4)
1
2C(s) + 3H2(g) + O2 C2H5OH …(5)
2
If 0.2 mol of Cl2 is added at the same temperature, the equilibrium concentrations of PCl5 is _____×
10–2 mol L–1
Given: K C for the reaction at 298 K is 20
Sol. 48
[PCl5 ] 0.4
Kc 20
[PCl3 ][Cl2 ] 0.2 0.1
PCl3 + Cl2 PCl5
teq1 0.2 M 0.1 M 0.4 M
teq2 0.2 – x 0.1 + 0.2 – x 0.4 + x
0.4 x
K c 20
(0.2 x)(0.3 x)
After solving by quadratic equation. We can get value of x.
X = 0.084
[PCl5] = 0.4 + x
= 0.4 + 0.084
= 0.484 = 48.4 10–2
Ans. 48
90. The number of species having a square planar shape from the following is___________________
XeF4 ,SF4 ,SiF4 ,BF4– ,BrF4– [Cu(NH3 ) 4 ]2 ,[FeCl 4 ]2– ,[PtCl 4 ]2–
Sol. 4
XeF4 ,BrF4– [Cu(NH3 ) 4 ]2 ,[PtCl4 ]2– has square planar shape.
SECTION – A
1.
The area of the region (x, y) : x 2 y 8 x 2 , y 7 is.
(1) 24 (2) 21 (3) 20 (4) 18
Sol. (3)
y x2 y 8 x2 y7
x2 = 8 – x2
x2 = 4
x=+2
2
1
2 1.7 8 2x 2 dx 2 x 2 dx
1 0
2x 3 x 3
2 1
2 7 8x
2
3 1 3 0
16 2 1
2 7 16 8 2
3 3 3
32 22 10 2
2 7 2 7
3 3 3 3
60
20
3
3 1
Let P = 2 2 , A = 1 1 a b
2. and Q = PAPT. If PT Q2007 P , then 2a+ b -3c – 4d equal to
1 3 0 1 c d
-
2 2
(1) 2004 (2) 2007 (3) 2005 (4) 2006
Sol. (3)
Q = PAPT
PT. Q2007. P = PT. Q.Q … Q.P
= PT(PAPT) (P.APT) … (PAPT)P.
(PTP)A(PTP)A … A(PTP)
3 1 3 1
2 2 2 2 1 0 I
PT.P =
1 2 3 1 3 0 1
2 2 2
PT. Q2007. P = A2007
1 1 1 1 1 2
A2 =
0 1 0 1 0 1
1 2007 a b
A2007 =
0 1 c d
a = 1, b = 2007, c = 0, d = 1
2a + b – 3c – 4d = 2 + 2007 – 4 = 2005
3. Negation of (p q) (q p) is
(1) (-q) p (2) p (~ q) (3) (~ p) q (4) q (~ p)
Sol. (4)
p q q p
p q q p
p q q p
p q q p
q p.
4x + 28y = 244
4x + 3y = 69
– – –
_________
25y = 175
y = 7, x = 12
A(12, 7)
– 3x + 4y = 17
3x + 21y = 183
___________
25y = 200
y = 8, x = 5
B(5, 8)
Circumcenter
17 15
2 2
17 15
,
2 2
2
1+16 = 17
5. Let , , , be the three roots of the equation x3 + bx + c = 0. If = 1= -, then b3 + 2c3 – 33 – 63 – 83 is
equal to
155 169
(1) (2) 21 (3) 19 (4)
8 8
Sol. (3)
= 1
= – 1
Put = –1
–1–b+c=0
c–b=1
also
.. = – c
–1=–c c=1
b=0
x3 + 1 = 0
= – 1, = – w, = – w2
b3 + 2c3 – 33 – 63 – 83
0 + 2 + 3 + 6 + 8 = 19
6. Let the number of elements in sets A and B be five and two respectively. Then the number of subsets of A × B
each having at least 3 and at most 6 elements is:
(1) 752 (2) 772 (3) 782 (4) 792
Sol. (4)
n A B 10
10
C3 10 C4 10 C5 10 C6 792
7. If the coefficients of three consecutive terms in the expansion of (1 + x)n are in the ratio 1 : 5 : 20, then the
coefficient of the fourth term is
(1) 5481 (2) 3654 (3) 2436 (4) 1817
Sol. (2)
n n
Cr Cr 1
n
5 n
4
Cr 1 Cr
n r 1
5 n 5r 4 …(2)
r
n = 6r – 1 … (1)
n 29,r 5
29
Coeff of 4th term = C3
= 3654
8. Let R be the focus of the parabola y2 = 20x and the line y = mx + c intersect the parabola at two points P and Q.
Let the point G(10, 10) be the centroid of the triangle PQR. If c – m = 6, then (PQ)2 is
(1) 325 (2) 346 (3) 296 (4) 317
Sol. (1)
y2 = 20x , y = mx + c
yc
y2 = 20
m
20y 20c y1 y 2 y3
y2 – 0 10
m m 3
20
30
m
m2
3
and c – m = 6
2 20
c= 6 c
3 3
20 20
y2 – 30y + 3 0 y2 – 30y + 200 = 0
2
3
y = 10, y = 20
y = 20, x = 20 P(5, 10); (20, 20)Q
20 5 x
10 x = 5 PQ2 = 152 + 102 = 225 + 100 = 325
3
1+ 2 + ... + K n n
9. Let SK and S2 = (Bn2 + Cn+D), where A, B, C, D N and A has least value. Then
K j=1 j A
(1) A + B is divisible by D (2) A + B = 5 (D –C)
(3) A + C + D is not divisible by B (4) A + B + D is divisible by 5
Sol. (1)
k 1
Sk
2
k 2
1 2k
S2k
4
n
1 n n 1 2n 1
S2j n n n 1
j1 4 6
n n 1 2n 1
1 n 1
4 6
n 2n 2 3n 1
n 2
4 6
n 2n 2 9n 13 n
2n 9n 13
2
4 6 24
A = 24, B = 2, C = 9, D = 13
Sd
a b n n
1 2
n1 n 2
a 4, 2, 3
b 1,3, 4
n1 4,5,3
n 2 3, 4, 2
i j k
n1 n 2 4 5 3 ˆi 2 ˆj 1 kˆ 1 2,1,1
3 4 2
Sd
3, 5, 7 2,1,1 6 5 7 3 6
6 6
11. The number of arrangements of the letters of the word "INDEPENDENCE" in which all the vowels always
occur together is.
(1) 16800 (2) 14800 (3) 18000 (4) 33600
Sol. (1)
IEEEE,
NNN, DD, P, C
8! 6!
16800
3!2! 41
12. If the points with position vectors ˆi 10jˆ 13k, ˆ 9 ˆi ˆj 8kˆ are collinear, then (19 - 6)2 is
ˆ 6iˆ 11jˆ 11k,
2
equal to
(1) 49 (2) 36 (3) 25 (4) 16
Sol. (2)
,10,13 ; 6,11,11 , , , 8
9
2
6 1 2
3 11 19
2
3
6 19 22 2
19
3 117
6 2 41
19 19
19 6 117 123 36
2 2
13. In a bolt factory, machines A, B and C manufacture respectively 20%, 30% and 50% of the total bolts. Of their
output 3, 4 and 2 percent are respectively defective bolts. A bolt is drawn at random form the product. If the
bolt drawn is found the defective, then the probability that it is manufactured by the machine C is.
5 3 9 2
(1) (2) (3) (4)
14 7 28 7
Sol. (1)
3 5
P(A) = P(B) = P(C) =
10 10 10
P(Defective/A) =
3
100
, P Defective
B
4
100
, P Defective
C
2
100
5 2
10 100 10
P(E) =
2
3
3 4
5 2 6 12 10
10 100 10 100 10 100
10
28
5
14
14. If for z = + i, |z + 2| = z + 4(1 +i), then + and are the roots of the equation
(1) x2 + 3x -4 = 0 (2) x2 + 7x + 12= 0
2
(3) x + x -12 = 0 (4) x2 + 2x -3 = 0
Sol. (2)
|z + 2| = |+ i+ 2|
i 4 4i
2 2 4 i 4
2
+4=0
2 16 4
2 2
=–4
2 4 4 16 2 16 8
4 = 4
=1
= 1, = – 4
+ = – 3, = – 4
Sum of roots = – 7
Product of roots = 12
x2 + 7x + 12 = 0
16. The number of ways, in which 5 girls and 7 boys can be seated at a round table so that no two girls sit together,
is
(1) 7(720)2 (2) 720 (3) 7(360)2 (4) 126(5!)2
Sol. (4)
6! 7 C5 5!
720 21 120
2 360 7 3 120
126 5!
