Name:Ahood ID:1906271

Mohammed Almalawi
Section: XBR Group:3

Title:Preparation and analysis of double salt diammonium disulfato

nickel(ll) hexahydrate Ni(NH4)2(SO4)2.6H2O

The preparation equation and the type of the reaction:

NiSO4.6H2O + (NH4)2SO4 —> [Ni(NH4)2(SO4)2].6H2O

Addition Reaction

Preparations:

No Reagent Concentratio Volum Calculations

. n e
1 BaCl2 5٪ 100ml Wt= 5×100/100 = 5g

2 NH4OH 4:1 100ml on 80ml of NH4OH and 20ml of

H2O H2O

3 NH4OH 1:10 50ml on 5ml of NH4OH and 45ml of

H2O H2O

4 DMG 1٪ 100ml on Wt= 1×100/100 = 1g

ethanol
The chemical name and formula of the complex:

Double salt diammonium disulfato nickel(ll) hexahydrate

Ni(NH4)2(SO4)2.6H2O

The chemical structure of the complex and its geometry:

There is no structure for the double salt

The calculations of Yield & % Yield:

(2.2/154.75)×395=5.61g

2.461- 0.3 =2.161g

=(2.161/5.61)×100=38.52%
The experimental Analysis:
1) Analysis of Metal:

(29.6-29.34)×58.69/288.91=0.0528
58.69/395×100=14.85%

(0.052/0.3)×100=17.6%

2) Analysis of Ligand:

(18.753-18.5)×96/233.38=0.10

(0.10/0.2)×100=52%

=96/395×100=24.30%
 3) Calculations

%H2O=100-(17.6+52+9.12)=21.28

17.3/58.69=0.29 52/96=0.54 9.12/18=0.51 21.28/18=1.18

0.29/0.29=1 0.54/0.29=2 0.51/0.29=2 1.19/0.29=4

The empirical formula is Ni(NH4)2(SO4)2.4H2O

Ratio is 1:2:2:4

=58.69/395×100=14.85%

=96/395×100=24.30%

=18/395×100=4.55%

Theoretical % of H2O = 100% - Ni% - SO4% - NH4% =

=100-14.85-24.30-4.55 = 56.3%
Questions & Answers:

1-White powder after it crushed with

smell of ammonia
2-Red after the oven with no smell