2
18. If the eqation of the plane containing the line x + 2y + 3z – 4 = 0 2x + y –z + 5 and perpendicular to the plane
r (iˆ ˆj) (iˆ ˆj k)
ˆ (iˆ 2jˆ 3k)
ˆ is ax+by +cz = 4, then (a-b+c) is equal to
(1) 22 (2) 24 (3) 20 (4) 18
Sol. (1)
D.R’s of line n1 5iˆ 7j ˆ
ˆ 3k
D.R’s of normal of second plane
n2 5iˆ 2j ˆ
ˆ 3k
n1 n2 27iˆ 30j ˆ
ˆ 25k
11 14
A point on the required plane is 0, ,
5 5
The equation of required plane is
27x + 30y + 25z = 4
a – b + c = 22
2 1 0
19. Let A = 1 2 1 . If |adj(adj(adj2A))| =(16)n, then n is equal to
0 1 2
(1) 8 (2) 9 (3) 12 (4) 10
Sol. (4)
|A| = 2[3] – 1[2] = 4
adj adj adj2A
3
n1 8
2A 2A 16n
8
23 A 16n
2
8
3
22 16n
240 16n
1610 16n n 10
(x 1)
20. Let I(x) = dx, x > 0. If lim I(x) 0, then I(1) is equal to
x(1 x ex )2 x
e 1 e2
(1) log e (e 1) (2) log e (e 1)
e2 e 1
e2 e 1
(3) log e (e 1) (4) log e (e 1)
e 1 e2
Sol.
Ix
x 1 dx
x 1 xe x
2
1 xex t
xex ex dx dt
1
x 1 dx dt
ex
dt dt dt t t 1
t 1 t t t 1 t t t 1 t dt
xex.t2 2
dt dt t t 1 1
t t 1 t2 t t 1 dt t c
1
ln t 1 ln t c
t
1
ln xex ln 1 xex c
1 xex
xex 1
I(x) = ln x
c
1 xe 1 xex
lim I x c 0
x
e 1
I 1 ln
1e 1e
1
lne ln 1 e
1e
e2
ln 1 e
e 1
SECTION - B
21. Let A = {0,3 4, 6, 7, 8, 9, 10} and R be the relation defined on A such that R ={x,y) A × A: x – y is odd
positive integer or x – y = 2}. The minimum number of elements that must be aadded to the relation R, so that
it is a symmetric relation, is equal to ______.
Sol. (19)
A = {0, 3, 4, 6, 7, 8, 9, 10} 3, 7, 9 odd
R x y odd veor x y 2 0, 4, 6, 8, 10 even
3
C1 5 C1 15 (6, 4), (8, 6), (10, 8), (9, 7)
Minm ordered pairs to be added must be
: 15 + 4 = 19
7
1
22. Let (t) denote the greatest integer t, If the constant term in the expansion of 3x 2 5 is , then [ ] is
2x
equal to ______.
Sol. (1275)
7
2 1
3x 5
2x
r
1
Tr 1 Cr 3x
7
2 7r
5
2x
14 – 2r – 5r = 14 – 7r = 0
r 2
1 21 243
2
T3 C2 .3
7
1275.75
2 4
1275
5
23. Let 1, 2 be the values of for which the points ,1, and (–2, 0, 1) are at equal distance from the plane 2x
2
x 5 y 1 z 7
+ 3y – 6z + 7 = 0. If 1 > 2, then the distance of the point (12, 2, 1) from the line is
1 2 2
______.
Sol. 9
5
2x + 3y – 6z + 7 = 0 ,1, , 2, 0,1
2
5 3 6 7 4 6 7
d1 d2
7 7
15 6 3
15 – 6 = 3 or 15 – 6 = – 3
6 = 12 6 = 18
=2 =3
1 = 3, 2 = 2
x 5 y 1 z 7
P 1, 2,3
1 2 2
d
4, 1, 10 1, 2, 2
18i 18j 9kˆ
9
3 3
24. If the solution curve of the differential equation (y-2 loge x)dx + (x loge x2) dy = 0, x > 1 passes through the
4
points e, and e4 , , then is equal to ______.
3
Sol. (3)
y 2ln x dx 2x ln x dy 0
dy 2x ln x 2ln x y dx
dy 1 y
dx x 2x ln x
dy y 1
dx 2x ln x x
1
dx
I.F = e 2x ln x
1 dt 1
ln ln x
= e2 t
= e2
I.F lnx
1
2
y ln x
ln x
x
dx Let , lnx u
2
1
2 u2du dx 2udu
x
ln x 2 c e,
2 3 4
y ln x
3 3
4 2 2
cc
3 3 3
y ln x ln x 2 e 4 ,
2 3 2
3 3
2 2
2 8
3 3
3
25. Let a 6iˆ 9jˆ 12k,
ˆ b ˆi 11jˆ 2kˆ and c be vectors such that a c a b . If a.c 12,c.(iˆ 2jˆ k)
ˆ 5,
then c.(iˆ ˆj k)
ˆ is equal to ___.
Sol. (11)
a c a 5
a c b 0
a ||rl c b
a c b
6,9,12 x , y 11, z 2
x y 11 z 2
2 3 4
4y – 44 = 3z + 6
4y – 3z = 50
6x + 9y + 12z = – 12
2x + 3y + 4z = – 4 ( x – 2y + z = 5)
2x – 4y + 2z = 10
+ – –
_______________
7y + 2z = – 14 …(2)
8y – 6z = 100
21y + 6z = – 42
____________
29y = 58
y = 2, z = – 14
x – 4 – 14 = 5
x = 23
c 23, 2, 14
c 1,1,1 23 2 14 11
26. The largest natural number n such that 3n divides 66! is ______.
Sol. (31)
66 66 66
3 9 27
22 + 7 + 2 = 31
n3
27. If aa is the greatest term in the sequence an= , n = 1,2,3,..., then a is equal to ______.
n 4 147
Sol. (0.158)
x3
f(x) =
x 4 147
f ' (x) =
x 4
147 3x 2 x 3 4x 3
x 147
4 2
3x 6 147 3x 2 4x 6
x 2 44 x 4
ve
f ' x 0 at x6 = 147 × 3x2
x2 = 0, x4 = 147 × 3
x = 0, x2 = + 147 3
x2 = + 21
x = + 21
28. Let the mean and variance of 8 numbers x, y, 10, 12, 6, 12, 4, 8 be 9 and 9.25 respectively. If x > y, then 3x -2y
is equal to _________.
Sol. (25)
x y 52
9 x + y = 20
8
For variance
x – 9, y – 9, 3, 3, 1, –5, –1, –3
x =0
x 9 y 9 54
2 2
0 2 9.25
8
x 9 11 x
20
2 2
x = 7 or 13 y = 13, 7
3x – 2y = 3 × 13 – 2 × 7 = 25
29. Consider a circle C1 : x2 + y2 – 4x –2y = – 5. Let its mirror image in the line y = 2x +1 be another circle C2 :
5x2 + 5y2 –10fx – 10gy + 36 = 0. Let r be the radius of C2. Then + r is equal to ______.
Sol. (2)
x 2 y2 4x 2y 5 0 ,
C1 2,1 r1
2x – y + 1 = 0
Image of (2, 1)
x2 y 1 2 4 1 1
2 1 5
x2 y 1 8
2 1 5
16 6 8 13
x 2 , y 1
5 5 5 5
36
x2 + y2 – 2fx – 2gy + =0
5
C2(f, g)
36
r2 f 2 g 2
5
36
f 2 g2
5
6 3
f ,g
5 5
36 169 36
25 25 5
36 169 180
1 r 1
25
r 2
5 /6
2
30. Let [t] denote the greatest integer t. The
/6
(8[cosec x] 5[cotx])dx is equal to _____.
Sol. (14)
5
6
8 cosecx dx
6
5
6 16
8 dx 3
16
6
3
5
6
I cot x dx
6
x x
5
6
I cotx dx
6
5
6
2I cot x cot x dx
6
5
1 6
1 4
I
2 dx 2
6
6
.
3
2 16 5 2 21
3 3 3
= 14
SECTION - A
31. A cylindrical wire of mass (0.4 0.01)g has length (8 ± 0.04) cm and radius (6 ± 0.03) mm. The maximum error
in its density will be:
(1) 4% (2) 1% (3) 3.5% (4) 5%
Sol. (1)
Cylindrical wire m = (0.4 ± 0.01) g
= (8 ± 0.04) cm
r = (6 ± 0.03) mm
m 1
Density = 2 r2m-1 = = const.
r
Differentiating after taking log on both side
d 2dr d dm
+ + - =0
r m
m 2 r
= - -
m r
0.01 0.04 0.03
= 2
max 0.4 8 6
= 0.04
max
Percentage error = 0.04 × 100 = 4%
32. The engine of a train moving with speed 10 ms–1 towards a platform sounds a whistle at frequency 400 Hz. The
frequency heard by a passenger inside the train is : (neglect air speed. Speed of sound in air = 330 ms–1)
(1) 400 Hz (2) 388 Hz (3) 200 Hz (4) 412 Hz
Sol. (1)
The passenger inside the train is at rest wrt train so frequency heard by passenger inside the train is same as the
source frequency i.e., 400 Hz.
33. The weight of a body on the earth is 400 N. Then weight of the body when taken to a depth half of the radius of
the earth will be:
(1) 300 N (2) Zero (3) 100 N (4) 200 N
Sol. (4)
Weight on the earth surface = mg
mg = 400 N (given)
GM(R d)
Weight at a depth d w = m
R3
d
W = mg 1
R
R 1 mg
d= w = mg 1 w =
2 2 2
w = 200 N
34. A TV transmitting antenna is 98 m high and the receiving antenna is at the ground level. If the radius of the
earth is 6400 km, the surface area covered by the transmitting antenna is approximately:
(1) 1240 km2 (2) 1549 km2 (3) 4868 km2 (4) 3942 km2
Sol. (4)
Max. distance covered d = 2Rh T
(R = radius of earth, hT = height of antenna)
Area A = d2
A = (2RhT)
A = 2 × 3.14 × 6400 × 98 × 10-3
A 3942 km2
35. Certain galvanometers have a fixed core made of non magnetic metallic material. The function of this metallic
material is
(1) To produce large deflecting torque on the coil
(2) To bring the coil to rest quickly
(3) To oscillate the coil in magnetic field for longer period of time
(4) To make the magnetic field radial
Sol. (2)
To bring the coil at rest quickly
1
36. Dimension of should be equal to
0 0
(1) T/L (2) T2 / L2 (3) L/T (4) L2/T2
Sol. (4)
1
Dimension of
0 0
1 1
C= = c2
0 0 0 0
1 2
= [c ]
0 0
L2
= 2
T
37. Two projectiles A and B are thrown with initial velocities of 40 m/s and 60 m/s at angles 30° and 60° with the
horizontal respectively. The ratio of their ranges respectively is (g = 10 m/s2)
(1) 2 : 3 (2) 3 : 2 (3) 4 : 9 (4) 1 : 1
Sol. (3)
u 2 sin 2
R=
g
{u1 = 40 m/s, 1 = 30°, u2 = 60 m/s, 2 = 60°}
2
R1 u sin 21
= 1
R2 u2 sin 22
sin 60
2
R1 40 R 4
= × 1 =
R2 60 sin120 R2 9
38. In this figure the resistance of the coil of galvanometer G is 2 . The emf of the cell is 4 V. The ratio of potential
difference across C1 and C2 is:
5 4 3
(1) (2) 1 (3) (4)
4 5 4
Sol. (3)
At steady state current will not be in the capacitor branch.
4
i= i
6 28 2
1 i
i= A
4 i i
VC1 i(6 2)
VC2 i(2 8)
VC1 4
VC 2 5
39. A charge particle moving in magnetic field B, has the components of velocity along B as well as perpendicular
to B. The path of the charge particle will be
(1) Helical path with the axis along magnetic field B
(2) Straight along the direction of magnetic field B
(3) Helical path with the axis perpendicular to the direction of magnetic field B
(4) Circular path
Sol. (1)
Path will be helical with axis along uniform B -.
40. Proton (P) and electron (e) will have same de-Broglie wavelength when the ratio of their momentum is (assume,
mp = 1849 me):
(1) 1 : 43 (2) 43 : 1 (3) 1 : 1849 (4) 1 : 1
Sol. (4)
h
Debroglie wavelength =
p
p = e
h h pp
= =1
pp pe pe
41. Graphical variation of electric field due to a uniformly charged insulating solid sphere of radius R, with distance
r from the centre O is represented by:
Sol. (4)
Electric field due to uniformly charged insulating solid sphere
kQr
R 3 r R
E
kQ r R
r 2
43. At any instant the velocity of a particle of mass 500 g is 2tiˆ 3t 2 ˆj ms–1 . If the force acting on the particle at
t = 1s is ˆi xjˆ N . Then the value of x will be:
(1) 2 (2) 6 (3) 3 (4) 4
Sol. (3)
V (2tiˆ 3t 2 ˆj) m/ s , mass m = 500 gm
Force, F ma -
F
1 dv 1 ˆ ˆ
F 2i 6tj
2 dt 2
F ˆi 3tjˆ
At t = 1 s F ˆi 3jˆ
x=3
44. Given below are two statements:
E
Statement I : If E be the total energy of a satellite moving around the earth, then its potential energy will be
2
Statement II : The kinetic energy of a satellite revolving in an orbit is equal to the half the magnitude of total
energy E.
In the light of the above statements, choose the most appropriate answer from the options given below
(1) Both Statement I and Statement II are incorrect
(2) Statement I is incorrect but Statement II is correct
(3) Statement I is correct but Statement II is incorrect
(4) Both Statement I and Statement II are correct
Sol. (1)
2
1 1 GM
For satellite K.E. = mv2 = m
2 2 r
GMm
K.E. =
2r
GMm
Potential energy U = –
r
Total energy = K.E + U
GMm
E=–
2r
U = 2E St I – incorrect
K.E. = |E| St II - incorrect
A
45. Two forces having magnitude A and are perpendicular to each other. The magnitude of their resultant is:
2
5A 5A 2 5A 5A
(1) (2) (3) (4)
2 2 4 2
Sol. (4)
A
F1 A , F2 =
2 2
Fnet = F12 F22
2
A
= A
2
2
5A
Fnet =
2
46. For the logic circuit shown, the output waveform at Y is:
(1) (2)
(3) (4)
Sol. (2)
A
= A.B
y = A.B y = A + B
y=A+B
1 1
A B yAB
0 0 1 1 1
0 0 0
0 1 1 0
1 1
0 0 1 0 1
1 1 1
47. An aluminium rod with Young's modulus Y = 7.0 × 1010 N/m2 undergoes elastic strain of 0.04%. The energy
per unit volume stored in the rod in SI unit is:
(1) 5600 (2) 2800 (3) 11200 (4) 8400
Sol. (1)
Aluminium rod Young’s modulus
N
y = 7.0 × 1010 2
m
strain 0.04%
0.04
strain =
100
1
Energy per unit volume = stress × strain
2
1
= y strain × strain
2
1
= y (strain)2
2
2
1 0.04
= × 7 × 1010 ×
2 100
J
Energy per unit volume = 5600 3
m
SECTION – B
51. The momentum of a body is increased by 50%. The percentage increase in the kinetic energy of the body is
_________ %.
Sol. (125)
P2
Ki i
2m
2
Pi
Pi 9 Pi2
Kf
2
Kf
2m 4 2m
K Ki
Percentage increase in K.E. = f 100
Ki
9
1
= 4 100
1
5
= 100 = 125%
4
52. A nucleus with mass number 242 and binding energy per nucleon as 7.6 MeV breaks into two fragment each
with mass number 121. If each fragment nucleus has binding energy per nucleon as 8.1 MeV, the total gain in
binding energy is __________ MeV.
Sol. (121)
Gain in binding energy = B.Ef – BEi
= 2(121 × 8.1) – 242 × 7.6
= 121 MeV
53. An electric dipole of dipole moment is 6.0 × 10–6 C m placed in a uniform electric field of 1.5 × 103 NC–1 in
such a way that dipole moment is along electric field. The work done in rotating dipole by 180° in this field will
be __________ mJ.
Sol. (18)
Wext = Uf – Ui U –P.E
= –PE cos – (–PE cos 0)
= 2PE
= 2 × 6 × 10–6 × 1.5 × 103
= 18 mJ
54. An organ pipe 40 cm long is open at both ends. The speed of sound in air is 360 ms –1. The frequency of the
second harmonic is __________ Hz.
Sol. (900)
Open organ pipe = 40 cm
Speed of sound v = 360 m/s
2v
Frequency of second harmonics f 2
2
v 360
f2 f2
0.4
f 2 900 Hz
55. The moment of inertia of a semicircular ring about an axis, passing through the center and perpendicular to the
1
plane of ring, is MR2, where R is the radius and M is the mass of the semicircular ring. The value of x will
x
be __________.
Sol. (1)
R
I
axis
I dmR 2 R 2 dm MR 2
I = MR2
1
Given I = MR 2
x
x=1
56. Two vertical parallel mirrors A and B are separated by 10 cm. A point object O is placed at a distance of 2 cm
from mirror A. The distance of the second nearest image behind mirror A from the mirror A is _________ cm.
Sol. (18)
d = 2 + 16
d = 18 cm
57. The magnetic intensity at the center of a long current carrying solenoid is found to be 1.6 × 10 3 Am–1. If the
number of turns is 8 per cm, then the current flowing through the solenoid is __________ A.
Sol. (2)
H = 1.6 × 103 A/m, n = 8 per cm = 800 per m
H
H = nI I =
n
1.6 103
I= I=2A
8 10 2
58. A current of 2 A through a wire of cross-sectional area 25.0 mm2. The number of free electrons in a cubic meter
are 2.0 × 1028. The drift velocity of the electrons is ________ × 10–6 ms–1
(given, charge on electron = 1.6 × 10–19 C).
Sol. (25)
I = neAVd
I 2
Vd = Vd =
neA 2 10 1.6 10 19 25 10 6
28
Vd = 25 m/s
59. An oscillating LC circuit consists of a 75 mH inductor and a 1.2 F capacitor. If the maximum charge to the
capacitor is 2.7 C. The maximum current in the circuit will be __________ mA.
Sol. (9)
LC oscillation L = 75 mH
C = 1.2 F
Umax L = Umax C
1 1 q 2max
LI2max =
2 2 C
q 2.7 10 6
Imax = max Imax =
LC 75 10 3 1.2 10 6
Imax = 9 × 10-3 A
Imax = 9 mA
60. An air bubble of diameter 6 mm rises steadily through a solution of density 1750 kg/m3 at the rate of 0.35 cm/s.
TGe co-efficient of viscosity of the solution (neglect density of air) is __________ Pas (given, g = 10 ms–2).
Sol. (10)
Fv=6prv
For uniform velocity net force = 0
B = 6rv
4
r3g = 6rv
3
2 r 2 g
=
9v
2 1750 (3 10 3 ) 2 10
=
9 0.35 10 2
= 10 Pa-s
SECTION - A
61. The reaction
1
H2(g)+Ag(Cl)(s) H+(aq)+Cl–(aq)+Ag(s)
2
occurs in which of the given galvanic cell.
(1) Pt H2(g)HCl(soln)AgNO3(soln)Ag (2) Pt H2(g) HCl(soln)AgCl(s) Ag
(3) Pt H2(g)KCl(soln)AgCl(s)Ag (4) Ag AgCl(s) KCl(soln)AgNO3 Ag
Sol. 2
Anode H2 2H+ + 2e–
Cathode AgCl + e– Ag + Cl–
62. Sulphur (S) containing amino acids from the following are:
(a) isoleucine (b) cysteine (c) lysine (d) methionine
(e) glutamic acid
(1) b, c, e (2) a, d (3) a, b, c (4) b, d
Sol. 4
(a) isoleucine : CH3 CH2 CH CH COOH
CH3 NH2
(b) cysteine : HS CH2 CH COOH
NH2
(c) lysine H
: 2N—(CH )
2 4—CH—COOH
NH2
(d) methionine : CH3—S—CH2—CH2—CH—COOH
NH2
(e) glutamic acid : HOOC—CH2—CH2—CH—COOH
NH2
63. Which of the following complex is octahedral, diamagnetic and the most stable?
(1) K3[Co(CN)6] (2) [Ni(NH3)6]Cl2 (3) [Co(H2O)6]Cl2 (4) Na3[CoCl6]
Sol. 1
K3[Co(CN)6]
+3+x–6=0
x 3
Co+3 3d6
u-e = 0
So diamagnetic
64. Which of the following metals can be extracted through alkali leaching technique?
(1) Cu (2) Au (3) Pb (4) Sn
Sol. 4
Sn due to Amphoteric nature.
65. The correct order of spin only magnetic moments for the following complex ions is
(1) [CoF6]3–<[MnBr4]2–< [Fe(CN)6]3–<[Mn(CN)6]3–
(2) [Fe(CN)6]3–<[CoF6]3–< [MnBr4]2–<[Mn(CN)6]3–
(3) [MnBr4]2–<[CoF6]3–< [Fe(CN)6]3–<[Mn(CN)6]3–
(4) [Fe(CN)6]3–<[Mn(CN)6]3–< [CoF6]3–<[MnBr4]2–
Sol. 4
[CoF6]3– [MnBr4]2– [Fe(CN)6]3– [Mn(CN)6]3–
+3 +2 5
CO Mn 3d Mn+3
– – –
F WFL Br WFL CM SFL CN– is SFL
So no pairing So no pairing Pairing occur So pairing occur
(3) (4)
Sol. 4
COOH COOH
(i) LiBH4/EtOH
C—O—Et (ii) H3O+
CH2—CH2—OH
O
Note: Lithium borohydride is commonly used for selective reduction of esters and lactones to the corresponding
alcohol.
(1) A-III, B-II, C-I, D-IV (2) A-II, B-I, C-III, D-IV
(3) A-IV, B-III, C-II, D-I (4) A-I, B-II, C-III, D-IV
Sol. Bouns
Data based
Maximum allowed (ppm)
F– < 2 ppm
SO2–
4
< 5 ppm
–
NO3 < 50 ppm
Zn < 500 ppm
71. In chromyl chloride, the number of d-electrons present on chromium is same as in (Given at no. of Ti : 22, V :
23, Cr : 24, Mn : 25, Fe : 26)
(1) Fe (III) (2) V (IV) (3) Ti (III) (4) Mn (VII)
Sol. 4
CrO2Cl2 Chromyl chloride
Cr+6 4s0 3d0
Mn(vii) Mn+7 Same
4s0 3d0
72. Given below are two statements: One is labelled as Assertion A and the other is labelled as Reason R.
Assertion A : Butan-1-ol has higher boiling point than ethoxyethane.
Reason R : Extensive hydrogen bonding leads to stronger association of molecules.
In the light of the above statements, choose the correct answer from the options given below:
(1) Both A and R are true but R is not the correct explanation of A
(2) Both A and R are true and R is the correct explanation of A
(3) A is false but R is true
(4) A is true but R is false
Sol. 2
At comparable molecular mass, alcohol has higher b.p. than ether due to H-bond, because H-bond leads to
stronger associated of molecules.
I.
B. Neutral FeCl3 solution
II.
C. Alkaline chloroform
solution
III.
D. Potassium iodide and
sodium hypochlorite
IV.
A. I.
B. HBF4,
II.
C. Cu, HCl
III.
D. CuCN/KCN
IV.
N2Cl HBF4, F
(B) + BF3 + N2
(Bolz-schimann reaction)
N2Cl (Cu, HCl) Cl
(C) (Gattermann synthesis)
N2Cl CuCN/KCN CN
(D)
P log P
79. Which halogen is known to cause the reaction given below:
2Cu2+ + 4X– Cu2X2(s) + X2
(1) All halogens (2) Only chlorine (3) Only Bromine (4) Only Iodine
Sol. 4
(Only iodine)
2Cu2+ + 4I– Cu2I2 + I2
80. Choose the halogen which is most reactive towards SN1 reaction in the given compounds (A, B, C, & D)
(C)
Br(a) Br(b) Becouse, we con’t remove Br(a) from bridge head carbon (Bredt’s rule)
Me
Br(b)
(D) Becouse, formed intermediate by Br(a), 3o carbocation is more stable (stability of
Br(a)
carbocation 3o > 2o > 1o)
SECTION - B
81. Molar mass of the hydrocarbon (X) which on ozonolysis consumes one mole of O3 per mole of (X) and gives
one mole each of ethanol and propanone is ___________g mol–1 (Molar mass of C : 12 g mol–1, H : 1 gmol–1)
Sol. 70
O
O3
Reactant + CH3CHO
CH3
CH3 C CH CH3
(C5H10)
Molecular Mass = 70
84. The titration curve of weak acid vs. strong base with phenolphthalein as indictor) is shown below. The
Kphenolphthalein = 4×10-10
Given : log 2 = 0.3
The number of following statements/s which is/are correct about phenolphthalein is__________
(1) It can be used as an indicator for the titration of weak acid with weak base.
(2) It begins to change colour at pH = 8.4
(3) It is a weak organic base
(4) It is colourless in acidic medium
Sol. 2
(B) pk n log(4 10 10 ) 9.4
Indicator range
pkIn 1
i.e. 8.4 to 10.4
(D) In acidic medium, phenolphthalein is in unionized form and is colourless.
85. When a 60 W electric heater is immersed in a gas for 100s in a constant volume container with adiabatic walls,
the temperature of the gas rises by 5oC. The heat capacity of the given gas is_______J K–1 (Nearest integer)
Sol. 1200
Adiabatic wall {no heat exchange between system and surrounding}
Cv × T = P × t/sec
Cv × 5 = 60 × 100
Cv = 1200
86. The vapour pressure vs. temperature curve for a solution solvent system is shown below:
87. 0.5 g of an organic compound (X) with 60% carbon will produce______×10–1 g of CO2 on complete combustion.
Sol. 11
0.5 0.6
Moles of carbon =
12
0.5 0.6
Moles of CO2 =
12
0.5 0.6
Mass of CO2 = 44 11 10 –1 gram
12
88. The number of following factors which affect the percent covalent character of the ionic bond is_____
(1) Polarising power of cation (2) Extent of distortion of anion
(3) Polarisability of the anion (4) Polarising power of anion
Sol. 3
Percent covalent character of the ionic bond
(1) Polarising power of cation (2) Extent of distortion of anion
(3) Polarisability of the anion
89.
Three bulbs are filled with CH4, CO2 and Ne as shown the picture. The bulbs are connected through pipes of
zero volume. When the stopcocks are opened and the temperature is kept constant throughout, the pressure of
the system is found to be________atm. (Nearest integer)
Sol. 3
Pf Vf = P1 V1 + P2 V2 + P3 V3
Pf × 9 = 2 × 2 + 4 × 3 + 3 × 4
28
Pf 3.11 3
9
x 1 y 2 z 5
2. Let P be the plane passing through the line and the point (2, 4, –3). If the image of the
1 3 7
point (-1, 3, 4) in the plane P is (, , ) then + + is equal to
(1) 12 (2) 9 (3) 10 (4) 11
Sol. (3)
Equation of plane is given by
x 1 y 2 z 5
1 2 2 =0
1 3 7
4x – y – z = 7
1 3 4 2 4 3 4 7
2
4 1 1 16 1 1
= 7, = 1, = 2
+ + = 10 (Option 3)
1 5 -1
If A , A = A + I and + = -2, then 4 + + is equal to :
2 2 2
3.
10
(1) 14 (2) 12 (3) 19 (4) 10
Sol. (1)
1 x 5
A xI 0 0 x2 – 11x + 10 – 5 = 0
10 x
10 5 A 1 A 11I
1 11
and
10 5 10 5
10
2 2 10-5 = –5 =3
10 5
1 11
&
5 5
4 121 2
4a 2 2 2 3 14 Ans.
25 25
4. The area of the quadrilateral ABCD with vertices A(2,1,1), B (1,2, 5), C(–2,–3, 5) and D (1, -6, -7) is equal to
(1) 54 (2) 9 38 (3) 48 (4) 8 38
Sol. (4)
Vector Area = v
1 1
AB AC AC AD
2 2
AB i j 4kˆ
1
2
AB AD AC AD i 7 j 8kˆ
AC 4i 4 j 4kˆ
1
2
8j 12kˆ 4 i j kˆ
i j kˆ
1
0 8 12
2
1 1 1
= (–2) 20i 12j 8kˆ
8 5i 3j 2kˆ
Area = v 8 25 9 4 8 38 Ans.
Circumcircle of OPQ
(x – 0) (x–3) + (y–0) (y + 2) = 0
x2 + y2 – 3x + 2y = 0
1
passes through ,
2
1
2 + – 3 + 1 = 0
4
5
2 – 3 + = 0 42 – 12 + 5 = 0
4
42 – 10 – 2 + 5 = 0
1 5
(2 – 1) (2 – 5) = 0 , Ans.
2 2
n
7. Let an be the nth term of the series 5 + 8 + 14 + 23 + 35 + 50 +.... and Sn a K . Then S30 a40 is equal to
k 1
O = 5 + 3 + 6 + 9 + 12 + 15 + .... – an
an = 5 + (3 + 6 + 9 + ... (n–1) terms)
3n 2 3n 10
an
2
3 40 3 40 10
2
a 40 2345
2
30 30 30
3 n 2 3 n 101
S30 n 1 n 1 n 1
2
3 30 31 61 3 30 31
10 30
6 2
2
S30 = 13635
S30 – a40 = 13635 – 2345
= 11290 (Option (3))
1
1 cos(x 2 bx a) 2 1 1 1
8. If > > 0 are the roots of the equation ax2 + bx + 1 = 0, and lim , then k
x
1 2(1 ax)2 k
is equal to
(1) (2) 2 (3) 2 (4)
Sol. (2)
1
ax2 + bx + 1 = a(x – )(x – )
a
x2 + bx + a = a (1 – x) (1 –x)
1 1
1 cos x 2 bx a 2 1 cosa 1 x 1 x 2 2
2
lim lim1 a 1 x
x 2 a 1 x 1 x
1 2 2
x 2 1 x
2
1
1 1 2 2
a 2 1
2 2
1 1 1 1 1
1 2
2 2
1 1 1 11 1
2 k
k 2 Ans.
9. If the number of words, with or without meaning, which can be made using all the letters of the word
MATHEMATICS in which C and S do not come together, is (6!)k, is equal to
(1) 1890 (2) 945 (3) 2835 (4) 5670
Sol. (4)
M2A2T2HEICS
= total words – when C & S are together
11 10
2
2 2 2 2 2 2
10
9
2 2 2
9 10 9 8 7
6
8
= 5670 6
k = 5670 (Option 4)
10. Let S be the set of all values of [–,] for which the system of linear equations
x y 3z 0
x tan y 7z 0
x y tan z 0
120
has non-trivial solution. Then is equal to
S
(1) 20 (2) 40 (3) 30 (4) 10
Sol. (1)
For non trivial solutions
D=0
1 1 3
1 tan 7 0
1 1 tan
tan 2
3 1 3 0
tan 3, 1
2 3
, , ,
3 3 4 4
120 120
20 (Option 1)
6
11. For a, b Z and |a b| 10, let the angle between the plane P : ax + y z = b and the line l : x 1 = a y = z
1
+1 be cos 1 . If the distance of the point (6, 6, 4) from the plane P is 3 6 , then a4 + b2 is equal to
3
(1) 85 (2) 48 (3) 25 (4) 32
Sol. (4)
1 1 2 2
cos1 sin 1
3 9 3
a 1 1 1 1 1 2 2
sin
a2 11 3 3
3 a 2 24 a 2 2
2
3 a 2 4a 4 8a 2 16
5a 2 12a 4 0
5a 2 10a 2a 4 0
2
a 2, az
5
a 2
Distance of (6, –6, 4) from
–2x + y – z – b = 0 is 3 6
12 6 4 b
3 6
4 11
b 22 18 b 40, 4
a b 10
b 4
a 4 b2
= 32 Ans.
12. Let the vectors u1 ˆi ˆj ak,
ˆ ˆi bjˆ kˆ and u ciˆ ˆj kˆ be coplanar. If the vectors
2 3
11
1
13. The absolute difference of the coefficients of x10 and x7 in the expansion of 2x 2 is equal to
2x
(1) 103 10 (2) 113 11 (3) 123 12 (4) 133 13
Sol. (3)
r
1
Tr+1 = 11Cr(2x2)11–r
2x
11 11–2r 22–3r
= Cr 2 x
22 – 3r = 10 and 22 – 3r = 7
r = 4 and r=5
Coefficient of x10 = 11C4 23
Coefficient of x7 = 11C5 21
difference = 11C4 23 – 11C5 2
11 10 9 8 11 10 9 8 7
8 2
24 120
= 11 10 3 8 – 11 3 4 7
= 11 3 4 (20 – 7)
= 11 12 13
= 12 (12 – 1) (12 + 1)
= 12 (122 – 1)
= 123 – 12 (Option 3)
14. Let A = {1, 2, 3, 4, 5, 6, 7}. Then the relation R = {(x,y) A × A : x + y =7} is
(1) Symmetric but neither reflexive nor transitive
(2) Transitive but neither symmetric nor reflexive
(3) An equivalence relation
(4) Reflexive but neither symmetric nor transitive
Sol. (1)
R = {(1,6), (2,5), (3,4), (4,3),(5,2), (6,1)}
15. If the probability that the random variable X takes values x is given by P(X=x) = k (x+1)3-x, x = 0, 1,2, 3, ...,
where k is a constant, then P(X 2) is equal to
7 11 7 20
(1) (2) (3) (4)
27 18 18 27
Sol. (1)
PX x 1
x 0
2s 1 1 1
1 2 2 ...
3 3 3 3
2s 1 3
3 1 1 2
3
9
s
4
4
so k
9
P X 2 1 P x 0 P x 1
4 2
1 1
9 3
7
(Option 1)
27
x x 2 x
16. The integral log2 x dx is equal to
2 x
x x x
x 2 x 2
(1) log 2 C (2) C
2 x 2 x
x x x
x x x 2
(3) log 2 C (4) C
2 2 2 x
Sol. (2) Bonus
x 2 2 x log2 dx
x x x x x
e e x ln 2 ex ln 2 e x ln x dx
x ln x
e e x ln 2 x ln x
x ln x x ln 2 ln x
dx
ln 2
let xlnx – xln2 = t
(lnx + 1 – ln2) dx = dt
17. The value of 36 (4cos2 9º 1)(4 cos2 27º 1) (4 cos2 81º 1) (4 cos2 243º 1) is
(1) 27 (2) 54 (3) 18 (4) 36
Sol. (4)
sin 3
4cos2 – 1 = 4(1–sin2) – 1 = 3 – 4 sin2 =
sin
so given expression can be written as
sin 27o sin 81o sin 243o sin 729o
36
sin 9o sin 27o sin 81o sin 243o
sin 729o
36 36
sin 9o
18. Let A (0, 1), B(1,1) and C (1,0) be the mid-points of the sides of a triangle with incentre at the point D. If the
focus of the parabola y2 = 4ax passing through D is 3,0 , where and are rational numbers, then 2
is equal to
9
(1) 6 (2) 8 (3) (4) 12
2
Ans. (2)
a = OP = 2 b = OQ = 2 c = PQ = 2 2
(2,0) (0,2) (0,0)
4 4 2 2
D , D ,
222 2 222 2 2 2 2 2
2
2 2
y 4ax
2
4a
2 2 2 2
1 2 2 1
4a
2
2 2
a
2 42
2 2
4
2 1 1
4 2 4
2 8 Ans.
9
20. Let the mean and variance of 12 observations be and 4 respectively. Later on, it was observed that two
2
m
observations were considered as 9 and 10 instead of 7 and 14 respectively. If the correct variance is , where
n
m and n are coprime, then m + n is equal to
(1) 316 (2) 317 (3) 315 (4) 314
Sol. 2
x 9
12 2
x = 54
x 2 9
2
4
12 2
x2 = 291
xnew = 54 – (9 + 10) + 7 + 14 = 56
x2new = 291 – (81 + 100) + 49 + 196 = 355
2
355 56
2new
12 12
281 m
2new
36 n
m n 317 Option (2)
SECTION - B
21. Let R = {a, b, c, d, e} and S = {1, 2, 3, 4}. Total number of onto functions f : R S such that f(a) 1, is equal
to _______.
Sol. 180
Total onto function
5
4 240
3 2
Now when f(a) = 1
4
4 3 = 24 + 36 = 60
2 2
so required fn = 240 – 60 = 180
22. Let m and n be the numbers of real roots of the quadratic equations x2 12x + [x] + 31 = 0 and x2 5 |x + 2 | 4
= 0 respectively,where [x] denotes the greatest integer x. Then m2 +mn + n2 is equal to ________.
Sol. 9
x2 – 12x + [x] + 31 = 0
{x} = x2 – 11 x + 31
0 x 2 11x 31 1
x2 – 11x + 30 < 0
x (5, 6)
so [x] = 5
x2 – 12x + 5 + 31 = 0
x2 – 12x + 36 = 0
x 6 but x(5, 6)
so x
m0
Now
x2 –5x–14=0 x2 + 5x +6 = 0
(x–7)(x+2)=0 (x+3)(x+2) =0
x = 7, –2 x = –3, –2
23. Let P1 be the plane 3x y 7z = 11 and P2 be the plane passing through the points (2,1,0), (2,0,1), and (5, 1,
1). If the foot of the perpendicular drawn from the point (7, 4, 1) on the line of intersection of the planes P1
and P2 is (, , ), then + + is equal to _____.
Sol. 11
P2 is given by
x 5 y 1 z 1
3 2 1 0
3 1 2
xyz 3
DR of line intersection of P1 & P2
i j k
1 1 1
3 1 7
6i 4j 2kˆ
Let z = 0, x – y = 3
3x – y = 11
2x = 8
x=4
y=1
So Line is
x 4 y 1 z 0
r
6 4 2
() = (6r +4, 4r + 1, 2r)
6 7 4 4 2 1 0
6 42 4 16 2 2 0
36r 24 16r 4 4r 56 0
56r 28
1
r
2
+ + = 12r + 5
= 6 + 5 = 11
6x 2 5x 1 1 2x 3x 4
2
24. If domain of the function loge cos is (,) (,], then, 18( + + + )
2 2 2 2
2x 1 3x 5
is equal to
Sol. 20
6x 2 5x 1
0
2x 1
3x 1 2x 1 0
2x 1
1 1 1
x , , ....(A)
2 3 2
and
2x 2 1 2x 2 6x 9
0 and 0
3x 5 3x 5
and 3x – 5 < 0
1 1 5
x , , ...(B)
2 2 3
5
x ...(C)
3
1 1 1 1
A BC , ,
2 3 2 2
1 1 1 1
So 18 2 2 2 2 18
4 9 4 2
= 18 + 2 = 20
3
25. Let the area enclosed by the lines x + y = 2, y = 0 x = 0 and the curve f (x) min x 2 ,1 [x] where [x]
4
denotes the greatest integer x, be A. Then the value of 12A is______.
Sol. 17
3 1 3 1
2
x dx 1
2
0
4 2 2 2
1
x 3 3x 2
1
3 4 0
1 3
A 1
24 8
1 36
12A 12
2 8
1 9
12
2 2
= 5 + 12
= 17
1 1 1
26. Let 0 < z < y < x be three real numbers such that , , are in an arithmetic progression and x, 2y, z are in
x y z
3
a geometric progression. If xy + yz + zx = xyz , then 3(x + y + z)2 is equal to______.
2
Sol. 150
2 1 1
y x z
2y2 xz
2 xz xz
y xz 2y2
x + z = 4y
3
xy + yz + zx = xyz
2
3
y(x+z) + zx = xz y
2
3
4y 2 2y 2 y 2y 2
2
6y 2 3 2y3
y 2
x + y + z = 5y = 5 2
3(x + y + z)2 = 3 50 = 150
27. Let the solution curve x = x (y), 0 < y < , of the differential equation (loge (cos y))2 cos y dx (1 + 3x loge
2
1 1
(cos y)) sin y dy = 0 satisfy x . If x , where m and n are co-prime, then mn
3 2log e 2 6 log e m log e n
is equal to
Sol. 12
Cos yln2cosydx = (1 + 3x ln cosy)sin y dy
dx 3x 1
tan y 2
dy ln cos y ln cos y
dx 3tan y tan y
x 2
dy ln cos y ln cos y
3 sin y
dy
ln cos y cos y
If = e
ln cosy = t
1
sin ydy dt
cos y
3
dt
If = e t e3ln t t 3 ln 3 cos y
sin y
solution is x ln 3 cos y ln cos ydy C
cos y
ln 2 cos y
x ln 3 cos y C
2
1
ln 3
1
ln 3 = C
1 1 2
x so
3 2ln 2 2ln 2 2 2
C=0
3 1 3
y x ln 3 ln 2 0
6 2 2 2
1
x
3
2ln
2
1 1
x
4 ln 4 ln 3
ln
3
mn = 12
2.4
_______.
Sol. 6
1 2 3 2 5 2 4
0dx 1dx
0 1
2dx 3dx 4dx
2
5dx
2 3 5
2 1 2
3 2 3 2 3 4
5 2 5 2 4 5
9 2 3 5
9 111 6
29. The ordinates of the points P and Q on the parabola with focus (3.0) and directrix x=3 are in the ratio 3 : 1 :.
2
If R (,) is the point of intersection of the tangents to the parabola at P and Q, then is equal to ________.
Sol. 16
Parabola is y2 = 12x
Let Q(3t2, 6t)
so P(27t2, 18t)
R , at1t 2 ,a t1 t 2
= (3t3t, 3(t + 3t))
R() = (9t2, 12t)
2 12t 144
2
16
9t 2 9
3x 2 k x 1, 0 x 1
30. Let k and m be positive real numbers such that the function f x is differentiable
mx k ,
2 2
x 1
8f '(8)
for all x > 0. Then is equal to_______.
1
f '
8
Sol. 309
function is differentiable x < 0
so f(1–) = f(1)
3 2k m k 2 ...(1)
and f 1 1 f –1 1
k
2mx x 1 6x x 1
2 x 1
k
2m 6
2 2
k
m 3 ...(2)
4 2
k
k2 3 3 2k
4 2
7
k ,0
4 2
7
m 3
32
103
m
32
8f ' 8 2mx x 8
So 8
1 k
f ' 6x
8 2 x 1 x
1
8
103
8 28
32
16
12
= 103 3 = 309
SECTION - A
31. A hydraulic automobile lift is designed to lift vehicles of mass 5000 kg. The area of cross section of the cylinder
carrying the load is 250 cm2. The maximum pressure the smaller piston would have to bear is
[Assume g = 10 m/s2] :
(1) 2 × 10+5 Pa (2) 20 × 10+6 Pa (3) 200 × 10+6 Pa (4) 2 × 10+6 Pa
Sol. (4)
5000 kg
A=250 cm2
32. The orbital angular momentum of a satellite is L, when it is revolving in a circular orbit at height h from earth
surface. If the distance of satellite from the earth center is increased by eight times to its initial value, then the
new angular momentum will be-
(1) 8L (2) 3L (3) 4L (4) 9L
Sol. (2)
GM
L = mv0r v 0
h
L m GMh …….(1)
m v0
h’ h + 8h = 9h
L’ = m GM9h ……..(2)
h
L'
3
L M
L’ = 3L
33. The waves emitted when a metal target is bombarded with high energy electrons are
(1) Microwaves (2) X-rays (3) Radio Waves (4) Infrared rays
Sol. (2)
By theory
36. The power radiated from a linear antenna of length l is proportional to (Given, = Wavelength of wave):
2
l l2 l l
(1) (2) (3) 2 (4)
Sol. (4)
37. Electric potential at a point 'P' due to a point charge of 5 × 10–9C is 50 V. The distance of 'P' from the point
charge is:
1
(Assume, = 9 × 10+9 Nm2C–2)
4 0
(1) 3 cm (2) 9 cm (3) 0.9 cm (4) 90 cm
Sol. (4)
1 q
V
40 r
9 109 5 109
r=
50
9
r= 100cm
10
r = 90 cm
38. The acceleration due to gravity at height h above the earth if h<<R (Radius of earth) is given by
h2 h 2h 2 2h
(1) g ' g 1 (2) g ' g 1 (3) g ' g 1 2 (4) g ' g 1
2R 2
2R R R
Sol. (4)
GM
g’ =
(R h)2
GM
g’ = 2
h
R2 1
R
using binomial expansion & neglect higher order term
2h
g’ = g 1
R
39. An emf of 0.08 V is induced in a metal rod of length 10 cm held normal to a uniform magnetic field of 0.4 T,
when moves with a velocity of:
(1) 2 ms–1 (2) 20 ms–1 (3) 3.2 ms–1 (4) 0.5 ms–1
Sol. (1)
= Blv
10
0.08 v 0.4
100
v = 2 m/s
40. Work done by a Carnot engine operating between temperatures 127°C and 27°C is 2 kJ. The amount of heat
transferred to the engine by the reservoir is:
(1) 2 kJ (2) 4 kJ (3) 2.67 kJ (4) 8 kJ
Sol. (4)
T1
(400 k) 127°C = 127 + 273 = 400 k
Q1
H.E w = 2kJ
Q2
41. The width of fringe is 2 mm on the screen in a double slits experiment for the light of wavelength of 400 nm.
The width of the fringe for the light of wavelength 600 nm will be:
(1) 1.33 mm (2) 3 mm (3) 2 mm (4) 4 mm
Sol. (2)
D
=
d
1 1 2 400
2 2 600
= 3 mm
42. The temperature at which the kinetic energy of oxygen molecules becomes double than its value at 27°C is
(1) 1227°C (2) 627°C (3) 327°C (4) 927°C
Sol. (3)
1
KE of O2 molecules = 5 × KT
2
1 5
(KE)27°C = 5 × k(27 273) k 300
2 2
5 5
(KE)T = 2 k 300 k(600)
2 2
i.e. T = 600 K
= 600 – 273
T = 327°C
43. Given below are two statements : one is labelled as Assertion A and the other is labelled as Reason R
Assertion A : Electromagnets are made of soft iron.
Reason R : Soft iron has high permeability and low retentivity.
In the light of above, statements, chose the most appropriate answer from the options given below.
(1) A is correct but R is not correct
(2) Both A and R are correct and R is the correct explanation of A
(3) Both A and R are correct but R is NOT the correct explanation of A
(4) A is not correct but R is correct
Sol. (2)
x2
44. The trajectory of projectile, projected from the ground is given by y = x . Where x and y are measured in
20
meter. The maximum height attained by the projectile will be.
(1) 10 m (2) 200 m (3) 10 2 m (4) 5 m
Sol. (4)
x2
y=x–
20
dy x dy
1– for ymax ;
dx
=0
dx 10
x = 10
100
ymax = 10 – 5m
20
45. A bullet of mass 0.1 kg moving horizontally with speed 400 ms–1 hits a wooden block of mass 3.9 kg kept on a
horizontal rough surface. The bullet gets embedded into the block and moves 20 m before coming to rest. The
coefficient of friction between the block and the surface is _______.
(Given g = 10 m/s2)
(1) 0.90 (2) 0.65 (3) 0.25 (4) 0.50
Sol. (3)
0.1kg
3.9kg
kg
400 m/s kg
Before collision
u’ v=0
4kg
20m
After collision
Apply momentum conservation just before and just after the collision
0.1 × 400 = (3.9 + .1) u’
u = 10 m/s
1
0– (4)(10)2 (4)g 20
2
= 0.25
46. For a given transistor amplifier circuit in CE configuration V CC = 1 V, RC = 1 k, Rb = 100 k and = 100.
Value of base current Ib is
(1) Ib = 100 A (2) Ib = 10 A (3) Ib = 0.1 A (4) Ib = 1.0 A
Sol. (2)
Vcc = 1 V
Rc Ic = 1
1
Ic = 3 A = 1 mA
10
I
= c
I
IC
I
= 1 × 10-5 A
= 10 A
47. For particle P revolving round the centre O with radius of circular path r and angular velocity , as shown in
below figure, the projection of OP on the x-axis at time t is
(1) x(t) = rcos t (2) x(t) = rcos t
6 6
(3) x(t) = rcos (t) (4) x(t) = rsin t
6
Sol. (1)
= t
y
30°
r
Angle from x axis = t +
6
Projection of OP on x axis = r cos t
6
48. A radio active material is reduced to 1/8 of its original amount in 3 days. If 8 × 10 –3 kg of the material is left
after 5 days the initial amount of the material is
(1) 64 g (2) 40 g (3) 32 g (4) 256 g
Sol. (4)
m = m0 e-t
m0
= m0 e-t
8
–ln8 = –t
ln 8
== per day
3
m = m0 e-t
ln 8
5
3
8 = m0 e
3ln 2
5
8 = m0 e 3
5
8 = m0 e ln 2
1
= 8 m0 5
2
m0 = 8 × 25
= 8 × 32
m0 = 256 gm
53. The number density of free electrons in copper is nearly 8 × 1028 m–3. A copper wire has its area of cross section
= 2 × 10–6 m2 and is carrying a current of 3.2 A. The drift speed of the electrons is ________ ×10–6 ms–1
Sol. (125)
I = neAvd
3.2 = 8 × 1028 × 1.6 × 10–19 × 2 × 10–6 (vd)
1
vd = 6
8 10 109
vd = 125 × 10–6 m/s
54. A hollow spherical ball of uniform density rolls up a curved surface with an initial velocity 3 m/s (as shown in figure).
Maximum height with respect to the initial position covered by it will be _________ cm (take, g = 10 m/s2)
Sol. (75)
For pure rolling
0=v0/R B
Hmax
v
A
(M.E)A = (M.E)B
2
1 1 2 v
mv 20 mR 2 0 mg H max
2 2 3 R
5 v 20 5 32
H max 0.75m
6 g 6 10
Hmax 75cm
55. A steel rod of length 1 m and cross sectional area 10–4 m2 is heated from 0°C to 200°C without being allowed
to extend or bend. The compressive tension produced in the rod is __________ × 104N. (Given Young's modulus
of steel = 2 × 1011 Nm–2, coefficient of linear expansion = 10–5K–1)
Sol. (4)
Thermal stress = Y T
F = Y A T
= 2 × 1011 × 10–4 × 10– 5 × 200
= 4 × 104
x=4
56. The ratio of magnetic field at the centre of a current carrying coil of radius r to the magnetic field at distance r
from the centre of coil on its axis is x :1 . The value of x is ________
Sol. (8)
0iR 2
Baxis =
2(R 2 x 2 )3/2
0 iR 2
(Baxis )x R 2(R 2 R 2 )3/2 R3 1
2
(Baxis )x 0 0 iR 3/2 3
2 R 8
2 3/2
2(R )
(B)At centrs 8
(B)At x R 1
x=8
x
57. The ratio of wavelength of spectral lines H and H in the Balmer series is . The value of x is _______
20
Sol. (27)
58. Two transparent media having refractive indices 1.0 and 1.5 are separated by a spherical refracting surface of
radius of curvature 30 cm. The centre of curvature of surface is towards denser medium and a point object is
placed on the principle axis in rarer medium at a distance of 15 cm from the pole of the surface. The distance of
image from the pole of the surface is __________ cm.
Sol. (30)
=1
= 1.5
u
15 cm
R = 30 cm
1.5 1 1.5 1
–
v (–15) 30
1.5 1 1 14
– –
v 60 15 60
V = – 30 cm
= 30 cm
59. A guitar string of length 90 cm vibrates with a fundamental frequency of 120 Hz. The length of the string
producing a fundamental frequency of 180 Hz will be __________ cm.
Sol. (60)
v
f= (Fundamental Frequency)
2L
v
120 = …….(1)
2L
v
180 = …….(2)
2L'
L' 120
L 180
2
L’ = × 90
3
L’ = 60 cm
60. A body of mass 5 kg is moving with a momentum of 10 kg ms–1. Now a force of 2 N acts on the body in the
direction of its motion for 5 s. The increase in the Kinetic energy of the body is _________ J.
Sol. (30)
P2
(KE) =
2M
10
2
1
mu2 =
2 25
1 100
= × 5 × u2 =
2 10
Initial speed u = 2 m/s
KE = wall forces
= F.S ( = 0°)
1
= F ut at 2
2
1 2
= 2. 2 5 52
2 5
= 30 J
SECTION - A
Topic: Chemistry in everyday life
Level: Med
61. The statement/s which are true about antagonists from the following is/are :
A. They bind to the receptor site
B. Get transferred inside the cell for their action
C. Inhibit the natural communication of the body
D. Mimic the natural messenger.
Choose the correct answer from the options given below:
(1) A and B (2) A and C (3) A, C and D (4) B only
Sol. 2
Antagonists bind to receptor site and inhibit the natural communication of both
(1) (2)
(3) (4)
Sol. 4
Catalysts decrease activation energy only.
Topic :
Sub Topic :
Level :
63. Given below are two statements : One is labelled as Assertion A and other is labelled as Reason R
Assertion A : Sodium is about 30 times as abundant as potassium in the oceans.
Reason R : Potassium is bigger in size than sodium.
In the light of the above statements, choose the correct answer from the options given below
(1) Both A and R are true but R is NOT the correct explanation of A
(2) A is true but R is false
(3) A is false but R is true
(4) Both A and R are true and R is the correct explanation of A
Sol. 1
Due to bigger size of potassium, it forms more efficient lattices as compared to sodium with silicates.
The abundance of sodium in ocean is more due to the more soluble nature of salt of sodium as compared to
potassium salts.
Topic :
Sub Topic :
Level :
64. Which of these reactions is not a part of breakdown of ozone in stratosphere?
(1) CF2Cl2(g)
uv
Cl(g) C F2 Cl(g) (2) C l(g) +O3(g) ClO(g) +O2(g)
(3) 2 ClO ClO2(g)+ C l (g) (4) ClO (g)+O(g) C l (g)+O2(g)
Sol. 3
Ozone destruction
CF2Cl2
hv
C l C F2 Cl(g)
C l + O3 ClO + O2
ClO + O C l O 2
Topic: Nomenclature
Level: Easy
65. The correct IUPAC nomenclature for the following compound is :
(1) (2)
(3) (4)
Sol. 2
v Z
Topic :
Sub Topic :
Level :
67. Match list I with list II
List I List II
Coordination complex Number of
unpaired electrons
A. [Cr(CN)6]3– I. 0
2+
B. [Fe(H2O)6] II. 3
C. [Co(NH3)6]3+ III. 2
D. [Ni(NH3)6]2+ IV. 4
Choose the correct answer from the options given below:
(1) A-II, B-IV, C-I, D-III (2) A-IV, B-III, C-II, D-I
(3) A-II, B-I, C-IV, D-III (4) A-III, B-IV, C-I, D-II
Sol. 1
For option (A)
Cr+3 : 3d3
CN– SFL
No. of unpaired electrons = 3
For option (B)
Fe+2 : 3d6
H2O : WFL
No. of unpaired electrons = 4
For option (C)
Co+3 : 3d6
NH3 : SFL
No. of unpaired electrons = 0
For option (D)
Ni+2 : 3d8
NH3 : SFL
No. of unpaired electrons = 2
Topic: Hydrocarbon
Level: Med
68. Major product ‘P’ formed in the following reaction is :
(1) (2)
(3) (4)
Sol. 3
••
OH O H
••
Br2
Br
O O
NaHCO3
Br O
O
Topic :
Sub Topic :
Level :
69. For a good quality cement, the ratio of lime to the total of the oxides of Si, Al and Fe should be as close as to
(1) 2 (2) 1 (3) 3 (4) 4
Sol. 1
%CaO
1.9 – 2.1
%SiO2 %Al2O3 %Fe2O3
Option (1) is correct.
Topic: Biomolecule
Level: Easy
70. Match list I with list II
List I List II
Natural amino acid One letter code
A. Glutamic acid I. Q
B. Glutamine II. W
C. Tyrosine III. E
D. Tryptophan IV. Y
Choose the correct answer from the options given below:
(1) A-III, B-I, C-IV, D-II (2) A-IV, B-III, C-I, D-II
(3) A-II, B-I, C-IV, D-III (4) A-III, B-IV, C-I, D-II
Sol. 1
A-III, B-I, C-IV, D-II
Fact
+ – +
CH3
Na O3 S N N N
H CH3
Topic: GOC
Level: Easy
73. The descending order of acidity for the following carboxylic acid is –
A. CH3COOH B. F3C – COOH C. ClCH2 – COOH D. BrCH2 – COOH
Choose the correct answer from the options given below:
(1) D > B > A > E > C (2) B > D > C > E > A
(3) E > D > B > A > C (4) B > C > D < E > A
Sol. 2
Acidity stability of conjugate base
Stability order
F3C – COO F – CH2 – COO Cl – CH2 – COO– Br – CH 2 – COO CH3COO
Topic :
Sub Topic :
Level :
74. In Hall-Heroult process, the following is used for reducing Al2O3 :-
(1) Magnesium (2) Graphite (3) Na3AlF6 (4) CaF2
Sol. 2
In case of Hall’s process, reduction of Al2O3 to Al can be done using graphite.
Topicp: Real gas
Sub: Vanderwals costant
Level: M
75. Arrange the following gases in increasing order of van der waals constant ‘a’
A. Ar B. CH4 C. H2O D. C6H6
Choose the correct options from the following
(1) A, B, C and D (2) B, C, D and A (3) C, D, B and A (4) D, C, B and A
Sol. 1
A force of attraction vanderwaal force depends on molecular size and molecular mass and there is H-bonding
in water, so correct option will be A < B < C < D.
Topic: Stoichiometry-II
Sub: titration
Level: M
76. Given below are two statement :
Statement I : In redox titration, the indicators used are sensitive to change in pH of the solution.
Statement II : In acid-base titration, the indicators used are sensitive to change in oxidation potential.
In the light of the above statement, choose the most appropriate answer from the options given below
(1) Both statement I and Statement II are incorrect
(2) Statement I is incorrect but Statement II is correct
(3) Statement I is correct but Statement II is incorrect
(4) Both Statement I and Statement II are correct
Sol. 1
Fact
Topic :
Sub Topic :
Level :
77. Which of the following can reduce decomposition of H2O2 on exposure to light
(1) Dust (2) Urea
(3) Glass containers (4) Alkali
Sol. 2
Urea acts as a stabilizer in the decomposition of H2O2
Topic :
Sub Topic :
Level :
79. A compound ‘X’ when treated with phthalic anhydride in presence of concentrated H2SO4 yields ‘Y’. ‘Y’ is
used as an acid/base indicator. ‘X’ and ‘Y’ are respectively:
(1) Anisole, methyl orange (2) Toludine, Phenolphthalein
(3) Carbolic acid, Phenolphthalein (4) Salicylaldehyde, Phenolphthalein
Sol. 3
N2Cl–
+
NO2 NO2 NH2
Br
CH3
SECTION - B
Topic :
Sub Topic :
Level :
81. The observed magnetic moment of the complex [Mn(NCS)6]x– is 6.06 BM. The numerical value of x is________
Sol. 4
[Mn(NCS)6]x–
Number of unpaired electron = 5
So, Mn must be in +2 oxidation state (Mn+2)
2 + (–6) = –x –4 = –x x=4
Topic: Thermochemistry
Sub: bomb calorimetery
Level: M
82. For complete combustion of ethane,
C2H4(g)+3O2(g) 2CO2(g)+2H2O(l)
The amount of heat produced as measured in bomb calorimeter is 1406 KJ mol–1 at 300K. The minimum value
of TS needed to reach equilibrium is (–)__________KJ (Nearest integer)
Given : R = 8.3 JK–1mol–1
Sol. 1411
G H T S at equilibrium:-
G 0
3
T S H U ngRT = 1406 ( 2) 8.3 300 10 = 1410.98 1411
Topic:Liquid solution
Sub: elvation ir boiling point
Level:E
87. If the boiling points of two solvents X and Y (having same molecular weights) are in the ratio 2 : 1 and their
enthalpy of vaporizations are in the ratio 1 : 2, then the boiling point elevation constant of X is m times the
boiling point elevation constant of Y. The value of m is________(nearest integer)
Sol. 8
RTb2 m
Kb
1000 H vap
2
(K b ) x (Tb2 M) x ( H) y 2 2 8
(K b ) y (Tb2 M) y ( H) x 1 1 1
Topic :
Sub Topic :
Level :
88. The number of species from the following carrying a single lone pair on central atom Xenon is_______
XeF5+, XeO3, XeO2F2, XeF5–, XeO3F2,XeOF4, XeF4
Sol. 4
So, Answer is 4
Topic :
Sub Topic :
Level :
89. The ratio of sigma and bonds present in pyrophosphoric acid is________
Sol. 6
12
6
2
So, Answer is 6
Topic :
Sub Topic :
Level :
90. The sum of oxidation state of the metals in Fe(CO)5, VO2+ and WO3 is_______
Sol. 10
(0) ( 4) ( 6)
Fe(CO)5 V O2 W O3
So, Sum of oxidation state = 0 + 4 + 6 = 10